CN110204847A - Fibre modification alloy material - Google Patents
Fibre modification alloy material Download PDFInfo
- Publication number
- CN110204847A CN110204847A CN201910454015.8A CN201910454015A CN110204847A CN 110204847 A CN110204847 A CN 110204847A CN 201910454015 A CN201910454015 A CN 201910454015A CN 110204847 A CN110204847 A CN 110204847A
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- CN
- China
- Prior art keywords
- parts
- flyash
- alloy material
- industrial residue
- fibre
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08L27/18—Homopolymers or copolymers or tetrafluoroethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/005—Additives being defined by their particle size in general
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The embodiment of the invention discloses fibre modification alloy material, the component including following parts by weight: 25-30 parts of industrial residue, 30-40 parts of flyash, 20-30 parts of polytetrafluoroethylene (PTFE), 15-20 parts of glass fibre, 10-15 parts of carbon fiber, 3-6 parts of silane coupling agent, 3-5 parts of toughener, 2-5 parts of polyester fiber.Industrial residue and flyash production fibre modification material is utilized, can be realized the recycling and reusing of industrial residue and flyash, and the improvement alloy material produced has the advantage that modified fibre diameter 200-300nm again, draw ratio is 15 or more；Loading is big in the polymer for industrial residue and flyash, can reach 50 or more；Raw material cost is low, and materials are easy, and has very high cost performance；Stability is good, has good resistance to compression, anti-bending strength, has anti-chemical corrosivity；This alloy material is had excellent performance, complete green material, can be used in preparing floor, dalle, Furniture panel, door and window etc..
Description
Technical field
The present embodiments relate to technical field of material modification, and in particular to fibre modification alloy material.
Background technique
With the development of science and technology, the requirement to fibrous material performance is higher and higher, there is method for modifying fibers for mentioning
The properties of high microsteping alloy.Make chemical fibre prepared by fibre modification with chemically or physically method.By physical modification
Fiber have profiled filament, textured fibre and composite fibre.Chemically modified fiber have graft fibres, copolymer fibre and
Fiber etc. through chemical processing denaturation.
The solid waste such as solid slag, flyash, if cannot timely handle, heap carrys out not only land occupation,
And ambient enviroment can be polluted.
Therefore, how the solid waste such as solid slag, flyash are handled, makes its fibre modification at alloy material
Material obtains the material that can be used in producing floor, dalle, Furniture panel, door and window etc., is that those skilled in the art urgently solve
Certainly the technical issues of.
Summary of the invention
For this purpose, the embodiment of the present invention provides fibre modification alloy material, to solve in the prior art due to caused by
Problem.
To achieve the goals above, the embodiment of the present invention provides the following technical solutions:
According to embodiments of the present invention, a kind of fibre modification alloy material is provided, the component including following parts by weight: industry
25-30 parts of waste residue, 30-40 parts of flyash, 20-30 parts of polytetrafluoroethylene (PTFE), 15-20 parts of glass fibre, 10-15 parts of carbon fiber, silicon
3-6 parts of alkane coupling agent, 3-5 parts of toughener, 2-5 parts of polyester fiber.
Further, industrial residue 27-30 parts, 35-40 parts of flyash, 20-25 parts of polytetrafluoroethylene (PTFE), glass fibre 16-
18 parts, 10-12 parts of carbon fiber, 3-4 parts of silane coupling agent, 3-5 parts of toughener, 2-5 parts of polyester fiber.
Further, 30 parts of industrial residue, 36 parts of flyash, 23 parts of polytetrafluoroethylene (PTFE), 16 parts of glass fibre, carbon fiber 12
Part, 4 parts of silane coupling agent, 5 parts of toughener, 5 parts of polyester fiber.
Further, the toughener is carboxylic acrylonitrile butadiene rubber latex or polyvinyl alcohol.
Further, the granularity of the industrial residue is 700-800 mesh.
Further, the granularity of the flyash is 1000-1200 mesh.
The embodiment of the present invention has the advantages that
Industrial residue and flyash production fibre modification material is utilized, can be realized the recycling of industrial residue and flyash
It recycles, and the improvement alloy material produced has the advantage that
1, modified fibre diameter 200-300nm again, draw ratio is 15 or more；
2, loading is big in the polymer for industrial residue and flyash, can reach 50 or more；
3, raw material cost is low, and materials are easy, and has very high cost performance；
4, stability is good, has good resistance to compression, anti-bending strength, has anti-chemical corrosivity；
5, this alloy material is had excellent performance, complete green material, can be used in preparing floor, dalle, furniture
Plate, door and window etc..
Specific embodiment
Embodiments of the present invention are illustrated by particular specific embodiment below, those skilled in the art can be by this explanation
Content disclosed by book is understood other advantages and efficacy of the present invention easily, it is clear that described embodiment is the present invention one
Section Example, instead of all the embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art are not doing
Every other embodiment obtained under the premise of creative work out, shall fall within the protection scope of the present invention.
According to a first aspect of the embodiments of the present invention, fibre modification alloy material, the component including following parts by weight: industry
25-30 parts of waste residue, 30-40 parts of flyash, 20-30 parts of polytetrafluoroethylene (PTFE), 15-20 parts of glass fibre, 10-15 parts of carbon fiber, silicon
3-6 parts of alkane coupling agent, 3-5 parts of toughener, 2-5 parts of polyester fiber.
Further, the toughener is carboxylic acrylonitrile butadiene rubber latex or polyvinyl alcohol.
Further, the granularity of the industrial residue is 700-800 mesh.
Further, the granularity of the flyash is 1000-1200 mesh.
In production, industrial residue and flyash are ground respectively, and is sieved, specifically, industrial residue mistake
700-800 mesh collects the industrial residue pulvis by screening；Flyash crosses 1000-1200 mesh, collects the powder by screening
Coal ash；
Industrial residue and flyash are dried, drying temperature is 120-140 DEG C, and drying time is 2-3 hours；
Dry industrial residue, flyash, glass fibre, polyester fiber and carbon fiber are weighed by weight ratio, and addition is stirred
It mixes in mixing machine and mixes, mix 0.5-1 hours, then be proportionally added into polytetrafluoroethylene (PTFE), silane coupling agent into stirring mixer
And toughener, and be stirred together 10-30 minutes, until mixture is uniformly mixed；
It feeds the mixture into double screw extruder, is squeezed out at a temperature of 240-260 DEG C by melting mixing, cooling is made
Grain, drying are to get fibre modification alloy material of the invention.
Embodiment 1
According to a first aspect of the embodiments of the present invention, fibre modification alloy material, the component including following parts by weight: industry
25 parts of waste residue, 40 parts of flyash, 20 parts of polytetrafluoroethylene (PTFE), 20 parts of glass fibre, 10 parts of carbon fiber, 3 parts of silane coupling agent, toughening
3 parts of agent, 5 parts of polyester fiber.
In this embodiment, the toughener is carboxylic acrylonitrile butadiene rubber latex or polyvinyl alcohol, specifically uses polyvinyl alcohol and makees
For toughener.
In this embodiment, the granularity of the industrial residue is 800 mesh.
In this embodiment, the granularity of the flyash is 1000 mesh.
Embodiment 2
According to a first aspect of the embodiments of the present invention, fibre modification alloy material, the component including following parts by weight: industry
30 parts of waste residue, 30 parts of flyash, 20 parts of polytetrafluoroethylene (PTFE), 15 parts of glass fibre, 10 parts of carbon fiber, 6 parts of silane coupling agent, toughening
5 parts of agent, 2 parts of polyester fiber.
Further, the toughener is carboxylic acrylonitrile butadiene rubber latex or polyvinyl alcohol.Polyvinyl alcohol is selected to make in this embodiment
For toughener.
Further, the granularity of the industrial residue is 800 mesh.
Further, the granularity of the flyash is 1200 mesh.
Embodiment 3
According to a first aspect of the embodiments of the present invention, fibre modification alloy material, the component including following parts by weight: industry
30 parts of waste residue, 36 parts of flyash, 23 parts of polytetrafluoroethylene (PTFE), 16 parts of glass fibre, 12 parts of carbon fiber, 4 parts of silane coupling agent, toughening
5 parts of agent, 5 parts of polyester fiber.
Further, the toughener is carboxylic acrylonitrile butadiene rubber latex or polyvinyl alcohol.Polyvinyl alcohol is selected to make in this embodiment
For toughener.
Further, the granularity of the industrial residue is 700 mesh.
Further, the granularity of the flyash is 1000 mesh.
Embodiment 4
According to a first aspect of the embodiments of the present invention, fibre modification alloy material, the component including following parts by weight: industry
27 parts of waste residue, 40 parts of flyash, 20 parts of polytetrafluoroethylene (PTFE), 18 parts of glass fibre, 12 parts of carbon fiber, 4 parts of silane coupling agent, toughening
3 parts of agent, 5 parts of polyester fiber.
Further, the toughener is polyvinyl alcohol.
Further, the granularity of the industrial residue is 700 mesh.
Further, the granularity of the flyash is 1000 mesh.
Embodiment 5
According to a first aspect of the embodiments of the present invention, fibre modification alloy material, the component including following parts by weight: industry
30 parts of waste residue, 40 parts of flyash, 25 parts of polytetrafluoroethylene (PTFE), 16 parts of glass fibre, 10 parts of carbon fiber, 4 parts of silane coupling agent, toughening
3 parts of agent, 2 parts of polyester fiber.
Further, the toughener is carboxylic acrylonitrile butadiene rubber latex or polyvinyl alcohol.
Further, the granularity of the industrial residue is 800 mesh.
Further, the granularity of the flyash is 1000 mesh.
Embodiment 6
According to a first aspect of the embodiments of the present invention, fibre modification alloy material, the component including following parts by weight: industry
27 parts of waste residue, 40 parts of flyash, 23 parts of polytetrafluoroethylene (PTFE), 17 parts of glass fibre, 10 parts of carbon fiber, 3 parts of silane coupling agent, toughening
5 parts of agent, 5 parts of polyester fiber.
Further, the toughener is carboxylic acrylonitrile butadiene rubber latex or polyvinyl alcohol.
Further, the granularity of the industrial residue is 800 mesh.
Further, the granularity of the flyash is 1200 mesh.
Floor is produced using the fibre modification alloy material produced in embodiment 1-6 as above, and to the correlated performance on floor
It is detected.Testing result is as follows:
Note: alkali-resisting power is compared with existing commercially available timber floor.
The embodiment of the present invention has the advantages that
Industrial residue and flyash production fibre modification material is utilized, can be realized the recycling of industrial residue and flyash
It recycles, and the improvement alloy material produced has the advantage that
1, modified fibre diameter 200-300nm again, draw ratio is 15 or more；
2, loading is big in the polymer for industrial residue and flyash, can reach 50 or more；
3, raw material cost is low, and materials are easy, and has very high cost performance；
4, stability is good, has good resistance to compression, anti-bending strength, has anti-chemical corrosivity；
3, this alloy material is had excellent performance, complete green material, can be used in preparing floor, dalle, furniture
Plate, door and window etc..
Although above having used general explanation and specific embodiment, the present invention is described in detail, at this
On the basis of invention, it can be made some modifications or improvements, this will be apparent to those skilled in the art.Therefore,
These modifications or improvements without departing from theon the basis of the spirit of the present invention are fallen within the scope of the claimed invention.
Claims (6)
1. fibre modification alloy material, which is characterized in that the component including following parts by weight: 25-30 parts of industrial residue, flyash
30-40 parts, 20-30 parts of polytetrafluoroethylene (PTFE), 15-20 parts of glass fibre, 10-15 parts of carbon fiber, 3-6 parts of silane coupling agent, toughening
3-5 parts of agent, 2-5 parts of polyester fiber.
2. fibre modification alloy material as described in claim 1, which is characterized in that 27-30 parts of industrial residue, flyash 35-
40 parts, 20-25 parts of polytetrafluoroethylene (PTFE), 16-18 parts of glass fibre, 10-12 parts of carbon fiber, 3-4 parts of silane coupling agent, toughener 3-
5 parts, 2-5 parts of polyester fiber.
3. fibre modification alloy material as claimed in claim 2, which is characterized in that 30 parts of industrial residue, 36 parts of flyash, gather
23 parts of tetrafluoroethene, 16 parts of glass fibre, 12 parts of carbon fiber, 4 parts of silane coupling agent, 5 parts of toughener, 5 parts of polyester fiber.
4. fibre modification alloy material as claimed in claim 3, which is characterized in that the toughener be carboxylic acrylonitrile butadiene rubber latex or
Polyvinyl alcohol.
5. fibre modification alloy material as claimed in claim 3, which is characterized in that the granularity of the industrial residue is 700-
800 mesh.
6. fibre modification alloy material as claimed in claim 3, which is characterized in that the granularity of the flyash is 1000-
1200 mesh.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910454015.8A CN110204847A (en) | 2019-05-28 | 2019-05-28 | Fibre modification alloy material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910454015.8A CN110204847A (en) | 2019-05-28 | 2019-05-28 | Fibre modification alloy material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110204847A true CN110204847A (en) | 2019-09-06 |
Family
ID=67789133
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910454015.8A Pending CN110204847A (en) | 2019-05-28 | 2019-05-28 | Fibre modification alloy material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110204847A (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01256427A (en) * | 1988-04-02 | 1989-10-12 | Murakashi Sekkai Kogyo Kk | Transport method for granule |
| CN101885871A (en) * | 2010-07-21 | 2010-11-17 | 天津工业大学 | Fire-retardant cellulose reinforced plastic composite material and preparation method thereof |
| CN103554752A (en) * | 2013-10-25 | 2014-02-05 | 大英县斯佩克新材料有限公司 | Pulverized coal ash and PVC (Poly Vinyl Chloride) composited micro-foaming building template reinforced by long glass fibers, and preparation method of building template |
| CN103709703A (en) * | 2013-12-11 | 2014-04-09 | 上海交通大学 | Recycled carbon fiber reinforced thermoplastic resin composite material and preparation method thereof |
| CN105694517A (en) * | 2016-03-17 | 2016-06-22 | 合肥晨煦信息科技有限公司 | Processing method of high-hardness and high-toughness composite material |
| CN108948667A (en) * | 2018-07-27 | 2018-12-07 | 旌德县源远新材料有限公司 | A kind of glass fibre reinforced composion |
-
2019
- 2019-05-28 CN CN201910454015.8A patent/CN110204847A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01256427A (en) * | 1988-04-02 | 1989-10-12 | Murakashi Sekkai Kogyo Kk | Transport method for granule |
| CN101885871A (en) * | 2010-07-21 | 2010-11-17 | 天津工业大学 | Fire-retardant cellulose reinforced plastic composite material and preparation method thereof |
| CN103554752A (en) * | 2013-10-25 | 2014-02-05 | 大英县斯佩克新材料有限公司 | Pulverized coal ash and PVC (Poly Vinyl Chloride) composited micro-foaming building template reinforced by long glass fibers, and preparation method of building template |
| CN103709703A (en) * | 2013-12-11 | 2014-04-09 | 上海交通大学 | Recycled carbon fiber reinforced thermoplastic resin composite material and preparation method thereof |
| CN105694517A (en) * | 2016-03-17 | 2016-06-22 | 合肥晨煦信息科技有限公司 | Processing method of high-hardness and high-toughness composite material |
| CN108948667A (en) * | 2018-07-27 | 2018-12-07 | 旌德县源远新材料有限公司 | A kind of glass fibre reinforced composion |
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| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20190906 |
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