CN110156258A - A kind of advanced sewage treatment system and technique - Google Patents

A kind of advanced sewage treatment system and technique Download PDF

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Publication number
CN110156258A
CN110156258A CN201910423988.5A CN201910423988A CN110156258A CN 110156258 A CN110156258 A CN 110156258A CN 201910423988 A CN201910423988 A CN 201910423988A CN 110156258 A CN110156258 A CN 110156258A
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CN
China
Prior art keywords
activated coke
bed filter
filtrate
fiber
haydite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910423988.5A
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Chinese (zh)
Inventor
许生军
邓银
蓝天
沈宏豪
陈倩倩
杨林鹏
田启平
武兵文
姚新兰
杨彦飞
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chaohu City Urban Construction Investment Co Ltd
Xing Yuan Environmental Science And Technology Ltd Co
Original Assignee
Chaohu City Urban Construction Investment Co Ltd
Xing Yuan Environmental Science And Technology Ltd Co
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Filing date
Publication date
Application filed by Chaohu City Urban Construction Investment Co Ltd, Xing Yuan Environmental Science And Technology Ltd Co filed Critical Chaohu City Urban Construction Investment Co Ltd
Priority to CN201910423988.5A priority Critical patent/CN110156258A/en
Publication of CN110156258A publication Critical patent/CN110156258A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/24Treatment of water, waste water, or sewage by flotation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/281Treatment of water, waste water, or sewage by sorption using inorganic sorbents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/283Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • C02F1/5245Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents using basic salts, e.g. of aluminium and iron
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/54Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
    • C02F1/56Macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/08Chemical Oxygen Demand [COD]; Biological Oxygen Demand [BOD]
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/10Solids, e.g. total solids [TS], total suspended solids [TSS] or volatile solids [VS]
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/14NH3-N
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/16Total nitrogen (tkN-N)
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/18PO4-P
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/28Anaerobic digestion processes
    • C02F3/2806Anaerobic processes using solid supports for microorganisms

Abstract

The present invention discloses a kind of advanced sewage treatment system, including sequentially connected flotation tank, denitrification deep-bed filter, activated coke absorption tower, and flotation tank is equipped with PAC adding of agent mouth and PAM adding of agent mouth, for chemistry except total phosphorus and removal SS;The filtrate of denitrification deep-bed filter is using quartz sand, haydite and fiber-like wastes of crops mixing composition, for removing total nitrogen;The filtrate on activated coke absorption tower is activated coke and zeolite mixing composition, for removing COD and ammonia nitrogen.Invention additionally discloses a kind of sewerage advanced treatment process.The present invention is combined using flotation tank, denitrification deep-bed filter, activated coke absorption tower, can be removed COD, ammonia nitrogen, total nitrogen, total phosphorus and the SS in sewage simultaneously, be can guarantee the qualified discharge of each index of tail water, simple, effective, stable.

Description

A kind of advanced sewage treatment system and technique
Technical field
The present invention relates to technical field of sewage, and in particular to a kind of advanced sewage treatment system and technique.
Background technique
In the further treatment technique of sewage, denitrification deep-bed filter is one of main technology, but due to sewage plant two Grade is discharged carbon source needed for remaining carbon source is insufficient for denitrification biological denitrogenation, it usually needs carbon source is additionally added, so with Conventional denitrification carbon source is replaced rich in a large amount of fiber-like wastes of crops, moreover it is possible to be provided with the table for adhering to conducive to microorganism and surviving Area, but pure fiber-like wastes of crops have the characteristics that as the filtrate of denitrification deep-bed filter it is easy to wear.
In addition, advanced treatment of wastewater should develop to simple, effective, stabilising direction.
Summary of the invention
It is an object of the present invention to provide a kind of advanced sewage treatment system and techniques, so as to solve the deficiencies in the prior art.
The invention adopts the following technical scheme:
A kind of advanced sewage treatment system, including sequentially connected flotation tank, denitrification deep-bed filter, activated coke absorb Tower, flotation tank are equipped with PAC adding of agent mouth and PAM adding of agent mouth, for chemistry except total phosphorus and removal SS;The filter of denitrification depth bed The filtrate in pond is using quartz sand, haydite and fiber-like wastes of crops mixing composition, for removing total nitrogen;Activated coke absorption tower Filtrate is activated coke and zeolite mixing composition, for removing COD and ammonia nitrogen.
Further, the filtrate of denitrification deep-bed filter by quartz sand, haydite and fiber-like wastes of crops by volume 3:2:1 mixing composition.
Further, quartz sand particle size 2-4mm;Haydite partial size is 4-8mm;Fiber-like wastes of crops include stalk, Rice husk, sawdust, bagasse, corncob.
Further, the filtrate on property coke absorption tower is made of activated coke and zeolite 4-2:1 mixing by volume.
Further, activated coke is that coal quality seed activity is burnt, and partial size 2-8mm, iodine number is greater than 600mg/g;Sized zeolite particles For 2-4mm.
A kind of sewerage advanced treatment process, includes the following steps:
Step 1: sewage is handled through biochemistry pool, water outlet COD is not higher than 80mg/L, and ammonia nitrogen is not higher than 15mg/L, and total phosphorus is not high It is not higher than 20mg/L in 1.5mg/L, SS, total nitrogen is not higher than 20mg/L, introduces flotation tank afterwards, PAC solution and PAM solution is added, For chemistry except total phosphorus and removal SS, flotation tank is discharged SS control in 5mg/L;
Step 2: flotation tank water outlet introduces denitrification deep-bed filter, quartz sand, haydite and fiber-like wastes of crops are utilized The microorganism grown on the filtrate of composition is mixed, in the environment of anoxic, denitrification is carried out, thus total in sewage of degrading Nitrogen, denitrification deep-bed filter water outlet total nitrogen reach 1.5mg/L or less;
Step 3: the water outlet of denitrification deep-bed filter introduces activated coke absorption tower, formed using active carbon and zeolite mixing Filtrate passes through physisorption and removes COD and ammonia nitrogen in sewage simultaneously, denitrification deep-bed filter be discharged COD20mg/L with Under, ammonia nitrogen 1mg/L or less.
Further, 3:2:1 is mixed by volume for quartz sand, haydite and fiber-like wastes of crops.
Further, quartz sand particle size 2-4mm;Haydite partial size is 4-8mm;Fiber-like wastes of crops include stalk, Rice husk, sawdust, bagasse, corncob.
Further, 4-2:1 is mixed by volume for activated coke and zeolite.
Further, activated coke is that coal quality seed activity is burnt, and partial size 2-8mm, iodine number is greater than 600mg/g;Sized zeolite particles For 2-4mm.
Beneficial effects of the present invention:
1, the present invention is combined using flotation tank, denitrification deep-bed filter, activated coke absorption tower, can be removed in sewage simultaneously COD, ammonia nitrogen, total nitrogen, total phosphorus and SS, can guarantee the qualified discharge of each index of tail water, it is simple, effectively, stablize.
2, the present invention is in denitrification deep-bed filter, for the defect for overcoming fiber-like wastes of crops itself, in conjunction with tradition Quartz sand filter media, the preferable haydite of reselection porosity select quartz sand, haydite and fiber-like wastes of crops body as filtrate Proportion of the product than 3:2:1 realizes the economic stability operation of denitrification deep-bed filter.Quartz sand and haydite, which combine, increases the strong of filtrate Degree and porosity (porosity increases, that is, increases the bond area of removal total nitrogen microorganism), fiber-like wastes of crops increases hole While gap rate, carbon source needed for emphasis provides denitrification.Traditional filtrate quartz sand, haydite and fiber-like wastes of crops Combination the shortcomings that can overcoming traditional filtrate addition carbon source, while the disadvantage for overcoming fiber-like wastes of crops intensity inadequate, It ensure that outlet effect, and saved cost.
3, activated coke adsorption tower of the present invention is set to after denitrification deep-bed filter, is conducive to absorb fine in denitrification process The COD that class wastes of crops generates is tieed up, while being adsorbed the COD in sewage by filtering suction-operated, and activated coke pair The removal effect of ammonia nitrogen is smaller, carries out Adsorption to ammonia nitrogen by zeolite, it can keep two indexes up to standard, improve the association of the two Same filtration.Using activated coke and zeolite, 4-2:1 is mixed by volume, can remove tail water and the leaching of fiber-like wastes of crops COD and ammonia nitrogen out guarantee each index emission compliance in tail water.
Detailed description of the invention
Fig. 1 is present system schematic diagram.
Specific embodiment
The present invention is done below with reference to embodiment and attached drawing and is further explained.The following example is merely to illustrate this hair It is bright, but be not used to limit practical range of the invention.
A kind of advanced sewage treatment system, as shown in Figure 1, including sequentially connected flotation tank, denitrification deep-bed filter, work Property coke absorption tower.
Flotation tank is equipped with PAC adding of agent mouth and PAM adding of agent mouth, for chemistry except total phosphorus and removal SS.
3:2:1 is mixed by volume using quartz sand, haydite and fiber-like wastes of crops for the filtrate of denitrification deep-bed filter It is combined into, quartz sand particle size 2-4mm;Haydite partial size is 4-8mm;Fiber-like wastes of crops include stalk, rice husk, sawdust, Bagasse, corncob.Denitrification deep-bed filter is for removing total nitrogen.
The filtrate on activated coke absorption tower is activated coke and the zeolite composition of 4-2:1 mixing by volume, and activated coke is coal quality Grain activated coke, partial size 2-8mm, iodine number are greater than 600mg/g;Sized zeolite particles are 2-4mm.Activated coke absorption tower is for removing COD And ammonia nitrogen.
A kind of sewerage advanced treatment process, includes the following steps:
Step 1: sewage is handled through biochemistry pool, water outlet COD is not higher than 80mg/L, and ammonia nitrogen is not higher than 15mg/L, and total phosphorus is not high In 1.5mg/L, SS is not higher than 20mg/L, and total nitrogen is not higher than 20mg/L, introduces flotation tank afterwards, be added 3-10wt%PAC solution and ‰ PAM solution of 0.5-2wt, additive amount are 1-5ml/L sewage, and except total phosphorus and removal SS, flotation tank is discharged SS control and exists chemistry 5mg/L。
Step 2: flotation tank water outlet introduces denitrification deep-bed filter, quartz sand, haydite and fiber-like wastes of crops are utilized The microorganism grown on the filtrate of the composition of 3:2:1 mixing by volume carries out denitrification in the environment of anoxic, thus Total nitrogen in degradation sewage, denitrification deep-bed filter water outlet total nitrogen reach 1.5mg/L or less;Wherein, quartz sand particle size 2- 4mm;Haydite partial size is 4-8mm;Fiber-like wastes of crops includes stalk, rice husk, sawdust, bagasse, corncob.
Step 3: the water outlet of denitrification deep-bed filter introduces activated coke absorption tower, active carbon and zeolite 4- by volume are utilized The filtrate of 2:1 mixing composition, COD and ammonia nitrogen in sewage are removed by physisorption simultaneously, and denitrification deep-bed filter goes out Water COD20mg/L is hereinafter, ammonia nitrogen 1mg/L or less;Wherein, activated coke is that coal quality seed activity is burnt, partial size 2-8mm, and iodine number is big In 600mg/g;Sized zeolite particles are 2-4mm.

Claims (10)

1. a kind of advanced sewage treatment system, which is characterized in that including sequentially connected flotation tank, denitrification deep-bed filter, work Property coke absorption tower, flotation tank be equipped with PAC adding of agent mouth and PAM adding of agent mouth, for chemistry except total phosphorus and removal SS;Anti- nitre Change the filtrate of deep-bed filter using quartz sand, haydite and fiber-like wastes of crops mixing composition, for removing total nitrogen;Activated coke The filtrate on absorption tower is activated coke and zeolite mixing composition, for removing COD and ammonia nitrogen.
2. advanced sewage treatment system according to claim 1, which is characterized in that the filtrate of denitrification deep-bed filter is by stone Sand, haydite and fiber-like the wastes of crops composition of 3:2:1 mixing by volume.
3. advanced sewage treatment system according to claim 1, which is characterized in that quartz sand particle size 2-4mm;Haydite grain Diameter is 4-8mm;Fiber-like wastes of crops includes stalk, rice husk, sawdust, bagasse, corncob.
4. advanced sewage treatment system according to claim 1, which is characterized in that the filtrate on property coke absorption tower is by activated coke With the zeolite composition of 4-2:1 mixing by volume.
5. advanced sewage treatment system according to claim 1, which is characterized in that activated coke is that coal quality seed activity is burnt, Partial size is 2-8mm, and iodine number is greater than 600mg/g;Sized zeolite particles are 2-4mm.
6. a kind of sewerage advanced treatment process, which comprises the steps of:
Step 1: sewage is handled through biochemistry pool, water outlet COD is not higher than 80mg/L, and ammonia nitrogen is not higher than 15mg/L, and total phosphorus is not higher than 1.5mg/L, SS are not higher than 20mg/L, and total nitrogen is not higher than 20mg/L, introduces flotation tank afterwards, and PAC solution and PAM solution is added, and change It learns except total phosphorus and removal SS, flotation tank is discharged SS control in 5mg/L;
Step 2: flotation tank water outlet introduces denitrification deep-bed filter, mixed using quartz sand, haydite and fiber-like wastes of crops The microorganism grown on the filtrate of composition carries out denitrification in the environment of anoxic, thus the total nitrogen in sewage of degrading, Denitrification deep-bed filter water outlet total nitrogen reaches 1.5mg/L or less;
Step 3: the water outlet of denitrification deep-bed filter introduces activated coke absorption tower, the filtrate formed using active carbon and zeolite mixing, Remove the COD and ammonia nitrogen in sewage simultaneously by physisorption, denitrification deep-bed filter is discharged COD20mg/L hereinafter, ammonia Nitrogen 1mg/L or less.
7. sewerage advanced treatment process according to claim 6, which is characterized in that quartz sand, haydite and fiber-like farming 3:2:1 is mixed object waste material by volume.
8. sewerage advanced treatment process according to claim 6, which is characterized in that quartz sand particle size 2-4mm;Haydite grain Diameter is 4-8mm;Fiber-like wastes of crops includes stalk, rice husk, sawdust, bagasse, corncob.
9. sewerage advanced treatment process according to claim 6, which is characterized in that activated coke and zeolite 4-2 by volume: 1 mixing.
10. sewerage advanced treatment process according to claim 6, which is characterized in that activated coke is that coal quality seed activity is burnt, Partial size is 2-8mm, and iodine number is greater than 600mg/g;Sized zeolite particles are 2-4mm.
CN201910423988.5A 2019-05-21 2019-05-21 A kind of advanced sewage treatment system and technique Pending CN110156258A (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08294699A (en) * 1995-04-26 1996-11-12 Ebara Corp Biological denitrification apparatus of waste water
CN102092900A (en) * 2010-12-29 2011-06-15 江南大学 Method for treating micro polluted water by using biological nitrogen removal and physicochemical enhanced phosphorus removal combined process
CN102249478A (en) * 2011-05-10 2011-11-23 襄樊赛洁环保科技有限公司 Deep nitrogen and phosphorus removal process for surface water body
CN105366802A (en) * 2015-12-11 2016-03-02 南京大学 Eco-biofilter apparatus and method for treating sewage by eco-biofilter apparatus
CN108862929A (en) * 2018-08-04 2018-11-23 浙江水美环保工程有限公司 The processing system and its processing method of mark transformation are proposed for sewage treatment plant tail water
CN109650652A (en) * 2018-12-24 2019-04-19 浙江中昌水处理科技有限公司 Biochemistry pool MBBR technique coupling denitrification deep-bed filter denitrification dephosphorization system and method

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08294699A (en) * 1995-04-26 1996-11-12 Ebara Corp Biological denitrification apparatus of waste water
CN102092900A (en) * 2010-12-29 2011-06-15 江南大学 Method for treating micro polluted water by using biological nitrogen removal and physicochemical enhanced phosphorus removal combined process
CN102249478A (en) * 2011-05-10 2011-11-23 襄樊赛洁环保科技有限公司 Deep nitrogen and phosphorus removal process for surface water body
CN105366802A (en) * 2015-12-11 2016-03-02 南京大学 Eco-biofilter apparatus and method for treating sewage by eco-biofilter apparatus
CN108862929A (en) * 2018-08-04 2018-11-23 浙江水美环保工程有限公司 The processing system and its processing method of mark transformation are proposed for sewage treatment plant tail water
CN109650652A (en) * 2018-12-24 2019-04-19 浙江中昌水处理科技有限公司 Biochemistry pool MBBR technique coupling denitrification deep-bed filter denitrification dephosphorization system and method

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Application publication date: 20190823