CN110178853A - A kind of environmentally protective mineral negative ion sterilizing ball - Google Patents

A kind of environmentally protective mineral negative ion sterilizing ball Download PDF

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Publication number
CN110178853A
CN110178853A CN201910403993.XA CN201910403993A CN110178853A CN 110178853 A CN110178853 A CN 110178853A CN 201910403993 A CN201910403993 A CN 201910403993A CN 110178853 A CN110178853 A CN 110178853A
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China
Prior art keywords
sterilizing
parts
ball
particle
negative ion
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CN201910403993.XA
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Chinese (zh)
Inventor
崔建中
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Baoying Lianhua (xiamen) Biotechnology Co Ltd
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Baoying Lianhua (xiamen) Biotechnology Co Ltd
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Priority to CN201910403993.XA priority Critical patent/CN110178853A/en
Publication of CN110178853A publication Critical patent/CN110178853A/en
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/34Shaped forms, e.g. sheets, not provided for in any other sub-group of this main group
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/16Heavy metals; Compounds thereof
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • C08K2003/0806Silver
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Agronomy & Crop Science (AREA)
  • Toxicology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

A kind of environmentally protective mineral negative ion sterilizing ball, including sterilizing ball ontology and sterilizing coating, sterilizing coating are coated uniformly on the sterilizing ball body surface;The sphere that sterilizes is the smooth metal ball body in surface;The composition of sterilizing coating is as follows according to the mass fraction: 1-5 parts of radium ore particles, 1-5 parts of nano-Ag particles, 1-5 parts of TiO2 particle, 1-5 parts of ZnO particle, 45-50 parts of polyurethanes, 25-35 parts of polystyrene, 5-10 parts of bentonite, 3-19 parts of antioxidant.The sterilizing particle formed using ore particles, nano-Ag particles, TiO2 particle and ZnO particle, has good sterilization effect, and radium ore can discharge anion, be conducive to human lives.Method that the present invention the uses ball obtained that sterilizes, it is environmentally protective, have sterilizing well, sterilization, can negative ion-releasing function, using effect is good, and preparation method of the present invention is simple, environmental friendly, is conducive to environment.

Description

A kind of environmentally protective mineral negative ion sterilizing ball
Technical field
The present invention relates to a kind of environmentally protective mineral negative ion sterilizing balls.
Background technique
Radium ore contains microelement such as zinc, magnesium, manganese, calcium etc. largely beneficial to human body, is a kind of ultra-fine monocrystalline ore, Radium ore can produce 0.06 milliampere of micro-current to match with human body, therefore also known as Tourmaline stone is with calcium carbide.The energy of radium ore Amount releases the elements such as far infrared, anion, sub- ion, bioelectricity, biological magnetic, trace mineral by heating quickly.Radium Ore has good sterilizing, deodorization, eliminates the unusual smell and dirt-removing functions.
Therefore, a small amount of radium ore is applied in daily life, develop it is a kind of environmentally protective and have sterilizing, sterilization, The sterilizing ball that anion can be discharged also more is concerned by people.
Summary of the invention
In view of the above-mentioned problems, the invention proposes a kind of environmentally protective mineral negative ion sterilizing balls.
Specific technical solution is as follows:
A kind of environmentally protective mineral negative ion sterilizing ball, which is characterized in that including sterilizing ball ontology and sterilizing coating, institute It states sterilizing coating and is coated uniformly on the sterilizing ball body surface;The sterilizing sphere is the smooth metal ball body in surface;
The composition of the sterilizing coating is as follows according to the mass fraction:
1-5 parts of radium ore particles, 1-5 parts of nano-Ag particles, 1-5 parts of TiO2 particle, 1-5 parts of ZnO particle, polyurethane 45-50 parts of ester, 25-35 parts of polystyrene, 5-10 parts of bentonite, 3-19 parts of antioxidant.
Further, the sterilizing sphere is stainless steel material.
Further, the partial size of the radium ore particles is 30-60 microns.
Further, the partial size of the nano-Ag particles is 10-60nm.
Further, the TiO2 particle and the ZnO particle are nano-scale particle, and partial size is 100-200 nanometers.
Further, the antioxidant is antioxidant 1010.
A kind of preparation method of environmentally protective mineral negative ion sterilizing ball, which is characterized in that preparation step is as follows:
A. radium ore particles pre-process: pulverize processing to powdered for radium ore particles, pass through multilayer screening plant The radium ore particles for screening out 30-60 micron grain size are spare;
B. particulate matter premixes: radium ore particles, nano-Ag particles, TiO2 particle and ZnO particle are put into premix tooling Premix processing is inside carried out, incorporation time 10min, revolving speed 80r/min obtain sterilizing particle after the completion of mixing;
C. polyurethanes, polystyrene, bentonite, antioxidant and sterilizing particle are placed in reaction kettle and are mixed It closes, incorporation time 1-1.5H, revolving speed 380r/min, sterilization coating is obtained after the completion of mixing;
D. sterilizing ball ontology pretreatment;Sterilizing ball ontology is washed away 3-5 times using deionized water cleaning, is wiped away with dry gauze After surface moisture, is wiped 1-2 times using dehydrated alcohol, complete pretreatment work after surface parches completely;
E. it coats: sterilization coating is coated uniformly on sterilizing ball body surface, sterilization coating coating using the method for spraying With a thickness of 1-1.5mm;
F. baking and curing;Coated sterilizing ball is placed and carries out ultraviolet curing under ultraviolet radiator, when ultraviolet curing Between be 10-20min;Then sterilizing ball is subjected to hot setting, solidification temperature is 80-90 DEG C, curing time 10-20min;With After carry out secondary ultraviolet curing, the secondary ultraviolet curing time is 10-20min;Sterilizing ball is finally carried out secondary high-temperature to consolidate Change, solidification temperature is 80-90 DEG C, curing time 10-20min;It is placed at shady and cool ventilation, naturally cools to after the completion of solidification Finished product can be obtained in room temperature.
The invention has the benefit that
The sterilizing particle formed using ore particles, nano-Ag particles, TiO2 particle and ZnO particle is had good Sterilization effect, radium ore can discharge anion, be conducive to human lives.The method that the present invention the uses ball obtained that sterilizes is green Colour circle protect, have well sterilizing, sterilization, can negative ion-releasing function, using effect is good, and preparation method of the present invention is simple, It is environmental friendly, be conducive to environment.
Detailed description of the invention
Fig. 1 is multistage screening plant diagrammatic cross-section.
Fig. 2 is sieving plate top view.
Fig. 3 is sieving plate A-A to sectional view.
Fig. 4 is premix tooling section schematic internal view.
Fig. 5 is swingle schematic top plan view.
Fig. 6 is curing apparatus schematic diagram.
Fig. 7 solidifies carriage body schematic internal view.
Fig. 8 is ultraviolet radiator in the first mounting plate bottom distribution schematic diagram.
Fig. 9 is electric heating tube in the second mounting plate bottom distribution schematic diagram.
Figure 10 is enlarged diagram at A '.
Specific embodiment
Clear to be more clear technical solution of the present invention, the present invention is described further with reference to the accompanying drawing, The technical characteristic of any pair of technical solution of the present invention carries out the scheme that equivalencing is obtained with conventional reasoning and each falls within guarantor of the present invention Protect range.Fixed setting mentioned in the present embodiment, the connection type being fixedly connected are that welding, screwing, bolt connect The common knowledge known to a person skilled in the art such as connect, this will not be repeated here.
Multistage screening plant, premix tooling and the curing apparatus that the present invention uses are special equipment;
Multistage screening plant, including bracket, four screening framves, four the storage box and a collection box;
The bracket includes bottom plate, sidewall paneling and three support plates;The floor level setting, the bottom plate quantity are One, the bottom plate top side is placed with a storage box, and the other side is placed with a collection box;The bottom plate two respectively connects A sidewall paneling is connect, the sidewall paneling is vertically arranged, and the sidewall paneling bottom is fixedly connected with the bottom plate side, the branch Fagging be it is horizontally disposed, described support plate one end is fixedly connected with the sidewall paneling, and a storage is placed in the support plate Box;
The screening frame includes connecting plate, sieving plate, guide plate and surrounding baffle, the connecting plate, sieving plate, guide plate Be an integral structure, the connecting plate be it is horizontally disposed, the one end of the connection board is fixedly connected with the sidewall paneling, the other end with Described sieving plate one end is fixedly connected;The sieving plate is to be obliquely installed, and multiple screening holes are provided on the sieving plate, described Screening hole is circular through hole structure, and the high one end of the screening Board position is fixedly connected with the connecting plate, the low one end in position It is fixedly connected with the guide plate, the guide plate is to be obliquely installed, the high one end of the guiding Board position and the sieving plate It is fixedly connected;The surrounding baffle is fixedly connected on the sieving plate two sides;
The storage box is located at the sieving plate bottom position;The sieving frame is in two sidewall panelings of the bracket Between up and down be interspersed, position it is next screening frame sieving plate be located above screening frame guide plate bottom;The collection Box is located at the lower position of the guide plate of bottommost screening frame.
Further, further include having limit plate, the limit plate is vertically arranged, be set in addition to top sieve frame with On other outer screening framves, it is fixedly connected at the top of sieving plate described in the limit plate bottom.
Further, mounting table is additionally provided on the sidewall paneling of side, the mounting table is square protruding structure, fixed setting In a sidewall paneling top side, the mounting table is for placing conveying pipeline.
Further, the connecting plate two sides positioned at the screening frame of top are also equipped with surrounding baffle.
Further, screening hole is distributed on the sieving plate in matrix.
Further, guiding raised line is provided on the sieving plate, the guiding raised line is on the sieving plate in longitudinal It is uniformly arranged, the guiding raised line is an integral structure with the sieving plate.
Further, the screening hole size of the two screening framves in top is identical, the screening hole size phase of the two screening framves in bottom Together, the aperture in the screening hole of two, top screening frame is greater than the aperture in the screening hole of the screening frame of bottom two.
Further, the section of the guiding raised line is trapezoidal.
Multistage screening plant makes the material being sized glide automatically using gravity, during downslide, passes through screening In the particles fall to the storage box that hole makes partial size small, the bulky grain not screened out finally is automatically fallen into inside collection box, automatic complete At screening work.Service efficiency is high, does not need additionally to use the energy, energy-saving and emission-reduction, using effect is good.
Tooling, including shell are premixed, there are four support leg, the support leg is to set vertically for the shell surrounding fixed setting It sets, the case top is provided with feed inlet, and the housing bottom is provided with discharge port, which is characterized in that the shell is one Body formula structure, the case top is cylindrical, the housing bottom cone with a narrow upper and lower width, during the enclosure interior is in Sky setting, the case top are provided with rotating electric machine,
The enclosure interior is provided with rotary shaft, the first swingle, the second swingle, third swingle, the 4th swingle, Hook is stirred in stirring block and bottom;The rotary shaft is fixed with the rotating electric machine at the top of the rotary shaft and is connected in being vertically arranged It connects, the case top is run through in the rotary shaft bottom, stretches to the enclosure interior, first swingle, the second rotation Bar, third swingle and the 4th swingle are sequentially distributed from top to bottom in the rotary shaft, first swingle, second Swingle, third swingle and the 4th swingle are horizontally disposed, first swingle, the second swingle, third rotation The length of bull stick and the 4th swingle is successively successively decreased;First swingle, the second swingle, third swingle and the 4th The equal one end of swingle connects the rotary shaft, and the other end connects a stirring block;
The stirring block side be square structure, the other end is the arcwall face being obliquely installed, the arcwall face side close to The enclosure interior lower sides;
Bottom stirring hook is " V " character form structure, is in integral structure, bottom stirring one lateral roof of hook with it is described Rotary shaft bottom is fixedly connected, and the bottom stirring hook quantity is four, and four bottom stirrings are hooked in the rotary shaft bottom Portion is uniformly distributed in circumferential.
Further, the feed inlet quantity is two, is symmetrically disposed on the case top two sides, the discharge port number Amount is one, is set to the housing bottom center, is provided with valve on the discharge port.
Further, the hull outside is fixedly installed connection ring, and the connection ring is cirque structure, the connection Ring is linked in the hull outside upper position, and the bottom of the connection ring surrounding is fixedly connected with the support leg.
Further, the rotary shaft is cylindrical structure.
Further, the quantity of first swingle is four, is uniformly distributed in the rotary shaft in circumferential.
Further, the quantity of second swingle is four, is uniformly distributed in the rotary shaft in circumferential.
Further, the quantity of the third swingle is four, is uniformly distributed in the rotary shaft in circumferential.
Further, the quantity of the 4th swingle is four, is uniformly distributed in the rotary shaft in circumferential.
Tooling is premixed using the setting of multiple groups swingle cooperation stirring block on vertical direction, can be improved internal stirring effect Rate accomplishes to be sufficiently stirred, and enables to radium mineral dust that can be uniformly mixed, and is provided with bottom in bottom and stirs hook, in use, It can be avoided bottommost material to be deposited, improve service efficiency, optimize using effect.
Curing apparatus, including conveyer belt and solidification carriage body, the solidification carriage body side are provided with inlet port, and the other side is set It is equipped with outlet, the conveyer belt enters solidification carriage body from the inlet port, inside solidification carriage body, and from the outlet Solidification carriage body is left, the conveyer belt is for placing sterilizing ball semi-finished product;The solidification carriage body is internally provided with ultraviolet curing The quantity of device and hot setting device, the ultraviolet curing device and the hot setting device is two, in institute State solidification carriage body inside from inlet port to outlet be successively in ultraviolet curing device, hot setting device, ultraviolet curing dress It sets, the arrangement of the sequence of hot setting device;
The ultraviolet curing device includes the first support column, the first mounting plate and ultraviolet radiator.First support Column is vertically arranged, and is fixedly connected at the top of first support column with the solidification carriage body inner top, bottom and described first Mounting plate top center is fixedly connected, first mounting plate be square plate structure, first mounting plate bottom with The ultraviolet radiator is fixedly connected;The ultraviolet radiator quantity is nine, is evenly distributed on first mounting plate bottom surface;
The hot setting device includes the second support column, the second mounting plate and electric heating tube;Second support column Top is fixedly connected with the solidification carriage body inner top, and bottom is fixedly connected with the second mounting plate top center, Second mounting plate is square plate structure, and second mounting plate bottom is fixedly connected with the electric heating tube;The electricity Heating tube is cylindrical structure, and the heating tube quantity is five, and the heating tube is evenly distributed on second mounting plate bottom Portion.
Further, holding tray is provided on the conveyer belt, sterilizing ball semi-finished product are placed on inside the holding tray.Make Used time, holding tray are placed in below the ultraviolet curing device or hot setting device.
Further, described solidify is arranged at least that there are two the observation window that is made of pyroceram, the sights on carriage body It examines window and is symmetricly set on the solidification carriage body two sides, the observation window is square structure.
It further, further include that electric heating pipe mounting seat and electric heating tube installation clip, the electric heating tube are added by electricity Heat pipe mounting base and electric heating tube installation clip are fixed on second mounting plate bottom, and the electric heating mounting base is length Strip structure, top are square structure, and bottom is arc-shaped recess structure, are pacified at the top of the electric heating tube mounting base with described second Loading board is fixedly connected, and bottom fits with the electric heating tube;The electric heating tube installation clip is U-shaped structure, two sides setting Have fixed flanging, be provided with screw hole on the fixed flanging, the electrothermal tube installation clip quantity be it is multiple, be evenly distributed on electricity In heating tube, the electric heating tube installation hoop sleeve is closed in electric heating tube bottom surrounding, passes through fixed flanging by screw On screw hole and be embedded in the second mounting plate bottom, realize the fixation between electric heating tube and second mounting plate.
Further, the electric heating mounting base is made of high temperature resistant heat insulation material.
Further, first support column is cylindrical body.
Further, second support column is cylindrical body.
Further, the ultraviolet radiator is distributed in first mounting plate bottom in 3*3 matrix.
Control timing moving conveyor belt mentioned by curing apparatus, timing controlled can be artificial start and stop conveyer belt herein, It is also possible to additional PLC controller to be controlled, is the technological means that the prior art can be completed, this will not be repeated here.
Mentioned high temperature resistant heat insulation material mentioned by curing apparatus is that high temperature resistant heat insulation cotton or aluminum silicate ceramic are fine Heat insulating mattress is tieed up, the above material can be directly enough on the market, and this will not be repeated here.
Curing apparatus uses special solidification carriage body structure, while the ultraviolet radiator that uses and high temperature electric heating tube Structure, it is only necessary in use, serialization curing process can be realized in control timing moving conveyor belt, avoid and semi-finished product sterilize The process that ball is converted between different devices back and forth, service efficiency are high.
Embodiment 1
A kind of preparation method of environmentally protective mineral negative ion sterilizing ball, which is characterized in that preparation step is as follows:
A. radium ore particles pre-process: pulverize processing to powdered for radium ore particles, pass through multilayer screening plant The radium ore particles for screening out 30-60 micron grain size are spare;
B. particulate matter premixes: radium ore particles, nano-Ag particles, TiO2 particle and ZnO particle are put into premix tooling Premix processing is inside carried out, incorporation time 10min, revolving speed 80r/min obtain sterilizing particle after the completion of mixing;
C. polyurethanes, polystyrene, bentonite, antioxidant and sterilizing particle are placed in reaction kettle and are mixed It closes, incorporation time 1.5H, revolving speed 380r/min, sterilization coating is obtained after the completion of mixing;
D. sterilizing ball ontology pretreatment;Sterilizing ball ontology is washed away 5 times using deionized water cleaning, wipes table away with dry gauze After the moisture of face, is wiped 2 times using dehydrated alcohol, complete pretreatment work after surface parches completely;
E. it coats: sterilization coating is coated uniformly on sterilizing ball body surface, sterilization coating coating using the method for spraying With a thickness of 1-1.5mm;
F. baking and curing;Coated sterilizing ball is placed and carries out ultraviolet curing under ultraviolet radiator, when ultraviolet curing Between be 20min;Then sterilizing ball is subjected to hot setting, solidification temperature is 90 DEG C, curing time 20min;Then carry out two Secondary ultraviolet curing, secondary ultraviolet curing time are 20min;Sterilizing ball is finally subjected to secondary high-temperature solidification, solidification temperature It is 90 DEG C, curing time 20min;It is placed at shady and cool ventilation after the completion of solidification, naturally cooling to room temperature can be obtained finished product.
The composition of the sterilizing coating is as follows according to the mass fraction:
5 parts of radium ore particles, 5 parts of nano-Ag particles, 5 parts of TiO2 particle, 5 parts of ZnO particle, 50 parts of polyurethanes, 35 parts of polystyrene, 10 parts of bentonite, 19 parts of antioxidant.
Further, the sterilizing sphere is stainless steel material.
Further, the partial size of the radium ore particles is 60 microns.
Further, the partial size of the nano-Ag particles is 60nm.
Further, the TiO2 particle and the ZnO particle are nano-scale particle, and partial size is 200 nanometers.
Further, the antioxidant is antioxidant 1010.
Embodiment 2
Compared with Example 1, this embodiment differs from embodiment 1 in that,
The composition of the sterilizing coating is as follows according to the mass fraction:
1 part of radium ore particles, 1 part of nano-Ag particles, 1 part of TiO2 particle, 1 part of ZnO particle, 45 parts of polyurethanes, 25 parts of polystyrene, 5 parts of bentonite, 3 parts of antioxidant.
Further, the partial size of the radium ore particles is 30 microns.
Further, the partial size of the nano-Ag particles is 10nm.
Further, the TiO2 particle and the ZnO particle are nano-scale particle, and partial size is 100 nanometers.
Embodiment 3
Compared with Example 1, this embodiment differs from embodiment 1 in that,
The composition of the sterilizing coating is as follows according to the mass fraction:
2 parts of radium ore particles, 3 parts of nano-Ag particles, 4 parts of TiO2 particle, 2 parts of ZnO particle, 48 parts of polyurethanes, 28 parts of polystyrene, 8 parts of bentonite, 12 parts of antioxidant.
Further, the partial size of the radium ore particles is 35 microns.
Further, the partial size of the nano-Ag particles is 45nm.
Further, the TiO2 particle and the ZnO particle are nano-scale particle, and partial size is 120 nanometers.
Description of symbols
Multistage screening plant 1, bracket 11, bottom plate 111, sidewall paneling 112, support plate 113, screening frame 12, connecting plate 121, Sieving plate 122, guiding raised line 1221, guide plate 123., surrounding baffle 124, the storage box 13, collection box 14, screening hole 15, limit plate 16, mounting table 17, conveying pipeline 18
Premix tooling 2, shell 21, connection ring 211, support leg 22, feed inlet 23, discharge port 24, valve 241, electric rotating Machine 25, rotary shaft 26, the first swingle 261, the second swingle 262, third swingle the 263, the 4th rotate 264, stirring block 265, hook 266 is stirred in arcwall face 2651, bottom.
Curing apparatus 3, conveyer belt 31, holding tray 311, solidification carriage body 32, inlet port 321, outlet 322, observation window 323, ultraviolet curing device 33, the first support column 331, the first mounting plate 332, ultraviolet radiator 333, hot setting device 34, Second support column 341, the second mounting plate 342, electric heating tube 343, electric heating pipe mounting seat 35, arc-shaped recess 351, electric heating tube peace Be loaded hoop 36, fixed flanging 361, screw 37.

Claims (7)

1. a kind of environmentally protective mineral negative ion sterilizing ball, which is characterized in that described including sterilizing ball ontology and sterilizing coating Sterilizing coating is coated uniformly on the sterilizing ball body surface;The sterilizing sphere is the smooth metal ball body in surface;
The composition of the sterilizing coating is as follows according to the mass fraction:
1-5 parts of radium ore particles, 1-5 parts of nano-Ag particles, 1-5 parts of TiO2 particle, 1-5 parts of ZnO particle, polyurethanes 45-50 parts, 25-35 parts of polystyrene, 5-10 parts of bentonite, 3-19 parts of antioxidant.
2. a kind of environmentally protective mineral negative ion sterilizing ball as described in claim 1, it is characterized in that, the sterilizing sphere is not Rust steel material.
3. a kind of environmentally protective mineral negative ion sterilizing ball as claimed in claim 1 or 2, it is characterized in that, the radium ore The partial size of grain is 30-60 microns.
4. a kind of environmentally protective mineral negative ion sterilizing ball as claimed in claim 1 or 2, it is characterized in that, the nano silver The partial size of grain is 10-60nm.
5. a kind of environmentally protective mineral negative ion sterilizing ball as claimed in claim 1 or 2, it is characterized in that, the TiO2 particle It is nano-scale particle with the ZnO particle, partial size is 100-200 nanometers.
6. a kind of environmentally protective mineral negative ion sterilizing ball as claimed in claim 1 or 2, it is characterized in that, the antioxidant is Antioxidant 1010.
7. a kind of preparation method of environmentally protective mineral negative ion sterilizing ball, which is characterized in that preparation step is as follows:
A. radium ore particles pre-process: pulverize processing to powdered for radium ore particles, sieved by multilayer screening plant The radium ore particles of 30-60 micron grain size are spare out;
B. particulate matter premix: by radium ore particles, nano-Ag particles, TiO2 particle and ZnO particle be put into premix tooling in into The processing of row premix, incorporation time 10min, revolving speed 80r/min obtain sterilizing particle after the completion of mixing;
C. polyurethanes, polystyrene, bentonite, antioxidant and sterilizing particle are placed in reaction kettle and are mixed, mixed The conjunction time is 1-1.5H, revolving speed 380r/min, and sterilization coating is obtained after the completion of mixing;
D. sterilizing ball ontology pretreatment;Sterilizing ball ontology is washed away 3-5 times using deionized water cleaning, wipes surface away with dry gauze After moisture, is wiped 1-2 times using dehydrated alcohol, complete pretreatment work after surface parches completely;
E. it coats: sterilization coating is coated uniformly on sterilizing ball body surface, sterilization coating coating thickness using the method for spraying For 1-1.5mm;
F. baking and curing;Coated sterilizing ball is placed and carries out ultraviolet curing under ultraviolet radiator, the ultraviolet curing time is 10-20min;Then sterilizing ball is subjected to hot setting, solidification temperature is 80-90 DEG C, curing time 10-20min;With laggard The secondary ultraviolet curing of row, secondary ultraviolet curing time are 10-20min;Sterilizing ball is finally subjected to secondary high-temperature solidification, Gu Changing temperature is 80-90 DEG C, curing time 10-20min;It is placed at shady and cool ventilation after the completion of solidification, naturally cools to room temperature Finished product can be obtained.
CN201910403993.XA 2019-05-16 2019-05-16 A kind of environmentally protective mineral negative ion sterilizing ball Pending CN110178853A (en)

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Publication number Priority date Publication date Assignee Title
JPH02101003A (en) * 1988-10-11 1990-04-12 Nippon Foil Mfg Co Ltd Antibacterial film
CN103964826A (en) * 2014-04-08 2014-08-06 安徽省亚欧陶瓷有限责任公司 Ceramic tile containing radium stone powder and preparation method of ceramic tile
CN105883986A (en) * 2014-10-26 2016-08-24 重庆鼎升生物科技有限公司 Biological ceramic sterilizing ball
CN109535807A (en) * 2018-12-12 2019-03-29 英德市雅家涂料有限公司 A kind of composite Nano inorganic antiseptic and the antifreeze finishing coat of nano antibacterial water woodenware paint and preparation method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02101003A (en) * 1988-10-11 1990-04-12 Nippon Foil Mfg Co Ltd Antibacterial film
CN103964826A (en) * 2014-04-08 2014-08-06 安徽省亚欧陶瓷有限责任公司 Ceramic tile containing radium stone powder and preparation method of ceramic tile
CN105883986A (en) * 2014-10-26 2016-08-24 重庆鼎升生物科技有限公司 Biological ceramic sterilizing ball
CN109535807A (en) * 2018-12-12 2019-03-29 英德市雅家涂料有限公司 A kind of composite Nano inorganic antiseptic and the antifreeze finishing coat of nano antibacterial water woodenware paint and preparation method thereof

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