CN110219170A - A kind of preparation method of automobile negative oxygen ion mask - Google Patents
A kind of preparation method of automobile negative oxygen ion mask Download PDFInfo
- Publication number
- CN110219170A CN110219170A CN201910374271.6A CN201910374271A CN110219170A CN 110219170 A CN110219170 A CN 110219170A CN 201910374271 A CN201910374271 A CN 201910374271A CN 110219170 A CN110219170 A CN 110219170A
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- China
- Prior art keywords
- oxygen ion
- negative oxygen
- preparation
- automobile
- powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000001301 oxygen Substances 0.000 title claims abstract description 92
- 229910052760 oxygen Inorganic materials 0.000 title claims abstract description 92
- 238000002360 preparation method Methods 0.000 title claims abstract description 31
- 239000000463 material Substances 0.000 claims abstract description 64
- 239000000843 powder Substances 0.000 claims abstract description 33
- 239000010985 leather Substances 0.000 claims abstract description 22
- 229920001410 Microfiber Polymers 0.000 claims abstract description 16
- 239000003658 microfiber Substances 0.000 claims abstract description 16
- 229920003023 plastic Polymers 0.000 claims abstract description 14
- 239000004033 plastic Substances 0.000 claims abstract description 14
- 239000002131 composite material Substances 0.000 claims abstract description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 5
- -1 oxygen ion Chemical class 0.000 claims description 91
- 239000004800 polyvinyl chloride Substances 0.000 claims description 24
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 24
- 238000000034 method Methods 0.000 claims description 18
- 239000004814 polyurethane Substances 0.000 claims description 18
- 239000000835 fiber Substances 0.000 claims description 12
- 229920002635 polyurethane Polymers 0.000 claims description 12
- 239000000839 emulsion Substances 0.000 claims description 9
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 7
- 150000001412 amines Chemical class 0.000 claims description 6
- 239000003054 catalyst Substances 0.000 claims description 6
- 239000012948 isocyanate Substances 0.000 claims description 6
- 150000002513 isocyanates Chemical class 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 239000003921 oil Substances 0.000 claims description 6
- 229920000570 polyether Polymers 0.000 claims description 6
- 229920005862 polyol Polymers 0.000 claims description 6
- 150000003077 polyols Chemical class 0.000 claims description 6
- 238000012545 processing Methods 0.000 claims description 6
- 239000002994 raw material Substances 0.000 claims description 6
- 239000003381 stabilizer Substances 0.000 claims description 6
- 102000004190 Enzymes Human genes 0.000 claims description 5
- 108090000790 Enzymes Proteins 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 238000000576 coating method Methods 0.000 claims description 4
- 239000003086 colorant Substances 0.000 claims description 4
- 150000004702 methyl esters Chemical class 0.000 claims description 4
- 230000008569 process Effects 0.000 claims description 4
- 239000004575 stone Substances 0.000 claims description 4
- 150000005846 sugar alcohols Polymers 0.000 claims description 4
- QEOSCXACXNFJCY-AKHDSKFASA-N (2R,3R,4S,5R)-6-benzyl-7-phenylheptane-1,2,3,4,5,6-hexol Chemical compound C(C1=CC=CC=C1)C(O)([C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO)CC1=CC=CC=C1 QEOSCXACXNFJCY-AKHDSKFASA-N 0.000 claims description 3
- 239000004593 Epoxy Substances 0.000 claims description 3
- 229920000426 Microplastic Polymers 0.000 claims description 3
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 125000001931 aliphatic group Chemical group 0.000 claims description 3
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 claims description 3
- AGXUVMPSUKZYDT-UHFFFAOYSA-L barium(2+);octadecanoate Chemical compound [Ba+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O AGXUVMPSUKZYDT-UHFFFAOYSA-L 0.000 claims description 3
- 229920000402 bisphenol A polycarbonate polymer Polymers 0.000 claims description 3
- 239000006227 byproduct Substances 0.000 claims description 3
- HBGGXOJOCNVPFY-UHFFFAOYSA-N diisononyl phthalate Chemical class CC(C)CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC(C)C HBGGXOJOCNVPFY-UHFFFAOYSA-N 0.000 claims description 3
- 229940008099 dimethicone Drugs 0.000 claims description 3
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 3
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 3
- XWVQUJDBOICHGH-UHFFFAOYSA-N dioctyl nonanedioate Chemical compound CCCCCCCCOC(=O)CCCCCCCC(=O)OCCCCCCCC XWVQUJDBOICHGH-UHFFFAOYSA-N 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 239000000945 filler Substances 0.000 claims description 3
- 239000003063 flame retardant Substances 0.000 claims description 3
- 239000004088 foaming agent Substances 0.000 claims description 3
- 150000002334 glycols Chemical class 0.000 claims description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 3
- SEQVSYFEKVIYCP-UHFFFAOYSA-L magnesium hypophosphite Chemical compound [Mg+2].[O-]P=O.[O-]P=O SEQVSYFEKVIYCP-UHFFFAOYSA-L 0.000 claims description 3
- 229910001381 magnesium hypophosphite Inorganic materials 0.000 claims description 3
- 235000012054 meals Nutrition 0.000 claims description 3
- 239000011707 mineral Substances 0.000 claims description 3
- 239000004745 nonwoven fabric Substances 0.000 claims description 3
- 239000000049 pigment Substances 0.000 claims description 3
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 3
- 239000004417 polycarbonate Substances 0.000 claims description 3
- 229920005906 polyester polyol Polymers 0.000 claims description 3
- 229920001228 polyisocyanate Polymers 0.000 claims description 3
- 239000005056 polyisocyanate Substances 0.000 claims description 3
- 229920006389 polyphenyl polymer Polymers 0.000 claims description 3
- 229920003225 polyurethane elastomer Polymers 0.000 claims description 3
- 238000012805 post-processing Methods 0.000 claims description 3
- 239000000047 product Substances 0.000 claims description 3
- 238000000746 purification Methods 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- 239000011435 rock Substances 0.000 claims description 3
- 229920002545 silicone oil Polymers 0.000 claims description 3
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 claims description 3
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 3
- 238000005507 spraying Methods 0.000 claims description 3
- 238000004381 surface treatment Methods 0.000 claims description 3
- 239000012970 tertiary amine catalyst Substances 0.000 claims description 3
- 239000012974 tin catalyst Substances 0.000 claims description 3
- 229910052613 tourmaline Inorganic materials 0.000 claims description 3
- 239000011032 tourmaline Substances 0.000 claims description 3
- 229940070527 tourmaline Drugs 0.000 claims description 3
- TUUQISRYLMFKOG-UHFFFAOYSA-N trihexyl 2-acetyloxypropane-1,2,3-tricarboxylate Chemical compound CCCCCCOC(=O)CC(C(=O)OCCCCCC)(OC(C)=O)CC(=O)OCCCCCC TUUQISRYLMFKOG-UHFFFAOYSA-N 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- XAEWLETZEZXLHR-UHFFFAOYSA-N zinc;dioxido(dioxo)molybdenum Chemical compound [Zn+2].[O-][Mo]([O-])(=O)=O XAEWLETZEZXLHR-UHFFFAOYSA-N 0.000 claims description 3
- 150000001335 aliphatic alkanes Chemical class 0.000 claims 1
- JSIRWKUDLWXOJO-UHFFFAOYSA-N dioctyltin;dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O.CCCCCCCC[Sn]CCCCCCCC JSIRWKUDLWXOJO-UHFFFAOYSA-N 0.000 claims 1
- 229920006380 polyphenylene oxide Polymers 0.000 claims 1
- 229920003002 synthetic resin Polymers 0.000 claims 1
- 239000000057 synthetic resin Substances 0.000 claims 1
- QQTGFPSIUPIFGW-UHFFFAOYSA-N trimethylsilylmethylphosphonic acid Chemical compound C[Si](C)(C)CP(O)(O)=O QQTGFPSIUPIFGW-UHFFFAOYSA-N 0.000 claims 1
- 238000005034 decoration Methods 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 3
- 230000036541 health Effects 0.000 abstract description 3
- 230000002526 effect on cardiovascular system Effects 0.000 abstract description 2
- 210000002345 respiratory system Anatomy 0.000 abstract description 2
- 241000196324 Embryophyta Species 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- DBLXXVQTWJFJFI-UHFFFAOYSA-N 1-phenyloctadecan-1-one Chemical compound CCCCCCCCCCCCCCCCCC(=O)C1=CC=CC=C1 DBLXXVQTWJFJFI-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 2
- XQBCVRSTVUHIGH-UHFFFAOYSA-L [dodecanoyloxy(dioctyl)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCCCCCC)(CCCCCCCC)OC(=O)CCCCCCCCCCC XQBCVRSTVUHIGH-UHFFFAOYSA-L 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000012975 dibutyltin dilaurate Substances 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000011022 opal Substances 0.000 description 2
- 229920013636 polyphenyl ether polymer Polymers 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 241000195493 Cryptophyta Species 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 238000004887 air purification Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000037452 priming Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60R—VEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
- B60R13/00—Elements for body-finishing, identifying, or decorating; Arrangements or adaptations for advertising purposes
- B60R13/02—Internal Trim mouldings ; Internal Ledges; Wall liners for passenger compartments; Roof liners
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/49—Oxides or hydroxides of elements of Groups 8, 9,10 or 18 of the Periodic Table; Ferrates; Cobaltates; Nickelates; Ruthenates; Osmates; Rhodates; Iridates; Palladates; Platinates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/76—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon oxides or carbonates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/80—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with boron or compounds thereof, e.g. borides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
- D06M15/568—Reaction products of isocyanates with polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
- D06M16/003—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic with enzymes or microorganisms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2265—Oxides; Hydroxides of metals of iron
- C08K2003/2272—Ferric oxide (Fe2O3)
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/38—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- Microbiology (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Vehicle Interior And Exterior Ornaments, Soundproofing, And Insulation (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
Abstract
The invention belongs to automobile interior decoration field, specifically a kind of preparation method of automobile negative oxygen ion mask.The preparation method is that negative oxygen ion powder is added in facing material；The facing material is any one in micro fiber leather or PVC composite material or functional plastics or PU material.The present invention can be effectively improved interior VOC and air quality.Applicable position is more, has extraordinary application value.The present invention can produce 2500 every square centimeter or more negative oxygen ion concentrations, be purified automobile indoor air, is conducive to the health for improving cardiovascular and cerebrovascular, respiratory tract of occupant etc., crew module is made to have the effect of mobile oxygen bar.
Description
Technical field
The invention belongs to automobile interior decoration field, specifically a kind of preparation method of automobile negative oxygen ion mask.
Background technique
With economic growth and social progress, passenger car consumer also more payes attention to in-car air quality.Negative oxygen from
Son, also referred to as negative aeroion (Aeroanion) can have preferably driver and passenger to the feeling of people's spirit and QI cleaning
Health-care effect, while negative oxygen ion has absorption, aggregation and sedimentation to act on suspended particulate in air, at present negative oxygen ion
Using also limiting to very much, have no it in the related application of automobile interior decoration mask.
Summary of the invention
The present invention provides a kind of preparation method of automobile negative oxygen ion mask, and the negative oxygen ion mask of preparation can be made negative
Oxonium ion health cockpit has filled up the blank that negative oxygen ion is not used in existing automobile to meet the higher vehicle demand of consumer.
Technical solution of the present invention is described with reference to the drawings as follows:
A kind of preparation method of automobile negative oxygen ion mask, the preparation method are that negative oxygen ion powder is added to mask material
In material；The facing material is any one in micro fiber leather or PVC composite material or functional plastics or PU material.
The negative oxygen ion powder is that the plant enzyme powder or natural nano generating material by crushing purification processes are
One or more of six ring stone of natural minerals, the light rock powder of opal, nano-tourmaline powder, partial size 50nm-2000nm.
When the facing material is micro fiber leather, negative oxygen ion mask specific the preparation method is as follows:
Step 1: micro fiber leather is by the small fiber number i.e. three dimensional entanglement non-woven fabrics of 0.1D-0.6D fiber and polyurethane elastomer
Based on prepare, base layer is made of PA6 superfine fibre；
Step 2: marine organism extract is made to 100-500 nanometers of nanoscale negative oxygen ion powder, and is added to
In PA6 superfine fibre, percentage is no more than 10%；
Step 3: take 70 parts of dioctyl azelates, 12 parts of polytetramethylene glycols, 5 parts of polyphenyl polymethylene polyisocyanates mixed
Conjunction obtains mixed liquor, is added in 6 parts of step 2 nanometer grade powder is made thereto, by them after mixing evenly in 50 degrees Celsius of items
It is mixed 3 hours under part；
Step 4: taking 100 parts of polyether polyol again, 1 part of stabilizer, 1 part of amines catalyst, that is, tertiary amine catalyst, and 0.6 part
They are uniformly mixed to obtain prepolymer by dibutyl tin dilaurate；
Step 5: acquisition mixed emulsion is sufficiently stirred in step 3 and step 4 products therefrom, obtains negative oxygen ion function
The aqueous polyurethane emulsion of change；By aqueous polyurethane emulsion after the spraying of micro fiber leather surface, used at 100-120 DEG C, drying
Pressure roller carries out roll-in, platen pressure 300kg/m2；
Step 6: by product in step 5 after post treatment and surface treatment to get negative oxygen ion function micro fiber leather
Mask.
When the facing material is PVC composite material, negative oxygen ion mask specific the preparation method is as follows:
Step 1: the used raw material for preparing has polyvinyl chloride resin, epoxy aliphatic acid methyl ester, bisphenol A polycarbonate, polyphenyl
Ether, Bis(lauroyloxy)dioctyltin, zinc molybdate, magnesium hypophosphite, barium stearate, aluminium-magnesium silicate, sodium tripolyphosphate, stearoyl benzene first
Acyl methane, dioctyl azelate, Dipentaerythritol Ester, hydrogenated diisononyl phthalate, trimethylsilyl methylphosphine
Dimethyl phthalate, acetyl trihexyl citrate, modified conch meal, white oil, dimethicone, dibenzyl sorbitol, pigment and
Toner；
Step 2: being added to negative oxygen ion powder in PVC composite material, wherein the mass percent 1- of negative oxygen ion powder
20%, by processing and post-processing, obtain the PVC functional material of releasable negative oxygen ion；
Step 3: negative-oxygen ionization, the oxygen wherein control technique is negative are carried out using the double-deck coating processes to existing PVC leather
Diameter, additional amount and the adding manner of ionic material, are added total mass ratio 0.3%-21%, and uniformly mixed PVC material is passed through
Post-process and be surface-treated the PVC leather material up to negative oxygen ion function.
When the facing material is functional plastics, negative oxygen ion mask specific the preparation method is as follows:
Step 1: raw materials used is plastic granule, that is, PP, ABS, PET, POM, PC, one or more of PBT, synthesis tree
Rouge, negative oxygen ion material, mass percent 1-20%, silane coupling agent, white oil, filler, colorant, surface treating agent；
Step 2: the interior trim plastics of different parts are made using different technique；Specific method is according to for automobile interiors
Depending on part processing criterion；
Step 3: being added a certain amount of negative oxygen ion powder in forming process, and mass ratio 0.1%-20% is made
The functional plastics of negative-oxygen ionization.
When the facing material is PU material, negative oxygen ion mask specific the preparation method is as follows:
Step 1: the functional polyurethane material that automobile contains negative oxygen ion be by a certain amount of negative oxygen ion material, it is more
First alcohol includes the pure and mild polyester polyol of polyether polyols, stabilizer, foaming agent, amines catalyst, tin catalyst, water, silicone oil,
The mixture of fire retardant, isocyanates, that is, TDI, MDI, PAPI, one or more of HDI is prepared；
Step 2: the negative oxygen ion material that ratio is 0.1%-20% is uniformly mixed with isocyanates；
Step 3: mixture in step 2 is added in the polyalcohol bottom material mixed, and premix is sufficiently stirred；
Step 4: foam-in-mould is carried out at 150 DEG C -220 DEG C, the porous functional polyurethane containing negative oxygen ion is made
Material.
A kind of automobile negative oxygen ion mask is made according to any of the above-described kind of method.
The invention has the benefit that
1, the invention proposes specific automobile interior decoration mask negative-oxygen ionization scheme, interior VOC and sky can be effectively improved
Makings amount.Applicable position is more, has extraordinary application value.
2, the present invention can produce 2500 every square centimeter or more negative oxygen ion concentrations, obtain automobile indoor air
Purification is conducive to the health for improving cardiovascular and cerebrovascular, respiratory tract of occupant etc., crew module is made to have the effect of mobile oxygen bar.
3, a variety of facing materials of in-car decorations prepared by the present invention can build more healthy, more environmentally-friendly low smell
Whole driving environment.
Detailed description of the invention
Fig. 1 is plant enzyme powder；
Fig. 2 is natural nano generating material.
Specific embodiment
A kind of preparation method of automobile negative oxygen ion mask, the preparation method are that negative oxygen ion powder is added to mask material
In material；The facing material is any one in micro fiber leather or PVC composite material or functional plastics or PU material.
The negative oxygen ion powder is that the plant enzyme powder or natural nano generating material by crushing purification processes are
One or more of six ring stone of natural minerals, the light rock powder of opal, nano-tourmaline powder, partial size 50nm-2000nm.
When the facing material is micro fiber leather, negative oxygen ion mask specific the preparation method is as follows:
Step 1: micro fiber leather is by the small fiber number i.e. three dimensional entanglement non-woven fabrics of 0.1D-0.6D fiber and polyurethane elastomer
Based on prepare, base layer is made of PA6 superfine fibre；
Step 2: marine organisms (the plant enzyme powder extracted from marine algae) extract is made 100-500 and received
The nanoscale negative oxygen ion powder of rice, and be added in PA6 superfine fibre, percentage is no more than 10%；
Step 3: take 70 parts of dioctyl azelates, 12 parts of polytetramethylene glycols, 5 parts of polyphenyl polymethylene polyisocyanates mixed
Conjunction obtains mixed liquor, is added in 6 parts of step 2 nanometer grade powder is made thereto, by them after mixing evenly in 50 degrees Celsius of items
It is mixed 3 hours under part；
Step 4: taking 100 parts of polyether polyol again, 1 part of stabilizer, 1 part of amines catalyst, that is, tertiary amine catalyst, and 0.6 part
They are uniformly mixed to obtain prepolymer by dibutyl tin dilaurate；
Step 5: acquisition mixed emulsion is sufficiently stirred in step 3 and step 4 products therefrom, obtains negative oxygen ion function
The aqueous polyurethane emulsion of change；By aqueous polyurethane emulsion after the spraying of micro fiber leather surface, used at 100-120 DEG C, drying
Pressure roller carries out roll-in, platen pressure 300kg/m2；
Step 6: by product in step 5 after post treatment and surface treatment to get negative oxygen ion function micro fiber leather
Mask.
When the facing material is PVC composite material, negative oxygen ion mask specific the preparation method is as follows:
Step 1: the used raw material for preparing has polyvinyl chloride resin, epoxy aliphatic acid methyl ester, bisphenol A polycarbonate, polyphenyl
Ether, Bis(lauroyloxy)dioctyltin, zinc molybdate, magnesium hypophosphite, barium stearate, aluminium-magnesium silicate, sodium tripolyphosphate, stearoyl benzene first
Acyl methane, dioctyl azelate, Dipentaerythritol Ester, hydrogenated diisononyl phthalate, trimethylsilyl methylphosphine
Dimethyl phthalate, acetyl trihexyl citrate, modified conch meal, white oil, dimethicone, dibenzyl sorbitol, pigment and
Toner；
Step 2: being added to negative oxygen ion powder in PVC composite material, wherein the mass percent 1- of negative oxygen ion powder
20%, by processing and post-processing, obtain the PVC functional material of releasable negative oxygen ion；
Step 3: carrying out negative-oxygen ionization using double-deck coating processes, that is, priming coat, top coating to existing PVC leather,
Middle control technique is diameter, additional amount and the adding manner of negative oxygen ion material, and total mass ratio 0.3%-21% is added, and mixing is equal
Even PVC material is after post treatment and the PVC leather material that is surface-treated up to negative oxygen ion function.
When the facing material is functional plastics, negative oxygen ion mask specific the preparation method is as follows:
Step 1: raw materials used is plastic granule, that is, PP, ABS, PET, POM, PC, one or more of PBT, synthesis tree
Rouge, negative oxygen ion material, mass percent 1-20%, silane coupling agent, white oil, filler, colorant, surface treating agent；
Step 2: the interior trim plastics of different parts are made using different technique；Specific method is according to for automobile interiors
Depending on part processing criterion, the including but not limited to different work such as molding, injection molding, plastic uptake, hot pressing, mixing, pultrusion, membrane formation process
Skill；
Step 3: being added a certain amount of negative oxygen ion powder in forming process, and mass ratio 0.1%-20% is made
The functional plastics of negative-oxygen ionization.
When the facing material is PU material, negative oxygen ion mask specific the preparation method is as follows:
Step 1: the functional polyurethane material that automobile contains negative oxygen ion be by a certain amount of negative oxygen ion material, it is more
First alcohol includes the pure and mild polyester polyol of polyether polyols, stabilizer, foaming agent, amines catalyst, tin catalyst, water, silicone oil,
The mixture of fire retardant, isocyanates, that is, TDI, MDI, PAPI, one or more of HDI is prepared；
Step 2: the negative oxygen ion material that ratio is 0.1%-20% is uniformly mixed with isocyanates；
Step 3: mixture in step 2 is added in the polyalcohol bottom material mixed, and premix is sufficiently stirred；
Step 4: foam-in-mould is carried out at 150 DEG C -220 DEG C, the porous functional polyurethane containing negative oxygen ion is made
Material.
A kind of automobile negative oxygen ion mask is made according to any of the above-described kind of method.
Claims (7)
1. a kind of preparation method of automobile negative oxygen ion mask, which is characterized in that the preparation method is to add negative oxygen ion powder
Enter into facing material；The facing material is any in micro fiber leather or PVC composite material or functional plastics or PU material
It is a kind of.
2. a kind of preparation method of automobile negative oxygen ion mask according to claim 1, which is characterized in that described is negative
Oxonium ion powder is six ring stone of plant enzyme powder or natural nano generating material, that is, natural minerals, the egg by crushing purification processes
One or more of the light rock powder of white stone, nano-tourmaline powder, partial size 50nm-2000nm.
3. a kind of preparation method of automobile negative oxygen ion mask according to claim 1, which is characterized in that when described
When facing material is micro fiber leather, negative oxygen ion mask specific the preparation method is as follows:
Step 1: it is base that micro fiber leather, which is by the small fiber number i.e. three dimensional entanglement non-woven fabrics of 0.1D-0.6D fiber and polyurethane elastomer,
Plinth preparation, base layer is made of PA6 superfine fibre；
Marine organism extract: being made 100-500 nanometers of nanoscale negative oxygen ion powder by step 2, and it is super to be added to PA6
In fine fibre, percentage is no more than 10%；
Step 3: 70 parts of dioctyl azelates, 12 parts of polytetramethylene glycols, 5 parts of polyphenyl polymethylene polyisocyanates are taken to mix
To mixed liquor, it is added in 6 parts of step 2 nanometer grade powder is made thereto, by them after mixing evenly under 50 degrees celsius
Mixing 3 hours；
Step 4: 100 parts of polyether polyol, 1 part of stabilizer, 1 part of amines catalyst, that is, tertiary amine catalyst, 0.6 part of February are taken again
They are uniformly mixed to obtain prepolymer by dilaurylate；
Step 5: acquisition mixed emulsion is sufficiently stirred in step 3 and step 4 products therefrom, obtains negative oxygen ion function
Aqueous polyurethane emulsion；By aqueous polyurethane emulsion after the spraying of micro fiber leather surface, pressure roller is used at 100-120 DEG C, drying
Carry out roll-in, platen pressure 300kg/m2；
Step 6: by product in step 5 after post treatment and surface treatment to get negative oxygen ion function micro fiber leather mask.
4. a kind of preparation method of automobile negative oxygen ion mask according to claim 1, which is characterized in that when described
When facing material is PVC composite material, negative oxygen ion mask specific the preparation method is as follows:
Step 1: the used raw material for preparing has polyvinyl chloride resin, epoxy aliphatic acid methyl ester, bisphenol A polycarbonate, polyphenylene oxide, and two
Lauric acid dioctyltin, zinc molybdate, magnesium hypophosphite, barium stearate, aluminium-magnesium silicate, sodium tripolyphosphate, stearoyl benzoyl first
Alkane, dioctyl azelate, Dipentaerythritol Ester, hydrogenated diisononyl phthalate, trimethylsilyl methylphosphonic acid two
Methyl esters, acetyl trihexyl citrate, modified conch meal, white oil, dimethicone, dibenzyl sorbitol, pigment and colorant；
Step 2: being added to negative oxygen ion powder in PVC composite material, wherein the mass percent 1- of negative oxygen ion powder
20%, by processing and post-processing, obtain the PVC functional material of releasable negative oxygen ion；
Step 3: negative-oxygen ionization is carried out using the double-deck coating processes to existing PVC leather, wherein control technique is negative oxygen ion
Diameter, additional amount and the adding manner of material, are added total mass ratio 0.3%-21%, and uniformly mixed PVC material warp is located later
Manage and be surface-treated the PVC leather material up to negative oxygen ion function.
5. a kind of preparation method of automobile negative oxygen ion mask according to claim 1, which is characterized in that when described
When facing material is functional plastics, negative oxygen ion mask specific the preparation method is as follows:
Step 1: it is raw materials used be plastic granule, that is, PP, ABS, PET, POM, PC, one or more of PBT, synthetic resin,
Negative oxygen ion material, mass percent 1-20%, silane coupling agent, white oil, filler, colorant, surface treating agent；
Step 2: the interior trim plastics of different parts are made using different technique；Specific method is according to part for automobile interiors
Depending on processing criterion；
Step 3: being added a certain amount of negative oxygen ion powder in forming process, and negative oxygen is made in mass ratio 0.1%-20%
The functional plastics of ionization.
6. a kind of preparation method of automobile negative oxygen ion mask according to claim 1, which is characterized in that when described
When facing material is PU material, negative oxygen ion mask specific the preparation method is as follows:
Step 1: the functional polyurethane material that automobile contains negative oxygen ion is by a certain amount of negative oxygen ion material, polyalcohol
It include the pure and mild polyester polyol of polyether polyols, stabilizer, foaming agent, amines catalyst, tin catalyst, water, silicone oil is fire-retardant
The mixture of agent, isocyanates, that is, TDI, MDI, PAPI, one or more of HDI is prepared；
Step 2: the negative oxygen ion material that ratio is 0.1%-20% is uniformly mixed with isocyanates；
Step 3: mixture in step 2 is added in the polyalcohol bottom material mixed, and premix is sufficiently stirred；
Step 4: foam-in-mould is carried out at 150 DEG C -220 DEG C, the porous functional polyurethane material containing negative oxygen ion is made.
7. a kind of automobile negative oxygen ion mask, which is characterized in that be made according to any method of claim 1-6.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112878061A (en) * | 2021-01-11 | 2021-06-01 | 中国第一汽车股份有限公司 | Negative oxygen ion PVC (polyvinyl chloride) protective surface for automobile seat and preparation method thereof |
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| CN1827662A (en) * | 2005-03-02 | 2006-09-06 | 李青山 | Technology for preparing foaming elastic materials with negative ion release function |
| CN105696360A (en) * | 2016-04-29 | 2016-06-22 | 储著国 | PVC artificial leather capable of efficiently releasing negative ions and preparation method thereof |
| CN109367492A (en) * | 2018-10-17 | 2019-02-22 | 中国第汽车股份有限公司 | A kind of automobile cabin of releasing negative oxygen ion |
| CN109403055A (en) * | 2018-09-29 | 2019-03-01 | 中国第汽车股份有限公司 | The preparation method of automotive seat negative oxygen ion corium mask and micro fiber leather mask |
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2019
- 2019-05-07 CN CN201910374271.6A patent/CN110219170A/en active Pending
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1827662A (en) * | 2005-03-02 | 2006-09-06 | 李青山 | Technology for preparing foaming elastic materials with negative ion release function |
| CN105696360A (en) * | 2016-04-29 | 2016-06-22 | 储著国 | PVC artificial leather capable of efficiently releasing negative ions and preparation method thereof |
| CN109403055A (en) * | 2018-09-29 | 2019-03-01 | 中国第汽车股份有限公司 | The preparation method of automotive seat negative oxygen ion corium mask and micro fiber leather mask |
| CN109367492A (en) * | 2018-10-17 | 2019-02-22 | 中国第汽车股份有限公司 | A kind of automobile cabin of releasing negative oxygen ion |
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| CN112878061A (en) * | 2021-01-11 | 2021-06-01 | 中国第一汽车股份有限公司 | Negative oxygen ion PVC (polyvinyl chloride) protective surface for automobile seat and preparation method thereof |
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Application publication date: 20190910 |