CN110029334A - A kind of production method of high tin steel bead wire - Google Patents
A kind of production method of high tin steel bead wire Download PDFInfo
- Publication number
- CN110029334A CN110029334A CN201910285806.2A CN201910285806A CN110029334A CN 110029334 A CN110029334 A CN 110029334A CN 201910285806 A CN201910285806 A CN 201910285806A CN 110029334 A CN110029334 A CN 110029334A
- Authority
- CN
- China
- Prior art keywords
- bead wire
- steel bead
- pickling
- production method
- high tin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/18—Pretreatment of the material to be coated
- C23C18/1803—Pretreatment of the material to be coated of metallic material surfaces or of a non-specific material surfaces
- C23C18/1824—Pretreatment of the material to be coated of metallic material surfaces or of a non-specific material surfaces by chemical pretreatment
- C23C18/1837—Multistep pretreatment
- C23C18/1844—Multistep pretreatment with use of organic or inorganic compounds other than metals, first
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/31—Coating with metals
- C23C18/38—Coating with copper
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/08—Iron or steel
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/08—Iron or steel
- C23G1/081—Iron or steel solutions containing H2SO4
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25F—PROCESSES FOR THE ELECTROLYTIC REMOVAL OF MATERIALS FROM OBJECTS; APPARATUS THEREFOR
- C25F1/00—Electrolytic cleaning, degreasing, pickling or descaling
- C25F1/02—Pickling; Descaling
- C25F1/04—Pickling; Descaling in solution
- C25F1/06—Iron or steel
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Electrochemistry (AREA)
- Inorganic Chemistry (AREA)
- Electroplating Methods And Accessories (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Abstract
The present invention provides a kind of production method of high tin steel bead wire, and the production method is the following steps are included: pickling, cathodic pickling, electroless copper, neutralization, hot water wash and dry, oiling；The high tin steel bead wire of preparation: diameter 0.96-1.20mm, 0.09-0.5 μm of copper coating thickness, tin percentage 9-12%.The pickling: pickling solution uses 120-180g/L hydrochloric acid or 210-330g/L sulfuric acid.Speed of production of the present invention is fast, the high tin steel bead wire finished product tin percentage 9-12% of preparation, and quality is stable, reliable.
Description
Technical field
The present invention relates to steel bead wire production and processing field more particularly to a kind of production methods of high tin steel bead wire.
Background technique
Steel bead wire generallys use bronze, brass, red copper as coating, with the development of steel bead wire industry, red copper plating
Layer steel wire is not recommended to use, is abandoned substantially by tire plant.Low tin bronze steel bead wire is largely used by tire plant, but is gradually in
Existing the phenomenon that drug on the market, Market competition, profit decline.But supply falls short of demand for high-tin bronze steel bead wire, profit margin compared with
Greatly.
High tin steel bead wire generally requires Theil indices 10% or so.Since coating Theil indices are higher, production control difficulty is very
Greatly.High tin requirement is not achieved in generalization plating, to reach high tin requirement, need to use plating replacementization plating.And the plating of electroplating device ratioization is set
Standby land occupation is big, and disposable investment is big, and copper plating rate is slow.
If useization is plated, the stannous sulfate concentration that high tin plating solution needs is significantly raised, stannous sulfate easy oxygen in the plating solution
Change, hydrolysis, causes tin concentration in plating solution unstable.Therefore, the prior art is to be improved.
CN201010183053.3 is suitable for the plating solution of plating high tin bronze coating on bead wire surface in chemical replacement mode, by leading
Salt, activator, stabilizer, adjuvant and five part of water are formed: main salt is by two kinds of sulfate of cupric sulfate pentahydrate and stannous sulfate
Composition, wherein cupric sulfate pentahydrate content is 10 ~ 30g/L, and stannous sulfate is 5 ~ 20g/L, and cupric sulfate pentahydrate and stannous sulfate
Mass ratio is maintained in 1.0 ~ 2.5 ranges；Activator uses 98% concentrated sulfuric acid, content 100-160g/L；Stabilizer uses
Five kinds of isonicotinic acid, aspartic acid, tartaric acid, citric acid and ascorbic acid ingredients press 0.1 ~ 0.2: 0.5 ~ 1: 0.5 ~ 1: 0.5 ~ 1:
0.01 ~ 0.05 mass ratio mixes, content 20-40g/L；Adjuvant uses neopelex, to benzene two
Five kinds of phenol, catechol, resorcinol and Macrogol 4000 ingredients press 0.5 ~ 1: 0.05 ~ 0.1: 0.05 ~ 0.1: 0.05 ~ 0.1:
0.1 ~ 0.2 mass ratio mixes, content 1-10g/L.
CN201410030324.X tempered bead steel wire surface chemical plating high-tin bronze plating solution and its electroless plated method, it is public
A kind of tempered bead steel wire surface chemical plating high-tin bronze plating solution and its electroless plated method are opened, the plating solution is by main salt, 15-
65g/L stabilizer, 0.01-10g/L complexing agent and solvent composition, according to the plating solution composition proportional arrangement electroless solution and by this
It, can stability contorting tempered bead steel wire chemical plating bronze plating thickness after electroless plated method is invented to tempered bead steel wire plating
For 1.5-2.5 μm, the coating and mass percent of tempered bead steel wire is 0.15-0.80g/kg, stanniferous amount is up to 8- in coating
12%, it is easy to operate without using plating, it is easy to control, it is at low cost, and plating solution has certain inoxidizability, is not easy muddiness, no
Acid mist is generated, maintenance cost is reduced, coating effect is good.
A kind of steel bead wire electroplating method of CN201710560222.2, using electro-plating method, " wire after washing enters
Copper plating groove, successively by containing copper-bath, stannous sulfate solution, sulfuric acid copper plating groove, and real-time detection iron ion and water
The concentration of chloride ion is washed, iron concentration≤25g/L washes chlorine ion concentration≤100g/L, and the control of stannous sulfate concentration exists
0.08~0.12g/L, sulfuric acid concentration control each bath temperature in 8~12g/L, copper plating groove are controlled at 25~35 DEG C ".
The above-mentioned prior art, however it remains the high tin steel bead wire unstable quality of finished product, speed of production is slow, and performance is undesirable
The technical issues of.
Summary of the invention
According in view of the above technical problems, the present invention provides a kind of production methods of high tin steel bead wire, steady to obtain
The steel bead wire of fixed high-tin bronze coating improves steel wire properties, improves speed of production.
To realize the above goal of the invention, the present invention adopts the following technical scheme:
A kind of production method of high tin steel bead wire, the described method comprises the following steps:
A) pickling.Pickling is carried out to steel bead wire.Pickling is carried out to steel bead wire in descaling bath, steel wire is carried out again after pickling
Washing.Pickling solution uses 120-180g/L hydrochloric acid or 210-330g/L sulfuric acid.30-70 DEG C of pickling temperature, pickling time is
0.01-0.03s。
This step strict control pickling degree, to guarantee tightness and plated layer compact degree that coating combines, the steel of guarantee
The performance of silk.
B) cathodic pickling.Cathodic pickling is carried out to the steel bead wire after pickling.In cathodic pickling slot to steel bead wire into
Row cathodic pickling, again washes steel wire after cathodic pickling.Cathodic pickling uses 20-40g/L sulfuric acid, voltage 3-15V.Temperature
Degree is 25-40 DEG C, and the cathodic pickling time is 0.01-0.03s.
The degree of this step strict control cathodic pickling improves the binding strength of steel wire and coating, was using steel wire
The further cleaning that bonding force and rubber coating rate are improved, while also being carried out to steel wire surface in journey, the performance of the steel wire of guarantee.
C) electroless copper.Electroless copper is carried out to the steel bead wire after cathodic pickling.In copper plating groove to steel bead wire into
Row copper facing, washes steel wire after copper facing.In copper plating groove, concentration of copper sulfate 8-16g/L, stannous sulfate concentration 0.4-1.6g/
L, sulfuric acid concentration 8-16g/L, 35-45 DEG C of bath temperature, copper facing time 0.025-0.065s.Filtering is added in copper plating groove solution
Stick, and carry out within every 12 hours replacing primary.Copper sulphate and stannous sulfate are stablized by added automatically system to be added.
During copper facing, required to calculate concentration of copper sulfate in plating solution, stannous sulfate concentration, bath temperature, plating according to layers of copper
The copper time.Guarantee that layers of copper reaches quality requirement, while controlling the consistency of coating.The quality of plating solution is stablized, and guarantees the height of coating
Stability.
D) it neutralizes.Steel bead wire after copper facing is neutralized.In neutralization chamber using sodium hydroxide to steel bead wire into
Row neutralizes, and the naoh concentration used is 0.5-2g/L.Steel bead wire is washed after neutralization.
The step ensure that the no acidic remnants of steel wire surface, effectively prevents the corrosion of steel wire, ensure that making for steel bead wire
Use the service life.
E) it hot water wash and dries.Hot water wash and drying are carried out to the steel bead wire after neutralization.To tyre bead steel in hot bath
Silk carries out hot water wash, carries out drying operation to steel bead wire in drying tank after hot water wash.Hot water wash temperature is greater than 85 DEG C.Drying
150-170 DEG C of temperature, drying time 0.006-0.02s.
The step ensure that steel wire surface moisture, effectively controls the oxidation of steel wire, wire quality is made to be guaranteed.
F) oiling.Oiling is carried out to steel bead wire in oil coating box.The oiling: every kilogram of steel bead wire surface coating
0.02-0.13g coumarone indene resin.
After the completion of oiling, the high tin steel bead wire of the present invention is made.
The step effectively increases the antirust ability of steel wire and the bonding force of steel bead wire, improves steel bead wire quality.
The production method of high tin steel bead wire of the present invention has the advantages that
(1) high tin steel bead wire finished product prepared by the present invention: diameter 0.96-1.20mm, 0.09-0.5 μm of copper coating thickness, tin hundred
Divide than 9-12%, quality is stable, reliable.
(2) speed of production of the present invention is fast, and speed of production reaches 350-450m/min.Stable it can reach high tin steel bead wire
Large-scale production.
(3) finished product steel bead wire prepared by the present invention is high-quality, and quality of coating is stablized, and deviation is small, has excellent performance, and can be used for
Prepare the tire of high-quality.
(4) cost of present invention process is low, than 10% or more prior art save the cost, is conducive to promote.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation
Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, art technology
Personnel's every other embodiment obtained without creative efforts, shall fall within the protection scope of the present invention.
A kind of production method of high tin steel bead wire of embodiment 1
The present embodiment provides a kind of production method of high tin steel bead wire, the production method the following steps are included:
A) pickling is carried out to steel bead wire.Pickling is carried out to steel bead wire in descaling bath.Steel wire is washed after pickling.Acid
Dilution use 150g/L hydrochloric acid, pickling temperature, 65 DEG C, pickling time 0.027s.
B) cathodic pickling is carried out to the steel bead wire after pickling.Electrolysis acid is carried out to steel bead wire in cathodic pickling slot
It washes.Steel wire is washed after cathodic pickling.Cathodic pickling uses 30g/L sulfuric acid, voltage 13V.Temperature is 30 DEG C, electrolysis acid
Washing the time is 0.027s.
C) electroless copper is carried out to the steel bead wire after cathodic pickling.Copper facing is carried out to steel bead wire in copper plating groove.Plating
Steel wire is washed after copper.Concentration of copper sulfate 12g/L, stannous sulfate concentration 1g/L, sulfuric acid concentration 12g/L, bath temperature 35
DEG C, copper facing time 0.038s.
D) steel bead wire after copper facing is neutralized.To in steel bead wire progress and to tire after neutralization in neutralization chamber
Circle steel wire is washed.Naoh concentration is 2g/L.
E) hot water wash and drying are carried out to the steel bead wire after neutralization.Hot water wash is carried out to steel bead wire in hot bath,
Drying operation is carried out to steel bead wire in drying tank after hot water wash.Hot water wash temperature is greater than 85 DEG C.It 160 DEG C of drying temperature, dries
Dry time 0.011s.
F) oiling is carried out to the steel bead wire after drying.Oiling is carried out to steel bead wire in oil coating box.The oiling: ancient
The grand amount of resin control of horse is in 0.85g/kg.
The steel bead wire finished product that the present embodiment is prepared be diameter 1.20mm, 0.1 μm of copper layer thickness, tin percentage 10%
Qualified steel wire.
3 sections of steel wires are wherein taken to be tested, as a result such as the following table 1.
1 copper coating inspection result of table
As seen in table, this method can obtain stable high tin coating steel bead wire finished product.The thickness of coating and tin percentage compared with
For stabilization.
A kind of production method of high tin steel bead wire of embodiment 2
The present embodiment provides a kind of production method of high tin steel bead wire, the production method the following steps are included:
A) pickling is carried out to steel bead wire.Pickling is carried out to steel bead wire in descaling bath.Steel wire is washed after pickling.Acid
Dilution uses 160g/L hydrochloric acid.55 DEG C of pickling temperature, pickling time 2.8s.
B) cathodic pickling is carried out to the steel bead wire after pickling.Electrolysis acid is carried out to steel bead wire in cathodic pickling slot
It washes.Steel wire is washed after cathodic pickling.Cathodic pickling uses 30g/L sulfuric acid, voltage 7V.Temperature is 35 DEG C, electrolysis acid
Washing the time is 2.8s.
C) electroless copper is carried out to the steel bead wire after cathodic pickling.Copper facing is carried out to steel bead wire in copper plating groove.Plating
Steel wire is washed after copper.Concentration of copper sulfate 12.5g/L, stannous sulfate concentration 1g/L, sulfuric acid concentration 12.5g/L, plating bath temperature
40 DEG C of degree, copper facing time 0.036s.
D) steel bead wire after copper facing is neutralized.To in steel bead wire progress and to tire after neutralization in neutralization chamber
Circle steel wire is washed.Naoh concentration is 1g/L.
E) hot water wash and drying are carried out to the steel bead wire after neutralization.Hot water wash is carried out to steel bead wire in hot bath,
Drying operation is carried out to steel bead wire in drying tank after hot water wash.Hot water wash temperature is greater than 85 DEG C.It 160 DEG C of drying temperature, dries
Dry time 0.01s.
F) oiling is carried out to the steel bead wire after drying.Oiling is carried out to steel bead wire in oil coating box.The oiling: ancient
The grand amount of resin control of horse is in 0.05g/kg.
The steel bead wire finished product that the present embodiment is prepared be diameter 0.96mm, 0.5 μm of copper layer thickness, tin percentage 11%
Qualified steel wire.
3 sections of steel wires are wherein taken to be tested, as a result such as the following table 2.
2 copper coating inspection result of table
As seen in table, this method can obtain stable high tin coating steel bead wire finished product.
A kind of production method of high tin steel bead wire of embodiment 3
The present embodiment provides a kind of production method of high tin steel bead wire, the production method the following steps are included:
A) pickling is carried out to steel bead wire.Pickling is carried out to steel bead wire in descaling bath.Steel wire is washed after pickling.Acid
Dilution uses 260g/L sulfuric acid.50 DEG C of pickling temperature, pickling time 0.025s.
B) cathodic pickling is carried out to the steel bead wire after pickling.Electrolysis acid is carried out to steel bead wire in cathodic pickling slot
It washes.Steel wire is washed after cathodic pickling.Cathodic pickling uses 30g/L sulfuric acid, voltage 13V.Temperature is 30 DEG C, electrolysis acid
Washing the time is 0.025s.
C) electroless copper is carried out to the steel bead wire after cathodic pickling.Copper facing is carried out to steel bead wire in copper plating groove.Plating
Steel wire is washed after copper.Concentration of copper sulfate 12g/L, stannous sulfate concentration 0.8g/L, sulfuric acid concentration 12g/L, bath temperature
35 DEG C, copper facing time 0.05s.
D) steel bead wire after copper facing is neutralized.To in steel bead wire progress and to tire after neutralization in neutralization chamber
Circle steel wire is washed.Naoh concentration is 1.5g/L.
E) hot water wash and drying are carried out to the steel bead wire after neutralization.Hot water wash is carried out to steel bead wire in hot bath,
Drying operation is carried out to steel bead wire in drying tank after hot water wash.Hot water wash temperature is greater than 85 DEG C.It 150 DEG C of drying temperature, dries
Dry time 0.015s.
F) oiling is carried out to the steel bead wire after drying.Oiling is carried out to steel bead wire in oil coating box.The oiling:
Coumarone indene resin dosage is controlled in 0.07g/kg.
The steel bead wire finished product that the present embodiment is prepared be diameter 1.42mm, 0.1 μm of copper layer thickness, tin percentage 8.5%
Qualified steel wire.
3 sections of steel wires are wherein taken to be tested, as a result such as the following table 3.
3 inspection of coating result of table
As seen in table, this method can obtain stable high tin coating steel bead wire finished product.
Steel bead wire reaches requirement in above-described embodiment, and finished product is stablized, and superior in quality, speed of production is fast, mode of expanding production
Simply, low production cost has effectively reached the production of high tin steel bead wire.
It, can according to the technique and scheme of the present invention and this hair it is understood that for those of ordinary skills
Bright design is subject to equivalent substitution or change, and all these changes or replacement all should belong to the guarantor of appended claims of the invention
Protect range.
Claims (9)
1. a kind of production method of high tin steel bead wire, it is characterised in that: the production method is the following steps are included: pickling, electricity
Solution pickling, electroless copper, neutralization, hot water wash are simultaneously dried, oiling；The high tin steel bead wire of preparation: diameter 0.96-1.20mm, copper
0.09-0.5 μm of thickness of coating, tin percentage 9-12%.
2. a kind of production method of high tin steel bead wire according to claim 1, it is characterised in that: the pickling: pickling
Solution uses 120-180g/L hydrochloric acid or 210-330g/L sulfuric acid.
3. a kind of production method of high tin steel bead wire according to claim 1, it is characterised in that: the pickling: pickling
30-70 DEG C of temperature, pickling time 0.01-0.03s.
4. a kind of production method of high tin steel bead wire according to claim 1, it is characterised in that: the cathodic pickling:
Cathodic pickling uses 20-40g/L sulfuric acid, voltage 3-15V.
5. a kind of production method of high tin steel bead wire according to claim 1, it is characterised in that: the cathodic pickling:
Temperature is 25-45 DEG C, and the cathodic pickling time is 0.01-0.03s.
6. a kind of production method of high tin steel bead wire according to claim 1, it is characterised in that: the electroless copper:
The plating solution of use: concentration of copper sulfate 8-16g/L, stannous sulfate concentration 0.4-1.6g/L, sulfuric acid concentration 8-16g/L, bath temperature
35-45 DEG C, copper facing time 0.025-0.065s.
7. a kind of production method of high tin steel bead wire according to claim 1, it is characterised in that: it is described to copper facing after
Steel bead wire carries out neutralization procedure: the naoh concentration used is 0-2g/L.
8. a kind of production method of high tin steel bead wire according to claim 1, it is characterised in that: the hot water wash is simultaneously dried
Dry: hot water wash temperature is greater than 85 DEG C, 150-170 DEG C of drying temperature, drying time 0.006-0.02s.
9. a kind of production method of high tin steel bead wire according to claim 1, it is characterised in that: the oiling: ancient horse
The coating weight control of grand resin is in 0.02-0.13g/kg.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910285806.2A CN110029334A (en) | 2019-04-10 | 2019-04-10 | A kind of production method of high tin steel bead wire |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910285806.2A CN110029334A (en) | 2019-04-10 | 2019-04-10 | A kind of production method of high tin steel bead wire |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110029334A true CN110029334A (en) | 2019-07-19 |
Family
ID=67237922
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910285806.2A Pending CN110029334A (en) | 2019-04-10 | 2019-04-10 | A kind of production method of high tin steel bead wire |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110029334A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111962136A (en) * | 2020-08-06 | 2020-11-20 | 山东大业股份有限公司 | Method for improving rubber coating rate of tire bead steel wire |
| CN112195472A (en) * | 2020-08-06 | 2021-01-08 | 山东大业股份有限公司 | Control method for preventing oxidation of tire bead steel wire |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101824612A (en) * | 2010-05-24 | 2010-09-08 | 张家港市胜达钢绳有限公司 | Plating solution suitable for plating high tin bronze coating on bead wire surface in chemical replacement mode |
| CN102517581A (en) * | 2011-12-27 | 2012-06-27 | 山东大业股份有限公司 | High-strength tin-plated bronze tire bead steel wire and preparation method thereof |
| CN102586787A (en) * | 2012-03-27 | 2012-07-18 | 张家港市胜达钢绳有限公司 | Method for producing tin bronze tempering tire bead steel wires highly bonded with rubber |
| CN103924225A (en) * | 2014-01-23 | 2014-07-16 | 江苏兴达钢帘线股份有限公司 | High tin bronze plating solution for chemical plating of surface of tempered bead wire, and its chemical dip plating method |
| CN105420705A (en) * | 2015-12-30 | 2016-03-23 | 江苏兴达钢帘线股份有限公司 | Method of electroless Cu-Sn-Co ternary alloy plating of tire bead steel wire |
| CN106148923A (en) * | 2016-08-16 | 2016-11-23 | 无锡益联机械有限公司 | A kind of surface treatment method of radial tyre bead steel wire |
| CN107419245A (en) * | 2017-07-11 | 2017-12-01 | 李文军 | A kind of steel bead wire electroplating method |
| CN107955876A (en) * | 2017-11-28 | 2018-04-24 | 江苏胜达科技有限公司 | The method that laser-impact combines processing steel wire surface with chemical plating stannum bronze |
-
2019
- 2019-04-10 CN CN201910285806.2A patent/CN110029334A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101824612A (en) * | 2010-05-24 | 2010-09-08 | 张家港市胜达钢绳有限公司 | Plating solution suitable for plating high tin bronze coating on bead wire surface in chemical replacement mode |
| CN102517581A (en) * | 2011-12-27 | 2012-06-27 | 山东大业股份有限公司 | High-strength tin-plated bronze tire bead steel wire and preparation method thereof |
| CN102586787A (en) * | 2012-03-27 | 2012-07-18 | 张家港市胜达钢绳有限公司 | Method for producing tin bronze tempering tire bead steel wires highly bonded with rubber |
| CN103924225A (en) * | 2014-01-23 | 2014-07-16 | 江苏兴达钢帘线股份有限公司 | High tin bronze plating solution for chemical plating of surface of tempered bead wire, and its chemical dip plating method |
| CN105420705A (en) * | 2015-12-30 | 2016-03-23 | 江苏兴达钢帘线股份有限公司 | Method of electroless Cu-Sn-Co ternary alloy plating of tire bead steel wire |
| CN106148923A (en) * | 2016-08-16 | 2016-11-23 | 无锡益联机械有限公司 | A kind of surface treatment method of radial tyre bead steel wire |
| CN107419245A (en) * | 2017-07-11 | 2017-12-01 | 李文军 | A kind of steel bead wire electroplating method |
| CN107955876A (en) * | 2017-11-28 | 2018-04-24 | 江苏胜达科技有限公司 | The method that laser-impact combines processing steel wire surface with chemical plating stannum bronze |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111962136A (en) * | 2020-08-06 | 2020-11-20 | 山东大业股份有限公司 | Method for improving rubber coating rate of tire bead steel wire |
| CN112195472A (en) * | 2020-08-06 | 2021-01-08 | 山东大业股份有限公司 | Control method for preventing oxidation of tire bead steel wire |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN110029334A (en) | A kind of production method of high tin steel bead wire | |
| CN108060442B (en) | Method for preparing zinc-copper composite coating on surface of copper-aluminum composite busbar | |
| CN106757264B (en) | A kind of wide temperature anodic oxidation electrolyte of aluminum alloy environment-friendly type and method for oxidation | |
| CN103695976A (en) | Treatment method for copper product before electronickelling | |
| CN105778570A (en) | High-brightness and high-color-saturation super-flash type silvery white pearlescent pigment and preparation method thereof | |
| CN105463454A (en) | Ceramic surface multi-layer composite coating film and preparing method thereof | |
| CN110158136B (en) | Aluminum electrolytic coloring titanium golden surface treatment method | |
| CN112609212A (en) | Zinc-nickel alloy electroplating process for part with spinning surface | |
| US2648626A (en) | Method of electrolytic coating | |
| CN106086957A (en) | A kind of process of surface treatment of flange face bolt | |
| CN110565133A (en) | method for manufacturing low-roughness electroplated nickel and gold | |
| CN107267968A (en) | A kind of thick process for copper of chemical plating for printed wiring board | |
| CN105951125B (en) | A kind of manganese base magnetism electroplate liquid and preparation method thereof | |
| JPS6020467B2 (en) | Colored chromate treatment method for zinc-nickel alloy plated products | |
| CN104532354B (en) | A kind of preparation method of light-colored conductive whisker | |
| CN109594106B (en) | Method for eliminating fault of potassium chloride cyanide-free cadmium plating caused by tin impurities | |
| CN104120415B (en) | Performing nano-plating on mirror surface solution and method | |
| CN110565124A (en) | Chromium plating solution for automobile ornaments and electroplating method thereof | |
| CN111733404A (en) | Chemical nickel plating solution and preparation method thereof | |
| CN109762389A (en) | A kind of Ceramic Tiles metal effect surface treating agent and preparation method thereof | |
| CN104294326A (en) | Plating tin liquor on printed plate and tin plating method | |
| CN113088941B (en) | Process for preparing morning gold zipper and tooth color liquid medicine | |
| CN101525748B (en) | Clean rare-earth salt passive film | |
| CN109379857B (en) | Bonding treatment agent, preparation method and use method thereof | |
| CN110129842A (en) | A kind of compound cyanide-free gold electroplating plating solution preparation and gold process is electroplated using its |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190719 |
|
| RJ01 | Rejection of invention patent application after publication |