CN110075667A - Exhaust treatment system - Google Patents

Exhaust treatment system Download PDF

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Publication number
CN110075667A
CN110075667A CN201910465712.3A CN201910465712A CN110075667A CN 110075667 A CN110075667 A CN 110075667A CN 201910465712 A CN201910465712 A CN 201910465712A CN 110075667 A CN110075667 A CN 110075667A
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CN
China
Prior art keywords
pipeline
gas
temperature
treatment system
exhaust treatment
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Granted
Application number
CN201910465712.3A
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Chinese (zh)
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CN110075667B (en
Inventor
吴天添
杨苏川
王云枫
徐新宇
李俐俐
秦伟
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Jiangsu Xinju Environmental Protection Technology Co Ltd
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Jiangsu Xinju Environmental Protection Technology Co Ltd
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Priority to CN201910465712.3A priority Critical patent/CN110075667B/en
Publication of CN110075667A publication Critical patent/CN110075667A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/06Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G7/00Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
    • F23G7/06Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases
    • F23G7/061Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases with supplementary heating
    • F23G7/063Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases with supplementary heating electric heating
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G7/00Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
    • F23G7/06Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases
    • F23G7/07Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases in which combustion takes place in the presence of catalytic material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708Volatile organic compounds V.O.C.'s
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2202/00Combustion
    • F23G2202/60Combustion in a catalytic combustion chamber
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2209/00Specific waste
    • F23G2209/14Gaseous waste or fumes

Abstract

The present invention provides a kind of exhaust treatment system, including sequentially connected first pretreatment unit, second pretreatment unit, zeolite runner, heat-exchange device, catalytic combustion system, the zeolite runner includes desorption area, the desorption area is connect by third pipeline with the heat-exchange device, second pretreatment unit includes outlet side and inlet end, the outlet side is connect with the heat-exchange device again after being connect by the 4th pipeline with the third pipeline, the inlet end is connect with waste gas inlet by pipeline and passes through lateral and is connected on the third pipeline, gas in the third pipeline enters the lateral, and then enter in the 4th pipeline, the residual temperature being had using desorption gas keeps the temperature the temperature in the 4th pipeline.The residual temperature for the organic gas that exhaust treatment system provided by the invention is desorbed out using the first pretreatment unit keeps the temperature the pipeline of the second pretreatment unit, and formaldehyde exhaust-gas can be effectively treated.

Description

Exhaust treatment system
Technical field
The present invention relates to waste gas purification field more particularly to a kind of exhaust treatment systems.
Background technique
Volatile organic compounds is a kind of common atmosphere pollution, results from paint production, chemical fibre industry, metal The industries such as coating, chemical coating, shoemaking process hides, plywood making, Tire production.Volatile organic compounds is divided into: alkanes, virtue Hydro carbons, esters, aldehydes and other etc..It is most common to have benzene,toluene,xylene, styrene, diisocyanate, two isocyanide toluene Ester, formaldehyde etc..Currently used method for gas purification includes absorption method, biological degradation method, combustion method.Wherein absorption method structure letter It is single, it is easy to use, but due to the special chemical performance of some pollutants, tube wall is attached to as formaldehyde is easy crystallization in low temperature On, current processing equipment can not be handled together the pollutant of different chemical characteristics, and other tables of equipment is needed to stay alone reason, be increased Cost and the time of processing volatile organic compounds are added.
Summary of the invention
In view of this, being capable of handling multiple gases, save the cost it is necessary to provide a kind of improved exhaust treatment system And the time.
The present invention provides a kind of exhaust treatment system, including sequentially connected first pretreatment unit, zeolite runner, heat are handed over Changing device, catalytic combustion system and the exhaust outlet being connect respectively with the zeolite runner and heat-exchange device by pipeline, it is described Zeolite runner includes desorption area, and the desorption gas gas outlet in the desorption area is connected by third pipeline and the heat-exchange device It connecing, the exhaust treatment system further includes the second pretreatment unit, and second pretreatment unit includes outlet side and inlet end, The outlet side is connect with the heat-exchange device again after being connect by the 4th pipeline with the third pipeline, and the inlet end is logical Piping connect with waste gas inlet and passes through lateral and is connected on the third pipeline, the desorption in the third pipeline Gas part enters in the lateral, and is entered in the 4th pipeline by second pretreatment unit, using de- The residual temperature that attached gas has keeps the temperature the temperature in the 4th pipeline.
Further, the 4th pipeline is equipped with temperature sensor, for sensing the temperature in the 4th pipeline.
Further, it is additionally provided with air inlet adjustment valve on the lateral, for what is sensed according to the temperature sensor Temperature adjusts the amount that desorption gas enters the 4th pipeline, and the temperature in the 4th pipeline is maintained at required range It is interior.
Further, the lateral is connected to the pipeline of the neighbouring waste gas inlet.
Further, pipeline heater, the pipeline heater and the temperature sensing are additionally provided on the 4th pipeline Device collaboration is for when second pretreatment unit works independently, guaranteeing the temperature in the 4th pipeline in required range It is interior.
Further, the third pipeline be equipped with desorption blower, the lateral be connected to the desorption blower and On the third pipeline between 4th pipeline.
Further, absorption blower, intake valve and check-valves are also successively arranged on the 4th pipeline, it is described for accelerating The flowing of 4th gas in pipelines avoids the initiation reflux that conflicts with the desorption gas in the third pipeline.
Further, the desorption blower and absorption blower with corresponding pipeline are to be flexible coupling, the noise elimination for blower Noise reduction and pipeline damping.
Further, the 4th pipeline is connect through branch line with the exhaust outlet, and described branch line one end position On the 4th pipeline between the absorption blower and intake valve, the branch line is equipped with drain valve.
Further, it is additionally provided with pipe insulation facility on the 4th pipeline, for preventing the temperature in the 4th pipeline Fast loss is spent, the temperature in pipeline is kept.
In above-mentioned exhaust treatment system, by setting, there are two waste gas inlet and pretreatment units, can handle more Kind of organic exhaust gas, the pipeline of the residual temperature of the organic gas for being desorbed out using the first pretreatment unit to the second pretreatment unit It is kept the temperature, formaldehyde exhaust-gas can be effectively treated, therefore, can handle a variety of organic exhaust gas and formaldehyde exhaust-gas, increased without additional If processing equipment, processing cost, faster processing time are saved.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of the exhaust treatment system in an embodiment of the present invention.
Main element symbol description
The present invention that the following detailed description will be further explained with reference to the above drawings.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other Embodiment shall fall within the protection scope of the present invention.
It should be noted that it can be directly on another component when component is referred to as " being installed in " another component Or there may also be components placed in the middle.When a component is considered as " being set to " another component, it, which can be, is directly set Set on another component or may be simultaneously present component placed in the middle.
Unless otherwise defined, all technical and scientific terms used herein and belong to technical field of the invention The normally understood meaning of technical staff is identical.Term as used herein in the specification of the present invention is intended merely to description tool The purpose of the embodiment of body, it is not intended that in the limitation present invention.Term as used herein " and/or " it include one or more phases Any and all combinations of the listed item of pass.
Referring to Fig. 1, exhaust treatment system 100 shown in Fig. 1 is for handling volatile organic compounds, the exhaust-gas treatment System 100 includes the first pretreatment unit 10 for passing sequentially through pipeline connection, zeolite runner 20, heat-exchange device 30 and catalysis combustion Device 40 is burnt, the exhaust treatment system 100 further includes the second pretreatment unit 50 connecting with the heat-exchange device 30, control System (not shown) processed and the row being connect respectively with the zeolite runner 20, heat-exchange device 30 and the second pretreatment unit 50 Port 60, the exhaust outlet 60 are used for the uncontaminated gases after emission treatment.
Described first pretreatment unit, 10 one end is connect through pipeline with the first waste gas inlet 11, the other end and the zeolite Runner 20 connects, and one end that first pretreatment unit 10 is connect with first waste gas inlet 11 is additionally provided with the first benefit wind Valve 13, the first benefit air-valve 13 are managed between first pretreatment unit 10 and first waste gas inlet 11 for controlling Adsorption capacity in road controls the flowing velocity of waste exhaust gases in pipeline with this.In one embodiment, the first pretreatment dress 10 are set as filter, the filter is bag filter.In one embodiment, first pretreatment unit 10 with it is described At least one piping filter is also set up on pipeline between first waste gas inlet 11, for reinforcing the filtering of pre-treatment step Effect.In one embodiment, on the pipeline between first pretreatment unit 10 and first waste gas inlet 11 also At least one diminishing separating device is set, for reducing the moisture in exhaust gas.
The zeolite runner 20 includes adsorption zone 21, cooling zone 22 and desorption area 23, and one end of the adsorption zone 21 passes through Pipeline is connect with first pretreatment unit 10.The other end of the adsorption zone 21 is connected by pipeline and the exhaust outlet 60 It connects, the pipeline between the adsorption zone 21 and the exhaust outlet is equipped with second and mends air-valve 211 and the first absorption blower 212, leads to It crosses the first absorption blower 212 and most of filtered exhaust gas is sent into the adsorption zone 21, by the adsorption zone 21 Zeolite adsorption filtration after exhaust gas in organic matter, reach discharge standard and by the exhaust outlet 60 to purify exhaust gas Discharge.It should be understood that pipeline can be arranged at least one on pipeline between the adsorption zone 21 and the exhaust outlet Filter is further to filter gas.
One end of the cooling zone 22 is connect with first pretreatment unit 10 by pipeline, and the other end is through first pipe 22a and second pipe 22b is connect with the heat-exchange device 30 and desorption area 23 respectively.It is successively set on the first pipe 22a There are cold air adjusting valve 221 and desorption blower 222, fire arrester 223 is successively arranged on the second pipe 22b, desorption cold wind is adjusted Valve 224 and wind-mixer 225 are also connected with lateral 22c, the connection of the one end the lateral 22c on the second pipe 22b In the wind-mixer 225, the other end is connected on the pipeline between the heat-exchange device 30 and exhaust outlet 60, the branched pipe Road 22c is equipped with desorption hot wind regulating valve 226.The one end in the desorption area 23 is connected to the cold wind tune through third pipeline 23a It saves on valve 221 and the pipeline being desorbed between blower 222, the other end is connect with second pipe 22b.The desorption cold air adjusting valve 224 are used to adjust the gas flow into the wind-mixer 225 with desorption hot wind regulating valve 226, are controlled with this into described de- The gas temperature in attached area 23, in one embodiment, the gas temperature are 190-220 DEG C.
The exhaust gas of fraction enters the cooling zone 22 after first pretreatment unit 10 filtering and carries out cooling drying, Then a part of exhaust gas enters the heat-exchange device 30 through the first pipe 22a and is heated, by the lateral 22c flows into the second pipe 22b, and another part exhaust gas is through the heating in the second pipe 22b and the lateral 22c Enter the desorption area 23 after exhaust gas mixing, the organic matter heating on the zeolite of adsorption saturation is desorbed out, restores zeolite Adsorption capacity, the high-concentration waste gas under being desorbed successively is sent through the third pipeline 23a to the heat by the desorption blower 222 to be handed over In changing device 30 and catalytic combustion system 40, burnt after becoming uncontaminated gases under the effect of the catalyst through the exhaust outlet 60 Discharge.
The heat-exchange device 30 is equipped with the first air inlet 30a, the first gas outlet 30b, the second air inlet 30c and second and goes out Port 30d, the first air inlet 30a are connect with the desorption blower 222 by pipeline, the first gas outlet 30b and institute It states exhaust outlet 60 to connect by pipeline, the pipeline between the first gas outlet 30b and the exhaust outlet 60 is equipped with drain valve 61, the drain valve 61 is used to control the discharge of gas, and one end of the lateral 22c is connected to first gas outlet On pipeline between 30b and drain valve 61.The second air inlet 30c and the second gas outlet 30d, which burns with the catalysis, to be filled Set 40 connections.High-concentration waste gas under specific desorption is through described in the third pipeline 23a and the first air inlet 30a entrance Heat-exchange device 30 carries out heat exchange, enters the catalytic combustion system 40 through the second gas outlet 30d, passes through after catalysis burning The second air inlet 30c enters the heat-exchange device 30, is discharged through the first gas outlet 30b, and most of gas passes through The exhaust outlet 60 is discharged, and small portion of gas enters the lateral 22c and uses as desorption gas.
The catalytic combustion system 40 is equipped with third air inlet 41 and third gas outlet 42, the third air inlet 41 and institute It states the second gas outlet 30d to connect by pipeline, the third gas outlet 42 is connect with the second air inlet 30c, the catalysis Burner 40 makes former exhaust gas become non-contaminated air, reaches under the effect of the catalyst decomposing the organic matter in gas To discharge standard.The catalytic combustion system 40 further includes electric heater 43, and the electric heater 43 is used to fire in the catalysis Burning device 40, just starting following period of time preheats it to reach ignition temperature standard, in one embodiment, the electricity The quantity of heater 43 is two, and ignition temperature is greater than 300 DEG C.
Second pretreatment unit 50 includes inlet end and outlet side, and the inlet end is through pipeline and the second gas inlet Mouth 51 connects, and the 4th pipeline 50a of outlet side is connected to the pipe between the desorption blower 222 and the first air inlet 30a On road, second pretreatment unit 50 is used to carry out primary filtration to exhaust gas, in one embodiment, second pretreatment Device 50 is bag filter.It is successively arranged temperature sensor 52, second on the 4th pipeline 50a and adsorbs blower 53, air inlet Valve 54, check-valves 55 and fire arrester 56.A branch is connected on pipeline between the second absorption blower 53 and intake valve 54 Pipeline 50b, the other end of the branch line 50b are connect with the exhaust outlet 60, and the branch line 50b is equipped with drain valve 57, the branch line 50b are used to mention when second pretreatment unit 50 is used alone for the catalytic combustion system 40 For preheating time.Second pretreatment unit 50 further includes lateral 50c, and one end of the lateral 50c is connected to On pipeline between second pretreatment unit 50 and the second waste gas inlet 51, the other end is connected to the desorption blower 222 and the 4th pipeline between pipeline 50a on, in one embodiment, the lateral 50c adjacent to second exhaust gas into Port 51 is arranged.The lateral 50c is used to for being passed through the organic gas part that the desorption area 23 desorption comes out described In 4th pipeline 50a, the residual temperature being had by the organic gas that desorption comes out carries out the temperature in the 4th pipeline 50a Heat preservation.The lateral 50c is equipped with air inlet adjustment valve 58, for adjusting the ratio for the organic gas for being desorbed out in turn Control the temperature in the 4th pipeline 50a.Specifically, the temperature sensor 52 is connect with control series, according to the temperature The temperature that sensor 52 senses is spent, the ratio of the air inlet adjustment valve 58 opened or closed is controlled by the control system, The temperature in the 4th pipeline 50a is kept with this.In one embodiment, formaldehyde is passed through in second waste gas inlet 51 Gas handles it, and because formaldehyde gas is easy crystallization in low temperature, adjusting the temperature in the 4th pipeline 50a keeps it big In 40 degree, in order to being further processed for subsequent step PARA FORMALDEHYDE PRILLS(91,95) gas.It should be understood that first pretreatment unit 10 can To handle the organic exhaust gas such as alkanes, aromatic hydrocarbons, esters, second pretreatment unit 50 can also handle the organic wastes such as styrene Gas.
In one embodiment, the 4th pipeline 50a is equipped with pipeline heater (not shown), the pipeline heater It is connect with control system, for keeping temperature, such as formaldehyde needed for handling special volatile organic matter in the 4th pipeline 50a Deng.The pipeline heater can be used in 50 isolated operation of the second pretreatment unit.
In one embodiment, the pipeline between the lateral 22c, the heat-exchange device 30 and drain valve 61, Pipeline between third pipeline 23a, the 4th pipeline 50a and the desorption blower 222 and the 4th pipeline 50a is equipped with pipe insulation Facility 70 keeps the temperature in pipeline for preventing the too fast loss of the temperature in pipeline, it is possible to understand that, pipe insulation is set The position of facility is not limited to the position in above embodiment, can according to need and is equipped with pipe insulation in other connecting pipes Facility.
In one embodiment, the first gas outlet 30b, catalytic combustion system 40,43 third pipeline 23a of electric heater And temperature sensor 80 is provided on wind-mixer 225 to the pipeline between desorption area 23, the temperature sensor 80 is used for The preheating of exhaust treatment system 100 and desorption stage guarantee that the temperature in corresponding pipeline and device reaches operation standard.? In one embodiment, the wind-mixer 225 to the pipeline between desorption area 23 is equipped at least two temperature sensors 80.It is described All control valves in temperature sensor 80 and exhaust treatment system 100 are connect with the control system, the control system The opening and closing united for controlling the control valve, and the temperature sensed according to temperature sensor 80, the control system control correspond to The opening and closing degree of control valve on pipeline guarantees the normal operation of the exhaust treatment system 100 with this.
It should be understood that the first absorption blower 212, desorption blower 222 and the second absorption blower 53 are soft with pipeline Connection is used for fan noise elimination noise reduction and pipeline damping.
Exhaust treatment system provided by the invention, there are two waste gas inlet and pretreatment units for setting, can handle more Kind of organic exhaust gas, the pipeline of the residual temperature of the organic gas for being desorbed out using the first pretreatment unit to the second pretreatment unit It is kept the temperature, formaldehyde exhaust-gas can be effectively treated, be not necessarily to additional processing equipment, save processing cost, in addition quickening is handled Time increases gas treatment amount, by the way that pipeline heater is arranged, equally can individually locate when the first pretreatment unit does not work Manage formaldehyde gas.
Those skilled in the art it should be appreciated that more than embodiment be intended merely to illustrate the present invention, And be not used as limitation of the invention, as long as in spirit of the invention, to made by embodiment of above Appropriate change and variation are all intended to fall within the scope of the claimed invention.

Claims (10)

1. a kind of exhaust treatment system, including sequentially connected first pretreatment unit, zeolite runner, heat-exchange device, catalysis Burner and the exhaust outlet being connect respectively with the zeolite runner and heat-exchange device by pipeline, the zeolite runner include Area is desorbed, the desorption gas gas outlet in the desorption area is connect by third pipeline with the heat-exchange device, it is characterised in that: The exhaust treatment system further includes the second pretreatment unit, and second pretreatment unit includes outlet side and inlet end, institute It states after outlet side is connect by the 4th pipeline with the third pipeline and is connect again with the heat-exchange device, the inlet end passes through Pipeline connect with waste gas inlet and passes through lateral and is connected on the third pipeline, the desorption gas in the third pipeline Body portion enters in the lateral, and is entered in the 4th pipeline by second pretreatment unit, utilizes desorption The residual temperature that gas has keeps the temperature the temperature in the 4th pipeline.
2. exhaust treatment system as described in claim 1, it is characterised in that: the 4th pipeline is equipped with temperature sensor, For sensing the temperature in the 4th pipeline.
3. exhaust treatment system as claimed in claim 2, it is characterised in that: be additionally provided with air inlet adjustment on the lateral Valve, the temperature adjustment desorption gas for being sensed according to the temperature sensor enter the amount of the 4th pipeline, will be described Temperature in 4th pipeline is maintained in required range.
4. exhaust treatment system as described in claim 1, it is characterised in that: the lateral is connected to the neighbouring exhaust gas The pipeline of air inlet.
5. exhaust treatment system as claimed in claim 2, it is characterised in that: be additionally provided with pipeline heating on the 4th pipeline Device, the pipeline heater are cooperateed with the temperature sensor for guaranteeing when second pretreatment unit works independently Temperature in 4th pipeline is in required range.
6. exhaust treatment system as described in claim 1, it is characterised in that: the third pipeline is equipped with desorption blower, institute It states on the third pipeline that lateral is connected between the desorption blower and the 4th pipeline.
7. exhaust treatment system as claimed in claim 6, it is characterised in that: be also successively arranged absorption wind on the 4th pipeline Machine, intake valve and check-valves avoid and the desorption gas in the third pipeline for accelerating the 4th gas in pipelines flowing Body conflict causes reflux.
8. exhaust treatment system as claimed in claim 7, it is characterised in that: the desorption blower and absorption blower with it is corresponding Pipeline is to be flexible coupling, noise elimination noise reduction and pipeline damping for blower.
9. exhaust treatment system as claimed in claim 7, it is characterised in that: the 4th pipeline is through branch line and the row Port connection, and described branch line one end is located on the 4th pipeline between the absorption blower and intake valve, it is described Branch line is equipped with drain valve.
10. exhaust treatment system as described in claim 1, it is characterised in that: be additionally provided with pipe insulation on the 4th pipeline Facility keeps the temperature in pipeline for preventing the too fast loss of temperature in the 4th pipeline.
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CN109354375A (en) * 2018-11-26 2019-02-19 西南石油大学 A kind of the greasy filth two-stage thermal desorption system and its integrated skid of high-moisture percentage
CN210332180U (en) * 2019-05-30 2020-04-17 江苏新聚环保科技有限公司 Exhaust gas treatment system

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Publication number Priority date Publication date Assignee Title
CN110075667B (en) * 2019-05-30 2024-04-02 江苏新聚环保科技有限公司 Exhaust gas treatment system

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