CN110157334A - It is a kind of can purifying formaldehyde graphene mineral coating preparation method - Google Patents
It is a kind of can purifying formaldehyde graphene mineral coating preparation method Download PDFInfo
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- CN110157334A CN110157334A CN201810079255.XA CN201810079255A CN110157334A CN 110157334 A CN110157334 A CN 110157334A CN 201810079255 A CN201810079255 A CN 201810079255A CN 110157334 A CN110157334 A CN 110157334A
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- graphene
- purifying formaldehyde
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D201/00—Coating compositions based on unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The present invention relates to paint fields, and in particular to it is a kind of can purifying formaldehyde graphene mineral coating preparation method.The present invention provide it is a kind of can purifying formaldehyde graphene mineral coating, in parts by weight, it includes lotion 100-500 parts, 20-300 parts of natural minerals powder filler, 6-300 parts of inorganic mineral pigments, 8-200 parts of imidazolidinone derivatives, 10-150 parts of talcum powder, 10-80 parts of graphene, 50-100 parts of Sodium Polyacrylate, 20-120 parts of nano-titanium dioxide, 25-70 parts of epoxy resin, 140-320 parts of deionized water, 100-300 parts of pigment, 5-20 parts of antifreeze, 5-15 parts of reactive diluent, 1-5 parts of curing agent, 2-6 parts of defoaming agent that it, which is formed,.It is of the invention can the graphene mineral coating of purifying formaldehyde can have the function of the pernicious gases such as purifying formaldehyde while keeping good conventional application performance.
Description
Technical field
The present invention relates to paint fields, and in particular to it is a kind of can purifying formaldehyde graphene mineral coating preparation method.
Background technique
The coating material of the industries such as domestic construction is all to be mostly absolutely using organic coating, raw material main source at present
It is extracted in petroleum, coal or natural gas, produces such organic coating and need to consume a large amount of energy, while can also generate big
By-product and escaping gas are measured, there is very big harm to environment.Meanwhile the antistatic property resistance tocrocking etc. of organic coating
It is bad.
And mineral coating is the coating of humatite and inorganic binder composition, main component is alkali silicate (custom
Claim " aqueous glass "), inorganic pigment, mineral filler etc., this is the important composition factor of difference with organic coating.Inorganic mineral applies
Material is nontoxic, free from extraneous odour, nonirritant ecological, environmental protective coating material, to environment and human health without any harm.Coating by
Pure mineral filler, non-fading inorganic pigment and the synthesis of top grade liquid potassium silicate, can make color forever with metope silicification reaction
Attachment long is on the wall.
Summary of the invention
It is an object of the invention to customer service at present on the market mineral coating exist can not the pernicious gases such as purifying formaldehyde even
Discharge harmful substance, while the defect of anti-microbial property difference, provide one kind can purifying formaldehyde graphene mineral coating preparation side
Method, it is of the invention can the graphene mineral coating of purifying formaldehyde can have net while keeping good conventional application performance
Change the function of the pernicious gases such as formaldehyde.
The present invention provide it is a kind of can purifying formaldehyde graphene mineral coating, in parts by weight, composition includes cream
100-500 parts of liquid, 20-300 parts of natural minerals powder filler, 6-300 parts of inorganic mineral pigments, imidazolidinone derivatives 8-200
Part, 10-150 parts of talcum powder, 10-80 parts of graphene, 50-100 parts of Sodium Polyacrylate, 20-120 parts of nano-titanium dioxide, epoxy
25-70 parts of resin, 100-300 parts of pigment, 5-20 parts of antifreeze, 5-15 parts of reactive diluent, is consolidated 140-320 parts of deionized water
1-5 parts of agent, 2-6 parts of defoaming agent.
Preferably, the imidazolidinone derivatives are hydroxy imidazole alkanone.
Preferably, described one kind can purifying formaldehyde graphene mineral coating preparation method comprising following steps:
(1) graphene, reactive diluent are mixed with defoaming agent, obtains graphene slurry；
(2) by graphene slurry, lotion, natural minerals powder filler, inorganic mineral pigments imidazolidinone derivatives, talcum powder,
Graphene, Sodium Polyacrylate, nano-titanium dioxide, deionized water, epoxy resin, pigment, reactive diluent, antifreeze, defoaming
Agent mixing, obtains ready coating；
(3) ready coating is mixed with curing agent, obtain it is described can purifying formaldehyde graphene mineral coating.
The invention has the following advantages that the application substitutes existing common volatile organic solvent with reactive diluent,
And effectively disperse graphene, graphene slurry is formed, further by lotion, natural minerals powder filler, inorganic mineral
Pigment imidazolidinone derivatives, talcum powder, graphene, Sodium Polyacrylate, nano-titanium dioxide, deionized water, epoxy resin, face
Material, reactive diluent, antifreeze, defoaming agent mixing, finally obtain it is solvent-free can purifying formaldehyde graphene mineral coating, because
This coating and preparation method thereof is to environment fanout free region.
Specific embodiment
The technical solution in embodiment of the present invention will be clearly and completely described below, it is clear that described reality
Applying mode, only present invention a part is constantly placed, rather than whole embodiments.Based on the embodiment in the present invention,
Other embodiments obtained by those of ordinary skill in the art without making creative efforts, belong to the present invention
The range of protection.
The present invention provide it is a kind of can purifying formaldehyde graphene mineral coating, in parts by weight, composition includes cream
100-500 parts of liquid, 20-300 parts of natural minerals powder filler, 6-300 parts of inorganic mineral pigments, imidazolidinone derivatives 8-200
Part, 10-150 parts of talcum powder, 10-80 parts of graphene, 50-100 parts of Sodium Polyacrylate, 20-120 parts of nano-titanium dioxide, go from
Sub- water 140-320 parts, 100-300 parts of pigment, 5-20 parts of antifreeze, 5-15 parts of reactive diluent, 1-5 parts of curing agent, defoaming agent
2-6 parts.
The imidazolidinone derivatives are hydroxy imidazole alkanone.
Described one kind can purifying formaldehyde graphene mineral coating preparation method comprising following steps:
(1) graphene, reactive diluent are mixed with defoaming agent, obtains graphene slurry；
(2) by graphene slurry, lotion, natural minerals powder filler, inorganic mineral pigments imidazolidinone derivatives, talcum powder,
Graphene, Sodium Polyacrylate, nano-titanium dioxide, deionized water, pigment, reactive diluent, antifreeze, defoaming agent mixing, obtain
To ready coating；
(3) ready coating is mixed with curing agent, obtain it is described can purifying formaldehyde graphene mineral coating.
Combined with specific embodiments below to one kind of the present invention can purifying formaldehyde graphene mineral coating preparation
Method is illustrated:
Embodiment 1
It is a kind of can purifying formaldehyde graphene mineral coating, in parts by weight, composition include 110 parts of lotion, natural mine
22 parts of powder filler, 150 parts of imidazolidinone derivatives, 20 parts of talcum powder, 30 parts of graphene, gathers at 80 parts of inorganic mineral pigments
60 parts of sodium acrylate, 35 parts of nano-titanium dioxide, 65 parts of epoxy resin, 200 parts of deionized water, 150 parts of pigment, 8 parts of antifreeze,
10 parts of reactive diluent, 3 parts of curing agent, 4 parts of defoaming agent.
The imidazolidinone derivatives are hydroxy imidazole alkanone.
Described one kind can purifying formaldehyde graphene mineral coating preparation method comprising following steps:
(1) graphene, reactive diluent are mixed with defoaming agent, with high-speed shearing machine to disperse under 3000rad/min revolving speed
60min obtains graphene slurry.
(2) graphene slurry, lotion obtained by step (1), natural minerals powder filler, inorganic mineral pigments imidazolidine
Ketone derivatives, talcum powder, graphene, Sodium Polyacrylate, nano-titanium dioxide, it is deionized water, pigment, reactive diluent, freeze proof
Agent, defoaming agent are proportionally mixed, and are ground after mixing evenly with sand mill, and fineness≤50 μm obtain ready coating；
(3) curing agent is added in ready coating obtained by step (2), is turned with blender with 300rad/min-500rad/min
Speed stirring 10min, can be obtained can purifying formaldehyde graphene mineral coating.
Embodiment 2
It is a kind of can purifying formaldehyde graphene mineral coating, in parts by weight, composition include 80 parts of lotion, natural minerals
20 parts of powder stuffing, 60 parts of inorganic mineral pigments, 100 parts of imidazolidinone derivatives, 15 parts of talcum powder, 25 parts of graphene, poly- third
50 parts of olefin(e) acid sodium, 25 parts of nano-titanium dioxide, 55 parts of epoxy resin, 230 parts of deionized water, 130 parts of pigment, 10 parts of antifreeze,
12 parts of reactive diluent, 4 parts of curing agent, 3 parts of defoaming agent.
The imidazolidinone derivatives are hydroxy imidazole alkanone.
Described one kind can purifying formaldehyde graphene mineral coating preparation method comprising following steps:
(1) graphene, reactive diluent are mixed with defoaming agent, with high-speed shearing machine to disperse under 3000rad/min revolving speed
60min obtains graphene slurry.
(2) graphene slurry, lotion obtained by step (1), natural minerals powder filler, inorganic mineral pigments imidazolidine
Ketone derivatives, talcum powder, graphene, Sodium Polyacrylate, nano-titanium dioxide, it is deionized water, pigment, reactive diluent, freeze proof
Agent, defoaming agent are proportionally mixed, and are ground after mixing evenly with sand mill, and fineness≤50 μm obtain ready coating；
(3) curing agent is added in ready coating obtained by step (2), is turned with blender with 300rad/min-500rad/min
Speed stirring 10min, can be obtained can purifying formaldehyde graphene mineral coating.
Embodiment 3
It is a kind of can purifying formaldehyde graphene mineral coating, in parts by weight, composition include 130 parts of lotion, natural mine
90 parts of powder filler, 120 parts of imidazolidinone derivatives, 60 parts of talcum powder, 30 parts of graphene, gathers at 160 parts of inorganic mineral pigments
70 parts of sodium acrylate, 90 parts of nano-titanium dioxide, 50 parts of epoxy resin, 200 parts of deionized water, 120 parts of pigment, 8 parts of antifreeze,
9 parts of reactive diluent, 3 parts of curing agent, 4 parts of defoaming agent.
The imidazolidinone derivatives are hydroxy imidazole alkanone.
Described one kind can purifying formaldehyde graphene mineral coating preparation method comprising following steps:
(1) graphene, reactive diluent are mixed with defoaming agent, with high-speed shearing machine to disperse under 3000rad/min revolving speed
60min obtains graphene slurry.
(2) graphene slurry, lotion obtained by step (1), natural minerals powder filler, inorganic mineral pigments imidazolidine
Ketone derivatives, talcum powder, graphene, Sodium Polyacrylate, nano-titanium dioxide, it is deionized water, pigment, reactive diluent, freeze proof
Agent, defoaming agent are proportionally mixed, and are ground after mixing evenly with sand mill, and fineness≤50 μm obtain ready coating；
(3) curing agent is added in ready coating obtained by step (2), is turned with blender with 300rad/min-500rad/min
Speed stirring 10min, can be obtained can purifying formaldehyde graphene mineral coating.
Embodiment 4
It is a kind of can purifying formaldehyde graphene mineral coating, in parts by weight, composition include 110 parts of lotion, natural mine
30 parts of powder filler, 100 parts of imidazolidinone derivatives, 80 parts of talcum powder, 70 parts of graphene, gathers at 10 parts of inorganic mineral pigments
90 parts of sodium acrylate, 30 parts of nano-titanium dioxide, 40 parts of epoxy resin, 150 parts of deionized water, 120 parts of pigment, 7 parts of antifreeze,
6 parts of reactive diluent, 2 parts of curing agent, 5 parts of defoaming agent.
The imidazolidinone derivatives are hydroxy imidazole alkanone.
Described one kind can purifying formaldehyde graphene mineral coating preparation method comprising following steps:
(1) graphene, reactive diluent are mixed with defoaming agent, with high-speed shearing machine to disperse under 3000rad/min revolving speed
60min obtains graphene slurry.
(2) graphene slurry, lotion obtained by step (1), natural minerals powder filler, inorganic mineral pigments imidazolidine
Ketone derivatives, talcum powder, graphene, Sodium Polyacrylate, nano-titanium dioxide, it is deionized water, pigment, reactive diluent, freeze proof
Agent, defoaming agent are proportionally mixed, and are ground after mixing evenly with sand mill, and fineness≤50 μm obtain ready coating；
(3) curing agent is added in ready coating obtained by step (2), is turned with blender with 300rad/min-500rad/min
Speed stirring 10min, can be obtained can purifying formaldehyde graphene mineral coating.
The above is a preferred embodiment of the present invention, it is noted that for those skilled in the art
For, without departing from the principle of the present invention, several modifications and retouching can also be made, these improvements and modifications also regard
For protection scope of the present invention.
Claims (3)
1. one kind can purifying formaldehyde graphene mineral coating, which is characterized in that in parts by weight, composition include lotion
100-500 parts, 20-300 parts of natural minerals powder filler, 6-300 parts of inorganic mineral pigments, 8-200 parts of imidazolidinone derivatives,
10-150 parts of talcum powder, 10-80 parts of graphene, 50-100 parts of Sodium Polyacrylate, 20-120 parts of nano-titanium dioxide, epoxy resin
25-70 parts, 140-320 parts of deionized water, 100-300 parts of pigment, 5-20 parts of antifreeze, 5-15 parts of reactive diluent, curing agent
1-5 parts, 2-6 parts of defoaming agent.
2. one kind according to claim 1 can purifying formaldehyde graphene mineral coating, which is characterized in that the imidazolidine
Ketone derivatives are hydroxy imidazole alkanone.
3. according to claim 1 it is a kind of can purifying formaldehyde graphene mineral coating preparation method, which is characterized in that its
The following steps are included:
(1) graphene, reactive diluent are mixed with defoaming agent, obtains graphene slurry；
(2) by graphene slurry, lotion, natural minerals powder filler, inorganic mineral pigments imidazolidinone derivatives, talcum powder,
Graphene, Sodium Polyacrylate, nano-titanium dioxide, deionized water, epoxy resin, pigment, reactive diluent, antifreeze, defoaming
Agent mixing, obtains ready coating；
(3) ready coating is mixed with curing agent, obtain it is described can purifying formaldehyde graphene mineral coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810079255.XA CN110157334A (en) | 2018-01-26 | 2018-01-26 | It is a kind of can purifying formaldehyde graphene mineral coating preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810079255.XA CN110157334A (en) | 2018-01-26 | 2018-01-26 | It is a kind of can purifying formaldehyde graphene mineral coating preparation method |
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| Publication Number | Publication Date |
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| CN110157334A true CN110157334A (en) | 2019-08-23 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201810079255.XA Pending CN110157334A (en) | 2018-01-26 | 2018-01-26 | It is a kind of can purifying formaldehyde graphene mineral coating preparation method |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111701830A (en) * | 2020-06-24 | 2020-09-25 | 宁波计氏金属新材料有限公司 | Metal spraying treatment process |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20110089243A (en) * | 2011-07-13 | 2011-08-05 | 이재환 | Illite-aerogel paint compositions |
| CN103127646A (en) * | 2011-11-28 | 2013-06-05 | 北京市理化分析测试中心 | Spraying reagent for purifying formaldehyde |
| CN105315814A (en) * | 2015-10-19 | 2016-02-10 | 青岛瑞利特新材料科技有限公司 | Graphene formaldehyde-resisting paint and preparing method thereof |
| CN105838026A (en) * | 2015-01-12 | 2016-08-10 | 中国科学院宁波材料技术与工程研究所 | Graphene dispersing method, graphene dispersion system, and preparation method and application of graphene dispersion system |
-
2018
- 2018-01-26 CN CN201810079255.XA patent/CN110157334A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20110089243A (en) * | 2011-07-13 | 2011-08-05 | 이재환 | Illite-aerogel paint compositions |
| CN103127646A (en) * | 2011-11-28 | 2013-06-05 | 北京市理化分析测试中心 | Spraying reagent for purifying formaldehyde |
| CN105838026A (en) * | 2015-01-12 | 2016-08-10 | 中国科学院宁波材料技术与工程研究所 | Graphene dispersing method, graphene dispersion system, and preparation method and application of graphene dispersion system |
| CN105315814A (en) * | 2015-10-19 | 2016-02-10 | 青岛瑞利特新材料科技有限公司 | Graphene formaldehyde-resisting paint and preparing method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 苹果日报地产中心: "《家庭装修建材选购大全》", 30 September 2015, 江西科学技术出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111701830A (en) * | 2020-06-24 | 2020-09-25 | 宁波计氏金属新材料有限公司 | Metal spraying treatment process |
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Application publication date: 20190823 |