CN110183743A - A kind of structural chelating anti-slip material of compounded rubber - Google Patents
A kind of structural chelating anti-slip material of compounded rubber Download PDFInfo
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- CN110183743A CN110183743A CN201910422677.7A CN201910422677A CN110183743A CN 110183743 A CN110183743 A CN 110183743A CN 201910422677 A CN201910422677 A CN 201910422677A CN 110183743 A CN110183743 A CN 110183743A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/02—Mixing; Kneading non-continuous, with mechanical mixing or kneading devices, i.e. batch type
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/02—Mixing; Kneading non-continuous, with mechanical mixing or kneading devices, i.e. batch type
- B29B7/22—Component parts, details or accessories; Auxiliary operations
- B29B7/28—Component parts, details or accessories; Auxiliary operations for measuring, controlling or regulating, e.g. viscosity control
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/80—Component parts, details or accessories; Auxiliary operations
- B29B7/82—Heating or cooling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2206—Oxides; Hydroxides of metals of calcium, strontium or barium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/222—Magnesia, i.e. magnesium oxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2234—Oxides; Hydroxides of metals of lead
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Thermal Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
The invention discloses a kind of structural chelating anti-slip materials of compounded rubber, prepare raw material including following weight parts: 70 parts of SVR-3L natural rubber, 35 parts of oil-extended butadiene rubber, white 35 parts of carbon, 3 parts of PEG4000 polyethylene glycol, 5 parts of zinc oxide, 4 parts of magnesia, 2 parts of calcium oxide, 1 part of stearic acid, 4 parts of lead orthoplumbate, 2 parts of triallyl cyanurate, 1.5 parts of triallyl isocyanurate, 6.5 parts of promotor, 0.5 part of age resister, 3 parts of coupling agent and 2 parts of vulcanizing agent.The present invention passes through addition oil-extended butadiene rubber and adjusts the rational proportion of SVR-3L natural rubber and oil-extended butadiene rubber, and some specific auxiliary agents are added, so that the non-skid property of the composite rubber material is greatly enhanced.
Description
Technical field
The present invention relates to compounded rubber preparation technical field, specially a kind of structural chelating anti-slip material of compounded rubber.
Background technique
Compounded rubber be on the basis of natural rubber plus a little synthetic rubber and a part of chemical products mixing refine and
At, in recent years, the developing state of synthetic rubber industry makes people joyful, with production-scale continuous expansion, synthetic rubber
Industry will will occupy more importantly status in CHINESE INDUSTRIES economy, synthetic rubber mainly for the manufacture of automobile tire, adhesive tape,
There are many type of sebific duct, rubber overshoes, cable, sealing article, druggist rubber sundrier, adhesive and latex product etc., sole materials, can
It is divided into two kinds of class bottom material of natural class bottom material and synthesis, natural class bottom material includes natural bottom leather, bamboo and wood material etc., synthesizes class bottom material packet
Include rubber, plastics, rubber and plastic suitable materials, regenerated leather, elastic hardboard etc., anti-skid property of soles made of existing compounded rubber
Poor, use is dangerous, therefore the present invention designs a kind of structural chelating anti-slip material of compounded rubber to solve the above problems.
Summary of the invention
(1) the technical issues of solving
In view of the deficiencies of the prior art, it the present invention provides a kind of structural chelating anti-slip material of compounded rubber, solves
The undesirable problem of traditional sole compounded rubber non-skid property.
(2) technical solution
To achieve the above object, the invention provides the following technical scheme: a kind of structural chelating anti-slip material of compounded rubber,
Prepare raw material including following weight parts: 70 parts of SVR-3L natural rubber, 35 parts of oil-extended butadiene rubber, white 35 parts of carbon,
3 parts of PEG4000 polyethylene glycol, 5 parts of zinc oxide, 4 parts of magnesia, 2 parts of calcium oxide, 1 part of stearic acid, 4 parts of lead orthoplumbate, triolefin
2 parts of propyl cyanurate, 1.5 parts of triallyl isocyanurate, 6.5 parts of promotor, 0.5 part of age resister, 3 parts of coupling agent and
2 parts of vulcanizing agent.
Preferably, the promotor include 1.5 parts of accelerant MBT, 2 parts of accelerant MBT S, 1.5 parts of promotor ZMBT,
0.5 part and 1 part of accelerator CBS of TM monex TM.
Preferably, the age resister is set as age resister 4010NA.
Preferably, the coupling agent is set as one of KH550, KH560 and KH570 or several mixtures.
Preferably, the vulcanizing agent is set as elementary sulfur.
Preferably, the anti-slip material process flow the following steps are included:
Step 1: it plasticates to SVR-3L natural rubber, scorching hot compressed air is passed through into SVR-3L natural rubber,
Under the action of heat and oxygen, long-chain molecule degradation is set to shorten, to obtain plasticity；
Step 2: plasticating to oil-extended butadiene rubber, scorching hot compressed air is passed through into oil-extended butadiene rubber, in heat
Under the action of oxygen, long-chain molecule degradation is set to shorten, to obtain plasticity；
Step 3: being kneaded, 23 parts of white carbon are added in 70 parts of SVR-3L natural rubbers, is uniformly mixed, is kneaded 5min, together
When 12 parts of white carbon are added in 35 parts of oil-extended butadiene rubbers, be uniformly mixed, be also kneaded 5min, then said mixture is blended in
Together, then sequentially add 3 parts of PEG4000 polyethylene glycol, 5 parts of zinc oxide, 4 parts of magnesia, 2 parts of calcium oxide, 1 part of stearic acid,
It is 4 parts of lead orthoplumbate, 2 parts of triallyl cyanurate, 1.5 parts of triallyl isocyanurate, 6.5 parts of promotor, anti-aging
It 0.5 part and 3 parts of coupling agent of agent, is uniformly mixed, is kneaded, 6h or more is stood after mixing, obtains rubber compound；
Step 4: by above-mentioned blend glue stuff by extruding, certain shapes blank is made, then be placed on vulcanizing press and vulcanize
Molding, obtains compounded rubber anti-slip material.
Preferably, melting temperature is 50-60 DEG C in the step 3, mixing time 25min.
Preferably, curing temperature is 150 DEG C, sulfide stress 12Mpa, vulcanization time 12min in the step 4.
(3) beneficial effect
The present invention provides a kind of structural chelating anti-slip material of compounded rubber, have it is following the utility model has the advantages that
(1) present invention passes through addition oil-extended butadiene rubber and adjusts the reasonable of SVR-3L natural rubber and oil-extended butadiene rubber
Proportion, and some specific auxiliary agents are added, so that the non-skid property of the composite rubber material is greatly enhanced.
(2) when being kneaded, white carbon is first kneaded with SVR-3L natural rubber and oil-extended butadiene rubber the present invention respectively,
Whole raw material are kneaded again, and this method enables white charcoal to be thoroughly mixed with rubber, composite rubber products quality obtained
More preferably.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation
Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common
Technical staff's every other embodiment obtained without making creative work belongs to the model that the present invention protects
It encloses.
Embodiment 1
A kind of structural chelating anti-slip material of compounded rubber, prepares raw material including following weight parts: the natural rubber of SVR-3L
70 parts of glue, 35 parts of oil-extended butadiene rubber, white 35 parts of carbon, 3 parts of PEG4000 polyethylene glycol, 5 parts of zinc oxide, 4 parts of magnesia, oxygen
Change 2 parts of calcium, 1 part of stearic acid, 4 parts of lead orthoplumbate, 2 parts of triallyl cyanurate, 1.5 parts of triallyl isocyanurate,
6.5 parts of promotor, 0.5 part of age resister, 3 parts of coupling agent and 2 parts of vulcanizing agent, promotor include 1.5 parts of accelerant MBT, promote
2 parts of agent MBTS, 1.5 parts of promotor ZMBT, 0.5 part of TM monex TM and 1 part of accelerator CBS, age resister is set as anti-
Aging agent 4010NA, coupling agent is set as one of KH550, KH560 and KH570 or several mixtures, vulcanizing agent are set
It is set to elementary sulfur.
The process flow of anti-slip material the following steps are included:
Step 1: it plasticates to SVR-3L natural rubber, scorching hot compressed air is passed through into SVR-3L natural rubber,
Under the action of heat and oxygen, long-chain molecule degradation is set to shorten, to obtain plasticity；
Step 2: plasticating to oil-extended butadiene rubber, scorching hot compressed air is passed through into oil-extended butadiene rubber, in heat
Under the action of oxygen, long-chain molecule degradation is set to shorten, to obtain plasticity；
Step 3: being kneaded, 23 parts of white carbon are added in 70 parts of SVR-3L natural rubbers, is uniformly mixed, is kneaded 5min, together
When 12 parts of white carbon are added in 35 parts of oil-extended butadiene rubbers, be uniformly mixed, be also kneaded 5min, then said mixture is blended in
Together, then sequentially add 3 parts of PEG4000 polyethylene glycol, 5 parts of zinc oxide, 4 parts of magnesia, 2 parts of calcium oxide, 1 part of stearic acid,
It is 4 parts of lead orthoplumbate, 2 parts of triallyl cyanurate, 1.5 parts of triallyl isocyanurate, 6.5 parts of promotor, anti-aging
It 0.5 part and 3 parts of coupling agent of agent, is uniformly mixed, is kneaded, melting temperature is 50-60 DEG C, mixing time 25min, is kneaded knot
6h or more is stood after beam, obtains rubber compound；
Step 4: by above-mentioned blend glue stuff by extruding, certain shapes blank is made, then be placed on vulcanizing press and vulcanize
Molding, curing temperature are 150 DEG C, sulfide stress 12Mpa, vulcanization time 12min and obtain compounded rubber anti-slip material.
Embodiment 2
A kind of structural chelating anti-slip material of compounded rubber, prepares raw material including following weight parts: the natural rubber of SVR-3L
70 parts of glue, 15 parts of oil-extended butadiene rubber, white 35 parts of carbon, 3 parts of PEG4000 polyethylene glycol, 5 parts of zinc oxide, 4 parts of magnesia, oxygen
Change 2 parts of calcium, 1 part of stearic acid, 4 parts of lead orthoplumbate, 2 parts of triallyl cyanurate, 1.5 parts of triallyl isocyanurate,
6.5 parts of promotor, 0.5 part of age resister, 3 parts of coupling agent and 2 parts of vulcanizing agent, promotor include 1.5 parts of accelerant MBT, promote
2 parts of agent MBTS, 1.5 parts of promotor ZMBT, 0.5 part of TM monex TM and 1 part of accelerator CBS, age resister is set as anti-
Aging agent 4010NA, coupling agent is set as one of KH550, KH560 and KH570 or several mixtures, vulcanizing agent are set
It is set to elementary sulfur.
The process flow of anti-slip material the following steps are included:
Step 1: it plasticates to SVR-3L natural rubber, scorching hot compressed air is passed through into SVR-3L natural rubber,
Under the action of heat and oxygen, long-chain molecule degradation is set to shorten, to obtain plasticity；
Step 2: plasticating to oil-extended butadiene rubber, scorching hot compressed air is passed through into oil-extended butadiene rubber, in heat
Under the action of oxygen, long-chain molecule degradation is set to shorten, to obtain plasticity；
Step 3: being kneaded, 29 parts of white carbon are added in 70 parts of SVR-3L natural rubbers, is uniformly mixed, is kneaded 5min, together
When 6 parts of white carbon are added in 15 parts of oil-extended butadiene rubbers, be uniformly mixed, be also kneaded 5min, then said mixture is blended in
Together, then sequentially add 3 parts of PEG4000 polyethylene glycol, 5 parts of zinc oxide, 4 parts of magnesia, 2 parts of calcium oxide, 1 part of stearic acid,
It is 4 parts of lead orthoplumbate, 2 parts of triallyl cyanurate, 1.5 parts of triallyl isocyanurate, 6.5 parts of promotor, anti-aging
It 0.5 part and 3 parts of coupling agent of agent, is uniformly mixed, is kneaded, melting temperature is 50-60 DEG C, mixing time 25min, is kneaded knot
6h or more is stood after beam, obtains rubber compound；
Step 4: by above-mentioned blend glue stuff by extruding, certain shapes blank is made, then be placed on vulcanizing press and vulcanize
Molding, curing temperature are 150 DEG C, sulfide stress 12Mpa, vulcanization time 12min and obtain compounded rubber anti-slip material.
Embodiment 3
A kind of structural chelating anti-slip material of compounded rubber, prepares raw material including following weight parts: the natural rubber of SVR-3L
70 parts of glue, 25 parts of oil-extended butadiene rubber, white 35 parts of carbon, 3 parts of PEG4000 polyethylene glycol, 5 parts of zinc oxide, 4 parts of magnesia, oxygen
Change 2 parts of calcium, 1 part of stearic acid, 4 parts of lead orthoplumbate, 2 parts of triallyl cyanurate, 1.5 parts of triallyl isocyanurate,
6.5 parts of promotor, 0.5 part of age resister, 3 parts of coupling agent and 2 parts of vulcanizing agent, promotor include 1.5 parts of accelerant MBT, promote
2 parts of agent MBTS, 1.5 parts of promotor ZMBT, 0.5 part of TM monex TM and 1 part of accelerator CBS, age resister is set as anti-
Aging agent 4010NA, coupling agent is set as one of KH550, KH560 and KH570 or several mixtures, vulcanizing agent are set
It is set to elementary sulfur.
The process flow of anti-slip material the following steps are included:
Step 1: it plasticates to SVR-3L natural rubber, scorching hot compressed air is passed through into SVR-3L natural rubber,
Under the action of heat and oxygen, long-chain molecule degradation is set to shorten, to obtain plasticity；
Step 2: plasticating to oil-extended butadiene rubber, scorching hot compressed air is passed through into oil-extended butadiene rubber, in heat
Under the action of oxygen, long-chain molecule degradation is set to shorten, to obtain plasticity；
Step 3: being kneaded, 26 parts of white carbon are added in 70 parts of SVR-3L natural rubbers, is uniformly mixed, is kneaded 5min, together
When 9 parts of white carbon are added in 25 parts of oil-extended butadiene rubbers, be uniformly mixed, be also kneaded 5min, then said mixture is blended in
Together, then sequentially add 3 parts of PEG4000 polyethylene glycol, 5 parts of zinc oxide, 4 parts of magnesia, 2 parts of calcium oxide, 1 part of stearic acid,
It is 4 parts of lead orthoplumbate, 2 parts of triallyl cyanurate, 1.5 parts of triallyl isocyanurate, 6.5 parts of promotor, anti-aging
It 0.5 part and 3 parts of coupling agent of agent, is uniformly mixed, is kneaded, melting temperature is 50-60 DEG C, mixing time 25min, is kneaded knot
6h or more is stood after beam, obtains rubber compound；
Step 4: by above-mentioned blend glue stuff by extruding, certain shapes blank is made, then be placed on vulcanizing press and vulcanize
Molding, curing temperature are 150 DEG C, sulfide stress 12Mpa, vulcanization time 12min and obtain compounded rubber anti-slip material.
Embodiment 4
A kind of structural chelating anti-slip material of compounded rubber, prepares raw material including following weight parts: the natural rubber of SVR-3L
70 parts of glue, 45 parts of oil-extended butadiene rubber, white 35 parts of carbon, 3 parts of PEG4000 polyethylene glycol, 5 parts of zinc oxide, 4 parts of magnesia, oxygen
Change 2 parts of calcium, 1 part of stearic acid, 4 parts of lead orthoplumbate, 2 parts of triallyl cyanurate, 1.5 parts of triallyl isocyanurate,
6.5 parts of promotor, 0.5 part of age resister, 3 parts of coupling agent and 2 parts of vulcanizing agent, promotor include 1.5 parts of accelerant MBT, promote
2 parts of agent MBTS, 1.5 parts of promotor ZMBT, 0.5 part of TM monex TM and 1 part of accelerator CBS, age resister is set as anti-
Aging agent 4010NA, coupling agent is set as one of KH550, KH560 and KH570 or several mixtures, vulcanizing agent are set
It is set to elementary sulfur.
The process flow of anti-slip material the following steps are included:
Step 1: it plasticates to SVR-3L natural rubber, scorching hot compressed air is passed through into SVR-3L natural rubber,
Under the action of heat and oxygen, long-chain molecule degradation is set to shorten, to obtain plasticity；
Step 2: plasticating to oil-extended butadiene rubber, scorching hot compressed air is passed through into oil-extended butadiene rubber, in heat
Under the action of oxygen, long-chain molecule degradation is set to shorten, to obtain plasticity；
Step 3: being kneaded, 21 parts of white carbon are added in 70 parts of SVR-3L natural rubbers, is uniformly mixed, is kneaded 5min, together
When 14 parts of white carbon are added in 45 parts of oil-extended butadiene rubbers, be uniformly mixed, be also kneaded 5min, then said mixture is blended in
Together, then sequentially add 3 parts of PEG4000 polyethylene glycol, 5 parts of zinc oxide, 4 parts of magnesia, 2 parts of calcium oxide, 1 part of stearic acid,
It is 4 parts of lead orthoplumbate, 2 parts of triallyl cyanurate, 1.5 parts of triallyl isocyanurate, 6.5 parts of promotor, anti-aging
It 0.5 part and 3 parts of coupling agent of agent, is uniformly mixed, is kneaded, melting temperature is 50-60 DEG C, mixing time 25min, is kneaded knot
6h or more is stood after beam, obtains rubber compound；
Step 4: by above-mentioned blend glue stuff by extruding, certain shapes blank is made, then be placed on vulcanizing press and vulcanize
Molding, curing temperature are 150 DEG C, sulfide stress 12Mpa, vulcanization time 12min and obtain compounded rubber anti-slip material.
Embodiment 5
A kind of structural chelating anti-slip material of compounded rubber, prepares raw material including following weight parts: the natural rubber of SVR-3L
70 parts of glue, 55 parts of oil-extended butadiene rubber, white 35 parts of carbon, 3 parts of PEG4000 polyethylene glycol, 5 parts of zinc oxide, 4 parts of magnesia, oxygen
Change 2 parts of calcium, 1 part of stearic acid, 4 parts of lead orthoplumbate, 2 parts of triallyl cyanurate, 1.5 parts of triallyl isocyanurate,
6.5 parts of promotor, 0.5 part of age resister, 3 parts of coupling agent and 2 parts of vulcanizing agent, promotor include 1.5 parts of accelerant MBT, promote
2 parts of agent MBTS, 1.5 parts of promotor ZMBT, 0.5 part of TM monex TM and 1 part of accelerator CBS, age resister is set as anti-
Aging agent 4010NA, coupling agent is set as one of KH550, KH560 and KH570 or several mixtures, vulcanizing agent are set
It is set to elementary sulfur.
The process flow of anti-slip material the following steps are included:
Step 1: it plasticates to SVR-3L natural rubber, scorching hot compressed air is passed through into SVR-3L natural rubber,
Under the action of heat and oxygen, long-chain molecule degradation is set to shorten, to obtain plasticity；
Step 2: plasticating to oil-extended butadiene rubber, scorching hot compressed air is passed through into oil-extended butadiene rubber, in heat
Under the action of oxygen, long-chain molecule degradation is set to shorten, to obtain plasticity；
Step 3: being kneaded, 20 parts of white carbon are added in 70 parts of SVR-3L natural rubbers, is uniformly mixed, is kneaded 5min, together
When 15 parts of white carbon are added in 55 parts of oil-extended butadiene rubbers, be uniformly mixed, be also kneaded 5min, then said mixture is blended in
Together, then sequentially add 3 parts of PEG4000 polyethylene glycol, 5 parts of zinc oxide, 4 parts of magnesia, 2 parts of calcium oxide, 1 part of stearic acid,
It is 4 parts of lead orthoplumbate, 2 parts of triallyl cyanurate, 1.5 parts of triallyl isocyanurate, 6.5 parts of promotor, anti-aging
It 0.5 part and 3 parts of coupling agent of agent, is uniformly mixed, is kneaded, melting temperature is 50-60 DEG C, mixing time 25min, is kneaded knot
6h or more is stood after beam, obtains rubber compound；
Step 4: by above-mentioned blend glue stuff by extruding, certain shapes blank is made, then be placed on vulcanizing press and vulcanize
Molding, curing temperature are 150 DEG C, sulfide stress 12Mpa, vulcanization time 12min and obtain compounded rubber anti-slip material.
Non-skid property experiment is carried out to the Antiskid sole produced through embodiment 1-5, experimental method is anti-using footwear static state
Sliding method for testing performance HGT3780-2005, obtains following table data:
When oil-extended butadiene rubber is 35 parts, non-skid property is best, and the present invention is by addition oil-extended butadiene rubber and adjusts
The rational proportion of SVR-3L natural rubber and oil-extended butadiene rubber, and some specific auxiliary agents are added, so that the compounded rubber material
The non-skid property of material is greatly enhanced.
It should be noted that, in this document, relational terms such as first and second and the like are used merely to a reality
Body or operation are distinguished with another entity or operation, are deposited without necessarily requiring or implying between these entities or operation
In any actual relationship or order or sequence.Moreover, the terms "include", "comprise" or its any other variant are intended to
Non-exclusive inclusion, so that the process, method, article or equipment including a series of elements is not only wanted including those
Element, but also including other elements that are not explicitly listed, or further include for this process, method, article or equipment
Intrinsic element.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention is defined by the appended.
Claims (8)
1. a kind of structural chelating anti-slip material of compounded rubber, it is characterised in that: prepare raw material including following weight parts: SVR-
70 parts of 3L natural rubber, 35 parts of oil-extended butadiene rubber, white 35 parts of carbon, 3 parts of PEG4000 polyethylene glycol, 5 parts of zinc oxide, oxidation
4 parts of magnesium, 2 parts of calcium oxide, 1 part of stearic acid, 4 parts of lead orthoplumbate, 2 parts of triallyl cyanurate, triallyl isocyanuric acid
1.5 parts of ester, 6.5 parts of promotor, 0.5 part of age resister, 3 parts of coupling agent and 2 parts of vulcanizing agent.
2. the structural chelating anti-slip material of a kind of compounded rubber according to claim 1, it is characterised in that: the promotor
Including 1.5 parts of accelerant MBT, 2 parts of accelerant MBT S, 1.5 parts of promotor ZMBT, 0.5 part of TM monex TM and promotor
1 part of CBS.
3. the structural chelating anti-slip material of a kind of compounded rubber according to claim 1, it is characterised in that: described anti-aging
Agent is set as age resister 4010NA.
4. the structural chelating anti-slip material of a kind of compounded rubber according to claim 1, it is characterised in that: the coupling agent
It is set as one of KH550, KH560 and KH570 or several mixtures.
5. the structural chelating anti-slip material of a kind of compounded rubber according to claim 1, it is characterised in that: the vulcanizing agent
It is set as elementary sulfur.
6. the structural chelating anti-slip material of a kind of compounded rubber according to claim 1, it is characterised in that: the ribband
The process flow of material the following steps are included:
Step 1: plasticating to SVR-3L natural rubber, scorching hot compressed air is passed through into SVR-3L natural rubber, in heat
Under the action of oxygen, long-chain molecule degradation is set to shorten, to obtain plasticity；
Step 2: plasticating to oil-extended butadiene rubber, scorching hot compressed air is passed through into oil-extended butadiene rubber, in heat and oxygen
Under the action of, so that long-chain molecule degradation is shortened, to obtain plasticity；
Step 3: being kneaded, 23 parts of white carbon are added in 70 parts of SVR-3L natural rubbers, is uniformly mixed, is kneaded 5min, simultaneously will
12 parts of white carbon are added in 35 parts of oil-extended butadiene rubbers, are uniformly mixed, are also kneaded 5min, then said mixture is blended in one
It rises, then sequentially adds 3 parts of PEG4000 polyethylene glycol, 5 parts of zinc oxide, 4 parts of magnesia, 2 parts of calcium oxide, 1 part of stearic acid, four
Aoxidize 4 parts of three lead, 2 parts of triallyl cyanurate, 1.5 parts of triallyl isocyanurate, 6.5 parts of promotor, age resister
It 0.5 part and 3 parts of coupling agent, is uniformly mixed, is kneaded, 6h or more is stood after mixing, obtains rubber compound；
Step 4: by above-mentioned blend glue stuff by extrusion, certain shapes blank is made, then be placed in sulfidization molding on vulcanizing press,
Obtain compounded rubber anti-slip material.
7. the structural chelating anti-slip material of a kind of compounded rubber according to claim 6, it is characterised in that: the step 3
Middle melting temperature is 50-60 DEG C, mixing time 25min.
8. the structural chelating anti-slip material of a kind of compounded rubber according to claim 6, it is characterised in that: the step 4
Middle curing temperature is 150 DEG C, sulfide stress 12Mpa, vulcanization time 12min.
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