CN110093076A - A kind of ordor removing degerming aqueous latex paint and preparation method thereof - Google Patents
A kind of ordor removing degerming aqueous latex paint and preparation method thereof Download PDFInfo
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- CN110093076A CN110093076A CN201910362520.XA CN201910362520A CN110093076A CN 110093076 A CN110093076 A CN 110093076A CN 201910362520 A CN201910362520 A CN 201910362520A CN 110093076 A CN110093076 A CN 110093076A
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- latex paint
- aqueous latex
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
- C09D5/025—Preservatives, e.g. antimicrobial agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/387—Borates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of ordor removing degerming aqueous latex paint, the raw material including following parts by weight: 28-35 parts of lotion, 20-30 parts of titanium dioxide, 25-28 parts of packing agent, 10-13 parts of six ring stone, 0.5-1.2 parts of sodium humate, 0.5-1.0 parts of activator, 5-8 parts of oxidant, 3-5 parts of buffer, 0.2-0.5 parts of surfactant and 90-105 parts of water.Ordor removing degerming aqueous latex paint provided by the invention is suitable for various Environment spaces, has achieved the effect that ordor removing, degerming by the interaction between the far infrared and substance of itself release, and brush functional.
Description
Technical field
The present invention relates to technical field of coatings, more particularly to a kind of ordor removing degerming aqueous latex paint and its preparation
Method.
Background technique
With the continuous development of continuous improvement of people's living standards and aqueous latex paint technology, indoor environment is to people's
Health is particularly important, and the environment of especially public place has been to be concerned by more and more people, such as hospital, school, hotel
The strong and intensive place of equal populations fluidity, needs periodically to carry out disinfection to interior, reduces the growth of bacterium, to guarantee public
The pure and fresh degree of place air.
Internal wall emulsion coating is the important revolution product in modern age interior decoration field, the convenient, color with surface construction
Selection is abundant, smooth surface and it is easy to maintain the advantages that, dominate in inner wall decoration at home, the market share is more than
80%, but internal wall emulsion coating can only largely play decoration, beautification wall to building, do not have ordor removing and degerming, resist
The effects of bacterium.
Common Antibacterial Waterborne Emulsion Paint generally uses the compound of organic antibacterial agent CMIT/MIT/ organic bromine currently on the market
Object or inorganic silver ion antimicrobial agent, but organic antibacterial agent is sensitive to pH, additive amount is big, and toxicity is relatively large, to people and animals
Irritant, inorganic antiseptic price is high, and activity is low, and the requirement to environment is more harsh.
Therefore, a kind of environment-friendly type how is provided, aqueous latex paint at low cost and being capable of ordor removing degerming is this field skill
The problem of art personnel's urgent need to resolve.
Summary of the invention
In view of this, the present invention provides the aqueous latex paints and preparation method thereof that one kind is capable of ordor removing degerming.
In order to achieve the above object, the present invention adopts the following technical scheme:
A kind of ordor removing degerming aqueous latex paint, the raw material including following parts by weight: 28-35 parts of lotion, is filled out 20-30 parts of titanium dioxide
Agent 25-28 parts of material, 10-13 parts of six ring stone, 0.5-1.2 parts of sodium humate, 0.5-1.0 parts of activator, 5-8 parts of oxidant, buffering
3-5 parts of agent, 0.2-0.5 parts of surfactant and 90-105 parts of water.
It preferably, further include 5-9 parts of tourmaline and corrosion inhibiter 0.02- in a kind of above-mentioned ordor removing degerming aqueous latex paint
0.08 part.
The beneficial effect of above-mentioned technical proposal is: tourmaline and six ring stones act synergistically, and can enhance aqueous latex paint
Antibiotic and sterilizing effect, and the addition of corrosion inhibiter can slow down external substance to the corrosiveness of emulsion paint coat.
Preferably, in a kind of above-mentioned ordor removing degerming aqueous latex paint, the lotion is by acrylate copolymer emulsion and pure
The weight ratio of acrylic emulsion composition, the acrylate copolymer emulsion and the pure-acrylic emulsion is 1:2-2.5.
The beneficial effect of above-mentioned technical proposal is: acrylate copolymer emulsion and pure-acrylic emulsion are aqueous in conjunction with being prepared
Weatherability, corrosion resistance and the ageing resistance of emulsion paint are remarkably reinforced, and it is not easy to crack, fall off, service life increase.
Preferably, in a kind of above-mentioned ordor removing degerming aqueous latex paint, the activator is selected from acetylsalicylic acid, four acetyl
Ethylenediamine, four acetyl glycolurils, four acetyl aldopentoses, any one or a few the mixture in pelargonyl group benzene sulfonic acid sodium salt.
The beneficial effect of above-mentioned technical proposal is: the activator uses the compound containing amide structure or ester structure,
At room temperature the peroxy acid that can kill microorganism can be generated by react with oxidant.
Preferably, in a kind of above-mentioned ordor removing degerming aqueous latex paint, the oxidant be selected from carbonate, perborate,
Perphosphate, persilicate, any one or several mixtures in carbamide peroxide.
The beneficial effect of above-mentioned technical proposal is: the hydrogen peroxide of the oxidant release can be to bacterium, fungi and disease
Poison is effectively inhibited.
Preferably, in a kind of above-mentioned ordor removing degerming aqueous latex paint, the buffer is selected from tartaric acid, malic acid, lemon
Lemon acid, benzoic acid, salicylic acid, sulfamic acid, any one or several mixtures in phthalic acid.
The beneficial effect of above-mentioned technical proposal is: for adjusting pH, the peroxy acid stably generated drops the buffer simultaneously
The low extraneous corrosivity to interior wall.
Preferably, in a kind of above-mentioned ordor removing degerming aqueous latex paint, the surfactant is selected from linear alkylbenzene (LAB) sulphur
Sour sodium, sodium secondary alkyl sulfonate, sodium alkyl sulfate, sodium dioctyl sulfosuccinate, sulfosuccinic acid list lauryl disodium, fatty acid
Methanesulfonic sodium, polyoxyethylene lauryl ether phosphate ester salt, sodium POE nonylphenol ether sodiosulfosuccinate, polyoxy
Ethylene laurel ether, hydroxypropyl glycine betaine, N- lauroyl glutamate salt, any one in coco-nut oil fatty acid monoethanolamine
Or several mixture.
The beneficial effect of above-mentioned technical proposal is: the surfactant can enhance the killing energy to bacterium, fungi etc.
Power enhances bacteria-eliminating efficacy.
The invention also discloses a kind of preparation methods of ordor removing degerming aqueous latex paint, comprising the following steps:
(1) lotion, sodium humate are uniformly mixed, are stirred 15-20 minutes under conditions of 500-600rmp/min, it is spare；
(2) packing agent, six ring stones and tourmaline are put into sand mill and are ground 1-1.5 hours, obtain the powder of 500-700 mesh,
Then remaining component in addition to titanium dioxide is added, is stirred 30-40 minutes under conditions of 800-900rmp/min；
(3) titanium dioxide is added after mixing the material of step (1) with the material of step (2), is dispersed with stirring uniformly to obtain the final product.
It can be seen via above technical scheme that compared with prior art, the present disclosure provides a kind of ordor removing degerming water
Property emulsion paint, make full use of the natural energies stones such as six ring stones and tourmaline, realize aqueous latex paint radiation negative oxygen ion and remote
The function of infrared ray can improve the various harmful substances of bring and pernicious gas in building and fitment process, largely
On eliminate the microorganisms such as peculiar smell, mushroom caused by fixed field, improve people's lives environment；
Activating agent, oxidant etc. can equally play sterilization, antibacterial, antibacterial effect in the present invention, assist with six ring stones, tourmaline
Same-action further enhances the deodorization antibiotic performance of aqueous latex paint；
The present invention can with adjusting air humidity, purification air, and whole preparation process is simple, nontoxic and pollution-free, raw material at
This is low, and obtained aqueous latex paint paint film is water-fast, coating is fine and smooth plentiful, and scrub resistance is good, has sustainability in effect.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical scheme in the embodiment of the invention is clearly and completely described,
Obviously, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based in the present invention
Embodiment, every other embodiment obtained by those of ordinary skill in the art without making creative efforts, all
Belong to the scope of protection of the invention.
The invention discloses a kind of ordor removing degerming aqueous latex paint, the raw material including following parts by weight: 28-35 parts of lotion,
20-30 parts of titanium dioxide, 25-28 parts of packing agent, 10-13 parts of six ring stone, 0.5-1.2 parts of sodium humate, 0.5-1.0 parts of activator,
5-8 parts of oxidant, 3-5 parts of buffer, 0.2-0.5 parts of surfactant and 90-105 parts of water.
In order to further optimize the above technical scheme, the aqueous latex paint further includes 5-9 parts of tourmaline and corrosion inhibiter
0.02-0.08 parts.
In order to further optimize the above technical scheme, the lotion is made of acrylate copolymer emulsion and pure-acrylic emulsion,
The weight ratio of the acrylate copolymer emulsion and the pure-acrylic emulsion is 1:2-2.5.
In order to further optimize the above technical scheme, the activator is selected from acetylsalicylic acid, tetraacetyl ethylene diamine, tetrem
Acyl glycoluril, four acetyl aldopentoses, any one or a few the mixture in pelargonyl group benzene sulfonic acid sodium salt.
In order to further optimize the above technical scheme, the oxidant is selected from carbonate, perborate, perphosphate, mistake
Any one in silicate, carbamide peroxide or several mixtures.
In order to further optimize the above technical scheme, the buffer be selected from tartaric acid, malic acid, citric acid, benzoic acid,
Salicylic acid, sulfamic acid, any one or several mixtures in phthalic acid.
In order to further optimize the above technical scheme, the surfactant is selected from sodium n-alkylbenzenesulfonate, secondary alkyl
Sodium sulfonate, sodium dioctyl sulfosuccinate, sulfosuccinic acid list lauryl disodium, fatty acid methyl sodium sulfonate, gathers sodium alkyl sulfate
Ethylene oxide dodecyl ether phosphate salt, sodium POE nonylphenol ether sodiosulfosuccinate, polyoxyethylene laurel ether,
Hydroxypropyl glycine betaine, N- lauroyl glutamate salt, in coco-nut oil fatty acid monoethanolamine any one or it is several mixed
Close object.
In order to further optimize the above technical scheme, the packing agent is in kaolin, active coarse whiting and diatomite
Any one or several mixtures.
The invention also discloses a kind of preparation methods of ordor removing degerming aqueous latex paint, comprising the following steps:
(1) lotion, sodium humate are uniformly mixed, are stirred 15-20 minutes under conditions of 500-600rmp/min, it is spare；
(2) packing agent, six ring stones and tourmaline are put into sand mill and are ground 1-1.5 hours, obtain the powder of 500-700 mesh,
Then remaining component in addition to titanium dioxide is added, is stirred 30-40 minutes under conditions of 800-900rmp/min；
(3) titanium dioxide is added after mixing the material of step (1) with the material of step (2), is dispersed with stirring uniformly to obtain the final product.
The present invention passes through the additive amount for changing various raw material components, in conjunction with the preparation side of above-mentioned technical proposal aqueous latex paint
Method obtains embodiment 1-5 as shown in Table 1:
1 embodiment 1-5 of table
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | |
| Acrylate copolymer emulsion | 10 | 8 | 9 | 11 | 10.7 |
| Pure-acrylic emulsion | 22 | 20 | 19.8 | 23.1 | 23.54 |
| Titanium dioxide | 20 | 25 | 28 | 24 | 30 |
| Packing agent | 25 | 24 | 28 | 26 | 27 |
| Six ring stones | 10 | 12 | 11 | 13 | 12.5 |
| Tourmaline | - | 5 | 8 | 9 | - |
| Sodium humate | 0.5 | 0.8 | 1.2 | 1.2 | 0.7 |
| Activator | 0.5 | 1.0 | 0.7 | 0.9 | 0.6 |
| Oxidant | 5 | 5.8 | 6 | 7 | 8 |
| Buffer | 3 | 3.5 | 4 | 5 | 4.6 |
| Surfactant | 0.2 | 0.3 | 0.5 | 0.28 | 0.45 |
| Corrosion inhibiter | 0.02 | - | 0.06 | 0.08 | 0.05 |
| Water | 90 | 98 | 101 | 105 | 93 |
The generic latex paint that the present invention buys ordor removing degerming aqueous latex paint made of embodiment 1-5 and market carries out quality
Technology measurement, measurement at film outward appearance, drying time, state, application property and low-temperature stability result referring to table 2:
The measurement of 2 emulsion paint presentation quality of table
As shown in Table 1, ordor removing degerming aqueous latex paint provided by the invention has good at film outward appearance, state and application property,
And drying time is no more than one day, presentation quality is stablized.
The generic latex paint that the present invention buys ordor removing degerming aqueous latex paint made of embodiment 1-5 and market carries out matter
The measurement of amount technology, content of volatile organic compound, benezene material, free formaldehyde, soluble heavy metal and the antibiotic property of measurement
Can, testing result is referring to table 3:
The measurement of 3 emulsion paint harmful components of table
Volatile organic compounds, benezene material and soluble heavy metal etc. in ordor removing degerming aqueous latex paint provided by the invention
Content is well below national standard, and strong antibacterial, much due to existing emulsion paint on the market.
Each embodiment in this specification is described in a progressive manner, the highlights of each of the examples are with other
The difference of embodiment, the same or similar parts in each embodiment may refer to each other.For device disclosed in embodiment
For, since it is corresponded to the methods disclosed in the examples, so being described relatively simple, related place is said referring to method part
It is bright.
The foregoing description of the disclosed embodiments enables those skilled in the art to implement or use the present invention.
Various modifications to these embodiments will be readily apparent to those skilled in the art, as defined herein
General Principle can be realized in other embodiments without departing from the spirit or scope of the present invention.Therefore, of the invention
It is not intended to be limited to the embodiments shown herein, and is to fit to and the principles and novel features disclosed herein phase one
The widest scope of cause.
Claims (8)
1. a kind of ordor removing degerming aqueous latex paint, which is characterized in that the raw material including following parts by weight: 28-35 parts of lotion, titanium white
20-30 parts of powder, 25-28 parts of packing agent, 10-13 parts of six ring stone, 0.5-1.2 parts of sodium humate, 0.5-1.0 parts of activator, oxidation
5-8 parts of agent, 3-5 parts of buffer, 0.2-0.5 parts of surfactant and 90-105 parts of water.
2. a kind of ordor removing degerming aqueous latex paint according to claim 1, which is characterized in that further include 5-9 parts of tourmaline
With 0.02-0.08 parts of corrosion inhibiter.
3. a kind of ordor removing degerming aqueous latex paint according to claim 1, which is characterized in that the lotion is by acrylate
The weight ratio of copolymer emulsion and pure-acrylic emulsion composition, the acrylate copolymer emulsion and the pure-acrylic emulsion is 1:2-2.5.
4. a kind of ordor removing degerming aqueous latex paint according to claim 1, which is characterized in that the activator is selected from acetyl
Salicylic acid, tetraacetyl ethylene diamine, four acetyl glycolurils, four acetyl aldopentoses, any one or a few in pelargonyl group benzene sulfonic acid sodium salt
Mixture.
5. a kind of ordor removing degerming aqueous latex paint according to claim 1, which is characterized in that the oxidant is selected from carbonic acid
Salt, perborate, perphosphate, persilicate, any one or several mixtures in carbamide peroxide.
6. a kind of ordor removing degerming aqueous latex paint according to claim 1, which is characterized in that the buffer is selected from winestone
Acid, malic acid, citric acid, benzoic acid, salicylic acid, sulfamic acid, any one or several mixing in phthalic acid
Object.
7. a kind of ordor removing degerming aqueous latex paint according to claim 1, which is characterized in that the surfactant is selected from
Sodium n-alkylbenzenesulfonate, sodium secondary alkyl sulfonate, sodium alkyl sulfate, sodium dioctyl sulfosuccinate, sulfosuccinic acid list laurel
Ester disodium, fatty acid methyl sodium sulfonate, polyoxyethylene lauryl ether phosphate ester salt, nonylphenol polyoxyethylene ether sulfosuccinic acid list
Ester disodium salt, polyoxyethylene laurel ether, hydroxypropyl glycine betaine, N- lauroyl glutamate salt, coco-nut oil fatty acid monoethanolamine
In any one or several mixtures.
8. a kind of a kind of preparation method of ordor removing degerming aqueous latex paint according to claim 1-7, feature
It is, comprising the following steps:
(1) lotion, sodium humate are uniformly mixed, are stirred 15-20 minutes under conditions of 500-600rmp/min, it is spare；
(2) packing agent, six ring stones and tourmaline are put into sand mill and are ground 1-1.5 hours, obtain the powder of 500-700 mesh,
Then remaining component in addition to titanium dioxide is added, is stirred 30-40 minutes under conditions of 800-900rmp/min；
(3) titanium dioxide is added after mixing the material of step (1) with the material of step (2), is dispersed with stirring uniformly to obtain the final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201910362520.XA CN110093076A (en) | 2019-04-30 | 2019-04-30 | A kind of ordor removing degerming aqueous latex paint and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910362520.XA CN110093076A (en) | 2019-04-30 | 2019-04-30 | A kind of ordor removing degerming aqueous latex paint and preparation method thereof |
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| CN110093076A true CN110093076A (en) | 2019-08-06 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112646438A (en) * | 2020-12-16 | 2021-04-13 | 彭龙水 | Negative ion antibacterial coating and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| WO2008120922A1 (en) * | 2007-04-02 | 2008-10-09 | Pusan National University Industry-University Cooperation Foundation | Antifouling paint composition |
| CN101457057A (en) * | 2007-12-13 | 2009-06-17 | 靳彦涛 | Multifunctional novel inner wall paint |
| CN104621180A (en) * | 2015-02-02 | 2015-05-20 | 山东威高药业股份有限公司 | Novel sterilization powder |
| CN105086552A (en) * | 2015-09-01 | 2015-11-25 | 天长市开林化工有限公司 | Novel multifunctional full-efficiency emulsion paint and preparation method thereof |
| CN109370344A (en) * | 2018-09-25 | 2019-02-22 | 张�林 | Zeolite negative ion paint |
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2019
- 2019-04-30 CN CN201910362520.XA patent/CN110093076A/en not_active Withdrawn
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008120922A1 (en) * | 2007-04-02 | 2008-10-09 | Pusan National University Industry-University Cooperation Foundation | Antifouling paint composition |
| CN101457057A (en) * | 2007-12-13 | 2009-06-17 | 靳彦涛 | Multifunctional novel inner wall paint |
| CN104621180A (en) * | 2015-02-02 | 2015-05-20 | 山东威高药业股份有限公司 | Novel sterilization powder |
| CN105086552A (en) * | 2015-09-01 | 2015-11-25 | 天长市开林化工有限公司 | Novel multifunctional full-efficiency emulsion paint and preparation method thereof |
| CN109370344A (en) * | 2018-09-25 | 2019-02-22 | 张�林 | Zeolite negative ion paint |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112646438A (en) * | 2020-12-16 | 2021-04-13 | 彭龙水 | Negative ion antibacterial coating and preparation method thereof |
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Application publication date: 20190806 |