CN110250222A - 植物源杀虫剂组合物 - Google Patents
植物源杀虫剂组合物 Download PDFInfo
- Publication number
- CN110250222A CN110250222A CN201910628344.XA CN201910628344A CN110250222A CN 110250222 A CN110250222 A CN 110250222A CN 201910628344 A CN201910628344 A CN 201910628344A CN 110250222 A CN110250222 A CN 110250222A
- Authority
- CN
- China
- Prior art keywords
- oil
- insecticide composition
- polyoxyethylene ether
- parts
- plant insecticide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 48
- 239000002917 insecticide Substances 0.000 title claims abstract description 46
- 241000196324 Embryophyta Species 0.000 claims abstract description 46
- 239000010642 eucalyptus oil Substances 0.000 claims abstract description 31
- 229940044949 eucalyptus oil Drugs 0.000 claims abstract description 31
- 241000296609 Celastrus angulatus Species 0.000 claims abstract description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- WITLAWYGGVAFLU-UHFFFAOYSA-N 3-(6-methoxy-1,3-benzodioxol-5-yl)-8,8-dimethylpyrano[2,3-f]chromen-4-one Chemical compound C1=CC(C)(C)OC2=CC=C(C(C(C3=CC=4OCOC=4C=C3OC)=CO3)=O)C3=C21 WITLAWYGGVAFLU-UHFFFAOYSA-N 0.000 claims abstract description 14
- ZOJBYZNEUISWFT-UHFFFAOYSA-N allyl isothiocyanate Chemical compound C=CCN=C=S ZOJBYZNEUISWFT-UHFFFAOYSA-N 0.000 claims abstract description 12
- ZQIYJHBQRBBBRZ-UHFFFAOYSA-N nimbin Natural products COC(=O)CC1C2C(C(OC(=O)C)C3OC4CC(C(=C4C13C)C)c5cocc5)C(C)(C=CC2=O)C(=O)OC ZQIYJHBQRBBBRZ-UHFFFAOYSA-N 0.000 claims abstract description 8
- NHOIBRJOQAYBJT-IMGVWCFESA-N nimbin Chemical compound C=1([C@@H]2C[C@H]3O[C@H]4[C@](C3=C2C)(C)[C@@H]([C@]2(C(=O)C=C[C@](C)([C@@H]2[C@H]4OC(C)=O)C(=O)OC)C)CC(=O)OC)C=COC=1 NHOIBRJOQAYBJT-IMGVWCFESA-N 0.000 claims abstract description 8
- 239000005660 Abamectin Substances 0.000 claims abstract description 7
- HPUXDMUGCAWDFW-UHFFFAOYSA-N Osthole Natural products COc1ccc2CCC(=O)Oc2c1C=CC(=O)C HPUXDMUGCAWDFW-UHFFFAOYSA-N 0.000 claims abstract description 7
- RRZXIRBKKLTSOM-XPNPUAGNSA-N avermectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 RRZXIRBKKLTSOM-XPNPUAGNSA-N 0.000 claims abstract description 7
- 239000000470 constituent Substances 0.000 claims abstract description 7
- MBRLOUHOWLUMFF-UHFFFAOYSA-N osthole Chemical compound C1=CC(=O)OC2=C(CC=C(C)C)C(OC)=CC=C21 MBRLOUHOWLUMFF-UHFFFAOYSA-N 0.000 claims abstract description 7
- CLEXYFLHGFJONT-DNMILWOZSA-N Jervine Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H](C(=O)C2=C3C)[C@@H]1[C@@H]2CC[C@@]13O[C@@H]2C[C@H](C)CN[C@H]2[C@H]1C CLEXYFLHGFJONT-DNMILWOZSA-N 0.000 claims abstract description 6
- VQXSOUPNOZTNAI-UHFFFAOYSA-N Pyrethrin I Natural products CC(=CC1CC1C(=O)OC2CC(=O)C(=C2C)CC=C/C=C)C VQXSOUPNOZTNAI-UHFFFAOYSA-N 0.000 claims abstract description 6
- 235000016720 allyl isothiocyanate Nutrition 0.000 claims abstract description 6
- CLEXYFLHGFJONT-UHFFFAOYSA-N jervine Natural products C1C=C2CC(O)CCC2(C)C(C(=O)C2=C3C)C1C2CCC13OC2CC(C)CNC2C1C CLEXYFLHGFJONT-UHFFFAOYSA-N 0.000 claims abstract description 6
- QRXOCOSLDOPPKH-UHFFFAOYSA-N jervine sulfate Natural products CC1CNC2C(C1)OC3(CCC4=C(C3C)C(=O)C5C4CC=C6CC(O)CCC56C)C2C QRXOCOSLDOPPKH-UHFFFAOYSA-N 0.000 claims abstract description 6
- HYJYGLGUBUDSLJ-UHFFFAOYSA-N pyrethrin Natural products CCC(=O)OC1CC(=C)C2CC3OC3(C)C2C2OC(=O)C(=C)C12 HYJYGLGUBUDSLJ-UHFFFAOYSA-N 0.000 claims abstract description 6
- VJFUPGQZSXIULQ-XIGJTORUSA-N pyrethrin II Chemical compound CC1(C)[C@H](/C=C(\C)C(=O)OC)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1 VJFUPGQZSXIULQ-XIGJTORUSA-N 0.000 claims abstract description 6
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 38
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 38
- -1 Alkenyl phenol Chemical compound 0.000 claims description 20
- 238000002360 preparation method Methods 0.000 claims description 16
- 238000006243 chemical reaction Methods 0.000 claims description 15
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 claims description 14
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 14
- 229920000570 polyether Polymers 0.000 claims description 14
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims description 14
- 239000002904 solvent Substances 0.000 claims description 14
- 239000001593 sorbitan monooleate Substances 0.000 claims description 14
- 229940035049 sorbitan monooleate Drugs 0.000 claims description 14
- 235000011069 sorbitan monooleate Nutrition 0.000 claims description 14
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 12
- 239000003921 oil Substances 0.000 claims description 9
- 235000019198 oils Nutrition 0.000 claims description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 239000000375 suspending agent Substances 0.000 claims description 8
- DEQJNIVTRAWAMD-UHFFFAOYSA-N 1,1,2,4,4,4-hexafluorobutyl prop-2-enoate Chemical compound FC(F)(F)CC(F)C(F)(F)OC(=O)C=C DEQJNIVTRAWAMD-UHFFFAOYSA-N 0.000 claims description 7
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 7
- 239000005057 Hexamethylene diisocyanate Substances 0.000 claims description 7
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- 235000019260 propionic acid Nutrition 0.000 claims description 7
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims description 7
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 claims description 6
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 6
- 229940008099 dimethicone Drugs 0.000 claims description 6
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 6
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 6
- 150000002191 fatty alcohols Chemical class 0.000 claims description 6
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 238000004132 cross linking Methods 0.000 claims description 5
- 238000006116 polymerization reaction Methods 0.000 claims description 5
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 4
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 239000008267 milk Substances 0.000 claims description 4
- 235000013336 milk Nutrition 0.000 claims description 4
- 210000004080 milk Anatomy 0.000 claims description 4
- 229920001983 poloxamer Polymers 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 4
- 239000004094 surface-active agent Substances 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical class OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 3
- 229920002521 macromolecule Polymers 0.000 claims description 3
- JOLVYUIAMRUBRK-UHFFFAOYSA-N 11',12',14',15'-Tetradehydro(Z,Z-)-3-(8-Pentadecenyl)phenol Natural products OC1=CC=CC(CCCCCCCC=CCC=CCC=C)=C1 JOLVYUIAMRUBRK-UHFFFAOYSA-N 0.000 claims description 2
- YLKVIMNNMLKUGJ-UHFFFAOYSA-N 3-Delta8-pentadecenylphenol Natural products CCCCCCC=CCCCCCCCC1=CC=CC(O)=C1 YLKVIMNNMLKUGJ-UHFFFAOYSA-N 0.000 claims description 2
- JOLVYUIAMRUBRK-UTOQUPLUSA-N Cardanol Chemical compound OC1=CC=CC(CCCCCCC\C=C/C\C=C/CC=C)=C1 JOLVYUIAMRUBRK-UTOQUPLUSA-N 0.000 claims description 2
- FAYVLNWNMNHXGA-UHFFFAOYSA-N Cardanoldiene Natural products CCCC=CCC=CCCCCCCCC1=CC=CC(O)=C1 FAYVLNWNMNHXGA-UHFFFAOYSA-N 0.000 claims description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 2
- HDWLUGYOLUHEMN-UHFFFAOYSA-N Dinobuton Chemical compound CCC(C)C1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1OC(=O)OC(C)C HDWLUGYOLUHEMN-UHFFFAOYSA-N 0.000 claims description 2
- 244000166124 Eucalyptus globulus Species 0.000 claims description 2
- 235000004692 Eucalyptus globulus Nutrition 0.000 claims description 2
- 244000103090 Eucalyptus robusta Species 0.000 claims description 2
- 235000019134 Eucalyptus tereticornis Nutrition 0.000 claims description 2
- 229920001732 Lignosulfonate Polymers 0.000 claims description 2
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- 241000425573 Talanes Species 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 2
- PTFIPECGHSYQNR-UHFFFAOYSA-N cardanol Natural products CCCCCCCCCCCCCCCC1=CC=CC(O)=C1 PTFIPECGHSYQNR-UHFFFAOYSA-N 0.000 claims description 2
- 239000008367 deionised water Substances 0.000 claims description 2
- 229910021641 deionized water Inorganic materials 0.000 claims description 2
- MWYMHZINPCTWSB-UHFFFAOYSA-N dimethylsilyloxy-dimethyl-trimethylsilyloxysilane Polymers C[SiH](C)O[Si](C)(C)O[Si](C)(C)C MWYMHZINPCTWSB-UHFFFAOYSA-N 0.000 claims description 2
- 239000002270 dispersing agent Substances 0.000 claims description 2
- 239000002552 dosage form Substances 0.000 claims description 2
- 239000000839 emulsion Substances 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 238000001914 filtration Methods 0.000 claims description 2
- 229930182470 glycoside Natural products 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 239000000463 material Substances 0.000 claims description 2
- SWGZAKPJNWCPRY-UHFFFAOYSA-N methyl-bis(trimethylsilyloxy)silicon Polymers C[Si](C)(C)O[Si](C)O[Si](C)(C)C SWGZAKPJNWCPRY-UHFFFAOYSA-N 0.000 claims description 2
- 239000004530 micro-emulsion Substances 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 239000010452 phosphate Substances 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 claims description 2
- 159000000000 sodium salts Chemical class 0.000 claims description 2
- 239000004550 soluble concentrate Substances 0.000 claims description 2
- 239000000600 sorbitol Substances 0.000 claims description 2
- 239000004551 spreading oil Substances 0.000 claims description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 2
- 150000003871 sulfonates Chemical class 0.000 claims description 2
- 239000004548 suspo-emulsion Substances 0.000 claims description 2
- 235000005221 swamp mahogany Nutrition 0.000 claims description 2
- 239000003760 tallow Substances 0.000 claims description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 2
- 239000008158 vegetable oil Substances 0.000 claims description 2
- 238000009423 ventilation Methods 0.000 claims description 2
- 239000000052 vinegar Substances 0.000 claims description 2
- 235000021419 vinegar Nutrition 0.000 claims description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 3
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims 1
- RRTCFFFUTAGOSG-UHFFFAOYSA-N benzene;phenol Chemical compound C1=CC=CC=C1.OC1=CC=CC=C1 RRTCFFFUTAGOSG-UHFFFAOYSA-N 0.000 claims 1
- 239000006071 cream Substances 0.000 claims 1
- 235000014113 dietary fatty acids Nutrition 0.000 claims 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 239000000194 fatty acid Substances 0.000 claims 1
- 229930195729 fatty acid Natural products 0.000 claims 1
- 150000004665 fatty acids Chemical class 0.000 claims 1
- RRDQTXGFURAKDI-UHFFFAOYSA-N formaldehyde;naphthalene-2-sulfonic acid Chemical compound O=C.C1=CC=CC2=CC(S(=O)(=O)O)=CC=C21 RRDQTXGFURAKDI-UHFFFAOYSA-N 0.000 claims 1
- 239000003094 microcapsule Substances 0.000 claims 1
- 229920001568 phenolic resin Polymers 0.000 claims 1
- 229920000151 polyglycol Polymers 0.000 claims 1
- 239000010695 polyglycol Substances 0.000 claims 1
- 229920002545 silicone oil Polymers 0.000 claims 1
- 239000001384 succinic acid Substances 0.000 claims 1
- 230000000749 insecticidal effect Effects 0.000 abstract description 9
- 244000144977 poultry Species 0.000 abstract description 4
- 238000012545 processing Methods 0.000 abstract description 4
- 238000001228 spectrum Methods 0.000 abstract description 3
- WEEGYLXZBRQIMU-UHFFFAOYSA-N Eucalyptol Chemical compound C1CC2CCC1(C)OC2(C)C WEEGYLXZBRQIMU-UHFFFAOYSA-N 0.000 description 8
- 241000238631 Hexapoda Species 0.000 description 8
- 241000607479 Yersinia pestis Species 0.000 description 8
- 235000015459 Lycium barbarum Nutrition 0.000 description 6
- 244000269722 Thea sinensis Species 0.000 description 6
- 241000018137 Trialeurodes vaporariorum Species 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 241001414720 Cicadellidae Species 0.000 description 5
- 239000003814 drug Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 241001124076 Aphididae Species 0.000 description 4
- 240000008067 Cucumis sativus Species 0.000 description 4
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 4
- 244000241838 Lycium barbarum Species 0.000 description 4
- 235000015468 Lycium chinense Nutrition 0.000 description 4
- 244000061458 Solanum melongena Species 0.000 description 4
- 235000002597 Solanum melongena Nutrition 0.000 description 4
- 239000000575 pesticide Substances 0.000 description 4
- 210000002784 stomach Anatomy 0.000 description 4
- 206010059866 Drug resistance Diseases 0.000 description 3
- BTCSSZJGUNDROE-UHFFFAOYSA-N gamma-aminobutyric acid Chemical compound NCCCC(O)=O BTCSSZJGUNDROE-UHFFFAOYSA-N 0.000 description 3
- 239000002574 poison Substances 0.000 description 3
- 231100000614 poison Toxicity 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 231100000419 toxicity Toxicity 0.000 description 3
- 230000001988 toxicity Effects 0.000 description 3
- 239000000341 volatile oil Substances 0.000 description 3
- 150000000193 1,8-cineol derivatives Chemical class 0.000 description 2
- 241000239290 Araneae Species 0.000 description 2
- 235000009024 Ceanothus sanguineus Nutrition 0.000 description 2
- 241000277305 Electrophorus electricus Species 0.000 description 2
- WEEGYLXZBRQIMU-WAAGHKOSSA-N Eucalyptol Chemical compound C1C[C@H]2CC[C@]1(C)OC2(C)C WEEGYLXZBRQIMU-WAAGHKOSSA-N 0.000 description 2
- 244000166102 Eucalyptus leucoxylon Species 0.000 description 2
- 240000003553 Leptospermum scoparium Species 0.000 description 2
- 241001674048 Phthiraptera Species 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 240000004460 Tanacetum coccineum Species 0.000 description 2
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 2
- ROVGZAWFACYCSP-MQBLHHJJSA-N [2-methyl-4-oxo-3-[(2z)-penta-2,4-dienyl]cyclopent-2-en-1-yl] (1r,3r)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OC1C(C)=C(C\C=C/C=C)C(=O)C1 ROVGZAWFACYCSP-MQBLHHJJSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 229960005233 cineole Drugs 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- 239000000284 extract Substances 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 230000000855 fungicidal effect Effects 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- 230000001418 larval effect Effects 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 230000010534 mechanism of action Effects 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 229940015367 pyrethrum Drugs 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- OGNSCSPNOLGXSM-UHFFFAOYSA-N (+/-)-DABA Natural products NCCC(N)C(O)=O OGNSCSPNOLGXSM-UHFFFAOYSA-N 0.000 description 1
- 206010002091 Anaesthesia Diseases 0.000 description 1
- 241000310269 Anomis flava Species 0.000 description 1
- 241000256844 Apis mellifera Species 0.000 description 1
- 240000003291 Armoracia rusticana Species 0.000 description 1
- 235000011330 Armoracia rusticana Nutrition 0.000 description 1
- 241000238421 Arthropoda Species 0.000 description 1
- 241000255789 Bombyx mori Species 0.000 description 1
- 241000345998 Calamus manan Species 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 241000124008 Mammalia Species 0.000 description 1
- 206010033799 Paralysis Diseases 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 235000011609 Pinus massoniana Nutrition 0.000 description 1
- 241000018650 Pinus massoniana Species 0.000 description 1
- 206010039509 Scab Diseases 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- 241000489523 Veratrum Species 0.000 description 1
- ABUGVBRDFWGJRD-CHOYNLESSA-N [9-[(2r,3r,4s,5r)-3,4-dihydroxy-5-methyloxolan-2-yl]-2-(2,4-dinitrophenyl)sulfanylpurin-6-yl] [hydroxy(phosphonooxy)phosphoryl] hydrogen phosphate Chemical compound O[C@@H]1[C@H](O)[C@@H](C)O[C@H]1N1C2=NC(SC=3C(=CC(=CC=3)[N+]([O-])=O)[N+]([O-])=O)=NC(OP(O)(=O)OP(O)(=O)OP(O)(O)=O)=C2N=C1 ABUGVBRDFWGJRD-CHOYNLESSA-N 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229930013930 alkaloid Natural products 0.000 description 1
- 150000003797 alkaloid derivatives Chemical class 0.000 description 1
- 229940124277 aminobutyric acid Drugs 0.000 description 1
- 230000037005 anaesthesia Effects 0.000 description 1
- 230000003444 anaesthetic effect Effects 0.000 description 1
- 230000003698 anagen phase Effects 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000001887 anti-feedant effect Effects 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000019658 bitter taste Nutrition 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 230000010261 cell growth Effects 0.000 description 1
- 210000002421 cell wall Anatomy 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000032669 eclosion Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 1
- 238000003958 fumigation Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 229960003692 gamma aminobutyric acid Drugs 0.000 description 1
- 210000004907 gland Anatomy 0.000 description 1
- 230000012010 growth Effects 0.000 description 1
- 241000411851 herbal medicine Species 0.000 description 1
- 238000000338 in vitro Methods 0.000 description 1
- 238000011534 incubation Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000003120 macrolide antibiotic agent Substances 0.000 description 1
- 235000013372 meat Nutrition 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 230000029052 metamorphosis Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000005405 multipole Effects 0.000 description 1
- 210000003205 muscle Anatomy 0.000 description 1
- KVBGVZZKJNLNJU-UHFFFAOYSA-N naphthalene-2-sulfonic acid Chemical class C1=CC=CC2=CC(S(=O)(=O)O)=CC=C21 KVBGVZZKJNLNJU-UHFFFAOYSA-N 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 230000007830 nerve conduction Effects 0.000 description 1
- 210000000653 nervous system Anatomy 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 231100000194 ovacidal Toxicity 0.000 description 1
- 230000003151 ovacidal effect Effects 0.000 description 1
- 230000035479 physiological effects, processes and functions Effects 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 235000012950 rattan cane Nutrition 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229930000044 secondary metabolite Natural products 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000007619 statistical method Methods 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 229920001864 tannin Polymers 0.000 description 1
- 235000018553 tannin Nutrition 0.000 description 1
- 239000001648 tannin Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
- A01N43/12—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings condensed with a carbocyclic ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
- A01N47/46—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —N=C=S groups
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/12—Asteraceae or Compositae [Aster or Sunflower family], e.g. daisy, pyrethrum, artichoke, lettuce, sunflower, wormwood or tarragon
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/28—Myrtaceae [Myrtle family], e.g. teatree or clove
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Natural Medicines & Medicinal Plants (AREA)
- Microbiology (AREA)
- Biotechnology (AREA)
- Mycology (AREA)
- Botany (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
本发明涉及一种植物源杀虫剂组合物，包括1‑20重量份的有效成分A和0.1‑10的有效成分B,所述有效成分A包括桉叶油，所述有效成分B包括苦皮藤素、异硫氰酸烯丙酯、印楝素、除虫菊素、藜芦碱、阿维菌素、蛇床子素、小檗碱中的一种或多种。其不仅具有广谱的杀虫效果且防治效果好，而且环境友好、对人畜无害，有利于生态环境的保护、增加了处理后水体的安全性。
Description
技术领域
本发明涉及农药技术领域，更具体的说，它涉及一种植物源杀虫剂组合物。
背景技术
桉叶油是桉树(Eucalyptus)叶油腺细胞分泌出来的芳香精油，含有挥发油、苦味质、鞣质和树脂等多种成分，是清澈具有芳香味的液体。研究发现，一些桉油精对马尾松害虫有较高的活性，幼虫期施用导致畸形变态，幼虫死亡率较高，成虫羽化率较低，部分不孵化；成虫期施用有不育效应；孵化期施用有抑孵作用，可作为一种无毒、安全的新型杀虫剂。经进一步研究发现，桉油精中活性最好的组分为1,8-桉叶素。通过精油类物质对电鳗和赤拟谷盗离体条件下AChE的活性的抑制，发现1,8-桉叶素是电鳗AChE最具潜力的抑制剂。
苦皮藤的根皮和茎皮均含有多种强力杀虫成分，目前已从根皮或种子中分离鉴定出数十个新化合物，如苦皮藤酯I一Ⅳ、苦皮藤素I—V，这些苦皮藤中的杀虫活性成分均简称为苦皮藤素。近年来研究发现，苦皮藤的杀虫活性成分具有麻醉、拒食和胃毒、触杀作用,并且不产生抗药性、不杀伤天敌、理化性质稳定等特点。苦皮藤素Ⅰ对害虫具有拒食作用,苦皮藤素Ⅱ、Ⅲ对小地虎、甘蓝夜蛾、棉小造桥虫等昆虫有胃毒毒杀作用，苦皮藤素Ⅳ对昆虫具有选择麻醉作用。我们研究发现，以1,8-桉叶素和苦皮藤进行复配，可起到增效作用，大大提高植物源农药防治病虫害的效果，此项研究尚未见到相关报道，开辟了高效植物源农药研究运用的先河。
辣根素是指从辣根等十字花科植物中提取出来的一类次生代谢产物,在化学结构上都含有-N＝C＝S活性基团的化合物，在常温下可以挥发的、外观似油状的液体。由于其粗提物的强烈熏蒸活性一般用于土壤处理，其中其主要成分异硫氰酸烯丙酯作为一种生物熏蒸剂近年来已引起了同行的广泛关注。但辣根素和桉油精复配进行叶面喷施用于防治植物病虫害的研究不多。
印楝素是复杂的大分子物质，分子结构中有许多能够发生反应的官能团。它易分解，不污染环境，有利于生态平衡和发展可持续农业，生产绿色食品。印楝素的应用不易产生抗药性，防治害虫范围广，而且它只对那些植食性昆虫起作用，对以昆虫为食的益虫、蜘蛛、蜜蜂以及高等动物无害。
天然除虫菊素是从除虫菊花中分离萃取的具有杀虫效果的活性成分，含有六种杀虫活性物质，具有广谱高效、环保低毒及昆虫不易产生抗药性等优点，是国际公认的安全的杀虫剂。
藜芦碱对害虫具有触杀、胃毒作用。其作用机理为激活害虫的Na通道，使用害虫肌肉瘫痪、僵硬直至死亡。
阿维菌素是一种大环内酯双糖类化合物，是土壤微生物中分离的天然产物，具有胃毒和触杀作用，不能杀卵。作用机制是干扰神经生理活动，刺激释放γ-氨基丁酸，而氨基丁酸对节肢动物的神经传导有抑制作用。
蛇床子素是从中药材蛇床子中提取的具有杀虫、杀菌活性物质。杀虫机理：其有效成分作用于害虫神经系统，导致昆虫肌肉非功能性收缩，最终衰竭而死。杀菌机理：影响细胞壁的生长导致菌丝大量断裂，同时抑制病菌菌丝的生长。
小檗碱是中草药植物提取的生物碱杀菌剂，能迅速渗透到植物体内和病斑部位，通过干扰病原菌体代谢，抑制其生长和繁殖，达到杀菌作用。
本发明以桉叶油为主要有效成分，也可同时辅以苦皮藤素或辣根素或印楝素或天然除虫菊素或藜芦碱或阿维菌素或蛇床子素或小檗碱等植物源农药的一种或多种混合物制备桉油精系列植物源杀虫剂组合物。
发明内容
针对现有技术存在的不足，本发明的目的在于提供一种植物源杀虫剂组合物，其不仅具有广谱的杀虫效果且防治效果好，而且环境友好、对人畜无害，有利于生态环境的保护、增加了处理后水体的安全性。
本发明的上述技术目的是通过以下技术方案得以实现的：
植物源杀虫剂组合物，包括1-20重量份的有效成分A和0.1-10的有效成分B,所述有效成分A包括桉叶油，所述有效成分B包括苦皮藤素、异硫氰酸烯丙酯、印楝素、除虫菊素、藜芦碱、阿维菌素、蛇床子素、小檗碱中的一种或多种。
进一步，所述桉叶油采用下述方法制备：
(1)将蓝桉或大叶桉的枝叶加入到提取罐中,向提取罐通入水蒸汽，通气时间为1-1.5小时；停至通入水蒸汽,并冷却提取罐，待提取罐的温度降为室温时，将罐内液体通过过滤装置通至油水分离器，得到粗桉叶油；
(2)将步骤(1)得到的粗桉叶油通至蒸馏塔，收集175-180℃的馏出液，即桉叶油。
进一步，还包括10-60重量份数的表面活性剂。
更进一步，所述表面活性剂包括苯乙烯基酚聚氧乙烯聚氧丙烯醚、烷基酚甲醛树脂聚氧乙烯醚、腰果酚聚氧乙烯醚、二苯乙烯苯酚多聚甲醛缩合物聚氧乙烯醚、植物油聚氧乙烯醚、聚氧乙烯聚氧丙烯嵌段聚醚、脂肪酸聚氧乙烯醚、烷基酚聚氧乙烯醚、2-萘磺酸甲醛聚合物钠盐、木质素磺酸盐、丙烯酸系高分子分散剂、山梨醇酯聚氧乙烯醚、有机硅聚氧乙烯醚、失水山梨醇单油酸酯聚氧乙烯醚、牛脂胺聚氧乙烯醚、十二烷基苯磺酸钙、硫酸醋盐、磺酸盐类、聚醚改性七甲基三硅氧烷、琥珀酸酯磺酸盐、高分子聚羧酸盐、磷酸酯盐、改性端烯烃磺酸盐、木质素磺酸钠聚氧乙烯醚、非离子EO/PO嵌段共聚物和经修饰的羧酸酸盐复合物、新型脂肪醇聚氧乙烯醚、烷基糖苷中的一种或多种。
进一步，还包括0.3-0.5重量份的增效剂。
更进一步，所述增效剂采用下述方法制备：将包含六甲撑二异氰酸酯、二甲基硅油的混合料加热至90℃，聚合反应1小时；降温至85℃，加入二羟甲基丙酸，扩链反应3小时；加入三羟甲基丙烷，交联反应1小时；加入丙烯酸羟乙酯，封端反应1.5小时；降温至20-30℃，加入丙烯酸六氟丁酯和溶剂，自由基聚合反应0.25小时，除去溶剂，即得所述增效剂；以重量份数计，六甲撑二异氰酸酯20-22份、二甲基硅油9-10份、二羟甲基丙酸6-7份、三羟甲基丙烷1.5-1.7份、丙烯酸羟乙酯3-5份、溶剂30-50份、丙烯酸六氟丁酯7-10份。
更进一步，所述自由基聚合反应的引发条件是加入5-10重量份数的重量百分比浓度为30％的双氧水。
更进一步，所述溶剂为去离子水。
进一步，所述植物源杀虫剂组合物制成可溶液剂、水剂、微乳剂、水乳剂、悬浮剂、悬乳剂、可分散油悬浮剂、乳油、水可分散粒剂、油剂、展膜油剂、脂剂、油乳剂、油悬浮剂、微囊悬浮剂，油分散粉剂、水分散片剂、乳粉剂、乳粒剂的剂型。
综上所述，本发明具有以下有益效果：
第一、本发明提供的植物源杀虫剂组合物不仅具有广谱的杀虫效果且防治效果好，而且环境友好、对人畜无害，有利于生态环境的保护、增加了处理后水体的安全性。
第二、本发明提供的增效剂显著提高了本发明植物源杀虫剂组合物的杀虫效果。
具体实施方式
以下结合实施例对本发明作进一步详细说明。
增效剂的制备例1：将包含六甲撑二异氰酸酯0.20Kg、二甲基硅油0.10Kg的混合料加热至90℃，聚合反应1小时；降温至85℃，加入二羟甲基丙酸0.065Kg，扩链反应3小时；加入三羟甲基丙烷0.015Kg，交联反应1小时；加入丙烯酸羟乙酯0.03Kg，封端反应1.5小时；降温至20-30℃，加入丙烯酸六氟丁酯0.07Kg和溶剂0.30Kg，加入重量百分比浓度为30％的双氧水0.1Kg引发自由基聚合反应0.25小时，除去溶剂，即得增效剂。
增效剂的制备例2：将包含六甲撑二异氰酸酯0.21Kg、二甲基硅油0.09Kg的混合料加热至90℃，聚合反应1小时；降温至85℃，加入二羟甲基丙酸0.07Kg，扩链反应3小时；加入三羟甲基丙烷0.017Kg，交联反应1小时；加入丙烯酸羟乙酯0.05Kg，封端反应1.5小时；降温至20-30℃，加入丙烯酸六氟丁酯0.085Kg和溶剂0.40Kg，加入重量百分比浓度为30％的双氧水0.5Kg引发自由基聚合反应0.25小时，除去溶剂，即得增效剂。
增效剂的制备例3：将包含六甲撑二异氰酸酯0.22Kg、二甲基硅油0.09Kg的混合料加热至90℃，聚合反应1小时；降温至85℃，加入二羟甲基丙酸0.06Kg，扩链反应3小时；加入三羟甲基丙烷0.016Kg，交联反应1小时；加入丙烯酸羟乙酯0.04Kg，封端反应1.5小时；降温至20-30℃，加入丙烯酸六氟丁酯0.10Kg和溶剂0.50Kg，加入重量百分比浓度为30％的双氧水0.75Kg引发自由基聚合反应0.25小时，除去溶剂，即得增效剂。
实施例1
植物源杀虫剂组合物：包括桉叶油1Kg、苦皮藤素10Kg、聚氧乙烯聚氧丙烯嵌段聚醚5Kg、十二烷基苯磺酸钙10Kg。
实施例2
植物源杀虫剂组合物：包括桉叶油1Kg、异硫氰酸烯丙酯10Kg、聚氧乙烯聚氧丙烯嵌段聚醚5Kg、木质素磺酸钠聚氧乙烯醚5Kg。
实施例3
植物源杀虫剂组合物：包括桉叶油1Kg、印楝素10Kg、失水山梨醇单油酸酯聚氧乙烯醚25Kg、脂肪醇聚氧乙烯醚5Kg。
实施例4
植物源杀虫剂组合物：包括桉叶油10Kg、除虫菊素5Kg、失水山梨醇单油酸酯聚氧乙烯醚20Kg、脂肪醇聚氧乙烯醚10Kg。
实施例5
植物源杀虫剂组合物：包括桉叶油10Kg、藜芦碱5Kg、非离子EO/PO嵌段共聚物1Kg、琥珀酸酯磺酸盐14Kg。
实施例6
植物源杀虫剂组合物：包括桉叶油10Kg、阿维菌素5Kg、聚氧乙烯聚氧丙烯嵌段聚醚5Kg、失水山梨醇单油酸酯聚氧乙烯醚20Kg。
实施例7
植物源杀虫剂组合物：包括桉叶油20Kg、蛇床子素0.1Kg、聚氧乙烯聚氧丙烯嵌段聚醚5Kg、失水山梨醇单油酸酯聚氧乙烯醚20Kg。
实施例8
植物源杀虫剂组合物：包括桉叶油20Kg、小檗碱0.1Kg、聚氧乙烯聚氧丙烯嵌段聚醚5Kg、失水山梨醇单油酸酯聚氧乙烯醚20Kg。
实施例9
植物源杀虫剂组合物：包括桉叶油20Kg、苦皮藤素0.1Kg、聚氧乙烯聚氧丙烯嵌段聚醚5Kg、失水山梨醇单油酸酯聚氧乙烯醚20Kg。
实施例10
植物源杀虫剂组合物：包括桉叶油2Kg、苦皮藤素10Kg、聚氧乙烯聚氧丙烯嵌段聚醚5Kg、十二烷基苯磺酸钙10Kg、由增效剂制备1提供的增效剂0.3Kg。
实施例11
植物源杀虫剂组合物：包括桉叶油2Kg、异硫氰酸烯丙酯10Kg、聚氧乙烯聚氧丙烯嵌段聚醚5Kg、木质素磺酸钠聚氧乙烯醚5Kg、由增效剂制备2提供的增效剂0.4Kg。
实施例12
植物源杀虫剂组合物：包括桉叶油2Kg、印楝素10Kg、失水山梨醇单油酸酯聚氧乙烯醚25Kg、脂肪醇聚氧乙烯醚5Kg、由增效剂制备3提供的增效剂0.5Kg.
实施例13
植物源杀虫剂组合物：包括桉叶油10Kg、除虫菊素5Kg、失水山梨醇单油酸酯聚氧乙烯醚20Kg、脂肪醇聚氧乙烯醚10Kg、由增效剂制备1提供的增效剂0.3Kg。
实施例14
植物源杀虫剂组合物：包括桉叶油10Kg、藜芦碱5Kg、非离子EO/PO嵌段共聚物1Kg、琥珀酸酯磺酸盐14Kg、由增效剂制备2提供的增效剂0.4Kg。
实施例15
植物源杀虫剂组合物：包括桉叶油10Kg、阿维菌素5Kg、聚氧乙烯聚氧丙烯嵌段聚醚5Kg、失水山梨醇单油酸酯聚氧乙烯醚20Kg、由增效剂制备3提供的增效剂0.5Kg。
实施例16
植物源杀虫剂组合物：包括桉叶油20Kg、蛇床子素0.1Kg、聚氧乙烯聚氧丙烯嵌段聚醚5Kg、失水山梨醇单油酸酯聚氧乙烯醚20Kg、由增效剂制备1提供的增效剂0.3Kg。
实施例17
植物源杀虫剂组合物：包括桉叶油20Kg、小檗碱0.1Kg、聚氧乙烯聚氧丙烯嵌段聚醚5Kg、失水山梨醇单油酸酯聚氧乙烯醚20Kg、由增效剂制备2提供的增效剂0.4Kg。
实施例18
植物源杀虫剂组合物：包括桉叶油20Kg、苦皮藤素0.1Kg、聚氧乙烯聚氧丙烯嵌段聚醚5Kg、失水山梨醇单油酸酯聚氧乙烯醚20Kg、由增效剂制备3提供的增效剂0.5Kg。
采用实施例1-18提供的植物源杀虫剂组合物对茶小绿叶蝉、枸杞蚜虫、黄瓜白粉虱、茄子白粉虱进行防治试验，试验结果见表1-2。
试验于2018年10月20日在南昌市江西省蚕桑茶叶研究所茶园进行，茶树秋梢期、茶小绿叶蝉低龄若虫发生始盛期。
施药方法：将实施例1-18提供的植物源杀虫剂组合物进行稀释500倍进行喷淋施药，施药次数为1次。
药前(10月20日)调查虫口基数，药后1d(10月21日)、3d(10月23日)和7d(10月27日)各调查1次残存虫量。并采用邓肯氏新复极差(DMRT)法对试验数据进行统计分析。
表1防治茶树茶小绿叶蝉田间药效试验结果
由表1可以知，本发明提供的植物源杀虫剂组合物对茶小绿叶蝉的防治效果显著，尤其是加入本发明提供的增效剂，显著提高了本发明植物源杀虫剂组合物对茶小绿叶蝉的防治效果。
表2防治枸杞蚜虫、黄瓜白粉虱、茄子白粉虱田间药效试验结果
由表2可以知，本发明提供的植物源杀虫剂组合物对枸杞蚜虫、黄瓜白粉虱、茄子白粉虱的防治效果显著，尤其是加入本发明提供的增效剂，显著提高了本发明植物源杀虫剂组合物对枸杞蚜虫、黄瓜白粉虱、茄子白粉虱的防治效果。
除此之外，本发明提供的植物源杀虫剂组合物对环境友好、对人畜无害，有利于生态环境的保护、增加了处理后水体的安全性。
应该理解的是，本发明实施例所述制备方法仅仅是用于说明本发明，而不是对本发明的限制，在本发明的构思前提下对本发明制备方法的简单改进都属于本发明要求保护的范围。
Claims (9)
1.植物源杀虫剂组合物，其特征在于，包括1-20重量份的有效成分A和0.1-10的有效成分B,所述有效成分A包括桉叶油，所述有效成分B包括苦皮藤素、异硫氰酸烯丙酯、印楝素、除虫菊素、藜芦碱、阿维菌素、蛇床子素、小檗碱中的一种或多种。
2.根据权利要求1所述的植物源杀虫剂组合物，其特征在于，所述桉叶油采用下述方法制备：
(1)将蓝桉或大叶桉的枝叶加入到提取罐中,向提取罐通入水蒸汽，通气时间为1-1.5小时；停至通入水蒸汽,并冷却提取罐，待提取罐的温度降为室温时，将罐内液体通过过滤装置通至油水分离器，得到粗桉叶油；
(2)将步骤(1)得到的粗桉叶油通至蒸馏塔，收集 175-180℃的馏出液，即桉叶油。
3.根据权利要求1所述的植物源杀虫剂组合物，其特征在于，还包括10-60重量份数的表面活性剂。
4.根据权利要求3所述的植物源杀虫剂组合物，其特征在于，所述表面活性剂包括苯乙烯基酚聚氧乙烯聚氧丙烯醚、烷基酚甲醛树脂聚氧乙烯醚、腰果酚聚氧乙烯醚、二苯乙烯苯酚多聚甲醛缩合物聚氧乙烯醚、植物油聚氧乙烯醚、聚氧乙烯聚氧丙烯嵌段聚醚、脂肪酸聚氧乙烯醚、烷基酚聚氧乙烯醚、2-萘磺酸甲醛聚合物钠盐、木质素磺酸盐、丙烯酸系高分子分散剂、山梨醇酯聚氧乙烯醚、有机硅聚氧乙烯醚、失水山梨醇单油酸酯聚氧乙烯醚、牛脂胺聚氧乙烯醚、十二烷基苯磺酸钙、硫酸醋盐、磺酸盐类、聚醚改性七甲基三硅氧烷、琥珀酸酯磺酸盐、高分子聚羧酸盐、磷酸酯盐、改性端烯烃磺酸盐、木质素磺酸钠聚氧乙烯醚、非离子EO/PO嵌段共聚物和经修饰的羧酸酸盐复合物、新型脂肪醇聚氧乙烯醚、烷基糖苷中的一种或多种。
5.根据权利要求1所述的植物源杀虫剂组合物，其特征在于，还包括0.3-0.5重量份的增效剂。
6.根据权利要求5所述的植物源杀虫剂组合物，其特征在于，所述增效剂采用下述方法制备：将包含六甲撑二异氰酸酯、二甲基硅油的混合料加热至90℃，聚合反应1小时；降温至85℃，加入二羟甲基丙酸，扩链反应3小时；加入三羟甲基丙烷，交联反应1小时；加入丙烯酸羟乙酯，封端反应1.5小时；降温至20-30℃，加入丙烯酸六氟丁酯和溶剂，自由基聚合反应0.25小时，除去溶剂，即得所述增效剂；以重量份数计，六甲撑二异氰酸酯20-22份、二甲基硅油9-10份、二羟甲基丙酸6-7份、三羟甲基丙烷1.5-1.7份、丙烯酸羟乙酯3-5份、溶剂30-50份、丙烯酸六氟丁酯7-10份。
7.根据权利要求6所述的植物源杀虫剂组合物，其特征在于，所述自由基聚合反应的引发条件是加入5-10重量份数的重量百分比浓度为30％的双氧水。
8.根据权利要求6所述的植物源杀虫剂组合物，其特征在于，所述溶剂为去离子水。
9.根据权利要求1至8中任意一项所述的植物源杀虫剂组合物，其特征在于，所述植物源杀虫剂组合物制成可溶液剂、水剂、微乳剂、水乳剂、悬浮剂、悬乳剂、可分散油悬浮剂、乳油、水可分散粒剂、油剂、展膜油剂、脂剂、油乳剂、油悬浮剂、微囊悬浮剂，油分散粉剂、水分散片剂、乳粉剂、乳粒剂的剂型。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910628344.XA CN110250222A (zh) | 2019-07-12 | 2019-07-12 | 植物源杀虫剂组合物 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910628344.XA CN110250222A (zh) | 2019-07-12 | 2019-07-12 | 植物源杀虫剂组合物 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110250222A true CN110250222A (zh) | 2019-09-20 |
Family
ID=67925885
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910628344.XA Pending CN110250222A (zh) | 2019-07-12 | 2019-07-12 | 植物源杀虫剂组合物 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110250222A (zh) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112167271A (zh) * | 2020-09-26 | 2021-01-05 | 北京亚戈农生物药业有限公司 | 一种生物熏蒸增效组合物及安全长效生物熏蒸剂和应用 |
| CN112521783A (zh) * | 2020-11-30 | 2021-03-19 | 北部湾海洋新材料研究院 | 一种防污防腐海洋涂料 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102038011A (zh) * | 2009-10-20 | 2011-05-04 | 王海军 | 杀虫灭蝇喷雾剂 |
| CN105145663A (zh) * | 2015-10-08 | 2015-12-16 | 广西南宁益土生物科技有限责任公司 | 一种含印楝素和桉叶油的植物源农药组合物 |
| CN105284917A (zh) * | 2015-10-08 | 2016-02-03 | 广西南宁益土生物科技有限责任公司 | 一种含印楝素和丁香油的植物源农药组合物 |
| CN107646916A (zh) * | 2017-09-28 | 2018-02-02 | 张大勇 | 家用杀虫气雾剂 |
-
2019
- 2019-07-12 CN CN201910628344.XA patent/CN110250222A/zh active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102038011A (zh) * | 2009-10-20 | 2011-05-04 | 王海军 | 杀虫灭蝇喷雾剂 |
| CN105145663A (zh) * | 2015-10-08 | 2015-12-16 | 广西南宁益土生物科技有限责任公司 | 一种含印楝素和桉叶油的植物源农药组合物 |
| CN105284917A (zh) * | 2015-10-08 | 2016-02-03 | 广西南宁益土生物科技有限责任公司 | 一种含印楝素和丁香油的植物源农药组合物 |
| CN107646916A (zh) * | 2017-09-28 | 2018-02-02 | 张大勇 | 家用杀虫气雾剂 |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112167271A (zh) * | 2020-09-26 | 2021-01-05 | 北京亚戈农生物药业有限公司 | 一种生物熏蒸增效组合物及安全长效生物熏蒸剂和应用 |
| CN112521783A (zh) * | 2020-11-30 | 2021-03-19 | 北部湾海洋新材料研究院 | 一种防污防腐海洋涂料 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Patil et al. | Bioefficacy of Plumbago zeylanica (Plumbaginaceae) and Cestrum nocturnum (Solanaceae) plant extracts against Aedes aegypti (Diptera: Culicide) and nontarget fish Poecilia reticulata | |
| CN101720791A (zh) | 一种苦参碱纯植物源杀虫剂 | |
| CN110250222A (zh) | 植物源杀虫剂组合物 | |
| Mahmoud et al. | Effect of basil (Ocimum basilicum) Leaves Powder and Ethanolic-Extract on the 3 rd Larval Instar of Anopheles arabiensis (Patton, 1905)(Culicidae: Diptera) | |
| CN101984828B (zh) | 一种复配杀虫剂 | |
| CN104488918A (zh) | 一种含茶多酚与薯蓣皂苷的植物源增效复配杀虫剂 | |
| CN103300020B (zh) | 一种农药组合物 | |
| de Rodríguez et al. | Flourensia cernua DC: a plant from Mexican semiarid regions with a broad spectrum of action for disease control | |
| CN103271103B (zh) | 一种含苦参碱和伏毛铁棒锤生物碱的植物源复配杀虫剂及其制备方法 | |
| CN103355326A (zh) | 一种高效农药组合物 | |
| Alievi et al. | Ateleia glazioveana and Ocimum basilicum: plants with potential larvicidal and repellent against Aedes aegypti (Diptera, Culicidae) | |
| CN101485329A (zh) | 一种杀虫农药组合物及其应用 | |
| CN105123700A (zh) | 一种含有百里香酚与槟榔碱的杀虫杀菌剂及其制备方法 | |
| CN110169422A (zh) | 一种复方剂型植物杀菌剂及其制备方法和应用 | |
| WO2014126411A1 (ko) | 천연 살충제 조성물 | |
| CN102228044A (zh) | 一种含有硫氟肟醚的杀虫组合物 | |
| Amerasan et al. | Bioefficacy of Morinda tinctoria and Pongamia glabra plant extracts against the malaria vector Anopheles stephensi (Diptera: Culicidae) | |
| Habbachi et al. | Toxicity of aqueous extracts from Mediterranean plants on Culex pipiens (Mosquitoes), Case of Daphne gnidium (Thymelaeaceae) and Peganum harmala (Zygophyllaceae) | |
| CN108113929A (zh) | 一种纯植物的驱蚊止痒复方精油 | |
| CN105994431A (zh) | 高效持久的白蚁防治制剂及其制备方法 | |
| CN101653120B (zh) | 一种含有喹螨醚的杀螨组合物 | |
| CN105994275A (zh) | 一种环虫酰肼与生物源类的农药组合物 | |
| CN1140178C (zh) | 非洲山毛豆杀虫剂及其制造方法 | |
| El-Massad et al. | Insecticidal potentiality of Datura innoxia leaf extracts against the cluster bug (Agonoscelis pubescens (Thunberg)) | |
| CN110024803A (zh) | 一种含螺虫乙酯的杀虫组合物及其制剂 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190920 |