CN110079741A - A kind of armour plate and its manufacturing method - Google Patents

A kind of armour plate and its manufacturing method Download PDF

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Publication number
CN110079741A
CN110079741A CN201910529738.XA CN201910529738A CN110079741A CN 110079741 A CN110079741 A CN 110079741A CN 201910529738 A CN201910529738 A CN 201910529738A CN 110079741 A CN110079741 A CN 110079741A
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CN
China
Prior art keywords
plate
quenching
uncoiling
intensity
bell
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910529738.XA
Other languages
Chinese (zh)
Inventor
刘志璞
苗隽
赵迪
闵洪刚
周晏锋
张城铭
徐勇
崔洪涛
吴刚
许学利
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Bengang Steel Plates Co Ltd
Original Assignee
Bengang Steel Plates Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bengang Steel Plates Co Ltd filed Critical Bengang Steel Plates Co Ltd
Priority to CN201910529738.XA priority Critical patent/CN110079741A/en
Publication of CN110079741A publication Critical patent/CN110079741A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18Hardening; Quenching with or without subsequent tempering
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/26Methods of annealing
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/74Methods of treatment in inert gas, controlled atmosphere, vacuum or pulverulent material
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0226Hot rolling
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/42Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/50Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/54Ferrous alloys, e.g. steel alloys containing chromium with nickel with boron

Abstract

The invention belongs to steelmaking technical fields, more particularly to a kind of armour plate and its manufacturing method, high intensity and high tenacity are obtained by quenching plus tempering, and by bell-type annealing to reduce hot rolled coil intensity after normal hot rolling, be conducive to later period uncoiling and shaping, then keep good plate shape through press quenching processing.Using bullet proof steel produced by the invention, enterprise's blank is filled up, increases rolling shapes, realizes higher final product quality and yield rate, there is good economic benefit.

Description

A kind of armour plate and its manufacturing method
Technical field
The invention belongs to steelmaking technical fields, and in particular to a kind of armour plate and its manufacturing method.
Background technique
Armour plate can divide two major classes by its production technology at present: one kind is hot rolled steel plate, with Sweden Swedish Steel The Domax Protect (Defend) 250 and 300 of AB (SSAB) company is representative, and this kind of steel plate, which removes, has good shellproof function Can be outer, processing performance, solderability and cold-bending property are good, and tensile strength is greater than 900 MPa, generally less than 1 000 MPa; It is another kind of to pass through heat treatment after the hot rolling of this kind of steel plate system using the Domax500 of SSAB company, Sweden as representative for heat-treated steel plate It quenches and meets intensity requirement, intensity is high, typically larger than 1500 MPa, but processing performance, solderability and cold-bending property are remote Not as good as hot rolling class steel plate.
As the situation is tense for domestic and international anti-terrorism, the demand of the armored vehicle with ballistic performance is increased year by year.In addition, The armor demand required for higher ballistic protection level is consequently increased.In daily life, in addition to this, some steel plates are also Need to be manufactured with the ballistic gate of shellproof, anti-shooting function, bulletproof halmet, flak jackets, missile-resistant shield, or for silver to be made Row sales counter, confidential safety cabinet, antiriot vehicle, ballproof cash truck, submarine, landing craft, revenue cutter, the bullet-proof member of the devices such as helicopter.
This patent main inventive develops a kind of lightweight high-intensity armour plate for armoured van, armoured van armour plate Meet A grades of level of protection in " dedicated armoured van guard technology condition " (GA 164-2005).Domestic generally use contains Gao Ge The disadvantages of Tempering and Quenching steel plate of nickel, but its there are intensity high, forming property and welding performance are poor, price.
Summary of the invention
Bullet proof steel production is primarily present following technical problem:
1. reducing smelting cost: using microalloy treatment, add alloying element less and realize reduction smelting cost.
2. hot rolled coil intensity is high: reducing hot rolled coil intensity using bell-type annealing processing, be conducive to uncoiling and press quenching is heat-treated.
3. good quenching back plate shape: using press quenching and tempering, keep good plate shape.
4. steel plate hot process uniformity problem: it is pressed using press quenching multiple spot and is being uniformly distributed cooling water jet, it is real The uniform cooling of existing steel plate.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of manufacturing method of armour plate obtains high intensity and high tenacity by quenching plus tempering, and Be conducive to later period uncoiling and shaping, then handle through press quenching to reduce hot rolled coil intensity by bell-type annealing after normal hot rolling Keep good plate shape.
Including following process flow:
Molten iron pretreatment → converter smelting → LF refining → RH refining → continuous casting → heating → 2300mm hot continuous rolling → control Cool down → batch → sample → function inspection → packaging is payed into the treasury → delivers
Uncoiling → cutting plate → pressure heat treatment (quenching+tempering) → inspection by sampling performance → is packed and stored → delivers
(1) according to ingredient standard lower limit strict control each element content, microalloying smelting is carried out;
(2) coil of strip intensity being reduced using bell-type annealing, bell-type annealing parameter setting is that coil of strip is heated to 680 DEG C or more, 8-10 hour of furnace inside holding, then furnace cooling;
(3) uncoiling shaping carries out uncoiling and shaping on 2250 uncoilers, cuts plate;
(4) press quenching is heat-treated, static pressure quenching heat treatment, is guaranteed that plate is heated cooling uniform, is kept good profile.
The high-strength armour plate of the tensile strength 1700MPa of the method preparation.
A kind of armour plate, chemical composition are calculated as with quality %: C 0.24-0.26, Si 0.4-0.44, Mn 1.15-1.20, Al 0.035-0.050, Ni 0.33-0.97, Cr 0.49-0.55, Mo 0.30-0.34, Cu0.26-0.33, Ti 0.022-0.026, B 0.0016-0.0020.
Beneficial effects of the present invention:
1700MPa high-strength hot-rolled armor plate of the invention is the excellent strength-toughness being had based on microalloy Multiphase Steel Match, coil of strip intensity is reduced using bell-type annealing, is conducive to uncoiling, cutting, using press quenching holding plate shape, realizes good plate Shape control and easy processing technology, armour have excellent processing performance, solderability, reduce production cost and plate is thick Degree, alternative previous thick and heavy armour plate, reaches light-weighted purpose.Ingredient design on, alloy content is lower, save at This;In mechanical property, indices reach requirement, and meet the expectation of user;Reasonable heat treatment process reduces the energy and disappears Consumption reduces cost, protects environment;Reasonable plate thickness guarantees that ballistic performance realizes lightweight and corrosion-resistant effect simultaneously.
Effect: (1) armour plate produced by this technique has excellent mechanical property and good cutting, welding Etc. processing performances, and have certain weather resistance, user actual use achievees the purpose that reduce car body weight, fully meet use The use demand at family.
(2) bullet proof steel produced by the invention is used, enterprise's blank is filled up, increases rolling shapes, is realized higher at quality Amount and yield rate have good economic benefit.
Detailed description of the invention
In order to facilitate the understanding of those skilled in the art, the present invention will be further described below with reference to the drawings.
Fig. 1 is 670 DEG C of hot rolled coil metallographic microscopes of the invention;
Fig. 2 is the metallographic microscope of 200 DEG C of lonneal tissues of the invention.
Specific embodiment
Embodiment 1
One, it makes steel
1, hot metal pre process procedures
It pre-processes into furnace S≤0.005%, P≤0.010% scratches clean slag;Using fine fodder steel scrap.
2, converter procedure
Converter catch carbon hit at first time avoids a little blowing;Ladle argon gas purging before tapping, control tapping hole avoid diffusing.
3, refining procedure
Using LF+RH dual path process, strict control is required to gas content.It is required that LF treatment process keeps micro-positive pressure, Strict control LF increases N, it is desirable that increases N amount≤10ppm;LF makes the reducing slag of good fluidity, strict control using active lime, fluorite Argon intensity avoids molten steel exposed as far as possible;Using silicon-calcium wire Calcium treatments, 500 meters of CaSi line are fed, the sufficient nodularization of field trash is made, Improve properties of product.
4, continuous casting working procedure
Whole process carries out molding casting.It opens using being wrapped in argon gas purging before pouring, casting process accomplishes that no molten steel is exposed, stringent to control N is inhaled at the mouth of a river processed, and control increases N≤5ppm;Using cinder inclusion in high alkalinity, so as to the removal of steel inclusion;Steel pouring process investment is light Press function;Steel pouring process keeps permanent pulling rate;The continuous casting degree of superheat controls target and is not more than 25 DEG C.Slab heat crosses hot charging, remaining plate Base is placed on Ku Nei slow cooling area.
Two, hot rolling
1, heating furnace part
1150~1250 DEG C of heating temperature, 1200~1250 DEG C of target tapping temperature.Heating furnace oven cavity atmosphere is controlled, is reduced The generation of slab iron scale guarantees that heating temperature is uniform.
2, rolling, reel-up
Waste mill train time selection 3+3 scheme control;The sharing of load of finish rolling model is carried out, guarantees rolling stability;Finish to gauge temperature Degree: >=890;Coiling temperature: >=650, refrigerating mode opens cold, discontinuous manner using second group.Guarantee the essence of finish to gauge, coiling temperature Really control;Optimize and revise the control of interstand cooling water.
Heat treatment
1, the heat treatment of perhydro bell-type annealing is carried out using this steel cold rolling mill bell-type annealing line.By coil of strip be heated to 680 DEG C with On, 8 and a half hours to 10 hours of furnace inside holding, then furnace cooling.
2, quenching+tempering processing is carried out using pressure quenching apparatus.The 890-930 DEG C of time of heating temperature: 2-3min/mm, 3-5min/mm between 180-220 DEG C of tempering temperature.
Comparison diagram 1,2 can be seen that the tissue morphology after 200 DEG C of lonneals in contrast to 670 DEG C of hot rolled coils in Fig. 1 Metallographic is changed.
Embodiment 2
It is as follows according to the component of five groups of steel plates of method described in embodiment 1 manufacture, preparation condition and intensive parameter:
Experimental result:
Present invention disclosed above preferred embodiment is only intended to help to illustrate the present invention.There is no detailed for preferred embodiment All details are described, are not limited the invention to the specific embodiments described.Obviously, according to the content of this specification, It can make many modifications and variations.These embodiments are chosen and specifically described to this specification, is in order to better explain the present invention Principle and practical application, so that skilled artisan be enable to better understand and utilize the present invention.The present invention is only It is limited by claims and its full scope and equivalent.

Claims (4)

1. a kind of manufacturing method of armour plate, which is characterized in that obtain high intensity and high-ductility by quenching plus tempering Property, and after normal hot rolling by bell-type annealing to reduce hot rolled coil intensity, be conducive to later period uncoiling and shaping, then through pressure Quenching treatment keeps good plate shape.
2. a kind of manufacturing method of armour plate according to claim 1, which is characterized in that
Including following process flow:
Molten iron pretreatment → converter smelting → LF refining → RH refining → continuous casting → heating → 2300mm hot continuous rolling → control is cooling → batching → sample → and function inspection → packaging is payed into the treasury → delivers
Uncoiling → cutting plate → pressure heat treatment (quenching+tempering) → inspection by sampling performance → is packed and stored → delivers
(1) according to ingredient standard lower limit strict control each element content, microalloying smelting is carried out;
(2) coil of strip intensity is reduced using bell-type annealing, bell-type annealing parameter setting is that coil of strip is heated to 680 DEG C or more, in furnace 8-10 hour is kept the temperature, then furnace cooling;
(3) uncoiling shaping carries out uncoiling and shaping on 2250 uncoilers, cuts plate;
(4) press quenching is heat-treated, static pressure quenching heat treatment, is guaranteed that plate is heated cooling uniform, is kept good profile.
3. the high-strength armour plate of the tensile strength 1700MPa prepared method according to claim 1.
4. a kind of armour plate according to claim 3, which is characterized in that its chemical composition is calculated as with quality %: C 0.24-0.26, Si 0.4-0.44, Mn 1.15-1.20, Al 0.035-0.050, Ni 0.33-0.97, Cr 0.49-0.55, Mo 0.30-0.34, Cu0.26-0.33, Ti 0.022-0.026, B 0.0016-0.0020.
CN201910529738.XA 2019-06-19 2019-06-19 A kind of armour plate and its manufacturing method Pending CN110079741A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
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Publications (1)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111118412A (en) * 2020-03-10 2020-05-08 晟普特(北京)防护科技有限公司 Bulletproof steel plate and heat treatment method thereof
WO2023213109A1 (en) * 2022-05-06 2023-11-09 中国机械总院集团北京机电研究所有限公司 Accurate heat treatment method for low-carbon low-alloy high-strength thin steel plate

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0501874A1 (en) * 1991-03-01 1992-09-02 Creusot-Loire Industrie Procedure for the manufacturing of a plate composite product, stainless armour and an armoured reservoir obtained by that procedure
CN1308144A (en) * 2000-12-25 2001-08-15 钢铁研究总院 High-performance impact resisting steel
CN104674121A (en) * 2015-03-10 2015-06-03 山东钢铁股份有限公司 Armor steel plate with high anti-bullet property and manufacturing method of armor steel plate
CN105088090A (en) * 2015-08-28 2015-11-25 宝山钢铁股份有限公司 Armor plate with tensile strength being 2000 MPa and manufacturing method thereof
CN106319347A (en) * 2016-10-27 2017-01-11 钢铁研究总院淮安有限公司 Silicon vanadium steel plate with promoted bulletproof performance and manufacturing method
CN108425070A (en) * 2018-05-22 2018-08-21 首钢集团有限公司 A kind of 1000MPa grades of shock wave resistance steel plate and its manufacturing method
CN109628835A (en) * 2018-12-31 2019-04-16 钢铁研究总院 One kind can cold roll forming high performance ballistic steel plate and its manufacturing process

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0501874A1 (en) * 1991-03-01 1992-09-02 Creusot-Loire Industrie Procedure for the manufacturing of a plate composite product, stainless armour and an armoured reservoir obtained by that procedure
CN1308144A (en) * 2000-12-25 2001-08-15 钢铁研究总院 High-performance impact resisting steel
CN104674121A (en) * 2015-03-10 2015-06-03 山东钢铁股份有限公司 Armor steel plate with high anti-bullet property and manufacturing method of armor steel plate
CN105088090A (en) * 2015-08-28 2015-11-25 宝山钢铁股份有限公司 Armor plate with tensile strength being 2000 MPa and manufacturing method thereof
CN106319347A (en) * 2016-10-27 2017-01-11 钢铁研究总院淮安有限公司 Silicon vanadium steel plate with promoted bulletproof performance and manufacturing method
CN108425070A (en) * 2018-05-22 2018-08-21 首钢集团有限公司 A kind of 1000MPa grades of shock wave resistance steel plate and its manufacturing method
CN109628835A (en) * 2018-12-31 2019-04-16 钢铁研究总院 One kind can cold roll forming high performance ballistic steel plate and its manufacturing process

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111118412A (en) * 2020-03-10 2020-05-08 晟普特(北京)防护科技有限公司 Bulletproof steel plate and heat treatment method thereof
WO2023213109A1 (en) * 2022-05-06 2023-11-09 中国机械总院集团北京机电研究所有限公司 Accurate heat treatment method for low-carbon low-alloy high-strength thin steel plate

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Application publication date: 20190802