CN1101628A - Slurry acidifying and hydrolyzing three phase biological treatment method at normal at mospheric temperature - Google Patents

Slurry acidifying and hydrolyzing three phase biological treatment method at normal at mospheric temperature Download PDF

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Publication number
CN1101628A
CN1101628A CN94113963A CN94113963A CN1101628A CN 1101628 A CN1101628 A CN 1101628A CN 94113963 A CN94113963 A CN 94113963A CN 94113963 A CN94113963 A CN 94113963A CN 1101628 A CN1101628 A CN 1101628A
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China
Prior art keywords
waste water
mud
excess sludge
under
treatment
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Pending
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CN94113963A
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Chinese (zh)
Inventor
陈季华
奚旦立
刘振鸿
姜佩华
丁珊行
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CHINESE TEXTILE UNIV
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CHINESE TEXTILE UNIV
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Application filed by CHINESE TEXTILE UNIV filed Critical CHINESE TEXTILE UNIV
Priority to CN94113963A priority Critical patent/CN1101628A/en
Publication of CN1101628A publication Critical patent/CN1101628A/en
Pending legal-status Critical Current

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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/20Sludge processing

Abstract

The invention is specially applicable to treatment of waste water of caprolactam from the synthetic fibre mill and also from food processing plant. The waste residue, first treated in acid hydrolysis trough, is led to the eobiont waste water treatment system for 3-phase biological treatment, thereafter, the clear water is drained and the waste mud is returned to the aeration pool and the residue mud, after being concentrated, is sent to the acid hydrolysis trough. In this way, no waste mud need be discharged. It raises the rate of purification and the rate of CODcr removal from 70% to 80-98.2%.

Description

Slurry acidifying and hydrolyzing three phase biological treatment method at normal at mospheric temperature
The present invention is an a kind of novel process of administering the wastewater treatment plant excess sludge with normal temperature acidification hydrolization-three-phase biologic treatment process.Be specially adapted to handle the caprolactam waste water that produces in chemical fibre factory's polyamide fibre 6 production processes.
The excess sludge of waste water treatment plant can't dewater because of its thickness, can not adopt general method of chemical treatment.The mud stabilizing treatment of developed countries such as current Japanese America and Europe mostly adopts anaerobic digestion process, traditional anaerobic digestion process is the operational administrative complexity not only, and the solid matter residence time need 20 days, add aerogenesis fire-fighting requirement, general plant effluent treatment station is difficult to realize.And along with the raising to heavy metal content and hygienic requirements in the agricultural mud, the agricultural amount of its mud is subjected to certain limitation, adopts landfill as Japan, and is inaccurate agricultural; U.S. EPA regulation mud agricultural standards is 35~50 ℃ of temperature, and hydraulic detention time 15 days, VS are degraded and reached 38% at least, and the sludge treatment expense accounts for 100% of sewage disposal expense.So in recent years, the U.S. and Japan take much count of the research of anaerobic sludge digestion, attempt to find out a kind of organic removal rate height, the operating load height, and aspects such as good stability and the deactivation of pathogeny bacterium are better than traditional anaerobic digestion process.Studying more is diphasic anaerobic technique, thinks a kind of sludge stabilizing New Process for Treatment likely, but does not see industrial applications as yet.Domestic sludge stabilizing is handled and still is in the starting stage.The inventor handles at methanol rectified raffinate, antibiotic pharmaceutical wastewater is handled, and the fishery products wastewater treatment (CN92108434. *, 93112446.8) the double oxygen one aerobic treatment high density of employing, the organic waste water of difficult degradation.
The novel process that the object of the present invention is to provide a kind of organic sludge to handle.Adopt normal temperature acidification hydrolization groove series connection aeration tank, organic metabolism in mud metabolism and the waste water is combined in same system, same device, finish the purification of organic waste water, eliminated excess sludge simultaneously.
The inventive method provides the particularly bioremediation of excess sludge after polyamide fibre 6 biological wastewater treatment of a kind of organic sludge, its main technique route is, organic sludge concentration 17~28 grams per liters, VSS/SS93.5~99.9%, the pH value is 7~7.5 excess sludge, enter the oxygen acidification hydrolization groove of holding concurrently, low-speed agitator is set in the groove to be stirred, to improve hydrolysis rate, prevent mud knot cake, mud was in 25~30 ℃ of following hydraulic retentions 24~25 hours, and acidification hydrolization is 5.2 to the pH value under the effect of the oxygen animalcule of holding concurrently, enter original biological treatment waste water system then, in equalizing tank, mix, enter the aeration tank by the ratio of mixture 1~1.5: 250 of mud and waste water, under the revolution of aeration impeller with caprolactam waste water or food wastewater, air, mud, the waste water thorough mixing, under the aerobic microbiological effect, adsorb-absorb-metabolism-synthesize, discharge clear liquor, mud is back to the aeration tank, and excess sludge is got back to the oxygen acidification hydrolization groove of holding concurrently after concentrating.
Double oxygen acidification hydrolization groove in the inventive method is open in air, because sludge concentration height to 17~28 grams per liters, mud just under anoxia condition because acidification hydrolization is carried out in the effect of a series of heterotroph acid formerss, be converted into organic acid, alcohol, carbonic acid gas etc., molecular weight reduces.So can with waste water metabolism in same system, the oxygen acidification hydrolization groove of holding concurrently is connected in series in the protista treatment system of caprolactam or food wastewater.Metabolism simultaneously under the effect of mud and waste water aerobic microbiological in the aeration tank reaches the purpose of purification of waste water.
Advantage of the present invention is that sludge retention time only is 1.25 days, the purification rate 80~98.2% of CODcr, and need not to add any pharmaceutical chemicals, energy consumption is low, flow process is simple, except that the acidification hydrolization groove that to set up a volume be aerobic biochemical treatment device 1/100, if with original sewage disposal networking, convenient management.Fig. 1 is a process flow sheet of the present invention, accompanying drawing is used to describe main flow process proposed by the invention, the excess sludge 1 that produces in the Waste Water Treatment, enter the oxygen acidification hydrolization groove 2 of holding concurrently, at low speed impeller 2(1) carry out acidification hydrolization under stirring, the equalizing tank 4 that flows into then in the wastewater treatment mixes with waste water 3, mixing the back mixed solution promotes by lift pump 5, enter aeration tank 7, enter settling tank 8 then, outside clear liquor 12 outflow systems, precipitating sludge 9 enters sludge sump 10, most of mud 1(1) be promoted to the aeration tank by sludge reflux pump 11, excess sludge 1 is got back in the acidification reactor 2.
Enumerate below and implement object lesson of the present invention:
Example 1: the excess sludge of certain caprolactam Waste Water Treatment the results are shown in Table 1 through this flow processing.
Example 2: the excess sludge of certain dairy plant's Waste Water Treatment the results are shown in Table 2 through this flow processing.
Table 1
Project CODcr mg/1 Mud: waste water
Water inlet Water outlet
This technology 1600 64.45 6∶1000
Clearance (%) 95.97
Table 2
Project CODcr mg/1 Mud: waste water
Water inlet Water outlet
This technology 1495 40 4∶1000
Clearance (%) 97.32

Claims (2)

1, a kind of bioremediation of excess sludge, it is characterized in that organic sludge concentration 17~28 grams per liters, VSS/SS93.5~99.9%, the pH value is that 7~7.5 excess sludge enters the double oxygen acidification hydrolization groove under the stirring at low speed, mud was in 25~30 ℃ of following hydraulic retentions 24~25 hours, acidification hydrolization is 5.2 to the pH value under the effect of the oxygen animalcule of holding concurrently, enter original biological treatment waste water system then, in equalizing tank, mix with hexanolactam waste water, ratio of mixture 1~1.5 by mud and waste water: 250 enter the aeration tank, under the revolution of aeration impeller, air, mud, the waste water thorough mixing is under the aerobic microbiological effect, adsorb-absorb-metabolism-synthesize, discharge clear liquor, mud is back to the aeration tank, and excess sludge is got back to the oxygen acidification hydrolization groove of holding concurrently after concentrating.
2, the bioremediation of excess sludge according to claim 1, it is characterized in that waste water also can be food wastewater.
CN94113963A 1994-10-27 1994-10-27 Slurry acidifying and hydrolyzing three phase biological treatment method at normal at mospheric temperature Pending CN1101628A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN94113963A CN1101628A (en) 1994-10-27 1994-10-27 Slurry acidifying and hydrolyzing three phase biological treatment method at normal at mospheric temperature

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN94113963A CN1101628A (en) 1994-10-27 1994-10-27 Slurry acidifying and hydrolyzing three phase biological treatment method at normal at mospheric temperature

Publications (1)

Publication Number Publication Date
CN1101628A true CN1101628A (en) 1995-04-19

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CN94113963A Pending CN1101628A (en) 1994-10-27 1994-10-27 Slurry acidifying and hydrolyzing three phase biological treatment method at normal at mospheric temperature

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CN (1) CN1101628A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100418903C (en) * 2004-08-07 2008-09-17 安徽建筑工业学院 Tech. for treating urban sewage by complete mixed hydrolytic acidify
CN101693576B (en) * 2009-10-22 2011-05-11 燕山大学 Technology for rapidly treating domestic sewage discharged without residual mud by second-stage adsorption
WO2011066736A1 (en) * 2009-12-01 2011-06-09 Li Jinmin Sludge treatment method and apparatus thereof and application to wastewater bio-treatment
CN102108000A (en) * 2011-01-12 2011-06-29 中国海洋石油总公司 Biological treatment method of oilfield drilling waste
CN105000765A (en) * 2015-08-05 2015-10-28 天紫环保产业开发有限责任公司 Sludge acidification fermentation treatment system
CN109987794A (en) * 2019-04-25 2019-07-09 云南今业生态建设集团有限公司 A kind of chemical fibre factory's sewage disposal system

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100418903C (en) * 2004-08-07 2008-09-17 安徽建筑工业学院 Tech. for treating urban sewage by complete mixed hydrolytic acidify
CN101693576B (en) * 2009-10-22 2011-05-11 燕山大学 Technology for rapidly treating domestic sewage discharged without residual mud by second-stage adsorption
WO2011066736A1 (en) * 2009-12-01 2011-06-09 Li Jinmin Sludge treatment method and apparatus thereof and application to wastewater bio-treatment
CN102149645A (en) * 2009-12-01 2011-08-10 李进民 Sludge treatment method and apparatus thereof and application to wastewater bio-treatment
CN102149645B (en) * 2009-12-01 2011-11-16 李进民 Sludge treatment method and apparatus thereof and application to wastewater bio-treatment
JP2013512096A (en) * 2009-12-01 2013-04-11 リ、ジンミン Sludge treatment method using sludge biological treatment method, and sludge treatment apparatus and apparatus
US8932466B2 (en) 2009-12-01 2015-01-13 Jinmin Li Method and apparatus for sluge treatment and use thereof in sewage biotreatment
EA024049B1 (en) * 2009-12-01 2016-08-31 Цзиньминь Ли Sludge treatment method and apparatus and application of said method and apparatus for wastewater bio-treatment
CN102108000A (en) * 2011-01-12 2011-06-29 中国海洋石油总公司 Biological treatment method of oilfield drilling waste
CN102108000B (en) * 2011-01-12 2012-11-14 中国海洋石油总公司 Biological treatment method of oilfield drilling waste
CN105000765A (en) * 2015-08-05 2015-10-28 天紫环保产业开发有限责任公司 Sludge acidification fermentation treatment system
CN109987794A (en) * 2019-04-25 2019-07-09 云南今业生态建设集团有限公司 A kind of chemical fibre factory's sewage disposal system

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