CN110088543A - Cold storage plant, ion generating apparatus and collecting storage facility - Google Patents

Cold storage plant, ion generating apparatus and collecting storage facility Download PDF

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Publication number
CN110088543A
CN110088543A CN201780053632.6A CN201780053632A CN110088543A CN 110088543 A CN110088543 A CN 110088543A CN 201780053632 A CN201780053632 A CN 201780053632A CN 110088543 A CN110088543 A CN 110088543A
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CN
China
Prior art keywords
ion
space
accommodating space
electric conductor
generating apparatus
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Granted
Application number
CN201780053632.6A
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Chinese (zh)
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CN110088543B (en
Inventor
藤田司
宫田昭雄
井上善一
长浓笃史
青山遥
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Sharp Corp
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Sharp Corp
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Publication of CN110088543A publication Critical patent/CN110088543A/en
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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D23/00General constructional features
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01TSPARK GAPS; OVERVOLTAGE ARRESTERS USING SPARK GAPS; SPARKING PLUGS; CORONA DEVICES; GENERATING IONS TO BE INTRODUCED INTO NON-ENCLOSED GASES
    • H01T19/00Devices providing for corona discharge
    • H01T19/02Corona rings
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01TSPARK GAPS; OVERVOLTAGE ARRESTERS USING SPARK GAPS; SPARKING PLUGS; CORONA DEVICES; GENERATING IONS TO BE INTRODUCED INTO NON-ENCLOSED GASES
    • H01T23/00Apparatus for generating ions to be introduced into non-enclosed gases, e.g. into the atmosphere

Abstract

Cold storage plant (100,200) are provided and ion generating apparatus is provided.The cold storage plant (100,200) has: the first ion generation unit (110,110B), to supply ion to the first accommodating space (104,106,107);And first electric conductor (120), it configures near at least bottom or bottom of the first accommodating space (104,106,107).The ion generating apparatus provides ion to storage space (103), and has: generating unit (110), has the brush electrode (112) to generate ion;And the ejiction opening (113X) to spray the ion to the storage space is provided with the receiving area (114) for the electric conductor that receiving falls off from the brush electrode between the brush electrode and the ejiction opening.

Description

Cold storage plant, ion generating apparatus and collecting storage facility
Technical field
Technology of the present invention about the cold storage plant of receiving food or beverage etc., especially with respect to carrying ion generation unit Cold storage plant.Or about the ion generating apparatus for having the ion generation unit with brush electrode.
Background technique
In the past, it is known that ion generation unit and the refrigerator for having it.For example, Japanese Unexamined Patent Publication 2010-281526 bulletin is (specially Sharp document 1) disclose refrigerator.According to patent document 1, have the storeroom of storage reserve, the cooler of generation cold air, with cooling The cold air access for the cold air circulation that device generates is provided with the wall surface of storeroom and the cold air to circulate in cold air access is ejected to storage The ejiction opening for hiding room and the ion generating unit for generating ion configure the ion near the ejiction opening in cold air access and generate dress It sets.
It is produced simultaneously by anion with cation in addition, Japanese Unexamined Patent Publication 2002-58731 bulletin (patent document 2) is disclosed It is raw, generate reactive species i.e. hydrogen peroxide H2O2Or hydroxide free radical OH and this H2O2Or OH show it is extremely strong activity because This can remove planktonic bacteria etc..
In addition, Japanese Unexamined Patent Publication 2004-28498 bulletin (patent document 3) discloses refrigerator.More specifically, according to patent Document 3 imports forced ventilation cooling air being equipped with to carry out cooling direct cooling storeroom and configure in storeroom to receive Receive container and this accommodating container accommodating container lid to carry out the ice of indirectly cooling indirect cooling storeroom to the accommodating container Case wears ejiction opening and suction inlet in the accommodating container lid, makes in the accommodating container in the setting of the upper surface of the accommodating container lid The circulation pressure fan and anion generator of circulating cold air, by the air sprayed from the circulation pressure fan directly blow to moisture absorption/ It is deodorized piece.
Furthermore, it is known that the ion generating apparatus with brush electrode.For example, No. 2015/151309 brochure of International Publication No. Sub (patent document 4) discloses ion generating apparatus and electric machine.More specifically, it according to patent document 4, provides compared to adopting Use needle electrode as discharge electrode ion generating apparatus can higher efficiency generate ion ion generating apparatus.Ion generates Device has induction electrode, the discharge electrode to generate ion between induction electrode.Discharge electrode has multiple filiforms The joint portion of the root of electric conductor and bundle electric conductor.Induction electrode configures the root side in electric conductor.
Existing technical literature
Patent document
Patent document 1: Japanese Unexamined Patent Publication 2010-281526 bulletin
Patent document 2: Japanese Unexamined Patent Publication 2002-58731 bulletin
Patent document 3: Japanese Unexamined Patent Publication 2004-28498 bulletin
Patent document 4: No. 2015/151309 pamphlet of International Publication No.
Summary of the invention
As the accommodating space of storeroom has widened tendency, seek that the food being housed in accommodating space can be not dependent on Or the receiving location of beverage etc. removes the technology degermed.Being designed to provide for a form of the invention can be to the receipts in accommodating space Tolerant unbiased poorly high efficiency removes the cold storage plant to degerm.
In addition, the electric conductor for constituting brush electrode is several μm~tens of μm in the ion generating apparatus that patent document 4 discloses Shape thin and that front end unlatching is brushed and the energization to brush electrode, therefore the Filamentous electric conductor of brush electrode is constituted because logical Electricity and power-off are bent repeatedly, and Filamentous electric conductor is possible to fall off because long-time uses.
When the electric conductor to fall off is attached between discharge electrode, a possibility that impacting to ion generation is had.In addition, into It is also bad for entering in storage space.
Therefore, and it is an object of the present invention to provide the electric conductor of the brush electrode to fall off is housed in regulation receipts in another form of the present invention Hold the ion generating apparatus in region.
Solution to the problem
The cold storage plant of certain form according to the present invention, has: the first ion generation unit, to supply the first accommodating space Answer ion;And first electric conductor, it configures near at least bottom of the first accommodating space or bottom.
The ion for being preferred from the first ion generation unit does not utilize fan and is provided to the first accommodating space.
It is preferred that the composition of cold storage plant is to accommodate sky via composition first to cold air is not blown into directly in the first accommodating space Between box body indirectly cool down the first accommodating space in.
It is preferred that the second accommodating space or setting different from the first accommodating space the are arranged around the first accommodating space Two accommodating spaces.Cold storage plant is further equipped with to the second ion generation unit to the second accommodating space supply ion.Come The second accommodating space is provided to using fan from the ion of the second ion generation unit.
Preferably further has configuration in the upper surface of first accommodating space or the second neighbouring above electric conductor.
It is preferred that other conductive components of the first electric conductor and cold storage plant are not conductively connected.
It is preferred that the first ion generation unit has step-up transformer, which has the primary winding of connection power supply Carrying out boosting with the voltage to power supply becomes the secondary winding of discharge voltage;First electric conductor is connected to secondary winding.
Another form according to the present invention provides the ion generating apparatus to storage space supply ion.Ion generating apparatus Having has the ion generation unit to generate the brush electrode of ion and the ejection to spray ion toward storage space Mouthful.In addition, forming the recess portion being recessed downward between brush electrode and ejiction opening, the conduction to fall off from brush electrode is accommodated Body (is also referred to as brushed).
It is preferred that forming the attachment adhere to the electric conductor to fall off from brush electrode between brush electrode and ejiction opening Portion.
It is preferred that configuring the component for preventing the electric conductor to fall off from flowing out toward storage space between brush electrode and ejiction opening.
It is preferred that in the accommodating container of storage space configuration drawer type.Pass through one of the accommodating container when closing accommodating container Divide and abut, recess portion can vibrate.
It is preferred that brush electrode is towards approximate horizontal or approximately below configure.
Another form according to the present invention provides the collecting storage facility equipped with above-mentioned ion generating apparatus.
Invention effect
As above-mentioned, a form according to the present invention, provide can poorly high efficiency unbiased to the stored substance in accommodating space remove The cold storage plant of bacterium.In addition, another form according to the present invention, it is possible to provide be housed in the brush of regulation receiving area with electric conductor The ion generating apparatus of shape electrode.
The simple declaration of attached drawing
Fig. 1 is the whole front view of the refrigerator 100 of first embodiment.
Fig. 2 be first and the 8th implementation form refrigerator pipe 131 side view.
Fig. 3 is the side sectional view indicated near the refrigerating space 104 of first embodiment.
Fig. 4 is the top view of the refrigerating space 104 of first embodiment.
Fig. 5 is the side sectional view indicated near the ion generation unit 110 of first embodiment.
Fig. 6 is the in-built sectional view for indicating the ion generation unit 110 of first embodiment.
Fig. 7 is the circuit diagram of the ion generation unit 110 of first embodiment.
Fig. 8 is the side view for indicating the cation and anion of the refrigerating space 104 of first embodiment.
Fig. 9 is the top view of the refrigerating space 104 configured with plate 120 of the first case of the second implementation form.
Figure 10 be indicate the refrigerating space 104 configured with plate 120Y of second case of the second implementation form cation and bear from The side view of son.
Figure 11 is the third example of the second implementation form configured with plate 122A, the top view of the refrigerating space 104 of 122B.
Figure 12 is the conductive dish 123A of configuration of the 4th of the second implementation form, the top view of the refrigerating space 104 of 123B.
Figure 13 be indicate the refrigerating space 104 configured with plate 120X of first case of third implementation form cation and bear from The side view of son.
Figure 14 be indicate the refrigerating space 104 configured with plate 120Z of second case of third implementation form cation and bear from The side view of son.
Figure 15 be indicate the cation of the refrigerating space 104 configured with plate 120,120B of third example of third implementation form with The side view of anion.
Figure 16 be indicate the 4th of third implementation form configured with plate 120,120B, the refrigerating space 104 of 120C, 120D Cation and anion side view.
Figure 17 is the top view of the refrigerating space 104 configured with mesh members 127 of the 4th implementation form.
Figure 18 is the side view for indicating the cation and anion of the refrigerating space 104 configured with plate 120 of the 5th implementation form Figure.
Figure 19 is the side sectional view indicated near the refrigerating space 104 of the first case of the 6th implementation form.
Figure 20 is the side sectional view indicated near the refrigerating space 104 of the second case of the 6th implementation form.
Figure 21 is the side sectional view near the refrigerating space 104 for the third example for indicating the 6th implementation form.
Figure 22 is the vegetables accommodating space 106 for indicating the 7th implementation form and the side sectional view near fruit accommodating space 107.
Figure 23 is the front cross-sectional view in the main refrigerating space 103 for indicate the 7th implementation form.
Figure 24 is the rearview of the refrigerator pipe 131 of the 8th implementation form.
Figure 25 is the schematic diagram for indicating the storeroom 200 of the 9th implementation form.
Figure 26 is the side view for indicating the cation and anion of general refrigerating space.
Figure 27 is the stereoscopic figure for indicating the refrigerator 100 of the tenth implementation form.
Figure 28 is the front view for indicating the food storing space 103 of refrigerator 100 of the tenth implementation form.
Figure 29 is the side profile enlarged drawing for indicating the ion generating apparatus 1100 and drawer 109 of the tenth implementation form.
Figure 30 is the side profile enlarged drawing indicated near the ion generating apparatus 1100 of the tenth implementation form.
Figure 31 is the side profile enlarged drawing indicated near the ion generating apparatus 1100 of the 11st implementation form.
Figure 32 is the side profile enlarged drawing indicated near the ion generating apparatus 1100 of the 12nd implementation form.
Figure 33 is the side profile enlarged drawing indicated near the first ion generating apparatus 1100 of the 13rd implementation form.
Figure 34 is the side profile enlarged drawing indicated near the second ion generating apparatus 1100 of the 13rd implementation form.
Figure 35 is the side profile enlarged drawing indicated near the third ion generating apparatus 1100 of the 13rd implementation form.
Figure 36 is the side profile enlarged drawing indicated near the ion generating apparatus 1100 of the 14th implementation form.
Figure 37 is the side profile enlarged drawing indicated near the first ion generating apparatus 1100 of the 15th implementation form.
Figure 38 is the side profile enlarged drawing indicated near the second ion generating apparatus 1100 of the 15th implementation form.
Figure 39 is the side profile enlarged drawing indicated near the first ion generating apparatus 1100 of the 16th implementation form.
Figure 40 is the side profile enlarged drawing indicated near the second ion generating apparatus 1100 of the 16th implementation form.
Figure 41 is the side profile enlarged drawing indicated near the third ion generating apparatus 1100 of the 16th implementation form.
Figure 42 is the side profile enlarged drawing indicated near the ion generating apparatus 1100 of the 17th implementation form.
Figure 43 is the side profile enlarged drawing indicated near the ion generating apparatus 1100 of the 18th implementation form.
The embodiment of invention
Hereinafter, illustrating each implementation form of the invention referring to schema.In following explanation, identical attached drawing is assigned to identical parts Label.These title and function is all identical.Therefore, it does not repeat to be described in detail for these.
(first embodiment)
Fig. 1 is the whole front view of the refrigerator 100 of this implementation form.The ion generation unit 110 of this implementation form, such as It is equipped on the refrigerator 100 of an example shown in FIG. 1 as cold storage plant.In addition, cold storage plant can also be drawer, the cabinet in kitchen Son or wardrobe etc. will not be with cooling collecting storage facilities.
Refrigerator 100, by such as ontology 101 and door 102L, 102R etc. is constituted.In addition, the inside of ontology 101 includes main refrigeration Space 103, reefer space 105, vegetables accommodating space 106, fruit accommodating space 107, ice storage capacity 108 etc..This implementation form In, in main refrigerating space 103 be equipped with refrigerating space 104, the refrigerating space 104 be equipped with the refrigerating space 104 from Son generates unit 110.
Fig. 2 is the side view of the refrigerator pipe 131 of this implementation form.Fig. 3 is to indicate that the refrigerating space 104 of this implementation form is attached Close side sectional view.Referring to Fig. 3, the refrigerating space 104 of this implementation form, mainly by being mounted in main refrigerating space 103 The upper box 104B of wall, it can be formed relative to main refrigerating space 103 or upper box 104B toward the lower box 104A that front-rear direction slides.
At 104 rear of refrigerating space, as shown in Fig. 2, refrigerator pipe 131 is equipped with, at one of the cold air that refrigerator pipe 131 circulates Divide and circulate from ejiction opening 133 along the outer wall of lower box 104A or upper box 104B, indirectly in cooling refrigerating space 104.Therefore, can prevent Only cold wind directly touches the ingesta in refrigerating space 104, and ingesta can not be made dryly cooling.
Ion generation unit 110 is configured at the rear upper box 104B.In addition, it is equipped with opening portion 104X at the back side upper box 104B, The cation and anion that ion generation unit 110 generates flow into refrigerating space 104 by opening portion 104X.
Fig. 4 is the top view of the refrigerating space 104 of this implementation form.Bottom surface configuration referring to Fig. 4, on the inside of lower box 104A The plate 120 of electric conductivity.As be described hereinafter, by the plate of electric conductivity 120 can slow down ion generation unit 110 generation cation and The degree of anion deviation.
Fig. 5 is the side sectional view indicated near the ion generation unit 110 of this implementation form.The ion of this implementation form It generates unit 110 and is mounted on the installation space 113 that the inner wall of refrigerator 100 is constituted.Through lining around 113 front of installation space Pad 118 is connected with upper box 104B.In this implementation form, ion generation unit 110 has the discharge electrode 1,2 of brush, in brush Discharge electrode 1,2 nearby generate high concentration ion.Slit 1150 is configured in the front of discharge electrode 1,2, so that article is not Can mutually it enter between ion generation unit 110 and refrigerating space 104.
Herein, illustrate the construction of the ion generation unit 110 of this implementation form.Fig. 6 is the ion for indicating this implementation form Generate the internal structure of unit 110.Ion generation unit 110 has two discharge electrodes 1,2, cricoid induction electrode 3,4, two The printed base plate 5,6 of a oblong-shaped.Induction electrode 3 is the electrode to form electric field between discharge electrode 1.Induced electricity Pole 4 is the electrode to form electric field between discharge electrode 2.Discharge electrode 1 is to generate between induction electrode 3 The electrode of anion.Discharge electrode 2 is the electrode to generate cation between induction electrode 4.
Printed base plate 5,6 is separated by specified interval configured in parallel.Induction electrode 3 is formed using the wiring layer of printed base plate 5 On the surface in a square end portion of 5 longitudinal direction of printed base plate.The hole of perforation printed base plate 5 is offered in the inside of induction electrode 3 5a.Induction electrode 4 is the surface that another party end of 5 longitudinal direction of printed base plate is formed in using the wiring layer of printed base plate 5. The hole 5b of perforation printed base plate 5 is offered in the inside of induction electrode 4.
Each of discharge electrode 1,2 is vertically arranged relative to printed base plate 5,6.The base end part of discharge electrode 1 is inserted and is embedded in The hole of printed base plate 6, the other end penetrate through the center of the hole 5a of printed base plate 5.The base end part of discharge electrode 2, which is inserted, is embedded in printed base plate 6 hole, the other end penetrate through the center of the hole 5b of printed base plate 5.The base end part of each of discharge electrode 1,2 is fixed by solder In printed base plate 6.
Induction electrode 3,4 is formed in printed base plate 5, and discharge electrode 1,2 is fixed on the printed base plate different from printed base plate 5 6.Therefore, in the state that dust is piled up on printed base plate 5,6, even if ion generating apparatus is in the feelings under high humidity environment Shape can also inhibit the current leakage between discharge electrode 1,2 and induction electrode 3,4, can steadily generate ion.
The front end of each of discharge electrode 1,2 is formed as brush.Discharge electrode 1, which has, is located at the multiple of its front end The joint portion 7a of Filamentous electric conductor 7 and the root member for being bundled multiple electric conductors 7.Discharge electrode 2, which has, is located at the more of its front end The electric conductor 8 of a filiform, the joint portion 8a with the root member for being bundled multiple electric conductors 8.
Fig. 7 is the circuit diagram of the ion generation unit 110 of this implementation form.Reference Fig. 7, ion generation unit 110, in addition to Outside discharge electrode 1,2 and induction electrode 3,4, have power supply terminal T1, ground terminal T2, diode 32,33 and step-up transformer 31.The anode and cathode of DC power supply are separately connected in power supply terminal T1 and ground terminal T2.Apply direct current in power supply terminal T1 Supply voltage (for example,+12V or+15V), ground terminal T2 ground connection.Power supply terminal T1 and ground terminal T2 penetrates power circuit 30 It is connected to step-up transformer 31.
Step-up transformer 31 includes primary winding 31a and secondary winding 31b.Square end of secondary winding 31b is connected to Induction electrode 3,4, another party's terminal are connected to the cathode of diode 32 and the anode of diode 33.The anode of diode 32 connects In the base end part of discharge electrode 1, the cathode of diode 33 is connected to the base end part of discharge electrode 2.
Referring to Fig. 6 and Fig. 7, illustrate the movement of ion generation unit 110.Apply between power supply terminal T1 and ground terminal T2 When direct current power source voltage, capacitor (not shown) that charge charging has in power circuit 30.It charges in the charge of capacitor, thoroughly The primary winding 31a electric discharge for crossing step-up transformer 31 generates pulse voltage in once winding 31a.
When once winding 31a generates pulse voltage, in secondary winding 31b, just and negative high voltage pulse interacts on one side Decaying generates on one side.Negative high voltage pulse is applied to discharge electrode 1 through diode 32, and positive high voltage pulse penetrates two poles Pipe 33 is applied to discharge electrode 2.The electric conductor 7,8 in the front end of discharge electrode 1,2 generates corona discharge as a result, generates respectively Anion and cation.
In addition, cation is the clump cluster ion of multiple hydrones clump cluster around hydrogen ion (H<+>), it is expressed as H<+> (H2O) m (arbitrary integer that m is 0 or more).The clump cluster of the anion clump cluster that is multiple hydrones around oxonium ion (O2<->) Ion is expressed as O2<->(H2O) n (arbitrary integer that n is 0 or more).In addition, cation and anion be toward when indoor release, two Ion surrounds around the bacterium to suspend in air or virus, causes to chemically react on the surface thereof each other.By generating at this time Reactive species hydroxide free radical (OH) effect, remove flcating germ etc..
In addition, in this implementation form, constitute multiple filiforms of the front end of the discharge electrode 1,2 of brush electric conductor 7 and 8, the lateral bend deformation outward because of the electrical attraction of mutual electrical mutual exclusion and past induction electrode 3,4 respectively, electric conductor 7 and 8 The area in region existing for front end becomes larger.It is, the area for generating the region of ion becomes larger, with acicular discharge electrode phase Compared with ion generation amount when applying identical voltage increases.
In the refrigerator 100 or ion generation unit 110 of this implementation form, do not carry to be released to refrigerating space 104 The fan of ion.It can inhibit the drying of ingesta to the ingesta in refrigerating space 104 since wind will not be blowed as a result,. On the other hand, the cation and anion that the electric conductor 7,8 in the front end of discharge electrode 1,2 generates will not be past because of the wind-force of fan Refrigerating space 104 discharges, therefore is not easy to spread over making two uniform ions of cation and anion wide in refrigerating space 104 Range.
However, in the refrigerating space 104 of this implementation form, by the potential change of the plate 120 of electric conductivity, such as Fig. 8 institute Show, cation and anion are not easy deviation.As a result, can high efficiency except degerming or make its deactivation.
More specifically, as shown in figure 26, in general refrigerator, positive or negative clump cluster ion is spread because of free convection etc. When, by the electriferous state of wall material, cause repulsion between clump cluster ion and wall surface according to Coulomb's law.Wall material one As for mostly using the electrical insulating properties substance such as resin, hardly cause movement of the charge in wall surface, therefore electriferous state It is different in the everywhere of wall surface, as a result, shortcoming cation is with anion in the balanced of the everywhere of wall surface, degerming ability drop It is low.However, due to configuring conductive plate 120 in 104 bottom of refrigerating space, being configured with and leading in this implementation form The bottom of electrical plate 120, can be not dependent on the electriferous state of everywhere and keep the current potential of bottom identical.Therefore, can change Be apt to the locality of bottom cation and anion it is unbalanced.
In this implementation form, further also improves the whole cation near the bottom in refrigerating space 104 and bear Ion it is unbalanced.It is, assuming near the bottom in refrigerating space 104 there are when more cation, more cation It is obtained by the plate 120 of electric conductivity, the plate 120 of electric conductivity is positively charged.When the plate 120 of electric conductivity is positively charged, to anion Attraction increase, and to the repulsion of cation increase.Therefore, more anion is attracted to the bottom in refrigerating space 104 Near.In addition, more anion is by the plate of electric conductivity there are when more anion near the bottom in refrigerating space 104 120 obtain, and the plate 120 of electric conductivity is negatively charged.When the plate 120 of electric conductivity is negatively charged, the attraction of cation is increased, and The repulsion of anion is increased.
Therefore, near the plate of electric conductivity 120, cation or anion are easy balancedly to exist, and can pass through cation With the removing or deactivation reacting high efficiency and carry out bacterium of anion.
Furthermore preferably upper box 104A or lower box 104B does not include pigment such as titanium oxide or carbon etc. or makes this etc. less.? Be exactly that preferably the component near refrigerating space 104 itself or refrigerating space 104 easily becomes electrical neutrality, do not have due to The polarity of molecular configuration.The side wall that can inhibit as a result, in the upper box 104A or lower box 104B of the plate 120 that electric conductivity is not configured is attached Close cation and anion it is unbalanced.
(the second implementation form)
It is in first embodiment, the configuration of plate 120 of electric conductivity is whole in the bottom surface of the lower box 104A of refrigerating space. However it is not limited to such composition.For example, as shown in figure 9, before plate 120 also can be only fitted to the bottom surface of refrigerating space 104 Portion side.In addition, as shown in Figure 10, the plate 120Y of electric conductivity also can be only fitted to before refrigerating space 104.
Since ion is not easy to reach the region far from ion generation unit 110, have the tendency that ionic weight tails off.Cause This can improve the unevenness of cation and anion by configuring the plate of electric conductivity in the region far from ion generation unit 110 Weighing apparatus, even therefore less ionic weight can also be with high efficiency except degerming or make its deactivation.On the other hand, due to ionic weight It is abundant in the close region from ion generation unit 110, therefore even if generating the unbalanced of cation and anion, it can also be for Using with except degerming or make the sufficient cation of its deactivation and two ions of anion.Therefore, implement compared to first Form can reduce the usage amount of the plate 120 of electric conductivity.
Alternatively, as shown in figure 11, can also be arranged the plate of two electric conductivity in the lower box 104A of refrigerating space 122A,122B.In addition it is also possible to the size of refrigerating space 104 is cooperated to be arranged the plate 122A of multiple electric conductivity, 122B ..., the plate 122A, 122B ... of multiple electric conductivity that can also overlap.
Alternatively, as shown in figure 12, the dish 123A of one or more electric conductivity can also be configured in refrigerating space 104, 123B ... etc..It can be easy the equal of the cation and anion that keep configuration around the ingesta on dish 123A, 123B ... as a result, Weighing apparatus.
In this way, the plate as electric conductivity, can not be biggish a piece of plate, therefore can reduce cost.In addition, even leading When electrical plate takes out food together, the feelings for removing the plate of electric conductivity are wanted in the plate pollution or damage of electric conductivity Shape, without taking out all food of refrigerating space 104.
(third implementation form)
Furthermore for example, as shown in figure 13, the plate 120X of electric conductivity may be the bottom surface and front for covering lower box 104A The side view L-shaped of lower part.Furthermore as shown in figure 14, the plate 120Z of electric conductivity may be cover the bottom surface of lower box 104A with The side view U-shaped of front lower and lower backside.
Alternatively, as shown in figure 15, it can also be in the bottom surface of refrigerating space 104 and the plate of every one side configuration electric conductivity above Part 120,120B.The all areas that may extend over refrigerating space 104 as a result, are easy to keep cation balanced with anion.
Furthermore it as shown in figure 16, can also be configured in the bottom surface of refrigerating space 104 and above with every one side of side conductive The plate 120,120B, 120C, 120D of property.The all areas that may extend over refrigerating space 104 as a result, are easy to keep cation and bear The equilibrium of ion.
As above-mentioned, in this implementation form, compared to first embodiment, have to the height being stored in refrigerating space 104 The effect that the food in degree direction can also keep cation balanced with anion.
(the 4th implementation form)
In first~third implementation form, in the conductive plate 120 of refrigerating space 104.However it is not limited to Such composition.For example, as shown in figure 17, the mesh members 127 of electric conductivity can also be configured in refrigerating space 104.In addition, It can be the slit-shaped component of electric conductivity.Furthermore conductive film can also be configured in the face for forming refrigerating space 104.
(the 5th implementation form)
In addition, as shown in figure 18, the plate 120 of electric conductivity or mesh members 127 can also be electrically connected to ion production The secondary winding side of raw unit 110.More specifically, the plate of electric conductivity 120 or mesh members 127 etc. are penetrated into connector The intermediate potential for the secondary side that the induction electrodes 3,4 for being electrically connected at ion generation unit 110 such as 119 wait.It can make conduction as a result, The plate 120 of property or the current potential of mesh members 127 are relative to the ion stabilized in intermediate potential of generation.Therefore, refrigerating space 104 Interior electric field is stablized, and may extend over wide region and is easy to keep cation balanced with anion.
Furthermore it is preferred that the plate 120 or mesh members 127 of electric conductivity are the earthing potential of refrigerator 100.Additionally, it is preferred that door When 102L, 102R are opened, the plate 120 of electric conductivity or the secondary winding side of mesh members 127 and ion generation unit 110 are cut off Electric connection.At this point, the driving of more preferably ion generation unit 110 also stops.User can be excluded as a result, contacts electric conductivity Plate 120 or mesh members 127 and a possibility that get an electric shock.
(the 6th implementation form)
In the first~the 5th implementation form, the conductive plate 120 in refrigerating space 104.However, and unlimited In such composition.As shown in figure 19, can also in refrigerating space 104 in outer, for example main refrigerating space 103 with refrigerating space The plate 124X of the position configuration electric conductivity of the bottom surface opposite direction of lower box 104A.
Alternatively, as shown in figure 20, also the plate 124Y of electrically conductive property constitutes a part of the lower box 104Y of refrigerating space Such as a part etc. of bottom surface or front or upper box 104B.
Alternatively, as shown in figure 21, can also make conductive material be mixed into refrigerating space lower box 104Z or upper box 104B and Molding.
(the 7th implementation form)
In the first~the 6th implementation form, the conductive plate 120 in refrigerating space 104.However, and unlimited In such composition.As shown in figure 22, can also configure to make cold air do not circulate directly the vegetables accommodating space 106 being preferred or The ion generation unit 110B of the supply ion of fruit accommodating space 107.Ion generation unit 110B do not use yet fan will just from Son is supplied to vegetables accommodating space 106 or fruit accommodating space 107 with anion.This situation, preferably in vegetables accommodating space 106 Or fruit accommodating space 107 configures the plate 120 etc. of electric conductivity.
In addition, of course, the position of vegetable box or fruit box is not limited to form shown in FIG. 1, for example, such as Figure 23 institute Show, vegetables accommodating space 106 or fruit accommodating space 107 can also be located in main refrigerating space 103.
(the 8th implementation form)
In addition, can also more preferably supply main refrigerating space 103 shown in FIG. 1 or reefer space 105 or ice storage capacity 108 Answer ion.Cation and anion can also be blown into together with cold air using fan to the region.It is more detailed referring to Fig. 2 and Figure 24 It is illustrated.In addition, Figure 24 is the rearview of the refrigerator pipe 131 of this implementation form.
In this implementation form, the channel of the main cold air flowed by fan 132 on the way, the lower part of such as refrigerator pipe 131 Deng configuration ion generation unit 110C.As a result, by the air-supply of fan 132, by cold air and cation and anion from blow-off outlet 131X is blown into main refrigerating space 103 or reefer space 105.On the other hand, about refrigerating space 104 or vegetables accommodating space 106 Or fruit accommodating space 107, be not blown into cold air directly, that is, stable market supply on one side indirect cooling while cation and bear from Son.
(the 9th implementation form)
In the first~the 8th implementation form, as cold storage plant, it is illustrated by taking home-use refrigerator 100 as an example. However, the present invention is not limited thereto, kind is constituted.For example, as shown in figure 25, the bunker that people can enter the size of degree is also sharp With the technology of the first~the 8th implementation form.
It more specifically, can also be in the plate 125,125 ... of frame body 251,251 ... the mounting electric conductivity of mounting reserve Or mesh members 127.Surrounding that the cation and anion supplied as a result, from ion generating apparatus 210 can be in frame bodies 251,251 ... Equilibrium exists.
In addition to this, bunker can also be drawer, cabinet or the wardrobe in kitchen etc..
(the tenth implementation form)
About the ion generation unit 110 of above-mentioned implementation form, as described below, by being combined with surrounding composition, Achievable electric conductor is housed in the ion generating apparatus 1100 of regulation receiving area.Hereinafter, for convenience of explanation, by first to 110 ontology of ion generation unit of nine implementation forms is known as ion generation unit 110, by 110 ontology of ion generation unit and its The system of surrounding constituted altogether is known as ion generating apparatus 1100.
The ion generating apparatus 1100 of this implementation form, for example, being equipped on an example as collecting storage facility shown in Figure 27 Refrigerator 100.In addition, collecting storage facility can be drawer, micro-wave oven, cabinet or the wardrobe in kitchen etc..The collecting storage facilities such as refrigerator 100, it is general and Speech has ontology 101 and door 102.
The food storing space 103 of the configuration of ion generating apparatus 1100 refrigerator 100 shown in Figure 28.For example, ion produces Generating apparatus 1100 configures at the back side or fruit box (fruit of the back side of food storing space 103 or refrigerating box (refrigerating space) 104 Space) 107 back side or the back side etc. of vegetable box (vegetables space) 106, in food storing space 103 or in refrigerating box 104 Or ion is supplied in fruit box 107 or in vegetable box 106.
Figure 29 is the side sectional view for indicating the ion generating apparatus 1100 and drawer 109 of this implementation form.Figure 30 is table Show the side profile enlarged drawing near the ion generating apparatus 1100 of this implementation form.The ion generating apparatus of this implementation form 1100, as shown in Figure 29 and Figure 30, mainly it is made of installation space 113, ion generation unit 110, recess portion 114.Ion generates Unit 110 has brush electrode 112.
Installation space 113, for example, being formed in the back side of the food storing space 103 of refrigerator 100.The food of installation space 113 The end of 103 side of product storage space becomes the ejiction opening 113X for the ion that brush electrode 112 generates.
The configuration of ion generation unit 110 is in 113 inside of installation space.Ion generation unit 110, which has, is used as discharge electrode Brush electrode 112 and induction electrode (not shown) and circuit substrate etc..Generated between brush electrode 112 and induction electrode from Son.The ion of generation is sprayed by diffusion from ejiction opening 113X toward food storing space 103.
In addition, the composition of ion generation unit 110 and being not particularly limited, such as composition described in Patent Document 2 can be used Deng.It is, brush electrode 112 has the electric conductor (referred to as brushing) of multiple filiforms of its front end and is bundled multiple electric conductors Root member joint portion.Electric conductor is made of such as metal, carbon fiber, and preferably outer diameter is 5 μm or more 30 μm or less.In addition, excellent Select electric conductor from the prominent 3mm or more in joint portion.
Between the ejiction opening 113X and ion generation unit 110 of installation space 113, it is formed with recess portion 114 downward. Furthermore it is preferred that the length of the more Filamentous electric conductor of the depth H of recess portion 114 is long.For example, it is preferable to which recess portion 114 is compared with 3~4mm depth.
This reason it is assumed that electric conductor falls off from brush electrode 112, can also be fallen toward receiving area i.e. recess portion 114.Also It is that can accommodate electric conductor in regulation receiving area.
(the 11st implementation form)
In this implementation form, as shown in figure 31, other than the ion generating apparatus 1100 of the tenth implementation form, in ejiction opening Setting brush passes through preventing portion 115 between 113X and brush electrode 112.Brush is by preventing portion 115 by the structures such as mesh or net or slit At.It is preferred that brush is located near ejiction opening 113X by preventing portion 115.User can be prevented by preventing portion 115 by brush as a result, Unexpected contact brush electrode 112.
Brush passes through the size in the gap of preventing portion 115, and preferably short compared with the length of electric conductor and ion is easy the size passed through. For example, preferably counting mm degree, more preferable 4mm or less 2mm or more.
This reason it is assumed that electric conductor falls off from brush electrode 112, it can also be further decreased and be led by preventing portion 115 by brush A possibility that electric body is mobile outside toward regulation receiving area.
(the 12nd implementation form)
In this implementation form, as shown in figure 32, in addition to the tenth or the 11st implementation form ion generating apparatus 1100 other than, Brush facies posterior hepatis 116 is set near ejiction opening 113X.Brush facies posterior hepatis 116, surface is by Magic Tape (registered trademark) etc. Hair side or stick together band etc. stick together face etc. composition.
In addition, when electric conductor is compliant metal magnetite can also be configured inside 113 surface of installation space or its.Alternatively, A possibility that electric conductor is electrification when high specification, charge can also be applied to 113 bottom surface of installation space.
This reason it is assumed that electric conductor falls off from brush electrode 112, electric conductor can also be further decreased by brush facies posterior hepatis 116 A possibility that mobile outside toward regulation receiving area.
In addition, brush facies posterior hepatis 116 is not limited to be located at 113 bottom surface of installation space, may be alternatively provided at 113 side of installation space or Top surface.
Alternatively, brush facies posterior hepatis 116 may be alternatively provided at the side or bottom surface of recess portion 114.It can reduce as a result, and fall into recess portion 114 Electric conductor again returns to a possibility that installation space 113, as a result, electric conductor can be further decreased toward shifting outside regulation receiving area A possibility that dynamic.
(the 13rd implementation form)
In this implementation form, as shown in figure 33, in addition to the ion generating apparatus 1100 of the tenth~the 12nd implementation form Outside constituting, the ion generation unit 110 of ion generating apparatus 1100 is fixed on 101 side of ontology of refrigerator 100, generates dress with ion The recess portion 114 for setting 1100 is easy the mode vibrated relative to the ontology 101 of refrigerator 100, and recess portion 114 is through the equal installation of spring 117 In ontology 101.
As a result, for example, the wall surface of food storing space 103 is touched at the back side of drawer 109, recess portion when drawer 109 etc. are closed 114 are easy vibration.As a result, the electric conductor for being attached to 114 top of recess portion is easy to fall into 114 bottom surface of recess portion, can reduce fall into it is recessed The electric conductor in portion 114 again returns to a possibility that installation space 113, accommodates as a result, electric conductor can be further decreased toward regulation A possibility that mobile outside region.
On the contrary, as shown in figure 34, or the recess portion 114 of ion generating apparatus 1100 is fixed on the sheet of refrigerator 100 101 side of body is easy the side of vibration with the ion generation unit 110 of ion generating apparatus 1100 relative to the ontology 101 of refrigerator 100 Formula, ion generation unit 110 or installation space 113 are mounted on ontology 101 through spring 117 etc..
As a result, for example, the wall surface of food storing space 103 is touched at the back side of drawer 109 when drawer 109 etc. are closed, setting Space 113 or ion generation unit 110 are easy vibration.As a result, being located at leading for installation space 113 or ion generation unit 110 Electric body is easy to fall into recess portion 114, as a result, a possibility that electric conductor is mobile outside toward regulation receiving area can be further decreased.
Alternatively, as shown in figure 35, or with the installation space 113 and ion generation unit of ion generating apparatus 1100 110 are easy the mode of vibration with recess portion 114 relative to the ontology 101 of refrigerator 100, and installation space 113 and recess portion 114 penetrate spring 117 etc. are mounted on ontology 101.
As a result, for example, the wall surface of food storing space 103 is touched at the back side of drawer 109 when drawer 109 etc. are closed, setting Space 113 or ion generation unit 110 or recess portion 114 are easy vibration.As a result, being located at installation space 113 or ion generation list The electric conductor of member 110 is easy to fall into recess portion 114, and the electric conductor positioned at 114 top of recess portion is also easy to fall into 114 bottom surface of recess portion, can Further decrease a possibility that electric conductor is mobile outside toward regulation receiving area.
(the 14th implementation form)
In this implementation form, as shown in figure 36, it is anti-that there is ion generating apparatus 1100 brush of the 11st implementation form to pass through The brush facies posterior hepatis 116 of stop 115 and the 12nd implementation form, but not formed recess portion 114.
This reason it is assumed that electric conductor falls off from brush electrode 112, it can also by preventing portion 115 and brush facies posterior hepatis 116 by brush Stop electric conductor in advance.Therefore, just in case electric conductor falls off from brush electrode 112, the electric conductor can also be reduced and accommodated toward regulation A possibility that mobile outside region.
(the 15th implementation form)
In addition it is also possible to which the bottom surface for substituting the slave installation space 113 to form the tenth implementation form is further arranged toward lower section Recess portion 114, pass through preventing portion from the bottom surface of installation space 113 toward the brush that top is arranged using shown in Figure 37 and Figure 38 115B。
In other words, the brush of the 11st implementation form can also be substituted by covering ejiction opening 113X's as preventing portion 115 Whole components, the brush using the lower part of covering ejiction opening 113X pass through preventing portion 115B.
It is, be not limited to recess portion 114, between brush electrode 112 and ejiction opening 113X setting compared with brush electrode 112 with Both ejiction opening 113X low space.It can reach effect identical with recess portion 114 as a result,.
(the 16th implementation form)
In tenth to the 15th implementation form, horizontal arrangement ion generation unit 110 or brush electrode 112, but and it is unlimited In such form.In this implementation form, as shown in Figure 39 and Figure 40, ion generation unit 110 is in 113 downward vertical of installation space Configuration, brush electrode 112 configure upward.
More specifically, for example, as shown in figure 39, can also be formed in the side ejiction opening 113X of ion generation unit 110 Recess portion 114B.In this way, can be dropped if forming the recess portion 114B that electric conductor stops between brush electrode 112 and ejiction opening 113X A possibility that low electric conductor is mobile outside toward regulation receiving area.
Alternatively, as shown in figure 40, brush facies posterior hepatis 116 can also be arranged between brush electrode 112 and ejiction opening 113X.? It is exactly, it is assumed that electric conductor falls off from brush electrode 112, can also further decrease electric conductor by brush facies posterior hepatis 116 and receive toward regulation Hold a possibility that mobile outside region.
Furthermore as shown in figure 41, or ion generation unit 110 is configured in 113 upper vertical of installation space, brush Electrode 112 configures downward.In addition, such as the tenth implementation form, it can also be using the electric conductor to fall off from brush electrode 112 The composition of recess portion 114 is fallen into, shape can also be implemented by preventing portion 115 or the 12nd using the brush by the 11st implementation form The brush facies posterior hepatis 116 of state interferes electric conductor toward composition mobile outside regulation receiving area.
(the 17th implementation form)
In order to reduce a possibility that moving outside from the electric conductor that brush electrode 112 falls off toward regulation receiving area, can also adopt It is constituted with other.For example, as shown in figure 42, by making ejiction opening 113Y from horizontally toward top, electric conductor can be reduced toward regulation A possibility that mobile outside receiving area.
Alternatively, it is also possible in ejiction opening 113Y frosting, pass through the moisture X of wall surface by being constituted ejiction opening 113Y with metal Or the moisture Y fallen from wall surface, so that electric conductor Z is fallen into recess portion 114,114B or is not easy electric conductor Z from recess portion 114, the bottom 114B Face raises, and thus reduces a possibility that electric conductor Z is mobile outside toward regulation receiving area.
(the 18th implementation form)
In addition, brush electrode 112 is not limited to level or towards vertical direction or the composition of vertical lower, such as Figure 43 institute Show, oblique can also configure.
(summary)
In above-mentioned implementation form, cold storage plant 100,200 has: the first ion generation unit 110,110B, to receive to first Hold space 104,106,107 and supplies ion;And first electric conductor 120, configuration the first accommodating space 104,106,107 extremely Near few bottom or bottom.
The ion for being preferred from the first ion generation unit 110,110B does not utilize fan and is provided to the first receiving sky Between 104,106,107.
It is preferred that the composition of cold storage plant 100,200, to not being blown into cold air directly in the first accommodating space 104,106,107, The first accommodating space 104,106,107 is cooled down indirectly via the box body 104A, 104B that constitute the first accommodating space 104,106,107 It is interior.
It is received it is preferred that the second accommodating space 103 or setting are arranged around the first accommodating space 104,106,107 with first Hold the second different accommodating space 103 of space 104,106,107.Cold storage plant 100,200 is further equipped with to receive to second Hold the second ion generation unit 110C that ion is supplied in space 103.Ion from the second ion generation unit 110C utilizes wind Fan is provided to the second accommodating space 103.
Preferably further have configuration the upper surface of first accommodating space 104,106,107 or above near second conduction Body 120B.
It is preferred that other conductive components of the first electric conductor 120 and cold storage plant 100,200 are not conductively connected.
It is preferred that the first electric conductor 120 is connected to the secondary side of the first ion generation unit 110,110B.
In above-mentioned implementation form, the ion generating apparatus 1100 to storage space supply ion is provided.Ion generating apparatus 1100 have with to generate the brush electrode 112 of ion ion generation unit 110 and to by ion toward storage space The ejiction opening 113X, 113Y of ejection.Formed between brush electrode 112 and ejiction opening 113X, 113T be recessed downward it is recessed Portion 114,114B accommodates the electric conductor to fall off from brush electrode 112.
It is preferred that being formed between 113Y to make to lead from what brush electrode 112 fell off in brush electrode 112 and ejiction opening 113X The facies posterior hepatis 116 of electric body Z attachment.
It is preferred that configuration prevents the electric conductor Z to fall off from accommodating toward regulation between 113Y in brush electrode 112 and ejiction opening 113X The component 115 moved outside region.
It is preferred that in the accommodating container 109 of storage space configuration drawer type.Pass through the accommodating container when closing accommodating container 109 109 a part abuts, and recess portion 114,114A can vibrate.
It is preferred that brush electrode 112 is towards approximate horizontal or approximately below configure.
Additionally, it is provided the refrigerator 100 equipped with above-mentioned ion generating apparatus 1100.
The implementation form for being considered as this specification announcement is all to illustrate rather than be used to limit in all respects.Model of the invention Enclose not as shown in above description but as shown in claim, be intended to comprising with claim equalization meaning And being had altered in range.In addition, the composition for the different implementation forms that this specification illustrates is constituted obtained by being combined with each other Included in scope of the invention.
[description of symbols]
1 discharge electrode
2 discharge electrodes
3 induction electrodes
4 induction electrodes
5 printed base plates
The hole 5a
The hole 5b
6 printed base plates
7 electric conductors
The joint portion 7a
8 electric conductors
The joint portion 8a
30 power circuits
31 step-up transformers
31a is once wound
31b bis- times windings
32 diodes
33 diodes
100 refrigerators
101 ontologies
102
102L
102R
103 main refrigerating spaces (food storing space)
104 refrigerating spaces (refrigerating box)
Box under 104A
The upper box of 104B
The opening portion 104X
Box under 104Y
Box under 104Z
105 reefer spaces
106 vegetables accommodating spaces (vegetable box)
107 fruit accommodating spaces (fruit box)
108 ice storage regions
109 drawers
1100 ion generating apparatus
110 ion generation units
110B ion generation unit
110C ion generation unit
112 brush electrodes
113 installation spaces
113X ejiction opening
113Y ejiction opening
114 recess portions
114B recess portion
115 brushes pass through preventing portion
1150 slits
116 brush facies posterior hepatis
117 springs
118 liners
119 connectors
120 plates
120A plate
120B plate
120C plate
120D plate
120X plate
120Y plate
120Z plate
121 mesh members
122A plate
122B plate
123A dish
123B dish
124X plate
124Y plate
125 plates
127 mesh members
131 refrigerator pipes
132 fans
200 refrigerating chambers
210 ion generating apparatus
251 frame bodies
X, Y water
Z electric conductor (brush)

Claims (13)

1. a kind of cold storage plant, has:
First ion generation unit, to supply ion to the first accommodating space;And
First electric conductor configures near at least bottom or bottom of first accommodating space.
2. cold storage plant as described in claim 1, which is characterized in that the ion from first ion generation unit Fan is not utilized and is provided to first accommodating space.
3. cold storage plant as claimed in claim 2, which is characterized in that cold to not being blown into directly in first accommodating space Gas cools down in first accommodating space indirectly via the box body for constituting first accommodating space.
4. cold storage plant as claimed in claim 2 or claim 3, which is characterized in that be arranged second around first accommodating space Second accommodating space different from first accommodating space is arranged in accommodating space;
It is further equipped with to the second ion generation unit to second accommodating space supply ion;
The ion from second ion generation unit is provided to second accommodating space using fan.
5. cold storage plant according to any one of claims 1 to 4 is further equipped with configuration in first accommodating space The upper surface of or above near the second electric conductor.
6. the cold storage plant as described in any one of claims 1 to 5, which is characterized in that first electric conductor with it is described cold Other conductive components of hiding device are not conductively connected.
7. such as cold storage plant described in any one of claims 1 to 6, which is characterized in that the first ion generation unit tool There is step-up transformer, the step-up transformer has the primary winding of connection power supply and boosts into the voltage of the power supply For the secondary winding of discharge voltage;
First electric conductor is connected to the secondary winding.
8. a kind of ion generating apparatus supplies ion to storage space, which is characterized in that have:
Ion generation unit has the brush electrode to generate ion;And
Ejiction opening, to spray the ion toward the storage space;
The accommodating area for the electric conductor that receiving falls off from the brush electrode is equipped between the brush electrode and the ejiction opening Domain.
9. ion generating apparatus as claimed in claim 8, which is characterized in that between the brush electrode and the ejiction opening Form the facies posterior hepatis to make the electric conductor attachment to fall off.
10. ion generating apparatus as claimed in claim 8 or 9, which is characterized in that in the brush electrode and the ejiction opening Between configuration prevent the electric conductor to fall off toward the component flowed out outside the receiving area.
11. the ion generating apparatus as described in any one of claim 8 to 10, which is characterized in that in the storage space Configure the accommodating container of drawer type;
It is abutted by a part of the accommodating container described when closing the accommodating container, the recess portion can vibrate.
12. the ion generating apparatus as described in any one of claim 8 to 11, which is characterized in that the brush electrode direction It is approximate horizontal or configure approximately below.
13. a kind of collecting storage facility, equipped with ion generating apparatus described in any one of claim 8 to 12.
CN201780053632.6A 2016-12-14 2017-08-31 Refrigerator, ion generator, and storage Active CN110088543B (en)

Applications Claiming Priority (5)

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JP2016-242077 2016-12-14
JP2016242077 2016-12-14
JP2017077637 2017-04-10
JP2017-077637 2017-04-10
PCT/JP2017/031396 WO2018109989A1 (en) 2016-12-14 2017-08-31 Refrigeration device, ion generation device, and storage

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CN110088543B CN110088543B (en) 2021-02-09

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JP7049040B2 (en) 2019-12-21 2022-04-06 株式会社ケンエー Discharge brush electrode and method for manufacturing the discharge brush electrode
KR102289370B1 (en) * 2021-04-26 2021-08-11 이준석 Refrigerator equipped with a vegetable box grounding function

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TWI661843B (en) 2019-06-11
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WO2018109989A1 (en) 2018-06-21
JP6824286B2 (en) 2021-02-03
TW201821113A (en) 2018-06-16

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