CN110115923A - It is a kind of for examining the technique of testing laboratory's exhaust-gas treatment - Google Patents

It is a kind of for examining the technique of testing laboratory's exhaust-gas treatment Download PDF

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Publication number
CN110115923A
CN110115923A CN201910372841.8A CN201910372841A CN110115923A CN 110115923 A CN110115923 A CN 110115923A CN 201910372841 A CN201910372841 A CN 201910372841A CN 110115923 A CN110115923 A CN 110115923A
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CN
China
Prior art keywords
exhaust
section
technique
examining
gas treatment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910372841.8A
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Chinese (zh)
Inventor
付光明
李云玲
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Shanghai Tanzers Environmental Technology Co Ltd
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Shanghai Tanzers Environmental Technology Co Ltd
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Application filed by Shanghai Tanzers Environmental Technology Co Ltd filed Critical Shanghai Tanzers Environmental Technology Co Ltd
Priority to CN201910372841.8A priority Critical patent/CN110115923A/en
Publication of CN110115923A publication Critical patent/CN110115923A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/007Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by irradiation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/38Removing components of undefined structure
    • B01D53/40Acidic components
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/75Multi-step processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/76Gas phase processes, e.g. by using aerosols
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/81Solid phase processes
    • B01D53/82Solid phase processes with stationary reactants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/102Carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/106Silica or silicates
    • B01D2253/108Zeolites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/116Molecular sieves other than zeolites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Toxicology (AREA)
  • Dispersion Chemistry (AREA)
  • Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)

Abstract

The invention discloses a kind of for examining the technique of testing laboratory's exhaust-gas treatment, including oxygenolysis section, sour gas absorbing reaction section and activated carbon adsorption section, the sour gas absorbing reaction section includes solid basic material, and the side of sour gas absorbing reaction section is connected with activated carbon adsorption section, exhaust gas is discharged after peroxide decomposition section, sour gas absorbing reaction section, activated carbon adsorption section.The exhaust-gas treatment that technique for examining testing laboratory's exhaust-gas treatment of the invention is suitable for generating during laboratory internal routine work, the waste gas treatment process can extend active carbon service life, it will not lead to occur exhaust gas discharge situation not up to standard due to the active carbon replacement cycle is short because of activated carbon adsorption capacity problem, environmental hazard is reduced, accomplishes environmental protection.

Description

It is a kind of for examining the technique of testing laboratory's exhaust-gas treatment
Technical field
It is specifically a kind of for examining testing laboratory's exhaust-gas treatment the present invention relates to laboratory exhaust gas processing technology field Technique.
Background technique
With social development, requirement of the people for environmental condition is higher and higher, and the requirement to itself working environment is also got over Come higher.Examine testing laboratory discharge exhaust gas mainly by the exhaust gas for generation of volatilizing in laboratory internal personnel's operating process with And the exhaust gas composition that laboratory internal storage reagent is volatilized.Concentration is lower under normal conditions for the type exhaust gas, and ingredient is more multiple It is miscellaneous, predominantly some volatile sour gas and organic gas, such as: HCl, acetic acid, methanol, ethyl alcohol, n-hexane, acetone Deng.In view of the very low complicated component of concentration, recycling economic benefit is low, is suitble to destructive decomposition.
Many exhaust-gas treatments services commercial city is handled using activated carbon adsorption at present, but due to the work after adsorption saturation There is still a need for environmental protection treatments for property charcoal, not can solve real environmental problem.Therefore, it is necessary to one kind can prolong for low concentration gas The technique of long acting charcoal service life.
Summary of the invention
The purpose of the present invention is to provide a kind of for examining the technique of testing laboratory's exhaust-gas treatment, to solve above-mentioned back The problem of being proposed in scape technology.
To achieve the above object, the invention provides the following technical scheme:
It is a kind of for examining the technique of testing laboratory's exhaust-gas treatment, including oxygenolysis section, sour gas absorbing reaction section and Activated carbon adsorption section, the sour gas absorbing reaction section include solid basic material, and the one of sour gas absorbing reaction section Side is connected with activated carbon adsorption section, and exhaust gas is through peroxide decomposition section, sour gas absorbing reaction section, activated carbon adsorption section heel row Out.
As a further solution of the present invention: the oxygenolysis section includes that ozone oxidation and photooxidation are decomposed.
As further scheme of the invention: it includes UV oxygenolysis and photochemical catalytic oxidation point that the photooxidation, which is decomposed, Solution.
As further scheme of the invention: the solid basic material in the sour gas absorbing reaction section includes changing Property active carbon, modified molecular screen, alkaline adsorption material.
As further scheme of the invention: the modified molecular screen includes 3A molecular sieve, 4A molecular sieve, 5A molecular sieve And carbon molecular sieve.
As further scheme of the invention: the activated carbon adsorption section includes active carbon fibre peacekeeping carbon black active carbon.
As further scheme of the invention: the alkaline adsorption material refers to the composite wood with alkaline adsorption property Material.
Compared with prior art, the beneficial effects of the present invention are:
Technique for examining testing laboratory's exhaust-gas treatment of the invention is suitable for producing during laboratory internal routine work Raw exhaust-gas treatment, the waste gas treatment process can extend active carbon service life, will not lead because of activated carbon adsorption capacity problem It causes the active carbon replacement cycle short and exhaust gas occurs and discharge situation not up to standard, reduce environmental hazard, accomplish environmental protection.
Detailed description of the invention
Fig. 1 is a kind of flow chart of technique for examining testing laboratory's exhaust-gas treatment.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other Embodiment shall fall within the protection scope of the present invention.
Referring to Fig. 1, in the embodiment of the present invention, it is a kind of for examining the technique of testing laboratory's exhaust-gas treatment, including oxygen Change decomposition section, sour gas absorbing reaction section and activated carbon adsorption section, the sour gas absorbing reaction section and includes solid alkaline Substance, and the side of sour gas absorbing reaction section is connected with activated carbon adsorption section, exhaust gas is through peroxide decomposition section, sour gas It is discharged after absorbing reaction section, activated carbon adsorption section.
The oxygenolysis section includes that ozone oxidation and photooxidation are decomposed;The photooxidation decompose include UV oxygenolysis and Photochemical catalytic oxidation is decomposed, can generate in Photocatalytic Oxidation a large amount of hydroxyl radical free radical and ozone and other with Strong oxdiative Property substance, constantly reacted with the VOCs in exhaust gas in the mixed process with exhaust gas, reduce VOCs concentration;Without completely anti- The organic constituents and the remaining material composition with strong oxidizing property answered enter activated carbon adsorption section together and are adsorbed, in activity Further occurrence oxidation reaction in charcoal micropore decomposes VOCs, treating capacity of the enhancing active carbon to exhaust gas.
Solid basic material in the sour gas absorbing reaction section includes but is not limited to modified activated carbon, modified molecules Sieve, alkaline adsorption material, this substance mainly have basic character, and it is anti-that chemistry occurs for the sour gas for being easy and touching It answers;Laboratory discharge exhaust gas in sour gas in this conversion zone is absorbed and and remove, rear end active carbon will not be occupied Adsorption capacity.
In most cases sour gas is difficult to be oxidized, such as the hydrogen chloride and acetic gas that often have in laboratory, this Class exhaust gas changes by prime oxygenolysis section almost without what concentration, can be direct if absorbing neutralizing zone without sour gas Into activated carbon adsorption section, the adsorption capacity that can not only occupy active carbon can also be with the increase of adsorbance and gradually by active carbon Inside release, influences ambient enviroment.
The modified molecular screen includes 3A molecular sieve, 4A molecular sieve, 5A molecular sieve and carbon molecular sieve.
The activated carbon adsorption section includes active carbon fibre peacekeeping carbon black active carbon.
The alkaline adsorption material refers to the composite material with alkaline adsorption property.
Technique for examining testing laboratory's exhaust-gas treatment of the invention is suitable for laboratory internal routine work process The exhaust-gas treatment of middle generation, the waste gas treatment process can extend active carbon service life, will not ask because of activated carbon adsorption capacity Topic causes the active carbon replacement cycle short and exhaust gas occurs and discharge situation not up to standard, reduces environmental hazard, accomplishes environmental protection.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (7)

1. a kind of for examining the technique of testing laboratory's exhaust-gas treatment, including oxygenolysis section, sour gas absorbing reaction section With activated carbon adsorption section, the sour gas absorbing reaction section includes solid basic material, and sour gas absorbing reaction section Side is connected with activated carbon adsorption section, and exhaust gas is through peroxide decomposition section, sour gas absorbing reaction section, activated carbon adsorption section heel row Out.
2. according to claim 1 a kind of for examining the technique of testing laboratory's exhaust-gas treatment, which is characterized in that described Oxygenolysis section includes that ozone oxidation and photooxidation are decomposed.
3. according to claim 2 a kind of for examining the technique of testing laboratory's exhaust-gas treatment, which is characterized in that described It includes that UV oxygenolysis and photochemical catalytic oxidation are decomposed that photooxidation, which is decomposed,.
4. according to claim 1 a kind of for examining the technique of testing laboratory's exhaust-gas treatment, which is characterized in that described Solid basic material in sour gas absorbing reaction section includes modified activated carbon, modified molecular screen, alkaline adsorption material.
5. according to claim 4 a kind of for examining the technique of testing laboratory's exhaust-gas treatment, which is characterized in that described Modified molecular screen includes 3A molecular sieve, 4A molecular sieve, 5A molecular sieve and carbon molecular sieve.
6. according to claim 4 a kind of for examining the technique of testing laboratory's exhaust-gas treatment, which is characterized in that described Alkaline adsorption material refers to the composite material with alkaline adsorption property.
7. according to claim 1 a kind of for examining the technique of testing laboratory's exhaust-gas treatment, which is characterized in that described Activated carbon adsorption section includes active carbon fibre peacekeeping carbon black active carbon.
CN201910372841.8A 2019-05-06 2019-05-06 It is a kind of for examining the technique of testing laboratory's exhaust-gas treatment Pending CN110115923A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910372841.8A CN110115923A (en) 2019-05-06 2019-05-06 It is a kind of for examining the technique of testing laboratory's exhaust-gas treatment

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Application Number Priority Date Filing Date Title
CN201910372841.8A CN110115923A (en) 2019-05-06 2019-05-06 It is a kind of for examining the technique of testing laboratory's exhaust-gas treatment

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Publication Number Publication Date
CN110115923A true CN110115923A (en) 2019-08-13

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111346498A (en) * 2020-03-03 2020-06-30 上海坦泽环保科技有限公司 Biological filtration waste gas device

Citations (8)

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Publication number Priority date Publication date Assignee Title
KR20060107021A (en) * 2005-04-06 2006-10-13 조영봉 Device and method for treatment of odor and hazardous air pollutant
CN104548901A (en) * 2014-12-31 2015-04-29 环境保护部华南环境科学研究所 Integrated treating method for plastic pelletization waste gas
CN105311911A (en) * 2015-11-11 2016-02-10 华北电力大学(保定) Experimental ventilation cabinet filtering device
CN107088360A (en) * 2017-05-15 2017-08-25 扬州天辉实验室装备环保工程有限公司 A kind of special cleaning equipment for waste organic gas of laboratory hood pipeline
CN207102281U (en) * 2017-08-30 2018-03-16 佛山市高明高盛铝业有限公司 Aluminium alloy producing line emission-control equipment
CN207237655U (en) * 2017-08-07 2018-04-17 玛纳斯县舜达化纤有限责任公司 A kind of chemical fibre emission-control equipment
CN108854506A (en) * 2018-07-12 2018-11-23 芜湖鑫霖森椽环保科技有限公司 A kind of processing unit of acidity smog
CN208448871U (en) * 2018-03-01 2019-02-01 北京新绿祥瑞环保科技有限公司 Dry chemistry filters waste gas treatment equipment

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20060107021A (en) * 2005-04-06 2006-10-13 조영봉 Device and method for treatment of odor and hazardous air pollutant
CN104548901A (en) * 2014-12-31 2015-04-29 环境保护部华南环境科学研究所 Integrated treating method for plastic pelletization waste gas
CN105311911A (en) * 2015-11-11 2016-02-10 华北电力大学(保定) Experimental ventilation cabinet filtering device
CN107088360A (en) * 2017-05-15 2017-08-25 扬州天辉实验室装备环保工程有限公司 A kind of special cleaning equipment for waste organic gas of laboratory hood pipeline
CN207237655U (en) * 2017-08-07 2018-04-17 玛纳斯县舜达化纤有限责任公司 A kind of chemical fibre emission-control equipment
CN207102281U (en) * 2017-08-30 2018-03-16 佛山市高明高盛铝业有限公司 Aluminium alloy producing line emission-control equipment
CN208448871U (en) * 2018-03-01 2019-02-01 北京新绿祥瑞环保科技有限公司 Dry chemistry filters waste gas treatment equipment
CN108854506A (en) * 2018-07-12 2018-11-23 芜湖鑫霖森椽环保科技有限公司 A kind of processing unit of acidity smog

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111346498A (en) * 2020-03-03 2020-06-30 上海坦泽环保科技有限公司 Biological filtration waste gas device

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Application publication date: 20190813

RJ01 Rejection of invention patent application after publication