CN110237693A - A kind of cement plant kiln exit gas cooling, desulfurizing synergistic device - Google Patents

A kind of cement plant kiln exit gas cooling, desulfurizing synergistic device Download PDF

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Publication number
CN110237693A
CN110237693A CN201910516843.XA CN201910516843A CN110237693A CN 110237693 A CN110237693 A CN 110237693A CN 201910516843 A CN201910516843 A CN 201910516843A CN 110237693 A CN110237693 A CN 110237693A
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CN
China
Prior art keywords
outlet
import
flue gas
grinding system
wet
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Pending
Application number
CN201910516843.XA
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Chinese (zh)
Inventor
施勇
穆璐莹
吕忠新
朱孝峰
沈龙
陶巍
陈雪
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HEFEJI ZHONGYA ENVIRONMENTAL PROTECTION TECHNOLOGY Co Ltd
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HEFEJI ZHONGYA ENVIRONMENTAL PROTECTION TECHNOLOGY Co Ltd
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Priority to CN201910516843.XA priority Critical patent/CN110237693A/en
Publication of CN110237693A publication Critical patent/CN110237693A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/02Particle separators, e.g. dust precipitators, having hollow filters made of flexible material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D50/00Combinations of methods or devices for separating particles from gases or vapours
    • B01D50/60Combinations of devices covered by groups B01D46/00 and B01D47/00
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/50Sulfur oxides
    • B01D53/501Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
    • B01D53/502Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound characterised by a specific solution or suspension
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/50Sulfur oxides
    • B01D53/508Sulfur oxides by treating the gases with solids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/75Multi-step processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77Liquid phase processes
    • B01D53/78Liquid phase processes with gas-liquid contact
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/81Solid phase processes
    • B01D53/83Solid phase processes with moving reactants
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00Arrangements of devices for treating smoke or fumes
    • F23J15/06Arrangements of devices for treating smoke or fumes of coolers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • B01D2258/0283Flue gases

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Treating Waste Gases (AREA)

Abstract

The invention discloses a kind of cement plant kiln exit gas cooling, desulfurizing synergistic devices, it include raw grinding system, flue gas mixer, lime injection device, bag-type dusting reactor and wet desulfuration tower, the outlet import with raw grinding system respectively of kiln exit gas, the import of flue gas mixer connects, the outlet of raw grinding system, the outlet of flue gas mixer is connect with the feed inlet of lime injection device, lime injection device, bag-type dusting reactor, wet desulfuration tower, chimney is sequentially connected with, the outlet of wet desulfuration tower is connect by by-pass line with the import of flue gas mixer.The present invention carries out drying cooling to kiln exit gas using raw grinding system, when raw grinding system does not work, drying cooling is carried out to kiln exit gas using the wet flue gas that wet desulfuration tower is discharged, it ensure that entering kiln exit gas in wet desulfuration tower guarantees the normal work of wet desulfuration tower lower than 160 DEG C.

Description

A kind of cement plant kiln exit gas cooling, desulfurizing synergistic device
Technical field
The present invention relates to cement plant kiln exit gas process field, specifically a kind of cement plant kiln exit gas cooling, desulfurizing synergy System.
Background technique
As country is to the limitation of mining and the reduction of fat lime stone storage, many cement plants have to using Low-grade limestone causes the SO in kiln exit gas2It is exceeded, in order to reduce the SO in kiln exit gas2, wet process (kiln can be used Ash-gypsum) technique progress desulfurization.But the temperature of kiln exit gas is higher, it can be to wet if be directly entered in wet desulfuration tower Anti-corrosion material glass flake in method desulfurizing tower damages.
Cement plant can dry raw material grinding system using the hot fume of kiln tail, and Raw Material System can generate large quantities of lime stone Fine powder, limestone fines can be with the part SO in flue gas2Reaction, but raw material grinding system and kiln system operate sync rates about 85%, When raw material grinding system is out of service (flue-gas temperature increases), actual condition air quantity increases, after being directly entered kiln tail dust-precipitator, meeting Increase the resistance of deduster and the power consumption of last row blower;There is no a large amount of raw material fine powders, so2 concentration in flue gas can also increase, wet process The load of desulphurization system can significantly increase.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of cement plant kiln exit gas cooling, desulfurizing synergistic devices, using life Feed powder grinding system carries out drying cooling to kiln exit gas, when raw grinding system does not work, using wet desulfuration tower discharge Wet flue gas carries out drying cooling to kiln exit gas, ensure that into kiln exit gas in wet desulfuration tower lower than 160 DEG C, guarantees wet process The normal work of desulfurizing tower.
The technical solution of the present invention is as follows:
A kind of cement plant kiln exit gas cooling, desulfurizing synergistic device includes raw grinding system, flue gas mixer, lime The outlet of powder injection apparatus, bag-type dusting reactor and wet desulfuration tower, the cement plant kiln exit gas passes through admission line It is connect respectively with the import of raw grinding system, the import of flue gas mixer, the outlet of the raw grinding system, flue gas are mixed The outlet of clutch is connect with the feed inlet of lime injection device, and the jet exit and bag-type dusting of lime injection device are anti- The import of device is answered to connect, the outlet of bag-type dusting reactor and the import of wet desulfuration tower connect, the wet desulfuration tower Outlet is connect by discharge line with chimney, and by-pass line is connected on the discharge line, the wet desulfuration tower Outlet is connect by by-pass line with the import of flue gas mixer.
The junction of the discharge line and by-pass line is provided with electromagnetism by-passing valve, the electromagnetism by-passing valve, life Feed powder grinding system is connect with controller.
Booster fan is provided on the by-pass line, the outlet of wet desulfuration tower passes through by-pass line and booster fan Import connection, the outlet of booster fan is connect by by-pass line with the import of flue gas mixer.
The outlet of the bag-type dusting reactor is connected by the import of smoke induced draught fan and wet desulfuration tower.
Advantages of the present invention:
(1), the present invention is provided with raw grinding system, and kiln exit gas temperature after cogeneration is down to 200 DEG C or so, with Hot fume enters raw grinding system and dries to material afterwards, and the flue gas after drying can be near 120 DEG C or so, enters back into subsequent Bag-type dusting reactor and wet desulfuration tower are dusted and desulfurization process, avoids temperature is excessively high from causing anti-corrosion in wet desulfuration tower The damage of material glass scale;
(2), raw grinding system of the invention and kiln system operate sync rates general 85%, in raw grinding system and kiln When system is asynchronous, i.e., the intake valve of raw grinding system can close, and hot fume can enter flue gas mixer at this time and wet process is de- The wet flue gas of sulphur tower discharge is mixed, so that hot fume is carried out humidifying cooling to 150 DEG C, it is anti-to enter back into subsequent bag-type dusting It answers device and wet desulfuration tower to be dusted and desulfurization process, avoids temperature is excessively high from causing anti-corrosion material glass squama in wet desulfuration tower The damage of piece;
(3), lime injection device is arranged in the present invention before bag-type dusting reactor, passes through calcium-base absorbing agent-pulverized limestone Improve the calcium sulfur ratio of flue gas desulfurization.
It (4), can be effective by being humidified and being supplemented calcium-base absorbing agent-pulverized limestone into the flue gas before deduster The desulfuration efficiency for improving sack cleaner, reduces the operating load of wet desulphurization.
Detailed description of the invention
Fig. 1 is structural schematic diagram of the invention, wherein " -- " is saturation wet flue gas pipeline, and " --- " is the hot cigarette of kiln tail Air pipe.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other Embodiment shall fall within the protection scope of the present invention.
See that Fig. 1, a kind of cement plant kiln exit gas cooling, desulfurizing synergistic device include raw grinding system 1, flue gas mixing Device 2, lime injection device 3, bag-type dusting reactor 4 and wet desulfuration tower 6, the outlet of cement plant kiln exit gas pass through air inlet Pipeline is connect with the import of raw grinding system 1, the import of flue gas mixer 2 respectively, the outlet of raw grinding system 1, flue gas The outlet of mixer 2 is connect with the feed inlet of lime injection device 3, the jet exit and pocket type of lime injection device 3 The import of dedusting reactor 4 connects, and the outlet of bag-type dusting reactor 4 passes through the import of smoke induced draught fan 5 and wet desulfuration tower 6 The outlet of connection, wet desulfuration tower 6 is connect by discharge line with chimney 7, and by-pass line, bypass pipe are connected on discharge line Booster fan 8 is provided on road, the outlet of wet desulfuration tower 6 is connect by by-pass line with the import of booster fan 8, and wind is pressurized The outlet of machine 8 is connect by by-pass line with the import of flue gas mixer 2, and the junction of discharge line and by-pass line is provided with Electromagnetism by-passing valve 9, electromagnetism by-passing valve 9, raw grinding system 1 are connect with controller.
When 1 intake valve of raw grinding system is opened, kiln exit gas temperature after cogeneration is down to 200 DEG C or so, then Hot fume, which enters raw grinding system, dries material, and the flue gas after drying can be near 120 DEG C or so, enters back into subsequent bag Formula dedusting reactor and wet desulfuration tower are dusted and desulfurization process;When 1 intake valve of raw grinding system is not switched on, control Device acquires the switching value of 1 intake valve of raw grinding system, then controls electromagnetism by-passing valve 9 and opens, wet desulfuration tower is discharged at this time Wet flue gas can enter flue gas mixer be mixed with kiln tail hot fume, thus by hot fume progress humidifying cooling to 150 DEG C, It enters back into subsequent bag-type dusting reactor and wet desulfuration tower is dusted and desulfurization process, flue gas up to standard is discharged by chimney 7 To atmosphere.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding And modification, the scope of the present invention is defined by the appended.

Claims (4)

1. a kind of cement plant kiln exit gas cooling, desulfurizing synergistic device, it is characterised in that: include that raw grinding system, flue gas are mixed The outlet of clutch, lime injection device, bag-type dusting reactor and wet desulfuration tower, the cement plant kiln exit gas passes through Admission line is connect with the import of raw grinding system, the import of flue gas mixer respectively, and the raw grinding system goes out Mouthful, the outlet of flue gas mixer connect with the feed inlet of lime injection device, the jet exit of lime injection device and The import of bag-type dusting reactor connects, and the outlet of bag-type dusting reactor and the import of wet desulfuration tower connect, and described is wet The outlet of method desulfurizing tower is connect by discharge line with chimney, by-pass line is connected on the discharge line, described is wet The outlet of method desulfurizing tower is connect by by-pass line with the import of flue gas mixer.
2. a kind of cement plant kiln exit gas cooling, desulfurizing synergistic device according to claim 1, it is characterised in that: described The junction of discharge line and by-pass line is provided with electromagnetism by-passing valve, the electromagnetism by-passing valve, raw grinding system with Controller connection.
3. a kind of cement plant kiln exit gas cooling, desulfurizing synergistic device according to claim 1, it is characterised in that: described Booster fan is provided on by-pass line, the outlet of wet desulfuration tower is connected by the import of by-pass line and booster fan, increased The outlet of pressure fan is connect by by-pass line with the import of flue gas mixer.
4. a kind of cement plant kiln exit gas cooling, desulfurizing synergistic device according to claim 1, it is characterised in that: described The outlet of bag-type dusting reactor is connected by the import of smoke induced draught fan and wet desulfuration tower.
CN201910516843.XA 2019-06-14 2019-06-14 A kind of cement plant kiln exit gas cooling, desulfurizing synergistic device Pending CN110237693A (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02298315A (en) * 1989-05-11 1990-12-10 Chiyoda Corp Wet type treatment method for flue gas desulfurization drainage
CN1425491A (en) * 2002-12-09 2003-06-25 武汉凯迪电力股份有限公司 Composite Circulation fluidized dry desulfurization process for flue gas and desalfurizing reaction tower
CN103591599A (en) * 2013-11-21 2014-02-19 上海大学 Discharged flue gas self-heating technology of wet flue gas desulfurization and desulfuration purified flue gas self-heating device
CN108479332A (en) * 2018-04-16 2018-09-04 天津华赛尔传热设备有限公司 A kind of low-temperature flue gas desulphurization denitration disappears white system
CN108554144A (en) * 2018-06-07 2018-09-21 中国科学院过程工程研究所 A kind of SCR denitration system suitable for the high-alkali flue gas of the high dirt of cement kiln tail
CN207951081U (en) * 2018-01-05 2018-10-12 北京万信同和能源科技有限公司 Wet plume abatement equipment for catalytic cracking wet desulphurization device
CN108970355A (en) * 2018-09-06 2018-12-11 大唐环境产业集团股份有限公司 A kind of wet-dry change coupling smoke processing system and method
CN208333137U (en) * 2018-06-15 2019-01-04 重庆三维丝过滤技术有限公司 Cement kiln wet desulfurization flue gas takes off white system
CN109351156A (en) * 2018-11-20 2019-02-19 东方电气集团东方锅炉股份有限公司 A kind of the removing system and removal methods of cement kiln tail gas sulphur dioxide
CN210473593U (en) * 2019-06-14 2020-05-08 合肥中亚环保科技有限公司 Cement plant kiln tail flue gas cooling desulfurization increase system

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* Cited by examiner, † Cited by third party
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CN1425491A (en) * 2002-12-09 2003-06-25 武汉凯迪电力股份有限公司 Composite Circulation fluidized dry desulfurization process for flue gas and desalfurizing reaction tower
CN103591599A (en) * 2013-11-21 2014-02-19 上海大学 Discharged flue gas self-heating technology of wet flue gas desulfurization and desulfuration purified flue gas self-heating device
CN207951081U (en) * 2018-01-05 2018-10-12 北京万信同和能源科技有限公司 Wet plume abatement equipment for catalytic cracking wet desulphurization device
CN108479332A (en) * 2018-04-16 2018-09-04 天津华赛尔传热设备有限公司 A kind of low-temperature flue gas desulphurization denitration disappears white system
CN108554144A (en) * 2018-06-07 2018-09-21 中国科学院过程工程研究所 A kind of SCR denitration system suitable for the high-alkali flue gas of the high dirt of cement kiln tail
CN208333137U (en) * 2018-06-15 2019-01-04 重庆三维丝过滤技术有限公司 Cement kiln wet desulfurization flue gas takes off white system
CN108970355A (en) * 2018-09-06 2018-12-11 大唐环境产业集团股份有限公司 A kind of wet-dry change coupling smoke processing system and method
CN109351156A (en) * 2018-11-20 2019-02-19 东方电气集团东方锅炉股份有限公司 A kind of the removing system and removal methods of cement kiln tail gas sulphur dioxide
CN210473593U (en) * 2019-06-14 2020-05-08 合肥中亚环保科技有限公司 Cement plant kiln tail flue gas cooling desulfurization increase system

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Title
王丽萍等编著: "《煤炭气化工艺与操作》", vol. 1, 北京理工大学出版社, pages: 190 *

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