CN110093215A - A kind of boric acid crystallization remover and its application - Google Patents
A kind of boric acid crystallization remover and its application Download PDFInfo
- Publication number
- CN110093215A CN110093215A CN201810083755.0A CN201810083755A CN110093215A CN 110093215 A CN110093215 A CN 110093215A CN 201810083755 A CN201810083755 A CN 201810083755A CN 110093215 A CN110093215 A CN 110093215A
- Authority
- CN
- China
- Prior art keywords
- boric acid
- remover
- crystallization
- crystallizes
- acid crystallization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 title claims abstract description 90
- 239000004327 boric acid Substances 0.000 title claims abstract description 89
- 238000002425 crystallisation Methods 0.000 title claims abstract description 62
- 230000008025 crystallization Effects 0.000 title claims abstract description 62
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 33
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 21
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 21
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 6
- 239000006260 foam Substances 0.000 claims description 7
- 239000003595 mist Substances 0.000 claims description 6
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 5
- 229910052796 boron Inorganic materials 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 239000013078 crystal Substances 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 3
- 238000002347 injection Methods 0.000 claims description 3
- 239000007924 injection Substances 0.000 claims description 3
- 230000003213 activating effect Effects 0.000 claims description 2
- 150000001450 anions Chemical class 0.000 claims description 2
- 125000000129 anionic group Chemical group 0.000 claims 1
- 238000005516 engineering process Methods 0.000 abstract description 5
- 238000005202 decontamination Methods 0.000 abstract description 3
- 230000003588 decontaminative effect Effects 0.000 abstract description 3
- 238000004090 dissolution Methods 0.000 abstract description 3
- 238000000034 method Methods 0.000 description 5
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- XLYOFNOQVPJJNP-ZSJDYOACSA-N Heavy water Chemical compound [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 206010053615 Thermal burn Diseases 0.000 description 1
- YAWNFGAHEUCLNJ-UHFFFAOYSA-N [B].OB(O)O Chemical compound [B].OB(O)O YAWNFGAHEUCLNJ-UHFFFAOYSA-N 0.000 description 1
- 239000011358 absorbing material Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
- -1 halide ion Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000941 radioactive substance Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/02—Cleaning by the force of jets or sprays
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0043—For use with aerosol devices
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21D—NUCLEAR POWER PLANT
- G21D1/00—Details of nuclear power plant
- G21D1/003—Nuclear facilities decommissioning arrangements
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/20—Industrial or commercial equipment, e.g. reactors, tubes or engines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/24—Mineral surfaces, e.g. stones, frescoes, plasters, walls or concretes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/40—Specific cleaning or washing processes
- C11D2111/44—Multi-step processes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E30/00—Energy generation of nuclear origin
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Emergency Medicine (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Plasma & Fusion (AREA)
- General Engineering & Computer Science (AREA)
- High Energy & Nuclear Physics (AREA)
- Removal Of Specific Substances (AREA)
Abstract
The invention belongs to industrial decontamination technology field, it is related to a kind of boric acid crystallization remover and its application.The boric acid crystallization remover includes water, sodium hydroxide, glycerol and anionic surfactant.The application is that the boric acid crystallization remover is applied the removal that boric acid crystallizes in light water reactor.Crystallize remover using boric acid of the invention, not only can at normal temperature quickly, the crystallization of high-efficiency dissolution boric acid, but also be applicable to various complex environments, and be particularly suitable for the removal that boric acid crystallizes in light water reactor.
Description
Technical field
The invention belongs to industrial decontamination technology field, it is related to a kind of boric acid crystallization remover and its application.
Background technique
With flourishing for China's Nuclear Electricity, by the end of the year 2016, China has operation nuclear power unit 36, and arrives
The year two thousand twenty, it is contemplated that China's nuclear power unit quantity is up to more than 60 platforms, will be more than France from installed capacity, becomes the world the
Two nuclear power big country, is only second to the U.S..Currently, the nuclear power unit in China removes two of Qinshan third nuclear power plant as heavy water reactor
Outside, remaining is light-water reactor.
Boric acid plays the role of reactive control and neutron shield, is widely used in light water reactor as neutron-absorbing material
One loop of nuclear power station system.In the operation of light water reactor, caused due to equipment and conduit running and maintenance boric acid or
The different degrees of leakage of boron water, the solubility with temperature of boric acid in water changes greatly, with variation of ambient temperature and moisture
Evaporation, it is white crystals that boric acid, which carries radioactive substance and is precipitated, and certain dirt is formed in ground, wall, pipeline and equipment surface
Stain.
By the hydrochemical analyse to primary Ioops, the ingredient of boric acid crystallization is boric acid solid (H3BO3) and diboron trioxide water
Close object (B2O3·3H2O).Since the solvability under boric acid room temperature in water or strong base solution is limited, with common minimizing technology
It is difficult to effectively remove it.Therefore, a great problem for being treated as light water reactor decontamination of boric acid crystallization spot.
The minimizing technology of the existing boric acid crystallization spot of China's nuclear power station is usual are as follows: is poured using the demineralized water for being heated to boiling
Boric acid crystallization is drenched, makes the fracture of boric acid intermolecular part hydrogen bond and increases its solubility in water, while by its fast transfer
To reach certain clean effect.Though the method is simple, economical, there are elapsed times, and long, processing is not thorough, can apply model
Enclose the problems such as small and high temperature demineralized water easily scalds staff.
Summary of the invention
Primary and foremost purpose of the invention is to provide a kind of boric acid crystallization remover, with not only can at normal temperature quickly, efficiently
Boric acid crystallization is dissolved, and is applicable to various complex environments.
In order to achieve this, the present invention provides a kind of boric acid crystallization remover, the boron in the embodiment on basis
Acid crystal remover includes water, sodium hydroxide, glycerol and anionic surfactant.
In a preferred embodiment, the present invention provides a kind of boric acid crystallization remover, wherein the boric acid knot
Brilliant remover be aqueous solution, comprising mass percent concentration be 1-10% sodium hydroxide, the glycerol of 1-10%, 0.1-1%'s
Anionic surfactant.
In a preferred embodiment, the present invention provides a kind of boric acid crystallization remover, wherein the boric acid knot
Brilliant remover is aqueous solution, the sodium hydroxide for being 5% comprising mass percent concentration, 5% glycerol, 0.1% anion table
Face activating agent.
In a preferred embodiment, the present invention provides a kind of boric acid crystallization remover, wherein the water is core
The dedicated demineralized water in power station.
In a preferred embodiment, the present invention provides a kind of boric acid crystallization remover, wherein the anion
Surfactant is neopelex.
A second object of the present invention is to provide a kind of applications of boric acid crystallization remover, efficiently to remove light water reactor nuclear power
The boric acid crystallization generated in standing.
In order to achieve this, the present invention provides a kind of boric acid crystallization removal as described above in the embodiment on basis
Agent removes the application of boric acid crystallization in light water reactor.
In a preferred embodiment, the present invention provides boric acid crystallization remover as described above in light water reactor nuclear power
The application of boric acid crystallization is removed in standing, wherein spraying the boric acid crystallization remover in the form of mist or foam in light-water
Reactor of nuclear power plant boric acid crystallizes stained surface, while guaranteeing that boric acid crystallization is completely covered in the boric acid crystallization remover.
In a preferred embodiment, the present invention provides boric acid crystallization remover as described above in light water reactor nuclear power
The application of boric acid crystallization is removed in standing, wherein injection is in light after the boric acid crystallization remover is packed into the pressurization watering can of inflation
Water-water reactor nuclear power station boric acid crystallizes stained surface.
The application method of boric acid crystallization remover of the invention is: (1) using the pressurization watering can that can be inflated；(2) it sprays
After pot pressurization, boric acid crystallization remover is sprayed in the form of mist or foam and crystallizes stained surface in boric acid, while guaranteeing boron
Boric acid crystallization is completely covered in acid crystal remover；(3) boron crystallization has been dissolved with the erasing of common dirt removing cloth after reacting 1-10 minutes
Boric acid crystallizes remover, repeats aforesaid operations when necessary or with the secondary wiping of demineralized water.
The beneficial effects of the present invention are, not only can be normal using boric acid crystallization remover of the invention and its application
The lower boric acid crystallization quickly, in high-efficiency dissolution light water reactor of temperature, and it is applicable to various complex environments.Component in remover
It is clear, without to the harmful halide ion of nuclear power system；Remover, can be safe and applicable in various metals and material table in alkalinity
Face；Remover greatly reduces waste liquid yield with atomized soln or form of foam application.
The features of the present invention and effect are embodied in:
1, it quickly, efficiently can remove boron at normal temperature and crystallize spot；
2, the boric acid that remover is suitable for all related facilities of light water reactor, equipment and pipeline crystallizes removal；
3, since remover ingredient is relatively easy, reduce the introducing of impurity and harmful element；
4, remover is formed by mist and foam by using pressurization watering can, had not only reduced the usage amount of remover, but also energy
It is completely covered and contains boric acid crystallization, and then improve boric acid and crystallize removal efficiency；
5, boric acid crystallization removal simple process and low cost, secondary waste are easily handled, and meet sustainable development requirement,
With good practical value and wide application prospect.
Specific embodiment
A specific embodiment of the invention is further illustrated with reference to embodiments.
Embodiment 1: the preparation of different formulations boric acid crystallization remover
Remover is crystallized by the boric acid that such as the following table 1 prepares different formulations.
The formula of 1 boric acid of table crystallization remover
Embodiment 2: boric acid crystallizes the boric acid crystallization trial in remover removal light water reactor
The boric acid being respectively formulated in table 1 crystallization remover is used for the removal of the crystallization of the boric acid in light water reactor, method
It is as follows:
(1) by prepared boric acid crystallization remover pour into pressurization watering can in, volume should be less than watering can volume three/
Two and be greater than one third；
(2) pressurizing device above Manual press watering can is allowed to inflate into watering can, and watering can spray is adjusted after the completion of pressurization
Mouth, control spray the partial size of solution, guarantee that the boric acid sprayed crystallization remover can form mist or foam；
(3) it is uniformly sprayed with the stained region that watering can alignment has boric acid to crystallize, makes boric acid crystallization remover mist or foam
It is completely covered and contains boric acid crystallization；
(4) the removal liquid of boric acid crystallization has been dissolved in reaction with the erasing of common dirt removing cloth after five minutes.
Efficiency (the boric acid crystallization removal as shown in table 2 below for the boric acid crystallization remover removal boric acid crystallization of table 1 being respectively formulated
1 gram of boric acid crystallization/required remover volume milliliter of efficiency=dissolution, the bigger solute effect of the value of removal efficiency are better).
The efficiency of the boric acid crystallization remover removal boric acid crystallization of 2 different formulations of table
| Formula number | Boric acid crystallizes removal efficiency |
| 1 | 0.0667 |
| 2 | 0.1667 |
| 3 | 0.2857 |
| 4 | 0.125 |
| 5 | 0.1 |
Obviously, various changes and modifications can be made to the invention without departing from essence of the invention by those skilled in the art
Mind and range.If in this way, belonging to the model of the claims in the present invention and its equivalent technology to these modifications and changes of the present invention
Within enclosing, then the present invention is also intended to include these modifications and variations.Above-described embodiment or embodiment are only to the present invention
For example, the present invention can also be implemented with other ad hoc fashions or other particular form, without departing from of the invention
Main idea or substantive characteristics.Therefore, the embodiment of description is regarded as illustrative and non-limiting in any way.This
The range of invention should be illustrated that any variation equivalent with the intention and range of claim also should include by appended claims
Within the scope of the invention.
Claims (8)
1. a kind of boric acid crystallizes remover, it is characterised in that: the boric acid crystallization remover includes water, sodium hydroxide, glycerol
And anionic surfactant.
2. boric acid according to claim 1 crystallizes remover, it is characterised in that: the boric acid crystallization remover is water-soluble
Liquid, the sodium hydroxide for being 1-10% comprising mass percent concentration, the glycerol of 1-10%, the anion surface active of 0.1-1%
Agent.
3. boric acid according to claim 1 crystallizes remover, it is characterised in that: the boric acid crystallization remover is water-soluble
Liquid, the sodium hydroxide for being 5% comprising mass percent concentration, 5% glycerol, 0.1% anionic surfactant.
4. boric acid according to claim 1 to 3 crystallizes remover, it is characterised in that: the water is nuclear power station
Dedicated demineralized water.
5. boric acid according to claim 1 to 3 crystallizes remover, it is characterised in that: the anionic surface
Activating agent is neopelex.
6. the crystallization of boric acid described in -5 any one remover removes boric acid crystallization in light water reactor according to claim 1
Application.
7. application according to claim 6, it is characterised in that: by the described boric acid crystallization remover with mist or foam
Form injection crystallizes stained surface in light water reactor boric acid, while guaranteeing that boron is completely covered in the boric acid crystallization remover
Acid crystal.
8. application according to claim 6 or 7, it is characterised in that: the boric acid crystallization remover is packed into inflation
Injection crystallizes stained surface in light water reactor boric acid after pressurization watering can.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810083755.0A CN110093215A (en) | 2018-01-29 | 2018-01-29 | A kind of boric acid crystallization remover and its application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810083755.0A CN110093215A (en) | 2018-01-29 | 2018-01-29 | A kind of boric acid crystallization remover and its application |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110093215A true CN110093215A (en) | 2019-08-06 |
Family
ID=67442517
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810083755.0A Pending CN110093215A (en) | 2018-01-29 | 2018-01-29 | A kind of boric acid crystallization remover and its application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110093215A (en) |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3948888A (en) * | 1973-01-13 | 1976-04-06 | Bayer Aktiengesellschaft | Process for removing boric acid from lactams |
| CN1066876A (en) * | 1991-05-14 | 1992-12-09 | 权力敏 | Disinfecting cleaning cream and preparation method thereof |
| CN1390922A (en) * | 2001-06-08 | 2003-01-15 | 黄丁义 | Detergent |
| CN1788072A (en) * | 2003-05-19 | 2006-06-14 | 约翰逊迪瓦西公司 | High caustic foaming contact cleaner |
| CN103131565A (en) * | 2011-11-30 | 2013-06-05 | 李音 | Efficient decontamination cleaning agent |
| CN103937628A (en) * | 2014-05-12 | 2014-07-23 | 苏州禾川化学技术服务有限公司 | High-alkalinity non-foaming spraying cleaning agent |
| CN104916340B (en) * | 2014-03-12 | 2018-02-13 | 江苏核电有限公司 | A kind of end of term in nuclear power station longevity reactivity control method |
-
2018
- 2018-01-29 CN CN201810083755.0A patent/CN110093215A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3948888A (en) * | 1973-01-13 | 1976-04-06 | Bayer Aktiengesellschaft | Process for removing boric acid from lactams |
| CN1066876A (en) * | 1991-05-14 | 1992-12-09 | 权力敏 | Disinfecting cleaning cream and preparation method thereof |
| CN1390922A (en) * | 2001-06-08 | 2003-01-15 | 黄丁义 | Detergent |
| CN1788072A (en) * | 2003-05-19 | 2006-06-14 | 约翰逊迪瓦西公司 | High caustic foaming contact cleaner |
| CN103131565A (en) * | 2011-11-30 | 2013-06-05 | 李音 | Efficient decontamination cleaning agent |
| CN104916340B (en) * | 2014-03-12 | 2018-02-13 | 江苏核电有限公司 | A kind of end of term in nuclear power station longevity reactivity control method |
| CN103937628A (en) * | 2014-05-12 | 2014-07-23 | 苏州禾川化学技术服务有限公司 | High-alkalinity non-foaming spraying cleaning agent |
Non-Patent Citations (2)
| Title |
|---|
| 吉效科、王飞、王昊楠: "《设备质量控制概论》", 31 December 2017, 西安：陕西科学技术出版社 * |
| 夏延龄: "《核电厂核蒸汽供应系统概述》", 30 September 2010, 北京：原子能出版社 * |
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