CN110092435A - A kind of microwave-ultraviolet joint organic wastewater treating system - Google Patents

A kind of microwave-ultraviolet joint organic wastewater treating system Download PDF

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Publication number
CN110092435A
CN110092435A CN201910477243.7A CN201910477243A CN110092435A CN 110092435 A CN110092435 A CN 110092435A CN 201910477243 A CN201910477243 A CN 201910477243A CN 110092435 A CN110092435 A CN 110092435A
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China
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microwave
ultraviolet
lamp
waste water
organic wastewater
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CN110092435B (en
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王楠楠
刘妍颜
赵嫱
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Beijing Institute of Petrochemical Technology
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Beijing Institute of Petrochemical Technology
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/30Treatment of water, waste water, or sewage by irradiation
    • C02F1/302Treatment of water, waste water, or sewage by irradiation with microwaves
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/30Treatment of water, waste water, or sewage by irradiation
    • C02F1/32Treatment of water, waste water, or sewage by irradiation with ultraviolet light
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/32Details relating to UV-irradiation devices
    • C02F2201/322Lamp arrangement
    • C02F2201/3227Units with two or more lamps
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/04Disinfection

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  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Physical Water Treatments (AREA)

Abstract

The invention discloses a kind of microwave-ultraviolet joint organic wastewater treating systems, including microwave radiometer, waste water treater, ultraviolet radioactive and blender, microwave electrodeless lamp, microwave radiometer is made of microwave radiation chamber and waveguide, waste water treater is by wastewater outlet, water fender, purification tank for liquid waste, waterwater entrance composition, ultraviolet radioactive and blender are by rotation axis, disk, microwave electrodeless lamp lamp set, cushion composition, microwave electrodeless lamp is placed in microwave electrodeless lamp lamp set, ultraviolet radioactive and blender are placed in purification tank for liquid waste, waste water treater is fixed in microwave radiation chamber by the wastewater outlet and waterwater entrance.The system utilizes ultraviolet radioactive and blender, and waste water is made uniformly to receive microwave and ultraviolet radioactive, and capacity usage ratio is high, and good waste water treatment effect is also equipped with wastewater disinfection function.

Description

A kind of microwave-ultraviolet joint organic wastewater treating system
Technical field
The present invention relates to a kind of organic wastewater treating system more particularly to a kind of microwave-ultraviolet joint treatment of Organic Wastewater System.
Background technique
Microwave itself has certain treatment of Organic Wastewater ability, while can also combine with other method for processing organic wastewater It uses.Studies have shown that microwave is mainly reflected in two aspects of fuel factor and non-thermal effect to the processing of waste water.Fuel factor refers to micro- Wave energy can be transformed into waste water in the form of thermal energy, increase waste water temperature, accelerate rate of contaminant degradation;Non-thermal effect refers to Microwave radiation can weaken organic molecule valence link, reduce contaminant degradation activation energy.
For the fuel factor of microwave, it is that energy consumption is higher that now on the one hand existing dispute, which mainly includes two aspects that, pollutant drop The quickening of solution rate can not make up the loss of energy consumption bring;It on the other hand is that efflux wastewater can cause receiving because temperature is higher The thermal pollution of water body.To solve the above problems, scholars have done many explorations, one of them more mature method is using micro- Wave electrodeless ultraviolet lamp, the lamp can be lit under microwave radiation and generate ultraviolet light.In actual operation, we can make microwave It is contacted with microwave electrodeless lamp, by part microwave energy at ultraviolet luminous energy, to reduce the ratio that microwave energy is absorbed by waste water Example.This guarantees that understand some microwave energy is absorbed by waste water, will not excessively influence microwave while reducing waste water temperature Non-thermal effect.Since ultraviolet light is compared with microwave frequency height, keeps the energy of ultraviolet light stronger, organic molecule valence link can be opened, had Imitate degradable organic pollutant.Therefore, ultraviolet radioactive is matched with microwave non-thermal effect, can greatly improve the processing effect of organic wastewater Fruit.
When introducing microwave radiation and ultraviolet radiation, it is intended to consider wastewater property to the two in the shadow of water transmission that gives up It rings.For microwave, absorption due to waste water to microwave can make microwave generate certain penetration depth in waste water, penetrate depth Waste water except degree can not receive microwave radiation;For ultraviolet light, some waste water light transmittances are very poor, can seriously undermine ultraviolet Propagation of the light in waste water.Therefore, it should adopt an effective measure, enable waste water while uniformly receive microwave radiation and ultraviolet light Radiation.
Summary of the invention
The object of the present invention is to provide a kind of effective microwave-ultraviolet joint organic wastewater treating systems, realize microwave energy The uniform reception of effective conversion and waste water to microwave and ultraviolet light to ultraviolet luminous energy, avoids receiving water body from generating to realize Thermal pollution reduces energy consumption and improves triple targets for the treatment of of Organic Wastewater efficiency.
The purpose of the present invention is what is be achieved through the following technical solutions:
Microwave of the invention-ultraviolet joint organic wastewater treating system, including microwave radiometer 1, waste water treater 2 are purple External radiation and blender 3, microwave electrodeless lamp 4, the microwave radiometer 1 is by microwave radiation chamber 1-1 and two waveguide 1-2 Composition, the waste water treater 2 are made of wastewater outlet 2-1, water fender 2-2, purification tank for liquid waste 2-3, waterwater entrance 2-4, institute Ultraviolet radioactive and blender 3 are stated by rotation axis 3-1, disk 3-2, microwave electrodeless lamp lamp set 3-3, cushion 3-4 composition, institute It states microwave electrodeless lamp 4 to be placed in the microwave electrodeless lamp lamp set 3-3, the ultraviolet radioactive and blender 3 are placed in institute It states in purification tank for liquid waste 2-3, the waste water treater 2 is fixed on institute by the wastewater outlet 2-1 and the waterwater entrance 2-4 It states in microwave radiation chamber 1-1.
As seen from the above technical solution provided by the invention, microwave-ultraviolet joint provided in an embodiment of the present invention has Machine waste water treatment system can be effectively by microwave energy at ultraviolet by contacting microwave radiation with microwave electrodeless lamp Luminous energy reduces absorption of the waste water to microwave while excessively not influencing microwave non-thermal effect;Pass through ultraviolet radioactive and blender 3 rotation can make microwave electrodeless lamp lamp set generate perturbation action to waste water, and waste water is promoted to revolve in purification tank for liquid waste 2-3 Turn of tidal stream is dynamic.The system can significantly reduce wastewater outlet temperature, avoid generating thermal pollution to receiving water body;Waste water can be made equal simultaneously Even to receive microwave radiation and ultraviolet radiation, water treatment effect is good.In addition, it is noted that due to ultraviolet light Radiation, the system can also generate subsidiary sterilization effect to organic wastewater.
Detailed description of the invention
Fig. 1 is microwave provided in an embodiment of the present invention-ultraviolet joint organic wastewater treating system top view;
Fig. 2 is microwave provided in an embodiment of the present invention-ultraviolet joint organic wastewater treating system 1-1 sectional view;
Fig. 3 is microwave provided in an embodiment of the present invention-ultraviolet joint organic wastewater treating system microwave radiometer vertical view Figure;
Fig. 4 is that microwave provided in an embodiment of the present invention-ultraviolet joint organic wastewater treating system microwave radiometer 2-2 is cutd open Face figure;
Fig. 5 is microwave provided in an embodiment of the present invention-ultraviolet joint organic wastewater treating system waste water treater vertical view Figure;
Fig. 6 is that microwave provided in an embodiment of the present invention-ultraviolet joint organic wastewater treating system waste water treater 3-3 is cutd open Face figure;
Fig. 7 is microwave provided in an embodiment of the present invention-ultraviolet joint organic wastewater treating system ultraviolet radioactive and stirring Device top view;
Fig. 8 is microwave provided in an embodiment of the present invention-ultraviolet joint organic wastewater treating system ultraviolet radioactive and stirring Device 4-4 sectional view;
Fig. 9 is microwave provided in an embodiment of the present invention-ultraviolet joint organic wastewater treating system microwave electrodeless lamp Main view;
Figure 10 is microwave provided in an embodiment of the present invention-ultraviolet joint organic wastewater treating system size marking figure (1);
Figure 11 is microwave provided in an embodiment of the present invention-ultraviolet joint organic wastewater treating system size marking figure (2);
Figure 12 is microwave provided in an embodiment of the present invention-ultraviolet joint organic wastewater treating system size marking figure (3).
In figure:
1- microwave radiometer;2- waste water treater;3- ultraviolet radioactive and blender;4- microwave electrodeless lamp;1-1- is micro- Wave radiation chamber;1-2- waveguide;2-1- wastewater outlet;2-2- water fender;2-3- purification tank for liquid waste;2-4- waterwater entrance;3-1- Rotation axis;3-2- disk;3-3- microwave electrodeless lamp lamp set;3-4- cushion;The pivot center of M- rotation axis;At N- waste water Manage the axis in pond.
Specific embodiment
The embodiment of the present invention will be described in further detail below.What is be not described in detail in the embodiment of the present invention is interior Appearance belongs to the prior art well known to professional and technical personnel in the field.
Microwave of the invention-ultraviolet joint organic wastewater treating system, preferable specific embodiment such as Fig. 1 to Figure 12 It is shown:
Including microwave radiometer 1, waste water treater 2, ultraviolet radioactive and blender 3, microwave electrodeless lamp 4 is described micro- Wave emitter 1 is made of microwave radiation chamber 1-1 and waveguide 1-2, and the waste water treater 2 is by wastewater outlet 2-1, water fender 2- 2, purification tank for liquid waste 2-3, waterwater entrance 2-4 composition, the ultraviolet radioactive and blender 3 are by rotation axis 3-1, disk 3-2, microwave Electrodeless ultraviolet lamp lamp covers 3-3, cushion 3-4 composition, and the microwave electrodeless lamp 4 is placed in the microwave electrodeless lamp lamp set In 3-3, the ultraviolet radioactive and blender 3 are placed in the purification tank for liquid waste 2-3, and the waste water treater 2 passes through described useless The water out 2-1 and waterwater entrance 2-4 is fixed in the microwave radiation chamber 1-1.
Described two waveguide 1-2 geometric center lines are vertical with the cross section of any waveguide 1-2, the microwave For electrodeless ultraviolet lamp 4 after being inserted into the microwave electrodeless lamp lamp set 3-3, the length for the part that is exposed is L, described two Horizontal plane where waveguide 1-2 geometric center line will just be exposed partially flat described in the microwave electrodeless lamp 4 It is divided into two sections, i.e. L1=L/2.
The waterwater entrance 2-4 is annulus with the cross section the wastewater outlet 2-1 and the internal radius is identical, described useless The axis of the axis of water inlet 2-4 and the wastewater outlet 2-1 are on the same vertical plane.
In the one end of the wastewater outlet 2-1 being connected with the purification tank for liquid waste 2-3, the water fender 2-2 is set, The ultraviolet radioactive and blender 3 rotate counterclockwise, angular velocity of rotation ω is in 10- using the rotation axis 3-1 as axle center 500 revs/min, the rotation axis 3-1 cross-sectional diameter is between 2-5cm.
The cushion 3-4 is installed in the bottom of microwave electrodeless lamp lamp set 3-3.
The 4 diameter d of microwave electrodeless lamp13-3 diameter R is covered with the microwave electrodeless lamp lamp1The ratio between be 0.99, The microwave electrodeless lamp lamp covers 3-3 diameter R1Minimum 2.1cm.
The microwave electrodeless lamp lamp set 3-3 arranges in multiple circular ring shapes, and the multiple annulus has phase concentric, appoints The circle center distance d for the two neighboring microwave electrodeless lamp lamp set cross section 3-3 anticipated on an annulus2Be equal and Not less than 2R1, the difference d of the radius of the adjacent annulus of any two3It is equal and not less than 3R1
The minimum circle diameter R2It is not less than 5 with the ratio between the rotation axis 3-1 cross-sectional diameter.
The maximum circle diameter R3It is not less than 3R with the absolute value of the difference of the disk 3-2 diameter R1
The center of circle of the annulus is simultaneously in the axis of the pivot center M and the purification tank for liquid waste 2-3 of the rotation axis 3-1 On N.
Microwave of the invention-ultraviolet joint organic wastewater treating system makes to give up by the rotation of ultraviolet radioactive and blender Water rotates flowing in purification tank for liquid waste, this enables waste water sufficiently to receive microwave and ultraviolet radioactive, reduces waste water The influence of Microwave Absorption Properties and light transmittance to water treatment effect;By the way that water fender is arranged, waste water is made as far as possible in exit Enough steady outflows, streamflow regime not will receive the influence of waste water rotational flow.
Specific embodiment:
As shown in Fig. 1~Figure 12, microwave radiometer 1, waste water treater 2, ultraviolet radioactive and blender 3, micro-wave nonpolar are purple Outer lamp 4, the microwave radiometer 1 are made of microwave radiation chamber 1-1 and waveguide 1-2, and the waste water treater 2 is by wastewater outlet 2-1, water fender 2-2, purification tank for liquid waste 2-3, waterwater entrance 2-4 composition, the ultraviolet radioactive and blender 3 by rotation axis 3-1, Disk 3-2, microwave electrodeless lamp lamp cover 3-3, cushion 3-4 composition, the microwave electrodeless lamp 4 be placed in the microwave without Extreme ultraviolet lamp lamp covers in 3-3, and the ultraviolet radioactive and blender 3 are placed in the purification tank for liquid waste 2-3, the waste water treater 2 are fixed in the microwave radiation chamber 1-1 by the wastewater outlet 2-1 and the waterwater entrance 2-4.The system passes through addition On the one hand the mode of microwave electrodeless lamp reduces waste water and on the other hand utilizes microwave and ultraviolet light to the assimilation ratio of microwave Synergy reinforce waste water treatment effect;By promoting the rotational flow of waste water, receive waste water can while uniformly micro- Wave and ultraviolet radiation.
Described two waveguide 1-2 geometric center lines are vertical with the cross section of any waveguide 1-2, the microwave For electrodeless ultraviolet lamp 4 after being inserted into the microwave electrodeless lamp lamp set 3-3, the length for the part that is exposed is L, described two Horizontal plane where waveguide 1-2 geometric center line will just be exposed partially flat described in the microwave electrodeless lamp 4 It is divided into two sections, i.e. L1=L/2.By taking the structure, microwave homogeneous radiation in microwave radiometer can be made, while can also make Microwave is in contact with microwave electrodeless lamp first, and is lighted, and microwave energy is converted to the ultraviolet luminous energy of energy first, reduces waste water To the assimilation ratio of microwave.Preferably, L=11cm.
The waterwater entrance 2-4 is annulus with the cross section the wastewater outlet 2-1 and the internal radius is identical, described useless The axis of the axis of water inlet 2-4 and the wastewater outlet 2-1 are on the same vertical plane.By taking the structure, can make to give up For water during passing in and out waste water treater, wastewater flow is identical, while various convenient for carrying out to waste water inlet and wastewater outlet Technical operation.
In the one end of the wastewater outlet 2-1 being connected with the purification tank for liquid waste 2-3, the water fender 2-2 is set, The ultraviolet radioactive and blender 3 rotate counterclockwise, angular velocity of rotation ω is in 10- using the rotation axis 3-1 as axle center 500 revs/min, the rotation axis 3-1 cross-sectional diameter is between 2-5cm.Pass through the rotation counterclockwise of ultraviolet radioactive and blender 3 Turn, waste water can be made also to carry out rotational flow counterclockwise, as shown in figure 5, waste water is in rotary course due to the presence of water fender 2-2 In will not directly from wastewater outlet 2-1 be discharged, and will bypass water fender 2-2, this is greatly lowered waste water in wastewater outlet 2-1 The disturbance at place, to reduce the influence to detection devices various at wastewater outlet;Limitation rotation axis 3-1 cross-sectional diameter be for In the case where guaranteeing rotation axis intensity, retain spaces more as far as possible, thus settable microwave electrodeless lamp more as far as possible Lamp set.Preferably, angular velocity of rotation ω is 100 revs/min, and rotation axis 3-1 cross-sectional diameter is 2.5cm.
The cushion 3-4 is installed in the bottom of microwave electrodeless lamp lamp set 3-3.It, can by taking the structure Shock of the lamp set bottom to ultraviolet lamp during loading microwave electrodeless lamp 4 is effectively reduced, it is broken to substantially reduce ultraviolet lamp A possibility that broken.
The 4 diameter d of microwave electrodeless lamp13-3 diameter R is covered with the microwave electrodeless lamp lamp1The ratio between be 0.99. By taking the structure, it ensure that microwave electrodeless lamp can be successfully inserted in microwave electrodeless lamp lamp set 3-3, and protect It has demonstrate,proved ultraviolet radioactive and blender 3 during rotation, purple will not have been caused because the gap between ultraviolet lamp and lamp set is excessive The sharp impacts of outer lamp and lamp inner room.
The microwave electrodeless lamp lamp covers 3-3 diameter R1Minimum 2.1cm.It limits microwave electrodeless lamp lamp and covers 3-3 The minimum value of diameter is the minimum diameter in order to guarantee microwave electrodeless lamp, makes microwave electrodeless lamp in the radiation of microwave Under can smoothly be lighted.Preferably, the microwave electrodeless lamp lamp covers 3-3 diameter R1For 2.53cm.
The microwave electrodeless lamp lamp set 3-3 arranges in multiple circular ring shapes, and the multiple annulus has phase concentric, appoints The circle center distance d for the two neighboring microwave electrodeless lamp lamp set cross section 3-3 anticipated on an annulus2Be equal and Not less than 2R1, the difference d of the radius of the adjacent annulus of any two3It is equal and not less than 3R1.It, can by taking the structure It is distributed microwave electrodeless lamp lamp set 3-3 with certain rule, guarantees the uniformity stirred to waste water.Preferably, d2 For 5.06cm, d3For 7.59cm.
The minimum circle diameter R2It is not less than 5 with the ratio between the rotation axis 3-1 cross-sectional diameter.By taking the knot Structure makes the diameter of minimum annulus be unlikely to too small, to guarantee that generating effective agitation to the waste water at purification tank for liquid waste center makees With.
The maximum circle diameter R3It is not less than 3R with the absolute value of the difference of the disk 3-2 diameter R1.By taking the knot Structure limits the diameter of maximum annulus, avoids the outer edge of microwave electrodeless lamp lamp set 3-3 and the outer edge of disk 3-2 It is tangent.
The center of circle of the annulus is simultaneously in the axis of the pivot center M and the purification tank for liquid waste 2-3 of the rotation axis 3-1 On N.By taking the structure, make rotation axis 3-1 in driving entire ultraviolet radioactive and blender rotary course, waste water can be to turn Rotating with Uniform flows in purification tank for liquid waste 2-3 centered on moving axis 3-1 axis, so that waste water is uniformly received microwave and purple as far as possible The dual radiation of outer light.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, Within the technical scope of the present disclosure, any changes or substitutions that can be easily thought of by anyone skilled in the art, It should be covered by the protection scope of the present invention.Therefore, protection scope of the present invention should be with the protection model of claims Subject to enclosing.

Claims (10)

1. a kind of microwave-ultraviolet joint organic wastewater treating system, which is characterized in that including microwave radiometer, waste water treater, Ultraviolet radioactive and blender, microwave electrodeless lamp, the microwave radiometer are made of microwave radiation chamber and two waveguides, institute Waste water treater is stated to be made of wastewater outlet, water fender, purification tank for liquid waste, waterwater entrance, the ultraviolet radioactive and blender by Rotation axis, disk, microwave electrodeless lamp lamp set, cushion composition, the microwave electrodeless lamp are placed in the micro-wave nonpolar In ultraviolet lamp lamp set, the ultraviolet radioactive and blender are placed in the purification tank for liquid waste, and the waste water treater passes through described Wastewater outlet and the waterwater entrance are fixed in the microwave radiation chamber.
2. microwave according to claim 1-ultraviolet joint organic wastewater treating system, which is characterized in that described two waves Conduit geometric center line is vertical with the cross section of any waveguide, and the microwave electrodeless lamp is being inserted into the microwave After in electrodeless ultraviolet lamp lamp set, the length for the part that is exposed is L, horizontal plane where described two waveguide geometric center lines It will just be exposed described in the microwave electrodeless lamp and be partially divided into two sections, i.e. L1=L/2.
3. microwave according to claim 1-ultraviolet joint organic wastewater treating system, which is characterized in that the waste water enters Mouth is annulus with the wastewater outlet cross section and the internal radius is identical, and the axis of the waterwater entrance goes out with the waste water The axis of mouth is on the same vertical plane.
4. microwave according to claim 1-ultraviolet joint organic wastewater treating system, which is characterized in that in the waste water The water fender is arranged in the one end of outlet being connected with the purification tank for liquid waste, and the ultraviolet radioactive and blender are with described turn Moving axis is to rotate counterclockwise axle center, and angular velocity of rotation ω is at 10-500 revs/min, and the rotation axis cross-sectional diameter is in 2- Between 5cm.
5. microwave according to claim 1-ultraviolet joint organic wastewater treating system, which is characterized in that in the microwave The bottom of electrodeless ultraviolet lamp lamp set is installed by the cushion.
6. microwave according to claim 1-ultraviolet joint organic wastewater treating system, which is characterized in that the microwave without Extreme ultraviolet lamp diameter d1Diameter R is covered with the microwave electrodeless lamp lamp1The ratio between be 0.99, the microwave electrodeless lamp lamp set Diameter R1Minimum 2.1cm.
7. microwave according to claim 1-ultraviolet joint organic wastewater treating system, which is characterized in that the microwave without Extreme ultraviolet lamp lamp set is arranged in multiple circular ring shapes, and the multiple annulus has phase concentric, the phase on any one of annulus The circle center distance d of adjacent two microwave electrodeless lamp lamp sets cross section2It is equal and not less than 2R1, the adjacent institute of any two State the difference d of the radius of annulus3It is equal and not less than 3R1
8. microwave according to claim 7-ultraviolet joint organic wastewater treating system, which is characterized in that the minimum circle Ring diameter R2It is not less than 5 with the ratio between the rotation axis cross-sectional diameter.
9. microwave according to claim 7-ultraviolet joint organic wastewater treating system, which is characterized in that the maximum circle Ring diameter R3It is not less than 3R with the absolute value of the difference of the disk diameter R1
10. microwave according to claim 7-ultraviolet joint organic wastewater treating system, which is characterized in that the annulus The center of circle is simultaneously on the pivot center M of the rotation axis and the axis N of the purification tank for liquid waste.
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