CN110143780A - A kind of cement additive suitable for municipal works - Google Patents
A kind of cement additive suitable for municipal works Download PDFInfo
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- CN110143780A CN110143780A CN201910502453.7A CN201910502453A CN110143780A CN 110143780 A CN110143780 A CN 110143780A CN 201910502453 A CN201910502453 A CN 201910502453A CN 110143780 A CN110143780 A CN 110143780A
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- powder
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
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- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Soil Conditioners And Soil-Stabilizing Materials (AREA)
Abstract
The invention discloses a kind of cement additives suitable for municipal works, including following weight ratio raw material: gypsum 10~30%, palygorskite powder 5~15%, rice milk powder 5~10%, boron mud 1~10%, flyash 5~10%, aluminosilicate 1~10%, paraffin wax emulsions 5~10%, diatomite 5~15%, cellulose ether 1~5%, water-reducing agent 5~10%, gypsum selects ardealite, ardealite is the gypsum that the waste residue generated in chemical fertilizer factory's phosphoric acid producing process is produced, and palygorskite powder is the powder material that natural palygorskite obtains after purification, modification.In the present invention, the preparation method of cement additive, simple and easy, raw material is easy to get, cheap, it is of less demanding to equipment and reaction condition, cement after addition has the characteristics that preferable waterproof, crack resistence, high intensity and performance are stable, so that strength on concrete material, mobility, durability and anti-permeability performance effect are more significant, volume is less, it is plasticized the superior advantage of performance, the slump of concrete can be significantly increased.
Description
Technical field
The invention belongs to additive technology field, specially a kind of cement additive suitable for municipal works.
Background technique
During cement additive refers to cement applications, to improve or realizing auxiliary agent that various characteristics are added, such as fastly
Dry or enhancing, such as water-reducing agent, reduce water content, such as retarder slow setting.In recent years, constantly pushing away with Process of Urbanization Construction
Into the problem of urban construction is brought increasingly shows.Wherein, due to the performance bring qualitative problems of construction of concrete also Shi Youfa
It is raw.
During concrete is applied in practical projects, various more harsh environment are commonly exposed to, as environment is corroded
Property medium intrusion, the variation of ambient temperature and humidity, Frozen-thawed cycled destroy and part concrete works are ground often in heavy load
Damage etc., these external conditions will seriously affect the service life of concrete.Therefore, it is necessary to protective agent pair is added in concrete
Concrete carries out protective effect, and existing concrete additive, which exists, to be had a single function, and uses a variety of different additives, Ke Yida
To different effects.But simultaneously collocation in use, if the interaction of various additives, type selecting, proportion or addition manner not
Correctly, it will seriously affect the construction quality of concrete.Cement water reducing agent is one of numerous additives of concrete, industry
Change and commercialization has pushed directly on the concrete technologies such as self-stressing concretes, self-compacting concrete, high-strength super high strength concrete
Development.It is composition indispensable in concrete material, and now on the market almost without being specially adapted for city's political and ideological work
The cement additive of journey, therefore it is proposed that a kind of cement additive suitable for municipal works.
Summary of the invention
It is an object of the invention to: there is no the cement of tailored version to solve to correspond to municipal works in existing cement additive
The problem of additive, provides a kind of cement additive suitable for municipal works.
The technical solution adopted by the invention is as follows:
A kind of cement additive suitable for municipal works, including following weight ratio raw material: gypsum 10~30%, palygorskite
Powder 5~15%, rice milk powder 5~10%, boron mud 1~10%, flyash 5~10%, aluminosilicate 1~10%, paraffin wax emulsions 5~
10%, diatomite 5~15%, cellulose ether 1~5%, water-reducing agent 5~10%.
Wherein, each raw material weight percentage are as follows: gypsum 25%, palygorskite 15%, Rice & peanut milk 10%, boron mud 5%, fine coal
Grey 10%, aluminosilicate 8%, paraffin wax emulsions 5%, diatomite 10%, cellulose ether 7%, water-reducing agent 5%.
Wherein, the gypsum selects ardealite, and ardealite is what the waste residue generated in chemical fertilizer factory's phosphoric acid producing process was produced
Gypsum.
Wherein, the water-reducing agent selects poly carboxylic acid series water reducer.
Wherein, the palygorskite powder is the powder material that natural palygorskite obtains after purification, modification.
Wherein, the rice milk powder is made after water logging, stewing steaming, water dissolution by rice.
Wherein, the rice milk powder is the dissolved slurries of water manufactured powder material after dry milling.
Wherein, the rice selects glutinous rice.
Wherein, a kind of cement additive suitable for municipal works, preparation method includes the following steps:
Step 1: by the weight ratio claim rice milk powder, cellulose ether and palygorskite powder are put into container, convert suitable quantity of water into
Row mixing, stirs evenly, obtains mixed liquor；
Step 2: claiming to obtain gypsum, boron mud, flyash and diatomite by the weight ratio, carry out grinding using flour mill, obtain
Mixed powder；
Step 3: mixed liquor and mixed powder being mixed, stirred evenly, and paraffin wax emulsions and manosil AS are added while stirring
Salt obtains mixture；
Step 4: rear grinding is dried in mixture；
Step 5: the weight ratio water-reducing agent is added and stirs evenly to get cement additive powdery finished product.
In conclusion by adopting the above-described technical solution, the beneficial effects of the present invention are:
1, in the present invention, the preparation method of cement additive, simple and easy, raw material is easy to get, cheap, to equipment and instead
Answer condition of less demanding, the cement after addition has the characteristics that preferable waterproof, crack resistence, high intensity and performance are stable.
2, in the present invention, by the way that palygorskite powder is added, is conducive to the emulsification and bonding between raw material, is added to energy in cement
Enough greatly increase the adhesive property, antistrip performance and waterproof effect of cement, at the same palygorskite powder also have preferable suspension,
Levelability and thickening property, and hence it is also possible to greatly reduce consumption of raw materials instead of original suspending agent, thickener and stabilizer
And cost of material.
3, the present invention in, by be added cellulose ether so that addition after cement have preferable high temperature performance and compared with
Good adhesion property, additionally it is possible to so that it with preferable crack resistance at low-temperature, is effectively prevented caused by being cracked as cement
Building tear, phenomena such as collapsing.
4, in the present invention, made cement additive overcomes and has a single function existing for conventional additive agent, and volume is big,
It improves and improves strength on concrete material, mobility, durability and the unconspicuous problem of anti-permeability performance effect, so that concrete material
Expect that intensity, mobility, durability and anti-permeability performance effect are more significant, volume is less, is plasticized the superior advantage of performance, can be obvious
Increase the slump of concrete, improves concrete cohesiveness and workability.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, the present invention is carried out below further
It is described in detail.It should be appreciated that described herein, specific examples are only used to explain the present invention, is not intended to limit the present invention.
Embodiment one: a kind of cement additive suitable for municipal works, including following weight ratio raw material: gypsum 10~
30%, palygorskite powder 5~15%, rice milk powder 5~10%, boron mud 1~10%, flyash 5~10%, aluminosilicate 1~10%,
Paraffin wax emulsions 5~10%, diatomite 5~15%, cellulose ether 1~5%, water-reducing agent 5~10%.
Each raw material weight percentage are as follows: gypsum 25%, palygorskite 15%, Rice & peanut milk 10%, boron mud 5%, flyash
10%, aluminosilicate 8%, paraffin wax emulsions 5%, diatomite 10%, cellulose ether 7%, water-reducing agent 5%.
The gypsum selects ardealite, and ardealite is the gypsum that the waste residue generated in chemical fertilizer factory's phosphoric acid producing process is produced；
The water-reducing agent selects poly carboxylic acid series water reducer；The palygorskite powder is that natural palygorskite obtains after purification, modification
Powder material.
Embodiment two: a kind of cement additive suitable for municipal works, including following weight ratio raw material: gypsum 10~
30%, palygorskite powder 5~15%, rice milk powder 5~10%, boron mud 1~10%, flyash 5~10%, aluminosilicate 1~10%,
Paraffin wax emulsions 5~10%, diatomite 5~15%, cellulose ether 1~5%, water-reducing agent 5~10%.
Each raw material weight percentage are as follows: gypsum 25%, palygorskite 15%, Rice & peanut milk 10%, boron mud 5%, flyash
10%, aluminosilicate 8%, paraffin wax emulsions 5%, diatomite 10%, cellulose ether 7%, water-reducing agent 5%.
The gypsum selects ardealite, and ardealite is the gypsum that the waste residue generated in chemical fertilizer factory's phosphoric acid producing process is produced；
The water-reducing agent selects poly carboxylic acid series water reducer；The palygorskite powder is that natural palygorskite obtains after purification, modification
Powder material.
The rice milk powder produce the following steps are included:
Step 1: taking appropriate rice, soak in water, impregnate 12~20 hours, steep mellow and full to expanding；
Step 2: the rice after immersion being put into the stewing steaming of steamer high temperature, boils in a covered pot over a slow fire and steams 200~300 DEG C of temperature, boil in a covered pot over a slow fire and steam 15~30
Minute；
Step 3: the rice taking-up after stewing steaming being watered and is rubbed, 30~40 DEG C of water temperature, incorporates in water, obtains until rice is broken
To mixture；
Step 4: mixture being filtered removal bulky grain deposit, is then dried, obtains powder agglomates；
Step 4: the powder agglomates after drying being subjected to grinding, obtains rice milk powder.
Embodiment three: a kind of cement additive suitable for municipal works, including following weight ratio raw material: gypsum 10~
30%, palygorskite powder 5~15%, rice milk powder 5~10%, boron mud 1~10%, flyash 5~10%, aluminosilicate 1~10%,
Paraffin wax emulsions 5~10%, diatomite 5~15%, cellulose ether 1~5%, water-reducing agent 5~10%.
Each raw material weight percentage are as follows: gypsum 25%, palygorskite 15%, Rice & peanut milk 10%, boron mud 5%, flyash
10%, aluminosilicate 8%, paraffin wax emulsions 5%, diatomite 10%, cellulose ether 7%, water-reducing agent 5%.
The gypsum selects ardealite, and ardealite is the gypsum that the waste residue generated in chemical fertilizer factory's phosphoric acid producing process is produced；
The water-reducing agent selects poly carboxylic acid series water reducer；The palygorskite powder is that natural palygorskite obtains after purification, modification
Powder material.
The rice milk powder produce the following steps are included:
Step 1: taking appropriate rice, soak in water, impregnate 12~20 hours, steep mellow and full to expanding；
Step 2: the rice after immersion being put into the stewing steaming of steamer high temperature, boils in a covered pot over a slow fire and steams 200~300 DEG C of temperature, boil in a covered pot over a slow fire and steam 15~30
Minute；
Step 3: the rice taking-up after stewing steaming being watered and is rubbed, 30~40 DEG C of water temperature, incorporates in water, obtains until rice is broken
To mixture；
Step 4: mixture being filtered removal bulky grain deposit, is then dried, obtains powder agglomates；
Step 4: the powder agglomates after drying being subjected to grinding, obtains rice milk powder.
The rice selects glutinous rice, and glutinous rice is to harvest glutinous rice in 3 years.
Example IV: a kind of cement additive suitable for municipal works, including following weight ratio raw material: gypsum 10~
30%, palygorskite powder 5~15%, rice milk powder 5~10%, boron mud 1~10%, flyash 5~10%, aluminosilicate 1~10%,
Paraffin wax emulsions 5~10%, diatomite 5~15%, cellulose ether 1~5%, water-reducing agent 5~10%.
Each raw material weight percentage are as follows: gypsum 25%, palygorskite 15%, Rice & peanut milk 10%, boron mud 5%, flyash
10%, aluminosilicate 8%, paraffin wax emulsions 5%, diatomite 10%, cellulose ether 7%, water-reducing agent 5%.
The gypsum selects ardealite, and ardealite is the gypsum that the waste residue generated in chemical fertilizer factory's phosphoric acid producing process is produced；
The water-reducing agent selects poly carboxylic acid series water reducer；The palygorskite powder is that natural palygorskite obtains after purification, modification
Powder material.
The rice milk powder produce the following steps are included:
Step 1: taking appropriate rice, soak in water, impregnate 12~20 hours, steep mellow and full to expanding；
Step 2: the rice after immersion being put into the stewing steaming of steamer high temperature, boils in a covered pot over a slow fire and steams 200~300 DEG C of temperature, boil in a covered pot over a slow fire and steam 15~30
Minute；
Step 3: the rice taking-up after stewing steaming being watered and is rubbed, 30~40 DEG C of water temperature, incorporates in water, obtains until rice is broken
To mixture；
Step 4: mixture being filtered removal bulky grain deposit, is then dried, obtains powder agglomates；
Step 4: the powder agglomates after drying being subjected to grinding, obtains rice milk powder.
The rice selects glutinous rice, and glutinous rice is to harvest glutinous rice in 3 years.
The preparation of the palygorskite powder the following steps are included:
Step 1: taking natural palygorskite, crushed using ball mill；
Step 2: smashed palygorskite powder being watered and is stirred evenly, stands 15~30 minutes；
Step 3: the solution after standing being handled using ultrasonic wave, is handled the time 20~30 minutes；
Step 4: stirring filters out surface layer floating material；
Step 5: being put into dryer and be dried, then carry out grinding using flour mill, can be prepared by palygorskite
Powder.
Embodiment five: a kind of cement additive suitable for municipal works, including following weight ratio raw material: gypsum 10~
30%, palygorskite powder 5~15%, rice milk powder 5~10%, boron mud 1~10%, flyash 5~10%, aluminosilicate 1~10%,
Paraffin wax emulsions 5~10%, diatomite 5~15%, cellulose ether 1~5%, water-reducing agent 5~10%.
Each raw material weight percentage are as follows: gypsum 25%, palygorskite 15%, Rice & peanut milk 10%, boron mud 5%, flyash
10%, aluminosilicate 8%, paraffin wax emulsions 5%, diatomite 10%, cellulose ether 7%, water-reducing agent 5%.
The gypsum selects ardealite, and ardealite is the gypsum that the waste residue generated in chemical fertilizer factory's phosphoric acid producing process is produced；
The water-reducing agent selects poly carboxylic acid series water reducer；The palygorskite powder is that natural palygorskite obtains after purification, modification
Powder material.
The rice milk powder produce the following steps are included:
Step 1: taking appropriate rice, soak in water, impregnate 12~20 hours, steep mellow and full to expanding；
Step 2: the rice after immersion being put into the stewing steaming of steamer high temperature, boils in a covered pot over a slow fire and steams 200~300 DEG C of temperature, boil in a covered pot over a slow fire and steam 15~30
Minute；
Step 3: the rice taking-up after stewing steaming being watered and is rubbed, 30~40 DEG C of water temperature, incorporates in water, obtains until rice is broken
To mixture；
Step 4: mixture being filtered removal bulky grain deposit, is then dried, obtains powder agglomates；
Step 4: the powder agglomates after drying being subjected to grinding, obtains rice milk powder.
The rice selects glutinous rice, and glutinous rice is to harvest glutinous rice in 3 years.
The preparation of the palygorskite powder the following steps are included:
Step 1: taking natural palygorskite, crushed using ball mill；
Step 2: smashed palygorskite powder being watered and is stirred evenly, stands 15~30 minutes；
Step 3: the solution after standing being handled using ultrasonic wave, is handled the time 20~30 minutes；
Step 4: stirring filters out surface layer floating material；
Step 5: being put into dryer and be dried, then carry out grinding using flour mill, can be prepared by palygorskite
Powder.
The preparation method of the cement additive the following steps are included:
Step 1: by the weight ratio claim rice milk powder, cellulose ether and palygorskite powder are put into container, convert suitable quantity of water into
Row mixing, stirs evenly, obtains mixed liquor；
Step 2: claiming to obtain gypsum, boron mud, flyash and diatomite by the weight ratio, carry out grinding using flour mill, obtain
Mixed powder；
Step 3: mixed liquor and mixed powder being mixed, stirred evenly, and paraffin wax emulsions and manosil AS are added while stirring
Salt obtains mixture；
Step 4: rear grinding is dried in mixture；
Step 5: the weight ratio water-reducing agent is added and stirs evenly to get cement additive powdery finished product.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention
Made any modifications, equivalent replacements, and improvements etc., should all be included in the protection scope of the present invention within mind and principle.
Claims (9)
1. a kind of cement additive suitable for municipal works, which is characterized in that including following weight ratio raw material: gypsum 10~
30%, palygorskite powder 5~15%, rice milk powder 5~10%, boron mud 1~10%, flyash 5~10%, aluminosilicate 1~10%,
Paraffin wax emulsions 5~10%, diatomite 5~15%, cellulose ether 1~5%, water-reducing agent 5~10%.
2. a kind of cement additive suitable for municipal works as described in claim 1, which is characterized in that each raw material weight
Measure percentage are as follows: gypsum 25%, palygorskite 15%, Rice & peanut milk 10%, boron mud 5%, flyash 10%, aluminosilicate 8%, paraffin cream
Liquid 5%, diatomite 10%, cellulose ether 7%, water-reducing agent 5%.
3. a kind of cement additive suitable for municipal works as claimed in claim 2, which is characterized in that the gypsum is selected
Ardealite, ardealite are the gypsum that the waste residue generated in chemical fertilizer factory's phosphoric acid producing process is produced.
4. a kind of cement additive suitable for municipal works as described in claim 1, which is characterized in that the water-reducing agent choosing
Use poly carboxylic acid series water reducer.
5. a kind of cement additive suitable for municipal works as claimed in claim 2, which is characterized in that the palygorskite powder
The powder material obtained after purification, modification for natural palygorskite.
6. a kind of cement additive suitable for municipal works as claimed in claim 2, which is characterized in that the rice milk powder is
It is made after water logging, stewing steaming, water dissolution by rice.
7. a kind of cement additive suitable for municipal works as claimed in claim 6, which is characterized in that the rice milk powder is
The dissolved slurries of water manufactured powder material after dry milling.
8. a kind of cement additive suitable for municipal works as claimed in claim 6, which is characterized in that the rice is selected
Glutinous rice.
9. a kind of cement additive suitable for municipal works as described in claim 1~8 is any, which is characterized in that it is made
Preparation Method the following steps are included:
Step 1: by the weight ratio claim rice milk powder, cellulose ether and palygorskite powder are put into container, convert suitable quantity of water and mixed
It closes, stirs evenly, obtain mixed liquor；
Step 2: claiming to obtain gypsum, boron mud, flyash and diatomite by the weight ratio, carry out grinding using flour mill, must mix
Powder；
Step 3: mixed liquor and mixed powder being mixed, stirred evenly, and paraffin wax emulsions and aluminosilicate are added while stirring, is obtained
Mixture；
Step 4: rear grinding is dried in mixture；
Step 5: the weight ratio water-reducing agent is added and stirs evenly to get cement additive powdery finished product.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201910502453.7A CN110143780A (en) | 2019-06-11 | 2019-06-11 | A kind of cement additive suitable for municipal works |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910502453.7A CN110143780A (en) | 2019-06-11 | 2019-06-11 | A kind of cement additive suitable for municipal works |
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Family
ID=67590981
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Citations (3)
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| CN106830852A (en) * | 2017-04-06 | 2017-06-13 | 卢文书 | A kind of potent waterproof material of waterborne general |
| CN106927714A (en) * | 2017-03-29 | 2017-07-07 | 合肥天沃能源科技有限公司 | A kind of cement additire and preparation method |
| CN107500706A (en) * | 2017-09-13 | 2017-12-22 | 德阳艺空装饰设计有限公司 | A kind of environment-friendly type construction decoration material |
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2019
- 2019-06-11 CN CN201910502453.7A patent/CN110143780A/en active Pending
Patent Citations (3)
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| CN106927714A (en) * | 2017-03-29 | 2017-07-07 | 合肥天沃能源科技有限公司 | A kind of cement additire and preparation method |
| CN106830852A (en) * | 2017-04-06 | 2017-06-13 | 卢文书 | A kind of potent waterproof material of waterborne general |
| CN107500706A (en) * | 2017-09-13 | 2017-12-22 | 德阳艺空装饰设计有限公司 | A kind of environment-friendly type construction decoration material |
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Application publication date: 20190820 |