CN110183139A - A kind of concrete anti-seepage agent and preparation method - Google Patents
A kind of concrete anti-seepage agent and preparation method Download PDFInfo
- Publication number
- CN110183139A CN110183139A CN201910548298.2A CN201910548298A CN110183139A CN 110183139 A CN110183139 A CN 110183139A CN 201910548298 A CN201910548298 A CN 201910548298A CN 110183139 A CN110183139 A CN 110183139A
- Authority
- CN
- China
- Prior art keywords
- concrete
- concrete anti
- silicate
- seepage agent
- water
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/60—Agents for protection against chemical, physical or biological attack
- C04B2103/65—Water proofers or repellants
Abstract
The present invention proposes that a kind of concrete anti-seepage agent and preparation method, permeability-reducing admixture are made of silicate, ethyl potassium silicate, fatty acid salt, nano silica, polyvinyl alcohol, additive etc..Wherein the content of silicate is 1.0-8.0wt%, ethyl silicic acid potassium content is 0.4-11.6wt%, sodium soap content is 1.0-17.0wt%, nanometer titanium dioxide silicone content is 3.0-12.0wt%, polyvinyl alcohol content 2.0-17.5wt%, additive level is 0.02~0.09wt%, the rest is water.Each component content is mass percent.The present invention can be used for the waterproofs such as concrete, bathing pool, pond, basement, building top and penetrate into field, have many advantages, such as that waterproof infiltration capacity is high, waterproof effective time is long, waterproof is high-efficient, easy to use and nontoxic.
Description
Technical field
The invention belongs to the waterproof fields such as at the top of concrete, pond, basement, building, and it is anti-to be related to a kind of concrete high-efficiency
Penetration enhancer and preparation method.
Background technique
Concrete is a kind of very important construction material, is widely used in building constructions, concrete dykes and dams, bathroom, kitchen
The fields such as room, tunnel, swimming pool.After concrete hardens under the conditions of general maintenance, it is easy to occur seeping water or drainage, because
This solves the problems, such as that concrete water-proof is impervious particularly significant.Concrete waterproofer has the function of very big in terms of preventing water infiltration.
Waterproofing agent experienced the development of pitch, polyurethane resin, polyacrylic acid and polyacrylamide polymers, inorganic infiltration salt etc.
Journey.Wherein, pitch and polyurethane resin type waterproof material be because seriously polluted, and containing toxic, is prohibited by country;Propylene
Acid and acrylamide polymer class waterproof material persistence are poor, are easy aging, and the service life is short, once in addition, membrane waterproofing is destroyed,
Leakage phenomenon is occurred with regard to horse back.Patent CN201810116545.7 discloses a kind of waterproof material and its system for building construction
Preparation Method, the patent is using raw materials such as epoxy resin, polyurethane, quartz sand, pitch, zirconium dioxides, although having centainly
Waterproof effect, but service life is not grown.Patent CN1800291 discloses a kind of water-proofing material for stopping leak, the water-proofing material for stopping leak
It is portland cement 24-60%, high alumina 20-63%, Potassium aluminum sulfate dodecahydrate 0-10%, dihydrate gypsum by weight percent
1-5%, Sodium Polyacrylate 0-1%, bentonite 2-10%, latex powder 0-2%, quartz sand 10-20% composition, although in the short time
It is interior to have effects that slow down water infiltration, but after long-time use, water still is able to penetrate into quickly.Patent CN108359292A
A kind of preparation method of cement group water-proofing material is disclosed, and party's material is with water, ethyl alcohol, silane coupling agent, sodium bentonite and hydrogen
Sodium oxide molybdena etc. is raw material, not only complex process, but also waterproof effect is undesirable.Inorganic waterproofing agent main component has villaumite, chlorine
Lithium hydrochlorate, sulfate, waterglass, mineral powder etc., it is different degrees of due to haveing the shortcomings that, it is anti-to be difficult to meet concrete construction engineering
The impervious needs of water.CN106904928A discloses a kind of water-borne permeable crystalline waterproofing material that reaction speed is controllable, this is anti-
Water material is mainly by sodium metasilicate, surfactant, response delay agent, reducing agent, reaction promoter, anti-freeze agent, metal ion
Agent is blocked, surface hardening agent, antirust agent, deionized water is constituted, long although having certain waterproof ability in a short time
The decline of phase waterproof effect, and complicated composition, it is at high cost.
Summary of the invention
The present invention in view of the shortcomings of the prior art, has developed a kind of preparation method of high performance waterproof infiltration material, should
Material is configured by silicate, ethyl potassium silicate, fatty acid salt, nano silica, polyvinyl alcohol, additive etc., is had
Good waterproof penetrates into effect.
The specific technical proposal is:
A kind of concrete anti-seepage agent, the mass ratio of each ingredient of the permeability-reducing admixture are as follows: silicate 1.0-8.0wt%, ethyl silicic acid
Potassium 0.4-11.6wt%, sodium soap 1.0-17.0wt%, nano silica 3.0-12.0wt%, polyvinyl alcohol 2.0-
17.5wt%, 0.02~0.09wt% of additive, water 40.0-91.5wt%.
Further, above-mentioned additive is sodium citrate, laureth sodium sulfovinate, borax, according to mass ratio 1:
4:0.1 the mixture being configured to.
Further, above-mentioned silicate is at least one of sodium metasilicate, potassium silicate, silicic acid ammonia.
Further, the molecular weight of above-mentioned polyvinyl alcohol is 1-3 ten thousand.
Further, the average particle size of above-mentioned nano silica is 50-120 nanometers.
The preparation method of above-mentioned concrete anti-seepage agent comprises the following steps that the mass ratio according to each ingredient of permeability-reducing admixture, first
Polyvinyl alcohol is weighed, is dissolved in 80-90 DEG C of hot water;Then silicate, ethyl potassium silicate, sodium soap are sequentially added, is stirred
After mixing uniformly;Additive is added, continues to stir evenly;It is eventually adding nano silica, continues stirring 5 minutes, is made mixed
Solidifying soil permeability-reducing admixture.
The permeability-reducing admixture is directly sprayed when in use or is brushed in needing to do water-proofing treatment by the application of concrete anti-seepage agent
Concrete surface, just there is after 4-6min good waterproof effect.
Beneficial effects of the present invention are that the waterproofing agent is easily penetrated into concrete, can not only be crammed in concrete
Outer micropore, and it is capable of the surface of concrete and inside is formed simultaneously hydrophobic layer, the infiltration of water is prevented, therefore can be effective
Ground prevents the infiltration or infiltration of water.
Specific embodiment
The additive that following embodiment uses is sodium citrate, laureth sodium sulfovinate, borax, according to mass ratio 1:
4:0.1 the mixture being configured to.
Embodiment one:
Polyvinyl alcohol 7Kg is weighed first, is dissolved in 10 Kg hot water (80-90 DEG C), is then sequentially added silicate
5Kg, ethyl potassium silicate 4Kg, 3 Kg of sodium soap add additive 0.03Kg after mixing evenly, continue to stir evenly, most
It is 50nm silica 6Kg and water 65Kg that granularity is added afterwards, continues stirring 5 minutes, can prepare the product.
The seepage capability test method and result of the product: the product being sprayed or is brushed on concrete, after 5min,
Inspection of dripping carried out to its surface, water can be condensed into pearl (ball) shape on the surface of concrete, and droplet and concrete surface connect
Feeler is 140 degree, and it is constant to be able to maintain glomeration, will not quickly spread around, also not to concrete infiltration.Make water storage inspection
Test, which brushes or after being sprayed on the surface of concrete, maximum when concrete is waterproof can water pressure resistance be 2 meters.
Embodiment two:
Polyvinyl alcohol 5Kg is weighed first, is dissolved in 8 Kg hot water (80-90 DEG C), is then sequentially added silicate
9Kg, ethyl potassium silicate 10Kg, sodium soap 8Kg add additive 0.03Kg after mixing evenly, continue to stir evenly, most
53 Kg of silica 7Kg and water that granularity is 70nm is added afterwards, continues stirring 5 minutes, the product can be prepared.
The seepage capability test method and result of the product: the product being sprayed or is brushed on concrete, after 5min,
Inspection of dripping carried out to its surface, water can be condensed into pearl (ball) shape on the surface of concrete, and droplet and concrete surface connect
Feeler is 146 degree, and it is constant to be able to maintain glomeration, will not quickly spread around, also not to concrete infiltration.Make water storage inspection
Test, which brushes or after being sprayed on the surface of concrete, maximum when concrete is waterproof can water pressure resistance be 2.4 meters.
Embodiment three:
Polyvinyl alcohol 2Kg is weighed first, is dissolved in 6 Kg hot water (80-90 DEG C), is then sequentially added silicate
5Kg, ethyl potassium silicate 11Kg, sodium soap 17Kg add additive 0.06Kg after mixing evenly, continue to stir evenly, most
49 Kg of silica 1 0Kg and water that granularity is 100nm is added afterwards, continues stirring 5 minutes, the product can be prepared.
The seepage capability test method and result of the product: the product being sprayed or is brushed on concrete, after 5min,
Inspection of dripping carried out to its surface, water can be condensed into pearl (ball) shape on the surface of concrete, and droplet and concrete surface connect
Feeler is 150 degree, and it is constant to be able to maintain glomeration, will not quickly spread around, also not to concrete infiltration.Make water storage inspection
Test, which brushes or after being sprayed on the surface of concrete, maximum when concrete is waterproof can water pressure resistance be 2.9 meters.
Example IV:
Polyvinyl alcohol 2Kg is weighed first, is dissolved in 9 Kg hot water (80-90 DEG C), is then sequentially added silicate 7
Kg, ethyl potassium silicate 2Kg, 12 Kg of sodium soap add additive 0.08Kg after mixing evenly, continue to stir evenly, most
Silica 12 Kg and water 56Kg that granularity is 120nm are added afterwards, continues stirring 5 minutes, the product can be prepared.
The seepage capability test method and result of the product: the product being sprayed or is brushed on concrete, after 5min,
Inspection of dripping carried out to its surface, water can be condensed into pearl (ball) shape on the surface of concrete, and droplet and concrete surface connect
Feeler is 132 degree, and it is constant to be able to maintain glomeration, will not quickly spread around, also not to concrete infiltration.Make water storage inspection
Test, which brushes or after being sprayed on the surface of concrete, maximum when concrete is waterproof can water pressure resistance be 1.6 meters.
Claims (7)
1. a kind of concrete anti-seepage agent, which is characterized in that the mass ratio of each ingredient of the permeability-reducing admixture are as follows: silicate 1.0-8.0wt%,
Ethyl potassium silicate 0.4-11.6wt%, sodium soap 1.0-17.0wt%, nano silica 3.0-12.0wt%, polyvinyl alcohol
2.0-17.5wt%, 0.02~0.09wt% of additive, water 40.0-91.5wt%.
2. concrete anti-seepage agent according to claim 1, which is characterized in that the additive is sodium citrate, laurel
Alcohol polyethers sodium sulfovinate, borax, the mixture being configured to according to mass ratio 1:4:0.1.
3. concrete anti-seepage agent according to claim 1 or 2, which is characterized in that the silicate is sodium metasilicate, silicic acid
At least one of potassium, silicic acid ammonia.
4. concrete anti-seepage agent according to claim 1 or 2, which is characterized in that the molecular weight of the polyvinyl alcohol is
1-3 ten thousand.
5. concrete anti-seepage agent according to claim 1 or 2, which is characterized in that the nano silica is averaged
Granularity is 50-120 nanometers.
6. the preparation method of any concrete anti-seepage agent of claim 1-5, which is characterized in that comprise the following steps that by
According to the mass ratio of each ingredient of permeability-reducing admixture, polyvinyl alcohol is first weighed, is dissolved in 80-90 DEG C of hot water;Then silicic acid is sequentially added
Salt, ethyl potassium silicate, sodium soap, after mixing evenly;Additive is added, continues to stir evenly;It is eventually adding nano-silica
SiClx continues stirring 5 minutes, and concrete anti-seepage agent is made.
7. the application of any concrete anti-seepage agent of claim 1-5, which is characterized in that directly by the permeability-reducing admixture when use
Sprinkling is brushed in the surface for the concrete for needing to do water-proofing treatment.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111517690A (en) * | 2020-04-21 | 2020-08-11 | 杭州砺品科技有限公司 | Concrete anti-seepage agent and preparation process thereof |
CN113999649A (en) * | 2021-11-01 | 2022-02-01 | 安徽省交通规划设计研究总院股份有限公司 | Concrete bridge deck high-permeability waterproof bonding layer and preparation method thereof |
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CN104150954A (en) * | 2014-09-02 | 2014-11-19 | 上海坤美环境科技有限公司 | Concrete seal curing agent |
CN104386983A (en) * | 2014-10-28 | 2015-03-04 | 南京工业大学 | Water-tolerant silicate coating and preparation method thereof |
CN104961424A (en) * | 2015-06-11 | 2015-10-07 | 湖南交泰建材有限公司 | Concrete curing protective agent |
CN107140930A (en) * | 2017-05-17 | 2017-09-08 | 河北省交通规划设计院 | A kind of cement concrete constructions surface invisible coating and preparation method thereof |
CN109279841A (en) * | 2018-11-16 | 2019-01-29 | 东北大学 | A kind of high-performance water resistant penetrates into the preparation method of material |
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2019
- 2019-06-24 CN CN201910548298.2A patent/CN110183139A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104150954A (en) * | 2014-09-02 | 2014-11-19 | 上海坤美环境科技有限公司 | Concrete seal curing agent |
CN104386983A (en) * | 2014-10-28 | 2015-03-04 | 南京工业大学 | Water-tolerant silicate coating and preparation method thereof |
CN104961424A (en) * | 2015-06-11 | 2015-10-07 | 湖南交泰建材有限公司 | Concrete curing protective agent |
CN107140930A (en) * | 2017-05-17 | 2017-09-08 | 河北省交通规划设计院 | A kind of cement concrete constructions surface invisible coating and preparation method thereof |
CN109279841A (en) * | 2018-11-16 | 2019-01-29 | 东北大学 | A kind of high-performance water resistant penetrates into the preparation method of material |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111517690A (en) * | 2020-04-21 | 2020-08-11 | 杭州砺品科技有限公司 | Concrete anti-seepage agent and preparation process thereof |
CN113999649A (en) * | 2021-11-01 | 2022-02-01 | 安徽省交通规划设计研究总院股份有限公司 | Concrete bridge deck high-permeability waterproof bonding layer and preparation method thereof |
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Application publication date: 20190830 |
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