CN110172200A - A kind of packaging film of cold soluble solution - Google Patents

A kind of packaging film of cold soluble solution Download PDF

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Publication number
CN110172200A
CN110172200A CN201910598235.8A CN201910598235A CN110172200A CN 110172200 A CN110172200 A CN 110172200A CN 201910598235 A CN201910598235 A CN 201910598235A CN 110172200 A CN110172200 A CN 110172200A
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CN
China
Prior art keywords
packaging film
accounting
packaging
cold soluble
soluble solution
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910598235.8A
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Chinese (zh)
Inventor
欧发刚
朱文军
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JIANGSU UPASS MATERIAL TECHNOLOGY Co Ltd
Original Assignee
JIANGSU UPASS MATERIAL TECHNOLOGY Co Ltd
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Filing date
Publication date
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Publication of CN110172200A publication Critical patent/CN110172200A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04Homopolymers or copolymers of ethene
    • C08J2323/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04Homopolymers or copolymers of ethene
    • C08J2323/08Copolymers of ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/04Homopolymers or copolymers of ethene
    • C08J2423/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/04Homopolymers or copolymers of ethene
    • C08J2423/08Copolymers of ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2453/00Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
    • C08J2453/02Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers of vinyl aromatic monomers and conjugated dienes

Abstract

The invention discloses a kind of packaging films of cold soluble solution, the raw material of the packaging film includes low density polyethylene (LDPE), ethylene-vinyl acetate copolymer, styrene-isoprene-phenylethene and s-B-S, wherein, it is calculated by mass percentage, low density polyethylene (LDPE) accounting 40-75%, ethylene-vinyl acetate copolymer accounting 20-45%, styrene-isoprene-phenylethene accounting 5-15%, s-B-S accounting 5-15%.By above-mentioned, the packaging film of cold soluble solution provided by the invention may replace traditional release paper and release film packaging, the packaging for being directly used in hot melt blob of viscose has saved resource without being coated with mould release, packaging film can be dissolved completely in hot melt adhesive, No Assets waste, it is easy to operate, it is high in machining efficiency, it is a kind of green and pollution-free product, so that hot melt adhesive is not necessarily to too high temperature when in use, greatly reduce energy consumption, saves cost.

Description

A kind of packaging film of cold soluble solution
Technical field
The present invention relates in the technical field of packaging film, more particularly to a kind of packaging film of cold soluble solution.
Background technique
Since eighties of last century the eighties, world's adhesives industries towards save the energy, nuisanceless, inexpensive and high-performance side To development, solvent-free environmental-protection type adhesive has become the mainstream of gluing industrial development, and hot melt adhesive is exactly one kind without molten Agent with thermoplastic polymer (resin, rubber) be base-material solid adhesive, it be bonding rapidly, wide application, nonhazardous, Free of contamination environmental-protection type adhesive, hot melt adhesive comply with the needs of the times, be the world today's adhesive development a direction, nearly ten Nian Lai, hot melt adhesive industry enter the fast-developing phase, and yield is increased with annual 20% speed, are with fastest developing speed in adhesive One of kind.
The packaging of hot melt blob of viscose generally uses release paper or PET release film at present, this manner of packing: 1. release packing timbers Expect at high cost, the wasting of resources;2. hot melt blob of viscose needs first to remove packaging when in use, cumbersome, production efficiency is low;3. having used Afterwards, release paper is difficult to recycle, and PET release film cannot recycle, and discarding causes environmental pollution;4. separated type material is in summer In the higher situation of temperature, the risk for having stripping too busy to get away is scrapped once tearing to get off and will result in hot melt adhesive.
Summary of the invention
The invention mainly solves the technical problem of providing a kind of packaging film of cold soluble solution, may replace traditional release Paper and release film packaging, the packaging for being directly used in hot melt blob of viscose have saved resource, packaging film can be complete without being coated with mould release It being dissolved in hot melt adhesive, No Assets waste is easy to operate, and it is high in machining efficiency, it is a kind of green and pollution-free product, makes to heat Glue is not necessarily to too high temperature when in use, greatly reduces energy consumption, has saved cost.
In order to solve the above technical problems, one technical scheme adopted by the invention is that: provide a kind of cold soluble solution Packaging film, the raw material of the packaging film include low density polyethylene (LDPE), ethylene-vinyl acetate copolymer, styrene-isoamyl two Alkene-styrene and s-B-S, wherein be calculated by mass percentage, low density polyethylene (LDPE) accounting 40- 75%, ethylene-vinyl acetate copolymer accounting 20-45%, styrene-isoprene-phenylethene accounting 5-15%, styrene-fourth two Alkene-styrene accounting 5-15%, wherein the melting range of the low density polyethylene (LDPE) is between 110-130 DEG C.
In a preferred embodiment of the present invention, the melting range of the packaging film is between 90-110 DEG C.
In a preferred embodiment of the present invention, the packaging film is processed using coextrusion film blowing technique.
In a preferred embodiment of the present invention, the color of the packaging film is transparent.
In a preferred embodiment of the present invention, the packaging film with a thickness of 0.06-0.08mm.
The beneficial effects of the present invention are: the packaging film of cold soluble solution of the invention, may replace traditional release paper and from Type film packaging, the packaging for being directly used in hot melt blob of viscose have saved resource, packaging film can be dissolved completely in without being coated with mould release In hot melt adhesive, No Assets waste is easy to operate, high in machining efficiency, is a kind of green and pollution-free product, makes hot melt adhesive Used time is not necessarily to too high temperature, greatly reduces energy consumption, has saved cost.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation Example is only a part of the embodiments of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common Technical staff's all other embodiment obtained without making creative work belongs to the model that the present invention protects It encloses.
The embodiment of the present invention includes:
A kind of packaging film of cold soluble solution, the raw material of the packaging film include low density polyethylene (LDPE) (LDPE), ethyl vinyl acetate Ethylene copolymer (EVA), styrene-isoprene-phenylethene (SIS) and s-B-S (SBS), In, it is calculated by mass percentage, low density polyethylene (LDPE) accounting 40-75%, ethylene-vinyl acetate copolymer accounting 20-45%, benzene Ethylene-isoprene styrene accounting 5-15%, s-B-S accounting 5-15%.
Further, the packaging film is processed into using coextrusion film blowing technique, and selection low density polyethylene (LDPE) is major ingredient, The lower ethylene-vinyl acetate copolymer of fusing point is added between 110-130 DEG C in the melting range of low density polyethylene (LDPE), and The thermoplastic elastomer of styrene-isoprene-phenylethene and s-B-S with unsaturated interlude into Row is modified, and the solution temperature of packaging film made of doing is made to be reduced to 90-110 DEG C, reduces Energy in use.
Formula materials itself are the raw material of hot melt adhesive among the above, reduce solution temperature by modified, the packaging Film can be completely dissolved in 90-110 DEG C of temperature range, guarantee that it can be dissolved completely in hot melt adhesive, free from admixture residual.This makes heat Melten gel is not necessarily to too high temperature when in use, greatly reduces energy consumption, has saved cost.
The technical parameter of the packaging film of cold soluble solution provided by the invention:
The packaging film of cold soluble solution provided by the invention compared with the prior art, has the advantages that
1) packaging for being directly used in hot melt blob of viscose has saved resource without being coated with mould release;
2) hot melt blob of viscose is not necessarily to removing packaging when in use, and directly whole to dissolve, packaging film is dissolved in glue, easy to operate, no wave Take, is pollution-free, no removing risk;
3) hot melt adhesive is low (90-110 DEG C) using solution temperature, and production energy consumption is low.
In conclusion the packaging film of cold soluble solution of the invention, may replace traditional release paper and release film packaging, directly The packaging for heating blob of viscose is connect, without being coated with mould release, has saved resource, packaging film can be dissolved completely in hot melt adhesive, nothing The wasting of resources, it is easy to operate, it is high in machining efficiency, it is a kind of green and pollution-free product, is not necessarily to hot melt adhesive when in use too High temperature, greatly reduces energy consumption, has saved cost.
The above description is only an embodiment of the present invention, is not intended to limit the scope of the invention, all to utilize this hair Equivalent structure or equivalent flow shift made by bright description is applied directly or indirectly in other relevant technology necks Domain is included within the scope of the present invention.

Claims (5)

1. a kind of packaging film of cold soluble solution, which is characterized in that the raw material of the packaging film includes low density polyethylene (LDPE), second Alkene-acetate ethylene copolymer, styrene-isoprene-phenylethene and s-B-S, wherein according to matter It measures percentage to calculate, low density polyethylene (LDPE) accounting 40-75%, ethylene-vinyl acetate copolymer accounting 20-45%, styrene-isoamyl Styrene accounting 5-15%, s-B-S accounting 5-15%, wherein the low density polyethylene (LDPE) Melting range is between 110-130 DEG C.
2. the packaging film of cold soluble solution according to claim 1, which is characterized in that the melting range of the packaging film Between 90-110 DEG C.
3. the packaging film of cold soluble solution according to claim 1, which is characterized in that the packaging film is blown using co-extrusion Membrane process processing.
4. the packaging film of cold soluble solution according to claim 1, which is characterized in that the color of the packaging film is It is bright.
5. the packaging film of cold soluble solution according to claim 1, which is characterized in that the packaging film with a thickness of 0.06-0.08mm。
CN201910598235.8A 2018-08-10 2019-07-04 A kind of packaging film of cold soluble solution Pending CN110172200A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN2018109059668 2018-08-10
CN201810905966 2018-08-10

Publications (1)

Publication Number Publication Date
CN110172200A true CN110172200A (en) 2019-08-27

Family

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Application Number Title Priority Date Filing Date
CN201910598235.8A Pending CN110172200A (en) 2018-08-10 2019-07-04 A kind of packaging film of cold soluble solution

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5373682A (en) * 1992-05-18 1994-12-20 National Starch And Chemical Investment Holding Corporation Method for tackless packaging of hot melt adhesives
CN101094791A (en) * 2004-10-29 2007-12-26 伯斯蒂克公司 Process for packaging plastic materials like hot melt adhesives
CN103183897A (en) * 2013-04-11 2013-07-03 无锡市万力粘合材料有限公司 Coating film combination for hot melt adhesive and preparation method thereof
CN104334618A (en) * 2012-05-17 2015-02-04 汉高美国知识产权有限责任公司 Integral hot melt adhesive packaging films and use thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5373682A (en) * 1992-05-18 1994-12-20 National Starch And Chemical Investment Holding Corporation Method for tackless packaging of hot melt adhesives
CN101094791A (en) * 2004-10-29 2007-12-26 伯斯蒂克公司 Process for packaging plastic materials like hot melt adhesives
CN104334618A (en) * 2012-05-17 2015-02-04 汉高美国知识产权有限责任公司 Integral hot melt adhesive packaging films and use thereof
CN103183897A (en) * 2013-04-11 2013-07-03 无锡市万力粘合材料有限公司 Coating film combination for hot melt adhesive and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
冯孝中 主编: "《高分子材料》", 28 February 2007, 哈尔滨工业大学出版社 *

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Application publication date: 20190827