CN110156363A - A kind of sea sand desalting device and method - Google Patents

A kind of sea sand desalting device and method Download PDF

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CN110156363A
CN110156363A CN201910482965.1A CN201910482965A CN110156363A CN 110156363 A CN110156363 A CN 110156363A CN 201910482965 A CN201910482965 A CN 201910482965A CN 110156363 A CN110156363 A CN 110156363A
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water
sand
sea
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sea sand
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CN110156363B (en
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黄苏
瞿阳军
兰锦升
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/121Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/121Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering
    • C02F11/122Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering using filter presses
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/121Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering
    • C02F11/125Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering using screw filters
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/121Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering
    • C02F11/127Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering by centrifugation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/02Treatment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/283Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/442Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by nanofiltration
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/444Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by ultrafiltration or microfiltration
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/08Seawater, e.g. for desalination
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage

Abstract

The invention discloses a kind of sea sand desalting device and methods, the device includes recycled water manufacture system and sea sand desalting system, the recycled water manufacture system includes at least the sequentially connected pond Zhong Shui, in middle Water warfare desalination system and recycled water basin, the middle water in the pond Zhong Shui is stored in recycled water basin after the middle Water warfare desalination system processing;The sea sand desalting system then includes at least sea sand inactivation rupture of membranes system, impurity elimination vibrating screen device, first order sand washer, second level sand washer and the third level sand washer set gradually, the first order sand washer is connect with the pond Zhong Shui, and the second level sand washer and third level sand washer are then connect with the recycled water basin respectively.The sea sand desalting device using middle water or sea water desalination water as raw material desalted sea sand, can fresh-water-saving resource, reduce sea sand desalting cost.

Description

A kind of sea sand desalting device and method
Technical field
The present invention relates to a kind of sea sand desalting device and methods.
Background technique
Great attention with the exhaustive exploitation and government of natural sand stone resource to ecological environmental protection, this several years sandstones The trend that rises suddenly and sharply is presented in the price of aggregate, the awkward situation that can be bought without sand even occur in some areas, and many people start with sea sand preparation Concrete.But sea sand surface can contain a large amount of chloride, so sea sand contains a large amount of chloride ion ingredient, it is serious Standard beyond building sand destroys steel for that can have serious corrosiveness in engineering construction to the reinforcing bar of inside concrete The structure of reinforced concrete.In addition, sea sand also contains other objectionable impurities, such as: shell, mud, mica, light materials, organic Object, sulfide.Shell, mica and light materials can reduce the cohesive force of aggregate and cement and building stones in concrete.Therefore, country is bright Enable: sea sand is directly used in prestressed concrete without must not desalinate.Sea sand is to be only second to the second largest ocean mine of petroleum gas It produces, if its desalting is used, can solve the disparities between supply and demand of natural sand stone resource.In recent years, the desalination of sea sand Desalination technology and application are by attention.Standard is utilized for specification sea sand desalting, according to China " construction sand " (GB/T14684- 2011) standard, country have promulgated " building and municipal works purification sea sand " (JG/T 494-2016) standard, standard regulation: have built If a kind of sand chloride ion content used in sand must not exceed 0.001%, two classes must not exceed with sand chloride ion content 0.005%, and the three classes sand of minimum requirements, chloride ion content also must not exceed 0.01%.Currently, sea sand desalting mainly use it is light Water cleaning, desalting makes sea sand by three-level cleaning, desalting (i.e. level-one cleaning, desalting, second level cleaning, desalting and three-level cleaning, desalting) Salt content drop to 0.001% hereinafter, to meet " construction with sand " standard, it is light using this method using fresh water washing Change sea sand, one ton of sea sand of every desalination will at least consume 1.2 tons of fresh water, and therefore, desalted sea sand needs a large amount of freshwater resources.Mesh Before, China major part coastal area, scarcity of fresh water resources.But middle water and seawater resources are abundant, therefore, if in capable of using Water or seawater are raw material desalted sea sand, will be a kind of good selections.Therefore, it is badly in need of water or sea water desalination sea sand in a kind of utilization Device and method.
Summary of the invention
In order to solve the above-mentioned technical problem, the purpose of the present invention is to provide a kind of sea sand desalting device and methods.
The present invention is achieved through the following technical solutions: a kind of sea sand desalting device, including recycled water manufacture system and sea Sand desalting system, the recycled water manufacture system include at least the sequentially connected pond Zhong Shui, middle Water warfare desalination system In recycled water basin, the middle water in the pond Zhong Shui is stored in recycled water basin after the middle Water warfare desalination system processing In;The sea sand desalting system then includes at least the sea sand inactivation rupture of membranes system set gradually, impurity elimination vibrating screen device, the Level-one sand washer, second level sand washer and third level sand washer, the first order sand washer is connect with the pond Zhong Shui, described Second level sand washer and third level sand washer are then connect with the recycled water basin respectively.
Preferably, the water outlet of the three-level washed-out sand wastewater collection pond of third level sand washer is connected to the pond Zhong Shui.
Preferably, further including waste water treatment system, the waste water treatment system includes at least firsts and seconds washed-out sand waste water Sedimentation basin, three-level washed-out sand effluent settling chamber and three-level washed-out sand wastewater collection pond, the firsts and seconds washed-out sand effluent settling chamber connect It is connected to the water outlet of the first order sand washer and the second level sand washer, the water inlet of the three-level washed-out sand effluent settling chamber Mouth is then connect with the water outlet of the third level sand washer, and the three-level washed-out sand effluent settling chamber water outlet is connected to described three Grade washed-out sand wastewater collection pond, the water outlet of the three-level washed-out sand wastewater collection pond and the pond Zhong Shui are interconnected.
Preferably, the sludge outlet of the firsts and seconds washed-out sand effluent settling chamber and the three-level washed-out sand effluent settling chamber It is connected to a sludge-tank, the sludge-tank and a sludge dehydration device, which are attached, to carry out being dehydrated into clod,
Preferably, the sludge dehydration device can be centrifugal dehydrator, plate and frame filter press, folded spiral shell dewaterer or pocket type dehydration One of machine.
Preferably, the middle Water warfare desalination system includes pre-filtrating equipment and counter-infiltration system, the pre-filtrating equipment Including the first filter device and the second filter device, first filter device includes more Jie successively connecting with the pond Zhong Shui Mass filter and active carbon filter, second filter device are one of micro-filtration, ultrafiltration, MBR or nanofiltration.
The present invention also provides a kind of sea sand desalting device, including seawater desalination system and sea sand desalting system, institutes It states seawater desalination system and includes at least sequentially connected seawater water intake well, seawater cleaning desalination system and sea water desalination water basin, The seawater of the seawater water intake well is stored in sea water desalination water basin after seawater cleaning desalination system processing;The sea Sand desalting system then includes at least sea sand inactivation the rupture of membranes system, impurity elimination vibrating screen device, first order washed-out sand set gradually Machine, second level sand washer and third level sand washer, the first order sand washer, second level sand washer and third level sand washer difference It is connect with the sea water desalination water basin.
Preferably, the seawater cleaning desalination system includes sequentially connected seawater cleaning chlorination equipment, pre-filtrating equipment And desalination plant, the water outlet of the desalination plant are connected to the sea water desalination water basin.
The present invention also provides a kind of sea sand desalting methods, which comprises the steps of:
(1) preparation of recycled water: the middle water in the pond Zhong Shui is stored in regeneration after sewerage disposing system processing In water basin, chloride ion content Ying≤1.5mg/L of recycled water;
(2) sea sand inactivates rupture of membranes: the water of intermediate pool being promoted into electrolysis unit electrolysis and generates rupture of membranes agent, and then will Water containing rupture of membranes agent after electrolysis is sprayed onto the sea sand in sea sand rupture of membranes stockyard;
(3) be sieved impurity elimination: will by rupture of membranes treated that sea sand is transported in impurity elimination vibrating screen device, weed out shell and gravel Stone;
(4) clean: the sea sand after screening enters first order sand washer, first order sand washer and the pond Zhong Shui through hopper Connection, using the middle water in the pond Zhong Shui and the recycle-water by the cleaning of third level sand washer to the mortar in first order sand washer Carry out cleaning removal mud and desalination for the first time;Mortar after cleaning for the first time enters in the sand washer of the second level, is store with recycled water Recycled water in tank carries out second of cleaning and desalination;Mortar after second of cleaning enters third level sand washer, utilizes simultaneously The recycled water of recycled water basin carries out third time cleaning, desalting and obtains finished product desalted sea sand.
Preferably, the chloride ion content of first time cleaning, desalting Shi Zhongshui is 10mg~150mg/L, the water consumption of middle water is The 40%~70% of sea sand weight;When second of cleaning, desalting, the water consumption of recycled water is the 25%~40% of sea sand weight;The Three times when cleaning, desalting, regeneration water consumption is the 30%~50% of sea sand weight.
Of the invention is light as the sea sand of raw material using the recycled water of production aquatic in municipal sewage plant or sea water desalination water Change devices and methods therefor compared with existing sea sand desalination device and method, have the following obvious advantages:
1, it solves existing apparatus and method is needed using a large amount of freshwater resources, and China coast does not have a large amount of water supplies Contradiction, provide water-resource guarantee for a large amount of desalination sea sands;
2, the middle water purposes of existing municipal sewage plant is solved the problems, such as, currently, country advocates at municipal sewage energetically Factory's advanced treatment of wastewater is managed, how recycling utilization still makes full use of middle water to annoying industry development always;
3, the needs that country saves wa- ter resources strategy are implemented.The gross reserves of global water is 13.86 hundred million km3, and seawater just occupies 96.5%, the surface fresh water and shallow underground fresh water that the mankind can take are only 0.79%, and with region and seasonal variations distributed pole Unevenly.Shortage of fresh water has become one of three environment problems of 21 century.China is the state of a water resources shortage Family, the one third of the per capita freshwater resources deficiency world per capita are saved water to realize the strategy of sustainable development, are protected Hinder water resource supply, country has formulated saving wa- ter resources strategy, wherein carries out city sewage deep treatment, recycling utilization It is the important content that country saves wa- ter resources strategy.
4, sea sand desalination cost is reduced, tap water is substituted using the middle water of municipal sewage plant, desalination sea sand per ton can To conserve water 1 yuan of cost or more.
Detailed description of the invention
It, below will be to required in embodiment or description of the prior art in order to illustrate more clearly of technical solution of the present invention The attached drawing used is briefly described, it should be apparent that, drawings in the following description are only some embodiments of the invention, right For those of ordinary skill in the art, without creative efforts, it can also be obtained according to these attached drawings Its attached drawing.
Fig. 1 is the sea sand desalting schematic device of the embodiment of the present invention one.
Fig. 2 is the production technological process of Fig. 1 of the invention.
Fig. 3 is the connection schematic diagram of recycled water manufacture system (in Fig. 1 at A).
Fig. 4 is the connection schematic diagram of two seawater desalination system of the embodiment of the present invention.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, carries out to the technical solution in inventive embodiments clear, complete Ground description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based on this The embodiment of invention, those of ordinary skill in the art's every other reality obtained without making creative work Example is applied, shall fall within the protection scope of the present invention.
First embodiment
Reference book attached drawing 1 and attached drawing 3, a kind of sea sand desalting device, it is by municipal wastewater treatment plant recycled water manufacture system It is constituted with sea sand desalting system:
Recycled water manufacture system is at least made of the pond Zhong Shui 11, elevator pump, pre-filtrating equipment and counter-infiltration system 14, In, the pond Zhong Shui 11, elevator pump, pre-filtrating equipment and counter-infiltration system 14 (or being ion exchange desalination system) successively connect It connects, the water in the pond Zhong Shui 11 is by the middle water of municipal sewage plant.The pre-filtrating equipment includes the first filter device 131 With the second filter device 132, which includes the more medium filter a successively connecting with the pond Zhong Shui 11 and work Property carbon filter b, impurity, second filter device 132 such as silt particle, suspended matter, colloid in removal in water then can be micro- in advance One of filter, ultrafiltration, MBR or nanofiltration, wherein the micro-filtration or the membrane module of ultrafiltration can be organic film, ceramic membrane or metal film One of component three, nanofiltration membrane component are rolled membrane module, and the membrane material of nanofiltration membrane component is acetate fiber in organic film Film or composite nanometer filtering film, molecular cut off are 200~500MWCO, are 6.0~45.0bar into pressure, out pressure for 4.5~ 43.5bar, so that further impurities in water in removal, is purified middle water;The counter-infiltration system 14 is then by pre-filtrating equipment institute Water is pumped into counter-infiltration system 14 using high-pressure pump 31 after cartridge filter c filtering and is filtered desalination in the purification obtained, is obtained To the recycled water and condensed water of chloride ion Han Liang≤1.5mg/L, which is stored in the recycled water basin 32, this is dense Shrink then may be processed device and carry out purified treatment, which can be for by concentration water treatment unit and coagulating sedimentation unit Constitute, wherein the operating pressure of the high-pressure pump 31 are as follows: 6~35bar is 6.0~45.0bar into pressure, out pressure for 4.5~ 35bar, the membrane module of the counter-infiltration system 14 are rolled membrane module, and membrane material is cellulose acetate film or composite membrane in organic film, Its molecular cut off is 50~200MWCO, to retention Shuai≤99.5% of sodium chloride.
The sea sand desalting system then includes at least the sea sand inactivation rupture of membranes system 21 set gradually, impurity elimination vibrating screen dress Set 22, first order sand washer 23, second level sand washer 24, third level sand washer 25 and waste water treatment system, wherein the sea sand is gone out Rupture of membranes system 21 living includes sequentially connected intermediate pool 21a, electrolysis unit 21b and sea sand rupture of membranes stockyard 21c, wherein in this Between water in the 21a of pond preferably in water or seawater, the intermediate pool the same pond can be shared with the pond Zhong Shui, the intermediate water The water of pond 21a can be promoted in electrolysis unit 21b using elevator pump and is electrolysed, and it is (secondary to generate rupture of membranes agent by electrolysis Solution chlorate), finally again by containing on hypochlorous water spray to the sea sand of sea sand rupture of membranes stockyard 21c after electrolysis;This first Grade sand washer 23, second level sand washer 24 and third level sand washer 25 are utilized respectively first and stir washing machine, and second stirs washing machine and third It stirs washing machine stir washing, improves sea sand desalting effect, which connect with the pond Zhong Shui 11, second level sand washer 24 and third level sand washer 25 then connect respectively with recycled water basin 32;The waste water treatment system is washed including at least firsts and seconds Sand effluent settling chamber, three-level washed-out sand effluent settling chamber and three-level washed-out sand wastewater collection pond, the firsts and seconds washed-out sand wastewater sedimentation Pond is connected to the water outlet of the first order sand washer 23 and second level sand washer 24, the water inlet of the three-level washed-out sand effluent settling chamber Mouth is then connect with the water outlet of third level sand washer 25, and the water in three-level washed-out sand effluent settling chamber finally flows into the three-level and washes In sand wastewater collection pond, preferably, the water outlet of the three-level washed-out sand wastewater collection pond may connect to the pond Zhong Shui 11, it is further heavy It is multiple to utilize, it economizes on resources.Further, the sludge of the firsts and seconds washed-out sand effluent settling chamber and three-level washed-out sand effluent settling chamber Outlet is connected to a sludge-tank, and the sludge-tank and a sludge dehydration device are attached and carry out being dehydrated into clod, preferably, the dirt Mud dehydration device can be one kind of centrifugal dehydrator, plate and frame filter press, folded spiral shell dewaterer or pocket type dewaterer.
The implementation steps using water desalted sea sand in municipal wastewater treatment plant will be described below, steps are as follows:
(1) preparation of recycled water: the first filtering that the middle water of municipal sewage plant successively passes through pre-filtrating equipment is filled Set 131 and second filter device 132 be filtered, then the water after the pre-filtering enters counter-infiltration system 14 (or for ion Exchange desalination system) in carry out desalination, obtain the recycled water that chloride ion content is less than 1.5mg/L, recycled water is stored in recycled water In basin 32;
(2) sea sand inactivates rupture of membranes
The water of intermediate pool 21a is promoted into electrolysis unit 21b using elevator pump and is electrolysed, rupture of membranes agent is generated by electrolysis And then water containing rupture of membranes agent after the electrolysis is sprayed onto the sea sand of sea sand rupture of membranes stockyard 21c by (hypochlorite solution), utilize The microorganism in sea sand is killed in rupture of membranes agent, stacks 8-24 hours, makes the biomembrane liquefaction rupture of membranes on sea sand surface;
(3) be sieved impurity elimination: by batcher and conveyer belt will by rupture of membranes treated that sea sand is transported to impurity elimination vibrating screen In device 22, vibrating screen removal shell and gravel are utilized in impurity elimination vibrating screen device 22;
(4) clean: the sand after screening enters first order sand washer 23 through hopper, utilizes the middle water and warp in the pond Zhong Shui 11 The recycle-water for crossing the cleaning of third level sand washer 25 carries out the mud of cleaning removal for the first time simultaneously to the mortar in first order sand washer 23 Desalination, the mortar after cleaning for the first time enter in second level sand washer 24, carry out second with the recycled water in recycled water basin 32 Secondary cleaning and desalination, the mortar after second of cleaning enters third level sand washer 25, while utilizing the regeneration of recycled water basin 32 Water carries out third time cleaning, desalting and obtains finished product desalted sea sand, and last communicated band is delivered to product stockyard, the finished product desalted sea sand Chloride ion content less than 0.001~0.003% (weight percent).
Preferably, the sea sand desalting further includes waste water treatment step, the wastewater treatment is that first time is cleaned sea Sand and the waste water containing mud of second of cleaning sea sand discharge after being precipitated by firsts and seconds washed-out sand effluent settling chamber;It will be clear for the third time The waste water containing mud for washing sea sand enters in three-level washed-out sand wastewater collection pond after three-level washed-out sand effluent settling chamber precipitation and purification, and should Waste water and middle hydration in three-level washed-out sand wastewater collection pond simultaneously clean the water source of sea sand as first time, further reuse, Resource is saved, cost is reduced.
Preferably, the sea sand desalting further includes sludge dewatering step, the sludge dewatering is by mud by being concentrated It is dehydrated into clod using sludge dehydration device after tank concentration, preferably, the sludge dehydration device can be centrifugal dehydrator, sheet frame One kind of filter press, folded spiral shell dewaterer or pocket type dewaterer.
Detection case is as follows:
The first situation: through detecting, when initial, if Han Yan Liang≤650mg/ ㎏ of the sea sand, when first time cleaning, desalting Chloride ion Han Liang≤150mg/L of middle water, the water consumption of middle water is the 70% of sea sand weight, after first time cleaning, desalting, Chloride ion Han Liang≤120mg/ ㎏ of sea sand;The regeneration water consumption of second cleaning sea sand is the 25% of sea sand weight, by the After secondary cleaning desalination, chloride ion Han Liang≤40mg/ ㎏ of sea sand;The regeneration water consumption of third time cleaning sea sand is sea sand weight 30%, after third time cleaning, desalting, chloride ion Han Liang≤30mg/ ㎏ of sea sand.
Second situation: through detecting, when initial, if Han Yan Liang≤457mg/ ㎏ of sea sand, when first time cleaning, desalting, in Chloride ion Han Liang≤10mg/L of water, the water consumption of middle water is the 40% of sea sand weight, after first time cleaning, desalting, sea sand Chloride ion Han Liang≤90mg/ ㎏;The regeneration water consumption of second of cleaning sea sand is the 40% of sea sand weight, clear by second After salt elution, chloride ion Han Liang≤38mg/ ㎏ of sea sand;The regeneration water consumption of third time cleaning sea sand is sea sand weight 50%, after third time cleaning, desalting, chloride ion Han Liang≤10mg/ ㎏ of sea sand.
The third situation: through detecting, when initial, if Han Yan Liang≤390mg/ ㎏ of sea sand, when first time cleaning, desalting, in Chloride ion Han Liang≤150mg/L of water, the water consumption of middle water is the 60% of sea sand weight, after first time cleaning, desalting, sea Chloride ion Han Liang≤75mg/ ㎏ of sand;The regeneration water consumption of second of cleaning sea sand is the 30% of sea sand weight, by second After cleaning, desalting, chloride ion Han Liang≤31mg/ ㎏ of sea sand;The regeneration water consumption of third time cleaning sea sand is sea sand weight 40%, after third time cleaning, desalting, chloride ion Han Liang≤10mg/ ㎏ of sea sand.
Second embodiment:
Reference book attached drawing 4, a kind of using sea water desalination water as the sea sand desalting device of raw material, it is by seawater desalination system It is constituted with sea sand desalting system:
Seawater desalination system is at least by seawater water intake well 11 ', elevator pump, seawater cleaning chlorination equipment, pre-filtrating equipment and Desalination plant 14 ' (such as reverse-osmosis filtering device) is constituted;Seawater water intake well 11 ', elevator pump, seawater cleaning disinfection dress It sets, pre-filtrating equipment and desalination plant 14 ' are sequentially connected.The pre-filtrating equipment 13 includes the first filter device 131 ' and the Two filter devices 132 ', first filter device include the more medium filter a ' successively connecting with the pond Zhong Shui 11 and activity Carbon filter b ', impurity, second filter device 132 ' such as silt particle, suspended matter, colloid in removal in water then can be micro- in advance One of filter, ultrafiltration or nanofiltration, the water which is then filtered pre-filtrating equipment is through cartridge filter mistake It is pumped into desalination plant 14 ' after filter using high-pressure pump 31 ' and is filtered desalination, obtain sea water desalination water and condensed water, institute Sea water desalination water obtained is stored in the sea water desalination water basin 32 ', which then may be processed device and carry out at purification Reason, wherein the operating pressure of the high-pressure pump 31 ' is 45~60bar, is 45.0~60.0bar into pressure, and pressure is 43~58bar out.
Referring to attached drawing 1, which then includes at least the sea sand inactivation rupture of membranes system 21 set gradually, goes Miscellaneous vibrating screen device 22, first order sand washer 23, second level sand washer 24, third level sand washer 25 and waste water treatment system 26, Wherein, sea sand inactivation rupture of membranes system 21 includes sequentially connected intermediate pool 21a, electrolysis unit 21b and sea sand rupture of membranes stockyard 21c, wherein the water in intermediate pool 21a is preferably recycled water or seawater, and the water of intermediate pool 21a can utilize elevator pump It is promoted in electrolysis unit 21b and is electrolysed, rupture of membranes agent (hypochlorite solution) is generated by electrolysis, it finally again will electrolysis Afterwards containing on hypochlorous water spray to the sea sand of sea sand rupture of membranes stockyard 21c;The first order sand washer 23, second level sand washer 24 and third level sand washer 25 be utilized respectively first and stir washing machine, second stirs washing machine and third stirs washing machine and stir washing, and improves sea sand Fading effect.The sea water desalination water basin 32 ' respectively with first order sand washer 23, second level sand washer 24 and third level sand washer 25 connections;The waste water treatment system includes at least firsts and seconds washed-out sand effluent settling chamber, three-level washed-out sand effluent settling chamber and three Grade washed-out sand wastewater collection pond, which is connected to the first order sand washer 23 and the second level is washed The water inlet of the water outlet of sand machine 24, the three-level washed-out sand effluent settling chamber is then connect with the water outlet of third level sand washer 25, and And the water in three-level washed-out sand effluent settling chamber finally flows into the three-level washed-out sand wastewater collection pond, preferably, the three-level washed-out sand is useless The water outlet of water collecting pit may connect to the pond Zhong Shui, further reuses, economizes on resources.The firsts and seconds washed-out sand waste water The sludge outlet of sedimentation basin and three-level washed-out sand effluent settling chamber is connected to a sludge-tank, the sludge-tank and a sludge dehydration device into Row connection carries out being dehydrated into clod, preferably, the sludge dehydration device can be centrifugal dehydrator, plate and frame filter press, folded spiral shell dehydration One kind of machine or pocket type dewaterer.
The implementation steps using sea water desalination water desalted sea sand will be described below, steps are as follows:
(1) preparation of sea water desalination water: by seawater after elevator pump, the processing of seawater cleaning chlorination equipment purifying sterilizing, It is successively filtered by the first filter device 131 ' of pre-filtrating equipment and the second filter device 132 ', then after the pre-filtering Water enter and carry out desalination in desalination plant 14 ', obtain the sea water desalination water that chloride ion content is less than 1mg/L, seawater is light Change water to be stored in sea water desalination water basin 32 ';
(2) sea sand inactivates rupture of membranes
The water of intermediate pool 21a is promoted into electrolysis unit 21b using elevator pump and is electrolysed, rupture of membranes agent is generated by electrolysis And then water containing rupture of membranes agent after the electrolysis is sprayed onto the sea sand of sea sand rupture of membranes stockyard 21c by (hypochlorite solution), utilize The microorganism in sea sand is killed in rupture of membranes agent, stacks 8-24 hours, makes the biomembrane liquefaction rupture of membranes on sea sand surface;
(3) be sieved impurity elimination: by batcher and conveyer belt will by rupture of membranes treated that sea sand is transported to impurity elimination vibrating screen In device 22, vibrating screen removal shell and gravel are utilized in impurity elimination vibrating screen device 22;
(4) clean: the sand after screening enters first order sand washer 23 through hopper, using in sea water desalination water basin 32 ' Desalination water and the recycle-water cleaned by third level sand washer 25 carry out first time cleaning to the mortar in first order sand washer 23 Mud and desalination are removed, the mortar after cleaning for the first time enters in second level sand washer 24, in sea water desalination water basin 32 ' Desalination water carries out second of cleaning and desalination, and the mortar after second of cleaning enters third level sand washer 25, while utilizing seawater The desalination water of desalination water basin 32 ' carries out third time cleaning, desalting and obtains finished product desalted sea sand, and last communicated band is delivered to finished product Stockyard, the chloride ion content of the finished product desalted sea sand is less than 0.001~0.003% (weight percent).
Preferably, the sea sand desalting further includes waste water treatment step, the wastewater treatment is that first time is cleaned sea Sand and the waste water containing mud of second of cleaning sea sand discharge after being precipitated by firsts and seconds washed-out sand effluent settling chamber;It will be clear for the third time The waste water containing mud for washing sea sand enters in three-level washed-out sand wastewater collection pond after three-level washed-out sand effluent settling chamber precipitation and purification, and should Waste water and middle hydration in three-level washed-out sand wastewater collection pond simultaneously clean the water source of sea sand as water in utilization, further for the first time Recycling saves resource, reduces cost.
Preferably, the sea sand desalting further includes sludge dewatering step, the sludge dewatering is by mud by being concentrated It is dehydrated into clod using sludge dehydration device after tank concentration, preferably, the sludge dehydration device can be centrifugal dehydrator, sheet frame One kind of filter press, folded spiral shell dewaterer or pocket type dewaterer.
Detection case is as follows:
The first situation: through detecting, if Han Yan Liang≤600mg/ ㎏ of sea sand, when first time cleaning, desalting, desalination water Chloride ion Han Liang≤20mg/L, the water consumption of desalination water is the 70% of sea sand weight, after first time cleaning, desalting, sea sand Chloride ion Han Liang≤110mg/ ㎏;The desalination water consumption of second of cleaning sea sand is the 25% of sea sand weight, clear by second After salt elution, chloride ion Han Liang≤40mg/ ㎏ of sea sand;The desalination water consumption that goes of third time cleaning sea sand is sea sand weight 30%, after third time cleaning, desalting, chloride ion Han Liang≤30mg/ ㎏ of sea sand.
Second situation: through detecting, if Han Yan Liang≤500mg/ ㎏ of sea sand, when first time cleaning, desalting, desalination water Chloride ion Han Liang≤18mg/L, the water consumption of desalination water is the 70% of sea sand weight, after first time cleaning, desalting, sea sand Chloride ion Han Liang≤83mg/ ㎏;The desalination water consumption of second of cleaning sea sand is the 40% of sea sand weight, is cleaned by second After desalination, chloride ion Han Liang≤29mg/ ㎏ of sea sand;The desalination water consumption that goes of third time cleaning sea sand is sea sand weight 50%, after third time cleaning, desalting, chloride ion Han Liang≤10mg/ ㎏ of sea sand.
The third situation: through detecting, if Han Yan Liang≤375mg/ ㎏ of sea sand, when first time cleaning, desalting, desalination water Chloride ion Han Liang≤15mg/L, the water consumption of desalination water is the 60% of sea sand weight, after first time cleaning, desalting, sea sand Chloride ion Han Liang≤87mg/ ㎏;The desalination water consumption of second of cleaning sea sand is the 30% of sea sand weight, is cleaned by second After desalination, chloride ion Han Liang≤32mg/ ㎏ of sea sand;The desalination water consumption that goes of third time cleaning sea sand is sea sand weight 40%, after third time cleaning, desalting, chloride ion Han Liang≤10mg/ ㎏ of sea sand.
The preferred embodiment of the present invention has shown and described in above description, as previously described, it should be understood that the present invention is not office Be limited to form disclosed herein, should not be regarded as an exclusion of other examples, and can be used for various other combinations, modification and Environment, and can be changed within that scope of the inventive concept describe herein by the above teachings or related fields of technology or knowledge It is dynamic.And changes and modifications made by those skilled in the art do not depart from the spirit and scope of the present invention, then it all should be appended by the present invention In scope of protection of the claims.

Claims (10)

1. a kind of sea sand desalting device, which is characterized in that including recycled water manufacture system and sea sand desalting system, it is described again Unboiled water manufacture system includes at least the sequentially connected pond Zhong Shui, in middle Water warfare desalination system and recycled water basin, it is described in The middle water in water pond is stored in recycled water basin after the middle Water warfare desalination system processing;
The sea sand desalting system then include at least set gradually sea sand inactivation rupture of membranes system, impurity elimination vibrating screen device, First order sand washer, second level sand washer and third level sand washer, the first order sand washer are connect with the pond Zhong Shui, institute Second level sand washer and third level sand washer is stated then to connect with the recycled water basin respectively.
2. a kind of sea sand desalting device according to claim 1, which is characterized in that the three-level of the third level sand washer is washed The water outlet of sand wastewater collection pond is connected to the pond Zhong Shui.
3. a kind of sea sand desalting device according to claim 2, which is characterized in that it further include waste water treatment system, it is described Waste water treatment system includes at least firsts and seconds washed-out sand effluent settling chamber, three-level washed-out sand effluent settling chamber and three-level washed-out sand waste water Collecting pit, the firsts and seconds washed-out sand effluent settling chamber are connected to the first order sand washer and the second level sand washer Water outlet, the water inlet of the three-level washed-out sand effluent settling chamber is then connect with the water outlet of the third level sand washer, and institute It states three-level washed-out sand effluent settling chamber water outlet and is connected to the three-level washed-out sand wastewater collection pond, the described three-level washed-out sand wastewater collection The water outlet in pond and the pond Zhong Shui are interconnected.
4. a kind of sea sand desalting device according to claim 3, which is characterized in that the firsts and seconds washed-out sand waste water is heavy The sludge outlet of shallow lake pond and the three-level washed-out sand effluent settling chamber is connected to a sludge-tank, and the sludge-tank and a sludge dewatering fill It sets to be attached and carries out being dehydrated into clod.
5. a kind of sea sand desalting device according to claim 4, which is characterized in that the sludge dehydration device can be centrifugation Dewaterer, plate and frame filter press, folded one of spiral shell dewaterer or pocket type dewaterer.
6. a kind of sea sand desalting device according to claim 1, which is characterized in that the sewerage disposing system includes pre- mistake Device and counter-infiltration system are filtered, the pre-filtrating equipment includes the first filter device and the second filter device, first filtering Device includes the more medium filter and active carbon filter successively connecting with the pond Zhong Shui, and second filter device is micro- One of filter, ultrafiltration, MBR or nanofiltration.
7. a kind of sea sand desalting device, which is characterized in that including seawater desalination system and sea sand desalting system, the seawater Desalination system includes at least sequentially connected seawater water intake well, seawater cleaning desalination system and sea water desalination water basin, the sea The seawater of water water intake well is stored in sea water desalination water basin after seawater cleaning desalination system processing;
The sea sand desalting system then include at least set gradually sea sand inactivation rupture of membranes system, impurity elimination vibrating screen device, First order sand washer, second level sand washer and third level sand washer, the first order sand washer, second level sand washer and the third level Sand washer is connect with the sea water desalination water basin respectively.
8. a kind of sea sand desalting device according to claim 7, which is characterized in that the seawater cleaning desalination system includes Sequentially connected seawater cleaning chlorination equipment, pre-filtrating equipment and desalination plant, the water outlet of the desalination plant It is connected to the sea water desalination water basin.
9. a kind of sea sand desalting method, which comprises the steps of:
(1) preparation of recycled water: the middle water in the pond Zhong Shui is stored in regeneration after the middle Water warfare desalination system processing In water basin, chloride ion content Ying≤1.5mg/L of recycled water;
(2) sea sand inactivates rupture of membranes: the water of intermediate pool is promoted into electrolysis unit electrolysis and generates rupture of membranes agent, it and then will electrolysis Water afterwards containing rupture of membranes agent is sprayed onto the sea sand in sea sand rupture of membranes stockyard;
(3) be sieved impurity elimination: will by rupture of membranes treated that sea sand is transported in impurity elimination vibrating screen device, weed out shell and gravel;
(4) clean: the sea sand after screening enters first order sand washer through hopper, and first order sand washer and the pond Zhong Shui connect Connect, using in the pond Zhong Shui middle water and by the third level sand washer cleaning recycle-water to the mortar in first order sand washer into Row cleaning removal mud and desalination for the first time;Mortar after cleaning for the first time enters in the sand washer of the second level, with recycled water basin In recycled water carry out second cleaning and desalination;Mortar after second of cleaning enters third level sand washer, while using again The recycled water of unboiled water basin carries out third time cleaning, desalting and obtains finished product desalted sea sand.
10. a kind of sea sand desalting method according to claim 9, which is characterized in that first time cleaning, desalting Shi Zhongshui's Chloride ion content is 10~150mg/L, and the water consumption of middle water is the 40%~70% of sea sand weight;When second of cleaning, desalting, The water consumption of recycled water is the 25%~40% of sea sand weight;
When third time cleaning, desalting, regeneration water consumption is the 30%~50% of sea sand weight.
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Publication number Priority date Publication date Assignee Title
CN110885103A (en) * 2019-10-25 2020-03-17 深圳大学 Seawater desalination system and sea sand circulating desalination method
CN110885103B (en) * 2019-10-25 2022-05-31 深圳大学 Seawater desalination system and sea sand circulating desalination method
CN111003837A (en) * 2019-11-17 2020-04-14 金科环境股份有限公司 Circulating water sea sand desalination treatment system and method
CN111187020A (en) * 2020-02-26 2020-05-22 广东新龙海洋装备科技有限公司 Sea sand desalination equipment and sea sand desalination method
CN111196692A (en) * 2020-02-26 2020-05-26 广东新龙海洋装备科技有限公司 Sea sand processing apparatus
CN111187020B (en) * 2020-02-26 2023-09-01 广东新龙海洋装备科技有限公司 Sea sand desalination equipment and sea sand desalination method
CN111187019B (en) * 2020-02-26 2023-11-21 广东新龙海洋装备科技有限公司 Sea sand desalination device
CN111196692B (en) * 2020-02-26 2024-01-30 广东新龙海洋装备科技有限公司 Sea sand processing apparatus
CN113062639A (en) * 2021-03-17 2021-07-02 中交天津航道局有限公司 Multistage sea sand desalination factory building arrangement structure
CN113060960A (en) * 2021-03-17 2021-07-02 中交天津航道局有限公司 Efficient environment-friendly sea sand desalination treatment process and system
CN112960925A (en) * 2021-04-13 2021-06-15 中交天航南方交通建设有限公司 Deep dechlorination sand washing method for sea sand desalination
CN113617511A (en) * 2021-08-26 2021-11-09 福州市荣盛荣自动化设备有限公司 Sea sand desalting equipment and process thereof

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