CN110128710A - Pet toy of variable multicolor and preparation method thereof - Google Patents
Pet toy of variable multicolor and preparation method thereof Download PDFInfo
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- CN110128710A CN110128710A CN201910348829.3A CN201910348829A CN110128710A CN 110128710 A CN110128710 A CN 110128710A CN 201910348829 A CN201910348829 A CN 201910348829A CN 110128710 A CN110128710 A CN 110128710A
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- rubber
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- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- 229920001971 elastomer Polymers 0.000 claims abstract description 72
- 239000005060 rubber Substances 0.000 claims abstract description 72
- 238000002845 discoloration Methods 0.000 claims abstract description 68
- 239000000843 powder Substances 0.000 claims abstract description 63
- 239000002994 raw material Substances 0.000 claims abstract description 46
- 230000008859 change Effects 0.000 claims abstract description 20
- 239000000463 material Substances 0.000 claims abstract description 19
- 229920002725 thermoplastic elastomer Polymers 0.000 claims description 39
- 239000011256 inorganic filler Substances 0.000 claims description 26
- 229910003475 inorganic filler Inorganic materials 0.000 claims description 26
- 238000002156 mixing Methods 0.000 claims description 24
- 239000012752 auxiliary agent Substances 0.000 claims description 22
- 239000003795 chemical substances by application Substances 0.000 claims description 22
- 238000004073 vulcanization Methods 0.000 claims description 19
- 238000001746 injection moulding Methods 0.000 claims description 10
- 238000001035 drying Methods 0.000 claims description 9
- 238000012545 processing Methods 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 244000043261 Hevea brasiliensis Species 0.000 claims description 5
- 229920003052 natural elastomer Polymers 0.000 claims description 5
- 229920001194 natural rubber Polymers 0.000 claims description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 4
- 238000000071 blow moulding Methods 0.000 claims description 4
- 239000005662 Paraffin oil Substances 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- 150000001993 dienes Chemical class 0.000 claims description 2
- 239000006185 dispersion Substances 0.000 claims description 2
- 239000000945 filler Substances 0.000 claims description 2
- 229920003051 synthetic elastomer Polymers 0.000 claims description 2
- 239000005061 synthetic rubber Substances 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- 239000000969 carrier Substances 0.000 claims 1
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- 239000004416 thermosoftening plastic Substances 0.000 claims 1
- 150000003673 urethanes Chemical class 0.000 claims 1
- 230000005856 abnormality Effects 0.000 abstract description 16
- 230000004044 response Effects 0.000 abstract description 8
- 239000003921 oil Substances 0.000 description 27
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 10
- 239000005864 Sulphur Substances 0.000 description 10
- 239000000203 mixture Substances 0.000 description 10
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 8
- 206010037660 Pyrexia Diseases 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 6
- 210000003296 saliva Anatomy 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000003292 glue Substances 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- GPNLWUFFWOYKLP-UHFFFAOYSA-N s-(1,3-benzothiazol-2-yl)thiohydroxylamine Chemical group C1=CC=C2SC(SN)=NC2=C1 GPNLWUFFWOYKLP-UHFFFAOYSA-N 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 4
- 230000009466 transformation Effects 0.000 description 4
- 230000036760 body temperature Effects 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 235000012239 silicon dioxide Nutrition 0.000 description 3
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 229960002447 thiram Drugs 0.000 description 3
- 239000011787 zinc oxide Substances 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 235000005979 Citrus limon Nutrition 0.000 description 2
- 244000131522 Citrus pyriformis Species 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- 208000002193 Pain Diseases 0.000 description 2
- 239000004433 Thermoplastic polyurethane Substances 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 239000002775 capsule Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000008451 emotion Effects 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 2
- 244000144730 Amygdalus persica Species 0.000 description 1
- 241000699800 Cricetinae Species 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 206010016275 Fear Diseases 0.000 description 1
- 241000282326 Felis catus Species 0.000 description 1
- 206010021703 Indifference Diseases 0.000 description 1
- 235000000177 Indigofera tinctoria Nutrition 0.000 description 1
- OWIKHYCFFJSOEH-UHFFFAOYSA-N Isocyanic acid Chemical compound N=C=O OWIKHYCFFJSOEH-UHFFFAOYSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 229920000459 Nitrile rubber Polymers 0.000 description 1
- 241000283973 Oryctolagus cuniculus Species 0.000 description 1
- 241000009328 Perro Species 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 235000006040 Prunus persica var persica Nutrition 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- XLJMAIOERFSOGZ-UHFFFAOYSA-N anhydrous cyanic acid Natural products OC#N XLJMAIOERFSOGZ-UHFFFAOYSA-N 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical group C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 230000001055 chewing effect Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 229940097275 indigo Drugs 0.000 description 1
- COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229920003049 isoprene rubber Polymers 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 210000000214 mouth Anatomy 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000005987 sulfurization reaction Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
- A01K15/00—Devices for taming animals, e.g. nose-rings or hobbles; Devices for overturning animals in general; Training or exercising equipment; Covering boxes
- A01K15/02—Training or exercising equipment, e.g. mazes or labyrinths for animals ; Electric shock devices ; Toys specially adapted for animals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Environmental Sciences (AREA)
- Health & Medical Sciences (AREA)
- Zoology (AREA)
- Physical Education & Sports Medicine (AREA)
- Animal Husbandry (AREA)
- Biodiversity & Conservation Biology (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Toys (AREA)
Abstract
This application provides pet toys of a kind of variable multicolor and preparation method thereof, wherein the raw material for preparing of the pet toy of variable multicolor includes the raw material with rubber material and a variety of heat discoloration powder being scattered in raw material, and a variety of heat discoloration powder are a variety of with different form and aspect and with the toner of different discoloring temperatures.The a variety of heat discoloration powder being scattered in raw material are with different form and aspect and with the toner of different discoloring temperatures, it can thus change colour at a temperature of different, since multiple color variation can be presented in pet toy, when pet physical condition is preferable, it is exactly a kind of extremely interested toy to pet, even if thus pet is in a kind of dependence in when feeling badly, can also sustenance be generated to very interested pet toy and baited.Thus, the pet toy of the application may act as the toy with higher interest that pet is normally played, but can the body abnormality situation effectively to pet make a response.
Description
Technical field
This application involves pet toy fields more particularly to the pet toy of variable multicolor and preparation method thereof.
Background technique
In general, pet refers to the animal fed for non-economy purpose, for eliminating lonely spiritual purpose,
Or it entertains purpose and feeds.Nowadays, well-known pet is mainly dog, cat, hamster, rabbit.In order to cultivate the mankind and pet
Between emotion, the mankind would generally use pet toy establish and pet between close relation.Pet toy is some to doting on
Object is played dedicated some utensils, need it is with higher it is resistance to sting, the resistance to performance grabbed.This type toy is with the mankind in traditional sense
Toy it is different, e.g., traditional toy is used to exclude sense of emptiness or be used to child or girl, boy
The toy whiled away the time.Pet toy is a kind of based on a kind of parent-offspring's type that pet is born as human buddy's relationship
Toy type, purpose existing for this toy is exactly that the mankind and the pet of oneself is allowed really mutually to move up, on emotion
To bigger exchange and interaction.Pet as the mankind, can also exist it is sick, old, dead process, due to pet lack language
Say the ability linked up, it is difficult to pain and uneasiness in the minds of transmitting, thus the mankind are difficult to understand its body abnormality situation, and the mankind
Also the more difficult body to pet is detected and is judged, thus when pet feels badly, it is just difficult to establish with pet
Play good parent child relationship.
Although existing it has been proposed that a kind of pet body temperature clothing, using the color change of the high-temperature discoloration material layer on pet clothing,
It goes to judge the conditions such as the fever of doggie, it is well known that, many pets are to be unwilling to wear clothes, and are especially in
In or when hot weather, that is a kind of constraint of body for pet, thus this pet body temperature clothing practicability
It is poor.In addition, for those become mildewed or the pet of crinosity for, cover one layer of body temperature clothing, clothes itself again outside fur
The inside will reach very high temperature, be difficult to accurately reflect the body abnormality situation of pet itself.
Therefore, how preferably to establish this close relationship between the mankind and pet, and can understand at any time pet flu,
The body abnormalities situations such as fever, are the goal in research and hot spot of related fields researcher.
Apply for content
The applicant of this patent based on the above issues, provides a kind of new thinking, extremely interested in pet itself
Start on pet toy, pet toy is improved, making pet toy not only can satisfy the pleasant feeling of pet, but also can be to doting on
The body abnormality situation of object is made a response, and preferably establishes the mankind to allow the mankind timely to understand the body abnormality situation of pet
Close relationship between pet.
To achieve the above object, this application provides a kind of pet toys of variable multicolor, and preparing raw material includes having rubber
The raw material of glue material and a variety of heat discoloration powder being scattered in the raw material, a variety of heat discoloration powder are a variety of with not
With form and aspect and with the toner of different discoloring temperatures.
The pet toy of the application prepares raw material with rubber material, and the elasticity of rubber adds the interest of toy,
And it is resistance to sting, thus the usually interested type toy of pet.And be scattered in a variety of heat discoloration powder in raw material be with
Different form and aspect and the toner with different discoloring temperatures, thus can change colour at a temperature of different, under compared with low temperature
Discoloration pet toy can be made to be presented different colors, and color change is reversible, thus has beautiful visual effect, is avoided
Pet generates feeling dry as dust, greatly improves the playability and interest of toy, and pet is in the situations such as flu, fever
When, the saliva temperature in oral cavity is higher, thus when baiting pet toy, the toner to be changed colour by high temperature can also be such that pet plays
Tool is presented new color change, and whether the mankind are in flu, fever etc. by the color change of pet toy, i.e., knowable pet
Unusual condition, to timely be treated to pet.Furthermore since multiple color variation can be presented in pet toy, in body
It is exactly a kind of extremely interested toy to pet when situation is preferable, thus even if pet is in when feeling badly, it is in one
Kind dependence also can generate sustenance to very interested pet toy and bait.In short, the pet toy of the application
It may act as the toy with higher interest that pet is normally played, and body abnormality situation that can effectively to pet
It makes a response.
On the other hand the application provides the preparation of two kinds of pet toys for the different variable multicolors for preparing raw material
Method.
The preparation method of the pet toy of the first variable multicolor successively includes: by rubber carrier, inorganic filler, rubber
Oil and the mixing of other auxiliary agents；Water and drying are crossed after mixing and mill processing；Sulphur is added after a variety of heat discoloration powder mixing are added
Agent and vulcanization accelerator and injection molding after being vulcanized in 135~175 DEG C.First by rubber carrier, inorganic filler, rubber oil
After the mixing of other auxiliary agents, a variety of heat discoloration powder mixing are added, inorganic filler and heat discoloration powder are under the action of rubber oil
It can uniformly be scattered in rubber carrier, add vulcanizing agent and vulcanization accelerator and be vulcanized in 135~175 DEG C, sulphur
It is low to change temperature, thus the influence to heat discoloration powder is small, will not destroy the performance and structure of temperature-sensitive toner.
The preparation method of the pet toy of second of variable multicolor, successively include: by thermoplastic elastomer (TPE), inorganic filler,
Rubber oil and other auxiliary agents mix；Water and drying are crossed after mixing and mill processing；After a variety of heat discoloration powder mixing are added；In
200 DEG C or less be molded, squeezed out, blow molding.This preparation method uses thermoplastic elastomer (TPE) as rubber raw materials, thus can
Vulcanization process is omitted, inorganic filler and heat discoloration powder can uniformly be scattered in thermoplastic elastomer (TPE) under the action of rubber oil
In, and it is only i.e. plastic through injection molding, extrusion, blow molding in 200 DEG C or less.
Specific embodiment
The technical solution of the application is further illustrated below by specific embodiment, but does not constitute and the application is appointed
What is limited.
The application first aspect provides a kind of pet toy of variable multicolor, and preparing raw material includes having rubber material
Raw material and a variety of heat discoloration powder being scattered in raw material, a variety of heat discoloration powder are a variety of with different form and aspect and with difference
Discoloring temperature toner.
The pet toy of variable multicolor refers to the pet toy that can show multiple color.Raw material with rubber material is
Rubber material and other materials are mixed in a certain proportion and can present the mixture or only rubber material of the elastic characteristic of rubber.
Heat discoloration powder is because electronics transfer makes the molecular structure of the organic matter change under specific temperature, to realize that color turns
Become.A variety of heat discoloration powder of the application can change colour at multiple temperatures and pet toy is made to show different colors.
Further, the form and aspect of raw material be it is white or light-colored, and with the form and aspect of a variety of heat discoloration powder and with discoloration front and back
Secondary colour it is all different.In order to avoid interference, the secondary colour before and after the form and aspect of raw material and the form and aspect of heat discoloration powder and discoloration is answered
This is all different, and the form and aspect of heat discoloration powder are preferably that different basic form and aspect or different Essential colour are similar lower because of concentration difference
Different and composition form and aspect.Substantially form and aspect refer generally to red, orange, yellow, green, blue, purple, and different Essential colour phase factor concentration differences can be in
Reveal a variety of form and aspect, if yellow color can be divided into middle Huang, the colour of loess, lemon yellow, red can be divided into pink, pale red, pink, and purple can
It is divided into that greyish purple, wine is purple, peach is purple.For example, the form and aspect of raw material true qualities can be in true yellow or middle Huang, the colour of loess, lemon yellow
One kind, and heat discoloration powder can be the various concentration under other basic form and aspect or other basic form and aspect than yellow
Form and aspect, can such as be positive red or one of pink, pale red, pink.Raw material and heat discoloration powder should be avoided using same
The form and aspect that various concentration under kind basic form and aspect is constituted, form and aspect its color constituted by the various concentration under same basic form and aspect
Very close to, thus the accuracy that will affect the interest of pet toy and make a response to the body abnormality situation of pet.
Further, the discoloring temperature of a variety of heat discoloration powder is all between 28~38 DEG C, and each heat discoloration powder is in correspondence
Discoloring temperature under become colourless, the precision of the discoloring temperature of a variety of heat discoloration powder is ± 2 DEG C, and the higher discoloration of temperature is brighter
It is aobvious.Discoloring temperature is set as 28~38 DEG C comprising oral temperature when pet normal condition and flu, fever etc. are abnormal, because
And the toy with higher interest normally played as pet can be met simultaneously, and can be effectively different to the body of pet
Normal situation is made a response.Pet has the physiological system similar with the mankind, also fears cold and sweltering heat, usual pet, which is played, to be doted on
When object toy, the suitable outdoor of perhaps weather is typically chosen indoors without in hot or cold outdoor, normal
Under body abnormality situation, the oral temperature of pet is more than 28 DEG C, thus while baiting can be such that pet toy occurs at a lower temperature
Discoloration, and when flu occurs in body, fever oral temperature can reach 38 DEG C or so, pet toy may occur in which the change under high temperature again
Color and provide the sick signal of pet.The discoloration of heat discoloration powder is not in a flash, to be difficult accurately to make in a certain temperature
Reaction, usually it is a process, and the precision of discoloring temperature is ± 2 DEG C, for example assumes to select a kind of its discoloration of heat discoloration powder
Temperature is 28 DEG C, color change will be slowly showed in 26 DEG C, and as temperature increases, and at 29~30 DEG C, is presented
Color change out is most obvious.
Further, a variety of heat discoloration powder be 2 kinds of toners, and the discoloring temperature of the 1st kind of toner be 28 DEG C, the 2nd
The discoloring temperature of kind toner is 38 DEG C.Two kinds of heat discoloration powder make pet toy show 3 kinds of colors in entire colourshifting process,
At 28 DEG C hereinafter, pet toy is the secondary colour of raw material true qualities and two kinds of temperature-sensitive toners, this is the 1st kind of color, is reaching 28 DEG C
Left and right, the 1st kind of toner start change colour and present it is colourless, thus be more than the first toner discoloring temperature after, pet toy is in
The secondary colour of existing raw material true qualities and second of temperature-sensitive toner, this is the 2nd kind of color, and if temperature be lower than the change of the first toner again
When color temperature while no longer being baited (such as pet), pet toy reverts to the 1st kind of color, the 1st kind of color and the 2nd kind of face again
The transformation of color further increases the interest of pet toy.If body abnormality occurs in pet, oral temperature raising reaches the 2nd
When the discoloring temperature of kind toner, after pet toy is baited by pet, saliva of buccal cavity is rested on pet toy, and the 2nd kind of toner exists
It begins to change into colourless when close to 38 DEG C, thus makes pet toy that the true qualities of raw material be presented, this is the 3rd kind of color.Certainly, a variety of senses
Warm color-change powder can also be N kind toner, and N is the integer greater than 2, wherein the discoloring temperature of the 1st kind of toner is 28 DEG C, N-1 kind color
The discoloring temperature of powder, which is located at, to be greater than between 28 DEG C to less than 38 DEG C, and the discoloring temperature of N kind toner is 38 DEG C, the color presented
Variation should be N+1 kind, and the mechanism of its color change is similar with aforementioned two kinds of toners, and details are not described herein.In order to further
The secondary colour increased to the interest of pet toy, the raw material true qualities of pet toy or after first time changes colour is preferably similar
In the yellow or yellowish pink of skin.
Further, a variety of heat discoloration powder are all microcapsule-type toner, and a variety of heat discoloration powder is total
Weight and the weight ratio of the raw material are (1~1.6): (28~84).The content of heat discoloration powder is unsuitable excessively high, to avoid in original
Disperse in material uneven.Further, based on parts by weight, raw material include 20~40 parts rubber carrier, 6~24 parts inorganic
Filler, 0.3~1.2 part of vulcanizing agent, 0.35~2 part of vulcanization accelerator, 0.5~10 part of rubber oil and 0.45~6 part
Other auxiliary agents, or, raw material includes 20~40 parts of thermoplastic elastomer (TPE), 6~24 parts of inorganic filler, 0.5~10 part of rubber
Oil and 0.45~6 part other auxiliary agents.Rubber carrier is specific and is not limited to 20 parts, 25 parts, 30 parts, 35 parts, 40 parts, inorganic to fill out
Material is specific and is not limited to 6 parts, 10 parts, 14 parts, 18 parts, 21 parts, 24 parts, vulcanizing agent it is specific and be not limited to 0.3 part, 0.5 part,
0.8 part, 1.0 parts, 1.2 parts, vulcanization accelerator is specific and is not limited to 0.35 part, 0.5 part, 0.8 part, 1.0 parts, 1.4 parts, 1.8
Part, 2 parts, rubber oil is specific and is not limited to 0.5 part, 1 part, 2 parts, 5 parts, 7 parts, 10 parts, other auxiliary agents are specific and are not limited to
0.45 part, 1 part, 2 parts, 4 parts, 6 parts, thermoplastic elastomer (TPE) is specific and is not limited to 20 parts, 25 parts, 30 parts, 35 parts, 40 parts.Meaning
Taste, rubber material can be rubber carrier or thermoplastic elastomer (TPE), and rubber carrier can be natural rubber or synthetic rubber, synthesis
Rubber can be butadiene-styrene rubber, butadiene rubber, isoprene rubber, nitrile rubber, isopropyl rubber, neoprene, and thermoplastic elastomer (TPE) is
Phenylethylene TPE (referring generally to the copolymer of butadiene or isoprene and styrene block type, also referred to as TPS), olefines TPE
(refer generally to PP is hard segment and EPDM is the blend of soft chain segment, also referred to as TPO), dienes TPE (refer generally to the trans- day of thermoplasticity
Right rubber), polyvinyl chloride-base TPE (elastification of mainly PVC modifies object, also referred to as TPVC) and polyurethanes TPE (by with isocyanic acid
Thermoplastic polyurethane rubber of the urethane hard segment of ester reaction in conjunction with polyester or the mutual block of polyether soft segments, also referred to as TPU) in
It is one or more, rubber oil is one of naphthenic oil, paraffin oil and aromatic naphtha or a variety of.Inorganic filler be silica,
One of calcium carbonate, mica, carbon black, titanium dioxide, talcum powder and barium sulfate are a variety of, to enhance the intensity of pet toy,
Improve resistance to stinging property.Vulcanizing agent can be sulphur, and vulcanization accelerator can be benzothiazole sulfenamide, 2-mercaptobenzothiazole and two sulphur
Change one of tetra methylthiuram or a variety of.Other auxiliary agents can be lubricant, activating agent, anti-creme, anti-aging agent etc., and respectively help
The content summation of agent is 0.45~6 part.
Pet toy needs to meet the resistance to performance baited, so inorganic filler would generally be added to increase intensity, but nothing
Poor dispersion of the machine filler in rubber material, thus will affect the performance of pet toy performance, and be added after rubber oil,
Rubber oil can play the role of reducing the hardness of rubber carrier or thermoplastic elastomer (TPE), improve melt fluidity, thus can be by rubber
Carrier or thermoplastic elastomer (TPE) fully absorb, and enter in the strand of thermoplastic elastomer carrier, and inorganic filler and temperature-sensitive become
Toner can be scattered in rubber carrier or thermoplastic elastomer (TPE) with rubber oil.Vulcanizing agent and vulcanization accelerator, which is added, simultaneously to drop
Reaction temperature needed for the molding of low raw material, thus it is excessively high and destroy the capsule structure of microcapsule-type toner and influence to can avoid temperature
Its discoloration.
The application second aspect provides the preparation method of the pet toy of variable multicolor, successively include: by rubber carrier,
Inorganic filler, rubber oil and the mixing of other auxiliary agents；Water and drying are crossed after mixing and mill processing；It is mixed that a variety of heat discoloration powder are added
Injection molding after adding vulcanizing agent and vulcanization accelerator after conjunction and being vulcanized in 135~175 DEG C.The method is directed to for one kind
The preparation method of sulfuration process is needed, because joined vulcanization accelerator, can be vulcanized at 135~175 DEG C,
Vulcanization reaction temperature is low, thus it is excessively high and destroy the capsule structure of microcapsule-type toner and influence its discoloration to can effectively avoid temperature
Performance.Certainly, if rubber material be thermoplastic elastomer (TPE), the preparation method of the pet toy of variable multicolor can successively include: by
Thermoplastic elastomer (TPE), inorganic filler, rubber oil and the mixing of other auxiliary agents；Water and drying are crossed after mixing and mill processing；It is added more
After kind heat discoloration powder mixing；It is molded, squeezed out, blow molding in 200 DEG C or less.Pass through common plastics molding process
It can be prepared into type.
The technical solution of the application is further illustrated below by specific embodiment, involved in embodiments herein
Raw material can be obtained by commercially available.
Embodiment 1
A kind of pet toy of variable multicolor, preparing raw material is rubber carrier 30kg, inorganic filler 10.8kg, vulcanizing agent
0.7kg, vulcanization accelerator 0.65kg, rubber oil 3kg and other auxiliary agents 0.5kg and heat discoloration powder 0.75kg, wherein rubber
Glue carrier is natural rubber, and inorganic filler 10.8kg is superfine silicon dioxide 9kg and zinc oxide 1.8kg, and vulcanizing agent is sulphur, sulphur
Changing promotor is benzothiazole sulfenamide, 2-mercaptobenzothiazole and tetramethylthiuram disulfide with weight ratio 2:1:1's
Mixture, rubber oil are naphthenic oil, other auxiliary agents are the mixture of the Petropols that weight ratio is 1:1 and octadecyl, temperature-sensitive
Color-change powder is the pink toner that discoloring temperature is 28 DEG C and discoloring temperature is 38 DEG C of hyacinthine toners, and the weight ratio of the two is
1:1。
Preparation method is to mix rubber carrier, inorganic filler, rubber oil and other auxiliary agents；Mixing and mill processing
Water and drying are crossed afterwards；Vulcanizing agent and vulcanization accelerator are added after two kinds of heat discoloration powder mixing are added and after 160 DEG C of vulcanizations
Injection molding.
The pet toy of injection molding is a hollow dog dog chewable bar, and raw material sheet is white at normal temperature as white
Raw material and discoloring temperature be 28 DEG C pink toner and discoloring temperature be that 38 DEG C of hyacinthine toners show secondary colour purple,
It takes its section to be observed with scanning electron microscope (SEM) pet toy of this purple and finds that the particle of its section is uniformly dispersed,
I.e. inorganic filler is uniformly dispersed in rubber material with heat discoloration powder.Give the hollow dog dog chewable bar of this purple to a lady
Dog is played, after poodle baits, by its saliva of buccal cavity influenced discoloring temperature be 28 DEG C pink toner present it is colourless,
And it is i.e. blue so that hollow dog dog chewable bar is showed white and indigo secondary colour, and when not baiting, hollow dog dog
Chewable bar restores purple again, and the transformation of blue and purple makes poodle produce strong dependence to this toy.It is expensive in discovery
When woman dog is not in good state, this dog dog chewable bar is played for it, if discovery dog dog chewing presents white, the i.e. true qualities of raw material,
Then illustrating that the saliva temperature of poodle is very high makes 38 DEG C of hyacinthine toners of discoloring temperature become colourless, and dog dog chewable bar presents
True qualities show poodle and are in the conditions of high temperature such as flu, fever.
Comparative example 1
A kind of pet toy of variable multicolor, preparing raw material is rubber carrier 30kg, inorganic filler 10.8kg, vulcanizing agent
0.7kg, vulcanization accelerator 0.65kg, rubber oil 3kg and other auxiliary agents 0.5kg and heat discoloration powder 0.75kg, wherein rubber
Glue carrier is natural rubber, and inorganic filler 10.8kg is superfine silicon dioxide 9kg and zinc oxide 1.8kg, and vulcanizing agent is sulphur, sulphur
Changing promotor is benzothiazole sulfenamide, 2-mercaptobenzothiazole and tetramethylthiuram disulfide with weight ratio 2:1:1's
Mixture, rubber oil are naphthenic oil, other auxiliary agents are the mixture of the Petropols that weight ratio is 1:1 and octadecyl, temperature-sensitive
Color-change powder is the pink toner that discoloring temperature is 28 DEG C.
Preparation method is to mix rubber carrier, inorganic filler, rubber oil and other auxiliary agents；Mixing and mill processing
Water and drying are crossed afterwards；Vulcanizing agent and vulcanization accelerator are added after the mixing of heat discoloration powder is added and after 160 DEG C are vulcanized
Injection molding.
The pet toy of injection molding is a hollow dog dog chewable bar, and raw material sheet is white at normal temperature as white
Raw material and discoloring temperature be that 28 DEG C of pink toner shows secondary colour red, this red pet toy is taken into its section
It is observed with scanning electron microscope (SEM) and finds that the particle of its section is uniformly dispersed, is i.e. inorganic filler and heat discoloration powder is in rubber
It is uniformly dispersed in glue material.This red hollow dog dog chewable bar is given to a poodle to play, after poodle baits, by
The pink toner presentation that the influence discoloring temperature of its saliva of buccal cavity is 28 DEG C is colourless, and shows hollow dog dog chewable bar
True qualities are white, and when not baiting, hollow dog dog chewable bar reverts to red again, although this white and red transformation
Can increase interest, but can not the body abnormality situation to poodle make a response.
Comparative example 2
A kind of pet toy of variable multicolor, preparing raw material is rubber carrier 30kg, inorganic filler 10.8kg, vulcanizing agent
0.7kg, vulcanization accelerator 0.65kg, rubber oil 3kg and other auxiliary agents 0.5kg and heat discoloration powder 0.75kg, wherein rubber
Glue carrier is natural rubber, and inorganic filler 10.8kg is superfine silicon dioxide 9kg and zinc oxide 1.8kg, and vulcanizing agent is sulphur, sulphur
Changing promotor is benzothiazole sulfenamide, 2-mercaptobenzothiazole and tetramethylthiuram disulfide with weight ratio 2:1:1's
Mixture, rubber oil are naphthenic oil, other auxiliary agents are the mixture of the Petropols that weight ratio is 1:1 and octadecyl, temperature-sensitive
Color-change powder is the hyacinthine toner that discoloring temperature is 38 DEG C.
Preparation method is to mix rubber carrier, inorganic filler, rubber oil and other auxiliary agents；Mixing and mill processing
Water and drying are crossed afterwards；Vulcanizing agent and vulcanization accelerator are added after the mixing of heat discoloration powder is added and after 160 DEG C are vulcanized
Injection molding.
The pet toy of injection molding is a hollow dog dog chewable bar, and raw material sheet is white at normal temperature as white
Raw material and discoloring temperature be 38 DEG C of hyacinthine toners show secondary colour navy blue, take it to break this navy blue pet toy
Face is observed with scanning electron microscope (SEM) finds that the particle of its section is uniformly dispersed, i.e., inorganic filler and heat discoloration powder in
It is uniformly dispersed in rubber material.It gives the hollow dog dog chewable bar of this navy blue to a poodle to play, baits it in poodle
Afterwards, because under normal body condition, the saliva of buccal cavity temperature of poodle is not achieved 38 DEG C, therefore metachromatism is not presented, for
For poodle, with average pet toy and indifference, great interest is had no to it, thus is in body in subsequent poodle
When body exception, the more not interested dog dog chewable bar hollow to this navy blue is carried out by chew and is baited, this pet toy is difficult
To make a response to pet body abnormality situation.
Through the foregoing embodiment with the comparison of comparative example 1~2 it is found that heat discoloration powder is only set as a variety of color-change powders
When, pet toy just may act as the toy with higher interest that pet is normally played, and can be effectively to pet
Body abnormality situation make a response.Heat discoloration powder is set as a variety of with different form and aspect and with different discolorations by the application
The toner of temperature when being exactly in body abnormality to solve pet, to surrounding articles and uninterested problem, is set as more
Kind of temperature-sensitive toner is normally played in pet in use, the color-change powder under lower temperature can change colour when pet baits,
And can occur the transformation repeatedly of color during baiting and pet is made to generate dependence to pet toy, can just it promote in this way
It baits pet toy because of relying in body abnormality such as flu, fever, so that pet toy could be effective
Corresponding reaction is made to the body abnormality situation of pet.
It should be pointed out that embodiments above is merely to illustrate the application rather than limitation scope of the present application, readding
After having read the application, those skilled in the art are to the modifications or substitutions of the various equivalent forms of the application, e.g., the group of each raw material
Point and content, type number, color and the discoloring temperature of temperature-sensitive toner, the modification of preparation method and preparation section parameter etc. and replace
It changes, each falls within the application range defined in the appended claims.
Claims (10)
1. a kind of pet toy of variable multicolor, which is characterized in that preparing raw material includes raw material and the dispersion with rubber material
A variety of heat discoloration powder in the raw material, a variety of heat discoloration powder are a variety of with different form and aspect and with different
The toner of discoloring temperature.
2. the pet toy of variable multicolor according to claim 1, which is characterized in that the form and aspect of the raw material be white or
Light color, and from the form and aspect of a variety of heat discoloration powder and with discoloration front and back secondary colour it is all different.
3. the pet toy of variable multicolor according to claim 1, which is characterized in that the change of a variety of heat discoloration powder
Color temperature is all between 28~38 DEG C, and each heat discoloration powder becomes colourless under corresponding discoloring temperature, a variety of senses
The precision of the discoloring temperature of warm color-change powder is ± 2 DEG C, and the higher discoloration of temperature is more obvious.
4. the pet toy of variable multicolor according to claim 3, which is characterized in that a variety of heat discoloration powder are 2
Kind toner, and the discoloring temperature of the 1st kind of toner is 28 DEG C, the discoloring temperature of the 2nd kind of toner is 38 DEG C.
5. the pet toy of variable multicolor according to claim 3, which is characterized in that a variety of heat discoloration powder are N
Kind toner, N are the integer greater than 2, wherein the discoloring temperature of the 1st kind of toner is 28 DEG C, the change of toner described in N-1 kind
Color temperature, which is located at, to be greater than between 28 DEG C to less than 38 DEG C, and the discoloring temperature of toner described in N kind is 38 DEG C.
6. the pet toy of variable multicolor according to claim 1, which is characterized in that a variety of heat discoloration powder are all
Microcapsule-type toner, and the total weight of a variety of heat discoloration powder and the weight ratio of the raw material are (1~1.6): (28~
84)。
7. the pet toy of variable multicolor according to claim 6, which is characterized in that based on parts by weight, the raw material
Promote including 20~40 parts of rubber carriers, 6~24 parts of inorganic filler, 0.3~1.2 part of vulcanizing agent, 0.35~2 part of vulcanization
Into agent, 0.5~10 part of rubber oil and 0.45~6 part other auxiliary agents, or, the raw material includes 20~40 parts of thermoplastic elastomehc
Property body, 6~24 parts of inorganic filler, 0.5~10 part of rubber oil and 0.45~6 part other auxiliary agents.
8. the pet toy of variable multicolor according to claim 7, which is characterized in that the rubber carrier is natural rubber
Or synthetic rubber, the thermoplastic elastomer (TPE) is phenylethylene TPE, olefines TPE, dienes TPE, polyvinyl chloride-base TPE and poly-
One of urethane class TPE or a variety of, the rubber oil are one of naphthenic oil, paraffin oil and aromatic naphtha or a variety of.
9. a kind of preparation method of the pet toy of variable multicolor, which is characterized in that successively include: by rubber carrier, inorganic fill out
Material, rubber oil and the mixing of other auxiliary agents；Water and drying are crossed after mixing and mill processing；It is added after a variety of heat discoloration powder mixing again
Injection molding after vulcanizing agent and vulcanization accelerator is added and is vulcanized in 135~175 DEG C.
10. a kind of preparation method of the pet toy of variable multicolor, which is characterized in that successively include: by thermoplastic elastomer (TPE), nothing
Machine filler, rubber oil and the mixing of other auxiliary agents；Water and drying are crossed after mixing and mill processing；A variety of heat discoloration powder mixing are added
Afterwards；It is molded, squeezed out, blow molding in 200 DEG C or less.
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| CN201910348829.3A CN110128710A (en) | 2019-04-26 | 2019-04-26 | Pet toy of variable multicolor and preparation method thereof |
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| CN201910348829.3A CN110128710A (en) | 2019-04-26 | 2019-04-26 | Pet toy of variable multicolor and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN115428745A (en) * | 2021-06-02 | 2022-12-06 | 天津大学四川创新研究院 | Livestock thermochromic ear tag, preparation method and machine vision monitoring system thereof |
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