CN110194678A - A kind of curing compound and the maintenance process using the curing agent - Google Patents

A kind of curing compound and the maintenance process using the curing agent Download PDF

Info

Publication number
CN110194678A
CN110194678A CN201910437635.0A CN201910437635A CN110194678A CN 110194678 A CN110194678 A CN 110194678A CN 201910437635 A CN201910437635 A CN 201910437635A CN 110194678 A CN110194678 A CN 110194678A
Authority
CN
China
Prior art keywords
agent
parts
auxiliary agent
concrete
curing compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201910437635.0A
Other languages
Chinese (zh)
Other versions
CN110194678B (en
Inventor
万民晶
彭黎俊
马俊红
马海燕
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ma Haiyan
Ma Junhong
Peng Lijun
Wan Minjing
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201910437635.0A priority Critical patent/CN110194678B/en
Publication of CN110194678A publication Critical patent/CN110194678A/en
Application granted granted Critical
Publication of CN110194678B publication Critical patent/CN110194678B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/04Preventing evaporation of the mixing water

Abstract

This application involves the realm of building construction, it is intended to and it solves the problems, such as that concrete curing in the prior art is not in place, a kind of curing compound is provided, host agent and auxiliary agent including mass fraction meter;Paraffin wax emulsions, surfactant, bleeding agent and the water absorption Humectant that the host agent includes;The auxiliary agent includes film forming agent and hydroxypropyl methyl cellulose.A kind of maintenance process is also provided, sprinkling maintenance is first carried out;It is sprayed again using curing compound, reuses felt calender and rolled;Thin film is covered again, and uniformly sprinkles sawdust on film or carbon ash is covered, and maintenance work is completed after 15-19d.The present invention has preferable water retention, while improving the intensity and wearability of concrete to the maintenance effect of curing agent.Simultaneously added with auxiliary agent, it can make the host agent based on paraffin wax emulsions that there is preferable film-formation result after spraying host agent, further increase maintenance effect.

Description

A kind of curing compound and the maintenance process using the curing agent
Technical field
This application involves the realm of building construction, specifically a kind of maintenance agent prescription and its maintenance processes.
Background technique
Concrete curing is artificially to cause certain humidity and temperature condition, keep the concrete just poured normal or Accelerate its hardening and gain in strength.Concrete is cement aquation as a result, and water so can gradually harden and increase intensity The aquation of mud needs certain temperature and humidity condition.As ambient enviroment be not present the condition when, then need manually to concrete into Row maintenance.After concrete casting, such as hot climate is air-dried, and is conserved not in time, and moisture can evaporate in concrete Fastly, dehydrating phenomena is formed, the cement granules for having formed gelinite can be prevented from abundant aquation, stable crystallization cannot be converted into, Lack enough cohesive forces, to sheet can occur in concrete surface or powdery falls off.In addition, not yet having foot in concrete When enough intensity, the premature evaporation of moisture can also generate biggish contraction distortion, cup shake occur.So after concreting The maintenance of initial stage is extremely important, should be conserved immediately after concrete final set, after dry concrete Ying Yu is poured It is conserved immediately.
Existing concrete maintenance process has: one, natural curing: point sprinkling maintenance and spraying plastic membrane curing.The former uses Straw screen or mat etc. covers concrete, and often watering keeps wet.Curing time depends on cement type, as ordinary portland cement is mixed Solidifying soil no less than 7 is round the clock.The latter is suitable for being not easy towering structure and large area concrete structure of sprinkling maintenance etc., is by mistake Vinyl chloride resin plastic solution is sprayed at concrete surface with spray gun, forms thin film in concrete surface after solution evaporation, By concrete and air exclusion, moisture evaporation in concrete is prevented to guarantee that cement aquation is normally carried out, it is thin after the completion of maintenance Film can voluntarily fall off in aging.Two, steam curing: concrete component is placed on and mixes with air object full of saturated vapor or steam In fog room, accelerate concrete hardening in higher temperature and humidity environment.Maintenance effect is related with steam curing system, it is wrapped It includes: time of repose, heating and cooling rate, curing temperature, thermostatic curing time, relative humidity etc. before steam curing.Steam is supported There are pit, shaft kiln formula and tunnel-kiln type in shield room.
Curing compound, which is called, does concrete protectant, concrete nursing liquid, is one using modern high technology preparation Kind novel high polymer preparation.A kind of liquid film forming compound that adaptability is very extensive, the product be it is aqueous, nontoxic non-ignitable, It is easy to use, this curing agent is sprayed on concrete or mortar surface, when moisture evaporation to a certain extent, one layer can be quickly formed Colourless, fluid-tight film can prevent the moisture evaporation in concrete or mortar, reduce concrete shrinkage and cracking.And it uses Curing agent is conserved compared to direct sprinkling maintenance, not only saves water resource, while can effectively lock moisture, special needle For special concrete pouring structure (metope or complicated concrete surface) poor problem of watering adhesion effect, it is capable of providing Preferable maintenance effect.
But existing curing agent type is more, and because each component is formulated different, that there are film-formation results is poor, it is poor to disperse osmotic effect Concrete part moisture loss when maintenance is caused comparatively fast to lead to the problem of slight crack.The side that concrete curing is carried out using curing agent existing simultaneously Method is not quite similar, and fails to provide a kind of relatively stable and efficient maintenance construction scheme.
Summary of the invention
A kind of method that the application is intended to provide curing compound and is conserved using the curing agent, it is existing to solve The problem that middle curing agent film forming is poor in technology, dispersion effect difference causes concrete curing not in place.
Embodiments herein is achieved in that
In a first aspect, the application provides a kind of curing compound, host agent 90-95% and auxiliary agent 5- including mass fraction meter 10%, the host agent and auxiliary agent separate storage;
The host agent includes paraffin wax emulsions 45-85%, surfactant 7-15%, bleeding agent 8-12% and suction based on mass fraction Water moisturizer 15-30%;
The auxiliary agent includes film forming agent 70-85% and hydroxypropyl methyl cellulose 15-30% based on mass fraction;The film forming agent Separate with hydroxypropyl methyl cellulose and stores.
Wherein, paraffin wax emulsions are various waxes including pertroleum wax through a kind of aqueous equal of content of wax made of physical modification Uniform flow body, be paraffin and several variety classes, the emulsifier of performance and regulator appropriate through it is solid made of emulsion reaction- Oil-water multiphase dispersion stable emulsion, the type of paraffin needed for generally selecting depending on the application and emulsifier.Concrete exists In solidification process, the moisture evaporation such as surface is too fast, and a series of chemical reaction in its process of setting can be made to be unable to complete, and It is unable to reach the maximum compressive strength on its surface, therefore it is too fast in concrete curing period to must be prevented from moisture evaporation.Thus with Paraffin wax emulsions are that the film hardening agent of base stock can avoid unnecessary surface moisture evaporation, and promote the water of cement Cooperation is used.
Film forming agent be adjust photosensitive liquid can make photosensitive liquid be easy to be coated with and levelling;Improve sticking for photosensitive layer and version base Property and photosensitive layer photochemical reaction speed, these are all conducive to photosensitive liquid and form fixed film layer in version base.Film forming agent Allow for mixing with photosensitive material well, and with photosensitive material solubility having the same, including water-soluble, alkali soluble Property, organic solvent dissolubility etc..
Hydroxypropyl methyl cellulose also has simplification to make hydroxypropyl methylcellulose, is belonged in nonionic cellulose compound ether A kind.It is a kind of semi-synthetic, sluggish, viscoelasticity polymer, often in ophthalmology as lubrication section, and or Auxiliary material or excipients are served as in oral drugs, are common in various different types of commodity.As emulsifier, thickener, suspension The substitute of agent and animal gelatin.
The application also provides a kind of curing compound, host agent 90-95% and auxiliary agent 5-10% including mass fraction meter, institute It states host agent and auxiliary agent separates storage;
The host agent includes paraffin wax emulsions 45-85%, surfactant 7-15%, bleeding agent 8-12% and suction based on mass fraction Water moisturizer 15-30%;
The auxiliary agent includes film forming agent 70-85% and polyvinylpyrrolidone 15-30% based on mass fraction;The film forming agent with Polyvinylpyrrolidone separates storage.
Polyvinylpyrrolidone abbreviation PVP is a kind of non-ionic macromolecule compound, is N- vinylamide Type of Collective It is most characteristic in object, and it is studied most deep, extensive fine chemicals kind.Have evolved into nonionic, cation, yin from Sub 3 major class, 3 kinds of technical grade, pharmaceutical grade, food-grade specifications, relative molecular mass from it is thousands of to 1,000,000 or more homopolymer, altogether Polymers and crosslinking series of polymers product, and be widely applied with its excellent unique performance.PVP is water-soluble as a kind of synthesis Property high-molecular compound, with water-soluble high-molecular compound general aspects, colloid protective effect, film forming, caking property, suction Moist, solubilized or cohesion, but its is most characteristic, thus is its excellent solubility property and physiology phase by people's attention Capacitive.It is not only dissolved in water as PVP in synthesis macromolecule, but also is dissolved in that most of organic solvent, toxicity is very low, physiology intermiscibility Good is actually rare.Polyvinylpyrrolidone is as high molecular surfactant, in different dispersions, can be used as point Powder, emulsifier, thickener, levelling agent, particle size modifier, anti-redeposition agents, flocculating agent, cosolvent and detergent.
The application also provides a kind of curing compound, host agent 90-95% and auxiliary agent 5-10% including mass fraction meter, institute It states host agent and auxiliary agent separates storage;
The host agent includes paraffin wax emulsions 45-85%, surfactant 7-15%, bleeding agent 8-12% and suction based on mass fraction Water moisturizer 15-30%;
The auxiliary agent includes film forming agent 70-85% and diatomite 15-30% based on mass fraction;The diatomite is 100-150 Mesh, the film forming agent and diatomite, which separate, to be stored.
Diatomite is a kind of siliceous rock, is mainly distributed on the states such as China, the U.S., Japan, Denmark, France, Romania. It is a kind of biogenic siliceous sedimentary rock, it is mainly made of the remains of ancient times diatom.Its chemical component is with SiO2Based on, SiO can be used2·nH2O indicates that mineralogical composition is opal and its mutation.There is excellent extensibility, there is higher impact strength, drawing Stretch that intensity, tearing strength, light soft interior mill property is good, good etc. high-quality effect of doing Compressive Strength.Constitution is light and soft, and fineness is in 120 mesh To 1200 mesh.
Further, the paraffin wax emulsions include poly- with 3-8 parts of 34-48 parts of paraffin, the stearic acid of weight, oxidation 20-28 parts of ethylene waxes, 12-18 parts of high-carbon fatty alcohol polyoxyethylene ether and 80-145 parts of water.
Paraffin is also known as crystalline wax, the hydrocarbon mixture that carbon atom number is about 18~30, main component be linear paraffin (about 80%~95%), there are also the monocyclic naphthenes of alkane and belt length side chain on a small quantity with individual branches (the two add up to content 20% with Under).Paraffin is taken off from the resulting lube cut of crude distillation through solvent refining, solvent dewaxing or through wax freezing and crystallizing, squeezing It is waxed to obtain slack wax, then through de-oiling, and sheet made from post-refining or acicular crystal.It is different according to processing and refining degree, it can divide For fully refined paraffin wax, semi-refined paraffin wax and 3 kinds of scale wax.
Fatty acid mainly as surfactant basic material and be used widely, the country is mainly used in: rubber Vulcanizing activator is made in industry;Plastics industry is used as lubricant, stabilizer;Make softening agent in textile industry and house detergent and kills Microbial inoculum;Make wax-pattern in hot investment casting, makees soap base etc. in grease industry.
Oxidized polyethylene wax is excellent novel polar waxes, since oxidized polyethylene wax strand has a certain amount of carbonyl And hydroxyl, so just significantly improving with the intermiscibility of filler, pigment, polar resin.Wetability in polar system, point It dissipates property and is better than polyethylene wax, while also having both coupled, performance is suitable with U.S.'s Honeywell A-C wax.
Fatty alcohol polyoxyethylene ether (AEO), also known as polyoxyethylene aliphatic alcohol ether.It is to develop in nonionic surfactant Most fast, the maximum kind of dosage.Such surfactant is as made of polyethylene glycol (PEG) and fatty alcohol condensation Ether, indicated with following general formula: RO(CH2CH2O) nH, wherein n is the degree of polymerization, because of the degree of polymerization of polyethylene glycol and the kind of fatty alcohol Class is different and has different kinds.Trade name Brij (Brij), if Brij30 and Brij is by different number of polyethylene glycol It is formed with lauric acid polycondensation, all can be used as O/W type emulsifier.
Further, the paraffin wax emulsions include with 6 parts of 41 part, part stearic acid of paraffin of weight, the poly- second of oxidation 21 parts of alkene wax, 15 parts of high-carbon fatty alcohol polyoxyethylene ether and 138 parts of water.
Further, the paraffin wax emulsions include with 58-84 parts of the paraffin of weight, husky 24-35 parts of rope wax, sub- second Double 8-17 parts of the stearic amides of base, 10-19 parts of zinc stearate and 115-175 parts of water.
Ethylenebis stearic amide is a kind of chemicals, and molecular weight is 593.04.Ethylenebis stearic amide has acyl The title of amine wax, also known as N, a N ' ethylenebisstearamide, abbreviation EBS, EBA, structural formula are C17 H35 CONHCH2CH2NHCOCl7H35, molecular weight 593.04.White fine powdery object, relative density 0.98.140~145 ~ C of fusing point. Flash-point (opening cup) 285 ~ C.Most of organic solvents are not dissolved at room temperature, are dissolved in the aromatic hydrocarbon and chlorinated hydrocarbon solvent of heat, are not dissolved in Water.80 DEG C or more aobvious wettabilities, stablize soda acid and aqueous medium.It is nontoxic, it is without any side effects to human body.It can be to days such as starch Right adhesive is modified.It is mainly used as polyvinyl chloride, polyethylene, polypropylene, polystyrene, ABS, phenolic aldehyde, amino resins Lubricant or remover have good inside and outside lubricating action.
Further, the paraffin wax emulsions include hard with 74 parts of the paraffin of weight, husky 27 parts of rope wax, ethylenebis 12 parts of resin acid amide, 11 parts of zinc stearate and 168 parts of water.
Further, the surfactant is neopelex.Neopelex, abbreviation SDBS, White or faint yellow powdery or chip solid.Hardly possible volatilization, it is soluble easily in water, water is dissolved in into translucent solution.To alkali, diluted acid, firmly Water chemistry property is stablized, micro- poison.It is common anionic surfactant.It is simultaneously also various structures in a kind of improvement emulsion At the surface tension between phase, it is allowed to form the substance of uniform and stable dispersion or emulsion.Emulsifier is surface-active Substance has hydrophilic group and lipophilic group simultaneously in molecule, it is gathered on oil/water interface, can reduce interfacial tension and reduction Energy required for emulsion is formed, to improve the energy of emulsion.And neopelex is as a kind of anion Surfactant has good surface-active, and hydrophily is stronger, and the tension of oil-water interface is effectively reduced, and reaches emulsification and makees With.Therefore neopelex obtains wide in the preparation of the emulsion such as cosmetics, food, printing and dyeing assistant, pesticide Using.
Further, the film forming agent is Lauryl Alcohol rouge, and the bleeding agent is Negel, the water suction moisturizing Agent is cellulose-acrylic acid graft water absorbent.Negel can reduce the stickiness of solid particle, help as dispersing agent In the molded operation of ceramic product;As the viscosity depressant in butadiene-styrene rubber cryogenic vulcanization process;In pigment slurry Viscosity depressant;Dispersing agent and stabilizer in synthetic rubber polymerization process;And processed for leather and fur products dyeing, fabric, In the formula of color lake, paint, ink, pesticide etc..It is the main component of Nekal BX.Major product has sodium salt and ammonium salt.
The cellulose-acrylic acid graft water absorbent is a kind of cellulose graft propylene acids with high hygroscopicity resin, main There is preferable water-retaining property using cellulose as skeleton, by being formed with acrylic graft copolymer, addition be in curing agent for Offer Water-saving effect keeps the skin wet as wetting agent to cement.
On the other hand, the application also provides a kind of maintenance process of concrete, the specific steps are as follows:
G1. the sprinkling maintenance for pouring the concrete progress 14-28h finished is covered after sprinkling maintenance in concrete surface first Lid straw bag or macromolecule membrane;
G2. the straw bag of the concrete surface after sprinkling maintenance or macromolecule membrane are removed, and takes any of the above-described kind of coagulation Host agent in native curing agent is mixed, and is sprayed to concrete surface;
G3. after host agent is uniformly sprayed, the auxiliary agent independently stored is mixed, mixed auxiliary agent is uniformly sprayed at coagulation On the host agent layer of native surface covering;
G4. it after auxiliary agent has sprayed, is just rolled using felt calender in the concrete surface for spraying curing compound;
G5. thin film is just covered again on the curing compound of film forming after rolling 3-5h to felt calender, and in film On uniformly sprinkle sawdust or carbon ash is covered, maintenance work is completed after 15-19d.
Beneficial effects of the present invention:
The present invention uses paraffin wax emulsions, surfactant and compound emulsifying agent etc. for raw material, matches to New Type Curing Agent for Concrete Side is designed, and synthesizes compound curing agent.To the maintenance effect of curing agent, there is preferable water retention, while improving coagulation The intensity and wearability of soil.Simultaneously added with auxiliary agent, can make after spraying host agent host agent based on paraffin wax emulsions have compared with Good film-formation result, further increases maintenance effect.
Meanwhile the present invention carries out water spray operation in one day or so in early period by optimizing original maintenance process, so that mending Water-filling can infiltrate through in concrete, then the compound curing agent provided through the invention is retained, and finally by round brush It can be by maintenance oxidant layer film forming more homogeneous.
Specific embodiment
Embodiment 1:
The present embodiment provides a kind of curing compounds, host agent 93% and auxiliary agent 7% including mass fraction meter, the host agent with help Agent separates storage;
The host agent includes paraffin wax emulsions 67%, neopelex 8%, 8% and of Negel based on mass fraction Cellulose-acrylic acid graft water absorbent 17%;
The auxiliary agent includes Lauryl Alcohol rouge 78% and hydroxypropyl methyl cellulose 22% based on mass fraction;The Lauryl Alcohol Rouge and hydroxypropyl methyl cellulose separate storage.
Individually packaging is placed after above-mentioned host agent and auxiliary agent are prepared respectively, carries out product ingredient according to the proportion.It helps simultaneously Agent is equally individually packed, therefore single curing agent product is three independent packagings, is made after avoiding auxiliary agent early period that host agent is added It can not preferably be sprayed at lotion viscosity is higher.
A kind of maintenance process of concrete is also provided, the specific steps are as follows:
First to the sprinkling maintenance for pouring the concrete progress 19h finished, straw bag is covered in concrete surface after sprinkling maintenance Or macromolecule membrane;At the entire sprinkling maintenance stage, it is to be sprayed using spray tube to entire concrete surface, starts to spray Spilling the time is 9 points of night and starts that interval 30min sprinkling is primary, and each spraying time is 5min, then to morning 8 points start to cover Straw bag or straw mattress.If surface covers straw mattress or straw bag, it is adjusted according to daytime temperature, if daytime temperature is higher than 30 DEG C, Just continue the spray water on straw mattress or straw bag.And if being covered with macromolecule membrane, without sprinkling, water is waited to immerse coagulation In soil layer.
The straw bag of concrete surface after sprinkling maintenance or macromolecule membrane are removed, and is taken and is weighed above-mentioned concrete and support Host agent in shield agent is mixed, and is sprayed to concrete surface;Here host agent is first taken to be put into mixing plant It is stirred, then sprays again.Sprinkling process curing agent quantitative to the concrete spraying in unit area as far as possible, to each spray It spills operator to be planned, consequently facilitating the later period is uniformly coated.
After host agent is uniformly sprayed, the auxiliary agent independently stored is mixed, mixed auxiliary agent is uniformly sprayed at mixed On the host agent layer of solidifying soil surface covering;Here auxiliary agent is while also to increase viscosity to allow lotion preferably to form a film, to make The concreting body surface filming adhesion effect for obtaining some facades or inclined-plane is preferable.
After auxiliary agent has sprayed, just rolled using felt calender in the concrete surface for spraying curing compound It is dynamic;
Thin film is just covered again on the curing compound of film forming after rolling 4h to felt calender, and on film uniformly It sprinkles sawdust or carbon ash is covered, maintenance work is completed after 18d.
Embodiment 2:
The present embodiment provides a kind of curing compounds, host agent 92% and auxiliary agent 8% including mass fraction meter, the host agent with help Agent separates storage;
The host agent includes paraffin wax emulsions 70%, neopelex 7%, 8% and of Negel based on mass fraction Cellulose-acrylic acid graft water absorbent 15%;
The auxiliary agent includes Lauryl Alcohol rouge 81% and polyvinylpyrrolidone 19% based on mass fraction;The Lauryl Alcohol rouge Separate with polyvinylpyrrolidone and stores.
A kind of maintenance process of concrete is also provided, the specific steps are as follows:
First to the sprinkling maintenance for pouring the concrete progress 20h finished, straw bag is covered in concrete surface after sprinkling maintenance Or macromolecule membrane;At the entire sprinkling maintenance stage, it is to be sprayed using spray tube to entire concrete surface, starts to spray Spilling the time is 9 points of night and starts that interval 30min sprinkling is primary, and each spraying time is 5min, then to morning 8 points start to cover Straw bag or straw mattress.If surface covers straw mattress or straw bag, it is adjusted according to daytime temperature, if daytime temperature is higher than 30 DEG C, Just continue the spray water on straw mattress or straw bag.And if being covered with macromolecule membrane, without sprinkling, water is waited to immerse coagulation In soil layer.
The straw bag of concrete surface after sprinkling maintenance or macromolecule membrane are removed, and is taken and is weighed above-mentioned concrete and support Host agent in shield agent is mixed, and is sprayed to concrete surface;Here host agent is first taken to be put into mixing plant It is stirred, then sprays again.Sprinkling process curing agent quantitative to the concrete spraying in unit area as far as possible, to each spray It spills operator to be planned, consequently facilitating the later period is uniformly coated.
After host agent is uniformly sprayed, the auxiliary agent independently stored is mixed, mixed auxiliary agent is uniformly sprayed at mixed On the host agent layer of solidifying soil surface covering;Here auxiliary agent is while also to increase viscosity to allow lotion preferably to form a film, to make The concreting body surface filming adhesion effect for obtaining some facades or inclined-plane is preferable.
After auxiliary agent has sprayed, just rolled using felt calender in the concrete surface for spraying curing compound It is dynamic;
Thin film is just covered again on the curing compound of film forming after rolling 3h to felt calender, and on film uniformly It sprinkles sawdust or carbon ash is covered, maintenance work is completed after 16d.
Embodiment 3:
The present embodiment provides a kind of curing compounds, host agent 93% and auxiliary agent 7% including mass fraction meter, the host agent with help Agent separates storage;
The host agent includes paraffin wax emulsions 51%, neopelex 12%, Negel 10% based on mass fraction With cellulose-acrylic acid graft water absorbent 17%;
The auxiliary agent includes film forming agent 71% and diatomite 29% based on mass fraction;The diatomite is 150 mesh, the film forming Agent and diatomite, which separate, to be stored.
A kind of maintenance process of concrete is also provided, the specific steps are as follows:
First to the sprinkling maintenance for pouring the concrete progress 20h finished, straw bag is covered in concrete surface after sprinkling maintenance Or macromolecule membrane;At the entire sprinkling maintenance stage, it is to be sprayed using spray tube to entire concrete surface, starts to spray Spilling the time is 9 points of night and starts that interval 30min sprinkling is primary, and each spraying time is 5min, then to morning 8 points start to cover Straw bag or straw mattress.If surface covers straw mattress or straw bag, it is adjusted according to daytime temperature, if daytime temperature is higher than 30 DEG C, Just continue the spray water on straw mattress or straw bag.And if being covered with macromolecule membrane, without sprinkling, water is waited to immerse coagulation In soil layer.
The straw bag of concrete surface after sprinkling maintenance or macromolecule membrane are removed, and is taken and is weighed above-mentioned concrete and support Host agent in shield agent is mixed, and is sprayed to concrete surface;Here host agent is first taken to be put into mixing plant It is stirred, then sprays again.Sprinkling process curing agent quantitative to the concrete spraying in unit area as far as possible, to each spray It spills operator to be planned, consequently facilitating the later period is uniformly coated.
After host agent is uniformly sprayed, the auxiliary agent independently stored is mixed, mixed auxiliary agent is uniformly sprayed at mixed On the host agent layer of solidifying soil surface covering;Here auxiliary agent is while also to increase viscosity to allow lotion preferably to form a film, to make The concreting body surface filming adhesion effect for obtaining some facades or inclined-plane is preferable.
After auxiliary agent has sprayed, just rolled using felt calender in the concrete surface for spraying curing compound It is dynamic;
Thin film is just covered again on the curing compound of film forming after rolling 3h to felt calender, and on film uniformly It sprinkles sawdust or carbon ash is covered, maintenance work is completed after 16d.
Embodiment 4:
The present embodiment is specifically defined paraffin wax emulsions, paraffin wax emulsions include using any one of above-described embodiment 1-3 curing agent With 6 parts of 41 part, part stearic acid of paraffin, 21 parts of oxidized polyethylene wax, 15 parts of the high-carbon fatty alcohol polyoxyethylene ether of weight With 138 parts of water.
Embodiment 5:
The present embodiment is specifically defined paraffin wax emulsions, the paraffin wax emulsions using any one of above-described embodiment 1-3 curing agent Including with 74 parts of the paraffin of weight, husky 27 parts of rope wax, 12 parts of ethylenebis stearic amide, 11 parts of zinc stearate and water 168 parts.
9 formulas in above-mentioned 5 embodiments are tested, include wherein to be formulated in 6 in embodiment 4 and embodiment 5, But its formulation data difference is smaller, just embodiment 4 and embodiment 5 each take it is a kind of tested as experimental group, and increase by two The existing curing agent of group and 5 groups of formulas adjusted carry out experimental test together.
Experimental group 1-5 first is that 5 formulas in above-mentioned 5 embodiments carry out producing and being made 20 groups of samples, is then surveyed Test result takes mean value.
Experimental group 6
A kind of curing compound, including paraffin wax emulsions 67%, neopelex 8%, alkylnaphthalene based on mass fraction Sodium sulfonate 8% and cellulose-acrylic acid graft water absorbent 17%.(lacking auxiliary agent)
Experimental group 7
A kind of curing compound, host agent 93% and auxiliary agent 7% including mass fraction meter, the host agent and auxiliary agent, which separate, to be stored; The host agent includes paraffin wax emulsions 77%, neopelex 13%, Negel 10% based on mass fraction;Institute Stating auxiliary agent includes Lauryl Alcohol rouge 78% and hydroxypropyl methyl cellulose 22% based on mass fraction;The Lauryl Alcohol rouge and hydroxyl Propyl methocel separates storage.(lacking water absorbing agent)
Experimental group 8
A kind of curing compound, host agent 93% and auxiliary agent 7% including mass fraction meter, the host agent and auxiliary agent, which separate, to be stored; The host agent includes paraffin wax emulsions 67%, neopelex 8%, Negel 8% and fiber based on mass fraction Plain grafted propylene acids water absorbing agent 17%;The auxiliary agent is Lauryl Alcohol rouge.(lacking stick)
Experimental group 9
A kind of curing compound using the formula of embodiment 1, but is directly sprayed when maintenance and is waited after concrete surface 28d or so directly sampling is tested.
Experimental group 10
Using the curing agent of existing silicate solutions, when maintenance is directly sprayed waits 28d or so after concrete surface Directly sampling is tested.
Experimental test project includes:
Water retention, concrete soil sample compression strength and wearability.
Water retention test method: the water-retaining property of the curing agent coating sprayed on new molding surface of concrete structure it is good The bad every technical performance for directly affecting concrete.Experimental study is according to " cement concrete curing agent " (JC901-200) standard Defined test method and main technique requirements make normal concrete test specimen and spraying curing agent concrete sample, examination respectively Part exposed surface is having a size of 150mm*150mm, after the surface condition of test specimen reaches requirement, is accurately claimed to test specimen immediately Amount, then again equidistantly equably puts test specimen in environmental cabinet, and record the cartonning time.It is taken out from environmental cabinet after 72h Concrete sample simultaneously claims its quality respectively.
Compression strength: manufactured size is the concrete sample of 150*150*150mm, is then coated corresponding curing agent The disposed within and corresponding method of use is conserved, and then demoulding carries out compressive strength test.
Wearability test: manufactured size is the concrete sample of 150*150*150mm, is then coated corresponding maintenance Agent is disposed within and is conserved using corresponding method, and then demoulding carries out abrasion test, using stone mill under 200 turns It rubs to concrete surface, and tests the weight difference and record of front and back.
Test result is as follows:
Maintenance performance first after the test of experimental group 1-5 all has preferable performance indicator compared to control group and other groups, After only using special paraffin wax emulsions, dispersion effect is preferable, and the sample stratification situation of test is less, therefore the later period reaches The performance indicator highest arrived.And after experimental group 6 lacks auxiliary agent, cause the curing agent film-formation result on concrete sample surface poor, Then lead to the reduction of water retention index, while the mechanical property of concrete being caused also to have decline.And experimental group 7 is the absence of water absorbing agent, Same water retention decline is more obvious;Experimental group 8 is the absence of stick, that is, thickener, therefore also results in concrete sample Simulation shear wall surface maintenance situation is especially placed on multiple sample test surfaces by surface filming uneven thickness vertically in test Afterwards, lead to lower part curing agent film forming preferably, and the obvious adhesion amount of the curing agent on top is less, then average water retention decline occurs. And experimental group 9 is then to be also resulted in each group performance data using common maintenance process and be decreased obviously.
The foregoing is merely preferred embodiment of the present application, are not intended to limit this application, for the skill of this field For art personnel, various changes and changes are possible in this application.Within the spirit and principles of this application, made any to repair Change, equivalent replacement, improvement etc., should be included within the scope of protection of this application.

Claims (10)

1. a kind of curing compound, it is characterised in that: host agent 90-95% including mass fraction meter and auxiliary agent 5-10%, it is described Host agent and auxiliary agent, which separate, to be stored;
The host agent includes paraffin wax emulsions 45-85%, surfactant 7-15%, bleeding agent 8-12% and suction based on mass fraction Water moisturizer 15-30%;
The auxiliary agent includes film forming agent 70-85% and hydroxypropyl methyl cellulose 15-30% based on mass fraction;The film forming agent Separate with hydroxypropyl methyl cellulose and stores.
2. a kind of curing compound, it is characterised in that: host agent 90-95% including mass fraction meter and auxiliary agent 5-10%, it is described Host agent and auxiliary agent, which separate, to be stored;
The host agent includes paraffin wax emulsions 45-85%, surfactant 7-15%, bleeding agent 8-12% and suction based on mass fraction Water moisturizer 15-30%;
The auxiliary agent includes film forming agent 70-85% and polyvinylpyrrolidone 15-30% based on mass fraction;The film forming agent with Polyvinylpyrrolidone separates storage.
3. a kind of curing compound, it is characterised in that: host agent 90-95% including mass fraction meter and auxiliary agent 5-10%, it is described Host agent and auxiliary agent, which separate, to be stored;
The host agent includes paraffin wax emulsions 45-85%, surfactant 7-15%, bleeding agent 8-12% and suction based on mass fraction Water moisturizer 15-30%;
The auxiliary agent includes film forming agent 70-85% and diatomite 15-30% based on mass fraction;The diatomite is 100-150 Mesh, the film forming agent and diatomite, which separate, to be stored.
4. a kind of curing compound according to claim 1-3, it is characterised in that: the paraffin wax emulsions include With 3-8 parts of 34-48 parts of paraffin, the stearic acid of weight, 20-28 parts of oxidized polyethylene wax, high-carbon fatty alcohol polyoxyethylene 12-18 parts and water 80-145 parts of ether.
5. a kind of curing compound according to claim 4, it is characterised in that: the paraffin wax emulsions include with parts by weight 6 parts of 41 part, part stearic acid of paraffin, 21 parts of oxidized polyethylene wax, 15 parts of high-carbon fatty alcohol polyoxyethylene ether and the water 138 of proportion Part.
6. a kind of curing compound according to claim 1-3, it is characterised in that: the paraffin wax emulsions include With 58-84 parts of the paraffin of weight, husky 24-35 parts of rope wax, 8-17 parts of ethylenebis stearic amide, zinc stearate 10- 19 parts and water 115-175 parts.
7. a kind of curing compound according to claim 6, it is characterised in that: the paraffin wax emulsions include with parts by weight 74 parts of the paraffin of proportion, husky 27 parts of rope wax, 12 parts of ethylenebis stearic amide, 11 parts of zinc stearate and 168 parts of water.
8. a kind of curing compound according to claim 1-3, it is characterised in that: the surfactant is Neopelex.
9. a kind of curing compound according to claim 1-3, it is characterised in that: the film forming agent is 12 Carbon alcohol ester, the bleeding agent are Negel, and the water absorption Humectant is cellulose-acrylic acid graft water absorbent.
10. a kind of maintenance process of concrete, it is characterised in that: specific step is as follows:
G1. the sprinkling maintenance for pouring the concrete progress 14-28h finished is covered after sprinkling maintenance in concrete surface first Lid straw bag or macromolecule membrane;
Any one of G2. the straw bag of the concrete surface after sprinkling maintenance or macromolecule membrane are removed, and take claim 1-3 Curing compound in host agent be mixed, and concrete surface is sprayed;
G3. after host agent is uniformly sprayed, the auxiliary agent independently stored is mixed, mixed auxiliary agent is uniformly sprayed at coagulation On the host agent layer of native surface covering;
G4. it after auxiliary agent has sprayed, is just rolled using felt calender in the concrete surface for spraying curing compound;
G5. thin film is just covered again on the curing compound of film forming after rolling 3-5h to felt calender, and in film On uniformly sprinkle sawdust or carbon ash is covered, maintenance work is completed after 15-19d.
CN201910437635.0A 2019-05-24 2019-05-24 Concrete curing agent and curing method using same Active CN110194678B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910437635.0A CN110194678B (en) 2019-05-24 2019-05-24 Concrete curing agent and curing method using same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910437635.0A CN110194678B (en) 2019-05-24 2019-05-24 Concrete curing agent and curing method using same

Publications (2)

Publication Number Publication Date
CN110194678A true CN110194678A (en) 2019-09-03
CN110194678B CN110194678B (en) 2022-01-18

Family

ID=67753067

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910437635.0A Active CN110194678B (en) 2019-05-24 2019-05-24 Concrete curing agent and curing method using same

Country Status (1)

Country Link
CN (1) CN110194678B (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110452018A (en) * 2019-09-23 2019-11-15 交通运输部公路科学研究所 A kind of high temperature resistant cement concrete road shows stone agent and its preparation method and application
CN111138209A (en) * 2020-01-15 2020-05-12 江苏奥莱特新材料股份有限公司 Concrete external curing agent
CN113173803A (en) * 2021-06-08 2021-07-27 中建安装集团有限公司 Cement-based material maintenance system and method for water purification plant
CN113307655A (en) * 2021-05-31 2021-08-27 中建安装集团有限公司 Cement-based external curing and internal protecting material and preparation method thereof
CN115925307A (en) * 2022-12-23 2023-04-07 杭州构建新型材料有限公司 Concrete curing agent and preparation method thereof
CN116332673A (en) * 2023-03-30 2023-06-27 深圳场道工程有限公司 Concrete curing agent and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2928752A (en) * 1956-09-15 1960-03-15 Dehydag Gmbh Paraffin emulsions for protection of masonry surfaces during setting
CN102964086A (en) * 2012-12-18 2013-03-13 白玉清 Concrete curing agent
CN103964893A (en) * 2014-04-25 2014-08-06 交通运输部公路科学研究所 Early-strength wear-resistant concrete curing agent, as well as preparation method and application thereof
CN104529526A (en) * 2014-12-02 2015-04-22 科之杰新材料集团有限公司 Emulsion type concrete curing agent and prepration method thereof
WO2015059141A1 (en) * 2013-10-21 2015-04-30 Chryso Curing composition for a hydraulic composition providing reinforced adhesion

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2928752A (en) * 1956-09-15 1960-03-15 Dehydag Gmbh Paraffin emulsions for protection of masonry surfaces during setting
CN102964086A (en) * 2012-12-18 2013-03-13 白玉清 Concrete curing agent
WO2015059141A1 (en) * 2013-10-21 2015-04-30 Chryso Curing composition for a hydraulic composition providing reinforced adhesion
CN103964893A (en) * 2014-04-25 2014-08-06 交通运输部公路科学研究所 Early-strength wear-resistant concrete curing agent, as well as preparation method and application thereof
CN104529526A (en) * 2014-12-02 2015-04-22 科之杰新材料集团有限公司 Emulsion type concrete curing agent and prepration method thereof

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
吕百龄等: "《实用工业助剂全书》", 31 July 2001, 化学工业出版社 *
李广宇等: "《胶黏剂原材料手册》", 31 August 2004, 国防工业出版社 *
耿耀宗: "《现代水性涂料:工艺•配方•应用》", 31 March 2013, 中国石化出版社 *
陈立军等: "《混凝土制品及其工艺学》", 31 August 2012, 中国建材工业出版社 *

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110452018A (en) * 2019-09-23 2019-11-15 交通运输部公路科学研究所 A kind of high temperature resistant cement concrete road shows stone agent and its preparation method and application
CN111138209A (en) * 2020-01-15 2020-05-12 江苏奥莱特新材料股份有限公司 Concrete external curing agent
CN113307655A (en) * 2021-05-31 2021-08-27 中建安装集团有限公司 Cement-based external curing and internal protecting material and preparation method thereof
CN113173803A (en) * 2021-06-08 2021-07-27 中建安装集团有限公司 Cement-based material maintenance system and method for water purification plant
CN113173803B (en) * 2021-06-08 2024-03-26 中建安装集团有限公司 Cement-based material maintenance system and method for water purification plant
CN115925307A (en) * 2022-12-23 2023-04-07 杭州构建新型材料有限公司 Concrete curing agent and preparation method thereof
CN115925307B (en) * 2022-12-23 2024-01-23 杭州构建新型材料有限公司 Concrete curing agent and preparation method thereof
CN116332673A (en) * 2023-03-30 2023-06-27 深圳场道工程有限公司 Concrete curing agent and preparation method thereof
CN116332673B (en) * 2023-03-30 2024-03-26 深圳场道工程有限公司 Concrete curing agent and preparation method thereof

Also Published As

Publication number Publication date
CN110194678B (en) 2022-01-18

Similar Documents

Publication Publication Date Title
CN110194678A (en) A kind of curing compound and the maintenance process using the curing agent
EP0811584B1 (en) Cementitious materials
JP5719845B2 (en) Antibacterial quaternary ammonium organosilane composition
CN103450995B (en) Oily solid releasing agent and preparation method thereof
CN103613717B (en) A kind of self-emulsifying type vinylformic acid Organosilicon wax protective material and preparation method and application
DE60108152T2 (en) GRANULATED HYDROPHOBIC ADDITIVE MATERIAL FOR CEMENT COMPOSITIONS
JPH0925434A (en) Method for preparing coating composition and coating film based on powder containing water-redispersible water-solublepolymer and organosilicone compound
CN106380112B (en) Hydrophobic microcapsules are in the application for improving agent on crack resistance of concrete permeability
CN107011714B (en) A kind of moisture-proof anti-crack mastic powder
CN109534746A (en) Toilet liquid foam backfilling material and preparation method thereof
CN109777198A (en) Environmentally friendly oil-soluble oil ink and its preparation process
CN107935490A (en) A kind of durability concrete encaustic tile
CN107227111A (en) A kind of new type water burnt-in sand coating and preparation method thereof
CN108359337A (en) Mould-proof-type interior wall sealing wax and preparation method thereof
US2441927A (en) Mucilaginous composition
CN109970425A (en) A kind of artistic sculpture lightweight mud and preparation method thereof
JPH0130793B2 (en)
CN106927746B (en) A kind of exterior wall embossment powder and preparation method thereof
CN105505211B (en) A kind of interfacial agents poured for cement concrete and its production and use
CN108774530B (en) A kind of transplantation method of degradable soil consolidation agent and preparation method thereof and plantling
JP4537867B2 (en) Clay with excellent water resistance
CN108892415A (en) Curing compound and the preparation method and application thereof
CN115491930A (en) Degradable paper pulp molding product and preparation method and application thereof
CN107857603A (en) The agent of plant cover concrete surface-closed and its method being surface-treated to plant cover concrete
CN105263966A (en) Aqueous composition

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
TA01 Transfer of patent application right
TA01 Transfer of patent application right

Effective date of registration: 20211220

Address after: 030006 zone B, zhenguanyuan, Jinyang street, Taiyuan City, Shanxi Province

Applicant after: Wan Minjing

Applicant after: Peng Lijun

Applicant after: Ma Haiyan

Applicant after: Ma Junhong

Address before: 030006 zone B, zhenguanyuan, Jinyang street, Taiyuan City, Shanxi Province

Applicant before: Wan Minjing

Applicant before: Peng Lijun

Applicant before: Ma Haiyan

GR01 Patent grant
GR01 Patent grant