CN110105609A - The preparation process of colorful material - Google Patents
The preparation process of colorful material Download PDFInfo
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- CN110105609A CN110105609A CN201910464176.5A CN201910464176A CN110105609A CN 110105609 A CN110105609 A CN 110105609A CN 201910464176 A CN201910464176 A CN 201910464176A CN 110105609 A CN110105609 A CN 110105609A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/06—Coating with compositions not containing macromolecular substances
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/004—Reflecting paints; Signal paints
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
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- Engineering & Computer Science (AREA)
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Laminated Bodies (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
Present invention discloses the preparation processes of colorful material, using the self assembly of different monomers structure, form polymer network, height index matching, realize the part reflection of 380~750nm wave band, meet the colorful effect of multiple color, and the colorful tunic in colorful material monolithic is single coating, traditionally coating process can directly be substituted, it only needs to be coated with macromolecule layer on substrate and can reach tens of layers of traditional plated film of effect, reduce equipment investment, simple process and yields and be highly improved.Have reflectivity higher and mechanical strength, it is nontoxic, it is suitable for popularization and application.
Description
Technical field
The present invention relates to the preparation processes of colorful material, belong to the technical field of covering material preparation.
Background technique
The incrustation that colorful material is generally used for product uses, such as the decoration of some electronic products such as mobile phone backboard
Multiple color combination is presented under light illumination, and dazzles color effect as angle change exists for face.
Traditionally colorful layer preparation process is after selecting substrate, to utilize film design software design colours using plated film mode
Film program carries out, and plated film is essentially monochromatic coating, when carrying out colorful formable layer, needs through control thickness of coating and the coating number of plies
It realizes, filming equipment cost of investment is very high, and thickness of coating needs to control in nm rank, and monitoring and coating process control are very
Strictly, multicoating low efficiency, with high costs.And in high-temperature coating process, due to the shadow by high-energy particle bombardment and high temperature
It rings, macromolecule membrane performance is easily caused to change, become fragile and not weather-proof etc., be easy to produce scuffings, yields is only left 30%
It is right.
Summary of the invention
Present invention aim to address above-mentioned the deficiencies in the prior art, set for conventional multilayer plating form membrane colorful formable layer
Standby valuableness, complex process are also easy to produce the problems such as scuffing, propose the preparation process of colorful material.
In order to achieve the above object, the technical scheme adopted by the invention is as follows:
The preparation process of colorful material, includes the following steps:
S1 material prepares,
Coating material is chosen according to mass fraction:
20 parts of monomers,
0.5~1 part of initiator,
35~45 parts of solvents,
5~8 parts of crosslinking agents,
0~1 part of complexing agent, complexing agent include levelling agent, polymerization inhibitor, defoaming agent, diluent, ultraviolet absorbing agent, orientation
Any one or more combination in agent, surfactant, uv-curable glue and heat-curable glue,
Wherein, the monomer includes acrylic acid, methacrylic acid, acrylamide, n-isopropyl acrylamide, N- methylol
Acrylamide, N- isopropyl methyl acrylamide, methyl acrylate, ethyl acrylate, n-butyl acrylate, methyl methacrylate
Ester, ethyl methacrylate, at least two combinations in n-BMA,
The initiator includes ammonium persulfate, potassium peroxydisulfate, hydrogen peroxide, azo two (isobutyl amidine hydrochloride), azo
Two (isopropylimdazole quinoline hydrochlorides), 2- hydroxy-2-methyl -1- phenyl -1- acetone, diethoxy amyl phenyl ketone, 2,4,6- front three
Any one or more combination in base benzoylphenyl phosphonate ester, 1- hydroxycyclohexylphenylketone,
The solvent includes benzene,toluene,xylene, acetone, cyclopropanone, cyclohexanone, toluene cyclohexanone, dioxane, second
Glycol, glycerine, styrene, ethyl acetate, any one or more combination in glycol monoethyl ether,
The crosslinking agent includes N,N methylene bis acrylamide, ethylene glycol dimethacrylate, epoxy silane, poly- carbon
Any one or more combination in diimine,
The above coating material is uniformly mixed obtained base fluid,
Substrate selection, chooses 20 μm~60 μm of heat molten type light-sensitive surface；
S2 coating operations,
Substrate is soaked, then base fluid is uniformly coated on substrate surface and forms substrate body；
S3 toasts operation,
Built-in smooth metal pedestal layer in an oven, substrate body is placed on metal pedestal layer, oven baking temperature
70 DEG C~90 DEG C, baking time 20s~40s, melting substrate is made；
S4 curing operation,
UV is carried out to melting substrate and solidifies obtained semi-finished product；
S5 hot pressing is cut,
Semi-finished product hot pressing body and is cut to finished product in the form of sheets.
Preferably, in the step S1, coating material is chosen according to mass fraction:
15 parts of methacrylic acids, 5 parts of N hydroxymethyl acrylamides；
0.5 part of azo two (isobutyl amidine hydrochloride), 0.5 part of potassium peroxydisulfate；
20 parts of cyclohexanone, 20 parts of toluene；
5 parts of ethylene glycol dimethacrylates；
0.1 part of levelling agent, levelling agent are dimethyl silicone polymer.
Preferably, in the step S1, coating material is chosen according to mass fraction:
10 parts of acrylic acid, 5 parts of N hydroxymethyl acrylamides, 5 parts of ethyl methacrylate；
0.5 part of azo two (isobutyl amidine hydrochloride), 0.5 part of ammonium persulfate；
20 parts of cyclohexanone, 10 parts of cyclohexanone, 15 parts of dimethylbenzene；
4 parts of ethylene glycol dimethacrylates, 3 parts of N,N methylene bis acrylamides；
0.1 part of levelling agent, levelling agent are dimethyl silicone polymer.
Preferably, in the step S1, coating material is chosen according to mass fraction:
5 parts of methacrylic acids, 5 parts of acrylic acid, 5 parts of N- isopropyl methyl acrylamides, 5 parts of N hydroxymethyl acrylamides；
0.3 part of azo two (isobutyl amidine hydrochloride), 0.2 part of potassium peroxydisulfate, 0.3 part of diethoxy amyl phenyl ketone；
20 parts of cyclohexanone, 25 parts of toluene；
5 parts of ethylene glycol dimethacrylates；
Preferably, in the step S1, coating material is chosen according to mass fraction:
5 parts of acrylic acid, 5 parts of N hydroxymethyl acrylamides, 5 parts of n-butyl acrylates, 5 parts of n-BMAs；
0.5 part of azo two (isobutyl amidine hydrochloride), 0.1 part of potassium peroxydisulfate, 0.1 part of 2,4,6- trimethylbenzoyl benzene
Base phosphonate ester, 0.1 part of hydrogen peroxide；
20 parts of cyclohexanone, 20 parts of toluene；
5 parts of ethylene glycol dimethacrylates, 1 part of poly- carbodiimide, 1 part of N,N methylene bis acrylamide；
Preferably, in the step S1, coating material is chosen according to mass fraction:
10 parts of methacrylic acids, 2 parts of N hydroxymethyl acrylamides, 2 parts of N- isopropyl methyl acrylamides, 2 parts of acrylic acid
Ethyl ester, 2 parts of ethyl methacrylate, 2 parts of n-isopropyl acrylamide；
0.5 part of azo two (isobutyl amidine hydrochloride), 0.5 part of azo two (isopropylimdazole quinoline hydrochloride)；
20 parts of cyclohexanone, 20 parts of toluene；
5 parts of ethylene glycol dimethacrylates.
Preferably, in the step S1,50 μm of PET black film is chosen.
Preferably, in the step S2, OSP10# bar is selected to soak substrate, wetting gap is 10 μm.
Preferably, in the step S4, melting substrate passes through 40mj/cm2-800mj/cm2UV curing 30s.
Present invention further teaches the applications of colorful material, and colorful material is compounded in glass matrix table by coating hot-melt adhesive
Face.
The beneficial effects are mainly reflected as follows:
1. traditionally coating process can be substituted directly, it is only necessary to which being coated with macromolecule layer on substrate can reach traditional plated film
Tens of layers of effect reduces equipment investment, simple process and yields and is highly improved.
2. macromolecule layer utilizes the self assembly of different monomers structure, polymer network is formed, 380~750nm wave is realized
The part reflection of section, can show multiple color, meet colorful demand.
3. have reflectivity higher and mechanical strength, it is nontoxic, it is suitable for popularization and application.
Specific embodiment
The preparation process of present invention offer colorful material.Technical solution of the present invention is described in detail below, so that its
It is more readily understood and grasps.
The preparation process of colorful material, includes the following steps:
S1 material prepares,
Coating material is chosen according to mass fraction:
20 parts of monomers,
0.5~1 part of initiator,
35~45 parts of solvents,
5~8 parts of crosslinking agents,
0~1 part of complexing agent, complexing agent include levelling agent, polymerization inhibitor, defoaming agent, diluent, ultraviolet absorbing agent, orientation
Any one or more combination in agent, surfactant, uv-curable glue and heat-curable glue,
Wherein, the monomer includes acrylic acid, methacrylic acid, acrylamide, n-isopropyl acrylamide, N- methylol
Acrylamide, N- isopropyl methyl acrylamide, methyl acrylate, ethyl acrylate, n-butyl acrylate, methyl methacrylate
Ester, ethyl methacrylate, at least two combinations in n-BMA,
The initiator includes ammonium persulfate, potassium peroxydisulfate, hydrogen peroxide, azo two (isobutyl amidine hydrochloride), azo
Two (isopropylimdazole quinoline hydrochlorides), 2- hydroxy-2-methyl -1- phenyl -1- acetone, diethoxy amyl phenyl ketone, 2,4,6- front three
Any one or more combination in base benzoylphenyl phosphonate ester, 1- hydroxycyclohexylphenylketone,
The solvent includes benzene,toluene,xylene, acetone, cyclopropanone, cyclohexanone, toluene cyclohexanone, dioxane, second
Glycol, glycerine, styrene, ethyl acetate, any one or more combination in glycol monoethyl ether,
The crosslinking agent includes N,N methylene bis acrylamide, ethylene glycol dimethacrylate, epoxy silane, poly- carbon
Any one or more combination in diimine,
The above coating material is uniformly mixed obtained base fluid,
Substrate selection, chooses 20 μm~60 μm of heat molten type light-sensitive surface；
S2 coating operations,
Substrate is soaked, then base fluid is uniformly coated on substrate surface and forms substrate body；
S3 toasts operation,
Built-in smooth metal pedestal layer in an oven, substrate body is placed on metal pedestal layer, oven baking temperature
70 DEG C~90 DEG C, baking time 20s~40s, melting substrate is made；
S4 curing operation,
UV is carried out to melting substrate and solidifies obtained semi-finished product；
S5 hot pressing is cut,
Semi-finished product hot pressing body and is cut to finished product in the form of sheets.
The colorful material use macromolecular structure self assembly of this case forms molecular density gradient difference, and then realizes macromolecule
Polymeric inner height refringence, height index matching realize the part reflection of 380-750nm wave band, show a variety of face
Color, the colorful material are that can be coated directly onto the polymeric coating layer of substrate surface to greatly reduce instead of the coating process of transmission
The production cost of colorful film reduces production threshold.
It only needs to be coated with one layer of high molecular material in substrate surface and can achieve the effect that tens of layers of plated film, yields can
It is reflectivity height, high mechanical strength, nontoxic after application to reach 85% or more.
In specific embodiment, in step S1,50 μm of PET black film is chosen.In step S2, select OSP10# bar to substrate
It is soaked, wetting gap is 10 μm.In step S4, melting substrate passes through 40mj/cm2-800mj/cm2UV curing 30s.
The colorful material can be compounded in the higher substrate surface of the light transmittances such as PMMA, PC, glass by coating hot-melt adhesive.
Embodiment one
Coating material is chosen according to mass fraction:
15 parts of methacrylic acids, 5 parts of N hydroxymethyl acrylamides；
0.5 part of azo two (isobutyl amidine hydrochloride), 0.5 part of potassium peroxydisulfate；
20 parts of cyclohexanone, 20 parts of toluene；
5 parts of ethylene glycol dimethacrylates；
0.1 part of levelling agent, levelling agent are dimethyl silicone polymer.
Embodiment two
Coating material is chosen according to mass fraction:
10 parts of acrylic acid, 5 parts of N hydroxymethyl acrylamides, 5 parts of ethyl methacrylate；
0.5 part of azo two (isobutyl amidine hydrochloride), 0.5 part of ammonium persulfate；
20 parts of cyclohexanone, 10 parts of cyclohexanone, 15 parts of dimethylbenzene；
4 parts of ethylene glycol dimethacrylates, 3 parts of N,N methylene bis acrylamides；
0.1 part of levelling agent, levelling agent are dimethyl silicone polymer.
Embodiment three
Coating material is chosen according to mass fraction:
5 parts of methacrylic acids, 5 parts of acrylic acid, 5 parts of N- isopropyl methyl acrylamides, 5 parts of N hydroxymethyl acrylamides；
0.3 part of azo two (isobutyl amidine hydrochloride), 0.2 part of potassium peroxydisulfate, 0.3 part of diethoxy amyl phenyl ketone；
20 parts of cyclohexanone, 25 parts of toluene；
5 parts of ethylene glycol dimethacrylates；
Example IV
Coating material is chosen according to mass fraction:
5 parts of acrylic acid, 5 parts of N hydroxymethyl acrylamides, 5 parts of n-butyl acrylates, 5 parts of n-BMAs；
0.5 part of azo two (isobutyl amidine hydrochloride), 0.1 part of potassium peroxydisulfate, 0.1 part of 2,4,6- trimethylbenzoyl benzene
Base phosphonate ester, 0.1 part of hydrogen peroxide；
20 parts of cyclohexanone, 20 parts of toluene；
5 parts of ethylene glycol dimethacrylates, 1 part of poly- carbodiimide, 1 part of N,N methylene bis acrylamide；
Embodiment five
Coating material is chosen according to mass fraction:
10 parts of methacrylic acids, 2 parts of N hydroxymethyl acrylamides, 2 parts of N- isopropyl methyl acrylamides, 2 parts of acrylic acid
Ethyl ester, 2 parts of ethyl methacrylate, 2 parts of n-isopropyl acrylamide；
0.5 part of azo two (isobutyl amidine hydrochloride), 0.5 part of azo two (isopropylimdazole quinoline hydrochloride)；
20 parts of cyclohexanone, 20 parts of toluene；
5 parts of ethylene glycol dimethacrylates.
Embodiment six
Coating material is chosen according to mass fraction:
2 parts of acrylamides, 2 parts of n-isopropyl acrylamide, 2 parts of N hydroxymethyl acrylamides, 2 parts of N- isopropyl methyls third
Acrylamide, 2 parts of methyl acrylates, 2 parts of ethyl acrylates, 2 parts of n-butyl acrylates, 2 parts of methyl methacrylates, 2 parts of methyl
Ethyl acrylate, 2 parts of n-BMAs；
0.1 part of ammonium persulfate, 0.1 part of potassium peroxydisulfate, 0.1 part of hydrogen peroxide, 0.1 part of (isobutyl amidine hydrochloric acid of azo two
Salt), 0.1 part of azo two (isopropylimdazole quinoline hydrochloride), 0.1 part of 2- hydroxy-2-methyl -1- phenyl -1- acetone, 0.1 part two
Ethyoxyl amyl phenyl ketone, 0.1 part of 2,4,6- trimethylbenzoyl phenyl phosphonate ester, 0.1 part of 1- hydroxycyclohexylphenylketone；
5 parts of benzene, 5 parts of toluene, 5 parts of dimethylbenzene, 5 parts of acetone, 5 parts of cyclopropanones, 5 parts of cyclohexanone, 2 parts of toluene cyclohexanone, 2 parts
Dioxane, 2 parts of ethylene glycol, 2 parts of glycerine, 2 parts of styrene, 2 parts of ethyl acetate, 2 parts of glycol monoethyl ethers；
Crosslinking agent includes 2 parts of N,N methylene bis acrylamides, 2 parts of ethylene glycol dimethacrylates, 2 parts of epoxy silicon
Alkane, 2 parts of poly- carbodiimides；
Embodiment seven
Coating material is chosen according to mass fraction:
5 parts of acrylamides, 5 parts of n-isopropyl acrylamide, 5 parts of N hydroxymethyl acrylamides, 5 parts of methacrylic acid second
Ester；
0.5 part of azo two (isobutyl amidine hydrochloride), 0.1 part of azo two (isopropylimdazole quinoline hydrochloride), 0.1 part of 2- hydroxyl
Base-2- methyl-1-phenyl-1- acetone, 0.1 part of diethoxy amyl phenyl ketone, 0.1 part of 2,4,6- trimethylbenzoyl phenyl phosphonic acids
Ester；
5 parts of toluene, 5 parts of dimethylbenzene, 5 parts of acetone, 20 parts of cyclohexanone, 5 parts of dioxane, 2 parts of glycol monoethyl ethers；
2 parts of N,N methylene bis acrylamides, 2 parts of ethylene glycol dimethacrylates, 2 parts of poly- carbodiimides.
Embodiment eight
Coating material is chosen according to mass fraction:
10 parts of methacrylic acids, 5 parts of n-isopropyl acrylamide, 2 parts of methyl methacrylates, 3 parts of methacrylic acid second
Ester；
0.2 part of potassium peroxydisulfate, 0.2 part of hydrogen peroxide, 0.5 part of azo two (isobutyl amidine hydrochloride), 0.1 part of azo two
(isopropylimdazole quinoline hydrochloride)；
20 parts of cyclopropanones, 20 parts of styrene, 5 parts of glycol monoethyl ethers；
5 parts of ethylene glycol dimethacrylates, 1 part of epoxy silane.
Embodiment one realizes the part of 380~750nm wave band to ten gained colorful monolithic height index matching of embodiment
Reflection, can show that multiple color, product yield reach 85% or more, which has higher with after glass evacuated be bonded
Reflectivity, and surface high mechanical strength.
By above description it can be found that the preparation process of colorful material of the present invention, can directly substitute traditionally plated film work
Skill, it is only necessary to which it is the effect that can reach tens of layers of traditional plated film that macromolecule layer is coated on substrate, reduces equipment investment, technique letter
Single and yields is highly improved.Macromolecule layer utilizes the self assembly of different monomers structure, forms polymer network, realizes
The part reflection of 380~750nm wave band, can show multiple color, meet colorful demand.Have reflectivity higher and machinery
Intensity, it is nontoxic, it is suitable for popularization and application.
Technical solution of the present invention is fully described above, it should be noted that specific embodiment party of the invention
Formula is simultaneously not limited by the description set out above, the Spirit Essence of those skilled in the art according to the present invention structure, method or
All technical solutions that function etc. is formed using equivalents or equivalent transformation, all fall within protection scope of the present invention
Within.
Claims (10)
1. the preparation process of colorful material, it is characterised in that include the following steps:
S1 material prepares,
Coating material is chosen according to mass fraction:
20 parts of monomers,
0.5~1 part of initiator,
35~45 parts of solvents,
5~8 parts of crosslinking agents,
0~1 part of complexing agent, complexing agent include levelling agent, polymerization inhibitor, defoaming agent, diluent, ultraviolet absorbing agent, alignment agent, table
Any one or more combination in face activating agent, uv-curable glue and heat-curable glue,
Wherein, the monomer includes acrylic acid, methacrylic acid, acrylamide, n-isopropyl acrylamide, N- methylol propylene
Amide, N- isopropyl methyl acrylamide, methyl acrylate, ethyl acrylate, n-butyl acrylate, methyl methacrylate,
At least two combinations in ethyl methacrylate, n-BMA,
The initiator includes that ammonium persulfate, potassium peroxydisulfate, hydrogen peroxide, azo two (isobutyl amidine hydrochloride), azo two are (different
Propyl imidazole quinoline hydrochloride), 2- hydroxy-2-methyl -1- phenyl -1- acetone, diethoxy amyl phenyl ketone, 2,4,6- trimethylbenzene first
Any one or more combination in aminosulfonylphenyl phosphonate ester, 1- hydroxycyclohexylphenylketone,
The solvent include benzene,toluene,xylene, acetone, cyclopropanone, cyclohexanone, toluene cyclohexanone, dioxane, ethylene glycol,
Glycerine, styrene, ethyl acetate, any one or more combination in glycol monoethyl ether,
The crosslinking agent includes N,N methylene bis acrylamide, ethylene glycol dimethacrylate, epoxy silane, two Asia of poly- carbon
Any one or more combination in amine,
The above coating material is uniformly mixed obtained base fluid,
Substrate selection, chooses 20 μm~60 μm of heat molten type light-sensitive surface；
S2 coating operations,
Substrate is soaked, then base fluid is uniformly coated on substrate surface and forms substrate body；
S3 toasts operation,
Built-in smooth metal pedestal layer in an oven, substrate body is placed on metal pedestal layer, 70 DEG C of oven baking temperature
~90 DEG C, baking time 20s~40s, melting substrate is made；
S4 curing operation,
UV is carried out to melting substrate and solidifies obtained semi-finished product；
S5 hot pressing is cut,
Semi-finished product hot pressing body and is cut to finished product in the form of sheets.
2. the preparation process of colorful material according to claim 1, it is characterised in that:
In the step S1, coating material is chosen according to mass fraction:
15 parts of methacrylic acids, 5 parts of N hydroxymethyl acrylamides；
0.5 part of azo two (isobutyl amidine hydrochloride), 0.5 part of potassium peroxydisulfate；
20 parts of cyclohexanone, 20 parts of toluene；
5 parts of ethylene glycol dimethacrylates；
0.1 part of levelling agent, levelling agent are dimethyl silicone polymer.
3. the preparation process of colorful material according to claim 1, it is characterised in that:
In the step S1, coating material is chosen according to mass fraction:
10 parts of acrylic acid, 5 parts of N hydroxymethyl acrylamides, 5 parts of ethyl methacrylate；
0.5 part of azo two (isobutyl amidine hydrochloride), 0.5 part of ammonium persulfate；
20 parts of cyclohexanone, 10 parts of cyclohexanone, 15 parts of dimethylbenzene；
4 parts of ethylene glycol dimethacrylates, 3 parts of N,N methylene bis acrylamides；
0.1 part of levelling agent, levelling agent are dimethyl silicone polymer.
4. the preparation process of colorful material according to claim 1, it is characterised in that:
In the step S1, coating material is chosen according to mass fraction:
5 parts of methacrylic acids, 5 parts of acrylic acid, 5 parts of N- isopropyl methyl acrylamides, 5 parts of N hydroxymethyl acrylamides；
0.3 part of azo two (isobutyl amidine hydrochloride), 0.2 part of potassium peroxydisulfate, 0.3 part of diethoxy amyl phenyl ketone；
20 parts of cyclohexanone, 25 parts of toluene；
5 parts of ethylene glycol dimethacrylates.
5. the preparation process of colorful material according to claim 1, it is characterised in that:
In the step S1, coating material is chosen according to mass fraction:
5 parts of acrylic acid, 5 parts of N hydroxymethyl acrylamides, 5 parts of n-butyl acrylates, 5 parts of n-BMAs；
0.5 part of azo two (isobutyl amidine hydrochloride), 0.1 part of potassium peroxydisulfate, 0.1 part of 2,4,6- trimethylbenzoyl phenyl phosphine
Acid esters, 0.1 part of hydrogen peroxide；
20 parts of cyclohexanone, 20 parts of toluene；
5 parts of ethylene glycol dimethacrylates, 1 part of poly- carbodiimide, 1 part of N,N methylene bis acrylamide.
6. the preparation process of colorful material according to claim 1, it is characterised in that:
In the step S1, coating material is chosen according to mass fraction:
10 parts of methacrylic acids, 2 parts of N hydroxymethyl acrylamides, 2 parts of N- isopropyl methyl acrylamides, 2 parts of ethyl acrylates,
2 parts of ethyl methacrylate, 2 parts of n-isopropyl acrylamide；
0.5 part of azo two (isobutyl amidine hydrochloride), 0.5 part of azo two (isopropylimdazole quinoline hydrochloride)；
20 parts of cyclohexanone, 20 parts of toluene；
5 parts of ethylene glycol dimethacrylates.
7. the preparation process of colorful material according to claim 1, it is characterised in that:
In the step S1,50 μm of PET black film is chosen.
8. the preparation process of colorful material according to claim 1, it is characterised in that:
In the step S2, OSP10# bar is selected to soak substrate, wetting gap is 10 μm.
9. the preparation process of colorful material according to claim 1, it is characterised in that:
In the step S4, melting substrate passes through 40mj/cm2-800mj/cm2UV curing 30s.
10. the finished product that the method based on claim 1 to 9 any one is prepared is compounded in glass by coating hot-melt adhesive
The application of matrix surface.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113414081A (en) * | 2021-08-24 | 2021-09-21 | 苏州奥美材料科技有限公司 | Coating composition of colorful material, colorful material and preparation method of colorful material |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103044615A (en) * | 2013-01-17 | 2013-04-17 | 焦作瑞福莱反光材料有限公司 | Hydroxy acrylic resin for reflective film and preparation method thereof |
| US20150185373A1 (en) * | 2013-12-27 | 2015-07-02 | Hon Hai Precision Industry Co., Ltd. | Light reflective film and method for manufacturing the same |
| CN109206648A (en) * | 2018-04-20 | 2019-01-15 | 苏州科技大学 | A kind of reflection-type colorful film |
-
2019
- 2019-05-30 CN CN201910464176.5A patent/CN110105609A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103044615A (en) * | 2013-01-17 | 2013-04-17 | 焦作瑞福莱反光材料有限公司 | Hydroxy acrylic resin for reflective film and preparation method thereof |
| US20150185373A1 (en) * | 2013-12-27 | 2015-07-02 | Hon Hai Precision Industry Co., Ltd. | Light reflective film and method for manufacturing the same |
| CN109206648A (en) * | 2018-04-20 | 2019-01-15 | 苏州科技大学 | A kind of reflection-type colorful film |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113414081A (en) * | 2021-08-24 | 2021-09-21 | 苏州奥美材料科技有限公司 | Coating composition of colorful material, colorful material and preparation method of colorful material |
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