CN110029291A - A kind of iron base amorphous magnetically-soft alloy and preparation method thereof - Google Patents
A kind of iron base amorphous magnetically-soft alloy and preparation method thereof Download PDFInfo
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- CN110029291A CN110029291A CN201910432980.5A CN201910432980A CN110029291A CN 110029291 A CN110029291 A CN 110029291A CN 201910432980 A CN201910432980 A CN 201910432980A CN 110029291 A CN110029291 A CN 110029291A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/06—Continuous casting of metals, i.e. casting in indefinite lengths into moulds with travelling walls, e.g. with rolls, plates, belts, caterpillars
- B22D11/0611—Continuous casting of metals, i.e. casting in indefinite lengths into moulds with travelling walls, e.g. with rolls, plates, belts, caterpillars formed by a single casting wheel, e.g. for casting amorphous metal strips or wires
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- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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- C22C45/02—Amorphous alloys with iron as the major constituent
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- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
- H01F1/01—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
- H01F1/03—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
- H01F1/12—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials
- H01F1/14—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys
- H01F1/147—Alloys characterised by their composition
- H01F1/153—Amorphous metallic alloys, e.g. glassy metals
- H01F1/15341—Preparation processes therefor
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- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
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- H01F1/01—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
- H01F1/03—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
- H01F1/12—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials
- H01F1/14—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys
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- H01F1/153—Amorphous metallic alloys, e.g. glassy metals
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- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F41/00—Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties
- H01F41/02—Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties for manufacturing cores, coils, or magnets
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Abstract
The invention belongs to magnetic functional material technical field, a kind of iron base amorphous magnetically-soft alloy and preparation method thereof is disclosed.The expression formula of the alloy are as follows: FeaNbbBcCud, a, b, c, d in formula are atomic percentage, wherein 74.5≤a≤76,3.0≤b≤5.0,20≤c≤25,0.5≤d≤2.0, and a+b+c+d=100, preparation method includes ingredient, melting, gets rid of band method and prepare amorphous thin ribbon.Product crystallization initial temperature with higher of the present invention and wide supercooling liquid phase region, illustrate that the alloy has high thermal stability, excellent soft magnet performance and good amorphous formation ability, have high saturation induction density, low coercivity and high resistivity high simultaneously, and preparation process is simple, good forming ability.
Description
Technical field
The invention belongs to magnetic functional material technical field more particularly to a kind of iron base amorphous magnetically-soft alloy and its preparation sides
Method.
Background technique
Iron base amorphous magnetically-soft alloy has excellent magnetic performance (such as: high saturated magnetic induction, high magnetic permeability and low magnetic
Damage), high resistivity and the advantages that high rigidity, it has also become one of materialogy and the emphasis of physics area research.Currently, Fe base is non-
Brilliant magnetically soft alloy is in fields such as aerospace, power electronics, motors using very extensive.In distribution transformer field, it is used
The no-load loss and no-load current of transformer are reduced in substitution silicon steel sheet.Fe-based amorphous band is used to manufacture supermarket and library
The sensor magnetic stripe label of burglary-resisting system.In consumer electronic device field, it can be substantially reduced power volume, improve device efficiency,
Increase anti-interference ability.Fe-based amorphous alloy energy-saving consumption-reducing is had excellent performance, and is a ideal energy-saving and environment friendly material, is expected to
It substitutes the conventional soft magnetic materials such as silicon steel sheet, permalloy and is widely used in transformer, mutual inductor, disk memory and motor
The industrial circles such as iron core.With China's rapid development of economy, the demand to electric power increasingly increases, and becomes to high-efficiency and energy-saving type amorphous
The demand of depressor is very huge.Therefore, there is an urgent need to research and develop the novel Fe base noncrystal alloy with Good All-around Property, this gesture
The exploitation and application of entire Fe base amorphous will be favorably pushed, there is important social effect and economic benefits.
It is numerous since Duwez professor in 1967 reports the first Fe base amorphous soft-magnetic alloy in Fe-P-C system
Scientist has paid a large amount of effort during preparing new iron-based amorphous soft-magnetic alloy.1969, Pond and Maddin
The continuous amorphous ribbon with certain length is prepared, to create condition for large-scale production amorphous alloy.1988,
Yoshizawa etc. has developed Finemet type (Fe-Cu-Nb-Si-B) nano-crystal soft magnetic alloy, which has both Fe-based amorphous
The characteristics of high saturated magnetic induction of the high magnetic strength of alloy and cobalt base amorphous alloy, high magnetic permeability and low iron loss.At the same time,
Suzuki etc. is that Nanoperm type nano-crystal soft magnetic alloy is had developed in alloy in Fe-M-B (M=Zr, Hf, Nb).Currently,
The research and development of FeNbBCu system amorphous soft-magnetic alloy have become the emphasis of Fe base amorphous area research.Cu element is added with
Following advantage: (1) Cu and Fe has biggish positive enthalpy of mixing (+13 kJ/mol), and (2) reduce the distance of Fe-Fe atom pair, (3)
The appropriate addition of Cu can hinder electron motion in alloy, improve resistance alloys rate, reduce eddy-current loss, and the addition of (4) Cu element is led
Cause the big binding force between alloy constituent element, atom packing density height, diffusion coefficient low.Xue Lin substitutes Fe element by Cu and is prepared into
To Fe84-xNb2B14CuxAmorphous alloy, the alloy do not have glass transition phase, crystallization initial temperature in temperature-rise periodT x1It is small
In 698 K.Parsons etc. develops the FeNbBCu amorphous alloy at the low end B rich Fe, and crystallization initial temperature is about 650 K.
Torrens-Serra etc. reports Fe77Nb7B15Cu1Amorphous alloy, the crystallization initial temperature of the alloy are 774 K, are saturated magnetic strength
It answers intensity and coercivity is respectively 80 ± 2 Am2/ kg and 8 A/m.The FeNbBCu system amorphous alloy for disclosing report at present is equal
There is no that apparent glass transition phase, amorphous formation ability are weaker and thermal stability is low, seriously limits its industrial application.It is logical
Often, Fe-based amorphous alloy is used as a kind of functional material and is applied to the fields such as power electronics, thus it is excellent to require alloy to have
Soft magnet performance and high resistivity.Traditional silicon steel sheet has high saturation induction density (~ 2.0 T) and low resistivity (~ 50
μ Ω cm), but its energy-saving effect is undesirable.And Fe-based amorphous alloy excellent combination property, resistivity are the 2 of traditional silicon steel sheet
~3 times, eddy-current loss can be significantly reduced, is ideal energy conservation and environmental protection material, is expected to replace the conventional soft magnetic materials such as silicon steel sheet.
Fe base noncrystal alloy is due tos with excellent magnetic performance, high intensity and excellent corrosion resistance etc. by pole
Big concern, Fe-based amorphous alloy of the preparation with excellent soft magnet performance and high amorphous formation ability have extensive practical application valence
Value.By being continually striving in recent ten years, the FeNbBCu system that domestic and international researcher has developed several typical compositions is non-
Peritectic alloy.However, existing developed FeNbBCu system amorphous alloy is weaker there are amorphous formation ability and soft magnet performance is more low
Disadvantage, and almost or blank out to the research of alloy resistivity.Thus, as a kind of potential functional material, exploitation
There is important industrial application valence with a kind of Fe base amorphous soft-magnetic alloy for having both high amorphous formation ability and thermal stability is developed
Value.
Summary of the invention
The purpose of the present invention is overcoming amorphous formation ability of the existing technology weaker and the lower deficiency of thermal stability,
A kind of iron base amorphous magnetically-soft alloy and preparation method thereof is provided.
In order to achieve the above object, present invention provide the technical scheme that a kind of iron base amorphous magnetically-soft alloy, expression formula
For FeaNbbBcCud, a, b, c, d in formula respectively indicate the atomic percentage of each constituent element, wherein 74.5≤a≤76,3.0
≤ b≤5.0,20≤c≤25,0.5≤d≤2.0, and a+b+c+d=100.
The preparation method of above-mentioned iron base amorphous magnetically-soft alloy, comprising the following steps:
1) ingredient: according to atomic percent FeaNbbBcCudThe pure Fe of accurate weighing, pure Cu and Fe-Nb, Fe-B intermediate alloy;
2) master alloy melting ingot: the target component raw material claimed after proportion is put into quartz ampoule and uses B2O3Glass is by raw material packet
Cover, using radio-frequency induction coil and adjust electric current and be gradually increased to 20 A by 5 A, induction heating until sample is completely melt,
Make alloying component uniform melt back 5-6 times, Fe is obtained after furnace cooling x Nb3B20Cu y Master alloy ingot;It later, will with sand paper
The removal of master alloy ingot surface scale, is placed in ultrasonic cleaning 10-15 minutes in acetone, spare after drying;
3) amorphous alloy strips are prepared: by the molten Fe preparedaNbbBcCudMaster alloy is encased in high-purity stone that lower end is rectangular aperture
Ying Guanzhong revolves in furnace of quenching in high vacuum single roller and amorphous alloy strips is prepared.Preparation process is as follows: alloy will be housed first
Quartz ampoule is placed in induction coil;Then vacuum chamber is vacuumized and is evacuated to 3 × 10 using mechanical pump+molecular pump Primary pump system-3
Pa, it is to be achieved needed for after vacuum degree into furnace cavity reversely charging high-purity argon gas;Alloy is added using HF induction heating apparatus
Heat simultaneously makes its fusing, and adjusting electric current is that 28-35 A will be melted after aluminium alloy melts and overheats certain temperature using high-purity argon gas
The aluminium alloy melted is ejected into high-speed rotating copper roller surface, to obtain continuous alloy thin band.
Above-mentioned steps 3) in, the linear velocity of copper roller is 40 m/s, and injection pressure is 15 kPa.
Compared with prior art, the present invention having the advantage that
1) alloying component constituent element of the present invention is simple, and ingredient is unique, proportion is reasonable, is conducive to the amorphous formation energy for improving alloy
Power, mouldability.
2) there is excellent amorphous formation ability and high thermal stability, the Fe base noncrystal alloy being prepared has 78 K
The wide supercooling liquid phase region of ~ 87 K, and there is high crystallization initial temperature (>=831 K).
3) soft magnet performance is good, saturation induction density Ms=120 ~ 145 emu/g, coercivity H=0.04 ~ 0.24 Oe.
4) room temperature resistivity is high, and resistance alloys rate is 115 ~ 130 μ Ω cm.
5) the FeNbBCu amorphous soft-magnetic alloy preparation method described in is simple, and FeNbBCu alloy prepared by the present invention is not only
With excellent amorphous formation ability and high thermal stability, and there is excellent soft magnet performance and high resistivity, is one
The amorphous soft-magnetic alloy of money excellent combination property is expected to substitute the materials such as traditional silicon steel sheet applied to fields such as power electronics.
Detailed description of the invention
Fig. 1 is the XRD spectrum of amorphous alloy prepared by the embodiment of the present invention 1,2,3.
Fig. 2 is the DSC curve figure of amorphous alloy prepared by the embodiment of the present invention 2, and heating rate is 40 K/min.
Fig. 3 is the room temperature hysteresis loop for the Fe-based amorphous alloy being prepared according to embodiment 1,2,3.
Specific embodiment
The invention will be further described with reference to the accompanying drawings and embodiments.
Raw material involved in the embodiment of the present invention are as follows: and technical pure Fe (purity, 99.85 wt.%), pure Cu (purity, 99.9
Wt.%), the mass fraction that the mass fraction of Fe-Nb intermediate alloy Nb is 60%, Fe-B intermediate alloy B is 17.5%.
A kind of embodiment 1: preparation method of iron base amorphous magnetically-soft alloy, comprising the following steps:
1) ingredient: manufactured in the present embodiment is Fe76Nb3B20Cu1Amorphous soft-magnetic alloy, according to atomic percent Fe76Nb3B20Cu1
The pure Fe of accurate weighing, pure Cu and Fe-Nb, Fe-B intermediate alloy;
2) master alloy melting ingot: the target component raw material claimed after proportion is put into quartz ampoule and uses B2O3Glass is by raw material packet
Cover, using radio-frequency induction coil and adjust electric current and be gradually increased to 20 A by 5 A, induction heating until sample is completely melt,
Make alloying component uniform melt back 5 times, Fe is obtained after furnace cooling76Nb3B20Cu1Master alloy ingot;It later, will be female with sand paper
The removal of alloy pig surface scale, is placed in ultrasonic cleaning 15 minutes in acetone, spare after drying;
3) amorphous alloy strips are prepared: by the molten Fe prepared76Nb3B20Cu1It is the high-purity of rectangular aperture that master alloy, which is encased in lower end,
In quartz ampoule, is revolved in furnace of quenching in high vacuum single roller and amorphous alloy strips are prepared.Preparation process is as follows: alloy will be housed first
Quartz ampoule be placed in induction coil;Then vacuum chamber is vacuumized using mechanical pump+molecular pump Primary pump system and is evacuated to 3 ×
10-3Pa, it is to be achieved needed for after vacuum degree into furnace cavity reversely charging high-purity argon gas;Using HF induction heating apparatus to alloy into
Row heats and makes its fusing, and adjusting electric current is that 35 A will be melted after aluminium alloy melts and overheats certain temperature using high-purity argon gas
The aluminium alloy melted is ejected into high-speed rotating copper roller surface, and the linear velocity of copper roller is 40 m/s, and injection pressure is 15 kPa, thus
Obtain continuous alloy thin band.Fe obtained76Nb3B20Cu1About 20 m of the thickness of amorphous alloy ribbon.Vacuum degree is in vacuum chamber
3×10-3 Pa。
By Fe made from embodiment 176Nb3B20Cu1Alloy thin band through X-ray diffraction (XRD) verifying be have it is single non-
Crystalline structure feature (as shown in Figure 1).It is surveyed using differential scanning calorimeter (DSC), vibrating specimen magnetometer (VSM) and four probes
Try the correlated performance of instrument detection alloy, it can be deduced that: Fe76Nb3B20Cu1The glass transition temperature Tg of amorphous alloy=744 K and
The initial crystallization temperature K of Tx1=831 (as shown in table 1) illustrates the conjunction to obtain the supercooling liquid phase region K of Δ Tx=87 of the alloy
Fitting has stronger amorphous formation ability and high thermal stability;138 emu/g of saturation induction density, 0.04 Oe of coercivity;
Room temperature resistivity is 115 μ Ω cm.
A kind of embodiment 2: preparation method of iron base amorphous magnetically-soft alloy, comprising the following steps:
1) ingredient: manufactured in the present embodiment is Fe75.5Nb3B20Cu1.5Amorphous soft-magnetic alloy, according to atomic percent
Fe75.5Nb3B20Cu1.5The pure Fe of accurate weighing, pure Cu and Fe-Nb, Fe-B intermediate alloy;
2) master alloy melting ingot: the target component raw material claimed after proportion is put into quartz ampoule and uses B2O3Glass is by raw material packet
Cover, using radio-frequency induction coil and adjust electric current and be gradually increased to 20 A by 5 A, induction heating until sample is completely melt,
Make alloying component uniform melt back 5 times, Fe is obtained after furnace cooling75.5Nb3B20Cu1.5Master alloy ingot;Later, sand paper is used
Master alloy ingot surface scale is removed, ultrasonic cleaning 10 minutes in acetone are placed in, it is spare after drying;
3) amorphous alloy strips are prepared: by the molten Fe prepared75.5Nb3B20Cu1.5Master alloy is encased in the height that lower end is rectangular aperture
In pure quartz tube, is revolved in furnace of quenching in high vacuum single roller and amorphous alloy strips are prepared.Preparation process is as follows: first will be equipped with conjunction
The quartz ampoule of gold is placed in induction coil;Then vacuum chamber is vacuumized using mechanical pump+molecular pump Primary pump system and is evacuated to 3 ×
10-3Pa, it is to be achieved needed for after vacuum degree into furnace cavity reversely charging high-purity argon gas;Using HF induction heating apparatus to alloy into
Row heats and makes its fusing, and adjusting electric current is that 28-35 A use high-purity argon gas after aluminium alloy melts and overheats certain temperature
The aluminium alloy of melting is ejected into high-speed rotating copper roller surface, the linear velocity of copper roller is 40 m/s, and injection pressure is 15 kPa,
To obtain continuous alloy thin band.Fe obtained75.5Nb3B20Cu1.5About 30 μm of the thickness of amorphous alloy ribbon.In vacuum chamber
Vacuum degree is 3 × 10-3 Pa。
By Fe made from embodiment 275.5Nb3B20Cu1.5Alloy thin band has single through X-ray diffraction (XRD) verifying
Amorphous structure feature (as shown in Figure 1).Utilize differential scanning calorimeter (DSC), vibrating specimen magnetometer (VSM) and four probes
The correlated performance of tester detection alloy, it can be deduced that: Fe75.5Nb3B20Cu1.5The glass transition temperature Tg of amorphous alloy=
758 K and the initial K of crystallization temperature Tx1=839 (as shown in table 1), thus obtain the supercooling liquid phase region K of Δ Tx=81 of the alloy,
Illustrate that the alloy has stronger amorphous formation ability and high thermal stability;145 emu/g of saturation induction density, coercivity
0.20 Oe;Room temperature resistivity is 124 μ Ω cm.
A kind of embodiment 3: preparation method of iron base amorphous magnetically-soft alloy, comprising the following steps:
1) ingredient: manufactured in the present embodiment is Fe75Nb3B20Cu2Amorphous soft-magnetic alloy, according to atomic percent Fe75Nb3B20Cu2
The pure Fe of accurate weighing, pure Cu and Fe-Nb, Fe-B intermediate alloy;
2) master alloy melting ingot: the target component raw material claimed after proportion is put into quartz ampoule and uses B2O3Glass is by raw material packet
Cover, using radio-frequency induction coil and adjust electric current and be gradually increased to 20 A by 5 A, induction heating until sample is completely melt,
Make alloying component uniform melt back 6 times, Fe is obtained after furnace cooling75Nb3B20Cu2Master alloy ingot;It later, will be female with sand paper
The removal of alloy pig surface scale, is placed in ultrasonic cleaning 15 minutes in acetone, spare after drying;
3) amorphous alloy strips are prepared: by the molten Fe prepared75Nb3B20Cu2It is the high-purity of rectangular aperture that master alloy, which is encased in lower end,
In quartz ampoule, is revolved in furnace of quenching in high vacuum single roller and amorphous alloy strips are prepared.Preparation process is as follows: alloy will be housed first
Quartz ampoule be placed in induction coil;Then vacuum chamber is vacuumized using mechanical pump+molecular pump Primary pump system and is evacuated to 3 ×
10-3Pa, it is to be achieved needed for after vacuum degree into furnace cavity reversely charging high-purity argon gas;Using HF induction heating apparatus to alloy into
Row heats and makes its fusing, and adjusting electric current is that 28-35 A use high-purity argon gas after aluminium alloy melts and overheats certain temperature
The aluminium alloy of melting is ejected into high-speed rotating copper roller surface, the linear velocity of copper roller is 40 m/s, and injection pressure is 15 kPa,
To obtain continuous alloy thin band.Fe obtained75Nb3B20Cu2About 30 μm of the thickness of amorphous alloy ribbon.It is true in vacuum chamber
Reciprocal of duty cycle is 3 × 10-3 Pa。
By Fe made from embodiment 375Nb3B20Cu2Alloy thin band through X-ray diffraction (XRD) verifying be have it is single non-
Crystalline structure feature (as shown in Figure 1).It is surveyed using differential scanning calorimeter (DSC), vibrating specimen magnetometer (VSM) and four probes
Try the correlated performance of instrument detection alloy, it can be deduced that: Fe75Nb3B20Cu2The glass transition temperature Tg of amorphous alloy=763 K and
The initial crystallization temperature K of Tx1=841 (as shown in table 1) illustrates the conjunction to obtain the supercooling liquid phase region K of Δ Tx=78 of the alloy
Fitting has stronger amorphous formation ability and high thermal stability;120 emu/g of saturation induction density, 0.24 Oe of coercivity;
Room temperature resistivity is 130 μ Ω cm.
The performance parameter for the iron base amorphous magnetically-soft alloy that above-described embodiment obtains is shown in Table 1.
Table 1
Use above specific case is illustrated the present invention, is merely used to help understand the present invention, not to limit this
Invention.For those skilled in the art, according to the thought of the present invention, it can also make and several simply push away
It drills, deform or replaces.
Claims (3)
1. a kind of iron base amorphous magnetically-soft alloy, which is characterized in that its expression formula is FeaNbbBcCud, a, b, c, d in formula distinguish table
Show the atomic percentage of each constituent element, wherein 74.5≤a≤76,3.0≤b≤5.0,20≤c≤25,0.5≤d
≤ 2.0, and a+b+c+d=100.
2. iron base amorphous magnetically-soft alloy according to claim 1, which is characterized in that the preparation of the iron base amorphous magnetically-soft alloy
Method, comprising the following steps:
1) ingredient: according to atomic percent FeaNbbBcCudThe pure Fe of accurate weighing, pure Cu and Fe-Nb, Fe-B intermediate alloy;
2) master alloy melting ingot: the target component raw material claimed after proportion is put into quartz ampoule and uses B2O3Glass is by raw material packet
Cover, using radio-frequency induction coil and adjust electric current and be gradually increased to 20 A by 5 A, induction heating until sample is completely melt,
Make alloying component uniform melt back 5-6 times, Fe is obtained after furnace cooling x Nb3B20Cu y Master alloy ingot;It later, will with sand paper
The removal of master alloy ingot surface scale, is placed in ultrasonic cleaning 10-15 minutes in acetone, spare after drying;
3) amorphous alloy strips are prepared: by the molten Fe preparedaNbbBcCudMaster alloy is encased in high-purity stone that lower end is rectangular aperture
Ying Guanzhong revolves in furnace of quenching in high vacuum single roller and amorphous alloy strips is prepared;
Preparation process is as follows: the quartz ampoule equipped with alloy being placed in induction coil first;Then mechanical pump+molecular pump two is used
Grade pumping system, which vacuumizes vacuum chamber, is evacuated to 3 × 10-3Pa, it is to be achieved needed for after vacuum degree into furnace cavity reversely charging high-purity argon gas;
Its fusing is heated and made to alloy using HF induction heating apparatus, adjusting electric current is 28-35 A, simultaneously to aluminium alloy fusing
After overheating certain temperature, the aluminium alloy of melting is ejected into high-speed rotating copper roller surface using high-purity argon gas, to be connected
Continuous alloy thin band.
3. iron base amorphous magnetically-soft alloy according to claim 2, which is characterized in that in step 3), the linear velocity of copper roller is 40
M/s, injection pressure are 15 kPa.
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Cited By (1)
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CN114604958A (en) * | 2022-03-16 | 2022-06-10 | 安徽中科艾瑞智能环境技术有限公司 | Method for catalytically degrading organic pollutants in wastewater by iron-based amorphous composite material |
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CN101627141A (en) * | 2007-03-16 | 2010-01-13 | 日立金属株式会社 | Iron-based soft magnetic alloy, thin ribbon of amorphous alloy, and magnetic part |
CN104831169A (en) * | 2015-04-08 | 2015-08-12 | 朗峰新材料南通有限公司 | Fe-based nano crystal soft magnetic alloy material and preparation method thereof |
CN105671460A (en) * | 2016-01-19 | 2016-06-15 | 西安工业大学 | Preparation method for low-cost FeNbB ternary amorphous alloy soft magnetic material |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN101627141A (en) * | 2007-03-16 | 2010-01-13 | 日立金属株式会社 | Iron-based soft magnetic alloy, thin ribbon of amorphous alloy, and magnetic part |
CN104831169A (en) * | 2015-04-08 | 2015-08-12 | 朗峰新材料南通有限公司 | Fe-based nano crystal soft magnetic alloy material and preparation method thereof |
CN105671460A (en) * | 2016-01-19 | 2016-06-15 | 西安工业大学 | Preparation method for low-cost FeNbB ternary amorphous alloy soft magnetic material |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN114604958A (en) * | 2022-03-16 | 2022-06-10 | 安徽中科艾瑞智能环境技术有限公司 | Method for catalytically degrading organic pollutants in wastewater by iron-based amorphous composite material |
CN114604958B (en) * | 2022-03-16 | 2023-01-03 | 安徽中科艾瑞智能环境技术有限公司 | Method for catalytically degrading organic pollutants in wastewater by iron-based amorphous composite material |
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Application publication date: 20190719 |