CN110052973A - A kind of alusil alloy bonding agent skive and its manufacturing method - Google Patents

A kind of alusil alloy bonding agent skive and its manufacturing method Download PDF

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Publication number
CN110052973A
CN110052973A CN201910385115.XA CN201910385115A CN110052973A CN 110052973 A CN110052973 A CN 110052973A CN 201910385115 A CN201910385115 A CN 201910385115A CN 110052973 A CN110052973 A CN 110052973A
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CN
China
Prior art keywords
bonding agent
alusil alloy
skive
alloy bonding
diamond
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201910385115.XA
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Chinese (zh)
Inventor
张玉斌
穆德魁
廖信江
贺琦琦
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Huaqiao University
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Huaqiao University
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Priority to CN201910385115.XA priority Critical patent/CN110052973A/en
Publication of CN110052973A publication Critical patent/CN110052973A/en
Withdrawn legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D18/00Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D3/00Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
    • B24D3/02Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent
    • B24D3/04Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially inorganic
    • B24D3/06Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially inorganic metallic or mixture of metals with ceramic materials, e.g. hard metals, "cermets", cements

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Polishing Bodies And Polishing Tools (AREA)

Abstract

The invention discloses a kind of alusil alloy bonding agent skive and its manufacturing methods, the alusil alloy bonding agent ingredient includes elemental composition by weight: Si0~30%, Ti0.25%~6%, Mg0~0.5%, Cu0~5%, Ga0~0.5%, Ce0~0.5%, Sr0~0.5%, Na0~0.5%, surplus are Al together with inevitable impurity;After the mixture cold moudling of alusil alloy bonding agent and diamond dust;Under certain sintering process, vacuum heating-press sintering is carried out, alusil alloy base diamond grinding wheel carcass is obtained;The boart boart tire body that then sintering is obtained just obtains skive of the invention on grinding wheel base body.The aluminium silicon bonding agent that the present invention uses can realize low-temperature sintering, reduce diamond thermal damage, while the introducing of activity Ti element can dramatically increase the bonding streng of diamond abrasive grain, the two improves the wear-resisting property of grinding wheel jointly, increases the service life of skive.

Description

A kind of alusil alloy bonding agent skive and its manufacturing method
Technical field
The present invention relates to sintered diamond tool manufacturing technology field, in particular to a kind of alusil alloy bonding agent diamond Grinding wheel and its manufacturing method.
Background technique
Skive is the ideal tools for being ground hard brittle material and hard alloy as a kind of super-hard abrasive tool, is grinding Important component part in system, in grinding, it is desirable that skive grinding efficiency with higher and grinding quality, I.e. high in machining efficiency, machining accuracy is high, lower wear resistance ratio and higher service life.The skive being commonly used Bonding agent has resinoid bond, metallic bond and vitrified bond.Resin bond wheel quality is softer, and when processing cannot hold By biggish stress;Metal bonded wheel has the characteristics that thermal conductivity is good, bond strength is high, long service life, but certainly because of it Sharp property is poor, is easy to limit it in the application in high-speed grinding field the disadvantages of skidding;And prepared by Technique of Vitrified Diamond Wheels The sintering temperature for crossing range request is higher, therefore larger to diamond thermal damage, significantly reduces the grinding intensity of grinding wheel.Hot pressing is burnt Connection prepares the history that metal anchoring agent diamond wheel has had more than 50 years, but the drawback one exposed in actual production Directly fail to be fully solved, to diamond hold intensity is low, diamond is easy to fall off, abrasive material it is difficult go out sword etc., strongly limit hot pressing burning Connection prepares the scope of application of skive.Above-mentioned drawback is primarily due to the covalent bond structure of diamond, is difficult and metal Bonding agent forms stronger chemical bonding, so will lead to, diamond abrasive grain is easy to fall off, so influence grinding wheel processing quality and Service life.Therefore metallic bond becomes limitation grinding wheel service life and processing quality most to the holding power of diamond abrasive grain Principal element.In order to solve this problem, carbide tungsten can be added in some metallic bonds, make diamond with Chemistry key connection is formed between bonding agent, can effectively improve the holding power of diamond, but the fusing point of tungsten is higher, sintering process In serious thermal damage can be caused to diamond.Therefore, a kind of pair of diamond is developed with higher holding power, while to diamond The small metal bonded wheel of thermal damage is extremely urgent, it will the processing performance of skive is greatly improved.
Summary of the invention
Present invention aims at existing technical problem is solved, provide a kind of alusil alloy bonding agent skive and Its manufacturing method.Using, it can be achieved that low-temperature sintering, reducing diamond the characteristics of alusil alloy matrix phase low melting point and eutectic point Damage.And in bonding agent activity Ti element addition, diamond can be soaked well, and form fine and close carbide, pole The earth improves bonding agent to the holding power of diamond abrasive grain, and the two improves the wear-resisting property of mill jointly, increases Buddha's warrior attendant stone mill The service life of disk.By adding Si element, the mechanical strength of acieral can be effectively improved, while Si is also to be carbonized by force Object formation element is able to suppress reacting for Al and diamond, moreover it is possible to reduce fusing point.By adding active element Ce, Ge, Neng Gouxian Write the antioxygenic property for improving alloy.
The present invention provides a kind of alusil alloy bonding agent skive and its manufacturing methods, overcome in background technique The defect of the heart, the technical solution adopted by the present invention to solve the technical problems are:
A kind of manufacturing method of alusil alloy bonding agent skive, is to use alusil alloy as the knot of skive Mixture, the manufacturing method the following steps are included:
1) diamond dust and alusil alloy bonding agent powder are sufficiently mixed, the alusil alloy bonding agent is by weight packet Containing following component: Si0~30%, Ti0.25%~6%, Mg0~0.5%, Cu0~5%, Ga0~0.5%, Ce0~0.5%, Sr0~0.5%, Na0~0.5%, surplus are Al together with inevitable impurity;
2) using mold of different shapes needed for boart boart tire body by said mixture cold moudling;
3) mixture of cold moudling is subjected under certain sintering process vacuum heating-press sintering, obtains boart boart tire Body;
4) the boart boart tire body sintered is obtained into skive on grinding wheel base body.
In a preferred embodiment: diamond dust is synthetic single crystal diamond powder, and diamond in the step 1) Concentration is 50%~100%, and the granularity of diamond dust is 30/35~100/120.
In a preferred embodiment: the elemental composition packet of alusil alloy bonding agent described in step 1) by weight percentage It includes, Si10~13%, Ti0.25%~6%, Mg0~0.5%, Cu0~5%, Ga0~0.5%, Ce0~0.5%, Sr0~ 0.5%, Na0~0.5%, surplus are Al together with inevitable impurity.
In a preferred embodiment: the Mg or Cu or Ga or Ce or Sr or Na, which can add, to be not added.
In a preferred embodiment: certain sintering process sintering temperature described in step 3) is between 650~1000 DEG C, pressure Power is between 50~200MPa.
In a preferred embodiment: certain sintering process is included in 700~750 DEG C of guarantors under 100~150MPa pressure Temperature 30~60 minutes, then keeps the temperature 10~30 minutes at 600~650 DEG C under 50~90MPa pressure, furnace cooling.
A kind of a kind of aluminium silicon of the basis manufacturing method manufacture of alusil alloy bonding agent skive as described above closes Golden anchoring agent diamond grinding wheel.
The beneficial effects of the present invention are: a kind of alusil alloy bonding agent skive according to the present invention and its manufacturer Method, can not only greatly reduce thermal damage's degree of diamond, and can significantly improve alloy bonding agent to diamond Holding power can be realized the sintering of boart boart tire body at a lower temperature, and effectively increase skive uses the longevity Life and processing quality, expand the application range that existing sintering process prepares metal-base diamond grinding wheel.
Specific embodiment
The contents of the present invention are illustrated below by example:
Embodiment 1
A kind of manufacturing method of alusil alloy bonding agent skive, includes the following steps:
1) by granularity be 30/35 diamond dust and alusil alloy bonding agent down payment hard rock concentration be 75% in batch mixer In be sufficiently mixed, the alusil alloy bonding agent is by weight including following component: Si30%, Ti6%, Mg0.5%, Cu5%, Ga0.5%, Ce0.5%, Sr0.5%, Na0.5%, surplus are Al together with inevitable impurity;
2) using the mold of shape needed for diamond matrix by after said mixture cold moudling, at 150MPa, 700 DEG C Heat preservation 30 minutes, then keeps the temperature 15 minutes at 90MPa, 600 DEG C, furnace cooling obtains boart boart tire body;
3) the boart boart tire body sintered is obtained into skive of the invention on grinding wheel base body.
By a kind of alusil alloy bonding agent skive obtained by the above method, alusil alloy matrix phase eutectic is utilized The characteristics of point and eutectic point, is, it can be achieved that low-temperature sintering, reduces the damage of diamond.And in bonding agent activity Ti element plus Enter, diamond can be soaked well, and form fine and close carbide, greatly improves bonding agent to the handle of diamond abrasive grain Holding force, the two improve the wear-resisting property of mill jointly, increase the service life of diamond disk.It, can be with by adding Si element The mechanical strength of acieral is effectively improved, while Si is also carbide, is able to suppress Al and diamond Reaction, moreover it is possible to reduce fusing point.By adding active element Ce, Ge, the antioxygenic property of alloy can be significantly improved.
Embodiment 2
A kind of manufacturing method of alusil alloy bonding agent skive, includes the following steps:
1) by granularity be 100/120 diamond dust and alusil alloy bonding agent down payment hard rock concentration be 50% in mixing It is sufficiently mixed in machine, which includes following component by weight: Si30%, Ti6%, Mg0.5%, Cu5%, Ga0.5%, Ce0.5%, Sr0.5%, Na0.5%, surplus are Al together with inevitable impurity;
2) using the mold of shape needed for diamond matrix by after said mixture cold moudling, at 150MPa, 750 DEG C Heat preservation 30 minutes, then keeps the temperature 15 minutes at 90MPa, 650 DEG C, furnace cooling obtains boart boart tire body;
4) the boart boart tire body sintered is obtained into skive of the invention on grinding wheel base body.
The above, two kinds of specific embodiments only of the invention, but scope of protection of the present invention is not limited thereto, Anyone skilled in the art in the technical scope disclosed by the present invention, the variation that can readily occur in or replaces It changes, should be covered by the protection scope of the present invention.Therefore, protection scope of the present invention should be with the protection model of claim The above is only a preferred embodiment of the present invention subject to enclosing, but the scope of the present invention is not limited thereto, this those skilled in the art can To readily appreciate that variation disclosed in this invention or technical scope.Alternative solution is intended to cover within the scope of the invention.Cause This, protection scope of the present invention should be determined by the scope of the claims.

Claims (7)

1. a kind of manufacturing method of alusil alloy bonding agent skive, is to use alusil alloy as the combination of skive Agent, it is characterised in that: the manufacturing method the following steps are included:
1) diamond dust and alusil alloy bonding agent powder are sufficiently mixed, the alusil alloy bonding agent by weight comprising with Lower ingredient: Si0~30%, Ti0.25%~6%, Mg0~0.5%, Cu0~5%, Ga0~0.5%, Ce0~0.5%, Sr0 ~0.5%, Na0~0.5%, surplus are Al together with inevitable impurity;
2) using mold of different shapes needed for boart boart tire body by said mixture cold moudling;
3) mixture of cold moudling is subjected under certain sintering process vacuum heating-press sintering, obtains boart boart tire body;
4) the boart boart tire body sintered is obtained into skive on grinding wheel base body.
2. a kind of manufacturing method of alusil alloy bonding agent skive according to claim 1, which is characterized in that institute Stating diamond dust in step 1) is synthetic single crystal diamond powder, and diamond concentration is 50%~100%, diamond dust Granularity be 30/35~100/120.
3. a kind of manufacturing method of alusil alloy bonding agent skive according to claim 1, which is characterized in that step It is rapid 1) described in the elemental composition of alusil alloy bonding agent by weight percentage include Si10~13%, Ti0.25%~ 6%, Mg0~0.5%, Cu0~5%, Ga0~0.5%, Ce0~0.5%, Sr0~0.5%, Na0~0.5%, surplus Al Together with inevitable impurity.
4. a kind of manufacturing method of alusil alloy bonding agent skive according to claim 1 or 3, feature exist In the Mg or Cu or Ga or Ce or Sr or Na can add and can be not added.
5. a kind of manufacturing method of alusil alloy bonding agent skive according to claim 1, which is characterized in that step It is rapid 3) described in certain sintering process sintering temperature between 650~1000 DEG C, pressure is between 50~200MPa.
6. a kind of manufacturing method of alusil alloy bonding agent skive, feature exist according to claim 1 or 5 Be included under 100~150MPa pressure in, certain sintering process and keep the temperature 30~60 minutes for 700~750 DEG C, then 50~ 10~30 minutes are kept the temperature at 600~650 DEG C under 90MPa pressure, furnace cooling.
7. a kind of a kind of aluminium silicon of the manufacturing method manufacture of alusil alloy bonding agent skive according to claim 1 Alloy anchoring agent diamond grinding wheel.
CN201910385115.XA 2019-05-09 2019-05-09 A kind of alusil alloy bonding agent skive and its manufacturing method Withdrawn CN110052973A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110153908A (en) * 2019-05-09 2019-08-23 华侨大学 A kind of alusil alloy bonding agent diamond-impregnated wheel and its manufacturing method
CN114888278A (en) * 2021-12-28 2022-08-12 江苏锋泰工具有限公司 Metal-based composite sintered material and preparation method thereof

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU409841A1 (en) * 1970-08-24 1974-01-05
JPS5654278A (en) * 1979-10-09 1981-05-14 Sumitomo Electric Industries Compound sintered body for tool and its manufacture
CN101121254A (en) * 2006-09-06 2008-02-13 佛山市地天泰磨具有限公司 Metal binding agent diamond tool and its preparation method
CN101121253A (en) * 2006-09-06 2008-02-13 佛山市地天泰磨具有限公司 Novel aluminium based metal binding agent diamond tool and its preparation method
CN101380728A (en) * 2008-09-25 2009-03-11 华侨大学 Method for increasing abrasive particles control intensity in sintered diamond agglomeration
CN101934501A (en) * 2010-08-26 2011-01-05 郑州磨料磨具磨削研究所 Self-propagating sintering metal-bonded diamond grinding wheel and preparation method thereof
CN103331703A (en) * 2013-06-13 2013-10-02 江苏亚宝车业有限公司 CBN product metallic bond and production method thereof
CN110153908A (en) * 2019-05-09 2019-08-23 华侨大学 A kind of alusil alloy bonding agent diamond-impregnated wheel and its manufacturing method

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU409841A1 (en) * 1970-08-24 1974-01-05
JPS5654278A (en) * 1979-10-09 1981-05-14 Sumitomo Electric Industries Compound sintered body for tool and its manufacture
CN101121254A (en) * 2006-09-06 2008-02-13 佛山市地天泰磨具有限公司 Metal binding agent diamond tool and its preparation method
CN101121253A (en) * 2006-09-06 2008-02-13 佛山市地天泰磨具有限公司 Novel aluminium based metal binding agent diamond tool and its preparation method
CN101380728A (en) * 2008-09-25 2009-03-11 华侨大学 Method for increasing abrasive particles control intensity in sintered diamond agglomeration
CN101934501A (en) * 2010-08-26 2011-01-05 郑州磨料磨具磨削研究所 Self-propagating sintering metal-bonded diamond grinding wheel and preparation method thereof
CN103331703A (en) * 2013-06-13 2013-10-02 江苏亚宝车业有限公司 CBN product metallic bond and production method thereof
CN110153908A (en) * 2019-05-09 2019-08-23 华侨大学 A kind of alusil alloy bonding agent diamond-impregnated wheel and its manufacturing method

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110153908A (en) * 2019-05-09 2019-08-23 华侨大学 A kind of alusil alloy bonding agent diamond-impregnated wheel and its manufacturing method
CN114888278A (en) * 2021-12-28 2022-08-12 江苏锋泰工具有限公司 Metal-based composite sintered material and preparation method thereof

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