CN1102198A - Method for producing adhesion agent capable of adhering polypropylene film to paper printed matter - Google Patents
Method for producing adhesion agent capable of adhering polypropylene film to paper printed matter Download PDFInfo
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- CN1102198A CN1102198A CN 93118745 CN93118745A CN1102198A CN 1102198 A CN1102198 A CN 1102198A CN 93118745 CN93118745 CN 93118745 CN 93118745 A CN93118745 A CN 93118745A CN 1102198 A CN1102198 A CN 1102198A
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Abstract
The present invention relates to a water-based binding agent. It is made up by mainly using butadiene type rubber latex, ethylene-vinylacetate binary or ternary copolymer emulsion containing "introduced third monomer" (such as chloroethene or propenoic acid ester) and polyacrylic ester emulsion as main body binding materials, proportioning them to make their alloyed emulsion and adding a modifying ageng to make modification. As compared with organic solvent type binding agent, its contained "organic solvent quantity" is greatly reduced, so that it solves the problems that the organic solvent is inflammable, explosible and evaporable and harmful to human body and environment. Said product is a cream color colloidal solution, and mainly is used for sticking polypropylene film over the surface of paper-bound book, poster, full-page advertisement, front and back cover of picture album and paper packing box.
Description
The present invention relates to a kind of tackiness agent, especially polypropylene film is adhered to water-based adhesives on the paper printed matter for a kind of.
The bonding polypropylene film of paper printed matter surface is that the mid-80 printing industry is for improving a kind of new production technique (being commonly called as multiple film in printing industry) that the packaging class adopts.This new production technique is along with needs of society and development are popularized rapidly, thereby the demand of this new necessary tackiness agent of production technique also increases progressively rapidly year by year.But up to the present, employed tackiness agent still is the organic solvent type tackiness agent.Organic solvent in the tackiness agent is generally toluene, benzene, vinyl acetic monomer etc., account for more than 60% of tackiness agent total amount, the toxicity in various degree that a large amount of existence of these organic solvents and they are contained makes that tackiness agent is to produce all to exist safety and the healthy problem of worker inflammable, explosive, harm factory when also being to use.Simultaneously, organic solvent must almost all be evaporated again when answering film, and these organic solvents that are evaporated can't reclaim and can only discharge in atmosphere, has therefore seriously polluted environment again.
At present, both at home and abroad under the influence of policies such as environmental protection, safety, as primary solvent, water-based adhesives is safe in utilization owing to it with water, reduced infringement, alleviated the pollution of environment thereby become one of main developing direction of tackiness agent industry worker's health.Purpose of the present invention is exactly will prepare to reach the few water-based adhesives of containing of multiple membrane process requirement of organic solvent composition.In recent years, though both at home and abroad to polyacrylate dispersion, ethene-vinyl acetate binary copolymerization emulsion, preparation and application aspect water-based adhesives such as rubber-like emulsion have related to wide technical, but bonding with regard to paper printed matter and polypropylene film, the result that Shang Weiyou is satisfied.
Reach purpose of the present invention, what at first should consider is: the difference of paper printed matter surface all kinds paper, miscellaneous chemical substance in the various printing-inks, the different surface property complexity that typography caused, diverse characteristics; What consider then is to choose suitable adhesives.The present invention is after fully having studied the problems referred to above, by choosing butylbenzene class rubber latex and ethene-vinyl acetate binary or ethene-vinyl acetate-(introducing the 3rd monomer such as vinylchlorid, acrylate etc. again) ternary copolymer emulsion; Polyacrylate dispersion is the main body adhesives, and they are prepared blending emulsion by suitable mixed, is equipped with modifier modification again, promptly makes satisfactory tackiness agent.Because what the material of main part in the tackiness agent was selected for use is the emulsion type, thereby has reduced the usage quantity of organic solvent effectively.
The present invention be achieved in that (referring to: technological process of production figure)
1, the main body adhesives chooses and the proportioning and the preparation of blending emulsion
The main body adhesives is the main adhesive substance in the tackiness agent, consider the surface property of adhering object, the present invention has adopted: butylbenzene class rubber latex (styrene-butadiene latex or carboxylic styrene butadiene latex or butadiene styrene vinyl pyridine latex), ethene-vinyl acetate binary copolymerization emulsion or ethene-vinyl acetate-" introducing the 3rd monomer again " (vinylchlorid or acrylate) ternary copolymer emulsion, polyacrylate dispersion are as the main body adhesives.Prepare blending emulsion by the blend of main body adhesives.
The raw material of this blending emulsion, proportioning (weight percent): butylbenzene class rubber latex 10-95%, ethene-vinyl acetate binary copolymerization emulsion or ethene-vinyl acetate-" adding the 3rd monomer again " ternary copolymer emulsion 5～90%, polyacrylic acid fat liquor 0～50%, the solids content of these emulsions should be 40～55%.
Above-mentioned all emulsions at normal temperatures and pressures through mixing and stirring, promptly get blending emulsion by certain proportional quantity.
2, the selection of properties-correcting agent raw material and preparation thereof
Choose with material of main part excellent compatibility is arranged: tackifying resin (petroleum resin or alkyl phenolic resin (as: para-tert-butyl phenolic resin), or rosin and derivative (as: rosin thereof, staybelite, rosined soap) or polyterpene resin, organic solvent is generally selected solvent oil (as: 200# solvent oil) for use, aromatic organic solvent (as: toluene), softening agent adopts phthalic ester (as: dibutyl phthalate), organophosphate (as: phosphoric acid hexichol-monooctyl ester), tensio-active agent adopts anionic, nonionic surface active agent (as: Sodium dodecylbenzene sulfonate, nonyl phenyl Soxylat A 25-7), water.Material as properties-correcting agent.
The proportioning raw materials of this properties-correcting agent (weight percent): tackifying resin 15～60%, organic solvent 10～60%, softening agent 4～25%, tensio-active agent 4～30%; Water 0～35%.Tackifying resin adopts in all kinds of resin two or more composite preferable in use, and the proportional quantity in properties-correcting agent of the resin after it is composite still is 15～60%.
Tackify resin, organic solvent, softening agent, tensio-active agent and water are promptly got needed properties-correcting agent through mixing, fully stirring by certain proportional quantity under normal temperature, normal pressure.
Tackifying resin also can adopt the rosined soap in rosin and the derivative thereof a kind of, this condition, the composition of properties-correcting agent, proportioning (weight percent) are: rosined soap 45～75%, organic solvent 0～25%, water 5～35%, softening agent (as: dibutyl phthalate) 4～25%.
The solids content of used rosined soap should select 50% for use for good.Rosined soap has sale on the market, also can process voluntarily, can find on the processing mode adhesive applications handbook.When adopting rosined soap preparation properties-correcting agent, at normal temperatures and pressures, need rosined soap and softening agent (as: dibutyl phthalate mixes earlier), add water and organic solvent again, stir promptly and make, the performance of the properties-correcting agent that the properties-correcting agent that this method is made and other composition of above-mentioned employing are made and effect are close.
3, this tackiness agent mainly is made up of blending emulsion and properties-correcting agent, its proportional quantity (weight percent) is: blending emulsion 40～70%, and properties-correcting agent 30～60% is under normal temperature, normal pressure, need properties-correcting agent is joined in the blending emulsion, promptly make desired tackiness agent through stirring.
When further considering surface wettability, perviousness, the freeze thawing performance of its tackiness agent as need, when the preparation tackiness agent, also can add other auxiliary agent in right amount, because of belonging to general issues, the present invention no longer narrates.
Example 1: carboxylic styrene butadiene latex 3kg, ethene-vinyl acetate binary copolymerization emulsion 3kg, para-tert-butyl phenolic resin 1.0kg, rosin 0.8kg, 120# solvent oil 1.5kg, Sodium dodecylbenzene sulfonate 0.2kg, dibutyl phthalate 0.5kg.
Preparation technology:
(1) carboxylic styrene butadiene latex is mixed with ethene-vinyl acetate binary copolymerization emulsion, the back that stirs is standby.
(2) with para-tert-butyl phenolic resin and rosin fat, dissolve in the people 120# solvent oil, wait to dissolve complete back and add dibutyl phthalate, and Sodium dodecylbenzene sulfonate stirs.
(3) (2) being added (1) stirs and gets final product.
Example 2: carboxylic styrene butadiene latex 3kg,
Ethene-vinyl acetate binary copolymerization emulsion 2kg,
Polyacrylate dispersion 1kg,
Petroleum resin 1kg,
Rosin 0.5kg,
120# solvent oil 0.5kg,
Toluene 1kg,
Dibutyl phthalate 0.4kg,
Witco 1298 Soft Acid 0.6kg.
Preparation technology is the same
Example 3: carboxylic styrene butadiene latex 4kg,
Ethene-vinyl acetate-acrylic ester ternary polymerization emulsion 2kg,
Rosined soap (solids content 50%) 3kg,
Dibutyl phthalate 0.6kg,
Water 0.4kg
Preparation technology:
(1) carboxylic styrene butadiene latex is mixed with ethene-vinyl acetate-acrylate terpolymer, the back that stirs is standby.
(2) rosined soap is mixed with dibutyl phthalate, add entry again and stir standby.
(3) (1) is mixed with (2), stirring gets final product.
With regard to embodiment 1, embodiment 2 contained organic solvents 15%, compare with the organic solvent type tackiness agent, organic solvent content greatly reduces, it only is 1/4 of organic solvent type tackiness agent, and embodiment 3 does not contain any organic solvent, they can not burn evidence, what deserves to be mentioned is, tackiness agent in use, adjust the viscosity of tackiness agent according to the situation of paper and printing ink, the organic solvent type tackiness agent must re-use organic solvent and regulate, this just makes the usage quantity of organic solvent further increase, and gets final product and tackiness agent of the present invention uses general tap water to regulate.With regard to this point, not only can further reduce the usage quantity of organic solvent, and can reduce use cost.
In sum, tackiness agent of the present invention has solved the inflammable and explosive and safety problem brought of product effectively, and has alleviated the infringement to worker health greatly, and to the pollution level of environment.And can satisfy the requirement of membrane process again.This tackiness agent is the oyster white colloid, its main application is that paper printed matter (as: book cover, Picture album with advertisements front cover, daily paper pack surface) surface is bonded together through paper-plastic lamination machine and polypropylene film transparent, attractive in appearance, thereby plays the purpose that improves printed matter or its connection with wrapping of piece appearance decoration class, attractive in appearance and durable degree.In addition, this tackiness agent also can be used for kraft paper and Polywoven Bag are bonded together to prepare the bonding of complex cement packing bag and various paper and polyolefin plastics and plastics.
Bibliography:
1, adhesive technology and application manual in December, 1991
The tissue compiling of the bonding association in Beijing is edited nineteen ninety 3 editions HANOBOOK OF ADHESIVES that Van Nostrand Reinhold company publishes from American I ring Skeist.
2, fine chemistry industry handbook in the world's is sequeled in May, 1986
Institute of scientific-technical information of Ministry of Chemical Industry edits and publishes.
3, letex polymerization in June, 1991
Chemical Industry Press, author: Hutchinson, Paul C., Cao Tongyu, Liu Qingpu
4, adhesive applications handbook in November, 1987
The Wang Meng of Chemical Industry Press clock, Huang Yingchang chief editor
5, the practical publication and printing work handbook in January, 1992
The Luo Shu of Printing industry press treasured etc. is write
6, paper coating in May, 1987
The king of light industry press ten thousand seas, talk Yongnian, Lv Fuyin translates
Beautiful D.T. Harper work
Claims (4)
1, a kind of polypropylene film is adhered to the tackiness agent on the paper printed matter, it is characterized in that: this tackiness agent is made of blending emulsion, properties-correcting agent two portions, and the raw material of its all composition, proportioning (weight percent) are:
(1) blending emulsion by: butylbenzene class rubber latex 10～95%, ethene-vinyl acetate binary copolymerization emulsion or ethene-vinyl acetate-" introducing the 3rd monomer " ternary copolymer emulsion 5～90%, polyacrylate dispersion 0～50% are formed,
(2) properties-correcting agent is by tackifying resin 15～60%, organic solvent 0～60%, and softening agent 4～25%, tensio-active agent 4～30% and water 0～35% are formed.
2, according to the described tackiness agent of claim 1, it is characterized in that said: butylbenzene class rubber latex means: styrene-butadiene latex or carboxylic styrene butadiene latex or butadiene styrene vinyl pyridine latex; " introducing the 3rd monomer " means: vinylchlorid or acrylate; Tackifying resin means: petroleum resin or alkyl phenolic resin (as para-tert-butyl phenolic resin) or rosin and derivative or polyterpene resin; Softening agent adopts phthalic acid fat, organic phosphoric acid lipid (as dibutyl phthalate (DBP), phosphoric acid hexichol-monooctyl ester etc.); Tensio-active agent adopts anionic, nonionic surface active agent (as: Sodium dodecylbenzene sulfonate, nonyl phenyl Soxylat A 25-7 etc.); Organic solvent can adopt: solvent oil (as: 200# solvent oil), aromatic organic solvent (as toluene).
The solids content of all emulsions in the blending emulsion should be 40～55%; Tackifying resin adopts in all kinds of resin two or more composite preferable in use, and the proportional quantity in properties-correcting agent of the resin after it is composite still is 15～60%;
3, according to the described tackiness agent of claim 1, it is characterized in that said: " tackifying resin " also can adopt the rosined soap in rosin and the derivative thereof a kind of, and the composition of this condition properties-correcting agent, proportioning (weight percent) are: rosined soap 45～75%; Water 5～35%, organic solvent 0～25%, softening agent (as: dibutyl phthalate) 4～25%.
4, according to claim: 1, the production method of 3 described tackiness agents is characterized in that: all compositions of blending emulsion, all compositions of properties-correcting agent respectively under normal temperature, normal pressure mixing and stirring promptly make; When the tackifying resin in the properties-correcting agent adopts rosined soap, need rosined soap is mixed earlier with softening agent (as dibutyl phthalate), add entry and organic solvent again, stir promptly and make; Under normal temperature, normal pressure, properties-correcting agent (30～60%) is joined in the blending emulsion (40～70%), promptly make desired tackiness agent through stirring.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN93118745A CN1053916C (en) | 1993-10-26 | 1993-10-26 | Method for producing adhesion agent capable of adhering polypropylene film to paper printed matter |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN93118745A CN1053916C (en) | 1993-10-26 | 1993-10-26 | Method for producing adhesion agent capable of adhering polypropylene film to paper printed matter |
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| Publication Number | Publication Date |
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| CN1102198A true CN1102198A (en) | 1995-05-03 |
| CN1053916C CN1053916C (en) | 2000-06-28 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN93118745A Expired - Fee Related CN1053916C (en) | 1993-10-26 | 1993-10-26 | Method for producing adhesion agent capable of adhering polypropylene film to paper printed matter |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100343357C (en) * | 2002-12-27 | 2007-10-17 | 米其林研究和技术股份有限公司 | Adhesive composition for the direct joining of a pre-gelled polyester or vinyl ester to raw rubber |
| CN101376796B (en) * | 2008-09-08 | 2010-09-08 | 河北华夏实业有限公司 | Aqueous bottom glue for soft polychloroethylene contact adhesive tape and manufacturing method thereof |
| CN101376729B (en) * | 2007-08-27 | 2011-04-06 | 王致平 | Liquid curing elastic protective film and manufacturing method thereof |
| CN101058704B (en) * | 2007-05-29 | 2011-06-22 | 林润强 | Multifunctional aqueous adhesive and preparation method thereof |
| CN105315930A (en) * | 2014-06-11 | 2016-02-10 | 中国石油化工股份有限公司 | Styrene-type thermoplastic elastomer laminating adhesive emulsion and preparation method thereof |
| CN109703223A (en) * | 2018-12-17 | 2019-05-03 | 广东鑫瑞新材料科技有限公司 | A kind of production method of local positioning transfer paper and the transfer paper being prepared |
| CN112745783A (en) * | 2021-01-08 | 2021-05-04 | 上海佳衡胶粘制品有限公司 | Weather-resistant adhesive tape and preparation method thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5341167B2 (en) * | 1971-09-11 | 1978-10-31 |
-
1993
- 1993-10-26 CN CN93118745A patent/CN1053916C/en not_active Expired - Fee Related
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100343357C (en) * | 2002-12-27 | 2007-10-17 | 米其林研究和技术股份有限公司 | Adhesive composition for the direct joining of a pre-gelled polyester or vinyl ester to raw rubber |
| CN101058704B (en) * | 2007-05-29 | 2011-06-22 | 林润强 | Multifunctional aqueous adhesive and preparation method thereof |
| CN101376729B (en) * | 2007-08-27 | 2011-04-06 | 王致平 | Liquid curing elastic protective film and manufacturing method thereof |
| CN101376796B (en) * | 2008-09-08 | 2010-09-08 | 河北华夏实业有限公司 | Aqueous bottom glue for soft polychloroethylene contact adhesive tape and manufacturing method thereof |
| CN105315930A (en) * | 2014-06-11 | 2016-02-10 | 中国石油化工股份有限公司 | Styrene-type thermoplastic elastomer laminating adhesive emulsion and preparation method thereof |
| CN105315930B (en) * | 2014-06-11 | 2018-08-24 | 中国石油化工股份有限公司 | A kind of styrene analog thermoplastic elastomer laminating adhesive latex solution and preparation method thereof |
| CN109703223A (en) * | 2018-12-17 | 2019-05-03 | 广东鑫瑞新材料科技有限公司 | A kind of production method of local positioning transfer paper and the transfer paper being prepared |
| CN112745783A (en) * | 2021-01-08 | 2021-05-04 | 上海佳衡胶粘制品有限公司 | Weather-resistant adhesive tape and preparation method thereof |
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|---|---|
| CN1053916C (en) | 2000-06-28 |
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