CN110041752A - A kind of PVC edge band intaglio printing water-based ink that stability is good - Google Patents

A kind of PVC edge band intaglio printing water-based ink that stability is good Download PDF

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Publication number
CN110041752A
CN110041752A CN201910428051.7A CN201910428051A CN110041752A CN 110041752 A CN110041752 A CN 110041752A CN 201910428051 A CN201910428051 A CN 201910428051A CN 110041752 A CN110041752 A CN 110041752A
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China
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based ink
water
intaglio printing
edge band
parts
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Inventor
葛雅莉
盘茂森
曹更玉
吴文秀
莫才颂
黄扬风
林泽锋
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Guangdong University of Petrochemical Technology
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Guangdong University of Petrochemical Technology
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/006—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers provided for in C08G18/00
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

The present invention relates to a kind of good PVC edge band intaglio printing water-based ink of stability, the components including following mass parts: 30~40 parts of binder, 30~40 parts of water, 10~20 parts of pigment, 5~10 parts of auxiliary agent；The binder is modified polyurethane acrylic emulsion, and the modified polyurethane acrylic emulsion introduces hexafluoropropylene dimmer in the branch of acrylic molecules chain and hexafluoropropylene trimer, dialkyl maleate are modified.The good PVC edge band intaglio printing water-based ink of stability of the present invention has the characteristics that stability is high, adhesive force is strong and simple process.

Description

A kind of PVC edge band intaglio printing water-based ink that stability is good
Technical field
The present invention relates to a kind of good PVC edge band intaglio printing water-based inks of stability, belong to water-based ink technology neck Domain.
Background technique
In plate fitment production process, edge sealing is a procedure the most frequent, and basic process is (single with veneer Plate) edge in components is overlayed after the gluings such as item, batten, melamine, plastic strip, PVC item, ABS item, it plays waterproof, protect Shield, closing pernicious gas and reduction deformation etc. are used, while can beautify furniture.
Due to PVC edge band yield is big, price is low, it is functional, extrudability it is good, can print and paint, mesh Before be a kind of plastic edge banding that plate fitment is most widely used.And with the improvement of people's life quality, money to furniture Formula and the color diversification of demand, this requires matching edge band is colourful, decorative pattern multiplicity.It then becomes necessary to envelope Edge strip carries out the requirement that printing is just able to satisfy furniture actual use.
Although PVC is as a kind of polar macromolecule material, its adhesive property between water-based ink is poor, needs to it It is surface-treated, such as corona treatment, is just able to satisfy actual printing demand.It adheres to our company and pushes forward PVC furniture comprehensively The thinking of development of film Water-borne modification, the present invention propose that one kind without pre-treatment, can directly carry out the water-based ink of intaglio printing, mend It fills, the perfect Water-borne modification process of PVC furniture film series of products.
In view of this, it is aqueous to disclose a kind of PVC edge band intaglio printing by Chinese invention patent application CN109439064A Ink and preparation method thereof, the PVC edge band intaglio printing water-based ink are made of the raw material of following weight proportion: pigment 10 Part, 32-36 parts of resin, 1-3 parts of dispersing agent, 0.8-1.2 parts of wetting agent, 7-9 parts of cosolvent, 42.2-45.8 parts of pure water；Pass through Special formula design, ink of the present invention are not necessarily to that intaglio printing can be realized to the progress pre-treatment of PVC edge band, print levelability Good, bright in luster, clarity is good, and adhesive force is strong, perfect comprehensive Water-borne modification process of PVC furniture film series of products；Pass through The PVC edge band intaglio printing water-based ink of the optimal screening of recipe ingredient and special technology controlling and process, the invention has partial size Carefully, stable storing, the beneficial effects such as plasticizing agent migration resisting.But main binder is the poly- (methacrylic acid of PVC furniture film Methyl esters-methyl acrylate-glycidyl methacrylate) polymer resin emulsion ink resin, water solubility is poor, makes Relatively low at the adhesive force of the ink, the stability in wet environment is poor, the writing of printing be easy it is smudgy, cause compared with Big use puzzlement.
Summary of the invention
The present invention provides a kind of good PVC edge band intaglio printing water-based inks of stability, have stability height, attachment The characteristics of power is strong and simple process.
The technical solution adopted by the present invention are as follows:
The invention discloses a kind of good PVC edge band intaglio printing water-based ink of stability, the component including following mass parts: 30~40 parts of binder, 30~40 parts of water, 10~20 parts of pigment, 5~10 parts of auxiliary agent；
The binder is modified polyurethane acrylic emulsion, and the modified polyurethane acrylic emulsion is in acrylic molecules chain Branch introduces hexafluoropropylene dimmer and hexafluoropropylene trimer, dialkyl maleate are modified.
Changed by introducing hexafluoropropylene dimmer and hexafluoropropylene trimer, dialkyl maleate, fluorine in binder Property compound chain extension is carried out to the branch of binder, to increase the dissolubility of fluorine richness compound, fluorine richness compound can be with Water in moisture reacts film-forming, and the film coated surface tension of formation is low, high temperature resistant, after water-based ink printing has been effectively ensured Stability avoids ink mark is unclear in wet condition from obscuring
Further, it in the modified polyurethane acrylic emulsion, is additionally added organosilan and is modified.Since modified emulsion is simultaneous Have the advantages of polyurethane and acrylic resin, while increasing the active function groups of organosilicon, in addition to having one in lotion molecule As emulsion acrylic resin carboxyl (COO-) outside, more silylation (- SiO3 -).One silylation is equivalent to three carboxyls Activity, so the polyurethane acroleic acid lotion of this modification has interfacial energy more stronger than general emulsion acrylic resin, I.e. better adhesive force.Therefore, make the water-based ink of binder configuration with this organic-silicon-modified polyurethane acroleic acid lotion With very strong adhesive force, excellent drying property, weatherability and printing effect, it can be used in the surface print of igelite Brush.Meanwhile carboxyl (COO-) and silylation (- SiO3 -) activity with higher, convenient in conjunction with the ester group of alkyl maleates, With higher binding ability, improves and give full play to fluorine richness compound in the contribution for promoting water-based ink stability.
Further, the organosilan is γ-aminopropyltrialkoxysilane.It specifically can be according to actual selection γ- Aminopropyl trimethoxysilane and/or gamma-aminopropyl-triethoxy-silane.
Further, the quality of the hexafluoropropylene dimmer and hexafluoropropylene trimer, dialkyl maleate is institute State the 12~20% of polyurethane acroleic acid lotion.Not only guaranteed there is the effect for promoting water-based ink for the modification of binder, but also avoided The modified material excessively influence for water-based ink effective component.
Further, the pigment be selected from iron oxide yellow pigments, iron oxide red pigment, magenta pigment, titanium white powder pigment, charcoal blacks and One or more of organic yellow pigment.Flexible choice according to actual needs.
Further, the pH value of the water-based ink is 8.0~9.0.Both the too low corrosion for substrate of pH had been avoided, had also been protected Effective dissolution of pigment is demonstrate,proved.
Further, the ternary mixture and γ-aminopropyl of hexafluoropropylene dimmer, tripolymer, dialkyl maleate The molar ratio of trialkoxy silane is 0.92~0.95:1.15.γ-aminopropyltrialkoxysilane uses side slightly excessive Formula can effectively consume hexafluoropropylene dimmer, tripolymer, dialkyl maleate, unreacted γ-aminopropyl tri-alkoxy Silane can introduce silylation (- SiO for binder3 -), promote the adhesive force of water-based ink.
Further, the auxiliary agent of the water-based ink include cosolvent, stabilizer, dispersing agent, retarding agent, defoaming agent and/ Or cleaning agent.Can flexible choice according to actual needs, meet the needs of different usage scenarios.
Further, the cosolvent is selected from the mixing of one or more of ethyl alcohol, isopropanol, normal propyl alcohol Object.
Further, the dispersing agent is the alkane hydroxyl of polycarboxylic acid salt's dispersing agent, low molecular weight polycarboxylic acid polymers One or more of ammonium salt solution class dispersing agent, cellulose acetate class dispersing agent, polyacrylic acid derivative class dispersing agent Mixture.
Beneficial effects of the present invention:
The first, stability is high, by introducing hexafluoropropylene dimmer and hexafluoropropylene trimer, maleic acid dioxane in binder Base ester, fluorine richness compound carries out chain extension to the branch of binder, to increase the dissolubility of fluorine richness compound, fluorine richness Film-forming can be reacted with the water in moisture by closing object, and the film coated surface tension of formation is low, and water-based ink has been effectively ensured in high temperature resistant Stability after printing avoids ink mark is unclear in wet condition from obscuring；
The second, adhesive force is strong, and by introducing organosilan, a silylation is equivalent to the activity of three carboxyls, so this change Property polyurethane acroleic acid lotion have interfacial energy more stronger than general emulsion acrylic resin, i.e., better adhesive force, There is very strong adhesive force, excellent with the water-based ink that this organic-silicon-modified polyurethane acroleic acid lotion makees binder configuration Drying property, weatherability and printing effect；
Third, simple process, in the inventive solutions, the introducing of chitin and organosilan all occur in binder In preparation process, by being modified realization to binder, without changing the mature production technology of water-based ink.
Specific embodiment
A specific embodiment of the invention is described below with reference to embodiment, to better understand the present invention.
The invention discloses a kind of good PVC edge band intaglio printing water-based inks of stability, including following mass parts Component: 30~40 parts of binder, 30~40 parts of water, 10~20 parts of pigment, 5~10 parts of auxiliary agent；The binder is modified poly- ammonia Ester acrylic emulsion, the modified polyurethane acrylic emulsion acrylic molecules chain branch introduce hexafluoropropylene dimmer and Hexafluoropropylene trimer, dialkyl maleate are modified.
Further, it in the modified polyurethane acrylic emulsion, is additionally added organosilan and is modified.
Further, the organosilan is γ-aminopropyltrialkoxysilane.
In the present invention, modified polyurethane acrylic emulsion is by polyurethane, butyl acrylate (BA), methyl methacrylate (MMA), the polyurethane third modified by synthesizing organo-silicon after copolymerzation with cross-linking reaction and esterification such as modifier and initiator Olefin(e) acid lotion.Polyurethane be by toluene di-isocyanate(TDI) under the action of dibutyltin dilaurate by with polypropylene glycol, Methylpropanoic acid, 1,6- hexylene glycol, the aggregated obtained hydrophily of three kinds of monomers of hydroxy-ethyl acrylate and dihydromethyl propionic acid are pre- Aggressiveness, what is then obtained after the one or more neutralizer emulsion dispersion of addition ammonium hydroxide, triethanolamine and monoethanolamine is aqueous poly- Urethane aqueous dispersion.γ-aminopropyltrialkoxysilane is added using following steps in the synthesis of modifier in reaction kettle And after being passed through nitrogen 8-10min, it is warming up to 30-60 DEG C, opens and stirs and maintain mixing speed for 500-900r/min, by hexafluoro The ternary mixture of propylene dimerization body and hexafluoropropylene trimer and dialkyl maleate is added drop-wise in a kettle, is dripped Exothermic heat of reaction temperature the reaction was continued 12-24h is kept after finishing, and obtains modifier.
Further, the quality of the hexafluoropropylene dimmer and hexafluoropropylene trimer, dialkyl maleate is institute State the 12~20% of polyurethane acroleic acid lotion.
Further, the pigment be selected from iron oxide yellow pigments, iron oxide red pigment, magenta pigment, titanium white powder pigment, charcoal blacks and One or more of organic yellow pigment.
Further, the pH value of the water-based ink is 8.0~9.0.
Further, the ternary mixture and γ-aminopropyl of hexafluoropropylene dimmer, tripolymer, dialkyl maleate The molar ratio of trialkoxy silane is 0.92~0.95:1.15.
Further, the auxiliary agent of the water-based ink include cosolvent, stabilizer, dispersing agent, retarding agent, defoaming agent and/ Or cleaning agent.
Further, the cosolvent is selected from the mixing of one or more of ethyl alcohol, isopropanol, normal propyl alcohol Object.
Further, the dispersing agent is the alkane hydroxyl of polycarboxylic acid salt's dispersing agent, low molecular weight polycarboxylic acid polymers One or more of ammonium salt solution class dispersing agent, cellulose acetate class dispersing agent, polyacrylic acid derivative class dispersing agent Mixture.
Embodiment 1
The invention discloses a kind of good PVC edge band intaglio printing water-based ink of stability, the component including following mass parts: 40 parts of binder, 35 parts of water, 10 parts of pigment, 10 parts of auxiliary agent；The binder is modified polyurethane acrylic emulsion, the modification Polyurethane acroleic acid lotion introduces hexafluoropropylene dimmer and hexafluoropropylene trimer, maleic acid in the branch of acrylic molecules chain Dialkyl ester is modified.
In the present embodiment, it in the modified polyurethane acrylic emulsion, is additionally added organosilan and is modified.It is described to have Machine silane is γ-aminopropyltrialkoxysilane, specifically can be according to actual selection γ-aminopropyltrimethoxysilane.It is described The quality of hexafluoropropylene dimmer and hexafluoropropylene trimer, dialkyl maleate is the polyurethane acroleic acid lotion 16%.The pigment is iron oxide yellow pigments.The pH value of the water-based ink is 8.0~9.0.Hexafluoropropylene dimmer, tripolymer, horse The ternary mixture and γ-aminopropyltrialkoxysilane molar ratio for carrying out acid dialkyl ester are 0.92:1.15.The aqueous oil The auxiliary agent of ink includes cosolvent, stabilizer, dispersing agent, retarding agent, defoaming agent and/or cleaning agent.The cosolvent is ethyl alcohol.Institute Stating dispersing agent is polycarboxylic acid salt's dispersing agent.
Embodiment 2
The invention discloses a kind of good PVC edge band intaglio printing water-based ink of stability, the component including following mass parts: 35 parts of binder, 30 parts of water, 20 parts of pigment, 8 parts of auxiliary agent；The binder is modified polyurethane acrylic emulsion, the modification Polyurethane acroleic acid lotion introduces hexafluoropropylene dimmer and hexafluoropropylene trimer, maleic acid in the branch of acrylic molecules chain Dialkyl ester is modified.
In the present embodiment, it in the modified polyurethane acrylic emulsion, is additionally added organosilan and is modified.It is described to have Machine silane is γ-aminopropyltrialkoxysilane, specifically can be according to actual selection gamma-aminopropyl-triethoxy-silane.It is described The quality of hexafluoropropylene dimmer and hexafluoropropylene trimer, dialkyl maleate is the polyurethane acroleic acid lotion 12%.The pigment is iron oxide red pigment.The pH value of the water-based ink is 8.0~9.0.Hexafluoropropylene dimmer, tripolymer, horse The ternary mixture and γ-aminopropyltrialkoxysilane molar ratio for carrying out acid dialkyl ester are 0.95:1.15.The aqueous oil The auxiliary agent of ink includes cosolvent, stabilizer, dispersing agent, retarding agent, defoaming agent and/or cleaning agent.The cosolvent is isopropanol. The dispersing agent is the alkane hydroxylammonium salts solution class dispersing agent of low molecular weight polycarboxylic acid polymers.
Embodiment 3
The invention discloses a kind of good PVC edge band intaglio printing water-based ink of stability, the component including following mass parts: 30 parts of binder, 40 parts of water, 15 parts of pigment, 5 parts of auxiliary agent；The binder is modified polyurethane acrylic emulsion, the modification Polyurethane acroleic acid lotion introduces hexafluoropropylene dimmer and hexafluoropropylene trimer, maleic acid in the branch of acrylic molecules chain Dialkyl ester is modified.
In the present embodiment, it in the modified polyurethane acrylic emulsion, is additionally added organosilan and is modified.It is described to have Machine silane is γ-aminopropyltrialkoxysilane, specifically can be according to actual selection γ-aminopropyltrimethoxysilane and γ- Aminopropyl triethoxysilane.The quality of the hexafluoropropylene dimmer and hexafluoropropylene trimer, dialkyl maleate is The 20% of the polyurethane acroleic acid lotion.The pigment is magenta pigment.The pH value of the water-based ink is 8.0~9.0.Six Fluoropropene dimer, tripolymer, the ternary mixture of dialkyl maleate and γ-aminopropyltrialkoxysilane molar ratio For 0.93:1.15.The auxiliary agent of the water-based ink includes cosolvent, stabilizer, dispersing agent, retarding agent, defoaming agent and/or cleaning Agent.The cosolvent is normal propyl alcohol.The dispersing agent is cellulose acetate class dispersing agent.
Embodiment 4
The invention discloses a kind of good PVC edge band intaglio printing water-based ink of stability, the component including following mass parts: 38 parts of binder, 32 parts of water, 18 parts of pigment, 8 parts of auxiliary agent；The binder is modified polyurethane acrylic emulsion, the modification Polyurethane acroleic acid lotion introduces hexafluoropropylene dimmer and hexafluoropropylene trimer, maleic acid in the branch of acrylic molecules chain Dialkyl ester is modified.
In the present embodiment, it in the modified polyurethane acrylic emulsion, is additionally added organosilan and is modified.It is described to have Machine silane is γ-aminopropyltrialkoxysilane, specifically can be according to actual selection γ-aminopropyltrimethoxysilane or γ- Aminopropyl triethoxysilane.The quality of the hexafluoropropylene dimmer and hexafluoropropylene trimer, dialkyl maleate is The 14% of the polyurethane acroleic acid lotion.The pigment is organic yellow pigment.The pH value of the water-based ink is 8.0~9.0. Hexafluoropropylene dimmer, tripolymer, dialkyl maleate ternary mixture and γ-aminopropyltrialkoxysilane mole Than for 0.94:1.15.The auxiliary agent of the water-based ink includes cosolvent, stabilizer, dispersing agent, retarding agent, defoaming agent and/or clear Lotion.The cosolvent is the mixture of ethyl alcohol, normal propyl alcohol.The dispersing agent is polycarboxylic acid salt's dispersing agent, polyacrylic acid spreads out The mixture of biological species dispersing agent.
Embodiment 5
The invention discloses a kind of good PVC edge band intaglio printing water-based ink of stability, the component including following mass parts: 33 parts of binder, 37 parts of water, 13 parts of pigment, 7 parts of auxiliary agent；The binder is modified polyurethane acrylic emulsion, the modification Polyurethane acroleic acid lotion introduces hexafluoropropylene dimmer and hexafluoropropylene trimer, maleic acid in the branch of acrylic molecules chain Dialkyl ester is modified.
In the present embodiment, it in the modified polyurethane acrylic emulsion, is additionally added organosilan and is modified.It is described to have Machine silane is γ-aminopropyltrialkoxysilane, specifically can be according to actual selection γ-aminopropyltrimethoxysilane or γ- Aminopropyl triethoxysilane.The quality of the hexafluoropropylene dimmer and hexafluoropropylene trimer, dialkyl maleate is The 18% of the polyurethane acroleic acid lotion.The pigment is iron oxide yellow pigments, iron oxide red pigment, magenta pigment and organic yellow pigment.Institute The pH value for stating water-based ink is 8.0~9.0.Hexafluoropropylene dimmer, tripolymer, dialkyl maleate ternary mixture with γ-aminopropyltrialkoxysilane molar ratio is 0.94:1.15.The auxiliary agent of the water-based ink include cosolvent, stabilizer, Dispersing agent, retarding agent, defoaming agent and/or cleaning agent.The cosolvent is selected from ethyl alcohol, isopropanol, normal propyl alcohol.The dispersing agent For polycarboxylic acid salt's dispersing agent, alkane hydroxylammonium salts solution class dispersing agent, the cellulose acetate of low molecular weight polycarboxylic acid polymers Class dispersing agent, polyacrylic acid derivative class dispersing agent.
Embodiment 6
Embodiment 6 is the difference from embodiment 1 is that replace iron oxide yellow pigments with titanium white powder pigment.
Embodiment 7
Embodiment 7 is the difference from embodiment 1 is that replace iron oxide yellow pigments with charcoal blacks.
Comparative example 1
The difference of comparative example 1 and embodiment 4 is that organosilan, which is not added, to be modified.
Comparative example 2
The difference of comparative example 2 and embodiment 4 is that hexafluoropropylene dimmer, hexafluoropropylene trimer, maleic acid two is not added Arrcostab is modified.
Comparative example 3
The difference of comparative example 3 and embodiment 4 is that organosilan and hexafluoropropylene dimmer, hexafluoropropene trimerization is not added Body, dialkyl maleate are modified.
Performance of the invention for further evaluation, is respectively tested for the property embodiment and comparative example, concrete outcome It is as shown in table 1:
1 the performance test results of table
Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5 Comparative example 1 Comparative example 2 Comparative example 3
Adhesive force grade 0 0 0 0 0 2 1 2
First stemness (mm) 18-20 18-20 18-20 18-20 18-20 15-17 16-18 15-17
Water resistance 5 5 5 5 5 4 4 3
Boiling water resistance It is qualified It is qualified It is qualified It is qualified It is qualified It is unqualified It is unqualified It is unqualified
Print writing readability (water impregnates for 24 hours) Clear writing Clear writing Clear writing Clear writing Clear writing The handwriting is blurred The handwriting is blurred The handwriting is blurred
Print writing readability (water impregnates 72h) Clear writing Clear writing Clear writing Clear writing Clear writing The handwriting is blurred The handwriting is blurred The handwriting is blurred
The above is a preferred embodiment of the present invention, it is noted that for those skilled in the art, Various improvements and modifications may be made without departing from the principle of the present invention, these improvements and modifications are also considered as this hair Bright protection scope.

Claims (10)

1. a kind of good PVC edge band intaglio printing water-based ink of stability, it is characterised in that the component including following mass parts: 30~40 parts of binder, 30~40 parts of water, 10~20 parts of pigment, 5~10 parts of auxiliary agent；
The binder is modified polyurethane acrylic emulsion, and the modified polyurethane acrylic emulsion is in acrylic molecules chain Branch introduces hexafluoropropylene dimmer and hexafluoropropylene trimer, dialkyl maleate are modified.
2. the good PVC edge band intaglio printing water-based ink of stability according to claim 1, it is characterised in that: described In modified polyurethane acrylic emulsion, it is additionally added organosilan and is modified.
3. the good PVC edge band intaglio printing water-based ink of stability according to claim 2, it is characterised in that: described Organosilan is γ-aminopropyltrialkoxysilane.
4. the good PVC edge band intaglio printing water-based ink of stability according to claim 3, it is characterised in that: described The quality of hexafluoropropylene dimmer and hexafluoropropylene trimer, dialkyl maleate is the 12 of the polyurethane acroleic acid lotion ~20%.
5. the good PVC edge band intaglio printing water-based ink of stability according to claim 1, it is characterised in that: described Pigment be selected from one of iron oxide yellow pigments, iron oxide red pigment, magenta pigment, titanium white powder pigment, charcoal blacks and organic yellow pigment or It is two or more.
6. the good PVC edge band intaglio printing water-based ink of stability according to claim 5, it is characterised in that: described The pH value of water-based ink is 8.0~9.0.
7. the good PVC edge band intaglio printing water-based ink of stability according to claim 6, it is characterised in that: hexafluoro Propylene dimerization body, tripolymer, dialkyl maleate ternary mixture and γ-aminopropyltrialkoxysilane molar ratio be 0.92~0.95:1.15.
8. the good PVC edge band intaglio printing water-based ink of stability according to claim 7, it is characterised in that: described The auxiliary agent of water-based ink includes cosolvent, stabilizer, dispersing agent, retarding agent, defoaming agent and/or cleaning agent.
9. the good PVC edge band intaglio printing water-based ink of stability according to claim 8, it is characterised in that: described Cosolvent is selected from the mixture of one or more of ethyl alcohol, isopropanol, normal propyl alcohol.
10. the good PVC edge band intaglio printing water-based ink of stability according to claim 9, it is characterised in that: described Dispersing agent is alkane hydroxylammonium salts solution class dispersing agent, the acetic acid of polycarboxylic acid salt's dispersing agent, low molecular weight polycarboxylic acid polymers The mixture of one or more of cellulose family dispersing agent, polyacrylic acid derivative class dispersing agent.
CN201910428051.7A 2019-05-22 2019-05-22 A kind of PVC edge band intaglio printing water-based ink that stability is good Pending CN110041752A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110561935A (en) * 2019-09-10 2019-12-13 金石包装（嘉兴）有限公司 gravure printing method adopting water-based ink

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004250637A (en) * 2003-02-21 2004-09-09 Asia Kogyo Kk Water-based topcoating material composition
CN104017479A (en) * 2014-06-24 2014-09-03 博罗县石湾美源涂料有限公司 Bicomponent silicofluoride acrylic polyurethane coating as well as preparation and application methods thereof
CN104910383A (en) * 2010-07-12 2015-09-16 Dic株式会社 Inorganic fine particle dispersion liquid, inorganic fine particle dispersion, paint and cured product
CN107286746A (en) * 2017-07-28 2017-10-24 广东石油化工学院 A kind of high adhesion force water-based ink printed applied to PVC
US20170342288A1 (en) * 2014-12-19 2017-11-30 Dic Corporation Water-based ink for inkjet recording
CN109293846A (en) * 2018-09-19 2019-02-01 江苏三木化工股份有限公司 The preparation method of fluorinated silicone modified multi-arm type polyurethane-hydroxy acrylate lotion

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004250637A (en) * 2003-02-21 2004-09-09 Asia Kogyo Kk Water-based topcoating material composition
CN104910383A (en) * 2010-07-12 2015-09-16 Dic株式会社 Inorganic fine particle dispersion liquid, inorganic fine particle dispersion, paint and cured product
CN104017479A (en) * 2014-06-24 2014-09-03 博罗县石湾美源涂料有限公司 Bicomponent silicofluoride acrylic polyurethane coating as well as preparation and application methods thereof
US20170342288A1 (en) * 2014-12-19 2017-11-30 Dic Corporation Water-based ink for inkjet recording
CN107286746A (en) * 2017-07-28 2017-10-24 广东石油化工学院 A kind of high adhesion force water-based ink printed applied to PVC
CN109293846A (en) * 2018-09-19 2019-02-01 江苏三木化工股份有限公司 The preparation method of fluorinated silicone modified multi-arm type polyurethane-hydroxy acrylate lotion

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110561935A (en) * 2019-09-10 2019-12-13 金石包装（嘉兴）有限公司 gravure printing method adopting water-based ink

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Application publication date: 20190723