CN110252128A - A kind of oily sludge vent gas treatment bio-trickling filter and treatment process - Google Patents

A kind of oily sludge vent gas treatment bio-trickling filter and treatment process Download PDF

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Publication number
CN110252128A
CN110252128A CN201910644982.0A CN201910644982A CN110252128A CN 110252128 A CN110252128 A CN 110252128A CN 201910644982 A CN201910644982 A CN 201910644982A CN 110252128 A CN110252128 A CN 110252128A
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Prior art keywords
tail gas
gas
treatment
road
unit
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Pending
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CN201910644982.0A
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Chinese (zh)
Inventor
李朝廷
尤芳
陆丹枫
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Wuxi Xuelang Environmental Technology Co Ltd
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Wuxi Xuelang Environmental Technology Co Ltd
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Priority to CN201910644982.0A priority Critical patent/CN110252128A/en
Publication of CN110252128A publication Critical patent/CN110252128A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/007Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by irradiation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/38Removing components of undefined structure
    • B01D53/44Organic components
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/75Multi-step processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/76Gas phase processes, e.g. by using aerosols
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/84Biological processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/10Oxidants
    • B01D2251/104Ozone
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708Volatile organic compounds V.O.C.'s
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/80Employing electric, magnetic, electromagnetic or wave energy, or particle radiation
    • B01D2259/804UV light
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Molecular Biology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Toxicology (AREA)
  • Dispersion Chemistry (AREA)
  • Treating Waste Gases (AREA)

Abstract

The present invention provides a kind of oily sludge vent gas treatment bio-trickling filter, the treatment effect to tail gas can be turned up, and can reduce equipment volume simultaneously.Corresponding tail gas treatment process is provided simultaneously.It includes prizing body, vent gas treatment channel is arranged in prizing body inner cavity, vent gas treatment channel includes tail gas air inlet, fume treatment area, exhaust tube, fume treatment area includes tail gas treating unit, by being linked in sequence every road between tail gas treating unit, tail gas treating unit respectively includes the air intake duct set gradually from bottom to up, cell processing area, gas off-take;Between two adjacent tail gas treating units, the air intake duct of the gas off-take of previous tail gas treating unit, the latter tail gas treating unit is respectively communicated with the air inlet at the top every road between two tail gas treating units and the gas vent of bottom;Air intake duct in first processing unit in tail gas treating unit is connected to tail gas air inlet;Gas off-take in the last one processing unit in tail gas treating unit connects exhaust tube.

Description

A kind of oily sludge vent gas treatment bio-trickling filter and treatment process
Technical field
The present invention relates to tail gas disposal technique field, specially a kind of oily sludge vent gas treatment bio-trickling filter and tail Gas disposal technique.
Background technique
Petroleum substance in oily sludge is a kind of complicated hydrocarbon mixture being mainly made of hydrocarbon, ownership Hydrocarbon compound in mineral oils chemical substance, petroleum, relative molecular mass is from tens to thousands of, and corresponding boiling point is from normal Temperature is to 500 DEG C or more.New environmental law regulation must be effectively treated the danger wastes such as oily sludge, comply with corresponding Innoxious requirement in environmental regulation can generate the tail gas containing VOCs during carrying out harmless treatment to oily sludge. This tail gas equally also can generate pollution to environment.In the prior art, when handling the tail gas containing VOCs by bio-trickling filter, because For equipment volume is big, using gas residence time in equipment when horizontal type structure, short, gas is unevenly distributed equipment, cause to tail The poor processing effect of gas is unable to satisfy the environmental regulation requirement being increasingly stringenter, directly limits the popularization of bio-trickling technology Using.
Summary of the invention
Poor to vent gas treatment effect in the prior art in order to solve the problems, such as, the present invention is provided at a kind of oily sludge tail gas Reason bio-trickling filter, can be turned up the treatment effect to tail gas, and can reduce equipment volume simultaneously.For this purpose, of the invention Additionally provide a kind of tail gas treatment process of oily sludge vent gas treatment bio-trickling filter.
The technical scheme is that such: a kind of oily sludge vent gas treatment bio-trickling filter comprising prizing body, Vent gas treatment channel is arranged in the prizing body inner cavity, and the vent gas treatment channel includes tail gas air inlet, fume treatment area, exhaust Cylinder, it is characterised in that: the fume treatment area includes tail gas treating unit, by every road sequence between the tail gas treating unit Connection, the tail gas treating unit respectively include the air intake duct set gradually from bottom to up, cell processing area, gas off-take;It is adjacent Two tail gas treating units between, tail gas described in the gas off-take of the previous tail gas treating unit, the latter The air intake duct of processing unit is respectively communicated with air inlet and the bottom at the top every road between two tail gas treating units The gas vent in portion;The air intake duct in first processing unit in the tail gas treating unit is connected to the tail gas air inlet Mouthful;Gas off-take in the last one processing unit in the tail gas treating unit connects exhaust tube.
It is further characterized by:
It is described every in road be arranged ultraviolet lamp tube group;
Rib row's sieve is respectively set above each air intake duct;
Filled composite filler, the compounded mix use outside for netted polyethylene respectively inside each cell processing area Porous silicon carbide particulate matter is filled in round sphere, the compounded mix inside;
In each tail gas treating unit, spray head is all set above the compounded mix;
The number in the channel is set as 1;
Demister is arranged in each air inlet position every the top in road.
Based on a kind of tail gas treatment process of oily sludge vent gas treatment bio-trickling filter, comprising steps of
S1: tail gas to be processed enters the air intake duct in tail gas treating unit under the traction of blower by tail gas air inlet;
It is further comprised the steps of:
S2: after the tail gas to be processed passes through the rib row's sieve being arranged in above the air intake duct, into the unit communicated therewith Treatment region;
S3: after the tail gas to be processed enters the cell processing area, the tail gas to be processed enters the unit from lower to upper The compounded mix filled inside treatment region carries out tail gas resolution process by biodegrade;
S4: the tail gas to be processed after once decomposing is by the gas off-take above the cell processing area, into place Between two adjacent tail gas treating units every in road;
S5: every the tail gas to be processed in road further through the vent gas treatment list for entering every road and closing on described in entering In member;
S6: circulation step S2 ~ S5 the step of, until the tail gas to be processed is by the last one tail gas treating unit top The prizing body is discharged in the exhaust tube of connection.
It is described every ultraviolet lamp tube group is arranged in road, by the ultraviolet lamp tube group to by described every the described to be processed of road Tail gas is irradiated.
A kind of oily sludge vent gas treatment bio-trickling filter provided by the invention, by setting every road prizing body inner cavity point Multiple tail gas treating units are divided into, the time of contact of gas Yu compounded mix layer is effectively extended, equipment volume is enable to reduce 30%-50%, gas to be processed are prizing intracorporal extended residence time to 35 s -56s, ensure that VOCs class pollution group in gas Fully degraded can be able to by dividing, and vent gas treatment effect is improved while reducing device volume.When gas to be processed passes through After first order compounded mix layer, biodegradable component is decomposed in gas, every ultraviolet lamp tube, VOCs group difficult to degrade are arranged in road When dividing through ultraviolet lamp tube layer, in ultraviolet light irradiation and the O of generation3Under effect, molecular structure, which changes, to be become biological to drop Component is solved, final biological decomposition is carried out into second level compounded mix layer, ensure that life of the bio-trickling filter to VOCs component Object degradation efficiency further ensures that the VOCs in tail gas is sufficiently explained in 95%-99%, improves the processing effect of tail gas Fruit.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of the perspective of bio-trickling filter embodiment in the present invention;
Fig. 2 is the structural schematic diagram of bio-trickling filter embodiment solid in the present invention.
Specific embodiment
As shown in Fig. 1 ~ Fig. 2, the present invention includes a kind of oily sludge vent gas treatment bio-trickling filter comprising prizing body 1, Vent gas treatment channel is arranged in 1 inner cavity of prizing body, and vent gas treatment channel includes tail gas air inlet 11, fume treatment area, exhaust tube 7, cigarette Gas disposal area includes tail gas treating unit, and by being linked in sequence every road between tail gas treating unit, tail gas treating unit wraps respectively Include the air intake duct set gradually from bottom to up, cell processing area, gas off-take;Between the air intake duct of adjacent tail gas treating unit that This is not connected to, and is not also connected to each other between the gas off-take of adjacent tail gas treating unit;As shown in Figure 1, only being set in this embodiment 1 road Ge Ge 13 is set, then 1 inner cavity of prizing body is divided into two adjacent tail gas treating units;Two tail gas treating units include Liang Ge cell processing area: first unit treatment region 21 and second unit treatment region 22;First unit treatment region 21 and second unit Filled composite filler 8-1 and 8-2 is distinguished inside treatment region 22, compounded mix uses outside for netted polyethylene circle sphere, Porous silicon carbide particulate matter is filled inside compounded mix;Compounded mix 8-1 and 8-2 are directly filled into first unit processing without fixed In area 21 and second unit treatment region 22, specific surface area reaches 500-800m2/m3, using such compounded mix, by being not fixed The mode directly filled is filled into the bed for the treatment of region, be can achieve oxygenation property well, is facilitated microorganism growth metabolism, It can accomplish that the biofilm period is no more than 48h, acid and alkali-resistance, anti-aging, not only it is to the decomposable process of tail gas to be processed not by water flow It influences, service life can achieve 10 years or more, and easy for installation, be suitable for the application of.
Tail gas treating unit respectively includes the first air intake duct 19-1, the first unit treatment region set gradually from bottom to up 21, the first gas off-take 20-1, the second air intake duct 19-2, second unit treatment region 22, the second gas off-take 20-2, wherein the first air inlet It is isolation between road 19-1, the second air intake duct 19-2, is isolation between the first gas off-take 20-1, the second gas off-take 20-2; Between two adjacent tail gas treating units, the first gas off-take 20-1 of previous tail gas treating unit is connected to every the top in road 13 Air inlet 13-1, the latter tail gas treating unit the second air intake duct 19-2 connection every road 13 bottom gas vent 13-2; The first air intake duct 19-1 in first processing unit in tail gas treating unit is connected to tail gas air inlet 11;Tail gas treating unit In the last one processing unit in the second gas off-take 20-2 connection exhaust tube 7;Rib row is respectively set above each air intake duct Sieve, the first top air intake duct 19-1 are arranged sieve 17-1, sieve 17-2 are arranged above the second air intake duct 19-2;At each tail gas It manages in unit, spray head is all set above compounded mix;Spray head 5 is all respectively set above compounded mix 8-1,8-2, sprays First 5 are connected to low dense nutrient solution storage device.
Spray equipment 5 is placed in the top of 1 inside two compounded mix layers 8-1 and 8-2 of prizing body, and cyclic spray is low from top to bottom Dense nutrient solution.Degrading microorganism, which is attached on compounded mix layer 8-1 and 8-2, forms biomembrane, and tail gas passes through filler layer region, gas VOCs component in body enters liquid phase under the action of spray equipment 5, and biomembrane quilt is then entered under conditions of active transport Microbial metabolism is decomposed into CO2、H2O, the harmless components such as minerals, energy achieve the purpose that tail gas clean-up, can be seen by manhole 4 Examine the progress of spray process.Water tank 9 is arranged in the bottom of bio-trickling filter, links spray equipment 5 for mentioning by water circulating pump 16 For microbial metabolism moisture, dosing tank 18 is located at the side of bio-trickling filter for supplementing nutrition necessary to microorganism growth metabolism Substance.
Demister 6-1 is set at the air inlet 13-1 at the top in road 13, by the tail gas to be processed of a degradation treatment, By demister 6-1 purify after, enter among road 13, avoid carried secretly in tail gas to be processed impurity pollution be set to every Ultraviolet lamp tube group 12 between road 13.
It will be divided into the two-stage treatment region of head and the tail connection inside prizing body 1 every road 13, effectively extend gas and filled out with compound The time of contact of the bed of material, and equipment volume is enable to reduce 30-50%, extended residence time of the gas to be processed in prizing body 1 is extremely 35-56s ensure that VOCs class pollution components can be able to fully degraded in gas;When gas to be processed passes through compounded mix layer After 8-1, biodegradable component is decomposed in gas, when VOCs component difficult to degrade passes through ultraviolet lamp tube group 12, shines in ultraviolet lamp The O for penetrating and generating3Under effect, molecular structure, which changes, becomes biodegradable component, subsequently into compounded mix layer 8-2 into The final biological decomposition of row, ensure that bio-trickling filter to the biodegradable efficiency of VOCs component in 95-99%.
It is the flow direction of tail gas to be processed as shown in figure 1 shown in arrow direction: enters from tail gas air inlet 11 to be processed Tail gas enters first unit treatment region 21 by the first air intake duct 19-1 from bottom to top and carries out first time resolution process, then It by the first gas off-take 20-1, is entered between road 13 from top to bottom, then the second air intake duct is entered by gas vent 13-2 19-2 enters the tail gas of the second air intake duct 19-2, enters carry out second of tail gas in second unit treatment region 22 from bottom to top Prizing body 1 is discharged finally by the second gas off-take 20-2, exhaust tube 7 in processing.
Tail gas to be processed enters the first air intake duct 19-1 by tail gas air inlet 11 under the traction of blower 2;Tail to be processed Gas passes through the rib being arranged in above the first air intake duct 19-1 and arranges sieve 17-1, realizes uniform gas distribution under the action of rib arranges sieve, Into the first unit treatment region 21 communicated therewith;After tail gas to be processed enters first unit treatment region 21, enter from lower to upper In the compounded mix 8-1 filled inside vent gas treatment area, tail gas resolution process is carried out by biodegrade;After once decomposing Tail gas to be processed pass through the air inlet 13-1 for being set to every the top of road 13 and enter and be located at every the space in road 13;Every in road 13 Ultraviolet lamp tube group 12 is set, the tail gas to be processed passed through is irradiated by ultraviolet lamp tube group 12, in ultraviolet light irradiation and life At O3Under effect, molecular structure, which changes, becomes biodegradable component, and tail gas is promoted to decompose;From being set to every 13 bottom of road The gas vent 13-2 in portion enters the second air intake duct 19-2 being connected to gas vent 13-2;By the second air intake duct 19-2 is arranged On rib arrange sieve 17-2, enter the compounded mix 8-2 being filled in inside second unit treatment region 22 from the bottom to top, second The biodegradable processing of secondary progress;Biodegradable tail gas twice is eventually passed through to supervise online after demister 6-2 purification in tail gas It surveys under the monitoring of instrument 15 and prizing body 1 is discharged by exhaust tube 7.
In the present invention, complete equipment and all processes are controlled by robot control system(RCS) 3, are integrated with temperature in robot control system(RCS) 3 Degree, pH value, COD value, air quantity, wind pressure, VOCs concentration in tail gas, each tank level high (low), motor tripping, spray flow quantity The function of control and monitoring, while the periodically discharge sewage of discharge outlet 10 is automatically controlled, it can remotely operate without artificial on duty.At this The safety that guardrail 14 guarantees equipment when the maintenance of equipment necessity is also set up at the top of the bio-trickling filter of invention.

Claims (9)

1. a kind of oily sludge vent gas treatment bio-trickling filter comprising prizing body, the prizing body inner cavity setting vent gas treatment are logical Road, the vent gas treatment channel include tail gas air inlet, fume treatment area, exhaust tube, it is characterised in that: the fume treatment area Including tail gas treating unit, by being linked in sequence every road between the tail gas treating unit, the tail gas treating unit wraps respectively Include the air intake duct set gradually from bottom to up, cell processing area, gas off-take;Between two adjacent tail gas treating units, The air intake duct of tail gas treating unit described in the gas off-take of the previous tail gas treating unit, the latter, connects respectively The air inlet at the top every road between logical two tail gas treating units and the gas vent of bottom;The tail gas treating unit In first processing unit in the air intake duct be connected to the tail gas air inlet;Last in the tail gas treating unit Gas off-take in a processing unit connects exhaust tube.
2. a kind of oily sludge vent gas treatment bio-trickling filter according to claim 1, it is characterised in that: described every in road Ultraviolet lamp tube group is set.
3. a kind of oily sludge vent gas treatment bio-trickling filter according to claim 1, it is characterised in that: it is each described into Rib row's sieve is respectively set above air flue.
4. a kind of oily sludge vent gas treatment bio-trickling filter according to claim 1, it is characterised in that: each list Difference filled composite filler inside first treatment region, the compounded mix uses outside for netted polyethylene circle sphere, described Porous silicon carbide particulate matter is filled inside compounded mix.
5. a kind of oily sludge vent gas treatment bio-trickling filter according to claim 4, it is characterised in that: each tail In gas disposal unit, spray head is all set above the compounded mix.
6. a kind of oily sludge vent gas treatment bio-trickling filter according to claim 1, it is characterised in that: the channel Number is set as 1.
7. a kind of oily sludge vent gas treatment bio-trickling filter according to claim 1, it is characterised in that: it is each described every Demister is all arranged in the air inlet position at the top in road.
8. based on a kind of tail gas treatment process of oily sludge vent gas treatment bio-trickling filter, comprising steps of
S1: tail gas to be processed enters the air intake duct in tail gas treating unit under the traction of blower by tail gas air inlet;
It is further comprised the steps of:
S2: after the tail gas to be processed passes through the rib row's sieve being arranged in above the air intake duct, into the unit communicated therewith Treatment region;
S3: after the tail gas to be processed enters the cell processing area, the tail gas to be processed enters the unit from lower to upper The compounded mix filled inside treatment region carries out tail gas resolution process by biodegrade;
S4: the tail gas to be processed after once decomposing is by the gas off-take above the cell processing area, into place Between two adjacent tail gas treating units every in road;
S5: every the tail gas to be processed in road further through the vent gas treatment list for entering every road and closing on described in entering In member;
S6: circulation step S2 ~ S5 the step of, until the tail gas to be processed is by the last one tail gas treating unit top The prizing body is discharged in the exhaust tube of connection.
9. a kind of oily sludge tail gas treatment process according to claim 8, it is characterised in that: described ultraviolet every being arranged in road Light tube group is irradiated by the ultraviolet lamp tube group to by the tail gas to be processed every road.
CN201910644982.0A 2019-07-17 2019-07-17 A kind of oily sludge vent gas treatment bio-trickling filter and treatment process Pending CN110252128A (en)

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CN201910644982.0A CN110252128A (en) 2019-07-17 2019-07-17 A kind of oily sludge vent gas treatment bio-trickling filter and treatment process

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Application Number Priority Date Filing Date Title
CN201910644982.0A CN110252128A (en) 2019-07-17 2019-07-17 A kind of oily sludge vent gas treatment bio-trickling filter and treatment process

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CN110252128A true CN110252128A (en) 2019-09-20

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KR101024296B1 (en) * 2010-06-28 2011-03-29 지테크 주식회사 Biological deodorization system for removal of highly concentrated odors and volatile organic compounds
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CN210845871U (en) * 2019-07-17 2020-06-26 无锡雪浪环境科技股份有限公司 Oily sludge tail gas treatment biological trickling filter

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Title
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