CN110055858A - A kind of environment-friendly type mixing plastic cement race track and preparation method thereof - Google Patents

A kind of environment-friendly type mixing plastic cement race track and preparation method thereof Download PDF

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Publication number
CN110055858A
CN110055858A CN201910436362.8A CN201910436362A CN110055858A CN 110055858 A CN110055858 A CN 110055858A CN 201910436362 A CN201910436362 A CN 201910436362A CN 110055858 A CN110055858 A CN 110055858A
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plastic cement
link block
race track
cement race
environment
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CN110055858B (en
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黄先玉
彭俊杰
梁璐
田金钟
钟永瑞
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Environmental Science Institute Of Huizhou
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Environmental Science Institute Of Huizhou
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04Polyurethanes
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C13/00Pavings or foundations specially adapted for playgrounds or sports grounds; Drainage, irrigation or heating of sports grounds
    • E01C13/06Pavings made in situ, e.g. for sand grounds, clay courts E01C13/003
    • E01C13/065Pavings made in situ, e.g. for sand grounds, clay courts E01C13/003 at least one in situ layer consisting of or including bitumen, rubber or plastics
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2265Oxides; Hydroxides of metals of iron
    • C08K2003/2272Ferric oxide (Fe2O3)
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Road Paving Structures (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention provides a kind of environment-friendly type mixing plastic cement race track, including upper link block, intermediate link block, lower connecting block, the intermediate link block are cooperatively connected with upper link block, lower connecting block respectively;The upper link block includes the first mounting plate, is successively arranged the first elastic layer, the second elastic layer on first mounting plate;First elastic layer is mixing elastic layer;Second elastic layer is consistent with the first elastic layer structure.The present invention provides a kind of modular environment-friendly type mixing plastic cement race track prepared using footwear material waste material as primary raw material, the present invention replaces EPDM rubber particle as the elastic filler material in mixed type runway using footwear material waste material, the requirement of plastic cement race track elastic property can either be reached, part footwear material waste material is become into available resource simultaneously, reduces the adverse effect in waste and disposition to environment;And it is easy to assembly, it can effectively reduce influence of the expanded by heating to plastic cement race track elasticity.

Description

A kind of environment-friendly type mixing plastic cement race track and preparation method thereof
Technical field
The invention belongs to sports facility technical fields, and in particular to a kind of environment-friendly type mixing plastic cement race track and its preparation side Method.
Background technique
According to factual survey, entire Huidong County about generates 300t shoes industry waste material daily.Shoes industry leftover pieces account for about total material quantity 20%-40%.Major part shoes manufacturing enterprise, Huidong County, it is relatively simple to the management of shoes industry waste material rough, without written spoiled products management Article do not store classifiedly shoes industry waste material, increase the difficulty of waste material subsequent processing.Local shoes industry waste disposal mode compared with To be single, most of outward transport processing, and the enterprise that the local shoes industry waste recovery without large-scale utilizes.Still have in waste material big The waste material of part recoverable is landfilled processing.In this case, government should reinforce the guidance to enterprise, organize and coordinate phase Pass department, make shoes industry waste material obtains reasonably handling disposition, and enterprise should improve the yield that production technology reduces waste material, formulate Shoes industry waste management system reinforces the management to shoes industry waste material.Legal power generation by waste combustion, cement kiln synergic processing or planning industry park Area carries out resource utilization to shoes industry waste material, walks the direction that sustainable development route is future development.
It mainly include polyurethane (PU) waste material, ethylene and vinyl acetate copolymer (EVA) etc. in shoemaking waste, wherein Polyurethane (PU) waste material mainly based on foamed product, there is soft, hard, semi-rigid foam.P U is due to function admirable and purposes Extensively, development is very rapid, and waste is also more and more, therefore the recycling of its waste product can not only effective protection ring Border reduces pollution, and can save resource, turns waste into wealth.It is, in general, that the method for recycling waste polyurethane has physical method, changes Method and energy regenerating.Wherein energy regenerating is that burn under certain condition to PU waste material a large amount of thermal energy of generation recycle, If but will not exclusively generate toxic and harmful gas in burning process fuel simultaneously and cause secondary pollution, thus should not use.Physics Method is simple and easy, technical maturity, but the product properties that recycling comes is poor, is only suitable for making low grade products, and aging is eliminated more Fastly.Chemical recovering method technical matters is relative complex, and industrialization is mature later, and new biodegrading process still continuously emerges up to now, Some biodegrading process are still in the laboratory research stage, but good foam property made from final regenerant.
The crosslinked foaming material of ethylene and vinyl acetate copolymer (EVA) has high-flexibility, impact resistance, weather-proof The advantages that with anti-exposure, is widely used in fields such as sound insulation, vibration damping, heat preservation, toy, movement shoes materials.EVA waste material tool There is certain recycle value, therefore local footwear industry has had the recycling route of comparative maturity to EVA waste material.Recycling It is large grained waste material that EVA bottom plate waste material is generally carried out cutting and grinding by route, enters back into double screw extruder, melts, draws It is cut into fine granularity after silk, cooling, the raw material for regenerating EVA bottom plate is can be used as, the original of other purposes can also be made Material.
Shoes industry waste material safely and effectively dispose be it is very urgent, need to find out effective Countermeasures for Disposal as early as possible.Dew at present Common several processing modes such as its stacking, open incineration, landfill in the presence of pollution environment, damage ecology, endanger population health, The problem of waste of resource.Implement the resource utilization of shoes industry waste material, guarantees that the waste material that can be recycled obtains effectively as far as possible It utilizes, just seems especially urgent in the case where shortage of resources, pressure are increasing.In short, realizing the recycling of shoes industry waste material It utilizes, is allowed to reenter the circulatory system, be only the basic place for establishing cleaning, green, environmental protection, sustainable development.
In the prior art, plastic cement race track is under the higher weather of temperature, is easy expanded by heating, influence runway elasticity and The comfort of movement;The reduction of the screen resilience of plastic cement race track simultaneously, also improves the probability of sportsman's ankle injury.
Summary of the invention
In view of this, the present invention provides a kind of modular environment-friendly type mixing plastic cement prepared using footwear material waste material as primary raw material Runway, the present invention using footwear material waste material replace EPDM(EPDM) rubber grain as in mixed type runway elasticity fill Material can either reach the requirement of plastic cement race track elastic property, while part footwear material waste material is become available resource, reduce wave To the adverse effect of environment in taking and disposing;And it is easy to assembly, it can effectively reduce expanded by heating to plastic cement race track elasticity It influences.
The technical solution of the present invention is as follows:
A kind of environment-friendly type mixes plastic cement race track, which is characterized in that including upper link block, intermediate link block, lower connecting block, it is described in Between link block respectively with upper link block, lower connecting block be cooperatively connected;The upper link block includes the first mounting plate, first peace The first elastic layer, the second elastic layer are successively arranged in loading board;The side of first mounting plate is symmetrically arranged with the first installation parting bead; The intermediate link block includes connecting plate, and the two sides of the connecting plate are symmetrically arranged with connection projection, the connection projection respectively with Upper link block, lower connecting block are cooperatively connected;The lower connecting block includes the second mounting plate, is successively arranged on second mounting plate Water barrier, bottom;The side of second mounting plate is symmetrically arranged with the second installation parting bead;First elastic layer is mixing elasticity Layer;Second elastic layer is consistent with the first elastic layer structure.
Further, first elastic layer includes following parts by weight component: polyurethane particles 5-25, vinyl acetate Ester copolymer particle 3-22, intermixture A 15-28, intermixture B 37-49, nano-aluminum phosphate molecular sieve 8-15, hydrogenation zinc-iron Ferrite ceramics powder 4-9.
In the present invention, nano-aluminum phosphate molecular sieve, the zinc hydride ferrite ceramics powder of addition are that prior art preparation obtains ?;The nano-aluminum phosphate molecular sieve can increase the adhesiveness in mixing plastic cement between particle, improve its tensile strength and hang down The shock absorbing capability of mixing plastic cement can be improved in straight deformability, zinc hydride ferrite ceramics powder.Pass through nano-aluminum phosphate molecule The synergistic compounding of sieve, zinc hydride ferrite ceramics powder in component, is remarkably improved the physical property of elastic layer.
Further, the average grain diameter of the polyurethane particles is 1-5mm.
Further, the average grain diameter of the vinyl acetate copolymer particle is 1-5mm.
Further, the intermixture A includes following parts by weight component: isocyanates 16-29, polyalcohol 7-15, Polyether polyol 3-8, chloro vegetable oil 5-11, auxiliary agent 2-5;
Further, the intermixture B includes following parts by weight component: polyether polyol 11-19, chloro vegetable oil 13- 22, ethyl acetate 6-18, coupling agent 2-7, auxiliary agent 4-9, kaolin 5-12, mountain flour 3-11, iron oxide red 1-4.
Further, mounting hole is symmetrically arranged in the connecting plate, the mounting hole is connected with elastomeric connector strip.The present invention Each layer between the modes such as the laying, coating, assembling of the prior art can be used be attached.
Further, it is described first installation parting bead first installation plate surface in groined type arrange, it is described first install every The first mounting groove, the second mounting groove are respectively formed between item.
Further, it is described second installation parting bead second installation plate surface in groined type arrange, it is described second install every Third mounting groove, the 4th mounting groove are respectively formed between article.
Further, first mounting groove is cooperatively connected with projection is connect.
Further, the third mounting groove is cooperatively connected with projection is connect.
In the present invention, by the first mounting groove with connect projection be cooperatively connected, third mounting groove with connect projection cooperate company The intermediate link block mating connection with upper link block, lower connecting block respectively of realization is connect, then passes through symmetrically arranged peace in connecting plate Hole is filled, realizes that each environment-friendly type mixes the connection between plastic cement race track by elastomeric connector strip, forms a whole runway.The bullet The rubber material that the prior art can be used in property connection strap, first mounting plate, the second mounting plate, connecting plate prepares.
Further, second mounting groove, be respectively symmetrically placed with elastomer block in the 4th mounting groove.In the present invention, Fluid channel is formed in second mounting groove, the 4th mounting groove, in the event of high temperatures, can in the case where being under pressure incite somebody to action Fluid is discharged to two sides, reduces internal pressure, keeps internal stability.
Further, the elastomer block includes ball, and the ball surface is symmetrically arranged with arc projection.
Pass through elastomer block of arranging in the second mounting groove, the 4th mounting groove.It can be mixed inside plastic cement race track for environment-friendly type Effective elastic anchorage force and screen resilience are provided, by the setting of arc projection, can to occur in elastically-deformable runway Portion is easier to restore, and provides enough elastic anchorage forces, influence of the thermal deformation to plastic cement race track under hot conditions is effectively reduced.
Further, the bottom be high-strength osmosis type prime coat, the bottom be by high-strength osmosis type priming paint coating and At;The water barrier is aerogel layer, has excellent water proof heat-insulating property.By the setting of water barrier, bottom can effectively avoid Portion's water inlet, can be simultaneously reached good heat insulation, improves service life.
A kind of preparation method of above-mentioned environment-friendly type mixing plastic cement race track, which comprises the following steps:
S1. distinguish the average grain diameter of comminuted polyurethane particle, vinyl acetate copolymer particle to setting;
S2. intermixture A and intermixture B are uniformly mixed;
S3. nano-aluminum phosphate molecular sieve, zinc hydride ferrite ceramics powder, high speed is added to premixed slurries obtained in step S2 It is stirred homogeneous;
S4. polyurethane particles, vinyl acetate copolymer particle are separately added into mixed slurry obtained in step S3, mixed Stirring;
S5. the first elastic layer, the second elastic layer is made in reverse mould;
S6. upper link block, intermediate link block, lower connecting block are suppressed respectively, by upper link block, intermediate link block, lower connecting block point Plastic cement race track Zu Zhuan not formed.
The beneficial effects of the present invention are:
The present invention substitutes EPDM particle manufacture mixed type plastic track with footwear material EVA, PU waste material, helps to reduce production cost, Part footwear material waste material is become into available resource, reduces the adverse effect in waste and disposition to environment.The present invention simultaneously Volatile matter content and toluene+dimethylbenzene index, the content of soluble heavy metal lead meets national standard, be safety and environmental protection Mixing plastic cement race track;The present invention is easy to assembly, can effectively reduce influence of the expanded by heating to plastic cement race track elasticity.
Detailed description of the invention
Fig. 1 is the structural diagram of the present invention;
Fig. 2 is partial structural diagram of the invention;
Fig. 3 is partial structural diagram of the invention;
Fig. 4 is partial structural diagram of the invention;
Fig. 5 is partial structural diagram of the invention;
Fig. 6 is partial structural diagram of the invention;
Fig. 7 is partial structural diagram of the invention.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other Embodiment shall fall within the protection scope of the present invention.
Embodiment 1
A kind of environment-friendly type mixing plastic cement race track, which is characterized in that including upper link block 1, intermediate link block 2, lower connecting block 3, institute Intermediate link block is stated to be cooperatively connected with upper link block, lower connecting block respectively;The upper link block 1 includes the first mounting plate 11, institute It states and is successively arranged the first elastic layer 12, the second elastic layer 13 on the first mounting plate;The side of first mounting plate is symmetrically arranged with First installation parting bead 14;The intermediate link block 2 includes connecting plate 21, and the two sides of the connecting plate are symmetrically arranged with connection projection 22, the connection projection is cooperatively connected with upper link block, lower connecting block respectively;The lower connecting block 3 includes the second mounting plate 31, Water barrier 32, bottom 33 are successively arranged on second mounting plate;The side of second mounting plate is symmetrically arranged with the second installation Parting bead 34;First elastic layer is mixing elastic layer;Second elastic layer is consistent with the first elastic layer structure.
Further, first elastic layer includes following parts by weight component: polyurethane particles 15, vinyl acetate Copolymer pellet 12, intermixture A 18, intermixture B 42, nano-aluminum phosphate molecular sieve 13, zinc hydride ferrite ceramics powder 6.
Further, the average grain diameter of the polyurethane particles is 3mm.
Further, the average grain diameter of the vinyl acetate copolymer particle is 3mm.
Further, the intermixture A includes following parts by weight component: isocyanates 21, polyalcohol 11, polyethers are more First alcohol 5, chloro vegetable oil 7, auxiliary agent 3;
Further, the intermixture B includes following parts by weight component: polyether polyol 14, chloro vegetable oil 16, acetic acid Ethyl ester 9, coupling agent 5, auxiliary agent 6, kaolin 8, mountain flour 7, iron oxide red 2.
Further, it is symmetrically arranged with mounting hole 211 in the connecting plate 21, the mounting hole is connected with elastomeric connector strip 4. The modes such as the laying, coating, assembling of the prior art can be used between each layer of the invention to be attached.
Further, the first installation parting bead 14 is arranged in the first installation plate surface in groined type, first installation The first mounting groove 15, the second mounting groove 16 are respectively formed between parting bead.
Further, the second installation parting bead 34 is arranged in the second installation plate surface in groined type, second installation Third mounting groove 35, the 4th mounting groove 36 are respectively formed between parting bead.
Further, first mounting groove is cooperatively connected with projection is connect.
Further, the third mounting groove is cooperatively connected with projection is connect.
In the present invention, by the first mounting groove with connect projection be cooperatively connected, third mounting groove with connect projection cooperate company The intermediate link block mating connection with upper link block, lower connecting block respectively of realization is connect, then passes through symmetrically arranged peace in connecting plate Hole is filled, realizes that each environment-friendly type mixes the connection between plastic cement race track by elastomeric connector strip, forms a whole runway.The bullet The rubber material that the prior art can be used in property connection strap, first mounting plate, the second mounting plate, connecting plate prepares.
Further, second mounting groove, be respectively symmetrically placed with elastomer block 5 in the 4th mounting groove.In the present invention, Fluid channel is formed in second mounting groove, the 4th mounting groove, in the event of high temperatures, can in the case where being under pressure incite somebody to action Fluid is discharged to two sides, reduces internal pressure, keeps internal stability.
Further, the elastomer block includes ball, and the ball surface is symmetrically arranged with arc projection 51.
Pass through elastomer block of arranging in the second mounting groove, the 4th mounting groove.It can be mixed inside plastic cement race track for environment-friendly type Effective elastic anchorage force and screen resilience are provided, by the setting of arc projection, can to occur in elastically-deformable runway Portion is easier to restore, and provides enough elastic anchorage forces, influence of the thermal deformation to plastic cement race track under hot conditions is effectively reduced.
Further, the bottom be high-strength osmosis type prime coat, the bottom be by high-strength osmosis type priming paint coating and At;The water barrier is aerogel layer, has excellent water proof heat-insulating property.By the setting of water barrier, bottom can effectively avoid Portion's water inlet, can be simultaneously reached good heat insulation, improves service life.
A kind of preparation method of above-mentioned environment-friendly type mixing plastic cement race track, which comprises the following steps:
S1. distinguish the average grain diameter of comminuted polyurethane particle, vinyl acetate copolymer particle to setting;
S2. intermixture A and intermixture B are uniformly mixed;
S3. nano-aluminum phosphate molecular sieve, zinc hydride ferrite ceramics powder, high speed is added to premixed slurries obtained in step S2 It is stirred homogeneous;
S4. polyurethane particles, vinyl acetate copolymer particle are separately added into mixed slurry obtained in step S3, mixed Stirring;
S5. the first elastic layer, the second elastic layer is made in reverse mould;
S6. upper link block, intermediate link block, lower connecting block are suppressed respectively, by upper link block, intermediate link block, lower connecting block point Plastic cement race track Zu Zhuan not formed.
Embodiment 2
The present embodiment provides one kind to mix plastic cement race track with the consistent environment-friendly type of 1 structure of embodiment, the difference is that described first Elastic layer includes following parts by weight component: polyurethane particles 25, intermixture A 28, mix vinyl acetate copolymer particle 22 Mixture B 49, nano-aluminum phosphate molecular sieve 15, zinc hydride ferrite ceramics powder 9.
Further, the average grain diameter of the polyurethane particles is 1mm.
Further, the average grain diameter of the vinyl acetate copolymer particle is 1mm.
Further, the intermixture A includes following parts by weight component: isocyanates 29, polyalcohol 15, polyethers are more First alcohol 8, chloro vegetable oil 11, auxiliary agent 5;
Further, the intermixture B includes following parts by weight component: polyether polyol 19, chloro vegetable oil 22, acetic acid Ethyl ester 18, coupling agent 7, auxiliary agent 9, kaolin 12, mountain flour 11, iron oxide red 4.
Embodiment 3
The present embodiment provides one kind to mix plastic cement race track with the consistent environment-friendly type of 1 structure of embodiment, the difference is that described first Elastic layer includes following parts by weight component: polyurethane particles 5, intermixture A 15, mix vinyl acetate copolymer particle 3 Mixture B 37, nano-aluminum phosphate molecular sieve 8, zinc hydride ferrite ceramics powder 4.
Further, the average grain diameter of the polyurethane particles is 5mm.
Further, the average grain diameter of the vinyl acetate copolymer particle is 5mm.
Further, the intermixture A includes following parts by weight component: isocyanates 16, polyalcohol 7, polyethers are more First alcohol 3, chloro vegetable oil 5, auxiliary agent 2;
Further, the intermixture B includes following parts by weight component: polyether polyol 11, chloro vegetable oil 13, acetic acid Ethyl ester 6, coupling agent 2, auxiliary agent 4, kaolin 5, mountain flour 3, iron oxide red 1.
Embodiment 4
The present embodiment provides one kind to mix plastic cement race track with the consistent environment-friendly type of 1 structure of embodiment, the difference is that described first Elastic layer includes following parts by weight component: polyurethane particles 17, vinyl acetate copolymer particle 15, intermixture A 21, Intermixture B 43, nano-aluminum phosphate molecular sieve 11, zinc hydride ferrite ceramics powder 6.
Further, the average grain diameter of the polyurethane particles is 2mm.
Further, the average grain diameter of the vinyl acetate copolymer particle is 2mm.
Further, the intermixture A includes following parts by weight component: isocyanates 21, polyalcohol 10, polyethers are more First alcohol 5, chloro vegetable oil 6, auxiliary agent 4;
Further, the intermixture B includes following parts by weight component: polyether polyol 15, chloro vegetable oil 17, acetic acid Ethyl ester 11, coupling agent 5, auxiliary agent 6, kaolin 8, mountain flour 8, iron oxide red 2.
Embodiment 5
The present embodiment provides one kind to mix plastic cement race track with the consistent environment-friendly type of 1 structure of embodiment, the difference is that described first Elastic layer includes following parts by weight component: polyurethane particles 22, vinyl acetate copolymer particle 18, intermixture A 24, Intermixture B 45, nano-aluminum phosphate molecular sieve 13, zinc hydride ferrite ceramics powder 7.
Further, the average grain diameter of the polyurethane particles is 2.5mm.
Further, the average grain diameter of the vinyl acetate copolymer particle is 2.5mm.
Further, the intermixture A includes following parts by weight component: isocyanates 26, polyalcohol 12, polyethers are more First alcohol 7, chloro vegetable oil 9, auxiliary agent 4;
Further, the intermixture B includes following parts by weight component: polyether polyol 17, chloro vegetable oil 18, acetic acid Ethyl ester 15, coupling agent 5, auxiliary agent 7, kaolin 10, mountain flour 8, iron oxide red 3.
Comparative example 1
This comparative example provides one kind and mixes plastic cement race track with the consistent environment-friendly type of 1 structure of embodiment, the difference is that described first Elastic layer includes following parts by weight component: polyurethane particles 15, vinyl acetate copolymer particle 12, intermixture A 18, Intermixture B 42, zinc hydride ferrite ceramics powder 6.
Further, the average grain diameter of the polyurethane particles is 3mm.
Further, the average grain diameter of the vinyl acetate copolymer particle is 3mm.
Further, the intermixture A includes following parts by weight component: isocyanates 21, polyalcohol 11, polyethers are more First alcohol 5, chloro vegetable oil 7, auxiliary agent 3;
Further, the intermixture B includes following parts by weight component: polyether polyol 14, chloro vegetable oil 16, acetic acid Ethyl ester 9, coupling agent 5, auxiliary agent 6, kaolin 8, mountain flour 7, iron oxide red 2.
Comparative example 2
This comparative example provides one kind and mixes plastic cement race track with the consistent environment-friendly type of 1 structure of embodiment, the difference is that described first Elastic layer includes following parts by weight component: polyurethane particles 15, vinyl acetate copolymer particle 12, intermixture A 18, Intermixture B 42, nano-aluminum phosphate molecular sieve 13.
Further, the average grain diameter of the polyurethane particles is 3mm.
Further, the average grain diameter of the vinyl acetate copolymer particle is 3mm.
Further, the intermixture A includes following parts by weight component: isocyanates 21, polyalcohol 11, polyethers are more First alcohol 5, chloro vegetable oil 7, auxiliary agent 3;
Further, the intermixture B includes following parts by weight component: polyether polyol 14, chloro vegetable oil 16, acetic acid Ethyl ester 9, coupling agent 5, auxiliary agent 6, kaolin 8, mountain flour 7, iron oxide red 2.
Implementation result test
The first elastic layer in embodiment 1-4 and comparative example 1-2 is cut into 30mm × 30mm × 11mm sample, to its physics Performance is tested, as a result as shown in the table.
1 mixed type runway physical property testing result table of table
Economic feasibility analysis
Verified, this tests production equipment used, and production technology of the invention is with the mixed type runway of addition EPDM and entirely Plastotype runway does not have a difference, every batch of production time substantially, and scene mats formation, daily maintenance, protection etc. are also essentially identical, according to profession Personage estimates, and service life is also essentially identical.We only carry out the economic cost accounting of raw material substitution as a result,.
It is known that the plastic cement race track of a Zhou Changwei 400m more standardized, area of mating formation are about 7000m2, thickness is about 13mm;Useless footwear material particle substitution Economic Benefit Accounting is carried out, there is apparent economic benefit.
Table 2 give up footwear material particle substitution Economic Benefit Accounting
In short, substituting EPDM particle manufacture mixed type plastic track with footwear material EVA, PU waste material, help to reduce production cost, it will Part footwear material waste material becomes available resource, reduces the adverse effect in waste and disposition to environment.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie In the case where without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power Benefit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent elements of the claims Variation is included within the present invention.Any reference signs in the claims should not be construed as limiting the involved claims.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art The other embodiments being understood that.It is noted that the technical characteristic being not described in detail in the present invention, it can be by appointing One prior art is realized.

Claims (10)

1. a kind of environment-friendly type mixes plastic cement race track, which is characterized in that described including upper link block, intermediate link block, lower connecting block Intermediate link block is cooperatively connected with upper link block, lower connecting block respectively;The upper link block include the first mounting plate, described first The first elastic layer, the second elastic layer are successively arranged on mounting plate;The side of first mounting plate be symmetrically arranged with the first installation every Item;The intermediate link block includes connecting plate, and the two sides of the connecting plate are symmetrically arranged with connection projection, the connection projection difference It is cooperatively connected with upper link block, lower connecting block;The lower connecting block includes the second mounting plate, is successively set on second mounting plate There are water barrier, bottom;The side of second mounting plate is symmetrically arranged with the second installation parting bead;First elastic layer is mixing bullet Property layer;Second elastic layer is consistent with the first elastic layer structure.
2. environment-friendly type according to claim 1 mixes plastic cement race track, which is characterized in that first elastic layer includes following Parts by weight component: polyurethane particles 5-25, vinyl acetate copolymer particle 3-22, intermixture A 15-28, intermixture B 37-49, nano-aluminum phosphate molecular sieve 8-15, zinc hydride ferrite ceramics powder 4-9.
3. environment-friendly type according to claim 2 mixes plastic cement race track, which is characterized in that the average grain of the polyurethane particles Diameter is 1-5mm.
4. environment-friendly type according to claim 2 mixes plastic cement race track, which is characterized in that the vinyl acetate copolymer The average grain diameter of grain is 1-5mm.
5. environment-friendly type according to claim 2 mixes plastic cement race track, which is characterized in that the intermixture A includes following heavy Measure number component: isocyanates 16-29, polyalcohol 7-15, polyether polyol 3-8, chloro vegetable oil 5-11, auxiliary agent 2- 5。
6. environment-friendly type according to claim 2 mixes plastic cement race track, which is characterized in that the intermixture B includes following heavy Measure number component: polyether polyol 11-19, chloro vegetable oil 13-22, ethyl acetate 6-18, coupling agent 2-7, auxiliary agent 4- 9, kaolin 5-12, mountain flour 3-11, iron oxide red 1-4.
7. environment-friendly type according to claim 1 mixes plastic cement race track, which is characterized in that be symmetrically arranged with peace in the connecting plate Hole is filled, the mounting hole is connected with elastomeric connector strip.
8. environment-friendly type according to claim 1 mixes plastic cement race track, which is characterized in that the first installation parting bead is first Plate surface is installed to arrange in groined type, is respectively formed the first mounting groove, the second mounting groove between the first installation parting bead;It is described Second installation parting bead is arranged in the second installation plate surface in groined type, is respectively formed third installation between the second installation parting bead Slot, the 4th mounting groove.
9. environment-friendly type according to claim 8 mixes plastic cement race track, which is characterized in that first mounting groove is dashed forward with connecting Block is cooperatively connected;The third mounting groove is cooperatively connected with projection is connect;It is right respectively in second mounting groove, the 4th mounting groove Title is placed with elastomer block.
10. a kind of preparation method of the described in any item environment-friendly type mixing plastic cement race tracks of claim 1-9, which is characterized in that packet Include following steps:
S1. distinguish the average grain diameter of comminuted polyurethane particle, vinyl acetate copolymer particle to setting;
S2. intermixture A and intermixture B are uniformly mixed;
S3. nano-aluminum phosphate molecular sieve, zinc hydride ferrite ceramics powder, high speed is added to premixed slurries obtained in step S2 It is stirred homogeneous;
S4. polyurethane particles, vinyl acetate copolymer particle are separately added into mixed slurry obtained in step S3, mixed Stirring;
S5. the first elastic layer, the second elastic layer is made in reverse mould;
S6. upper link block, intermediate link block, lower connecting block are suppressed respectively, by upper link block, intermediate link block, lower connecting block point Plastic cement race track Zu Zhuan not formed.
CN201910436362.8A 2019-05-23 2019-05-23 Environment-friendly mixed plastic track and preparation method thereof Active CN110055858B (en)

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CN114292580A (en) * 2021-12-22 2022-04-08 广东高捷体育产业有限公司 Self-flowing flat ground material and preparation method thereof

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CN114292580A (en) * 2021-12-22 2022-04-08 广东高捷体育产业有限公司 Self-flowing flat ground material and preparation method thereof

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