CN110181920A - A kind of transparent flexible battery packaging material - Google Patents

A kind of transparent flexible battery packaging material Download PDF

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Publication number
CN110181920A
CN110181920A CN201910542630.4A CN201910542630A CN110181920A CN 110181920 A CN110181920 A CN 110181920A CN 201910542630 A CN201910542630 A CN 201910542630A CN 110181920 A CN110181920 A CN 110181920A
Authority
CN
China
Prior art keywords
flexible
layer
packaging material
battery packaging
flexible battery
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910542630.4A
Other languages
Chinese (zh)
Inventor
单化众
吕松
梁俊杰
王芳
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CHANGZHOU SIWEIKE PHOTOVOLTAIC NEW MATERIAL Co Ltd
Original Assignee
CHANGZHOU SIWEIKE PHOTOVOLTAIC NEW MATERIAL Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by CHANGZHOU SIWEIKE PHOTOVOLTAIC NEW MATERIAL Co Ltd filed Critical CHANGZHOU SIWEIKE PHOTOVOLTAIC NEW MATERIAL Co Ltd
Priority to CN201910542630.4A priority Critical patent/CN110181920A/en
Publication of CN110181920A publication Critical patent/CN110181920A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/28Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
    • B32B27/281Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42 comprising polyimides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/34Layered products comprising a layer of synthetic resin comprising polyamides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/36Layered products comprising a layer of synthetic resin comprising polyesters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings, jackets or wrappings of a single cell or a single battery
    • H01M50/116Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material
    • H01M50/124Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material having a layered structure
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings, jackets or wrappings of a single cell or a single battery
    • H01M50/183Sealing members
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/546Flexural strength; Flexion stiffness
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2457/00Electrical equipment
    • B32B2457/10Batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Abstract

The present invention relates to flexible battery technical field, especially a kind of transparent flexible battery packaging material;Including flexible cover sheet and flexible heat-sealing internal layer, it is provided with middle layer between the flexible cover sheet and flexible heat-sealing internal layer, adhesive layer is provided between the flexible cover sheet and middle layer, is provided with special adhesion layer between the middle layer and flexible heat-sealing internal layer;It is proposed by the present invention to propose a kind of completely new flexible battery encapsulating material, encapsulation applied to flexible battery, and provide good sealing insulating, after battery is made, in the case where radius of curvature R is the test condition of 15mm, flexible 20,000 times or more and the impregnable material of battery performance, solve on flexible battery technical field, encapsulating material from scratch the problem of.

Description

A kind of transparent flexible battery packaging material
Technical field
The present invention relates to flexible battery technical field, especially a kind of transparent flexible battery packaging material.
Background technique
Till now, flexible screen has begun commercialization to smart machine, and the flexibility development of smart machine is also city Where the trend of field, and market can be more more and more intense for the demand of flexible battery.
Now can the multiple flexible battery of bending fold development but there is no further improvement, reason is existing Secondary cell is all lump, inflexibility, and the flexibility of battery, and existing battery can not all expire from material to technique Foot.The application requirement of flexible battery folded bent first, so that the structure design and material selection inside battery core require completely newly Research and development, secondly be exactly existing encapsulating material be not able to satisfy its requirement.
At present in the world, the battery of development phase is made using existing battery packaging material, it may appear that bending Number is insufficient, and occurring plastic deformation after alternating bending for several times leads to the generation of wrinkle, and then squeezes and even puncture battery core, causes tight The security risk of weight.Therefore, in the technology development course that flexible battery is researched and developed and is promoted, it is necessary to have a suitable for its encapsulation It uses, in the case where radius of curvature R is the test condition of 15mm, can achieve 20000 alternating bendings without deformation, and energy Enough meet the basic requirement of battery, and the flexible encapsulant material of observation inside battery variation can be facilitated.
Summary of the invention
The purpose of the present invention is: the technological gap of flexible lithium ion battery is filled up, a kind of anti-plastic deformation of flexibility, energy are provided Enough be bent 20000 times or more, it is transparent convenient for observation inside battery core, meet the flexible battery package material for the performance requirement that battery uses Material.
In order to solve the above technical problems, The technical solution adopted by the invention is as follows:
A kind of transparent flexible battery packaging material, including flexible cover sheet and flexible heat-sealing internal layer, the flexible cover sheet and soft Property heat-sealing internal layer between be provided with middle layer, adhesive layer, the middle layer are provided between the flexible cover sheet and middle layer It is provided with special adhesion layer between flexible heat-sealing internal layer, middle layer and flexible heat-sealing internal layer can be made to be bonded together, and can Certain isolation performance is provided, there is extremely strong anti-swelling.
Further, the flexible cover sheet with a thickness of 12 μm ~ 30 μm.
Further, the material of the flexible cover sheet is nylon membrane, polyethylene terephthalate film or poly- to benzene Dioctyl phthalate butanediol ester film.
Further, the adhesive layer uses acrylic ester adhesive or polyurethane binder.
Further, the middle layer with a thickness of 20 μm ~ 60 μm.
Further, the material of the middle layer is polyimide film or poly (ethylene naphthalate) film.
Further, the special adhesion layer with a thickness of 5 μm ~ 50 μm.
Further, the material of the special adhesion layer is modified polypropene film.
Further, the flexible heat-sealing internal layer with a thickness of 5 μm ~ 80 μm.
Further, the material of the flexible heat-sealing internal layer is polypropylene film or polyethylene film.
It is using the beneficial effect of technical solution of the present invention:
It is proposed by the present invention to propose a kind of new flexible battery encapsulating material, applied to the encapsulation of flexible battery, have good Good sealing insulating, and being applicable in existing battery manufacturing process, being made after battery can multiple curved material.
Detailed description of the invention
Fig. 1 is the structural diagram of the present invention.
In figure: 1 flexible cover sheet, 2 adhesive layers, 3 middle layers, 4 special adhesion layers, 5 flexible heat-sealing internal layers.
Specific embodiment
In conjunction with the accompanying drawings, the present invention is further explained in detail.These attached drawings are simplified schematic diagram, only with Illustration illustrates basic structure of the invention, therefore it only shows the composition relevant to the invention.
Fig. 1 is the structural diagram of the present invention.
Embodiment 1
Referring to Fig. 1, a kind of transparent flexible battery packaging material, flexible cover sheet 1 uses 12 μm of nylon membrane (PA), adhesive layer 2 use acrylic ester adhesive, and middle layer 3 uses 20 μm of poly (ethylene naphthalate) film (PEN), and special adhesion layer 4 makes With 5 μm of star-like graft modification polypropylene film (MPP), flexibility heat-sealing internal layer 5 uses 45 μm of polyethylene film (PE).
Embodiment 2
Referring to Fig. 1, a kind of transparent flexible battery packaging material, flexible cover sheet 1 using 12 μm ~ 30 μm nylon membrane (PA) or Polyethylene terephthalate film (PET) or polybutylene terephthalate (PBT) film (PBT), adhesive layer 2 use acrylate Adhesive or polyurethane binder, polyimide film (PI) or polyethylene naphthalate of the middle layer 3 using 20 μm ~ 60 μm Film (PEN), special adhesion layer 4 use 5 μm ~ 50 μm of modified polypropene film (MPP), and flexibility heat-sealing internal layer 5 uses 5 μm ~ 80 μm Polypropylene film (PP) or polyethylene film (PE).
Embodiment 3
Referring to Fig. 1, a kind of transparent flexible battery packaging material, flexible cover sheet 1 uses 30 μm of poly terephthalic acid fourth two Alcohol ester film (PBT), adhesive layer 2 use polyurethane binder, and middle layer 3 uses 20 μm of polyimide film (PI), special adhesion Layer 4 uses 5 μm of graft modification modified polypropene film (MPP), and flexibility heat-sealing internal layer 5 uses 80 μm of polypropylene film (PP).
Embodiment 4
Referring to Fig. 1, a kind of transparent flexible battery packaging material, flexible cover sheet 1 uses 25 μm of poly terephthalic acid second two Alcohol ester film (PET), adhesive layer 2 use acrylic ester adhesive, and middle layer 3 uses 50 μm of polyimide film (PI), special viscous Layer 4 is closed using 50 μm of maleic acid glycosides graft modification polypropylene film (MPP), flexibility heat-sealing internal layer 5 is thin using 50 μm of polyethylene Film (PE).
Adhesion-layer materials used in embodiment 1- embodiment 4 can make middle layer and flexible heat-sealing internal layer be bonded together, And it is capable of providing certain isolation performance, there is extremely strong anti-swelling.
Laboratory test data: test condition, crooked process radius R=1.5mm, bend tension tension are 9.8N,
Sample Existing encapsulating material Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4
Number of bends 3000 times 23000 times 30000 times 20000 times 50000 times
State after bending Internal break It is bent spoken parts in an opera trace It is bent spoken parts in an opera trace It is bent spoken parts in an opera trace Fracture
Taking the above-mentioned ideal embodiment according to the present invention as inspiration, through the above description, relevant staff is complete Various changes and amendments can be carried out without departing from the scope of the technological thought of the present invention' entirely.It is all in essence of the invention Within mind and principle, any modification, equivalent substitution, improvement and etc. done be should all be included in the protection scope of the present invention.This The technical scope of item invention is not limited to the contents of the specification, it is necessary to its technology is determined according to scope of the claims Property range.

Claims (10)

1. a kind of transparent flexible battery packaging material, it is characterised in that: described soft including flexible cover sheet and flexible heat-sealing internal layer Property protective layer and flexible heat-sealing internal layer between be provided with middle layer, bonding is provided between the flexible cover sheet and middle layer Layer is provided with adhesive layer between the middle layer and flexible heat-sealing internal layer.
2. a kind of transparent flexible battery packaging material according to claim 1, it is characterised in that: the flexible cover sheet's With a thickness of 12 μm ~ 30 μm.
3. a kind of transparent flexible battery packaging material according to claim 1, it is characterised in that: the flexible cover sheet's Material is nylon membrane, polyethylene terephthalate film or polybutylene terephthalate (PBT) film.
4. a kind of transparent flexible battery packaging material according to claim 1, it is characterised in that: the adhesive layer uses third Olefin(e) acid ester adhesive or polyurethane binder.
5. a kind of transparent flexible battery packaging material according to claim 1, it is characterised in that: the thickness of the middle layer It is 20 μm ~ 60 μm.
6. a kind of transparent flexible battery packaging material according to claim 1, it is characterised in that: the material of the middle layer For polyimide film or poly (ethylene naphthalate) film.
7. a kind of transparent flexible battery packaging material according to claim 1, it is characterised in that: the special adhesion layer With a thickness of 5 μm ~ 50 μm.
8. a kind of transparent flexible battery packaging material according to claim 1, it is characterised in that: the special adhesion layer Material is modified polypropene film.
9. a kind of transparent flexible battery packaging material according to claim 1, it is characterised in that: the flexible heat-sealing internal layer With a thickness of 5 μm ~ 80 μm.
10. a kind of transparent flexible battery packaging material according to claim 1, it is characterised in that: in the flexible heat-sealing The material of layer is polypropylene film or polyethylene film.
CN201910542630.4A 2019-06-21 2019-06-21 A kind of transparent flexible battery packaging material Pending CN110181920A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910542630.4A CN110181920A (en) 2019-06-21 2019-06-21 A kind of transparent flexible battery packaging material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910542630.4A CN110181920A (en) 2019-06-21 2019-06-21 A kind of transparent flexible battery packaging material

Publications (1)

Publication Number Publication Date
CN110181920A true CN110181920A (en) 2019-08-30

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910542630.4A Pending CN110181920A (en) 2019-06-21 2019-06-21 A kind of transparent flexible battery packaging material

Country Status (1)

Country Link
CN (1) CN110181920A (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6455192B1 (en) * 1999-11-09 2002-09-24 Samsung Sdi Co., Ltd. Battery case
CN101197431A (en) * 2005-12-02 2008-06-11 索尼株式会社 Battery pack
TWM449695U (en) * 2012-06-19 2013-04-01 Asia Electronic Material Co Flexible battery packaging material layer structure
CN110077078A (en) * 2019-05-28 2019-08-02 东旭光电科技股份有限公司 Flexible battery packaging film and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6455192B1 (en) * 1999-11-09 2002-09-24 Samsung Sdi Co., Ltd. Battery case
CN101197431A (en) * 2005-12-02 2008-06-11 索尼株式会社 Battery pack
TWM449695U (en) * 2012-06-19 2013-04-01 Asia Electronic Material Co Flexible battery packaging material layer structure
CN110077078A (en) * 2019-05-28 2019-08-02 东旭光电科技股份有限公司 Flexible battery packaging film and preparation method thereof

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Application publication date: 20190830

RJ01 Rejection of invention patent application after publication