CN110158075A - A kind of patch and its application method for the processing of austenite stainless steel workpiece surface - Google Patents
A kind of patch and its application method for the processing of austenite stainless steel workpiece surface Download PDFInfo
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- CN110158075A CN110158075A CN201910385132.3A CN201910385132A CN110158075A CN 110158075 A CN110158075 A CN 110158075A CN 201910385132 A CN201910385132 A CN 201910385132A CN 110158075 A CN110158075 A CN 110158075A
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- patch
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- gel layer
- sealer
- passivator
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/48—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 not containing phosphates, hexavalent chromium compounds, fluorides or complex fluorides, molybdates, tungstates, vanadates or oxalates
- C23C22/50—Treatment of iron or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/73—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals characterised by the process
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/78—Pretreatment of the material to be coated
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/82—After-treatment
- C23C22/83—Chemical after-treatment
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- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention relates to a kind of patches and its application method for the processing of austenite stainless steel workpiece surface.The patch for the processing of austenite workpiece surface, comprising: the first patch, the second patch, third patch;First patch, the second patch, third patch are the substrate with gel layer;Wherein: the gel layer of first patch contains cleaning agent;The gel layer of second patch contains passivator;The gel layer of the third patch contains sealer.The case where present invention realizes that the corrosion resistant surfaces to large scale, special-shaped austenite workpiece are handled by using the combination of three kinds of patches containing different disposal agent, avoids inorganic agent flowing dispersion in conventional method;Under the cooperation of three kinds of inorganic agents, the preservative treatment effect of austenite workpiece is significantly improved.
Description
Technical field
The invention belongs to material atmospheric corrosion studying technological domains, and in particular to one kind is used for austenite stainless steel workpiece table
The patch and its application method of surface treatment.
Background technique
The etching problem of metal material and its workpiece spreads the every field of national economy, and resulting loss accounts for about gold
Belong to 50% or more of year loss amount, and other than huge economic loss, it also will cause many catastrophic failures.Therefore to gold
Belong to material and its workpiece progress anti-corrosion protection processing is significant.
There are many kinds of existing anti-corrosion protection measures, and wherein passivation protection has very important status, and is passivated
Processing goes to contact to start the cleaning processing, and Seal treatment is also carried out after Passivation Treatment.
It industrially commonly uses passivator (mainly oxidant) and processing is passivated to metal, form layer protecting film.With
Traditional physical containment method is compared, and is had the characteristics that not increase thickness of workpiece after Passivation Treatment and is changed color, improves product
Precision and added value, make more convenient operation;Secondly, oxygen minor structure passivating film, film that passivation promotes metal surface to be formed
Layer is fine and close, performance is stablized, and has self-repair function simultaneously in air, therefore the method phase with traditional painting antirust oil
, more corrosion resistance more more stable than, the passivating film for being passivated formation.
For workpiece in practical Passivation Treatment, surface can be because there is the pollutant effects Passivation Treatment effect such as grease to need to carry out
Cleaning carries out acid wash passivation processing, carries out the post-processing such as closing after pickling, dissimilar metal is avoided to contact with nonmetallic after cleaning
Equal destructions are passivated protection effect.
In the industrial production, certain austenitic stainless steel materials or workpiece are in molding or after processing is completed, traditional chemistry
Processing technique is not able to satisfy the requirement of actual condition, for example, on the one hand establishing large-scale for the solder joint Passivation Treatment of larger workpiece
Treatment trough will greatly increase production cost, influence production efficiency, do not meet actual demand;On the other hand, because of related reagent
Mobility, it cannot be guaranteed that related reagent, which converges to, wants treatment site.
In view of this, the present invention is specifically proposed.
Summary of the invention
In order to overcome the above technical problems, the present invention propose it is a kind of for austenite workpiece surface processing patch and its make
Use method.It realizes by using the combination of three kinds of patches containing different disposal agent to large scale, special-shaped austenite workpiece
Corrosion resistant surfaces processing, the case where avoiding in conventional method inorganic agent flowing dispersion;Under the cooperation of three kinds of inorganic agents, significantly
Improve the preservative treatment effect of austenite workpiece.Patch of the present invention and its application method in actual industrial production for having
Important meaning.
Technical scheme is as follows:
A kind of patch for the processing of austenite workpiece surface, comprising: the first patch, the second patch, third patch;It is described
First patch, the second patch, third patch include substrate and the gel layer formation for being attached to the substrate side;Wherein:
The gel layer of first patch contains cleaning agent;
The gel layer of second patch contains passivator;
The gel layer of the third patch contains sealer.
The material of the substrate can be selected from fabric hot rolled nonwoven fabrics, spunlace non-woven cloth, one of heat seal non-woven fabrics or a variety of.It adopts
Patch can be made preferably to be pasted on workpiece surface to be processed with this non-woven fabrics material, prevent displacement or inorganic agent volatilization or divided
Cloth is uneven.
The size of the substrate can be selected according to the size at the position to be processed of workpiece, it will usually in portion to be processed
Expand 5-8cm on the basis of plane product;For example, the site area to be processed of workpiece is long 5cm, wide 2cm, the logical choosing choosing of the size of substrate
Select long 13cm, wide 9.5cm.Further, it is contemplated that influence of situations such as inorganic agent air-dries to treatment effect, the thickness of the substrate is with 1-
5 millimeters are advisable.
Gel rubber material commonly used in the art can be selected in the material of the gel layer.But in view of gel layer is to each inorganic agent
The degree of scatter of adsorptivity, each inorganic agent in gel layer, each inorganic agent permeability during processing and patch and work
Adhesion property between part, the material of the gel layer are preferably starch hydrogel, cellulose family hydrogel, seaweed acids water
One of gel, chitosan class hydrogel are a variety of;Suggest that the thickness of gel layer is advisable in 1-3 millimeters of ranges simultaneously;It is solidifying
The porosity of glue-line reaches 90% or more.
With this condition, the effect of capable of utmostly playing each inorganic agent, treatment effect is significantly improved.
The size of the gel layer can be selected according to the size at workpiece position to be processed, can be with patch size
Exact matching, can also expand 3-5cm on the basis of site area to be processed;Concrete shape can be round, rectangular etc..
In the present invention, the formula and its mass fraction in gel layer same for final process effect ten of each inorganic agent
Divide important.
50% of the additive amount of the cleaning agent not less than gel layer gross mass in first patch.
The cleaning agent is selected from one of gluconate, tertiary sodium phosphate;It is preferred that gluconate, further preferably
K-IAO or sodium gluconate.
The passivator includes the component of following parts by weight: 20-30 parts of hydrogen peroxide, 2-4 parts of citric acid, and hexamethylenetetramine
3-4 parts;Preferably, the passivator includes the component of following parts by weight: 30 parts of hydrogen peroxide, 3 parts of citric acid, and hexamethylenetetramine
3 parts.
50% of the additive amount of the passivator not less than gel layer gross mass in second patch.
The sealer includes the component of following parts by weight: 10-15 parts of phytic acid, 2-5 parts of phosphate, and imidazolone
1-5 parts, 1-5 parts of pyrazinamide, 5-10 parts of hexanedioic acid, 0.1-2 parts of dodecyl sodium sulfate, 10-15 parts of malic acid, tannic acid
10-15 parts, 5-8 parts of triacetamide.
Preferably, the sealer includes the component of following parts by weight: 12 parts of phytic acid, 3 parts of phosphate, and imidazoline
3 parts of ketone, 2 parts of pyrazinamide, 8 parts of hexanedioic acid, 0.15 part of dodecyl sodium sulfate, 12 parts of malic acid, 12 parts of tannic acid, triacetyl
7 parts of amine.
50% of the additive amount of the sealer not less than gel layer gross mass in the third patch.
Experiment shows that under the conditions of above-mentioned gel layer, above-mentioned each inorganic agent can be preferably dispersed in respective gel layer,
And sufficiently oozed out when handling workpiece, its effect is played, to significantly improve the treatment effect of workpiece to be processed.
The present invention also provides the preparation methods of above-mentioned patch, comprising: in proportion, takes cleaning agent, passivator, sealer point
It is not diluted to certain density aqueous solution, three substrates with gel layer are impregnated in cleaning agent, passivator, sealer respectively
Aqueous solution in, be absorbed to each aqueous solution, respectively obtain the first patch, the second patch, third patch;
Wherein, the concentration of the aqueous solution of the cleaning agent is 20-30wt%, preferably 25wt%;
The concentration of the aqueous solution of the passivator is 25-38wt%, preferably 36wt%;
The concentration of the aqueous solution of the sealer is 30-80wt%, preferably 59-60wt%;
As the specific embodiment of the present invention, when preparing patch, the aqueous formulation of the cleaning agent: grape
Sugar lime 20-30wt%;Deionized water 70-80wt%;Preferably, K-IAO 24-26wt%, deionized water 74-
76wt%.
As the specific embodiment of the present invention, the aqueous formulation of the passivator are as follows: 20-30wt% dioxygen
Water;2-4wt% citric acid;3-4wt% hexamethylenetetramine;62-75wt% deionized water.Preferably, hydrogen peroxide 30wt%, lemon
Lemon acid 3wt%, hexamethylenetetramine 3wt%, deionized water 64wt%.
As the specific embodiment of the present invention, the aqueous formulation of the sealer are as follows: phytic acid 10-
15wt%;Phosphate 2-5wt%;Imidazolone 1-5wt%;Pyrazinamide 1-5wt%;Hexanedioic acid 5-10wt%;Dodecyl
Sodium sulfonate 0.1-2wt%;Malic acid 10-15wt%;Tannic acid 10-15wt%;Triacetamide 5-8wt%;Deionized water 20-
70wt%.Preferably, the formula of the sealer are as follows: phytic acid 12wt%;Phosphate 3wt%;Imidazolone 3wt%;
Pyrazinamide 2wt%;Hexanedioic acid 8wt%;Dodecyl sodium sulfate 0.15wt%;Malic acid 12wt%;Tannic acid 12wt%;Three
Acetamide 7wt%;Deionized water 40.85wt%.
Wherein, the preparation of the aqueous solution of the sealer can be directly soluble in water by sealer, can also use following
Method is made:
Step 1: by the phytic acid of 10-15wt%, the adipic acid of 5-10wt%, the malic acid of 10-15wt%, 10-
The tannic acid of 15wt% and the triethanolamine of 5-8wt% are mixed and are heated to 60-70 DEG C, and it is saturating to generate yellow for reaction 2 hours
Prescribed liquid;
Step 2: the pyrazinamide of the imidazoles beautiful jade ketone of 1-5wt% and 1-5wt% are added by several times and stirred, then is reacted 1 hour,
Appropriate amount of deionized water stirring is added, is separately added with agitation the phosphate of 2-5wt%, the dodecyl sodium sulfonate of 0.1-2wt%
Sodium is stirring evenly and then adding into excess water, is uniformly mixed, the sealer can be obtained.
The present invention also provides the application methods of above-mentioned patch, comprising: according to cleaning-passivation-closing step, by the first patch
Piece, the second patch, third patch successively affix to the position to be processed of austenite workpiece, and the processing time of each patch is 22-
26 hours.
In order to distinguish three kinds of patches, different colours are can be used in those skilled in the art or other modes are identified, such as red
Color patch is for cleaning, and yellow patch is for being passivated, and blue patch is for closing.
The present invention is realized by using the combination of three kinds of patches containing different disposal agent to large scale, special-shaped Ovshinsky
The case where corrosion resistant surfaces of body workpiece are handled, and avoid inorganic agent flowing dispersion in conventional method;In the cooperation of three kinds of inorganic agents
Under, significantly improve the preservative treatment effect of austenite workpiece.Patch of the present invention and its application method are for actual industrial
It has great significance in production.
Detailed description of the invention
Fig. 1 is the patch schematic diagram described in embodiment 1 for the processing of austenite stainless steel workpiece surface.In figure: 1, first
Patch;2, gel layer;3, the second patch;4, gel layer;5, third patch;6, gel layer.
Fig. 2 is that embodiment 2 cleans 301 austenite stainless steel workpieces, is passivated, the sample before and after Seal treatment is opened a way
Potential curve figure.
Fig. 3 be embodiment 2 301 austenite stainless steel workpieces are cleaned, are passivated, the sample polarization before and after Seal treatment
Curve graph.
Fig. 4 be embodiment 2 301 austenite stainless steel workpieces are cleaned, are passivated, the sample impedance before and after Seal treatment
Curve graph.
Specific embodiment
The following examples are used to illustrate the present invention, but are not intended to limit the scope of the present invention..
Embodiment 1
This example provides a kind of patch for the processing of austenite stainless steel workpiece surface, comprising:
First patch, the second patch, third patch;First patch, the second patch, third patch are with gel
The substrate of layer;Wherein:
The gel layer is starch hydrogel, and the thickness of gel layer is at 1-3 millimeters.90% or more gel porosity.
The gel layer of first patch contains cleaning agent;The total mass fraction that cleaning agent accounts for gel layer is 50%.
The gel layer of second patch contains passivator;The total mass fraction that passivator accounts for gel layer is 50%.
The gel layer of the third patch contains sealer;The total mass fraction that sealer accounts for gel layer is 50%.
As shown in Figure 1, red high adhesive sheet 1, the gel layer 2 with cleaning agent, the high adhesive sheet 3 of yellow have passivator
Gel layer 4, the high adhesive sheet 5 of yellow, the gel layer 6 with sealer.
The material of the substrate is non-woven fabrics, with a thickness of 1-5 millimeters.
The material of the gel layer is starch hydrogel, cellulose family hydrogel, seaweed acids hydrogel, chitosan class
One of hydrogel.With a thickness of 1-3 millimeters.
The cleaning agent is K-IAO.
The passivator includes the component of following parts by weight: 30 parts of hydrogen peroxide, 3 parts of citric acid, 3 parts of hexamethylenetetramine.
The sealer includes the component of following parts by weight: 12 parts of phytic acid, 3 parts of phosphate, and 3 parts of imidazolone,
2 parts of pyrazinamide, 8 parts of hexanedioic acid, 0.15 part of dodecyl sodium sulfate, 12 parts of malic acid, 12 parts of tannic acid, 7 parts of triacetamide.
Embodiment 2
The preparation method of patch described in embodiment 1, comprising: in proportion, cleaning agent, passivator, sealer is taken to dilute respectively
To certain density aqueous solution, by three substrates with gel layer be impregnated in respectively cleaning agent, passivator, sealer it is water-soluble
It in liquid, is all absorbed to each aqueous solution, respectively obtains the first patch, the second patch, third patch;
The aqueous formulation of the cleaning agent: K-IAO: 25wt%, deionized water: 75wt%.
The aqueous formulation of the passivator: citric acid: 3wt%;Deionized water: 64wt%;Hexamethylenetetramine:
3wt%;Hydrogen peroxide: 30wt%.
The aqueous formulation of the sealer: phytic acid: 12wt%;Phosphate: 3wt%;Imidazolone: 3wt%;
Pyrazinamide: 2wt%;Hexanedioic acid: 8wt%;Dodecyl sodium sulfate: 0.15wt%;Malic acid: 12wt%;Tannic acid:
12wt%;Triacetamide: 7wt%;Deionized water: 40.85wt%.
Embodiment 3
A kind of application method of patch described in embodiment 1, comprising:
S1, cleaning, comprising the following steps:
Step 1, first by 25wt%% K-IAO, the mixing of 75wt% deionized water stirs to get detergent solution.
Step 2, which is added dropwise at red patch mesophase gel, can be obtained after gel fully absorbs cleaning agent
To cleaning patch.
Step 3, cleaning patch is affixed on 301 austenitic stainless steels position to be processed, cleaning treatment 24 hours.
S2, passivation, comprising the following steps:
Step 1, by the citric acid of 3wt%, the deionized water of 64wt%, 30wt% hydrogen peroxide, 3wt% hexamethylenetetramine
Uniformly it is mixed to get passivator solution.
Step 2, which is added dropwise at yellow patch mesophase gel, can be obtained after gel fully absorbs passivator
To passivation patch.
Step 3, the position for patch will be passivated being affixed on 301 austenitic stainless steels cleaning treatment, Passivation Treatment 24 hours.
S3, closing, comprising the following steps:
Step 1, by the phytic acid of 12wt%, the adipic acid of 8wt%, the malic acid of 12wt%, 12wt% tannin
The triethanolamine of acid and 7wt% are mixed and are heated to 60-70 DEG C, and reaction 2 hours generates yellow transparent liquid.
Step 2, the pyrazinamide of the imidazoles beautiful jade ketone of 3wt% and 2wt% are added by several times and are stirred, then reacted 1 hour, is added
The stirring of 20.85wt% deionized water, is separately added with agitation the phosphate of 3wt%, the dodecyl sodium sulfate of 0.15wt%,
It is stirring evenly and then adding into 20wt% deionized water, is uniformly mixed, the sealer can be obtained.
Step 3, sealer is adsorbed at blue passivation post-chip mesophase gel, after gel fully absorbs sealer
Obtain closing patch.
Step 4, closing patch is affixed on 301 austenitic stainless steels and carries out over cleaning, the position of Passivation Treatment, at closing
Reason 24 hours.
Measure of merit
Embodiment 3 carries out at quickly local protection large volume assembly parts by the passivation note reagents of different colours
Reason, to realize efficient and convenient chemical treatment to molded massive structure part.
It, which is mainly characterized in that:, does not destroy other non-failure areas, continues manual operation without dismantling and being not required to.
For after protective treatment and untreated carry out experimental verification: before and after chemical surface treatment, the corrosion resistance of workpiece is such as
Shown in Fig. 2,3,4.
Although above the present invention is described in detail with a general description of the specific embodiments,
On the basis of the present invention, it can be made some modifications or improvements, this will be apparent to those skilled in the art.Cause
This, these modifications or improvements, fall within the scope of the claimed invention without departing from theon the basis of the spirit of the present invention.
Claims (10)
1. a kind of patch for the processing of austenite workpiece surface characterized by comprising the first patch, the second patch, third
Patch;
First patch, the second patch, third patch include substrate and the gel layer shape for being attached to the substrate side
At;Wherein:
The gel layer of first patch contains cleaning agent;
The gel layer of second patch contains passivator;
The gel layer of the third patch contains sealer.
2. patch according to claim 1, which is characterized in that the material of the substrate be selected from fabric hot rolled nonwoven fabrics, spun lacing without
Woven fabric, one of heat seal non-woven fabrics or a variety of;
And/or the thickness of the substrate is advisable with 1-5 millimeters.
3. patch according to claim 1 or 2, which is characterized in that the material of the gel layer be selected from starch hydrogel,
One of cellulose family hydrogel, seaweed acids hydrogel, chitosan class hydrogel are a variety of;
And/or the thickness of the gel layer is advisable in 1-3 millimeters of ranges.
4. patch according to claim 1 to 3, which is characterized in that the cleaning agent be selected from gluconate and/or
Tertiary sodium phosphate;It is preferred that gluconate;Further preferably K-IAO or sodium gluconate.
5. patch according to claim 1 to 4, which is characterized in that the additive amount of the cleaning agent is not less than described the
The 50% of gel layer gross mass in one patch.
6. -5 any patch according to claim 1, which is characterized in that the passivator includes the group of following parts by weight
Point: 20-30 parts of hydrogen peroxide, 2-4 parts of citric acid, 3-4 parts of hexamethylenetetramine;
Preferably, the passivator includes the component of following parts by weight: 30 parts of hydrogen peroxide, 3 parts of citric acid, and hexamethylenetetramine 3
Part.
7. -6 any patch according to claim 1, which is characterized in that the additive amount of the passivator is not less than described the
The 50% of gel layer gross mass in two patches.
8. -7 any patch according to claim 1, which is characterized in that the sealer includes the group of following parts by weight
Point: 10-15 parts of phytic acid, 2-5 parts of phosphate, 1-5 parts of imidazolone, 1-5 parts of pyrazinamide, 5-10 parts of hexanedioic acid, ten
0.1-2 parts of dialkyl sulfonates, 10-15 parts of malic acid, 10-15 parts of tannic acid, 5-8 parts of triacetamide;
Preferably, the sealer includes the component of following parts by weight: 12 parts of phytic acid, 3 parts of phosphate, and imidazolone 3
Part, 2 parts of pyrazinamide, 8 parts of hexanedioic acid, 0.15 part of dodecyl sodium sulfate, 12 parts of malic acid, 12 parts of tannic acid, triacetamide 7
Part;
And/or 50% of the additive amount of the sealer not less than gel layer gross mass in the third patch.
9. a kind of preparation method of any patch of claim 1-8 characterized by comprising in proportion, take cleaning agent,
Passivator, sealer are diluted to certain density aqueous solution respectively, and three substrates with gel layer are impregnated in cleaning respectively
Agent, passivator, sealer aqueous solution in, be absorbed to each aqueous solution, respectively obtain the first patch, the second patch, third patch
Piece;
Wherein, the concentration of the aqueous solution of the cleaning agent is 20-30wt%, preferably 24-26wt%;
The concentration of the aqueous solution of the passivator is 25-38wt%, preferably 35-37wt%;
The concentration of the aqueous solution of the sealer is 30-80wt%, preferably 59-60wt%.
10. a kind of application method of any patch of claim 1-8 characterized by comprising according to cleaning-passivation-envelope
Process is closed, the first patch, the second patch, third patch are successively affixed to the position to be processed of austenite workpiece, each patch
The processing time be 22-26 hours.
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KR930007922B1 (en) * | 1991-09-25 | 1993-08-21 | 강순식 | Method for baking a color coating black steel wire of a staple nail |
CN104338182A (en) * | 2013-08-08 | 2015-02-11 | 北京精密机电控制设备研究所 | Method for coating titanium alloy surface and coating layer formed by using same |
CN104531404A (en) * | 2014-12-30 | 2015-04-22 | 陕西师范大学 | Gel cleaning agent for lampblack on surface of polychrome cultural relic |
CN107858856A (en) * | 2017-10-17 | 2018-03-30 | 成都新柯力化工科技有限公司 | A kind of durability gas-phase anticorrosive non-woven fabric and preparation method thereof |
CN108660446A (en) * | 2018-07-20 | 2018-10-16 | 盐城市诚益通机械制造有限责任公司 | A kind of machine-building passivating device |
CN109487326A (en) * | 2018-12-20 | 2019-03-19 | 河南航天精工制造有限公司 | A kind of corrosion proof method of raising 1Cr17Ni2 martensitic stain less steel fastener |
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