CN110240417A - A kind of glass surface forms the film plating process of gradient color - Google Patents

A kind of glass surface forms the film plating process of gradient color Download PDF

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Publication number
CN110240417A
CN110240417A CN201910608438.0A CN201910608438A CN110240417A CN 110240417 A CN110240417 A CN 110240417A CN 201910608438 A CN201910608438 A CN 201910608438A CN 110240417 A CN110240417 A CN 110240417A
Authority
CN
China
Prior art keywords
toning
baffle
glass surface
plating process
film plating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910608438.0A
Other languages
Chinese (zh)
Inventor
陈诚
张少波
钟汝梅
张明明
黄金鑫
周俊
邵帅
张煜东
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ANHUI BENGBU HUAYI CONDUCTIVE FILM GLASS Co Ltd
Original Assignee
ANHUI BENGBU HUAYI CONDUCTIVE FILM GLASS Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ANHUI BENGBU HUAYI CONDUCTIVE FILM GLASS Co Ltd filed Critical ANHUI BENGBU HUAYI CONDUCTIVE FILM GLASS Co Ltd
Priority to CN201910608438.0A priority Critical patent/CN110240417A/en
Publication of CN110240417A publication Critical patent/CN110240417A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/001General methods for coating; Devices therefor
    • C03C17/002General methods for coating; Devices therefor for flat glass, e.g. float glass
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/22Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00Coatings on glass
    • C03C2217/20Materials for coating a single layer on glass
    • C03C2217/21Oxides
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00Coatings on glass
    • C03C2217/20Materials for coating a single layer on glass
    • C03C2217/25Metals
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00Coatings on glass
    • C03C2217/70Properties of coatings
    • C03C2217/72Decorative coatings
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00Methods for coating glass
    • C03C2218/10Deposition methods
    • C03C2218/15Deposition methods from the vapour phase

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Surface Treatment Of Glass (AREA)

Abstract

The present invention discloses a kind of film plating process of glass surface formation gradient color: using specific toning baffle, partial occlusion is carried out above electron gun evaporation source, deposition materials is made to form two kinds of transition gradient colors in glass surface;A variety of fade effects are formed by adjusting toning baffle shapes, size and blocking position;The film plating process, specifically includes the following steps: S1: the selection of Coating Materials;S2: the design for baffle of mixing colours;S3: optics gradual change plated film.Compared to traditional gradient color coating process, the method for the present invention is simple, easily controllable, need to only adjust shape, size and the blocking position of toning baffle, and control electron gun heating power, heating time can form the plated film of predetermined fade effect.

Description

A kind of glass surface forms the film plating process of gradient color
Technical field
The invention belongs to glass surface treatment technical fields, and in particular to a kind of glass surface forms the plated film side of gradient color Method.
Background technique
From in September, 2017, the design that OPPO releases red blue gradual change starts national all big enterprises and uses gradient color conduct one after another The new selection of cell phone rear cover.It is column, R series, the Reno series of oppo with the flagship type of major mobile phone producer in this year;Huawei P Series, Mate series and honor series etc., by gradient color on mobile phone.
Conventional mobile phone industry mostly uses pure color to match colors as mobile phone, and stereotyped be not black is exactly white, it appears thin And few taste even more seems cheap if manufacture craft is slightly insufficient.Compared to traditional pure color, gradient color is colorful and gorgeous , so that mobile phone has full individual character, can distinguish at a glance;Meanwhile the aperture demand of mobile phone at this stage is more and more, and mobile phone For forehead when needing using multiple black apertures, pure color mobile phone face value will receive very big influence, especially lily hand Machine.In addition, the design shielded of mobile phone now is also more and more, but the technology of Rimless design or not mature enough, greatly comprehensively Although the very little that most cell phone intelligents shrink frame, it is most of be also select black, so, lily rear cover is just more It is indisposed.Therefore, under the influence of various gradient color at most popular mobile phone color matching method instantly.
Currently, gradient color film plating process both domestic and external be broadly divided into it is following several:
1) anodic oxidation: here it is the common methods of metallic mobile phone shell, this technology is not so difficult, but go for managing The effect thought needs strict control dyeing temperature, time, pH value and dye strength etc.;
2) spraying dyeing: it will be sprayed directly into material surface after pigment atomization, the more local color of spraying is deeper, more Few more shallow s of local color is until white, this method is simple and crude, applies in general to monochromatic gradual change;
3) heat transfer colour ribbon: this is a kind of method similar to duplicating, first mixes up ink, is coloured in Transfer ribbon, The color on colour band is molten on material at high temperature again;
4) silk-screen printing: this method is usually used in printing, and does not have figuratum local silk screen extremely fine and closely woven, can stop oil Ink;Figuratum place mesh is bigger, and ink controls the size and density degree of screen mesh, energy through pattern is formed Control ink penetrate number, to form the effect of gradual change;
5) physical vapour deposition (PVD): this method is exactly then to spray to first by specific solid material high-temperature gasification at molecule On fuselage, due to the difference of coating thickness, when optical interference, diffraction, fuselage just shows different colors.
Optics gradual change coating technique research of the present invention is that one kind is based on vacuum nano gradually depositing process, by the gradually plating of field of jewelry Color technology covers after being applied to mobile phone glass, shows the color change being derived from nature spectrum, shows the technique beauty of other style Sense.
Summary of the invention
The purpose of the present invention is to provide the film plating process that a kind of glass surface forms gradient color, pass through specific toning baffle Regulate and control the thicknesses of layers of plated glass surface gradation zone deposition, different zones thicknesses of layers difference can make plated film color from one A color is slowly transitioned into another color.
Technical solution of the present invention is summarized as follows:
A kind of glass surface forms the film plating process of gradient color: using specific toning baffle, on electron gun evaporation source Fang Jinhang partial occlusion makes deposition materials form two kinds of transition gradient colors in glass surface;By adjusting toning baffle shapes, ruler Very little and blocking position forms a variety of fade effects;
The film plating process, specifically includes the following steps:
S1: the selection of Coating Materials: the optical color presented according to different materials, plated film target needed for selecting;
S2: the design for baffle of mixing colours: according to predetermined fade effect, design toning baffle shapes, size;
S3: optics gradual change plated film: being plated base with bright and clean smooth glass using optics evaporation coating machine as filming equipment Bottom, by specific toning baffle plate setting, the position 20~28cm, progress partial occlusion make deposition materials exist above electron gun evaporation source Glass surface forms two kinds of transition gradient colors;Electron gun evaporation source heating technique parameter: electron gun power be 10~ 300kW, heating time are 8~50min.
Preferably, the plated film target include the metal with optical color, metal oxide, metal salt, it is nonmetallic, Any one in nonmetal oxide.
Preferably, it is described toning baffle shape be rectangle, round rectangle, triangle, semicircle, it is trapezoidal in it is any It is a kind of.
Preferably, the toning baffle bottom edge and plated glass bottom edge are wide, and keeping parallelism;Toning baffle area be 0.4~0.6 times of plated transparency area.
Detailed description of the invention
Fig. 1 is film plating process flow chart of the present invention;
Fig. 2 is optics evaporation coating machine operation principle schematic diagram;
Fig. 3 is that optics evaporation coating machine of the present invention is coated with gradient color film schematic diagram.
Beneficial effects of the present invention:
1, compared to traditional gradient color coating process, the method for the present invention is simple, easily controllable, need to only adjust toning baffle Shape, size and blocking position, control electron gun heating power, heating time can form the plated film of predetermined fade effect.
2, the present invention provides evaporation energy by electron beam, makes to evaporate material with molecular state spilling from evaporating point to glass table Face is deposited, in coating process, since the amount that occlusion area deposits evaporation state is less than non-occluded area, the corresponding production of the two Product region just will form different thicknesses of layers, to make plated film color slowly be transitioned into another color from a color, together When, toning baffle is remoter apart from electron gun evaporation source, i.e. toning baffle is closer with glass base substrate, and shield effectiveness is more obvious, gradually Discoloration difference is also stronger, therefore, can also form a variety of fade effects by whole toning baffle shapes and position.
Specific embodiment
The present invention will be further described in detail below with reference to the embodiments, to enable those skilled in the art referring to specification Text can be implemented accordingly.
The glass surface that the present invention provides a specific embodiment forms the film plating process of gradient color, and plated film used in this method is set Standby is optics evaporation coating machine, its working principles are as follows: using electron beam for thermal evaporation sources, the thermoelectron emitted from filament is through yin High voltage electric field between pole and anode accelerates and focuses, and is allowed to deflection by magnetic field and reaches crucible evaporation material surface, heating evaporation material Material makes to evaporate material molecule spilling, gasifies and uniform deposition is attached to substrate surface, form the coating (film layer that this state is coated with It is evenly distributed as conventional coating process), above-mentioned operation principle schematic diagram is shown in Fig. 1;
The glass surface forms the film plating process of gradient color, specifically includes the following steps:
S1: Coating Materials selects: selecting blue-green chromium sulfate as plated film target, chromium sulfate boiling point is 330 DEG C, design From light green color to the gradient color of blue transition;
S2: the design for baffle of mixing colours: being rectangle by baffle design according to scheduled fade effect, and baffle bottom edge of mixing colours Wide with plated glass bottom edge, toning baffle area is 0.45 times of plated transparency area;
S3: optics gradual change plated film, the process schematic are as shown in Figure 2: using optics evaporation coating machine as filming equipment, choosing Selecting bright and clean smooth glass is plated substrate, by specific toning baffle plate setting above 50kW electron gun evaporation source the position 25cm, Regulating fender bottom edge and plated glass bottom edge keeping parallelism carry out partial occlusion gradual change plated film, and (i.e. chromium sulfate heats plated film time Evaporation time) it is 15min, evaporation energy is provided by electron beam, makes to evaporate material chromium sulfate with molecular state spilling by evaporating point It is deposited to glass surface, in coating process, is not blocked since the amount of the evaporation state chromium sulfate of occlusion area deposition is less than Region, the corresponding product area of the two just will form different thicknesses of layers, to be formed from light green color to the transition of blue gradually Discoloration, meanwhile, toning baffle is remoter apart from electron gun evaporation source, i.e. toning baffle is closer with glass base substrate, and shield effectiveness is got over Obviously, gradual change color difference is also stronger, therefore, can also form a variety of fade effects by whole toning baffle shapes and position.
Although the embodiments of the present invention have been disclosed as above, but its is not only in the description and the implementation listed With it can be fully applied to various fields suitable for the present invention, for those skilled in the art, can be easily Realize other modification, therefore without departing from the general concept defined in the claims and the equivalent scope, the present invention is simultaneously unlimited In specific details.

Claims (4)

1. the film plating process that a kind of glass surface forms gradient color, it is characterised in that: using specific toning baffle, in electron gun Partial occlusion is carried out above evaporation source, and deposition materials is made to form two kinds of transition gradient colors in glass surface;By adjusting toning gear Plate shape, size and blocking position form a variety of fade effects;
The film plating process, specifically includes the following steps:
S1: the selection of Coating Materials: the optical color presented according to different materials, plated film target needed for selecting;
S2: the design for baffle of mixing colours: according to predetermined fade effect, design toning baffle shapes, size;
S3: optics gradual change plated film: being plated substrate with bright and clean smooth glass using optics evaporation coating machine as filming equipment, By specific toning baffle plate setting, the position 20~28cm, progress partial occlusion make deposition materials in glass above electron gun evaporation source Glass surface forms two kinds of transition gradient colors;Electron gun evaporation source heating technique parameter: electron gun power is 10~300kW, Heating time is 8~50min.
2. a kind of glass surface forms the film plating process of gradient color according to claim 1, which is characterized in that the coated target Material includes the metal with optical color, metal oxide, metal salt, nonmetallic, any one in nonmetal oxide.
3. a kind of glass surface forms the film plating process of gradient color according to claim 1, which is characterized in that the toning gear The shape of plate be rectangle, round rectangle, triangle, semicircle, it is trapezoidal in any one.
4. a kind of glass surface forms the film plating process of gradient color according to claim 1, which is characterized in that the toning gear Board bottom side and plated glass bottom edge are wide, and keeping parallelism;Toning baffle area is 0.4~0.6 times of plated transparency area.
CN201910608438.0A 2019-07-08 2019-07-08 A kind of glass surface forms the film plating process of gradient color Pending CN110240417A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110607505A (en) * 2019-10-31 2019-12-24 苏州市三同真空镀膜有限公司 Method for coating mobile phone rear cover with color gradient
CN110760795A (en) * 2019-12-03 2020-02-07 泰州光丽光电科技有限公司 Gradually-changed film-coating typesetting mode and application method thereof
CN110826257A (en) * 2019-12-03 2020-02-21 泰州光丽光电科技有限公司 Optimization method of vacuum gradient coating film system process design
CN111519149A (en) * 2020-05-19 2020-08-11 深圳森丰真空镀膜有限公司 Method for manufacturing gradient color coating based on physical vapor deposition and product
CN114150274A (en) * 2021-10-31 2022-03-08 东莞市齐品光学有限公司 Coating device with up-down gradient and gradient color adjusting method
CN115074676A (en) * 2022-06-22 2022-09-20 东莞瑞彩光学薄膜有限公司 Coating process of gradient color film

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CN107840583A (en) * 2017-11-28 2018-03-27 信利光电股份有限公司 A kind of color gradient glass and preparation method thereof
CN108728796A (en) * 2017-04-19 2018-11-02 蓝思科技(长沙)有限公司 The preparation method and revision board of color gradient film
CN109023280A (en) * 2018-09-17 2018-12-18 深圳市三海科技有限公司 A kind of method that magnetron sputter prepares graduated colors film

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110607505A (en) * 2019-10-31 2019-12-24 苏州市三同真空镀膜有限公司 Method for coating mobile phone rear cover with color gradient
CN110760795A (en) * 2019-12-03 2020-02-07 泰州光丽光电科技有限公司 Gradually-changed film-coating typesetting mode and application method thereof
CN110826257A (en) * 2019-12-03 2020-02-21 泰州光丽光电科技有限公司 Optimization method of vacuum gradient coating film system process design
CN110826257B (en) * 2019-12-03 2023-07-21 泰州光丽光电科技有限公司 Optimization method for vacuum gradient coating film system process design
CN111519149A (en) * 2020-05-19 2020-08-11 深圳森丰真空镀膜有限公司 Method for manufacturing gradient color coating based on physical vapor deposition and product
CN111519149B (en) * 2020-05-19 2022-05-03 深圳森丰真空镀膜有限公司 Method for manufacturing gradient color coating based on physical vapor deposition and product
CN114150274A (en) * 2021-10-31 2022-03-08 东莞市齐品光学有限公司 Coating device with up-down gradient and gradient color adjusting method
CN115074676A (en) * 2022-06-22 2022-09-20 东莞瑞彩光学薄膜有限公司 Coating process of gradient color film

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