CN110055814A - A kind of fly ash base papermaking paint and preparation method thereof - Google Patents
A kind of fly ash base papermaking paint and preparation method thereof Download PDFInfo
- Publication number
- CN110055814A CN110055814A CN201910370924.3A CN201910370924A CN110055814A CN 110055814 A CN110055814 A CN 110055814A CN 201910370924 A CN201910370924 A CN 201910370924A CN 110055814 A CN110055814 A CN 110055814A
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- Prior art keywords
- parts
- fly ash
- agent
- flyash
- ash base
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Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
- D21H19/385—Oxides, hydroxides or carbonates
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
- D21H19/40—Coatings with pigments characterised by the pigments siliceous, e.g. clays
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/46—Non-macromolecular organic compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/58—Polymers or oligomers of diolefins, aromatic vinyl monomers or unsaturated acids or derivatives thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/60—Polyalkenylalcohols; Polyalkenylethers; Polyalkenylesters
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/62—Macromolecular organic compounds or oligomers thereof obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Paper (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of fly ash base papermaking paints and preparation method thereof, it is related to paint field, according to parts by weight includes following composition: 100-200 parts of flyash, 1-5 parts of dispersing agent, 3-6 parts of defoaming agent, 15-30 parts of adhesive, 3-6 parts of water repellent agent, 1-5 parts of brightening agent, 1-3 parts of step 1 of fungicide: deionized water is placed in dispersion cup, flyash is added in deionized water, keeps 3100-4150 revs/min of rate high speed shear to disperse and be added dispersing agent, obtains flyash dispersion liquid；Step 2: sequentially adding defoaming agent, adhesive, water repellent agent, brightening agent, fungicide, and the time interval of addition is 5-15 minutes, fully dispersed uniform to guarantee；Step 3: dispersing shear 55-62 minutes under 3200-4100 revs/min of rate, fly ash base papermaking paint is made.Papermaking paint is made by pigment of bulk solid waste flyash in the present invention, provides new direction for the comprehensive utilization of flyash, improves the added value of flyash.
Description
Technical field
The present invention relates to paint fields more particularly to a kind of fly ash base papermaking paint and preparation method thereof.
Background technique
Papermaking paint is the important component of painting processing paper, is by dispersible pigment dispersion, adhesive and other auxiliary agents
The mixed system of composition.It assigns some water-fast moisture-proof performances of paper and improves the printing adaptability of paper.Existing coating process,
Pigment generally selects kaolin.Kaolin belongs to non-renewable resources, and excessive exploitation causes ecological environment greatly broken
It is bad.
Flyash is the solid waste generated in industrial production, and is just being increased with every year with hundred million tons of quantity.
Common processing mode is to bury or be added to cement, in concrete.These types of processing mode or pollution environment or additional
It is worth low.Therefore solve the problems, such as that added value is low to become the task of top priority to flyash applying upper dosage to lack.
Flyash has chemical component similar with kaolin, and flyash has specific surface area small compared with kaolin, hole
The features such as gap rate is big, in acid, neutral or alkaline environment is inert substance, and source is wide, price is very cheap.
Summary of the invention
The invention proposes a kind of fly ash base papermaking paints and preparation method thereof.
To achieve the goals above, present invention employs following technical solutions:
A kind of fly ash base papermaking paint includes following composition according to parts by weight:
Further, the flyash is Class F fly ash.
Further, the partial size of the Class F fly ash is 1-5um.
Further, the efficient adhesive includes following composition according to parts by weight: 1-5 parts of polyvinyl alcohol, polypropylene
Sour sodium 1-5 parts, 5-10 parts of styrene-acrylic emulsion.
Further, the efficient adhesive is made by following steps: by polyvinyl alcohol, Sodium Polyacrylate and styrene-acrylic emulsion
It is reacted 2-3 hours at a temperature of 110-120 DEG C；70-80 DEG C is cooled to, is added carboxyl group-containing monomer 4-10 parts, is reacted 5-6 hours,
Obtain milky high-efficiency adhesion agent.
Further, the water repellent agent are as follows: at least one of potassium zirconium carbonate, PAPU, modified glyoxal.
Further, the brightening agent is Stilbene-based brightening agent.
Further, the dispersing agent is cationic polyacrylamide.
A kind of preparation method of fly ash base papermaking paint, its step are as follows:
Step 1: deionized water is placed in dispersion cup, and flyash is added in deionized water, keeps 3100-4150
Rev/min rate high speed shear disperse and be added dispersing agent, obtain flyash dispersion liquid；
Step 2: sequentially adding defoaming agent, adhesive, water repellent agent, brightening agent, fungicide, and the time interval of addition is 5-
It is 15 minutes, fully dispersed uniform to guarantee；
Step 3: dispersing shear 55-62 minutes under 3200-4100 revs/min of rate, fly ash base papermaking is made and applies
Material.
Usefulness: papermaking paint is made by pigment of bulk solid waste flyash in the present invention, is the comprehensive of flyash
It closes using new direction is provided, improves the added value of flyash.And it is reduced under the premise of not reducing quality of finished paper
The cost in paper mill.
Specific embodiment
The following is a clear and complete description of the technical scheme in the embodiments of the invention, it is clear that described embodiment
Only a part of the embodiment of the present invention, instead of all the embodiments.
Embodiment 1:
A kind of fly ash base papermaking paint includes following composition according to parts by weight: partial size is the Class F fly ash of 1um
100 parts, 1 part of cationic polyacrylamide, 3 parts of defoaming agent, 15 parts of adhesive, 3 parts of potassium zirconium carbonate, Stilbene-based brightening agent 1
Part, 1 part of fungicide.
Efficient adhesive includes following composition according to parts by weight: 1 part of polyvinyl alcohol, 1 part of Sodium Polyacrylate, styrene-acrylic emulsion
10 parts；
The efficient adhesive is made by following steps: by polyvinyl alcohol, Sodium Polyacrylate and styrene-acrylic emulsion in 110 DEG C of temperature
Degree lower reaction 2 hours；70 DEG C are cooled to, is added 4 parts of carboxyl group-containing monomer, reacts 5 hours, obtains milky high-efficiency adhesion agent.
Embodiment 2:
A kind of fly ash base papermaking paint includes following composition according to parts by weight: partial size is the Class F fly ash of 3.5um
150 parts, 3 parts of cationic polyacrylamide, 5 parts of defoaming agent, 20 parts of adhesive, modified 4 parts of glyoxal, Stilbene-based brightening agent
3 parts, 2 parts of fungicide.
Efficient adhesive includes following composition according to parts by weight: 5 parts of polyvinyl alcohol, 5 parts of Sodium Polyacrylate, styrene-acrylic emulsion
5 parts；
The efficient adhesive is made by following steps: by polyvinyl alcohol, Sodium Polyacrylate and styrene-acrylic emulsion in 120 DEG C of temperature
Degree lower reaction 3 hours；80 DEG C are cooled to, is added 10 parts of carboxyl group-containing monomer, reacts 6 hours, obtains milky high-efficiency adhesion agent.
Embodiment 3:
A kind of fly ash base papermaking paint includes following composition according to parts by weight: partial size is the Class F fly ash of 5um
200 parts, 5 parts of cationic polyacrylamide, 6 parts of defoaming agent, 30 parts of adhesive, 6 parts of PAPU, 5 parts of Stilbene-based brightening agent,
3 parts of fungicide.
Efficient adhesive includes following composition according to parts by weight: 3 parts of polyvinyl alcohol, 4 parts of Sodium Polyacrylate, styrene-acrylic emulsion
8 parts；
Efficient adhesive is made by following steps: by polyvinyl alcohol, Sodium Polyacrylate and styrene-acrylic emulsion at a temperature of 114 DEG C
Reaction 2.3 hours；76 DEG C are cooled to, is added 9 parts of carboxyl group-containing monomer, reacts 5.2 hours, obtains milky high-efficiency adhesion agent.
Embodiment 4:
On the basis of embodiment 1: a kind of preparation method of fly ash base papermaking paint, its step are as follows:
Step 1: deionized water is placed in dispersion cup, and 100 parts of flyash are added in deionized water, keeps 3500
Rev/min rate high speed shear disperse and be added 1 part of cationic polyacrylamide, obtain flyash dispersion liquid；
Step 2: 3 parts of defoaming agents, 15 parts of adhesives, 3 parts of potassium zirconium carbonates, 1 part of Stilbene-based brightening agent, 1 are sequentially added
The auxiliary agents such as part fungicide, the time interval of addition are 10 minutes, fully dispersed uniform to guarantee；
Step 3: fly ash base papermaking paint is made in dispersing shear 60 minutes under 4000 revs/min of rate.
Embodiment 5:
On the basis of embodiment 2: a kind of preparation method of fly ash base papermaking paint, its step are as follows:
Step 1: deionized water is placed in dispersion cup, and 150 parts of flyash are added in deionized water, keeps 3500
Rev/min rate high speed shear disperse and be added 3 parts of cationic polyacrylamide, obtain flyash dispersion liquid；
Step 2: 5 parts of defoaming agents are sequentially added, 20 parts of adhesives, 4 parts of modified glyoxals, 3 parts of Stilbene-baseds brighten
The auxiliary agents such as agent, 2 parts of fungicide, the time interval of addition are 10 minutes, fully dispersed uniform to guarantee；
Step 3: fly ash base papermaking paint is made in dispersing shear 60 minutes under 4000 revs/min of rate, and powder is made
Coal ash base papermaking paint.
Embodiment 6:
On the basis of embodiment 3: a kind of preparation method of fly ash base papermaking paint, its step are as follows:
Step 1: deionized water is placed in dispersion cup, and 200 parts of flyash are added in deionized water, keeps 3500
Rev/min rate high speed shear disperse and be added 5 parts of cationic polyacrylamide, obtain flyash dispersion liquid；
Step 2: sequentially add 6 parts of defoaming agents, 30 parts of adhesives, 6 parts of PAPU, 5 parts of Stilbene-based brightening agents, 3 parts kill
The auxiliary agents such as microbial inoculum, the time interval of addition are 10 minutes, fully dispersed uniform to guarantee；
Step 3: dispersing shear 60 minutes under 4000 revs/min of rate.
Embodiment 7:
On the basis of embodiment 1: a kind of preparation method of fly ash base papermaking paint, its step are as follows:
Step 1: deionized water is placed in dispersion cup, and 100 parts of flyash are added in deionized water, keeps 3100
Rev/min rate high speed shear disperse and be added 1 part of cationic polyacrylamide, obtain flyash dispersion liquid；
Step 2: 3 parts of defoaming agents, 15 parts of adhesives, 3 parts of potassium zirconium carbonates, 1 part of Stilbene-based brightening agent, 1 are sequentially added
The auxiliary agents such as part fungicide, the time interval of addition are 5 minutes, fully dispersed uniform to guarantee；
Step 3: fly ash base papermaking paint is made in dispersing shear 55 minutes under 3200 revs/min of rate.
Embodiment 8:
On the basis of embodiment 2: a kind of preparation method of fly ash base papermaking paint, its step are as follows:
Step 1: deionized water is placed in dispersion cup, and 150 parts of flyash are added in deionized water, keeps 4150
Rev/min rate high speed shear disperse and be added 3 parts of cationic polyacrylamide, obtain flyash dispersion liquid；
Step 2: 5 parts of defoaming agents are sequentially added, 20 parts of adhesives, 4 parts of modified glyoxals, 3 parts of Stilbene-baseds brighten
The auxiliary agents such as agent, 2 parts of fungicide, the time interval of addition are 15 minutes, fully dispersed uniform to guarantee；
Step 3: fly ash base papermaking paint is made in dispersing shear 62 minutes under 4100 revs/min of rate, and powder is made
Coal ash base papermaking paint.
Embodiment 9:
On the basis of embodiment 3: a kind of preparation method of fly ash base papermaking paint, its step are as follows:
Step 1: deionized water is placed in dispersion cup, and 200 parts of flyash are added in deionized water, keeps 3700
Rev/min rate high speed shear disperse and be added 5 parts of cationic polyacrylamide, obtain flyash dispersion liquid；
Step 2: sequentially add 6 parts of defoaming agents, 30 parts of adhesives, 6 parts of PAPU, 5 parts of Stilbene-based brightening agents, 3 parts kill
The auxiliary agents such as microbial inoculum, the time interval of addition are 11 minutes, fully dispersed uniform to guarantee；
Step 3: fly ash base papermaking paint is made in dispersing shear 58 minutes under 3800 revs/min of rate.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (9)
1. a kind of fly ash base papermaking paint, it is characterised in that: according to parts by weight include following composition:
2. a kind of fly ash base papermaking paint according to claim 1, which is characterized in that the flyash is low calcium fine coal
Ash.
3. a kind of fly ash base papermaking paint according to claim 2, which is characterized in that the partial size of the Class F fly ash
For 1-5um.
4. a kind of fly ash base papermaking paint according to claim 1, which is characterized in that the efficient adhesive is according to weight
Measuring number includes following composition: 1-5 parts of polyvinyl alcohol, 1-5 parts of Sodium Polyacrylate, and 5-10 parts of styrene-acrylic emulsion.
5. a kind of fly ash base papermaking paint according to claim 4, which is characterized in that the efficient adhesive is by following
Step is made: polyvinyl alcohol, Sodium Polyacrylate and styrene-acrylic emulsion are reacted 2-3 hours at a temperature of 110-120 DEG C；It cools to
70-80 DEG C, it is added carboxyl group-containing monomer 4-10 parts, reacts 5-6 hours, obtains milky high-efficiency adhesion agent.
6. a kind of fly ash base papermaking paint according to claim 1, which is characterized in that the water repellent agent are as follows: zirconium carbonate
At least one of potassium, PAPU, modified glyoxal.
7. a kind of fly ash base papermaking paint according to claim 1, which is characterized in that the brightening agent is talan
Type brightening agent.
8. a kind of fly ash base papermaking paint according to claim 1, which is characterized in that the dispersing agent is that cation is poly-
Acrylamide.
9. a kind of preparation method of the fly ash base papermaking paint as described in any one in claim 1-8, it is characterised in that:
Its step are as follows:
Step 1: deionized water is placed in dispersion cup by the first step, and flyash is added in deionized water, keeps 3100-
Dispersing agent is dispersed and be added to 4150 revs/min of rate high speed shear, obtains flyash dispersion liquid,
Step 2: sequentially adding defoaming agent, adhesive, water repellent agent, brightening agent, fungicide, and the time interval of addition is 5-15 points
Clock, it is fully dispersed uniform to guarantee；
Step 3: dispersing shear 55-62 minutes under 3200-4100 revs/min of rate, fly ash base papermaking paint is made.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910370924.3A CN110055814A (en) | 2019-05-06 | 2019-05-06 | A kind of fly ash base papermaking paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910370924.3A CN110055814A (en) | 2019-05-06 | 2019-05-06 | A kind of fly ash base papermaking paint and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110055814A true CN110055814A (en) | 2019-07-26 |
Family
ID=67322242
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910370924.3A Pending CN110055814A (en) | 2019-05-06 | 2019-05-06 | A kind of fly ash base papermaking paint and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110055814A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104404822A (en) * | 2014-11-06 | 2015-03-11 | 合肥东彩印刷科技有限公司 | Waterproof flame-retardant paint for cartons |
| CN105951517A (en) * | 2016-06-02 | 2016-09-21 | 山东源根化学技术研发有限公司 | Decorative base paper enhancer and preparation method thereof |
| CN107653738A (en) * | 2017-09-30 | 2018-02-02 | 衢州超群钙业有限公司 | A kind of powdered whiting base papermaking paint and preparation method thereof |
-
2019
- 2019-05-06 CN CN201910370924.3A patent/CN110055814A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104404822A (en) * | 2014-11-06 | 2015-03-11 | 合肥东彩印刷科技有限公司 | Waterproof flame-retardant paint for cartons |
| CN105951517A (en) * | 2016-06-02 | 2016-09-21 | 山东源根化学技术研发有限公司 | Decorative base paper enhancer and preparation method thereof |
| CN107653738A (en) * | 2017-09-30 | 2018-02-02 | 衢州超群钙业有限公司 | A kind of powdered whiting base papermaking paint and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 中国造纸学会（编）: "《中国造纸年鉴》", 30 November 2009, 中国轻工业出版社 * |
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