CN110227317A - A kind of Smoke pollutant treatment device based on electrostatic charged spray - Google Patents

A kind of Smoke pollutant treatment device based on electrostatic charged spray Download PDF

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Publication number
CN110227317A
CN110227317A CN201910540469.7A CN201910540469A CN110227317A CN 110227317 A CN110227317 A CN 110227317A CN 201910540469 A CN201910540469 A CN 201910540469A CN 110227317 A CN110227317 A CN 110227317A
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CN
China
Prior art keywords
desulfurization wastewater
gas
flue
electrostatic
fluid
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Pending
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CN201910540469.7A
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Chinese (zh)
Inventor
庞春波
王军锋
张伟
许浩杰
张澄澄
叶子怡
熊业飞
凌一洲
汪帅
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Jiangsu University
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Jiangsu University
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Priority to CN201910540469.7A priority Critical patent/CN110227317A/en
Publication of CN110227317A publication Critical patent/CN110227317A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D47/00Separating dispersed particles from gases, air or vapours by liquid as separating agent
    • B01D47/06Spray cleaning
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • B01D2258/0283Flue gases

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Treating Waste Gases (AREA)

Abstract

The invention discloses a kind of Smoke pollutant treatment devices based on electrostatic charged spray, including electrostatic atomizer, electrostatic atomizer is arranged on flue, the input end of electrostatic atomizer connects flue, the outlet end of electrostatic atomizer connects chimney, it is equipped with two-fluid spray nozzle at chimney intake, the spout of two-fluid spray nozzle is towards at flue outlet;The liquid-inlet of two-fluid spray nozzle and gas feed input desulfurization wastewater and air respectively;Desulfurization wastewater recyclable device is equipped in the bottom of electrostatic atomizer, two-fluid spray nozzle includes shell and spiral arm, shell is divided into fluid chamber and gas ionization chamber, the entrance of fluid chamber outlet end connection spiral arm, the channel formed among the outlet face spiral arm of gas ionization chamber, it is ejected into flue after desulfurization wastewater is atomized, to change the characteristic of flue gas, the present invention may be implemented desulfurization wastewater zero-emission and promote the removing of coal-fired flue-gas pollutant, can effectively apply the processing that waste gas and wastes are realized in coal-burning power plant.

Description

A kind of Smoke pollutant treatment device based on electrostatic charged spray
Technical field
The invention belongs to flue gas ash removal and organic matter removing sulfuldioxide field more particularly to a kind of flue gases based on electrostatic charged spray Pollutant handling arrangement.
Background technique
China is that maximum coal production state and country of consumption and the world were last uniquely using coal as main energy sources in the world Big country.Coal-burning power plant is the important emission source of Atmospheric particulates, and 2010, China's SO2 discharge amount cut down 10% total amount control Target processed is 2294.4 ten thousand tons, and wherein the control amount of power industry is 951.7 ten thousand tons, and wherein fine particle discharge amount is more than 300 Ten thousand tons.A large amount of coal smoke not only causes the substantial pollutions such as acid rain, while also seriously endangering human health.
In order to reduce sulfide in flue gas such as SO2Discharge, coal-burning power plant prevents in flue gas frequently with Wet Flue Gas Desulfurization Technique Soluble fraction, cl concn are more than specified value and guarantee gypsum quality, it is necessary to a certain amount of waste water are discharged from system, i.e. desulfurization is useless Water.Pollutant component in desulfurization wastewater is mainly from flue gas, and the impurity in flue gas derives from burning of coal.Contain packet in coal The multiple element including heavy metal is included, these elements generate multiple compounds after combustion, and wherein gaseous compound can be with flue gas Into desulphurization system, it is dissolved in and absorbs in slurries.The impurity contained in waste water mainly includes suspended matter, oversaturated sulfurous acid Salt, sulfate and heavy metal, wherein being much the first pollutant for requiring strict control in national environmental standard.
Due to the particularity of desulfurization water quality, desulfurization wastewater processing difficulty is larger, simultaneously as various heavy metal ion are to ring The pollution in border is very serious, and it is necessary for carrying out individually processing to desulfurization wastewater.Currently, the wet process of most domestic power plant is de- Sulphur waste water treatment system carries out the processing of desulfurization wastewater using traditional dosing flocculation sedimentation mode, generally existing operating cost compared with The problems such as height, equipment failure rate is high, operational percentage are very low.In addition, external such as electric flocculation method, evaporation handle the equal energy of desulfurization wastewater Heavy metal even chloride ion in effective processing desulfurization wastewater.But due to multi-party by technology, condition, environment, investment etc. The restriction of face factor fails power plant's application at home.Only external a small number of project inputs use at present, Partial key control Parameter and process still rest on development phase.
In view of the above-mentioned problems, the present invention provides a kind of double jet flow flue gas pollutant processing systems based on electrostatic charged spray, The characteristic that desulfurization wastewater atomized spray can be changed to flue gas into flue may be implemented desulfurization wastewater zero-emission and promote fire coal The removing of flue gas pollutant.
Summary of the invention
The present invention proposes a kind of flue gas pollutant processing based on electrostatic charged spray according to problems of the prior art Device is ejected into flue after being atomized desulfurization wastewater, to change the characteristic of flue gas, desulfurization wastewater zero-emission may be implemented simultaneously Promote the removing of coal-fired flue-gas pollutant, the device energy-wasting is low, purification efficiency is high, structure is simple, can effectively apply in fire coal The processing of waste gas and wastes is realized in power plant.
The technical solution adopted in the present invention is as follows:
A kind of Smoke pollutant treatment device based on electrostatic charged spray, including electrostatic atomizer, the electrostatic spray dress It installs on flue, the input end of electrostatic atomizer connects flue, and the outlet end of electrostatic atomizer connects chimney, in cigarette Road entrance is equipped with two-fluid spray nozzle, and the spout of two-fluid spray nozzle is towards at flue outlet;The liquid of the two-fluid spray nozzle into Mouth and gas feed input desulfurization wastewater and air respectively;Desulfurization wastewater recyclable device is equipped in the bottom of electrostatic atomizer.
Further, the two-fluid spray nozzle includes shell and spiral arm, and the enclosure interior is divided into together by ceramics pipe outer The fluid chamber and gas ionization chamber of axis arrangement, inner ring are gas ionization chamber, and outer ring is fluid chamber, the fluid chamber and gas ionization Chamber is separately connected desulfurization wastewater pond and air, intracavitary equipped with needle electrode in gas ionization, generates a large amount of positive charges for discharging; Fluid chamber outlet end connects the entrance of spiral arm, the channel formed among the outlet face spiral arm of gas ionization chamber, from spiral The desulfurization wastewater that the spout of arm sprays and the air through spraying among spiral arm mix, and netted gully-hole pair is arranged in device bottom surface Partial desulfurization cycling utilization of wastewater.
Further needle electrode connects negative high voltage electrostatic generator;
Further, the diameter of the spout is 0.5mm.
Further, the desulfurization wastewater pond is also in parallel with dilution device, inputs two-fluid after being diluted to desulfurization wastewater Nozzle.
Further, the desulfurization wastewater recyclable device is to be provided with netted gully-hole, netted collection in electrostatic atomizer bottom Water hole connects desulfurization wastewater pond by pipeline, realizes the recycling to the desulfurization wastewater after work.
Beneficial effects of the present invention:
1, a large amount of positive charges of needle electrode corona discharge generation are arranged in the present invention above spout, pass through charged air and liquid Mixed charged is dripped, liquid is avoided and is in direct contact with the electrode, improve the safety of operational process.
2, insulated enclosure mouth is arranged in gas ionization top of chamber in the present invention, and setting ceramics pipe outer in periphery avoids needle-shaped electricity The negative electrical charge that pole electric discharge generates is guided, and charged effect & Safety is improved.
3, the present invention forms strong turbulence under the disturbance of spiral arm, and negative electrical charge and spout in gas can be made to spray Atomized drop is more sufficiently mixed.
4, desulfurization depositing dust generally speaking, is carried out come the exhaust gas to flue using desulfurization wastewater, desulfurization wastewater zero may be implemented Discharge and promote the removing of coal-fired flue-gas pollutant.
5, the present invention use Charged atomization technology, atomization droplets diameter more it is small more evenly, charged droplet more have attract it is tiny The high-efficient purification of flue gas may be implemented applied to Desulphurization for Coal-fired Power Plant tower for the characteristic of particle.
Detailed description of the invention
Fig. 1 view present invention utilizes the structural schematic diagram of desulfurization wastewater electrostatic charged spray flue gas processing device;
Fig. 2 is spiral gas-liquid two-fluid spray nozzle structure chart;
Fig. 3 is spiral gas-liquid two-fluid spray nozzle diversion pipe cross-sectional view;
In figure, 1, flue, 2, two-fluid spray nozzle, 3, negative high voltage electrostatic generator, 4, netted gully-hole, 5, dilution device, 6, desulfurization wastewater pond, 7, chimney, 8, liquid-inlet, 9, fluid chamber, 10, gas ionization chamber, 11, needle electrode, 12, insulated enclosure Mouthful, 13, gas feed, 14, shell, 15, ceramics pipe outer, 16, spout, 17, spiral arm, 18, electrostatic atomizer, 19, lead Flow tube.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, with reference to the accompanying drawings and embodiments, right The present invention is further elaborated.It should be appreciated that described herein, the specific embodiments are only for explaining the present invention, not For limiting the present invention.
As shown in Figure 1, a kind of Smoke pollutant treatment device based on electrostatic charged spray designed by the present invention, including electrostatic Spraying device 18, in use, electrostatic atomizer 18 are mounted in flue 1 close to the position of chimney 7, in electrostatic spray The inside of device 18 is equipped with two-fluid spray nozzle 2, electrode 3 and desulfurization wastewater recyclable device;Two-fluid spray nozzle 2 is positioned close to flue Entrance, the spout 16 of two-fluid spray nozzle 2 is towards at flue outlet, intracavitary to electrostatic atomizer 18 to be sprayed, electrostatic Mist device 18 is grounded.
The bottom of electrostatic atomizer 18 is arranged in waste water reclaiming device, by being provided with net in 18 bottom of electrostatic atomizer Shape gully-hole 4, netted gully-hole 4 connect desulfurization wastewater pond 6 by pipeline, realize the recycling to the desulfurization wastewater after work.
The structure of two-fluid spray nozzle 2 is as shown in Figure 2,3, passes through ceramics pipe outer 15 inside insulation shell 14 for its inner part It is divided into coaxially arranged fluid chamber 9 and gas ionization chamber 10, the fluid chamber 9 of 14 outer ring of shell is separately connected desulfurization by pipeline and gives up With dilution device 5, the desulfurization wastewater after dilution is also inputted into fluid chamber 9 for pond 6;The gas ionization chamber 10 of 14 inner ring of shell is logical It crosses gas feed 13 and connects gas pipeline, needle electrode 11 is equipped in gas ionization chamber 10, needle electrode 11 and negative high voltage are quiet The connection of 3 one end of electric generator, the other end of negative high voltage electrostatic generator 3 are connect with ground, and 11 corona discharge of needle electrode generates A large amount of positive charges, gas ionization chamber 10 is interior to generate charged air;Needle electrode 11 passes through insulation with gas ionization chamber 10 on one side Seal 12 is sealed, and the fluid chamber 9 of another side shell 14 connects spiral arm 17, and spiral arm 17 is the cored screw of gradual shrinkage Pipe, spiral arm 17 is overlapped with shell axis, and the desulfurization wastewater after dilution is from inside the entrance spiral arm 17 of fluid chamber 9, and from spiral It is sprayed at uniformly distributed spout 16 on the bottom surface of arm 17, the charged air generated in gas ionization chamber 10 at this time is among spiral arm 17 Channel in spray, the drop sprayed with spout 16 is combined, and the present invention is charged by charged air and droplets mixing, is avoided Liquid is in direct contact with the electrode, and improves the safety of operational process.The present invention is evenly equipped with 8 on the bottom surface of spiral arm 17 A diameter is the spout 16 of 0.5mm.
In the present embodiment, spiral arm 17 and insulated enclosure mouth are made of the polytetrafluoroethylene (PTFE) of insulation.
For the clearer technical solution explaining the present invention and being protected, make below in conjunction with the course of work of the invention into one Step is explained:
In the course of work of electrostatic atomizer 18, the dilution of desulfurization wastewater in desulfurization wastewater pond 6 in dilution device 5 Under effect, the desulfurization wastewater after dilution is inputted in fluid chamber 9 from liquid-inlet 8, while air enters gas from gas feed 13 Volume ionization chamber 10 generates a large amount of electrically charged gases under the action of needle electrode 11, and the desulfurization wastewater after dilution enters spiral Arm 17 from lower part spout 16 spray, electrically charged gas from the channel of the central axes of spiral arm 17 spray, electrically charged gas with The drop of ejection forms electrostatic spray after fully mixed, in electrostatic atomizer 18.
At this point, being come into full contact with into the flue gas in flue 1 with electrostatic spray, on the one hand, charged droplet can to flue gas into Row humidification, cool down it is quenched;On the other hand, after the mixing drop contact of the particulate matter in flue gas and desulfurization wastewater, particle is enhanced Between viscous force, Coulomb force, promote flue gas in dust particles reunion grow up, the efficiency of removing is improved, to realize Desulfurization wastewater be effectively treated and the coalescence of superfine particulate matter removing.
Above embodiments are merely to illustrate design philosophy and feature of the invention, and its object is to make technology in the art Personnel can understand the content of the present invention and implement it accordingly, and protection scope of the present invention is not limited to the above embodiments.So it is all according to It is within the scope of the present invention according to equivalent variations made by disclosed principle, mentality of designing or modification.

Claims (7)

1. a kind of Smoke pollutant treatment device based on electrostatic charged spray, which is characterized in that quiet on flue (1) including being arranged The input end of electrospray device (18), the electrostatic atomizer (18) connects flue (1), and outlet end connects chimney (7), quiet The internal entrance of electrospray device (18) is equipped with two-fluid spray nozzle (2), and the spout (16) of two-fluid spray nozzle (2) goes out towards flue At mouthful;The liquid-inlet (8) of the two-fluid spray nozzle (2) and gas feed (13) input desulfurization wastewater and air in electrostatic respectively The bottom of spraying device (18) is equipped with desulfurization wastewater recyclable device.
2. a kind of Smoke pollutant treatment device based on electrostatic charged spray according to claim 1, which is characterized in that described Two-fluid spray nozzle (2) includes shell (14) and spiral arm (17), is divided into fluid chamber (9) and gas ionization inside the shell (14) The arrival end of chamber (10), the fluid chamber (9) and gas ionization chamber (10) is separately connected desulfurization wastewater pond (6) and air, in gas Needle electrode (11) are equipped in volume ionization chamber (10), generate a large amount of positive charges for discharging;The outlet end of fluid chamber (9) connects spiral shell The entrance of spiral arm (17), the intermediate channel formed of the outlet face spiral arm (17) of gas ionization chamber (10), from spiral arm (17) The desulfurization wastewater that sprays of spout (16) and air through spraying among spiral arm (17) mix, in device bottom surface, netted collection is set Water hole (3) is to partial desulfurization cycling utilization of wastewater.
3. a kind of Smoke pollutant treatment device based on electrostatic charged spray according to claim 2, which is characterized in that described Fluid chamber (9) and gas ionization chamber (10) be it is internal coaxially arranged in shell (14) by ceramics pipe outer (15), inner ring is gas Volume ionization chamber (10), outer ring are fluid chamber (9).
4. a kind of Smoke pollutant treatment device based on electrostatic charged spray according to claim 2, which is characterized in that described The diameter of spout (16) is 0.5mm.
5. a kind of Smoke pollutant treatment device based on electrostatic charged spray according to claim 2, which is characterized in that described Desulfurization wastewater pond (6) is also in parallel with dilution device (5), inputs two-fluid spray nozzle (2) after being diluted to desulfurization wastewater.
6. a kind of Smoke pollutant treatment device based on electrostatic charged spray according to claim 1, which is characterized in that described Desulfurization wastewater recyclable device is to be provided with netted gully-hole (4) in electrostatic atomizer (18) bottom, and netted gully-hole (4) passes through pipe Road connects recycling of desulfurization wastewater pond (6) realization to the desulfurization wastewater after work.
7. a kind of Smoke pollutant treatment device based on electrostatic charged spray according to claim 2, which is characterized in that described Needle electrode (11) connects negative high voltage electrostatic generator (3).
CN201910540469.7A 2019-06-21 2019-06-21 A kind of Smoke pollutant treatment device based on electrostatic charged spray Pending CN110227317A (en)

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CN201910540469.7A CN110227317A (en) 2019-06-21 2019-06-21 A kind of Smoke pollutant treatment device based on electrostatic charged spray

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Application Number Priority Date Filing Date Title
CN201910540469.7A CN110227317A (en) 2019-06-21 2019-06-21 A kind of Smoke pollutant treatment device based on electrostatic charged spray

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104174279A (en) * 2014-08-12 2014-12-03 江苏大学 Bipolar corona discharge flue gas desulfurization and dust removal method and equipment
CN106167283A (en) * 2016-08-17 2016-11-30 西安交通大学 Desulphurization for Coal-fired Power Plant waste water flue spray evaporation zero discharge treatment device and method
CN108554662A (en) * 2018-06-29 2018-09-21 江苏大学 A kind of spiral gas-liquid double-fluid electrostatic atomization nozzle
CN210699296U (en) * 2019-06-21 2020-06-09 江苏大学 Flue gas pollutant processing apparatus based on lotus electric spray

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104174279A (en) * 2014-08-12 2014-12-03 江苏大学 Bipolar corona discharge flue gas desulfurization and dust removal method and equipment
CN106167283A (en) * 2016-08-17 2016-11-30 西安交通大学 Desulphurization for Coal-fired Power Plant waste water flue spray evaporation zero discharge treatment device and method
CN108554662A (en) * 2018-06-29 2018-09-21 江苏大学 A kind of spiral gas-liquid double-fluid electrostatic atomization nozzle
CN210699296U (en) * 2019-06-21 2020-06-09 江苏大学 Flue gas pollutant processing apparatus based on lotus electric spray

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