CN110105793A - A kind of method of acetylene carbon black modification - Google Patents
A kind of method of acetylene carbon black modification Download PDFInfo
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- CN110105793A CN110105793A CN201910539716.1A CN201910539716A CN110105793A CN 110105793 A CN110105793 A CN 110105793A CN 201910539716 A CN201910539716 A CN 201910539716A CN 110105793 A CN110105793 A CN 110105793A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/44—Carbon
- C09C1/48—Carbon black
- C09C1/54—Acetylene black; thermal black ; Preparation thereof
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/44—Carbon
- C09C1/48—Carbon black
- C09C1/56—Treatment of carbon black ; Purification
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/44—Carbon
- C09C1/48—Carbon black
- C09C1/56—Treatment of carbon black ; Purification
- C09C1/565—Treatment of carbon black ; Purification comprising an oxidative treatment with oxygen, ozone or oxygenated compounds, e.g. when such treatment occurs in a region of the furnace next to the carbon black generating reaction zone
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/04—Physical treatment, e.g. grinding, treatment with ultrasonic vibrations
- C09C3/048—Treatment with a plasma
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/06—Treatment with inorganic compounds
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/22—Rheological behaviour as dispersion, e.g. viscosity, sedimentation stability
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/40—Electric properties
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Abstract
A kind of method of acetylene carbon black modification, belongs to carbon material field.The method of modification includes: to carry out hydridization processing to acetylene carbon black to increase hydrophilic radical on the surface of the acetylene carbon black to make the acetylene carbon black be constituted amphiphilic material.The intrinsic attribute of the acetylene carbon black of this method preparation has improved dispersibility, thus the occurrence of reducing reunion.
Description
Technical field
This application involves conductive material fields, in particular to a kind of method of acetylene carbon black modification.
Background technique
Acetylene carbon black is a kind of amorphous carbon.Its quality is lighter, and has biggish surface area, and because conductive characteristic
And it has broad application prospects.However, the reunion characteristic of acetylene carbon black keeps its application limited.
Summary of the invention
Based on above-mentioned deficiency, this application provides a kind of methods of acetylene carbon black modification, with partly or entirely
Improve, even solve the problems, such as that acetylene carbon black is reunited.
The application is achieved in that
The method of acetylene carbon black modification includes:
Hydridization processing is carried out to increase hydrophilic radical on the surface of acetylene carbon black to make acetylene carbon black structure to acetylene carbon black
At amphiphilic material.
With reference to first aspect, in the first possible embodiment of the first aspect of the application, hydridization processing includes:
In acetylene during cracking in pyrolysis furnace, surface modified dose is added into pyrolysis furnace.Wherein, hydrophilic radical by
Surface modified dose of offer.
By being surface modified other chemical groups (such as oxygen-containing group, hydrophilic radical) to acetylene carbon black, to make
The polarity and granulation uniformity of acetylene carbon black are enhanced, and are therefore easily dispersed and are mixed with other materials (such as organic polymer)
It closes.
The possible embodiment of with reference to first aspect the first, in second of possible reality of the first aspect of the application
Shi Fangzhong, surface modified dose is gas and/or liquid.
A plurality of types of surface modified doses can be used to live together acetylene carbon black, to be the implementation of method
Convenience is provided, sufficient selection is provided for implementer, is selected to be conducive to implementer according to own situation.
The possible embodiment of second with reference to first aspect, in the third possible reality of the first aspect of the application
Shi Fangzhong, the surface modified dose of mixture for nitrogenous compound, oxygenatedchemicals and hydrogen-containing compound.
Nitrogenous compound, oxygenatedchemicals and hydrogen-containing compound all have the substance being easily obtained, to be conducive to lead to
Cross the cost of manufacture for using the raw material of low cost to reduce modified acetylene carbon black.
The third possible embodiment with reference to first aspect, in the 4th kind of possible reality of the first aspect of the application
Shi Fangzhong, surface modified dose includes carbon dioxide, carbon monoxide, hydrogen, ammonia and hydrogen peroxide.
The possible embodiment of with reference to first aspect the first, in the 5th kind of possible reality of the first aspect of the application
Shi Fangzhong, the method for modification include: to separate to pyrolysis product, then carry out brokenly poly- and purified treatment again.
Since modified acetylene carbon black is easily dispersed, also easily separated with other materials, to be also easier to brokenly
Except its reunion, the impurity in aggregate may be included with release, and the high acetylene carbon black of degree of purity is obtained by purified treatment.
With reference to first aspect, in the 6th kind of possible embodiment of the first aspect of the application, hydridization processing includes
Gas phase hydridization, and gas phase hydridization includes: the mixed gas for constituting hydrogen, ozone, oxygen, nitrogen and air and acetylene carbon black
Mixing.
With reference to first aspect, in the 7th kind of possible embodiment of the first aspect of the application, hydridization processing includes
Liquid phase hydridization, and liquid phase hydridization includes: by hydrogen peroxide, nitric acid, perchloric acid, ammonium persulfate, potassium permanganate, hypochlorite and again
The solution that potassium chromate is constituted is mixed with acetylene carbon black.
With reference to first aspect, in the 8th kind of possible embodiment of the first aspect of the application, hydridization processing includes
Plasma hydridization, and plasma hydridization includes: to aoxidize the surface of acetylene carbon black by corona discharge.
During implementation above, acetylene carbon black provided by the embodiments of the present application makes its hydrophobic second by microcosmic modification
Alkynes carbon black particle surface has hydrophilic polar group, makes have enough electrostatic repulsions and/or space between acetylene black carbon particles
Resistance prevents from assembling, and therefore makes it have improved dispersibility, and can also obtain the electric conductivity of raising, to promote
Into its application in terms of electrical devices (such as battery).
Detailed description of the invention
In order to illustrate the technical solutions in the embodiments of the present application or in the prior art more clearly, to embodiment or will show below
There is attached drawing needed in technical description to be briefly described.
Fig. 1 is the structural schematic diagram of the device for being used to prepare acetylene carbon black provided in embodiments herein；
Fig. 2A is the contact angle test figure of the acetylene carbon black handled without surface hydridization；
Fig. 2 B is the contact angle test figure for having already passed through the acetylene carbon black of surface hydridization processing；
Fig. 3 A is the test chart of the Zeta potential value of the acetylene carbon black handled without surface hydridization；
Fig. 3 B is the test chart for having already passed through the Zeta potential value of acetylene carbon black of surface hydridization processing.
Icon: 201- adding set；202- pyrolysis furnace；203- feed separation equipment；204- breaks poly- purification device.
Specific embodiment
It is described in detail below in conjunction with embodiment of the embodiment to the application, but those skilled in the art will
Understand, the following example is merely to illustrate the application, and is not construed as limitation scope of the present application.It is not specified in embodiment specific
Condition person carries out according to conventional conditions or manufacturer's recommended conditions.Reagents or instruments used without specified manufacturer is
The conventional products that can be obtained by commercially available purchase.
In practice, acetylene cracking temperature is substantially at 1400 DEG C or more.By carrying out acetylene absolutely in preceding cleavage temperature
Oxygen cracks and obtains acetylene carbon black.This reaction temperature (cracking temperature) determines that acetylene carbon black is that one kind is easier to adhesion, is not easy
The material of dispersion, and size is uneven between the individual particles of acetylene carbon black, it is widely different.This is resulted in actual use
Acetylene carbon black material uniformly can not be combined very much with other materials, greatly reduce the electric conductivity, thermally conductive of composite material
Performance.
To find out its cause, inventor thinks that the small primary partical of acetylene carbon black, large specific surface area, surface free energy are high, therefore
Extremely strong autohemagglutination power is shown between carbon black particle, in addition the polarity on acetylene carbon black surface and nonpolar functional group are all seldom (such as
Oxygen-containing group is less) so that carbon black is very poor with the compatibility of most of polymer, organic solvent and water.And simultaneously because
Carbon blacksurface is mainly made of graphite linings structural carbon, therefore acetylene carbon black generally has good wetting to nonpolar solvents such as benzene
Performance, and the wettability in water isopolarity solvent is poor.This is unfavorable for the dispersion of carbon black in water, to improve its performance,
It then needs to be changed its polarity and granulation uniformity.
In order to improve the dispersibility of acetylene carbon black, in some schemes known for inventor, by control reaction temperature to drop
Low agglomeration.Although reducing reunion to a certain extent by scheme above-mentioned, also cause to occur lysis efficiency reduce,
The defects of product parameters are not easy to control, degree of graphitization reductions, electric conductivity decline, imbibition, oil absorption capacity decline.
In view of this, inventors herein proposing a kind of new scheme.Point of the improvement acetylene carbon black provided in the application example
The technique for dissipating property, also helping makes acetylene black carbon particles become uniform.
Above-mentioned technique is provided in this example in the method for acetylene carbon black modification.In the application, the modification
Method acetylene carbon black is adjusted from microcosmic angle, so that modified acetylene carbon black is had both hydrophily and lipophilic characteristic.It should
The method of modification can repair the defect of acetylene carbon black primary particle, adjust acetylene carbon black in different systems (polarity, non-pole
Property) dispersibility.
For from principle, the principle that acetylene carbon black is transformed in the method that the application example provides is: by hydridization tune
The polarity and granulation uniformity of whole carbon black.That is, it is surface modified to acetylene carbon black using hydridization method, reduce contact will pass through
Angle (increasing hydrophilic radical by carbon blacksurface to realize) promotes the hydrophily of acetylene carbon black.Meanwhile this method is also in acetylene charcoal
Black surface increases oxygen-containing group, and promotes Zeta potential value because of the use of oxygen-containing group, the acetylene charcoal after making modification
It is black be easier to dispersion, dispersion stabilization it is higher.In addition, modified acetylene carbon black also has the property that the hydrophily of carbon black is got over
Good, then its contact angle is better.In view of acetylene carbon black itself has relatively good lipophilicity, therefore to its surface modified master
It is to improve hydrophily.
Illustratively, the method for acetylene carbon black modification includes: to carry out hydridization processing in acetylene charcoal to acetylene carbon black
Black surface increases hydrophilic radical to make acetylene carbon black constitute amphiphilic material.In other words, containing due to acetylene carbon black surface
Oxygen functional group is less, fugitive constituent is low, the polarity on surface is smaller, while granulation uniformity is bad, to be unfavorable for carbon black in water material
It is evenly dispersed in Material system.To improve its performance, hydridization processing is carried out to it in the application example, changes its surface polarity simultaneously
Improve its particle uniformity.Hydridization treated carbon black oxygen content increases, pH value reduces, the hydrophily oxygen-containing functional group on surface
(such as carboxyl, hydroxyl) increases, and granulation uniformity tends to concentrate, therefore is easily dispersed in aqueous dispersion, moreover it is possible to keep length
Long dispersion stabilization.
As the first implementation, hydridization processing includes: in acetylene during cracking in pyrolysis furnace, to splitting
It solves and surface modified dose is added in furnace.During acetylene cracks, surface modified dose also assists in and reacted
Journey.Surface modified dose is integrated to acetylene carbon black surface, to realize the hybrid modification to acetylene carbon black.
Wherein, it is capable of providing hydrophilic radical above-mentioned for surface modified dose.In different examples, surface modified
Agent can use different components as requested.In some examples, surface modified dose is gas；In other examples,
Surface modified dose is liquid；In some other examples, surface modified dose is mixture of gas and liquid.It can replace
Dai Di, in the example of part, surface modified dose is selected as nitrogenous compound, oxygenatedchemicals and hydrogen-containing compound
Mixture.For example, surface modified dose includes carbon dioxide, carbon monoxide, hydrogen, ammonia and hydrogen peroxide.
In view of above surface modified dose, the oxygen content after acetylene carbon black hydridization be will increase, and carboxyl, hydroxyl group also can
With increasing, and these groups are hydrophilic.With the increase of surface hydridization, carbon blacksurface hydrophilic radical will increase on year-on-year basis
It is more, so that acetylene carbon black is changed into amphiphilic material, adds uniform granularity and good spatial distribution.Acetylene carbon black is just
It can achieve the purpose that be easily dispersed uniform stably dispersing degree in different dispersions high.
Generally, anti-to cracking in the ratio selected while acetylene Pintsch process in the first implementation
Answer area that compound (such as CO containing N, H, O is added2、CO、H2、NH3、H2O2/ liquid etc.), carbon blacksurface is modified with hydridization method
Modification.Further, the method for modification includes: to separate to pyrolysis product, then carries out brokenly poly- and purifies again
Processing.Wherein, the aggregating state that cumulative enough opens acetylene carbon black is broken, and association (high-temperature coking, equipment corruption are fallen by purified treatment
Lose, fall off) impurity have particle and the uniform feature of structure while so that acetylene carbon black is kept high-purity, easily dispersion.Example
Such as, surface modified dose is vapor, carbon dioxide and nitrogen, and the dosage of acetylene is surface modified dose of dosage
0.3 times.
It correspondingly, include adding set 201, pyrolysis furnace 202, material point in the acetylene carbon black Preparation equipment for implementing the program
From equipment 203 and poly- purification device 204 is broken, refering to fig. 1.Each equipment is connected by equipment such as pipeline, valve, flanges
It connects.Above each equipment uses equipment known for inventor or commercial equipment.
By implementing the first aforementioned implementation, on the one hand, this method can reduce the nucleation reaction temperature of charcoal, simultaneously
Carbon black pellet growth is terminated in time, so that carbon black pellet be made to become uniform.On the other hand, carbon black pellet surface forms function
Group, so as to improve particle adhesion, forms good spatial distribution.In another aspect, carbon blacksurface can reduce, reversing, lead to
It crosses and increases hydrophilic radical and oxygen-containing group on acetylene carbon black surface, acetylene carbon black finished product is made to reach amphiphilic (oleophylic, hydrophily).
It is not surface modified modified acetylene carbon black and passes through itself and liquid with the hydrophily that have passed through surface modified acetylene carbon black
The difference of contact angle between body is indicated by Fig. 2A and Fig. 2 B, and is connect what the different multiple test detections of sample progress obtained
Feeler (uses optical contact angle measuring instrument, the measurement of throughput supreme people's court.) comparison is as shown in table 1.Wherein, part does not carry out surface
The contact angle of the acetylene carbon black of modification is as shown in Figure 2 A；The partial contact that have passed through surface modified acetylene carbon black
Angle is as shown in Figure 2 B.
The contact angle of the different sample acetylene carbon blacks of table 1
In addition, the oxygen-containing group for being formed in acetylene carbon black surface makes acetylene carbon black be capable of forming stable solvation in water
Layer, while the cation in adsorption solvent forms double electrical layers, resulting repulsive force hinders the collision between carbon black pellet
Cohesion.Therefore, increase carbon blacksurface oxygen-containing group, system Zeta potential can be increased, the hydrophily and dispersibility for increasing carbon black (are divided
Dissipate stability).The Zeta potential value of acetylene carbon black whether surface modified (hydridization processing) is as shown in Figure 3A and Figure 3B.
The measurement method of Zeta potential value is as follows: Malvern zeta potential instrument directly measures: model NaNo-ZS, nano particle size and Zeta
Potentiometer, according to instrumentation regulation implement.
As a result, in use, the acetylene carbon black after surface modified can equably be mixed with other materials
Together, and therefore excellent conduction, heating conduction are given full play to.
In other examples of the application, hydridization handles the method for acetylene carbon black in addition to above in acetylene cracking process
It adds except surface modified dose, further includes gas phase hydridization, liquid phase hydridization, plasma hydridization etc..Wherein, gas phase hydridization
With liquid phase hydridization all mainly using addition exogenous material, and the exogenous material carried out with acetylene carbon black it is real after reaction bonded
Now to the modification of acetylene carbon black.Plasma hydridization can then be such that acetylene is modified by the way that oxidation reaction occurs, thus to acetylene
Carbon black is modified.
For gas phase hydridization, gas phase hydridization includes: the mixing for constituting hydrogen, ozone, oxygen, nitrogen and air
Gas is mixed with acetylene carbon black.Acetylene is injected and cracked by top in pyrolysis furnace, the latter end (pyrolysis furnace of cracking reaction
Lower part, the section of temperature 700-900 degree) it is passed through the compound of nitrogenous oxygen, which can be under conditions of high temperature and acetylene charcoal
Black surface forms N/O group.Such gas phase hydridization processing has the advantages that easy to operate.
For liquid phase hydridization, liquid phase hydridization include: by hydrogen peroxide, nitric acid, perchloric acid, ammonium persulfate, potassium permanganate,
The solution that hypochlorite and potassium bichromate are constituted is mixed with acetylene carbon black.Acetylene enters in pyrolysis furnace cracking process, is cracking
The lower part of furnace is passed through the compound of the nitrogenous oxygen of liquid, so that liquid phase substance reacts to form modification group with acetylene carbon black surface.
For plasma hydridization, plasma hydridization includes: to send out the surface of acetylene carbon black by corona discharge
Raw oxidation.High-frequency corona is selected as according to the type of voltage corona discharge above-mentioned.
The foregoing is merely preferred embodiment of the present application, are not intended to limit this application, for the skill of this field
For art personnel, various changes and changes are possible in this application.Within the spirit and principles of this application, made any to repair
Change, equivalent replacement, improvement etc., should be included within the scope of protection of this application.
Claims (9)
1. a kind of method of acetylene carbon black modification, which is characterized in that the method for the modification includes:
Hydridization processing is carried out to increase hydrophilic radical on the surface of the acetylene carbon black to make the acetylene charcoal to acetylene carbon black
It is black to constitute amphiphilic material.
2. the method for acetylene carbon black modification according to claim 1, which is characterized in that the hydridization, which is handled, includes:
In acetylene during cracking in pyrolysis furnace, surface modified dose is added into pyrolysis furnace；
Wherein, the hydrophilic radical is provided by described surface modified dose.
3. the method for acetylene carbon black modification according to claim 2, which is characterized in that described surface modified dose
For gas and/or liquid.
4. the method for acetylene carbon black modification according to claim 3, which is characterized in that described surface modified dose
For the mixture of nitrogenous compound, oxygenatedchemicals and hydrogen-containing compound.
5. the method for acetylene carbon black modification according to claim 4, which is characterized in that described surface modified dose
Including carbon dioxide, carbon monoxide, hydrogen, ammonia and hydrogen peroxide.
6. the method for acetylene carbon black modification according to claim 2, which is characterized in that the method for the modification
Include:
Pyrolysis product is separated, then carries out brokenly poly- and purified treatment again.
7. the method for acetylene carbon black modification according to claim 1, which is characterized in that the hydridization processing includes gas
Phase hydridization, and the gas phase hydridization includes:
The mixed gas that hydrogen, ozone, oxygen, nitrogen and air are constituted is mixed with acetylene carbon black.
8. the method for acetylene carbon black modification according to claim 1, which is characterized in that the hydridization processing includes liquid
Phase hydridization, and the liquid phase hydridization includes:
The solution and second that hydrogen peroxide, nitric acid, perchloric acid, ammonium persulfate, potassium permanganate, hypochlorite and potassium bichromate are constituted
The mixing of alkynes carbon black.
9. the method for acetylene carbon black modification according to claim 1, which is characterized in that hydridization processing includes etc.
Gas ions hydridization, and the plasma hydridization includes:
The surface of acetylene carbon black is aoxidized by corona discharge.
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111171607A (en) * | 2020-04-09 | 2020-05-19 | 北京化工大学 | Method for preparing hydrophilic carbon black, hydrophilic carbon black and application thereof |
| CN111269590A (en) * | 2020-03-04 | 2020-06-12 | 焦作市和兴化学工业有限公司 | Preparation method of easily-dispersible acetylene black |
| CN112226102A (en) * | 2020-09-25 | 2021-01-15 | 石嘴山市华昊化工有限公司 | Preparation method of easily-dispersible acetylene black |
| CN114316634A (en) * | 2021-12-15 | 2022-04-12 | 焦作市和兴化学工业有限公司 | Preparation method of high-structure acetylene carbon black |
| CN115867615A (en) * | 2020-07-01 | 2023-03-28 | 韩国核融合能源研究院 | Method for improving water dispersibility of conductive carbon powder and method for preparing colloidal solution of conductive carbon powder |
| CN117417654A (en) * | 2023-10-10 | 2024-01-19 | 江西缙禧纳米材料有限公司 | Modification method of carbon black for lithium ion battery and lithium ion battery |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1844266A (en) * | 2006-03-23 | 2006-10-11 | 华东理工大学 | Water-soluble conductive macromolecular surface modification carbon black and method for preparing same |
| CN101824126A (en) * | 2010-05-07 | 2010-09-08 | 华东理工大学 | Hydrophilic carbon black |
| EP2228343A1 (en) * | 2009-03-13 | 2010-09-15 | Bayer MaterialScience AG | Water vapour assisted ozonolysis of carbon nanotubes |
| CN103980742A (en) * | 2014-05-12 | 2014-08-13 | 梁洪奎 | Production method of modified carbon black |
| CN104804479A (en) * | 2015-03-23 | 2015-07-29 | 青岛科技大学 | Two-phase pyrolysis carbon black/white carbon black composite filler and preparation method thereof |
| CN108485317A (en) * | 2018-04-10 | 2018-09-04 | 刘欣 | A kind of processing method of natural gas acetylene coproduction carbon black |
| CN109370268A (en) * | 2018-10-24 | 2019-02-22 | 中昊黑元化工研究设计院有限公司 | Mixed gas expands the production technology of acetylene carbon black single line production capacity |
-
2019
- 2019-06-19 CN CN201910539716.1A patent/CN110105793A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1844266A (en) * | 2006-03-23 | 2006-10-11 | 华东理工大学 | Water-soluble conductive macromolecular surface modification carbon black and method for preparing same |
| EP2228343A1 (en) * | 2009-03-13 | 2010-09-15 | Bayer MaterialScience AG | Water vapour assisted ozonolysis of carbon nanotubes |
| CN101824126A (en) * | 2010-05-07 | 2010-09-08 | 华东理工大学 | Hydrophilic carbon black |
| CN103980742A (en) * | 2014-05-12 | 2014-08-13 | 梁洪奎 | Production method of modified carbon black |
| CN104804479A (en) * | 2015-03-23 | 2015-07-29 | 青岛科技大学 | Two-phase pyrolysis carbon black/white carbon black composite filler and preparation method thereof |
| CN108485317A (en) * | 2018-04-10 | 2018-09-04 | 刘欣 | A kind of processing method of natural gas acetylene coproduction carbon black |
| CN109370268A (en) * | 2018-10-24 | 2019-02-22 | 中昊黑元化工研究设计院有限公司 | Mixed gas expands the production technology of acetylene carbon black single line production capacity |
Non-Patent Citations (3)
| Title |
|---|
| 崔秀珍: "改造工艺条件提高乙炔炭黑尾气中的氢气含量", 《河南化工》 * |
| 朱永康: "炉法炭黑与乙炔炭黑低温等离子体改性的新可能性", 《橡胶参考资料》 * |
| 段建瑞等: "乙炔炭黑表面氧化改性及对硅橡胶压阻特性的影响", 《高分子材料科学与工程》 * |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111269590A (en) * | 2020-03-04 | 2020-06-12 | 焦作市和兴化学工业有限公司 | Preparation method of easily-dispersible acetylene black |
| CN111269590B (en) * | 2020-03-04 | 2021-10-22 | 焦作市和兴化学工业有限公司 | Preparation method of easily-dispersible acetylene black |
| CN111171607A (en) * | 2020-04-09 | 2020-05-19 | 北京化工大学 | Method for preparing hydrophilic carbon black, hydrophilic carbon black and application thereof |
| CN111171607B (en) * | 2020-04-09 | 2021-05-04 | 北京化工大学 | Method for preparing hydrophilic carbon black, hydrophilic carbon black and application thereof |
| CN115867615A (en) * | 2020-07-01 | 2023-03-28 | 韩国核融合能源研究院 | Method for improving water dispersibility of conductive carbon powder and method for preparing colloidal solution of conductive carbon powder |
| CN112226102A (en) * | 2020-09-25 | 2021-01-15 | 石嘴山市华昊化工有限公司 | Preparation method of easily-dispersible acetylene black |
| CN114316634A (en) * | 2021-12-15 | 2022-04-12 | 焦作市和兴化学工业有限公司 | Preparation method of high-structure acetylene carbon black |
| CN117417654A (en) * | 2023-10-10 | 2024-01-19 | 江西缙禧纳米材料有限公司 | Modification method of carbon black for lithium ion battery and lithium ion battery |
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