CN110041019A - A kind of preparation method of the concrete material of chimeric negative poisson's ratio foam - Google Patents

A kind of preparation method of the concrete material of chimeric negative poisson's ratio foam Download PDF

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Publication number
CN110041019A
CN110041019A CN201910388070.1A CN201910388070A CN110041019A CN 110041019 A CN110041019 A CN 110041019A CN 201910388070 A CN201910388070 A CN 201910388070A CN 110041019 A CN110041019 A CN 110041019A
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China
Prior art keywords
negative poisson
ratio
foam
mortar
ratio foam
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CN201910388070.1A
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Chinese (zh)
Inventor
任鑫
王仕龙
张相玉
韩传镇
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Nanjing Tech University
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Nanjing Tech University
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Priority to CN201910388070.1A priority Critical patent/CN110041019A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Forms Removed On Construction Sites Or Auxiliary Members Thereof (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention discloses a kind of preparation methods of the concrete material of chimeric negative poisson's ratio foam, belong to functional new material technology field.Operation of the present invention step are as follows: firstly, preparing the negative poisson's ratio foamed material of function admirable;Then, the influence in such a way that finite element model is come Parametric Analysis froth bed thickness, polymer cement mortar type, the two relative thickness and build-in etc. to New Style Concrete Materials performance, chooses optimal parameter combination;Finally, being conserved to the new concrete using mold build-in.Operation of the present invention is simple, and substrate used is cheap, and concrete surface has been effectively relieved cracks and flakes off problem, has great commercial application prospect.

Description

A kind of preparation method of the concrete material of chimeric negative poisson's ratio foam
Technical field
It the present invention relates to the use of negative poisson's ratio foamed material and design a kind of New Style Concrete Materials for being not easy to crack and flake off Method, belong to new material and new construction field.
Background technique
Reinforced concrete structure is a kind of structure type very widely used in building structure, is had cheap and steady Qualitative good feature, will long-term existence in the infrastructure construction in China.But concrete due to material, match ratio with And crack and flake off phenomenon caused by the problems in work progress and can be found everywhere, it greatly affected concrete material in building work Application in journey.
1987, conventional polyurethanes foam was put into aluminium-making mould by American scholar Lakes, right again after the three-dimensional compression of progress It is heated, is cooled down and relaxation processes, the auxetic polyurethane foam that Poisson's ratio is -0.7 has been made, this is first in the world Made auxetic foamed plastics.Since then, the research of auxetic foam starts active.Currently, negative poisson's ratio foamed material Type is increasingly various, preparation process is also greatly improved, and has the characteristics that preparation is convenient and low in cost.With conventional solid material Material is compared, and foamed material has excellent specific strength, specific stiffness, good buffering energy-absorbing, rich and changeful size and inside The advantages that micro-structure, is provided simultaneously with the functions such as filtration of sound, sound insulation, heat-insulated, humidity, can meet more under some extreme service environments Functional requirement.The new material kind that negative poisson's ratio foamed material has a high potential as one, be expected to be applied to textile, industry, Space flight, protection, biomedicine, sensor and other fields.
The introducing of negative poisson's ratio material can be effectively improved the stress distribution and cracking phenomena of concrete surface in concrete. There is both sides advantage in the negative poisson's ratio foamed material that is wrapped laterally of the concrete material of axial compression: on the one hand, coagulation When being pressurized lateral expansion can occur for soil material, can generate pressure to the negative poisson's ratio foamed material for being wrapped in external, make negative pool Pine assembles than material to compressive region, can play effect of contraction to the cracking of concrete;On the other hand, it can reduce since concrete is opened Split the pollution of the dust and particulate matter that peel off and generate to environment.Negative poisson's ratio material is widely used to various industries and takes at present Preferable effect is obtained, while various New Style Concrete Materials and concrete composite material emerge one after another.The present invention is by negative pool Pine is effectively combined than foamed material and concrete material, the advantage of two kinds of materials is utmostly played, so that development of new is embedding Close the concrete material of negative poisson's ratio foam.
Summary of the invention
The purpose of the present invention is in view of the defects existing in the prior art, by negative poisson's ratio foamed material and the organic knot of concrete It closes, has designed and prepared a kind of chimeric negative poisson's ratio foam volume New Style Concrete Materials, and propose specific implementation method, compared with Conventional concrete material has preferably anti-layering and anti-flaking energy.
The technical solution adopted by the invention is as follows: a kind of preparation method of the concrete material of chimeric negative poisson's ratio foam, The following steps are included:
Step 1: selecting conventional polyurethanes foamed plastics is basic material, prepares negative poisson's ratio foam using thermomechanometry: Firstly, being V by volume0Polyurethane foam be put into the aluminum grinding tool that volume is V, and in its surface coating lubricating oil;Then, After baking oven is preheated to temperature T, it is put into compressed foam and mold, volume compression ratio P;Finally, heating time t takes out, go It is light that the removal of foam is drawn to bond resistance except mold;
It will be heated to the softened temperature T of usual foam after foam compression, its compression is made to generate concave inward structure, cell after cooling Rib solidification, and compression shape is kept, to have Negative poisson's ratio;
Step 2: selecting polymer cement mortar, control ratio of mud W/C and aggregate prepares premixing cement mortar;Using having Finite element analysis software controls the thickness d of negative poisson's ratio foam, changes negative poisson's ratio foam and mortar build-in mode, analyzes coagulation The performance of soil;
Step 3: negative poisson's ratio foam and mortar mix ratio according to determined by step 1 and step 2, with the side's pvc plastic tube For mold, it is put into negative poisson's ratio foam and mortar in a manner of determining build-in, removes mold after air-drying one day, it is solid in drinking water Change one week;Obtain the concrete material of chimeric negative poisson's ratio foam.
Preferably, conventional polyurethanes foamed plastics is closed pore polyester-polyurethane foam in the step 1, reticulated polyester gathers At least one of urethane foam, aperture polyether-polyurethane foam.
Preferably, lubricating oil selects olive oil in the step 1, avoid after being heated in an oven using conventional lubricating oil The irritation peculiar smell of generation.
Preferably, in the step 2 polymer cement mortar be fiber reinforced cement mortar, Polymer-Modified Mortar, One of general polymer cement mortar.
Preferably, conventional polyurethanes foam plastic density ρ in the step 1 are as follows: 20kg/m3<ρ<200kg/m3
Preferably, in the step 1 baking oven control temperature T, heating time t and compression ratio P are as follows: 175 ± 7 DEG C < T < 200±6℃;6±0.5min<t<11±0.2min;2<P<5.
Preferably, the polymer cement mortar ratio of mud in the step 2 are as follows: 0.15 < W/C < 0.25.
Preferably, the thickness d of negative poisson's ratio foam meets in the step 2 are as follows: 5mm < d < 25mm.
Preferably, in the step 3 negative poisson's ratio foam and mortar build-in mode are as follows: negative poisson's ratio foam-mortar- Negative poisson's ratio foam, mortar-negative poisson's ratio foam-mortar-negative poisson's ratio foam-mortar, mortar-negative poisson's ratio foam-mortar.
Preferably, the usable vinyl acetate-ethylene of negative poisson's ratio foam and concrete joint is in the step 3 Interfacial bonder.
The utility model has the advantages that the present invention is that basic material prepares negative poisson's ratio using cheap conventional polyurethanes foamed plastics Foam is prepared as New Style Concrete Materials with polymer mortar.When being compressed axially due to negative poisson's ratio foam, vertical direction It can expand outward, wrap up concrete column using this effect, more traditional positive Poisson ratio material can be better protected from concrete delamination And peeling.And change the build-in mode of concrete composite material and the thickness of negative poisson's ratio foam according to different mortar, it can be with It is carried out under different operating conditions using will be with wide commercial application prospect after putting goods on the market.
Detailed description of the invention
Flow chart Fig. 1 of the invention.
Fig. 2 is the polyurethane foam with negative poisson's ratio property.
Fig. 3 is the ideal cell of negative poisson's ratio foam rotary unit.
Specific embodiment
The present invention is further illustrated with reference to the accompanying drawings and detailed description:
Embodiment 1 is 60ppi closed pore polyester-polyurethane foam, negative poisson's ratio foam is prepared as using thermomechanometry, with fibre The method that dimension reinforced cement mortar prepares a kind of New Style Concrete Materials of chimeric negative poisson's ratio foam.It is as shown in Figs. 1-3:
1. taking 60ppi closed-cell polyurethane foam for basic raw material, olive oil is smeared as lubrication on aluminium-making mould surface Volume is V by oil0Polyurethane foam be put into volume be V aluminum grinding tool in;Baking oven is preheated to 200 ± 5.6 DEG C of temperature Afterwards, it is put into compressed foam and mold, is taken out after heating time 11min, mold is removed, it is light to draw the removal of foam bonding resistance simultaneously It places for 24 hours.
2. fiber reinforced cement mortar is selected, by graded sand, high early strength canescence portland cement and natural fiber In the premixing cement mortar that small age is formulated, control the ratio of mud: 20 kilograms of cement 3-5 rise water.Use heated filament saw i.e. one Steel wire is heated with power supply, in this approach, the path that the heat melts of electric current pass through foam.Cut the thickness of negative poisson's ratio foam Spend 20mm.
3. release agent is smeared on surface, using the side's PVC plastic tube as mold with negative poisson's ratio foam-mortar-negative poisson's ratio foam Build-in mode, be first put into negative poisson's ratio foam and exist being close to die location, then pour into premixing cement mortar.It is gone after air-drying one day Except mold, solidify one week in drinking water.Obtain the New Style Concrete Materials of chimeric negative poisson's ratio foam.
Embodiment 2 is 30ppi open-celled polyurethane foam, negative poisson's ratio foam is prepared as using thermomechanometry, with polymer The method that modified cement mortar prepares a kind of New Style Concrete Materials of chimeric negative poisson's ratio foam.It is as shown in Figs. 1-3:
1. taking 30ppi aperture polyester-polyurethane foam for basic raw material, olive oil conduct is smeared on aluminium-making mould surface Volume is V by lubricating oil0Polyurethane foam be put into volume be V aluminum grinding tool in;Baking oven is preheated to temperature 175 ± 5.5 After DEG C, it is put into compressed foam and mold, is taken out after heating time 7min, removes mold, it is light that the removal of foam is drawn to bond resistance And it places for 24 hours.
2. fiber reinforced cement mortar is selected, by graded sand, canescence portland cement and polymeric additive (1.25%) the modified bonding base coating of the gelling polymer formed, control the ratio of mud: 20 kilograms of cement 3-5 rise water.Use heat Silk saw is a steel wire, is heated with power supply.In this approach, due to path that the heat melts of electric current pass through foam.Cutting The thickness 15mm of negative poisson's ratio foam.
3. release agent is smeared on surface, using the side's PVC plastic tube as mold with mortar-negative poisson's ratio foam-negative Poisson of mortar- Than foam-mortar build-in mode, negative poisson's ratio foam first is put into abutting die location and is existed, then pours into premixing cement mortar. Mold is removed after air-drying one day, is solidified one week in drinking water.Obtain the New Style Concrete Materials of chimeric negative poisson's ratio foam.
Embodiment 3 is 60ppi aperture polyether-polyurethane foam, is prepared as negative poisson's ratio foam using thermomechanometry, and poly- Close the method that object cement mortar prepares a kind of New Style Concrete Materials of chimeric negative poisson's ratio foam.It is as shown in Figs. 1-3:
1. taking 60ppi open-celled polyurethane foam for basic raw material, olive oil is smeared as lubrication on aluminium-making mould surface Volume is V by oil0Polyurethane foam be put into volume be V aluminum grinding tool in;Air dry oven is preheated to 182 DEG C of temperature After ± 7.3 DEG C, it is put into compressed foam and mold, is taken out after heating time 6min, removes mold, it is light to draw the removal of foam bonding Resistance is simultaneously placed for 24 hours.
2. selecting fiber reinforced cement mortar, a kind of cement base low performance mending mortar contains portland cement, polymer Powder, particulate graded sand and silicon ash, control the ratio of mud: 0.5-1.0 rises water, 20 kilograms of cement.The use of heated filament saw is a steel wire, uses Power supply heating.In this approach, due to path that the heat melts of electric current pass through foam.Cut the thickness of negative poisson's ratio foam For 15mm.
3. release agent is smeared on surface, using the side's PVC plastic tube as mold with mortar-negative poisson's ratio foam-mortar build-in side Formula is first put into negative poisson's ratio foamed material in abutting die location, then pours into premixing cement mortar.Mould is removed after air-drying one day Tool, solidifies one week in drinking water.Obtain the New Style Concrete Materials of chimeric negative poisson's ratio foam.
It should be pointed out that for those skilled in the art, without departing from the principle of the present invention, Several improvements and modifications can also be made, these modifications and embellishments should also be considered as the scope of protection of the present invention.It is unknown in this example The available prior art of true each component part is realized.

Claims (10)

1. a kind of preparation method of the concrete material of chimeric negative poisson's ratio foam, it is characterised in that: the following steps are included:
Step 1: selecting conventional polyurethanes foamed plastics is basic material, prepares negative poisson's ratio foam using thermomechanometry: firstly, It is V by volume0Polyurethane foam be put into the aluminum grinding tool that volume is V, and in its surface coating lubricating oil;Then, baking oven After being preheated to temperature T, it is put into compressed foam and mold, volume compression ratio P;Finally, heating time t takes out, mould is removed Tool is light that the removal of foam is drawn to bond resistance;
It will be heated to the softened temperature T of usual foam after foam compression, so that its compression is generated concave inward structure, cell rib is solid after cooling Change, and keep compression shape, to have Negative poisson's ratio;
Step 2: selecting polymer cement mortar, control ratio of mud W/C and aggregate prepares premixing cement mortar;Using finite element Software is analyzed, the thickness d of negative poisson's ratio foam is controlled, changes negative poisson's ratio foam and mortar build-in mode, analyzes concrete Performance;
Step 3: negative poisson's ratio foam and mortar mix ratio according to determined by step 1 and step 2, using the side's pvc plastic tube as mould Tool, is put into negative poisson's ratio foam and mortar in a manner of determining build-in, removes mold after air-drying one day, solidifies one in drinking water Week;Obtain the concrete material of chimeric negative poisson's ratio foam.
2. a kind of preparation method of the concrete material of chimeric negative poisson's ratio foam according to claim 1, feature exist In: conventional polyurethanes foamed plastics is closed pore polyester-polyurethane foam, reticulated polyester polyurethane foam, aperture in the step 1 At least one of polyether-polyurethane foam.
3. a kind of preparation method of the concrete material of chimeric negative poisson's ratio foam according to claim 1, feature exist In: lubricating oil selects olive oil in the step 1.
4. a kind of preparation method of the concrete material of chimeric negative poisson's ratio foam according to claim 1, feature exist In: polymer cement mortar is fiber reinforced cement mortar, Polymer-Modified Mortar, general polymer cement in the step 2 One of mortar.
5. a kind of preparation method of the concrete material of chimeric negative poisson's ratio foam according to claim 1, feature exist In: conventional polyurethanes foam plastic density ρ in the step 1 are as follows: 20kg/m3<ρ<200kg/m3
6. a kind of preparation method of the concrete material of chimeric negative poisson's ratio foam according to claim 1, feature exist In: control temperature T, heating time t and the compression ratio P of baking oven in the step 1 are as follows: 175 ± 7 DEG C < T < 200 ± 6 DEG C;6± 0.5min<t<11±0.2min;2<P<5.
7. a kind of preparation method of the concrete material of chimeric negative poisson's ratio foam according to claim 1, feature exist In: the polymer cement mortar ratio of mud in the step 2 are as follows: 0.15 < W/C < 0.25.
8. a kind of preparation method of the concrete material of chimeric negative poisson's ratio foam according to claim 1, feature exist In: the thickness d of negative poisson's ratio foam meets in the step 2 are as follows: 5mm < d < 25mm.
9. a kind of preparation method of the concrete material of chimeric negative poisson's ratio foam according to claim 1, feature exist In: the build-in mode of negative poisson's ratio foam and mortar in the step 3 are as follows: negative poisson's ratio foam-mortar-negative poisson's ratio foam, Mortar-negative poisson's ratio foam-mortar-negative poisson's ratio foam-mortar, mortar-negative poisson's ratio foam-mortar.
10. a kind of preparation method of the concrete material of chimeric negative poisson's ratio foam according to claim 1, feature exist In: it is interfacial bonder that negative poisson's ratio foam and concrete joint, which use vinyl acetate-ethylene, in the step 3.
CN201910388070.1A 2019-05-10 2019-05-10 A kind of preparation method of the concrete material of chimeric negative poisson's ratio foam Pending CN110041019A (en)

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Cited By (3)

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Publication number Priority date Publication date Assignee Title
CN113816676A (en) * 2021-09-06 2021-12-21 青岛理工大学 Negative Poisson's ratio cement-based composite material and preparation method thereof
JP2023518102A (en) * 2020-04-15 2023-04-27 スマート・マテリアルズ・リミテッド Method for synthesizing auxetic polyurethane foam having prescribed cell structure and auxetic polyurethane foam obtained by the method
US11873637B2 (en) 2022-02-15 2024-01-16 Joon Bu Park Bricks exhibiting negative Poisson's ratio

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2023518102A (en) * 2020-04-15 2023-04-27 スマート・マテリアルズ・リミテッド Method for synthesizing auxetic polyurethane foam having prescribed cell structure and auxetic polyurethane foam obtained by the method
JP7474865B2 (en) 2020-04-15 2024-04-25 スマート・マテリアルズ・リミテッド Method for synthesizing auxetic polyurethane foams having defined cell structure and auxetic polyurethane foams obtained by said method
CN113816676A (en) * 2021-09-06 2021-12-21 青岛理工大学 Negative Poisson's ratio cement-based composite material and preparation method thereof
CN113816676B (en) * 2021-09-06 2022-05-31 青岛理工大学 Negative Poisson's ratio cement-based composite material and preparation method thereof
WO2023030303A1 (en) * 2021-09-06 2023-03-09 青岛理工大学 Cement-based composite material having negative poisson's ratio, and preparation method therefor
US11873637B2 (en) 2022-02-15 2024-01-16 Joon Bu Park Bricks exhibiting negative Poisson's ratio

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Application publication date: 20190723