CN110218006B - Laminated glass for vehicle - Google Patents
Laminated glass for vehicle Download PDFInfo
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- CN110218006B CN110218006B CN201910338409.7A CN201910338409A CN110218006B CN 110218006 B CN110218006 B CN 110218006B CN 201910338409 A CN201910338409 A CN 201910338409A CN 110218006 B CN110218006 B CN 110218006B
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60J—WINDOWS, WINDSCREENS, NON-FIXED ROOFS, DOORS, OR SIMILAR DEVICES FOR VEHICLES; REMOVABLE EXTERNAL PROTECTIVE COVERINGS SPECIALLY ADAPTED FOR VEHICLES
- B60J1/00—Windows; Windscreens; Accessories therefor
- B60J1/02—Windows; Windscreens; Accessories therefor arranged at the vehicle front, e.g. structure of the glazing, mounting of the glazing
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/3411—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C27/00—Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing
- C03C27/06—Joining glass to glass by processes other than fusing
- C03C27/10—Joining glass to glass by processes other than fusing with the aid of adhesive specially adapted for that purpose
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/15—Deposition methods from the vapour phase
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- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Mechanical Engineering (AREA)
- Joining Of Glass To Other Materials (AREA)
- Laminated Bodies (AREA)
Abstract
The invention relates to the field of glass products, in particular to a window glass installed on a vehicle, and particularly provides a laminated glass for a vehicle, which can be matched with a laser radar or a near infrared camera for use. The laminated glass comprises an outer transparent plate, an inner transparent plate, a thermoplastic membrane and a nano antireflection film, wherein the nano antireflection film comprises a first high-refractive-index layer, a first low-refractive-index layer, a second high-refractive-index layer, a second low-refractive-index layer, a third high-refractive-index layer, a third low-refractive-index layer, a fourth high-refractive-index layer and a fourth low-refractive-index layer which are deposited in sequence. The laminated glass can meet the requirement that the energy loss of near infrared light of a laser or near infrared camera of a laser radar is less than 20% when the near infrared light penetrates through the laminated glass, can greatly reduce the signal energy loss of the laser radar or the near infrared camera during working, does not need to greatly improve the power of the laser radar or the near infrared camera, and can improve the use accuracy of the laser radar or the near infrared camera.
Description
The technical field is as follows:
the invention relates to the field of glass products, in particular to a window glass installed on a vehicle, and particularly provides a laminated glass for a vehicle, which can be matched with a laser radar or a near infrared camera for use.
Background art:
in order to meet the requirement of Advanced Driving Assistance System (ADAS), various sensors are usually equipped on the automobile, such as cameras, ultrasonic sensors, millimeter wave radar, etc., some of which may be near infrared cameras with a wavelength of 940 nm; similarly, in order to meet the requirement of automatic driving, each automatic driving automobile is also equipped with a laser radar, and the laser wavelength of the commonly used laser radar is about 905 nm. The existing laser radar and partial near infrared camera are installed outside the automobile, which requires that they can resist strong wind, salt fog, ultraviolet aging, and adapt to cold and hot environments, etc., so as to ensure normal operation in severe environments, thereby greatly increasing installation cost and maintenance cost.
In order to reduce the installation and maintenance costs of the lidar and the partial near-infrared camera, it is conceivable to install them in the interior of the vehicle, for example, on the inside of the front windshield of the vehicle, the laser of the lidar or the near-infrared light of the near-infrared camera operating through the front windshield. As is well known, most of near-infrared light with the wavelength of 780-1200 nm can be isolated by traditional laminated glass serving as front windshield glass, so that the penetration of laser of a laser radar or the near-infrared light of a near-infrared camera is blocked, and the normal work of the laser radar and the near-infrared camera in a vehicle is influenced.
In the prior art, in order to solve the problem of isolating the laser of a laser radar or the near infrared light of a near infrared camera by the traditional laminated glass, patent CN101037099A discloses a device and a method for installing an infrared camera with an outward visual angle in a vehicle, wherein an embedded part with a near infrared transmission part and a far infrared transmission part is installed in a notch or a hole of a windshield, a first camera receives the near infrared light through the near infrared part, and a second camera receives the far infrared light through the far infrared part; also patent CN101678651A discloses a laminated vehicle glazing suitable for use with an optical sensor, such as a LIDAR type sensor, comprising first and second plies of glazing material joined together by a ply of interlayer material therebetween, the first ply of glazing material being a pane of body-tinted glazing having a transmission of at least 30% over the wavelength range of 400 to 2100nm, the glazing having a transmission of at least 32% over the wavelength range of 750 to 1300nm, the glazing in this solution having a transmission of no more than 50% up to the wavelength range of 750 to 1300nm and still being of no practical use for laser radars and near infrared cameras.
The invention content is as follows:
the invention aims to solve the technical problem that the laminated glass in the prior art cannot be used with a laser radar or a near-infrared camera, and provides the laminated glass for the vehicle.
The technical scheme adopted by the invention for solving the technical problems is as follows: a laminated glass for a vehicle, a laser radar and/or a near infrared camera are installed in the vehicle, the laminated glass comprises an outer transparent plate, an inner transparent plate and a thermoplastic membrane sandwiched between the outer transparent plate and the inner transparent plate, the outer transparent plate is provided with a first surface and a second surface, the inner transparent plate is provided with a third surface and a fourth surface, and a nano antireflection film is arranged on the first surface and/or the fourth surface;
the outer transparent plate has at least 85% of transmittance within the wavelength range of 900-1000 nm;
the inner transparent plate has at least 90% of transmittance within the wavelength range of 900-1000 nm;
the nano antireflection film comprises a first high-refractive-index layer, a first low-refractive-index layer, a second high-refractive-index layer, a second low-refractive-index layer, a third high-refractive-index layer, a third low-refractive-index layer, a fourth high-refractive-index layer and a fourth low-refractive-index layer which are sequentially deposited from the outer transparent plate or the inner transparent plate to the outside;
the thickness of the first high refractive index layer is 10-100 nm, and the thickness of the first low refractive index layer is 90-200 nm;
the thickness of the second high refractive index layer is 20-130 nm, and the thickness of the second low refractive index layer is 110-200 nm;
the thickness of the third high refractive index layer is 10-80 nm, and the thickness of the third low refractive index layer is 130-210 nm;
the thickness of the fourth high refractive index layer is 5-40 nm, and the thickness of the fourth low refractive index layer is 10-90 nm.
Preferably, the thickness of the first high refractive index layer is 10-50 nm, and the thickness of the first low refractive index layer is 130-180 nm;
the thickness of the second high refractive index layer is 25-70 nm, and the thickness of the second low refractive index layer is 150-190 nm;
the thickness of the third high refractive index layer is 30-60 nm, and the thickness of the third low refractive index layer is 150-200 nm;
the thickness of the fourth high refractive index layer is 5-30 nm, and the thickness of the fourth low refractive index layer is 10-45 nm.
Preferably, the materials of the first high refractive index layer, the third high refractive index layer and the fourth high refractive index layer are selected from ZnSe, TiO2、ZnS、Ta2O5、Ti3O5At least one of (1).
Preferably, the material of the second high refractive index layer is selected from ZrO2、HfO2、Ta2O5And Si3N4At least one of (1).
Preferably, the materials of the first low refractive index layer, the second low refractive index layer, the third low refractive index layer and the fourth low refractive index layer are selected from MgF2、SiO2、Al2O3、MgO、AlF3、YbF3、YF3At least one of (1).
Preferably, the refractive index of the high refractive index layer is 1.7-2.7, and the refractive index of the low refractive index layer is 1.3-2.0.
More preferably, the refractive index of the high refractive index layer is 2.0 to 2.7, and the refractive index of the low refractive index layer is 1.3 to 1.7.
Preferably, the thermoplastic membrane has at least 90% of transmittance and no more than 10% of absorptivity in the wavelength range of 900-1000 nm.
Preferably, the thickness of the outer transparent plate is less than or equal to 2.1mm, the thickness of the inner transparent plate is less than or equal to 2.0mm, and the thickness of the inner transparent plate is less than or equal to the thickness of the outer transparent plate.
Preferably, at least one of the outer transparent plate and the inner transparent plate is made of ultra-white glass, a PC plate, a PVC plate, a PE plate or a PMMA plate.
Due to the adoption of the technical scheme, the invention has the following beneficial effects:
the laminated glass for the vehicle has the transmissivity of at least 80% within the wavelength range of 900-1000 nm, can be used in cooperation with a laser radar and/or a near-infrared camera arranged in the vehicle, greatly improves the capability of a signal with the wavelength of 900-1000 nm of the laser radar or the near-infrared camera to penetrate through the laminated glass, further meets the requirement that the energy loss of the laser radar or the near-infrared camera to penetrate through the laminated glass is less than 20%, can greatly reduce the signal energy loss of the laser radar or the near-infrared camera during working, does not need to greatly improve the power of the laser radar or the near-infrared camera, and can improve the use accuracy of the laser radar or the near-infrared camera.
Description of the drawings:
fig. 1 is a schematic structural view of a laminated glass for a vehicle according to the present invention;
FIG. 2 is a schematic view of a nano antireflection film according to the present invention;
the specific implementation mode is as follows:
the invention will be further explained with reference to the accompanying drawings.
As shown in fig. 1, the laminated glass for a vehicle according to the present invention can be used in combination with a laser radar and/or a near-infrared camera installed in the interior of the vehicle, and includes an outer transparent plate 1, an inner transparent plate 2, and a thermoplastic membrane 3 sandwiched between the outer transparent plate 1 and the inner transparent plate 2, wherein the outer transparent plate 1 is located outside the vehicle, the outer transparent plate 1 has a first surface 11 and a second surface 12, the first surface 11 is located away from the thermoplastic membrane 3, the second surface 12 is located close to the thermoplastic membrane 3, the inner transparent plate 2 is located inside the vehicle, the inner transparent plate 2 has a third surface 21 and a fourth surface 22, the third surface 21 is located close to the thermoplastic membrane 3, and the fourth surface 22 is located away from the thermoplastic membrane 3. Specifically, the laser radar and/or the near-infrared camera may be installed behind the laminated glass, or even on the fourth surface 22, a signal of the laser radar or the near-infrared camera may penetrate through the laminated glass, and in order to enable the laminated glass to meet the working requirements of the laser radar and the near-infrared camera, a nano antireflection film 4 is provided on the first surface 11 and/or the fourth surface 22, the nano antireflection film 4 is used to increase the transmittance of the laminated glass in the wavelength range of 900 to 1000nm, and an outer transparent plate 1 having a transmittance of at least 85% in the wavelength range of 900 to 1000nm and an inner transparent plate 2 having a transmittance of at least 90% in the wavelength range of 900 to 1000nm are also selected, so that the laminated glass has a transmittance of at least 80% in the wavelength range of 900 to 1000nm, thereby enabling the laminated glass to have a wavelength around 905nm of the laser radar and a wavelength around 940nm of the near-infrared camera The wavelength that has the transmissivity of at least 80% has on the right side, has promoted by a wide margin laser radar or near-infrared camera's wavelength is 900 ~ 1000 nm's signal permeation sandwich glass's ability, and then satisfies laser radar's laser or near-infrared camera's near infrared light permeates the requirement that energy loss when sandwich glass is less than 20%, need not to improve laser radar or near-infrared camera's power by a wide margin, guarantees laser radar or near-infrared camera's normal work, can also improve laser radar or near-infrared camera's use precision.
In fig. 1, the nano antireflection film 4 is disposed on the fourth surface 22, but may also be disposed on the first surface 11 as needed, or may even be disposed on both the first surface 11 and the fourth surface 22.
In order to make the effect of combining the nano antireflection film 4 with the outer transparent plate 1 and the inner transparent plate 2 better, the outer transparent plate 1 preferably has an absorptivity of not higher than 10% in a wavelength range of 900-1000 nm, and the inner transparent plate 2 preferably has an absorptivity of not higher than 3% in a wavelength range of 900-1000 nm; specifically, at least one of the outer transparent plate 1 and the inner transparent plate 2 is made of ultra-white glass, a PC plate, a PVC plate, a PE plate, or a PMMA plate. Meanwhile, it is also preferable that the thickness of the outer transparent plate 1 is less than or equal to 2.1mm, the thickness of the inner transparent plate 2 is less than or equal to 2.0mm, and the thickness of the inner transparent plate 2 is less than or equal to the thickness of the outer transparent plate 1.
In order to make the laminated glass better satisfy the requirement of having at least 80% transmittance in the wavelength range of 900-1000 nm, the invention preferably selects the thermoplastic film 3 having at least 90% transmittance and no more than 10% absorptivity in the wavelength range of 900-1000 nm, such as polyvinyl butyral (PVB) or ionic interlayer film (SGP).
As shown in FIG. 2, the nano antireflection film 4 of the present invention includes a laminated structure of four high refractive index layers/low refractive index layers, the refractive index of the high refractive index layers is 1.7 to 2.7, and the nano antireflection film 4 includes a structure of four high refractive index layers/low refractive index layersThe refractive index of the low-refractive-index layer is 1.3-2.0, and the nanometer antireflection film 4 arranged on the outer transparent plate 1 or the inner transparent plate 2 can reduce the reflectivity of the outer transparent plate 1 or the inner transparent plate 2 within the wavelength range of 900-1000 nm, so that the transmissivity within the wavelength range of 900-1000 nm is improved, and the laminated glass can be better matched with the normal work of a laser radar or a near-infrared camera. It can be understood that the nano antireflection film 4 of the present invention may also include a stacked structure of two, three, or even five high refractive index layers/low refractive index layers, so as to more specifically reduce the reflectivity of different outer transparent plates 1 or inner transparent plates 2 in the wavelength range of 900 to 1000 nm. In the invention, the refractive index of the high refractive index layer is preferably 2.0-2.7, and the refractive index of the low refractive index layer is preferably 1.3-1.7; meanwhile, the material of the high-refractive-index layer is also preferably selected from ZnSe and TiO2、ZnS、Ta2O5、Ti3O5、ZrO2、HfO2And Si3N4At least one of, the material of the low refractive index layer is selected from MgF2、SiO2、Al2O3、MgO、AlF3、YbF3、YF3At least one of (1).
In fig. 2, the nano antireflection film 4 specifically includes a first high refractive index layer 41, a first low refractive index layer 42, a second high refractive index layer 43, a second low refractive index layer 44, a third high refractive index layer 45, a third low refractive index layer 46, a fourth high refractive index layer 47, and a fourth low refractive index layer 48, which are deposited in this order from the inner transparent plate 2; wherein the thickness of the first high refractive index layer 41 is 10 to 100nm, and the thickness of the first low refractive index layer 42 is 90 to 200 nm; the thickness of the second high refractive index layer 43 is 20 to 130nm, and the thickness of the second low refractive index layer 44 is 110 to 200 nm; the thickness of the third high refractive index layer 45 is 10-80 nm, and the thickness of the third low refractive index layer 46 is 130-210 nm; the thickness of the fourth high refractive index layer 47 is 5-40 nm, and the thickness of the fourth low refractive index layer 48 is 10-90 nm; the thickness of each layer is designed so that the reflectivity of the outer transparent plate 1 or the inner transparent plate 2 within the wavelength range of 900-1000 nm can be better reduced by the nano antireflection film 4; preferably, the thickness of the first high refractive index layer is 10-50 nm, and the thickness of the first low refractive index layer is 130-180 nm; the thickness of the second high refractive index layer is 25-70 nm, and the thickness of the second low refractive index layer is 150-190 nm; the thickness of the third high refractive index layer is 30-60 nm, and the thickness of the third low refractive index layer is 150-200 nm; the thickness of the fourth high refractive index layer is 5-30 nm, and the thickness of the fourth low refractive index layer is 10-45 nm.
Specifically, the materials of the first high refractive index layer, the third high refractive index layer and the fourth high refractive index layer are selected from ZnSe and TiO2、ZnS、Ta2O5、Ti3O5At least one of, and the material of the second high refractive index layer is selected from ZrO2、HfO2、Ta2O5And Si3N4At least one of the first low refractive index layer, the second low refractive index layer, the third low refractive index layer and the fourth low refractive index layer is made of a material selected from MgF2、SiO2、Al2O3、MgO、AlF3、YbF3、YF3At least one of (1).
Examples
In order to illustrate and more persuasively support the inventive aspects of the present invention in more detail, some examples are now set forth in detail. The laminated glass prepared in the following embodiment is subjected to relevant parameter analysis by the following scheme:
transmittance: and analyzing the transmission spectrum of the sandwich glass by using Agilent spectrophotometer equipment, and taking the transmittance (T @905nm) corresponding to the wavelength of 905nm as an evaluation index.
Comparative example 1 and example 1
Comparative example 1: two pieces of soda-lime-silicate float white glass with the thickness of 1.6mm are used as substrates, the white glass substrates have the transmittance of 85.94% and the absorption rate of 7.14% within the wavelength range of 900-1000 nm, the substrates are subjected to cutting, edge grinding, washing, drying and other processes, then sheet preparation is carried out, the substrates are molded according to the high-temperature molding process of automobile glass, a PVB membrane with the thickness of 0.76mm is clamped in the middle of the substrates, and the laminated glass of the comparative example 1 is manufactured through the initial pressing and high-pressure processes of sheet combination and accessories of other processes, and is the existing common automobile laminated glass.
Example 1: the laminated glass of example 1 is manufactured by using soda-lime-silicate float white glass with a thickness of 1.6mm as a substrate, wherein the white glass substrate has a transmittance of 85.94% and an absorption rate of 7.14% within a wavelength range of 900-1000 nm, the substrate is subjected to film coating deposition after cutting, edge grinding, washing, drying and other processes, a nano antireflection film in the table 1 is deposited on the white glass substrate, another white glass substrate and the white glass substrate deposited with the nano antireflection film are taken for sheet matching, the white glass substrate and the white glass substrate are formed according to an automobile glass high-temperature forming process, a PVB film with a thickness of 0.76mm is sandwiched in the middle of the white glass substrate, and accessories of the sheet matching, the high-pressure process and other processes are mounted.
Table 1: laminated glass structures of example 1 and comparative example 1 and their transmission
As can be seen from Table 1, the maximum transmittance of the conventional common automobile laminated glass at the wavelength of 905nm is only 79.91%, and when the laser radar and the near-infrared camera are used in combination with the conventional common automobile laminated glass, the signal energy loss is more than 20%, so that the working requirements of the laser radar and the near-infrared camera cannot be met; in the embodiment 1, after the nano antireflection film is added, the transmittance of the laminated glass at the wavelength of 905nm is improved to 82.12%, the signal energy loss is less than 20%, and the working requirements of a laser radar and a near-infrared camera can be met.
Comparative example 2 and examples 2 to 5
Comparative example 2: the laminated glass of the comparative example 2 is manufactured by using soda-lime-silicate float white glass with the thickness of 1.8mm and ultra-white glass with the thickness of 1.1mm as substrates, wherein the white glass substrate with the thickness of 1.8mm has 85.27% of transmittance and 7.77% of absorptivity within the wavelength range of 900-1000 nm, the ultra-white glass with the thickness of 1.1mm has 91.24% of transmittance and 1.19% of absorptivity within the wavelength range of 900-1000 nm, the substrates are subjected to cutting, edge grinding, washing, drying and other processes, then are prepared into sheets, are molded according to the high-temperature molding process of automobile glass, a PVB film with the thickness of 0.76mm is sandwiched in the middle of the sheets, and are mounted through the initial pressing of sheet combination, the high-pressure process and other processes.
Examples 2 to 5: the laminated glass of the embodiments 2 to 5 is manufactured by using soda-lime-silicate float white glass with the thickness of 1.8mm and ultra-white glass with the thickness of 1.1mm as substrates, wherein the white glass substrate with the thickness of 1.8mm has 85.27% of transmittance and 7.77% of absorptivity within the wavelength range of 900-1000 nm, the ultra-white glass with the thickness of 1.1mm has 91.24% of transmittance and 1.19% of absorptivity within the wavelength range of 900-1000 nm, the substrates are subjected to film coating deposition after cutting, edge grinding, washing, drying and other processes, a nano antireflection film in the table 2 is deposited on the ultra-white glass with the thickness of 1.1mm, the ultra-white glass with the thickness of 1.1mm and the white glass substrate with the thickness of 1.8mm are subjected to sheet matching after the deposition, the high-temperature forming process of the automobile glass is carried out, a PVB film with the thickness of 0.76mm is sandwiched in the middle, and the accessories of the initial pressing and high-pressure process and other processes are.
Table 2: laminated glass structures and properties of examples 2-5 and comparative example 2
As can be seen from table 2, the transmittance of the laminated glass of comparative example 2 at the wavelength of 905nm can reach 83.21%, but in examples 2 to 5, after the nano antireflection film having the laminated structure of 2 to 4 high refractive index layers/low refractive index layers is added, the transmittance of the laminated glass at the wavelength of 905nm is increased to more than 85%, so that the signal energy loss of the laser radar or the near-infrared camera during operation can be greatly reduced, the power of the laser radar or the near-infrared camera does not need to be greatly increased, and the use accuracy of the laser radar or the near-infrared camera can be improved.
The above description specifically describes a laminated glass for a vehicle according to the present invention, but the present invention is not limited to the above description, and therefore, any improvements, equivalent modifications, substitutions and the like according to the technical gist of the present invention are within the scope of the present invention.
Claims (10)
1. A laminated glass for a vehicle having a lidar and/or a near-infrared camera mounted inside the vehicle, the laminated glass comprising an outer transparent plate, an inner transparent plate, and a thermoplastic membrane sandwiched between the outer transparent plate and the inner transparent plate, the outer transparent plate having a first surface and a second surface, the first surface being distal from the thermoplastic membrane, the second surface being proximal to the thermoplastic membrane, the inner transparent plate having a third surface and a fourth surface, the third surface being proximal to the thermoplastic membrane, the fourth surface being distal from the thermoplastic membrane, a nano antireflection film being provided on the first surface and/or the fourth surface;
the outer transparent plate has at least 85% of transmittance within the wavelength range of 900-1000 nm;
the inner transparent plate has at least 90% of transmittance within the wavelength range of 900-1000 nm;
the nano antireflection film comprises a first high-refractive-index layer, a first low-refractive-index layer, a second high-refractive-index layer, a second low-refractive-index layer, a third high-refractive-index layer, a third low-refractive-index layer, a fourth high-refractive-index layer and a fourth low-refractive-index layer which are sequentially deposited from the outer transparent plate or the inner transparent plate to the outside;
the thickness of the first high refractive index layer is 10-100 nm, and the thickness of the first low refractive index layer is 90-200 nm;
the thickness of the second high refractive index layer is 20-130 nm, and the thickness of the second low refractive index layer is 110-200 nm;
the thickness of the third high refractive index layer is 10-80 nm, and the thickness of the third low refractive index layer is 130-210 nm;
the thickness of the fourth high refractive index layer is 5-40 nm, and the thickness of the fourth low refractive index layer is 10-90 nm;
the laminated glass has at least 80% of transmittance to signals with the wavelength of 900-1000 nm of the laser radar and/or the near-infrared camera.
2. The laminated glass for a vehicle according to claim 1, characterized in that:
the thickness of the first high refractive index layer is 10-50 nm, and the thickness of the first low refractive index layer is 130-180 nm;
the thickness of the second high refractive index layer is 25-70 nm, and the thickness of the second low refractive index layer is 150-190 nm;
the thickness of the third high refractive index layer is 30-60 nm, and the thickness of the third low refractive index layer is 150-200 nm;
the thickness of the fourth high refractive index layer is 5-30 nm, and the thickness of the fourth low refractive index layer is 10-45 nm.
3. The laminated glass for a vehicle according to claim 1, characterized in that: the materials of the first high refractive index layer, the third high refractive index layer and the fourth high refractive index layer are selected from ZnSe and TiO2、ZnS、Ta2O5、Ti3O5At least one of (1).
4. The laminated glass for a vehicle according to claim 1, characterized in that: the material of the second high refractive index layer is selected from ZrO2、HfO2、Ta2O5And Si3N4At least one of (1).
5. The laminated glass for a vehicle according to claim 1, characterized in that: the materials of the first low refractive index layer, the second low refractive index layer, the third low refractive index layer and the fourth low refractive index layer are selected from MgF2、SiO2、Al2O3、MgO、AlF3、YbF3、YF3At least one of (1).
6. The laminated glass for a vehicle according to claim 1, characterized in that: the refractive index of the high refractive index layer is 1.7-2.7, and the refractive index of the low refractive index layer is 1.3-2.0.
7. The laminated glass for a vehicle according to claim 6, characterized in that: the refractive index of the high refractive index layer is 2.0-2.7, and the refractive index of the low refractive index layer is 1.3-1.7.
8. The laminated glass for a vehicle according to claim 1, characterized in that: the thermoplastic film has at least 90% of transmittance and no more than 10% of absorptivity within the wavelength range of 900-1000 nm.
9. The laminated glass for a vehicle according to claim 1, characterized in that: the thickness of the outer transparent plate is less than or equal to 2.1mm, the thickness of the inner transparent plate is less than or equal to 2.0mm, and the thickness of the inner transparent plate is less than or equal to the thickness of the outer transparent plate.
10. The laminated glass for a vehicle according to claim 1, characterized in that: at least one of the outer transparent plate and the inner transparent plate is made of ultra-white glass, a PC plate, a PVC plate, a PE plate or a PMMA plate.
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| CN201910338409.7A CN110218006B (en) | 2019-04-25 | 2019-04-25 | Laminated glass for vehicle |
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| CN110218006B true CN110218006B (en) | 2020-08-11 |
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| CN112526478A (en) * | 2019-11-22 | 2021-03-19 | 宁波舜宇车载光学技术有限公司 | Composite protection device and manufacturing method thereof, outer cover and laser radar device |
| FR3105944B1 (en) * | 2020-01-03 | 2023-11-24 | Saint Gobain | DEVICE WITH GLASS AND ASSOCIATED THERMAL CAMERA AND OPTIMIZATION PROCESSES |
| US20240302573A1 (en) | 2021-07-20 | 2024-09-12 | Agc Glass Europe | Ir transmissive pane |
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| CN115144945B (en) * | 2022-06-22 | 2024-05-14 | 长春理工大学 | Cosmetic mirror filter film with chromaticity adjusting function and cosmetic mirror |
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| CN115519853B (en) * | 2022-10-14 | 2024-01-23 | 福耀玻璃工业集团股份有限公司 | Vehicle window glass, preparation method thereof and vehicle |
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| CN117092726B (en) * | 2023-08-30 | 2024-02-13 | 有研国晶辉新材料有限公司 | Optical element and preparation method thereof |
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| JP2003043202A (en) * | 2001-07-31 | 2003-02-13 | Olympus Optical Co Ltd | Antireflection film and optical parts |
| JP2018058738A (en) * | 2016-10-07 | 2018-04-12 | 旭硝子株式会社 | Cover glass for display device and electronic apparatus |
| JP6881172B2 (en) * | 2017-09-13 | 2021-06-02 | Ａｇｃ株式会社 | Transparent substrate with antireflection film and display device using it |
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