CN110128907A - A kind of heat reflection coating and preparation method thereof - Google Patents
A kind of heat reflection coating and preparation method thereof Download PDFInfo
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- CN110128907A CN110128907A CN201910291138.4A CN201910291138A CN110128907A CN 110128907 A CN110128907 A CN 110128907A CN 201910291138 A CN201910291138 A CN 201910291138A CN 110128907 A CN110128907 A CN 110128907A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/02—Polyureas
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- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/004—Reflecting paints; Signal paints
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- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The present invention relates to a kind of heat reflection coatings, it is made of following substances in weight percentage: schmigel 0-10%, diamond dust 3-10%, carborundum powder 2-10%, self-luminescence powder 0-5%, silester 8-15%, sepiolite 5.5-8%, lubricant 3-7%, aqueous polyureas 15-25%, hollow glass micropearl 10-35%, graphene fiber 4.1-6.8%, rare earth 1.1-5.5%, hydroxypropyl methyl cellulose ether 8-17%, coupling agent 0.1-0.5%, dispersing agent 0.1-0.3%, pigment 0-8%, fungicide 1-8%, dedusting agent 0.2% -3%, surplus is modified resin.Preparation method includes hollow glass micropearl pretreatment, inorganic material mixing, four steps such as organic materials mixing and encapsulation.It is convenient that raw material of the present invention obtains, and raw material and low processing cost, toxic side effect is small, and producing process is simple, can greatly improve the synthesis service performance of coating and has reduced the operation and maintenance cost of coating.
Description
Technical field
The present invention relates to a kind of heat reflection coatings and preparation method thereof, belong to construction and anticorrosive construction technical field.
Background technique
In the various fields such as building, road and mechanical equipment, in order to effectively prevent heat radiation to building and machinery
Equipment etc. impacts, by coating such as asbestos, ceramic fiber cotton, glass for building or mechanical equipment surface when current main
The structures such as cellucotton and aluminium foil are thermally shielded protection, and when this class formation often exists in various degree, structure is complicated, difficulty of construction
The defects of big and external force resistance damage scarce capacity, seriously affected the heat-insulated protective capacities to building, equipment etc., furthermore currently this
The heat-insulated safeguard structure of class can not effectively meet the usage amounts such as precision equipment and road and the big occasion and equipment of abrasion loss
It uses, and is directed to this problem, although currently also developing a variety of heat-insulated paintings based on based on the high molecular polymers such as resin
Layer material, such as application No. is: 201580052163.7 and application No. is: described in 201810778056.8 patented technology
Such has the coating of heat reflection effect and its production or using technology, but finds in actual use, currently used
On the one hand to there is heat-insulating capability in all kinds of coating for having heat-insulating capability relatively poor in various degree, while there is also using
Cheng Zhong, phenomena such as easily damaging, crack and fall off because of external impacts, chemical attack and high temperature ablation and cryogenic freezing,
It is extremely limited and coating use to while causing heat-insulated protective capacities to decline, also result in coating use environment
With the relatively higher defect of maintenance cost, on the other hand it is currently used have heat reflection coating there is also density and from
Weight is relatively large, transhipment, the deficiencies of construction cost and labor intensity are high.
Therefore it is directed to this status, there is an urgent need to a kind of completely new figure layers for having heat reflection ability and its preparation side
Method, to meet the needs of actual use.
Summary of the invention
The object of the invention, which is that, overcomes above-mentioned deficiency, provides a kind of heat reflection coating and preparation method thereof.
To achieve the above object, the present invention is to be achieved through the following technical solutions:
A kind of heat reflection coating, is made of following substances in weight percentage: schmigel 0-10%, diamond dust 3-10%,
Carborundum powder 2-10%, self-luminescence powder 0-5%, silester 8-15%, sepiolite 5.5-8%, lubricant 3-7%, water
Property polyureas 15-25%, hollow glass micropearl 10-35%, graphene fiber 4.1-6.8%, rare earth 1.1-5.5%, hydroxypropyl
Ylmethyl cellulose ether 8-17%, coupling agent 0.1-0.5%, dispersing agent 0.1-0.3%, pigment 0-8%, fungicide 1-
8%, dedusting agent 0.2% -3%, surplus are modified resin.
Further, the schmigel, diamond dust, carborundum powder, sepiolite, rare earth are 100-500 mesh solid powders
Structure；The hollow glass micropearl average diameter is 0.28-0.5 μm, and compression strength is not less than 125MPa, the graphene
Fibre length is 0.1-1 millimeter.
Further, the coupling agent is silane coupling agent, titanate esters, any one in Aluminate；The lubricant
It is mixed for any one or a few in mineral oil, vegetable oil, polymeric alcohol, elastic graphite with arbitrary proportion；The dispersing agent is
High molecular weight is saturated the salt that polycarboxylic acids and amine derivative generate.
Further, the self-luminescence powder is rare earth self-luminescence powder.
Further, the pigment is any one in organic pigment and inorganic pigment.
Further, the dedusting agent is silica solution；The fungicide is silver oxide, any one in titanium oxide.
Further, the viscosity of the hydroxypropyl methyl cellulose ether is 50000-100000.
Further, the modified resin be epoxy resin, polyurethane, in acrylic resin any one or a few with
Arbitrary proportion mixing.
A kind of preparation method of heat reflection coating, comprising the following steps:
S1, hollow glass micropearl pretreatment, is added to the carbonic acid that concentration is 20% -40% for hollow glass micropearl first
In sodium solution, and ultrasonic cleaning 10-30 minutes in 20 DEG C-60 DEG C of isoperibol, then by the hollow glass after cleaning
Glass microballon is dried under 100 DEG C -300 DEG C isoperibols, and the hollow glass micropearl after drying is at the uniform velocity then added to concentration and is
0.1-3% sulfuric acid and concentration is in the mixed liquor of 0.5-1.5% hydrofluoric acid, and at the uniform velocity single in 20 DEG C-30 DEG C isoperibols
To being stirred 1-3.5 minutes, finally hollow glass micropearl is pulled out and by 50 DEG C-100 DEG C of deionized water to hollow glass
Glass microballon carries out spray cleaning, until hollow glass micropearl surface pH value is neutrality, then hollow glass micropearl is dipped into temperature
It is saved backup for constant temperature in 50 DEG C -100 DEG C of deionized waters；Then aqueous polyureas total amount 20% -35% and be heated to
450 DEG C -800 DEG C, then the hollow glass micropearl in preservation is directly appended in the aqueous polyureas after heating, and ultrasonic wave
Homogeneous is uniformly mixed, and then takes diamond dust total amount 10% -28% to be added in polyureas and hollow glass micropearl mixture and ultrasonic
Wave homogeneous is uniformly mixed, and then carries out mist projection granulating to mixture and drying to water content is not more than 3%, obtain diameter and be not more than
0.1 millimeter of Filled With Hollow Bead particle；
S2, inorganic material mixing, by schmigel, the diamond dust of remainder, carborundum powder, self-luminescence powder, sepiolite, stone
Black alkene fiber, rare earth, pigment, fungicide and S1 step, which are prepared Filled With Hollow Bead particle and are added to stirring, to be set
It in standby, and is at the uniform velocity stirred 10-30 minutes with 300-500 revs/min of revolving speeds, acquisition is uniformly mixed electrodeless mixture；
S3, organic materials mixing, by silester, lubricant, remaining aqueous polyureas, hydroxypropyl methyl cellulose ether, idol
Connection agent, dispersing agent, dedusting agent and modified resin are arrived together in heating reaction kettle, with 300-500 under atmosphere of inert gases
While rev/min revolving speed at the uniform velocity stirs, 500 DEG C-750 DEG C, and insulated and stirred 10-are at the uniform velocity warming up to 10-35 DEG C/minute
35 minutes；
S4, encapsulation, the electrodeless mixture that S2 step is obtained at the uniform velocity are added in the organic mixture of S3 step preparation, and
The ultrasonic wave homogenization 10-40 minutes under 500 DEG C-750 DEG C isoperibols, it is constant and naturally cold to be then kept stirring state
But to 20 DEG C-35 DEG C, finally by mixture after cooling under the inert gas driving that pressure is 5-10 times of standard atmospheric pressures
It is sealed in loading sealing hard support container and to closed hard support container, can be obtained finished product heat reflection coating,
And the air pressure in finished product product in hard support container is 2-8 times of standard atmospheric pressures.
It is convenient that raw material of the present invention obtains, and raw material and low processing cost, toxic side effect is small, and producing process is simple, and one
Aspect can effective coating heat-insulating capability and heat reflection ability, on the other hand effectively raise the attachment bonding energy of coating
Power, external force resistance damage, resist chemical and high temperature, low temperature erosion damage ability, additionally effectively reduce the close of coating
Degree and self weight, improve the convenience of coating transhipment and construction operation, and effectively reduce transhipment and construction cost, thus pole
The big synthesis service performance for improving coating and the operation and maintenance cost for reducing coating.
Detailed description of the invention
Fig. 1 is the method for the present invention flow diagram.
Specific embodiment
Embodiment 1
A kind of heat reflection coating, is made of following substances in weight percentage: diamond dust 3%, carborundum powder 2%, silicic acid
Ethyl ester 8%, sepiolite 5.5%%, lubricant 3%, aqueous polyureas 15%, hollow glass micropearl 10%, graphene fiber
4.1%, rare earth 1.1%, hydroxypropyl methyl cellulose ether 8%, coupling agent 0.1%, dispersing agent 0.1%, fungicide 1%, dedusting
Agent 0.2%, surplus are modified resin.
Wherein, the diamond dust, carborundum powder, sepiolite, rare earth are 100 mesh solid powder structures；The hollow glass
Glass microballon average diameter is 0.28 μm, and compression strength is not less than 125MPa, and the graphene fiber length is 0.1 millimeter.
In addition, the coupling agent is silane coupling agent；The lubricant is mineral oil；The dispersing agent is full for high molecular weight
The salt generated with polycarboxylic acids and amine derivative.
Meanwhile the dedusting agent is silica solution；The fungicide is silver oxide, the hydroxypropyl methyl cellulose ether
Viscosity is 50000, and the modified resin is epoxy resin.
A kind of preparation method of heat reflection coating, comprising the following steps:
S1, hollow glass micropearl pretreatment, is added to the sodium carbonate liquor that concentration is 20% for hollow glass micropearl first
In, and ultrasonic cleaning 10 minutes in 20 DEG C of isoperibol, then by the hollow glass micropearl after cleaning in 100 DEG C of constant temperature
It is dried under environment, then the hollow glass micropearl after drying is at the uniform velocity added to concentration is 0.1% sulfuric acid and concentration is 0.5% hydrogen
It in the mixed liquor of fluoric acid, and is at the uniform velocity unidirectionally stirred 1 minute in 20 DEG C of isoperibols, finally pulls hollow glass micropearl out
And spray cleaning is carried out to hollow glass micropearl by 50 DEG C of deionized water, until hollow glass micropearl surface pH value is neutrality,
Hollow glass micropearl constant temperature in the deionized water that temperature is 50 DEG C is dipped into again to save backup；Then aqueous polyureas total amount
20% and 450 DEG C are heated to, then the hollow glass micropearl in preservation is directly appended in the aqueous polyureas after heating, and surpasses
Sound wave homogeneous is uniformly mixed, and diamond dust total amount 10% is then taken to be added in polyureas and hollow glass micropearl mixture simultaneously ultrasonic wave
Homogeneous is uniformly mixed, and then carries out mist projection granulating to mixture and drying to water content is not more than 3%, obtain diameter and be not more than
0.1 millimeter of Filled With Hollow Bead particle；
S2, inorganic material mixing, by the diamond dust of remainder, carborundum powder, sepiolite, graphene fiber, rare earth, is killed
Microbial inoculum and S1 step are prepared Filled With Hollow Bead particle and are added in mixing plant, and are turned with 500 revs/min
Speed at the uniform velocity stirs 10 minutes, and acquisition is uniformly mixed electrodeless mixture；
S3, organic materials mixing, by silester, lubricant, remaining aqueous polyureas, hydroxypropyl methyl cellulose ether, idol
Connection agent, dispersing agent, dedusting agent and modified resin are arrived together in heating reaction kettle, with 300 revs/min under atmosphere of inert gases
While revolving speed at the uniform velocity stirs, 500 DEG C, and insulated and stirred 10 minutes are at the uniform velocity warming up to 10 DEG C/minute；
S4, encapsulation, the electrodeless mixture that S2 step is obtained at the uniform velocity are added in the organic mixture of S3 step preparation, and
Ultrasonic wave homogenization 10 minutes under 500 DEG C of isoperibols, it is constant and naturally cool to 20 DEG C to be then kept stirring state, most
Afterwards by mixture after cooling under the inert gas driving that pressure is 5 times of standard atmospheric pressures in loading sealing hard support container
And closed hard support container is sealed, it can be obtained finished product heat reflection coating, and hard carrying is held in finished product product
Air pressure in device is 2 times of standard atmospheric pressures.
Embodiment 2
A kind of heat reflection coating, is made of following substances in weight percentage: schmigel 10%, diamond dust 10%, carbonization
Silicon powder 10%, self-luminescence powder 5%, silester 15%, sepiolite 8%, lubricant 7%, aqueous polyureas 25%, hollow glass are micro-
Pearl 35%, graphene fiber 6.8%, rare earth 5.5%, hydroxypropyl methyl cellulose ether 17%, coupling agent 0.5%, dispersing agent
0.3%, pigment 8%, fungicide 8%, dedusting agent 3%, surplus are modified resin.
In the present embodiment, the schmigel, diamond dust, carborundum powder, sepiolite, rare earth are 500 mesh solid powder knots
Structure；The hollow glass micropearl average diameter is 0.5 μm, and compression strength is not less than 125MPa, the graphene fiber length
It is 1 millimeter.
In the present embodiment, the coupling agent is titanate esters；The lubricant is vegetable oil；The dispersing agent is high molecular weight
It is saturated the salt that polycarboxylic acids and amine derivative generate, the self-luminescence powder is rare earth self-luminescence powder, and the pigment is organic pigment.
In addition, the dedusting agent is silica solution；The fungicide is titanium oxide, the hydroxypropyl methyl cellulose ether
Viscosity is 100000.
At the same time, the modified resin is polyurethane.
A kind of preparation method of heat reflection coating, comprising the following steps:
S1, hollow glass micropearl pretreatment, is added to the sodium carbonate liquor that concentration is 40% for hollow glass micropearl first
In, and ultrasonic cleaning 30 minutes in 60 DEG C of isoperibol, then by the hollow glass micropearl after cleaning in 300 DEG C of constant temperature
It is dried under environment, then the hollow glass micropearl after drying is at the uniform velocity added to concentration is 3% sulfuric acid and concentration is 1.5% hydrogen fluorine
It in the mixed liquor of acid, and is at the uniform velocity unidirectionally stirred 3.5 minutes in 30 DEG C of isoperibols, finally pulls hollow glass micropearl out
And spray cleaning is carried out to hollow glass micropearl by 100 DEG C of deionized water, until hollow glass micropearl surface pH value is neutrality,
Hollow glass micropearl constant temperature in the deionized water that temperature is 100 DEG C is dipped into again to save backup；Then aqueous polyureas total amount
35% and be heated to 800 DEG C, then by the hollow glass micropearl in preservation be directly appended to heating after aqueous polyureas in, and
Ultrasonic wave homogeneous is uniformly mixed, and then takes diamond dust total amount 28% to be added in polyureas and hollow glass micropearl mixture and ultrasonic
Wave homogeneous is uniformly mixed, and then carries out mist projection granulating to mixture and drying to water content is not more than 3%, obtain diameter and be not more than
0.1 millimeter of Filled With Hollow Bead particle；
S2, inorganic material mixing, by schmigel, the diamond dust of remainder, carborundum powder, self-luminescence powder, sepiolite, stone
Black alkene fiber, rare earth, pigment, fungicide and S1 step, which are prepared Filled With Hollow Bead particle and are added to stirring, to be set
It in standby, and is at the uniform velocity stirred 30 minutes with 500 revs/min of revolving speeds, acquisition is uniformly mixed electrodeless mixture；
S3, organic materials mixing, by silester, lubricant, remaining aqueous polyureas, hydroxypropyl methyl cellulose ether, idol
Connection agent, dispersing agent, dedusting agent and modified resin are arrived together in heating reaction kettle, with 500 revs/min under atmosphere of inert gases
While revolving speed at the uniform velocity stirs, 750 DEG C, and insulated and stirred 35 minutes are at the uniform velocity warming up to 35 DEG C/minute；
S4, encapsulation, the electrodeless mixture that S2 step is obtained at the uniform velocity are added in the organic mixture of S3 step preparation, and
Ultrasonic wave homogenization 40 minutes under 750 DEG C of isoperibols, it is constant and naturally cool to 35 DEG C to be then kept stirring state, most
Afterwards by mixture after cooling under the inert gas driving that pressure is 10 times of standard atmospheric pressures loading sealing hard support container
In and closed hard support container is sealed, can be obtained finished product heat reflection coating, and in finished product product hard carry
Air pressure in container is 8 times of standard atmospheric pressures.
In the present solution, the components such as schmigel, diamond dust, carborundum powder, aqueous polyureas and hollow glass micropearl can be being passed through
It is effective to improve heat reflection coating structure intensity, supplemental stability Nian Jie with body surface and heat-insulated and heat reflection same
When, it is effective to improve heat reflection coating surface self-cleaning ability and sterilizing ability, prevent dust, drop etc. to apply in heat reflection
Layer surface deposition and caused by pollution and corrode caused by heat reflection coating, can additionally pass through sepiolite and hollow glass
The density and self weight of heat reflection coating is effectively reduced in microballon, and it is anti-thermal energy can be adjusted flexibly by pigment and self-luminescence powder component
The appearance color of coating is penetrated, and heat reflection coating is made to have the work that decoration and mark are played in the self-luminous under low brightness condition
With.
Embodiment 3
A kind of heat reflection coating, is made of following substances in weight percentage: schmigel 1%, diamond dust 5%, silicon carbide
Powder 5%, self-luminescence powder 1%, silester 10%, sepiolite 6%, lubricant 5%, aqueous polyureas 18%, hollow glass micropearl
15%, graphene fiber 5%, rare earth 2.5%, hydroxypropyl methyl cellulose ether 10%, coupling agent 0.3%, dispersing agent 0.2%,
Pigment 7%, fungicide 3%, dedusting agent 1.5%, surplus are modified resin.
In the present embodiment, the schmigel, diamond dust, carborundum powder, sepiolite, rare earth are 300 mesh solid powder knots
Structure；The hollow glass micropearl average diameter is 0.3 μm, and compression strength is not less than 125MPa, the graphene fiber length
It is 0.5 millimeter.
Meanwhile the coupling agent is Aluminate；The lubricant is polymeric alcohol；The dispersing agent is that high molecular weight saturation is poly-
The salt that carboxylic acid and amine derivative generate, the self-luminescence powder are rare earth self-luminescence powder, and the pigment is inorganic pigment.
In addition, the dedusting agent is silica solution；The fungicide is silver oxide, the hydroxypropyl methyl cellulose ether
Viscosity is 60000, and the modified resin is acrylic resin.
A kind of preparation method of heat reflection coating, comprising the following steps:
S1, hollow glass micropearl pretreatment, is added to the sodium carbonate liquor that concentration is 30% for hollow glass micropearl first
In, and ultrasonic cleaning 11 minutes in 40 DEG C of isoperibol, then by the hollow glass micropearl after cleaning in 150 DEG C of constant temperature
It is dried under environment, then the hollow glass micropearl after drying is at the uniform velocity added to concentration is 1.5% sulfuric acid and concentration is 0.8% hydrogen
It in the mixed liquor of fluoric acid, and is at the uniform velocity unidirectionally stirred 2.5 minutes in 25 DEG C of isoperibols, finally fishes out hollow glass micropearl
Spray cleaning is carried out out and by 80 DEG C of deionized water to hollow glass micropearl, in hollow glass micropearl surface pH value is
Property, then hollow glass micropearl is dipped into constant temperature in the deionized water that temperature is 80 DEG C and is saved backup；Then aqueous polyureas is total
Amount 27% and be heated to 600 DEG C, then by the hollow glass micropearl in preservation be directly appended to heating after aqueous polyureas in,
And ultrasonic wave homogeneous is uniformly mixed, and diamond dust total amount 18% is then taken to be added to polyureas and in hollow glass micropearl mixture and surpass
Sound wave homogeneous is uniformly mixed, and then carries out mist projection granulating to mixture and drying to water content is not more than 3%, it is little to obtain diameter
In 0.1 millimeter of Filled With Hollow Bead particle；
S2, inorganic material mixing, by schmigel, the diamond dust of remainder, carborundum powder, self-luminescence powder, sepiolite, stone
Black alkene fiber, rare earth, pigment, fungicide and S1 step, which are prepared Filled With Hollow Bead particle and are added to stirring, to be set
It in standby, and is at the uniform velocity stirred 15 minutes with 350 revs/min of revolving speeds, acquisition is uniformly mixed electrodeless mixture；
S3, organic materials mixing, by silester, lubricant, remaining aqueous polyureas, hydroxypropyl methyl cellulose ether, idol
Connection agent, dispersing agent, dedusting agent and modified resin are arrived together in heating reaction kettle, with 400 revs/min under atmosphere of inert gases
While revolving speed at the uniform velocity stirs, 600 DEG C, and insulated and stirred 15 minutes are at the uniform velocity warming up to 25 DEG C/minute；
S4, encapsulation, the electrodeless mixture that S2 step is obtained at the uniform velocity are added in the organic mixture of S3 step preparation, and
Ultrasonic wave homogenization 30 minutes under 650 DEG C of isoperibols, it is constant and naturally cool to 25 DEG C to be then kept stirring state, most
Afterwards by mixture after cooling under the inert gas driving that pressure is 6 times of standard atmospheric pressures in loading sealing hard support container
And closed hard support container is sealed, it can be obtained finished product heat reflection coating, and hard carrying is held in finished product product
Air pressure in device is 4 times of standard atmospheric pressures.
In the present solution, the components such as schmigel, diamond dust, carborundum powder, aqueous polyureas and hollow glass micropearl can be being passed through
It is effective to improve heat reflection coating structure intensity, supplemental stability Nian Jie with body surface and heat-insulated and heat reflection same
When, it is effective to improve heat reflection coating surface self-cleaning ability and sterilizing ability, prevent dust, drop etc. to apply in heat reflection
Layer surface deposition and caused by pollution and corrode caused by heat reflection coating, can additionally pass through sepiolite and hollow glass
The density and self weight of heat reflection coating is effectively reduced in microballon, and it is anti-thermal energy can be adjusted flexibly by pigment and self-luminescence powder component
The appearance color of coating is penetrated, and heat reflection coating is made to have the work that decoration and mark are played in the self-luminous under low brightness condition
With.
Embodiment 4
A kind of heat reflection coating, is made of following substances in weight percentage: corundum 4%, diamond dust 7%, carborundum powder
9%, self-luminescence powder 4.5%, silester 9%, sepiolite 6.1%, lubricant 4.5%, aqueous polyureas 23%, hollow glass are micro-
Pearl 17%, graphene fiber 5.8%, rare earth 4.5%, hydroxypropyl methyl cellulose ether 11%, coupling agent 0.2%, dispersing agent
0.15%, pigment 6%, fungicide 4.3%, dedusting agent 2.8%, surplus are modified resin.
In the present embodiment, the schmigel, diamond dust, carborundum powder, sepiolite, rare earth are 350 mesh solid powder knots
Structure；The hollow glass micropearl average diameter is 0.3 μm, and compression strength is not less than 125MPa, the graphene fiber length
It is 0.2 millimeter.
Meanwhile in the coupling agent Aluminate；The lubricant is elastic graphite；The dispersing agent is high molecular weight saturation
The salt that polycarboxylic acids and amine derivative generate, the self-luminescence powder are rare earth self-luminescence powder, and the pigment is organic pigment.
In addition, the dedusting agent is silica solution；The fungicide is silver oxide, any one in titanium oxide.Further
, the viscosity of the hydroxypropyl methyl cellulose ether is 80000.
Further, the modified resin is epoxy resin and acrylic resin with the mixing of 1:2 ratio.
A kind of preparation method of heat reflection coating, comprising the following steps:
S1, hollow glass micropearl pretreatment, is added to the sodium carbonate liquor that concentration is 31% for hollow glass micropearl first
In, and ultrasonic cleaning 27 minutes in 55 DEG C of isoperibol, then by the hollow glass micropearl after cleaning in 260 DEG C of constant temperature
It is dried under environment, then the hollow glass micropearl after drying is at the uniform velocity added to concentration is 1.9% sulfuric acid and concentration is 1.3% hydrogen
It in the mixed liquor of fluoric acid, and is at the uniform velocity unidirectionally stirred 2.2 minutes in 21 DEG C of isoperibols, finally fishes out hollow glass micropearl
Spray cleaning is carried out out and by 48 DEG C of deionized water to hollow glass micropearl, in hollow glass micropearl surface pH value is
Property, then hollow glass micropearl is dipped into constant temperature in the deionized water that temperature is 70 DEG C and is saved backup；Then aqueous polyureas is total
Amount 23% and be heated to 640 DEG C, then by the hollow glass micropearl in preservation be directly appended to heating after aqueous polyureas in,
And ultrasonic wave homogeneous is uniformly mixed, and diamond dust total amount 22% is then taken to be added to polyureas and in hollow glass micropearl mixture and surpass
Sound wave homogeneous is uniformly mixed, and then carries out mist projection granulating to mixture and drying to water content is not more than 3%, it is little to obtain diameter
In 0.1 millimeter of Filled With Hollow Bead particle；
S2, inorganic material mixing, by schmigel, the diamond dust of remainder, carborundum powder, self-luminescence powder, sepiolite, stone
Black alkene fiber, rare earth, pigment, fungicide and S1 step, which are prepared Filled With Hollow Bead particle and are added to stirring, to be set
It in standby, and is at the uniform velocity stirred 21 minutes with 420 revs/min of revolving speeds, acquisition is uniformly mixed electrodeless mixture；
S3, organic materials mixing, by silester, lubricant, remaining aqueous polyureas, hydroxypropyl methyl cellulose ether, idol
Connection agent, dispersing agent, dedusting agent and modified resin are arrived together in heating reaction kettle, with 460 revs/min under atmosphere of inert gases
While revolving speed at the uniform velocity stirs, 700 DEG C, and insulated and stirred 30 minutes are at the uniform velocity warming up to 18 DEG C/minute；
S4, encapsulation, the electrodeless mixture that S2 step is obtained at the uniform velocity are added in the organic mixture of S3 step preparation, and
Ultrasonic wave homogenization 20 minutes under 600 DEG C of isoperibols, it is constant and naturally cool to 22 DEG C to be then kept stirring state, finally
By mixture after cooling under the inert gas driving that pressure is 7 times of standard atmospheric pressures in loading sealing hard support container simultaneously
Closed hard support container is sealed, can be obtained finished product heat reflection coating, and hard support container in finished product product
In air pressure be 7 times of standard atmospheric pressures.
In the present solution, the components such as schmigel, diamond dust, carborundum powder, aqueous polyureas and hollow glass micropearl can be being passed through
It is effective to improve heat reflection coating structure intensity, supplemental stability Nian Jie with body surface and heat-insulated and heat reflection same
When, it is effective to improve heat reflection coating surface self-cleaning ability and sterilizing ability, prevent dust, drop etc. to apply in heat reflection
Layer surface deposition and caused by pollution and corrode caused by heat reflection coating, can additionally pass through sepiolite and hollow glass
The density and self weight of heat reflection coating is effectively reduced in microballon, and it is anti-thermal energy can be adjusted flexibly by pigment and self-luminescence powder component
The appearance color of coating is penetrated, and heat reflection coating is made to have the work that decoration and mark are played in the self-luminous under low brightness condition
With.
Embodiment 5
A kind of heat reflection coating, is made of following substances in weight percentage: schmigel 9%, diamond dust 5%, silicon carbide
Powder 4%, self-luminescence powder 3%, silester 11%, sepiolite 6.1%, lubricant 5.4%, aqueous polyureas 17.5%, hollow glass
Glass microballon 26%, graphene fiber 5.7%, rare earth 4.5%, hydroxypropyl methyl cellulose ether 9.5%, coupling agent 0.4%, dispersion
Agent 0.2%, pigment 4%, fungicide 7.5%, dedusting agent 2.2%, surplus are modified resin.
Wherein, the schmigel, diamond dust, carborundum powder, sepiolite, rare earth are 450 mesh solid powder structures；It is described
Hollow glass micropearl average diameter is 0.3 μm, and compression strength is not less than 125MPa, and the graphene fiber length is 0.3 milli
Rice.
Meanwhile the coupling agent is silane coupling agent；The lubricant is that polymeric alcohol and elastic graphite are mixed with arbitrary proportion
It closes；The dispersing agent is the salt that high molecular weight is saturated that polycarboxylic acids and amine derivative generate.
In addition, the self-luminescence powder is rare earth self-luminescence powder, the pigment is inorganic pigment；The dedusting agent is that silicon is molten
Glue；The fungicide is silver oxide, and the viscosity of the hydroxypropyl methyl cellulose ether is 90000.
It advanced optimizes, the modified resin is epoxy resin, polyurethane, acrylic resin are mixed with arbitrary proportion.
A kind of preparation method of heat reflection coating, comprising the following steps:
S1, hollow glass micropearl pretreatment, is added to the sodium carbonate liquor that concentration is 31% for hollow glass micropearl first
In, and ultrasonic cleaning 15 minutes in 45 DEG C of isoperibol, then by the hollow glass micropearl after cleaning in 260 DEG C of constant temperature
It is dried under environment, then the hollow glass micropearl after drying is at the uniform velocity added to concentration is 2.3% sulfuric acid and concentration is 1.1% hydrogen
It in the mixed liquor of fluoric acid, and is at the uniform velocity unidirectionally stirred 1.5 minutes in 21 DEG C of isoperibols, finally fishes out hollow glass micropearl
Spray cleaning is carried out out and by 60 DEG C of deionized water to hollow glass micropearl, in hollow glass micropearl surface pH value is
Property, then hollow glass micropearl is dipped into constant temperature in the deionized water that temperature is 70 DEG C and is saved backup；Then aqueous polyureas is total
Amount 24% and be heated to 670 DEG C, then by the hollow glass micropearl in preservation be directly appended to heating after aqueous polyureas in,
And ultrasonic wave homogeneous is uniformly mixed, and diamond dust total amount 19% is then taken to be added to polyureas and in hollow glass micropearl mixture and surpass
Sound wave homogeneous is uniformly mixed, and then carries out mist projection granulating to mixture and drying to water content is not more than 3%, it is little to obtain diameter
In 0.1 millimeter of Filled With Hollow Bead particle；
S2, inorganic material mixing, by schmigel, the diamond dust of remainder, carborundum powder, self-luminescence powder, sepiolite, stone
Black alkene fiber, rare earth, pigment, fungicide and S1 step, which are prepared Filled With Hollow Bead particle and are added to stirring, to be set
It in standby, and is at the uniform velocity stirred 20 minutes with 400 revs/min of revolving speeds, acquisition is uniformly mixed electrodeless mixture；
S3, organic materials mixing, by silester, lubricant, remaining aqueous polyureas, hydroxypropyl methyl cellulose ether, idol
Connection agent, dispersing agent, dedusting agent and modified resin are arrived together in heating reaction kettle, with 350 revs/min under atmosphere of inert gases
While revolving speed at the uniform velocity stirs, 560 DEG C, and insulated and stirred 10-35 minutes are at the uniform velocity warming up to 25 DEG C/minute；
S4, encapsulation, the electrodeless mixture that S2 step is obtained at the uniform velocity are added in the organic mixture of S3 step preparation, and
Ultrasonic wave homogenization 30 minutes under 640 DEG C of isoperibols, it is constant and naturally cool to 25 DEG C to be then kept stirring state, most
Afterwards by mixture after cooling under the inert gas driving that pressure is 6 times of standard atmospheric pressures in loading sealing hard support container
And closed hard support container is sealed, it can be obtained finished product heat reflection coating, and hard carrying is held in finished product product
Air pressure in device is 3.5 times of standard atmospheric pressures.
In the present solution, the components such as schmigel, diamond dust, carborundum powder, aqueous polyureas and hollow glass micropearl can be being passed through
It is effective to improve heat reflection coating structure intensity, supplemental stability Nian Jie with body surface and heat-insulated and heat reflection same
When, it is effective to improve heat reflection coating surface self-cleaning ability and sterilizing ability, prevent dust, drop etc. to apply in heat reflection
Layer surface deposition and caused by pollution and corrode caused by heat reflection coating, can additionally pass through sepiolite and hollow glass
The density and self weight of heat reflection coating is effectively reduced in microballon, and it is anti-thermal energy can be adjusted flexibly by pigment and self-luminescence powder component
The appearance color of coating is penetrated, and heat reflection coating is made to have the work that decoration and mark are played in the self-luminous under low brightness condition
With.
In addition to this, the usage amounts such as diamond dust, polyureas are on the one hand effectively reduced, product cost is reduced, on the other hand
Can be adjusted by characteristic of the modified resin to polyureas, thus realize to the adhesive property of heat reflection coating, mobile performance,
The physics such as solidifiability, antioxygenic property, corrosion resistance, shock resistance and wear resistance and chemical property carry out whole
Adjustment.
It is convenient that raw material of the present invention obtains, and raw material and low processing cost, toxic side effect is small, and producing process is simple, and one
Aspect can effective coating heat-insulating capability and heat reflection ability, on the other hand effectively raise the attachment bonding energy of coating
Power, external force resistance damage, resist chemical and high temperature, low temperature erosion damage ability, additionally effectively reduce the close of coating
Degree and self weight, improve the convenience of coating transhipment and construction operation, and effectively reduce transhipment and construction cost, thus pole
The big synthesis service performance for improving coating and the operation and maintenance cost for reducing coating.
The above shows and describes the basic principles and main features of the present invention and the advantages of the present invention.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the above embodiments and description only describe this
The principle of invention, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these changes
Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its
Equivalent thereof.
Claims (9)
1. a kind of heat reflection coating, it is characterised in that: the heat reflection coating is made of following substances in weight percentage:
Schmigel 0-10%, diamond dust 3-10%, carborundum powder 2-10%, self-luminescence powder 0-5%, silester 8-15%, sea
Afrodite 5.5-8%, lubricant 3-7%, aqueous polyureas 15-25%, hollow glass micropearl 10-35%, graphene fiber
4.1-6.8%, rare earth 1.1-5.5%, hydroxypropyl methyl cellulose ether 8-17%, coupling agent 0.1-0.5%, dispersing agent
0.1-0.3%, pigment 0-8%, fungicide 1-8%, dedusting agent 0.2%-3%, surplus are modified resin.
2. a kind of heat reflection coating according to claim 1, it is characterised in that: the schmigel, diamond dust, silicon carbide
Powder, sepiolite, rare earth are 100-500 mesh solid powder structures；The hollow glass micropearl average diameter is 0.28-0.5 μ
M, compression strength are not less than 125MPa, and the graphene fiber length is 0.1-1 millimeter.
3. a kind of heat reflection coating according to claim 1, it is characterised in that: the coupling agent be silane coupling agent,
Any one in titanate esters, Aluminate；The lubricant is mineral oil, vegetable oil, polymeric alcohol, any one in elastic graphite
Kind or several mixed with arbitrary proportion；The dispersing agent is the salt that high molecular weight is saturated that polycarboxylic acids and amine derivative generate.
4. a kind of heat reflection coating according to claim 1, it is characterised in that: the self-luminescence powder is rare earth self-luminous
Powder.
5. a kind of heat reflection coating according to claim 1, it is characterised in that: the pigment is organic pigment and inorganic
Any one in pigment.
6. a kind of heat reflection coating according to claim 1, it is characterised in that: the dedusting agent is silica solution；It is described
Fungicide is silver oxide, any one in titanium oxide.
7. a kind of heat reflection coating according to claim 1, it is characterised in that: the hydroxypropyl methyl cellulose ether
Viscosity be 50000-100000.
8. a kind of heat reflection coating according to claim 1, it is characterised in that: the modified resin be epoxy resin,
Any one or a few in polyurethane, acrylic resin is mixed with arbitrary proportion.
9. a kind of preparation method of heat reflection coating, it is characterised in that: the high-performance protective spray based on polyurea matrix
The preparation method of coating layer the following steps are included:
It is molten to be added to the sodium carbonate that concentration is 20% -40% first by S1, hollow glass micropearl pretreatment for hollow glass micropearl
It is then that the hollow glass after cleaning is micro- in liquid, and ultrasonic cleaning 10-30 minutes in 20 DEG C-60 DEG C of isoperibol
Pearl is dried under 100 DEG C -300 DEG C isoperibols, and the hollow glass micropearl after drying is at the uniform velocity then added to concentration and is
0.1-3% sulfuric acid and concentration is in the mixed liquor of 0.5-1.5% hydrofluoric acid, and at the uniform velocity single in 20 DEG C-30 DEG C isoperibols
To being stirred 1-3.5 minutes, finally hollow glass micropearl is pulled out and by 50 DEG C-100 DEG C of deionized water to hollow glass
Glass microballon carries out spray cleaning, until hollow glass micropearl surface pH value is neutrality, then hollow glass micropearl is dipped into temperature
It is saved backup for constant temperature in 50 DEG C -100 DEG C of deionized waters；Then aqueous polyureas total amount 20% -35% and be heated to
450 DEG C -800 DEG C, then the hollow glass micropearl in preservation is directly appended in the aqueous polyureas after heating, and ultrasonic wave
Homogeneous is uniformly mixed, and then takes diamond dust total amount 10% -28% to be added in polyureas and hollow glass micropearl mixture and ultrasonic
Wave homogeneous is uniformly mixed, and then carries out mist projection granulating to mixture and drying to water content is not more than 3%, obtain diameter and be not more than
0.1 millimeter of Filled With Hollow Bead particle；
S2, inorganic material mixing, by schmigel, the diamond dust of remainder, carborundum powder, self-luminescence powder, sepiolite, graphene
Fiber, rare earth, pigment, fungicide and S1 step are prepared Filled With Hollow Bead particle and are added to mixing plant
In, and at the uniform velocity stirred 10-30 minutes with 300-500 revs/min of revolving speeds, acquisition is uniformly mixed electrodeless mixture；
S3, organic materials mixing, by silester, lubricant, remaining aqueous polyureas, hydroxypropyl methyl cellulose ether, coupling agent,
Dispersing agent, dedusting agent and modified resin are arrived together in heating reaction kettle, with 300-500 revs/min under atmosphere of inert gases
While revolving speed at the uniform velocity stirs, 500 DEG C-750 DEG C, and insulated and stirred 10-35 minutes are at the uniform velocity warming up to 10-35 DEG C/minute；
S4, encapsulation, the electrodeless mixture that S2 step is obtained at the uniform velocity are added in the organic mixture of S3 step preparation, and
Ultrasonic wave homogenization 10-40 minutes under 500 DEG C-750 DEG C isoperibols, then it is kept stirring that state is constant and natural cooling
To 20 DEG C-35 DEG C, finally mixture after cooling is filled under the inert gas driving that pressure is 5-10 times of standard atmospheric pressures
It fills in closed hard support container and closed hard support container is sealed, can be obtained finished product heat reflection coating, and
Air pressure in finished product product in hard support container is 2-8 times of standard atmospheric pressures.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110964421A (en) * | 2019-12-18 | 2020-04-07 | 焦作大学 | Vehicle tire cavity coating and spraying equipment thereof |
| CN113117286A (en) * | 2020-01-16 | 2021-07-16 | 蔡育伦 | Multi-layer running board with static-free, wear-resistant and lubricating effects |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101174106B1 (en) * | 2012-03-27 | 2012-08-16 | (주)서현하이텍 | Method for waterproofing using polyurea |
| CN107494072A (en) * | 2017-10-11 | 2017-12-22 | 邢志强 | Cool net |
| CN108424715A (en) * | 2018-01-20 | 2018-08-21 | 金粤幕墙装饰工程有限公司 | Glass bead explosion-proof thermal insulation coating |
| CN108977064A (en) * | 2018-07-30 | 2018-12-11 | 苏州太星新材料科技有限公司 | A kind of environment-friendly water-based high-temperature resistant coating of silicone resin and its preparation and application |
| CN109207038A (en) * | 2018-09-04 | 2019-01-15 | 焦作大学 | A kind of high-performance protective spray-on coating and preparation method thereof based on polyurea matrix |
-
2019
- 2019-04-11 CN CN201910291138.4A patent/CN110128907A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101174106B1 (en) * | 2012-03-27 | 2012-08-16 | (주)서현하이텍 | Method for waterproofing using polyurea |
| CN107494072A (en) * | 2017-10-11 | 2017-12-22 | 邢志强 | Cool net |
| CN108424715A (en) * | 2018-01-20 | 2018-08-21 | 金粤幕墙装饰工程有限公司 | Glass bead explosion-proof thermal insulation coating |
| CN108977064A (en) * | 2018-07-30 | 2018-12-11 | 苏州太星新材料科技有限公司 | A kind of environment-friendly water-based high-temperature resistant coating of silicone resin and its preparation and application |
| CN109207038A (en) * | 2018-09-04 | 2019-01-15 | 焦作大学 | A kind of high-performance protective spray-on coating and preparation method thereof based on polyurea matrix |
Non-Patent Citations (4)
| Title |
|---|
| 方亮等: "《药用高分子材料学》", 31 August 2015, 中国医药科技出版社 * |
| 方小牛: "《生土类建筑保护技术与策略》", 31 January 2018, 同济大学出版社 * |
| 李玲: "高性能有机/无机水性保温隔热涂料的研究", 《中国优秀硕士学位论文全文数据库工程科技1辑》 * |
| 橡胶工业原材料与装备简明手册编审委员会: "《橡胶工业原材料与装备简明手册 原材料与工艺耗材分册》", 31 January 2019, 北京理工大学出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110964421A (en) * | 2019-12-18 | 2020-04-07 | 焦作大学 | Vehicle tire cavity coating and spraying equipment thereof |
| CN113117286A (en) * | 2020-01-16 | 2021-07-16 | 蔡育伦 | Multi-layer running board with static-free, wear-resistant and lubricating effects |
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