CN110117434A - BT120 alcohol water environmental protection compound oil ink - Google Patents
BT120 alcohol water environmental protection compound oil ink Download PDFInfo
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- CN110117434A CN110117434A CN201810118575.1A CN201810118575A CN110117434A CN 110117434 A CN110117434 A CN 110117434A CN 201810118575 A CN201810118575 A CN 201810118575A CN 110117434 A CN110117434 A CN 110117434A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/104—Polyesters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/108—Hydrocarbon resins
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The present invention relates to a kind of BT120 alcohol water environmental protection compound oil inks, it is made of raw material from the following weight, 30-70 parts of environmental protection acrylic resin, 20-40 parts of organic pigment, 5-10 parts of saturated polyester resin, 2-8 parts of dispersing agent, 2-8 parts of defoaming agent, 1-3 parts of dehydrated alcohol, 1-3 parts of starch phosphate, 1-5 parts of pH adjusting agent, 7-15 parts of deionized water.The present invention passes through the addition sequence and adding rate of each raw material of strict control, and reaction time and the reaction temperature of each step of control, each raw material, each step, each parameter concerted reaction, make environmental protection acrylic resin made from entire reaction system that there is preferable stability, environment protection health, good leveling property, viscosity stabilization, good water solubility, for printing BOPP, the films such as OPP, and there is good drying property, it is able to satisfy the requirement of high speed printing, and ink has splendid mobility, transfer effect is good, operating environment tolerance is big, it is less prone to knife silk, stifled version phenomenon.
Description
Technical field
The present invention relates to Printing ink producing technical field more particularly to a kind of BT120 alcohol water environmental protection compound oil inks.
Background technique
At this stage, chlorinated polypropylene ink, polyurethane oil is widely applied in the print fields such as printing by paper, food printing
Ink, polyacrylate ink, but be mostly solvent dye ink with curing ink, commonly use methanol, benzene, toluene, butanone, acetic acid second
The organic solvents such as ester, it is inflammable and explosive, cause the Transport Safety of ink low, and ink solvent flashing in printing process, pollutes
Air endangers the health of operator, and the solvent in ink easily corrodes or corrode printing equipment, compromises printing and sets
Standby service life；In addition, being printed with the package of solvent-based ink, paper articles etc., remaining solvent can pollute in packaging
Food and articles influence the health of user.
Summary of the invention
The purpose of the invention is to overcome the deficiencies of the prior art and provide a kind of BT120 alcohol water environmental protection compound oil ink.
The present invention is achieved through the following technical solutions:
BT120 alcohol water environmental protection compound oil ink, is made of raw material from the following weight:
30-70 parts of environmental protection acrylic resin, 20-40 parts of organic pigment, 5-10 parts of saturated polyester resin, dispersing agent 2-8
Part, 2-8 parts of defoaming agent, 1-3 parts of dehydrated alcohol, 1-3 parts of starch phosphate, 1-5 parts of pH adjusting agent, 7-15 parts of deionized water.
Further, the organic pigment is Chinese husky of common dye, benzidine yellow, forever solid orange, toluidine red, permanent bordeaux, toluidines
Wide red, the bright red coloured light in calcium salt color lake of purplish red, Lithol Red, barium salt toner yellow, lithol treasured be red, the red calcium purple lakes of blue light, phthalein
At least one of cyanines indigo plant, phthalocyanine green, phthalocyanine are red and phthalocyanine is purple；The dispersing agent is fatty acid dispersing agent, aliphatic amide
At least one of class dispersing agent and lipid dispersion agent；The pH adjusting agent is ammonium hydroxide, monoethanolamine, diethanol amine, three ethyl alcohol
At least one of amine, dimethylethanolamine and butyl diethanolamine.
Further, the defoaming agent is with weight ratio by DC-65 type defoaming agent, organosilicon and mineral oil for 0.8-1.2:
1:3.5-4.5 the mixture of composition.
Further, the environmental protection acrylic resin includes the raw material of following parts by weight:
60-100 parts of hard monomer, 20-60 parts of soft monomer, 10-30 parts of cross-linking monomer, 20-40 parts of acid value regulator, initiator
5-15 parts, 30-40 parts of pH adjusting agent, 180-220 parts of solvent.
Further, the hard monomer is at least one of styrene or methyl methacrylate；The soft monomer is
At least one of Isobutyl methacrylate, different monooctyl ester, butyl acrylate, butyl methacrylate and isobutyl acrylate；
The cross-linking monomer is hydroxy propyl methacrylate, N hydroxymethyl acrylamide, hydroxyethyl methacrylate, hydroxypropyl acrylate
At least one of with hydroxy-ethyl acrylate.
Further, the acid value regulator is at least one of acrylic acid, fine propylene acid or methacrylic acid；It is described
Initiator is azo, benzoyl peroxide, cumyl peroxide, peroxidized t-butyl perbenzoate, di t-amyl peroxide, mistake
It aoxidizes in di-t-butyl, isopropyl benzene hydroperoxide, isopropyl benzene hydroperoxide, t-amyl peroxy hydrogen and tert-butyl hydroperoxide
It is at least one；The pH adjusting agent is ammonium hydroxide, monoethanolamine, diethanol amine, triethanolamine, dimethylethanolamine and butyl diethyl
At least one of hydramine；The solvent is ethyl alcohol, n-butanol or propylene glycol.
Further, the preparation method of the environmental protection acrylic resin includes the following steps:
(1) solvent is added with the initiator for accounting for initiator total weight 30%-40% into reaction unit, is warming up to 75-
It 80 DEG C, is mixed, reaction bottom material is made, is kept the temperature at a temperature of 75-80 DEG C spare；
(2) by hard monomer, soft monomer, cross-linking monomer, acid value regulator and the initiation for accounting for initiator total weight 40%-50%
Agent is mixed, and mixture is made, and is added dropwise in step (1) reaction bottom material obtained at a temperature of 75-80 DEG C；
(3) after mixture made from step (2) is added dropwise to complete, remaining initiator is added, is kept the temperature at a temperature of 75-80 DEG C
Then 7.5-8.5h is cooled to 65-75 DEG C, add pH adjusting agent and adjust pH value to 8.0-8.8, environment-friendly type third is made in discharging
Olefin(e) acid resin.
Further, in the step (3), the drop rate control of mixture is added dropwise to complete in 3.5-4.5h.
Further, environmental protection acrylic resin is added into reaction unit, by organic pigment, dispersion while stirring
Agent, defoaming agent and water are sequentially added into reaction unit, stirring to fully reacting, are added pH adjusting agent and are adjusted pH value to 8.5-
9.0, environment-friendly type aqueous ink is made in grinding.
Further, the adding rate of the organic pigment, dispersing agent, defoaming agent and water controls within 5-5.5min
Addition is completed.
Compared with prior art, the beneficial effects of the present invention are:
The present invention and is used as solvent using water by using the raw material of environment-friendly type, and environment protection health is oily with traditional solvent type
Ink is compared, and has that volatility is low, smell is light, glossiness is high, good leveling property, viscosity stabilization, up to -4# glasss (25 of 20-40 seconds/bavin
DEG C), fineness≤10 μm, good water solubility can directly clean printing board material with clear water, reduce making for the cleaning solvents such as methanol, toluene
Dosage reduces erosion of the solvent to printing equipment, extends the service life of printing equipment, and water-based ink obtained makes in printing
Rate of drying after is fast, and the product quality after printing is strong, is not easy to shrink, be not easy fold, and stability is good, is suitable for paper product and prints
The print fields such as brush, plastic film printing, environmental protection acrylic process for preparing resins of the invention is easy to operate, by strictly controlling
Make the addition sequence and adding rate of each raw material, and reaction time and the reaction temperature of each step of control, each raw material, each step,
Each parameter concerted reaction, make environmental protection acrylic resin made from entire reaction system have preferable stability, environment protection health,
Good leveling property, viscosity stabilization, good water solubility for printing the films such as BOPP, OPP, and have good drying property, are able to satisfy
The requirement of high speed printing, and ink has splendid mobility, and transfer effect is good, and operating environment tolerance is big, is less prone to
Knife silk, stifled version phenomenon.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, with reference to embodiments, to the present invention
It is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to
Limit the present invention.
Embodiment 1
BT120 alcohol water environmental protection compound oil ink, the raw material including following parts by weight:
30 parts of environmental protection acrylic resin, 20 parts of organic pigment, 5 parts of saturated polyester resin, 2 parts of dispersing agent, defoaming agent 2
Part, 1 part of dehydrated alcohol, 1 part of starch phosphate, 1 part of pH adjusting agent, 7 parts of deionized water.
The organic pigment is forever solid orange；The dispersing agent is aliphatic amide type dispersing agent；The pH adjusting agent is ammonia
Water；The mixture that the defoaming agent is made of DC-65 type defoaming agent, organosilicon and mineral oil with weight ratio for 0.8:1:4.5.
The environmental protection acrylic resin includes the raw material of following parts by weight:
60 parts of hard monomer, 20 parts of soft monomer, 10 parts of cross-linking monomer, 20 parts of acid value regulator, 5 parts of initiator, pH adjusting agent
30 parts, 180 parts of solvent.The hard monomer is methyl methacrylate；The soft monomer is Isobutyl methacrylate；The friendship
Receipts or other documents in duplicate body is hydroxy propyl methacrylate；The acid value regulator is fine propylene acid；The initiator is azo or benzoyl peroxide
T-butyl formate；The pH adjusting agent is ammonium hydroxide；The solvent is n-butanol.
The preparation method of the environmental protection acrylic resin, includes the following steps:
(1) solvent is added with the initiator for accounting for initiator total weight 30% into reaction unit, is warming up to 80 DEG C, mixing
Stirring is made reaction bottom material, keeps the temperature at a temperature of 80 DEG C spare；
(2) it by hard monomer, soft monomer, cross-linking monomer, acid value regulator and accounts for the initiator of initiator total weight 50% and mixes
Stirring is closed, mixture is made, is added dropwise at a temperature of 80 DEG C in step (1) reaction bottom material obtained；
(3) after mixture made from step (2) is added dropwise to complete, remaining initiator is added, is kept the temperature at a temperature of 80 DEG C
Then 7.5h is cooled to 75 DEG C, add pH adjusting agent and adjust pH value to 8.0, environmental protection acrylic resin is made in discharging.
In the step (3), the drop rate control of mixture is added dropwise to complete in 3.5h.
A kind of preparation method of above-mentioned BT120 alcohol water environmental protection compound oil ink, includes the following steps:
Environmental protection acrylic resin and saturated polyester resin are added into reaction unit, by organic face while stirring
Material, starch phosphate, dispersing agent, defoaming agent and dehydrated alcohol are sequentially added into reaction unit, stirring to fully reacting, then plus
Enter pH adjusting agent and adjust pH value to 8.5, BT120 alcohol water environmental protection compound oil ink is made in grinding.
The organic pigment, dispersing agent, defoaming agent and water adding rate control to add within 5min and complete.
Embodiment 2
The difference of the present embodiment and above-described embodiment 1 is:
BT120 alcohol water environmental protection compound oil ink, the raw material including following parts by weight:
50 parts of environmental protection acrylic resin, 30 parts of organic pigment, 8 parts of saturated polyester resin, 5 parts of dispersing agent, defoaming agent 5
Part, 2 parts of dehydrated alcohol, 2 parts of starch phosphate, 3 parts of pH adjusting agent, 11 parts of deionized water.
The organic pigment is Chinese husky of common dye or benzidine yellow；The dispersing agent is aliphatic amide type dispersing agent；The pH
Regulator is monoethanolamine；The defoaming agent is with weight ratio by DC-65 type defoaming agent, organosilicon and mineral oil for 0.9:1:
The mixture of 4.3 compositions.
The environmental protection acrylic resin includes the raw material of following parts by weight:
70 parts of hard monomer, 30 parts of soft monomer, 15 parts of cross-linking monomer, 25 parts of acid value regulator, 8 parts of initiator, pH adjusting agent
32 parts, 190 parts of solvent.
The hard monomer is styrene；The soft monomer is butyl acrylate；The cross-linking monomer is N- methylol propylene
Amide；The acid value regulator is acrylic acid；The initiator is benzoyl peroxide or di t-amyl peroxide；The pH tune
Section agent is dimethylethanolamine；The solvent is ethyl alcohol.
The preparation method of the environmental protection acrylic resin, includes the following steps:
(1) solvent is added with the initiator for accounting for initiator total weight 33% into reaction unit, is warming up to 79 DEG C, mixing
Stirring is made reaction bottom material, keeps the temperature at a temperature of 79 DEG C spare；
(2) it by hard monomer, soft monomer, cross-linking monomer, acid value regulator and accounts for the initiator of initiator total weight 48% and mixes
Stirring is closed, mixture is made, is added dropwise at a temperature of 79 DEG C in step (1) reaction bottom material obtained；
(3) after mixture made from step (2) is added dropwise to complete, remaining initiator is added, is kept the temperature at a temperature of 79 DEG C
Then 7.8h is cooled to 72 DEG C, add pH adjusting agent and adjust pH value to 8.2, environmental protection acrylic resin is made in discharging.
In the step (3), the drop rate control of mixture is added dropwise to complete in 3.9h.
A kind of preparation method of above-mentioned BT120 alcohol water environmental protection compound oil ink, includes the following steps:
Environmental protection acrylic resin and saturated polyester resin are added into reaction unit, by organic face while stirring
Material, starch phosphate, dispersing agent, defoaming agent and dehydrated alcohol are sequentially added into reaction unit, stirring to fully reacting, then plus
Enter pH adjusting agent and adjust pH value to 8.7, BT120 alcohol water environmental protection compound oil ink is made in grinding.
The organic pigment, dispersing agent, defoaming agent and water adding rate control to add within 5.2min and complete.
Embodiment 3
The difference of the present embodiment and above-described embodiment 1 is:
BT120 alcohol water environmental protection compound oil ink, the raw material including following parts by weight:
70 parts of environmental protection acrylic resin, 40 parts of organic pigment, 10 parts of saturated polyester resin, 8 parts of dispersing agent, defoaming agent 8
Part, 3 parts of dehydrated alcohol, 3 parts of starch phosphate, 5 parts of pH adjusting agent, 15 parts of deionized water.
The organic pigment be toluidine red, permanent bordeaux, everbright fast maroon, Lithol Red, barium salt toner yellow it is wide it is red,
The precious red or phthalocyanine of the bright red coloured light in calcium salt color lake, lithol is red；The dispersing agent is fatty acid dispersant；The pH adjusting agent is diethyl
Hydramine or dimethylethanolamine；The defoaming agent is with weight ratio by DC-65 type defoaming agent, organosilicon and mineral oil for 1:1:4
The mixture of composition.
The environmental protection acrylic resin includes the raw material of following parts by weight:
80 parts of hard monomer, 40 parts of soft monomer, 30 parts of cross-linking monomer, 30 parts of acid value regulator, 10 parts of initiator, pH adjusting agent
35 parts, 200 parts of solvent.
The hard monomer is styrene；The soft monomer is different monooctyl ester；The cross-linking monomer is hydroxyethyl methacrylate；
The acid value regulator is acrylic acid；The initiator is cumyl peroxide or di-t-butyl peroxide；The pH is adjusted
Agent is monoethanolamine；The solvent is n-butanol.
The preparation method of the environmental protection acrylic resin, includes the following steps:
(1) solvent is added with the initiator for accounting for initiator total weight 35% into reaction unit, is warming up to 78 DEG C, mixing
Stirring is made reaction bottom material, keeps the temperature at a temperature of 78 DEG C spare；
(2) it by hard monomer, soft monomer, cross-linking monomer, acid value regulator and accounts for the initiator of initiator total weight 45% and mixes
Stirring is closed, mixture is made, is added dropwise at a temperature of 78 DEG C in step (1) reaction bottom material obtained；
(3) after mixture made from step (2) is added dropwise to complete, remaining initiator is added, keeps the temperature 8h at a temperature of 78 DEG C,
Then 70 DEG C are cooled to, pH adjusting agent is added and adjusts pH value to 8.4, environmental protection acrylic resin is made in discharging.
In the step (3), the drop rate of mixture is controlled to being added dropwise to complete in 4h.
A kind of preparation method of above-mentioned BT120 alcohol water environmental protection compound oil ink, includes the following steps:
Environmental protection acrylic resin and saturated polyester resin are added into reaction unit, by organic face while stirring
Material, starch phosphate, dispersing agent, defoaming agent and dehydrated alcohol are sequentially added into reaction unit, stirring to fully reacting, then plus
Enter pH adjusting agent and adjust pH value to 9.0, BT120 alcohol water environmental protection compound oil ink is made in grinding.
The organic pigment, dispersing agent, defoaming agent and water adding rate control to add within 5.5min and complete.
As stated above, the present invention by using environment-friendly type raw material, and using water as solvent, environment protection health, with tradition
Solvent-based ink compare, have volatility is low, smell is light, glossiness is high, good leveling property, viscosity stabilization, up to 20-40 seconds/
- 4# glasss of bavin (25 DEG C), fineness≤10 μm, good water solubility can directly clean printing board material with clear water, and it is clear to reduce methanol, toluene etc.
The usage amount of clean solvent reduces erosion of the solvent to printing equipment, extends the service life of printing equipment, and aqueous oil obtained
Rate of drying of the ink after printing use is fast, and the product quality after printing is strong, is not easy to shrink, be not easy fold, and stability is good, fits
For print fields such as printing by paper, plastic film printings, environmental protection acrylic process for preparing resins of the invention is easy to operate,
Pass through reaction time and the reaction temperature of the addition sequence and adding rate of each raw material of strict control, and each step of control, each original
Material, each step, each parameter concerted reaction have environmental protection acrylic resin made from entire reaction system and preferably stablize
Property, environment protection health, good leveling property, viscosity stabilization, good water solubility, for printing the films such as BOPP, OPP, and with good dry
Dry performance is able to satisfy the requirement of high speed printing, and ink has splendid mobility, and transfer effect is good, and operating environment is tolerant
Degree is big, is less prone to knife silk, stifled version phenomenon.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention
Made any modifications, equivalent replacements, and improvements etc., should all be included in the protection scope of the present invention within mind and principle.
Claims (10)
1.BT120 alcohol water environmental protection compound oil ink, which is characterized in that be made of raw material from the following weight:
30-70 parts of environmental protection acrylic resin, 5-10 parts of saturated polyester resin, 2-8 parts of dispersing agent, disappears at 20-40 parts of organic pigment
2-8 parts of infusion, 1-3 parts of dehydrated alcohol, 1-3 parts of starch phosphate, 1-5 parts of pH adjusting agent, 7-15 parts of deionized water.
2. BT120 alcohol water environmental protection compound oil ink according to claim 1, which is characterized in that the organic pigment is that the Chinese is husky
The wide red, calcium of Huang, benzidine yellow, forever solid orange, toluidine red, permanent bordeaux, everbright fast maroon, Lithol Red, barium salt toner yellow
The bright red coloured light in salt color lake, lithol treasured are red, the red calcium purple lakes of blue light, phthalocyanine blue, phthalocyanine green, phthalocyanine are red and phthalocyanine it is purple at least one
Kind；The dispersing agent is at least one of fatty acid dispersing agent, aliphatic amide type dispersing agent and lipid dispersion agent；It is described
PH adjusting agent be ammonium hydroxide, monoethanolamine, diethanol amine, triethanolamine, dimethylethanolamine and butyl diethanolamine at least
It is a kind of.
3. BT120 alcohol water environmental protection compound oil ink according to claim 1, which is characterized in that the defoaming agent is by DC-65
Type defoaming agent, organosilicon and mineral oil are with the mixture that weight ratio is that 0.8-1.2:1:3.5-4.5 is formed.
4. BT120 alcohol water environmental protection compound oil ink according to claim 1, which is characterized in that the environmental protection acrylic tree
Rouge includes the raw material of following parts by weight:
60-100 parts of hard monomer, 20-60 parts of soft monomer, 10-30 parts of cross-linking monomer, 20-40 parts of acid value regulator, initiator 5-15
Part, 30-40 parts of pH adjusting agent, 180-220 parts of solvent.
5. BT120 alcohol water environmental protection compound oil ink according to claim 4, which is characterized in that the hard monomer is styrene
Or at least one of methyl methacrylate；The soft monomer be Isobutyl methacrylate, different monooctyl ester, butyl acrylate,
At least one of butyl methacrylate and isobutyl acrylate；The cross-linking monomer is hydroxy propyl methacrylate, N- hydroxyl
At least one of Methacrylamide, hydroxyethyl methacrylate, hydroxypropyl acrylate and hydroxy-ethyl acrylate.
6. BT120 alcohol water environmental protection compound oil ink according to claim 4, which is characterized in that the acid value regulator is third
At least one of olefin(e) acid, fine propylene acid or methacrylic acid；The initiator is azo, benzoyl peroxide, peroxidating two
Isopropylbenzene, peroxidized t-butyl perbenzoate, di t-amyl peroxide, di-t-butyl peroxide, isopropyl benzene hydroperoxide, isopropylbenzene
At least one of hydrogen peroxide, t-amyl peroxy hydrogen and tert-butyl hydroperoxide；The pH adjusting agent is ammonium hydroxide, monoethanol
At least one of amine, diethanol amine, triethanolamine, dimethylethanolamine and butyl diethanolamine；The solvent is ethyl alcohol, just
Butanol or propylene glycol.
7. BT120 alcohol water environmental protection compound oil ink according to claim 4, which is characterized in that the environmental protection acrylic tree
The preparation method of rouge includes the following steps:
(1) solvent is added with the initiator for accounting for initiator total weight 30%-40% into reaction unit, is warming up to 75-80 DEG C,
It is mixed, reaction bottom material is made, is kept the temperature at a temperature of 75-80 DEG C spare；
(2) it by hard monomer, soft monomer, cross-linking monomer, acid value regulator and accounts for the initiator of initiator total weight 40%-50% and mixes
Stirring is closed, mixture is made, is added dropwise at a temperature of 75-80 DEG C in step (1) reaction bottom material obtained；
(3) after mixture made from step (2) is added dropwise to complete, remaining initiator is added, keeps the temperature 7.5- at a temperature of 75-80 DEG C
Then 8.5h is cooled to 65-75 DEG C, add pH adjusting agent and adjust pH value to 8.0-8.8, environmental protection acrylic is made in discharging
Resin.
8. BT120 alcohol water environmental protection compound oil ink according to claim 7, which is characterized in that in the step (3), mixing
The drop rate control of material is added dropwise to complete in 3.5-4.5h.
9. BT120 alcohol water environmental protection compound oil ink according to claim 1-8, which is characterized in that by environment-friendly type third
Olefin(e) acid resin is added into reaction unit, and stirring while sequentially adds organic pigment, dispersing agent, defoaming agent and water to reaction
In device, stirring to fully reacting adds pH adjusting agent and adjusts pH value to 8.5-9.0, and environment-friendly type aqueous oil is made in grinding
Ink.
10. BT120 alcohol water environmental protection compound oil ink according to claim 9, which is characterized in that the organic pigment, dispersion
The adding rate of agent, defoaming agent and water is controlled to add within 5-5.5min and be completed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810118575.1A CN110117434A (en) | 2018-02-06 | 2018-02-06 | BT120 alcohol water environmental protection compound oil ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810118575.1A CN110117434A (en) | 2018-02-06 | 2018-02-06 | BT120 alcohol water environmental protection compound oil ink |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110117434A true CN110117434A (en) | 2019-08-13 |
Family
ID=67519946
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810118575.1A Withdrawn CN110117434A (en) | 2018-02-06 | 2018-02-06 | BT120 alcohol water environmental protection compound oil ink |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111040511A (en) * | 2019-12-20 | 2020-04-21 | 江苏正红彩印有限公司 | Alcohol-water environment-friendly composite ink and preparation method thereof |
| CN112661921A (en) * | 2020-12-18 | 2021-04-16 | 苏州华裕佳和新材料科技有限公司 | Novel antibacterial agent, preparation method and application |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107118614A (en) * | 2017-06-22 | 2017-09-01 | 汕头市瑞宇科技有限公司 | A kind of environment-friendly type aqueous ink and preparation method thereof |
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107118614A (en) * | 2017-06-22 | 2017-09-01 | 汕头市瑞宇科技有限公司 | A kind of environment-friendly type aqueous ink and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111040511A (en) * | 2019-12-20 | 2020-04-21 | 江苏正红彩印有限公司 | Alcohol-water environment-friendly composite ink and preparation method thereof |
| CN112661921A (en) * | 2020-12-18 | 2021-04-16 | 苏州华裕佳和新材料科技有限公司 | Novel antibacterial agent, preparation method and application |
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Application publication date: 20190813 |