CN110029005A - A kind of vegetalitas cutting oil and its lubricating system - Google Patents

A kind of vegetalitas cutting oil and its lubricating system Download PDF

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Publication number
CN110029005A
CN110029005A CN201910385330.XA CN201910385330A CN110029005A CN 110029005 A CN110029005 A CN 110029005A CN 201910385330 A CN201910385330 A CN 201910385330A CN 110029005 A CN110029005 A CN 110029005A
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oil
vegetalitas
cutting
lubricating system
vegetable oil
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吴任
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Foshan City Big Pml Precision Mechanism Ltd
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Foshan City Big Pml Precision Mechanism Ltd
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Priority to CN201910385330.XA priority Critical patent/CN110029005A/en
Publication of CN110029005A publication Critical patent/CN110029005A/en
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • C10M169/048Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/026Butene
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02Hydroxy compounds
    • C10M2207/023Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/026Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/283Esters of polyhydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40Fatty vegetable or animal oils
    • C10M2207/401Fatty vegetable or animal oils used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40Fatty vegetable or animal oils
    • C10M2207/402Castor oils
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22Heterocyclic nitrogen compounds
    • C10M2215/223Five-membered rings containing nitrogen and carbon only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/024Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of esters, e.g. fats
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • C10M2223/041Triaryl phosphates
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • C10M2223/043Ammonium or amine salts thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • C10M2223/047Thioderivatives not containing metallic elements
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/04Detergent property or dispersant property
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/10Inhibition of oxidation, e.g. anti-oxidants
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/22Metal working with essential removal of material, e.g. cutting, grinding or drilling

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The present invention provides a kind of vegetalitas cutting oil and its lubricating system, by following weight percent at being grouped as: vegetable oil 15~60%, glycerol acrylate 25~45%, sulfurized olefin cotton oil 1~3%, compound phosphoric acid rouge 1~4%, butylene class adhesive 1~2%, antioxidant 1~5%;And vegetable oil is prepared into nanoparticle vegetable oil, so that the vegetalitas cutting oil of preparation has significant film forming, play good lubrication, cooling and buffer function, it is able to maintain the cleaning in cutting face, it is used by mixing the benzotriazole derivative, tea polyphenols, di-tert-butyl cresol of special ratios as antioxidant, with good synergistic effect, improves vegetalitas and cut oily oxidation stability, so that the quality of product is more preferably;And lubricating system is combined to use, accurate fountain height is obtained, losing quantity is reduced.

Description

A kind of vegetalitas cutting oil and its lubricating system
Technical field
The present invention relates to lubrication technical fields, cut oil and its lubricating system in particular to a kind of vegetalitas.
Background technique
Traditional metal cutting process carries out a large amount of shower formula lubrications and cooling using mineral oil or vegetable oil or cutting fluid, The usage amount of lubricant is big, not only waste of resource, and traditional cutting oil cuts the viscosity mistake of oil containing more large granular impurity Greatly, cause more rough when sprinkling, the atomizing effect for comparing refinement cannot be formed, cause the huge of processing site and environment Big pollution, while can also seriously affect the health of operator.There is also some cutting oil to pass through addition on the market Additive makes the lubricating oil achieve the effect that lubrication, cooling, but cannot accurately know the heat condition of cutting point, so The phenomenon that in the presence of excessive sprinkling.Therefore, advocate energy-saving and emission-reduction, environmental protection, green production today, be badly in need of a kind of new plant The lubricating system of object cutting oil and cooperation vegetalitas cutting oil sprinkling.Thermal imaging refer to using infrared detector and optics at As object lens receive the infrared radiation energy distribution pattern reflection of measured target on the light-sensitive element of infrared detector, to obtain Infrared Thermogram, this thermography are corresponding with the heat distribution field of body surface.Generally thermal infrared imager is exactly by object The invisible infrared energy issued is changed into visible thermal image.Different colours above thermal image represent the difference of testee Temperature.A set of lubricating system is designed for the cutting oil by base oil nanosizing, and by some advanced technologies, solves tradition It is big that oily usage amount is cut when processing, is easy pollution environment, is led to the problem of wasting, have very important significance.
A kind of vegetalitas cutting oil and its lubricating system, there are also many for the practical problem urgently handled in practical application Specific solution is not proposed.
Summary of the invention
It is an object of the invention to propose, a kind of vegetalitas cutting is oily and its lubricating system is affiliated to solve the problems, such as.
To achieve the goals above, the present invention adopts the following technical scheme:
A kind of vegetalitas cutting oil is by following weight percent at being grouped as: vegetable oil 15~60%, propylene acid glycerol Ester 25~45%, sulfurized olefin cotton oil 1~3%, compound phosphoric acid rouge 1~4%, butylene class adhesive 1~2%, antioxidant 1 ~5%;
The vegetable oil at room temperature, by magnetic agitation, is prepared into nanoparticle vegetable oil.
Optionally, the vegetable oil is in soybean oil, castor oil, jatropha curcas oil, sunflower oil, rice bran oil and palm oil It is one or more.
Optionally, the compound phosphoric acid rouge is di-n-butyl phosphite, tricresyl phosphate, isooctyl acid phosphate Octadecylamine salt, trithiophenyl phosphate, two or more any mixture in thiophosphoric acid complex ester amine salt.
Optionally, the butylene class adhesive is one or both of polybutene, polyisobutene.
Optionally, the antioxidant be benzotriazole derivative, tea polyphenols, di-tert-butyl cresol according to 1~3:1:1~ 3 ratio composition.
Optionally, the mixing speed of the magnetic agitation is 3000~8000r/min, and mixing time is 30~60min.
In addition, also provide a kind of lubricating system, including oil storage room 1, air-driven hydraulic pump 2, solenoid valve 3, oil water separator 5, Gas pressure detector 4, oil pressure detector 8, several nozzles 11 further include thermal imaging device 10, oil stream detector 7, automatic control Molding block 9.
Optionally, several described nozzles are correspondingly arranged on several lubricant housings within the scope of Metal Cutting, institute Pipeline 6 is connected separately between the nozzle and the oil storage room stated.
Optionally, the junction of oil storage room 1 Yu pipeline is arranged in oil stream detector 7.
Compared with prior art, advantageous effects obtained by the present invention are:
1, vegetalitas cutting oil of the invention by nanoparticle vegetable oil and glycerol acrylate, sulfurized olefin cotton oil, Phosphoramidic acid sodium, butylene class adhesive and antioxidant as raw material be prepared vegetalitas cutting oil, have significantly at Film property plays good lubrication, cooling and buffer function, is able to maintain the cleaning in cutting face.
2, by mixing the benzotriazole derivative, tea polyphenols, di-tert-butyl cresol of special ratios as anti-in the present invention Oxidant uses, and has good synergistic effect, improves vegetalitas and cuts oily oxidation stability, so that the quality of product is more preferably.
3, vegetable oil is prepared into nanoparticle vegetable oil by vegetalitas of the invention cutting oil, the amalgamation with other raw materials More preferably, cooperate thermal imaging combination lubricating system, form more preferably atomizing effect, uniformly spray, and lubricating system can also precisely be caught The heat condition of cutting point is caught, and then obtains more accurately lubricating oil fountain height, reduces vegetalitas cutting oil because of vaporization at high temperature journey The uneven abrasion for causing cutting face different degrees of of degree, and reduce the losing quantity of vegetalitas cutting oil.
Detailed description of the invention
From following description with reference to the accompanying drawings it will be further appreciated that the present invention.Process focuses on the original for showing embodiment In reason.
Fig. 1 is the control system figure of a kind of vegetalitas cutting oil and its lubricating system in one of embodiment of the present invention;
Fig. 2 is a kind of vegetalitas cutting oil and its thermal imaging picture of lubricating system in one of embodiment;
Fig. 3 is the thermograph of a kind of vegetalitas cutting oil and its local pyrexia point of lubricating system in one of embodiment Piece;
Fig. 4 is a kind of vegetalitas cutting oil and its system diagram of lubricating system in one of embodiment.
Description of symbols: 1- oil storage room, 2- air-driven hydraulic pump, 3- solenoid valve, 4- gas pressure detector, 5- water-oil separating Device, 6- pipeline, 7- oil stream detector, 8- oil pressure detector, 9- automatic control module, 11- nozzle, 10- thermal imaging device.
Specific embodiment
In order to enable the objectives, technical solutions, and advantages of the present invention are more clearly understood, below in conjunction with embodiment, to this Invention is further elaborated;It should be appreciated that described herein, the specific embodiments are only for explaining the present invention, and does not have to It is of the invention in limiting.To those skilled in the art, after access is described in detail below, other systems of the present embodiment System, method and/or feature will become obvious.All such additional systems, method, feature and advantage are intended to be included in It in this specification, is included within the scope of the invention, and by the protection of the appended claims.In description described in detail below The other feature of the disclosed embodiments, and these characteristic roots will be apparent according to described in detail below.
Concrete principle: oil and nanoparticle is prepared into based on vegetable oil, it is easier to go out to form atomization from nozzles spray. It prepares vegetalitas cutting oil and is arranged based on vegetalitas cutting oil setting lubricating system.Thermal imaging is infrared by non-contact detection Energy is converted into electric signal, and then generates thermal image and temperature value, and fever phenomenon occurs when Metal Cutting, passes through spray It spills lubricating oil and plays lubrication and cooling effect, and thermal imaging is able to achieve temperature monitoring, utilizes infrared detector and optical imagery object Mirror receives in the infrared radiation energy distribution pattern reflection to the light-sensitive element of infrared detector of measured target, to obtain infrared Thermography, this thermography are corresponding with the heat distribution field of body surface.Generally thermal infrared imager exactly issues object Invisible infrared energy be changed into visible thermal image.Different colours above thermal image represent the not equality of temperature of testee Degree is red, pink to indicate that relatively high temperature, blue and green illustrate lower temperature.By in automatic control module The heating information that sensor collection arrives, and the new wound of fever is transferred to signal analysis module, rear signal analysis module is by washed biography Defeated to arrive controller, controller issues control signal, controls the fountain height of the vegetalitas cutting oil of different lubricant housings, while oil stream Detector can perceive the oil pump capacity of output oil duct.
The present invention is a kind of vegetalitas cutting oil and its lubricating system, and following embodiment is told about according to Fig. 1~4:
Embodiment one:
A kind of vegetalitas cutting oil is by following weight percent at being grouped as: vegetable oil 60%, glycerol acrylate 26%, sulfurized olefin cotton oil 3%, compound phosphoric acid rouge 4%, butylene class adhesive 2%, antioxidant 5%;
The vegetable oil at room temperature, by magnetic agitation, is prepared into nanoparticle vegetable oil.
Nanoparticle vegetable oil is heated to 45 DEG C, sequentially adds glycerol acrylate, sulfurized olefin cotton oil, compound phosphorus Sour rouge and butylene class adhesive, and 20min is stirred at 45~60 DEG C of heat preservation, after mixing speed is maintained at 100~120min, add Enter antioxidant, continue to keep original mixing speed, continues to stir 20min to fully transparent, plant is obtained after natural cooling Property cutting oil.
Wherein, the vegetable oil is in soybean oil, castor oil, jatropha curcas oil, sunflower oil, rice bran oil and palm oil It is one or more;The compound phosphoric acid rouge uses di-n-butyl phosphite, tricresyl phosphate, isooctyl acid phosphate ten Eight amine salt, trithiophenyl phosphate, two or more any mixture in thiophosphoric acid complex ester amine salt;Described Butylene class adhesive is one or both of polybutene, polyisobutene;The antioxidant is benzotriazole derivative, tea is more Phenol, di-tert-butyl cresol are formed according to the ratio of 1:1:1;The mixing speed of the magnetic agitation is 3000r/min, when stirring Between be 60min.
In addition, also providing a kind of lubricating system based on the vegetalitas cutting oil, such as Fig. 4, including oil storage room 1, gas Hydrodynamic press pump 2, solenoid valve 3, oil water separator 5, gas pressure detector 4, oil pressure detector 8, several nozzles 11, further include heat Imaging device 10, oil stream detector 7, automatic control module 9.
Wherein, several described nozzles are correspondingly arranged on several lubricant housings within the scope of Metal Cutting, described Nozzle and the oil storage room between be connected separately with pipeline 6;The junction of oil storage room and pipeline is arranged in oil stream detector; The automatic control module includes receiving the sensor from thermal imaging device information, for analyzing conversion sensor information Signal analysis module receives the controller of signal analysis module signal, and the controller issues control signal, receives control letter Number warning device;In conjunction with shown in Fig. 2 and Fig. 3, the thermal imaging device information is Infrared Thermogram, the described infrared heat at Thermal expansion scatterplot as forming different area on figure can determine heating temperature according to the thermal expansion scatterplot of different area, when it is described by When hot temperature is lower than 30 DEG C, the fountain height of the controller control vegetalitas cutting oil is 0, when the heating temperature reaches At 50 DEG C, the fountain height of the described controller starting control vegetalitas cutting oil is 0.5ml/min, spraying time 5min, when When the heating temperature reaches 75 DEG C, the fountain height of the controller starting control vegetalitas cutting oil is 1ml/min, spray Spilling the time is 5min, when the heating temperature reaches 120 DEG C, the spray of the controller starting control vegetalitas cutting oil The amount of spilling is 2.5ml/min, spraying time 10min;When heating temperature is higher than 180 DEG C, the controller control starting report Alert signal.If being related to circuit connection in the present embodiment to realize entire lubricating system, repeated no more in system in embodiment Circuit connecting mode.
Embodiment two:
A kind of vegetalitas cutting oil is by following weight percent at being grouped as: vegetable oil 55%, glycerol acrylate 35%, sulfurized olefin cotton oil 1%, compound phosphoric acid rouge 3%, butylene class adhesive 2%, antioxidant 4%;
The vegetable oil at room temperature, by magnetic agitation, is prepared into nanoparticle vegetable oil.
Nanoparticle vegetable oil is heated to 45 DEG C, sequentially adds glycerol acrylate, sulfurized olefin cotton oil, compound phosphorus Sour rouge and butylene class adhesive, and 20min is stirred at 45~60 DEG C of heat preservation, after mixing speed is maintained at 100~120min, add Enter antioxidant, continue to keep original mixing speed, continues to stir 20min to fully transparent, plant is obtained after natural cooling Property cutting oil.
Wherein, the vegetable oil is in soybean oil, castor oil, jatropha curcas oil, sunflower oil, rice bran oil and palm oil It is one or more;The compound phosphoric acid rouge uses di-n-butyl phosphite, tricresyl phosphate, isooctyl acid phosphate ten Eight amine salt, trithiophenyl phosphate, two or more any mixture in thiophosphoric acid complex ester amine salt;Described Butylene class adhesive is one or both of polybutene, polyisobutene;The antioxidant is benzotriazole derivative, tea is more Phenol, di-tert-butyl cresol are formed according to the ratio of 3:1:3;The mixing speed of the magnetic agitation is 8000r/min, when stirring Between be 30min;As shown in figure 4, also providing a kind of lubricating system based on the vegetalitas cutting oil, including oil storage room 1, gas Hydrodynamic press pump 2, solenoid valve 3, oil water separator 5, gas pressure detector 4, oil pressure detector 8, several nozzles 11, further include heat Imaging device 10, oil stream detector 7, automatic control module 9;Several described nozzles are correspondingly arranged within the scope of Metal Cutting Several lubricant housings on, be connected separately with pipeline between the nozzle and the oil storage room;The setting of oil stream detector In the junction of oil storage room and pipeline;The automatic control module includes receiving the sensor from thermal imaging device information, For analyzing the signal analysis module of conversion sensor information, the controller of signal analysis module signal, the control are received Device issues control signal, receives the warning device of control signal;The thermal imaging device information is Infrared Thermogram, such as Fig. 2 With shown in Fig. 3, the thermal expansion scatterplot of different area is formed on the infrared thermal imaging figure, it can be according to the thermal expansion scatterplot of different area Determine heating temperature, when the heating temperature is lower than 30 DEG C, the fountain height of the controller control vegetalitas cutting oil It is 0, when the heating temperature reaches 30 DEG C, the fountain height of the controller starting control vegetalitas cutting oil is 0.5ml/min, spraying time 1min, when the heating temperature reaches 60 DEG C, the controller starting control plant Property cutting oil fountain height be 1ml/min, spraying time 5min, when the heating temperature reaches 90 DEG C, the control The fountain height of device starting control vegetalitas cutting oil processed is 2.5ml/min, spraying time 10min;When heating temperature is higher than 180 DEG C when, the described controller control starting alarm signal.If being related to circuit connection in the present embodiment to realize entire lubricating system , the circuit connecting mode in system is repeated no more in embodiment.
Embodiment three:
A kind of vegetalitas cutting oil is by following weight percent at being grouped as: vegetable oil 51%, glycerol acrylate 45%, sulfurized olefin cotton oil 1%, compound phosphoric acid rouge 1%, butylene class adhesive 1%, antioxidant 1%;
The vegetable oil at room temperature, by magnetic agitation, is prepared into nanoparticle vegetable oil.
Nanoparticle vegetable oil is heated to 45 DEG C, sequentially adds glycerol acrylate, sulfurized olefin cotton oil, compound phosphorus Sour rouge and butylene class adhesive, and 20min is stirred at 45~60 DEG C of heat preservation, after mixing speed is maintained at 100~120min, add Enter antioxidant, continue to keep original mixing speed, continues to stir 20min to fully transparent, plant is obtained after natural cooling Property cutting oil.
Wherein, the vegetable oil is in soybean oil, castor oil, jatropha curcas oil, sunflower oil, rice bran oil and palm oil It is one or more;The compound phosphoric acid rouge uses di-n-butyl phosphite, tricresyl phosphate, isooctyl acid phosphate ten Eight amine salt, trithiophenyl phosphate, two or more any mixture in thiophosphoric acid complex ester amine salt;Described Butylene class adhesive is one or both of polybutene, polyisobutene;The antioxidant is benzotriazole derivative, tea is more Phenol, di-tert-butyl cresol are formed according to the ratio of 2:1:2;The mixing speed of the magnetic agitation is 5000r/min, when stirring Between be 45min.
In addition, as shown in Figure 1 and Figure 4, also providing a kind of lubricating system based on the vegetalitas cutting oil, including storage Grease chamber 1, air-driven hydraulic pump 2, solenoid valve 3, oil water separator 5, gas pressure detector 4, oil pressure detector 8, several nozzles 11, It further include thermal imaging device 10, oil stream detector 7, automatic control module 9.The oil storage room is for storing vegetalitas cutting Oil;The air-driven hydraulic pump is set in fuel reserve tank above-mentioned, for lubricating oil to be extruded fuel reserve tank above-mentioned, inlet end connection There is a tracheae, fuel-displaced port is connected with an oil pipe;The solenoid valve is used to control the working frequency of the air-driven hydraulic pump, Set on aforementioned air-driven hydraulic pump inlet end;The oil water separator is set in the oil outlet pipe of the air-driven hydraulic pump; The gas pressure detector, in the air inlet pipeline of aforementioned control valve, for perceiving air pressure size in air inlet pipeline;Described Oil pressure detector, in the oil outlet pipe of aforementioned air-driven hydraulic pump, for perceiving pressure in the hydraulic pump output oil pipe Size;Several described nozzles are correspondingly arranged on several lubricant housings within the scope of Metal Cutting, the nozzle with Flowline is connected separately between the oil storage room;The junction of oil storage room and pipeline is arranged in oil stream detector, is used for Detect the oil stream amount of the vegetalitas cutting oil in flowline;The automatic control module includes receiving to come from thermal imaging device The sensor of information receives the control of signal analysis module signal for analyzing the signal analysis module of conversion sensor information Device, the controller issue control signal, receive the warning device of control signal;As shown in Figures 2 and 3, the described heat at Picture device information is Infrared Thermogram, and the thermal expansion scatterplot of different area is formed on the infrared thermal imaging figure, can be according to difference The thermal expansion scatterplot of area determines heating temperature, and when the heating temperature is lower than 30 DEG C, the controller controls vegetalitas The fountain height of cutting oil is 0, when the heating temperature reaches 40 DEG C, the controller starting control vegetalitas cutting oil Fountain height be 0.5ml/min, spraying time 3min, when the heating temperature reaches 70 DEG C, the controller is opened The fountain height of dynamic control vegetalitas cutting oil is 1ml/min, spraying time 6min, when the heating temperature reaches 100 DEG C When, the fountain height of the controller starting control vegetalitas cutting oil is 2.5ml/min, spraying time 15min;When heated When temperature is higher than 180 DEG C, the controller control starting alarm signal.If it is whole to realize to be related to circuit connection in the present embodiment A lubricating system repeats no more the circuit connecting mode in system in embodiment.
Comparative example 1
A kind of vegetalitas cutting oil is by following weight percent at being grouped as: vegetable oil 51%, glycerol acrylate 45%, sulfurized olefin cotton oil 1%, compound phosphoric acid rouge 1%, butylene class adhesive 1%, antioxidant 1%;
Vegetable oil is heated to 45 DEG C, sequentially adds glycerol acrylate, sulfurized olefin cotton oil, compound phosphoric acid rouge and fourth Alkenes adhesive, and 20min is stirred at 45~60 DEG C of heat preservation, after mixing speed is maintained at 100~120min, it is added anti-oxidant Agent continues to keep original mixing speed, continues to stir 20min to fully transparent, it is oily that vegetalitas cutting is obtained after natural cooling.
Wherein, the vegetable oil is in soybean oil, castor oil, jatropha curcas oil, sunflower oil, rice bran oil and palm oil It is one or more;The compound phosphoric acid rouge uses di-n-butyl phosphite, tricresyl phosphate, isooctyl acid phosphate ten Eight amine salt, trithiophenyl phosphate, two or more any mixture in thiophosphoric acid complex ester amine salt;Described Butylene class adhesive is one or both of polybutene, polyisobutene;The antioxidant is benzotriazole derivative, tea is more Phenol, di-tert-butyl cresol are formed according to the ratio of 2:1:2.
In addition, as shown in Figure 1 and Figure 4, also providing a kind of lubricating system based on the vegetalitas cutting oil, including storage Grease chamber 1, air-driven hydraulic pump 2, solenoid valve 3, oil water separator 5, gas pressure detector 4, oil pressure detector 8, several nozzles 11, It further include thermal imaging device 10, oil stream detector 7, automatic control module 9.The oil storage room is for storing vegetalitas cutting Oil;The air-driven hydraulic pump is set in fuel reserve tank above-mentioned, for lubricating oil to be extruded fuel reserve tank above-mentioned, inlet end connection There is a tracheae, fuel-displaced port is connected with an oil pipe;The solenoid valve is used to control the working frequency of the air-driven hydraulic pump, Set on aforementioned air-driven hydraulic pump inlet end;The oil water separator is set in the oil outlet pipe of the air-driven hydraulic pump; The gas pressure detector, in the air inlet pipeline of aforementioned control valve, for perceiving air pressure size in air inlet pipeline;Described Oil pressure detector, in the oil outlet pipe of aforementioned air-driven hydraulic pump, for perceiving pressure in the hydraulic pump output oil pipe Size;Several described nozzles are correspondingly arranged on several lubricant housings within the scope of Metal Cutting, the nozzle with Flowline is connected separately between the oil storage room;The junction of oil storage room and pipeline is arranged in oil stream detector, is used for Detect the oil stream amount of the vegetalitas cutting oil in flowline;The automatic control module includes receiving to come from thermal imaging device The sensor of information receives the control of signal analysis module signal for analyzing the signal analysis module of conversion sensor information Device, the controller issue control signal, receive the warning device of control signal;As shown in Figures 2 and 3, the described heat at Picture device information is Infrared Thermogram, and the thermal expansion scatterplot of different area is formed on the infrared thermal imaging figure, can be according to difference The thermal expansion scatterplot of area determines heating temperature, and when the heating temperature is lower than 30 DEG C, the controller controls vegetalitas The fountain height of cutting oil is 0, when the heating temperature reaches 40 DEG C, the controller starting control vegetalitas cutting oil Fountain height be 0.5ml/min, spraying time 3min, when the heating temperature reaches 70 DEG C, the controller is opened The fountain height of dynamic control vegetalitas cutting oil is 1ml/min, spraying time 6min, when the heating temperature reaches 100 DEG C When, the fountain height of the controller starting control vegetalitas cutting oil is 2.5ml/min, spraying time 15min;When heated When temperature is higher than 180 DEG C, the controller control starting alarm signal.If it is whole to realize to be related to circuit connection in the present embodiment A lubricating system repeats no more the circuit connecting mode in system in embodiment.
Comparative example 2
A kind of vegetalitas cutting oil is by following weight percent at being grouped as: vegetable oil 51%, glycerol acrylate 45%, sulfurized olefin cotton oil 1%, compound phosphoric acid rouge 1%, butylene class adhesive 1%, antioxidant 1%;
The vegetable oil at room temperature, by magnetic agitation, is prepared into nanoparticle vegetable oil.
Nanoparticle vegetable oil is heated to 45 DEG C, sequentially adds glycerol acrylate, sulfurized olefin cotton oil, compound phosphorus Sour rouge and butylene class adhesive, and 20min is stirred at 45~60 DEG C of heat preservation, after mixing speed is maintained at 100~120min, add Enter antioxidant, continue to keep original mixing speed, continues to stir 20min to fully transparent, plant is obtained after natural cooling Property cutting oil.
Wherein, the vegetable oil is in soybean oil, castor oil, jatropha curcas oil, sunflower oil, rice bran oil and palm oil It is one or more;The compound phosphoric acid rouge uses di-n-butyl phosphite, tricresyl phosphate, isooctyl acid phosphate ten Eight amine salt, trithiophenyl phosphate, two or more any mixture in thiophosphoric acid complex ester amine salt;Described Butylene class adhesive is one or both of polybutene, polyisobutene;The antioxidant is benzotriazole derivative, tea is more Phenol, di-tert-butyl cresol are formed according to the ratio of 2:1:2;The mixing speed of the magnetic agitation is 5000r/min, when stirring Between be 45min.
Vegetalitas cutting oil sprinkling or sprinkle directly by preparation is at Metal Cutting position.
Examples 1 to 3 and the vegetalitas of comparison 1~2 are cut into oil, through Physico-chemical tests, index such as the following table 1.
Table 1
So explanation is appearance using GB/T3555 experimental method;Kinematic viscosity uses GB/T265 experimental method;Pour point Using GB/T3535 experimental method;Copper sheet uses GB/T5096 experimental method;Flash-point uses GB/T3536 experimental method.By table 1 Middle data analysis is it is found that the vegetable oil in comparative example 1 is without nanometered disposal, and obtained vegetalitas cutting oil performance is compared with it Its difference.
The vegetalitas cutting oil of Examples 1 to 3 preparation is opened wide in the environment of being placed on 60 DEG C, with plain oil same Deng under conditions of, the observation of plant cutting oil time rotten with oil ageing.As a result prepared by the embodiment of the present invention 1~3 There is slight oxidation deterioration after obtained vegetalitas cutting oil 5d, and there is deterioration on day 3 in plain oil, explanation Vegetalitas cutting oil of the invention has more significant antioxidant system, and quality is more stable.
In other detection, by Examples 1 to 3 and the vegetalitas of comparison 1~2 cutting oil according to corresponding embodiment It is tested with the lubricating system in corresponding comparative example, selected cutting metal is aluminum profile, but is not limited to aluminum profile, often Group is done 3 repetitions and is tested, and as a result record is as shown in table 2 below.
Table 2
It is analyzed by table 2 it is found that vegetalitas cutting oil of the invention has significant lubrication, cooling, buffering effect, in conjunction with profit The use of sliding system shows more significant atomizing effect, and the vegetable oil in comparative example 1 is without nanometered disposal, atomization effect Fruit is poor compared with embodiment 3, and vegetalitas cutting oil is directly sprayed at Metal Cutting position by comparative example 2, and atomizing effect is also relatively implemented Example 3 is poor.It should be noted that coefficient of losses described in table 2 is the value relatively obtained compared with Example 3, circular are as follows:
Coefficient of losses %=(the oily consumption of vegetalitas cutting in consumption-embodiment 3 of vegetalitas cutting oil in comparative example Amount) the consumption x100% of vegetalitas cutting oil in/embodiment 3.As can be seen from table 2 vegetalitas cutting oil of the invention and its The comprehensive of lubricating system uses, and can reduce the losing quantity of vegetalitas cutting oil.
In synthesis, vegetalitas cutting oil of the present invention has significant film forming, plays good lubrication, cooling and buffering is made With being able to maintain the cleaning in cutting face, and lubricating system is combined to use, obtain accurate fountain height, reduce losing quantity.
Although describing the present invention by reference to various embodiments above, but it is to be understood that of the invention not departing from In the case where range, many changes and modifications can be carried out.That is methods discussed above, system and equipment are examples. Various configurations can be omitted suitably, replaced or added various processes in addition, can update as technology develops element therein, I.e. many elements are examples, are not intended to limit the range of the disclosure or claims.
To sum up, be intended to foregoing detailed description be considered as it is illustrative and not restrictive, and it is to be understood that below Claim (including all equivalents) is intended to limit the spirit and scope of the present invention.The above embodiment is interpreted as only using In illustrating the present invention rather than limit the scope of the invention.After the content for having read record of the invention, technology Personnel can make various changes or modifications the present invention, these equivalence changes and modification equally fall into the claims in the present invention and limited Fixed range.

Claims (9)

1. a kind of vegetalitas cutting oil, which is characterized in that by following weight percent at being grouped as: vegetable oil 15~60%, Glycerol acrylate 25~45%, sulfurized olefin cotton oil 1~3%, compound phosphoric acid rouge 1~4%, butylene class adhesive 1~ 2%, antioxidant 1~5%;
The vegetable oil at room temperature, by magnetic agitation, is prepared into nanoparticle vegetable oil.
2. vegetalitas cutting oil as described in claim 1, which is characterized in that the vegetable oil is soybean oil, castor oil, fiber crops One of crazy tree oil, sunflower oil, rice bran oil and palm oil are a variety of.
3. the vegetalitas as described in one of preceding claims cuts oil, which is characterized in that the compound phosphoric acid rouge is phosphorous Sour di-n-butyl, tricresyl phosphate, isooctyl acid phosphate octadecylamine salt, trithiophenyl phosphate and thiophosphoric acid are compound In ester amine salt it is any two or more.
4. the vegetalitas as described in one of preceding claims cuts oil, which is characterized in that the butylene class adhesive is poly- One or both of butylene, polyisobutene.
5. the vegetalitas as described in one of preceding claims cuts oil, which is characterized in that the antioxidant is benzotriazole Derivative, tea polyphenols, di-tert-butyl cresol are formed according to the ratio of 1~3:1:1~3.
6. the vegetalitas as described in one of preceding claims cuts oil, which is characterized in that the stirring speed of the magnetic agitation Degree is 3000~8000r/min, and mixing time is 30~60min.
7. a kind of lubricating system cuts oil, including oil storage room, Pneumatic Liquid using the described in any item vegetalitas of claim 1~6 Press pump, solenoid valve, oil water separator, gas pressure detector, oil pressure detector and several nozzles, which is characterized in that further include heat Imaging device, oil stream detector and automatic control module.
8. lubricating system as claimed in claim 7, which is characterized in that several described nozzles are correspondingly arranged at Metal Cutting On several lubricant housings in range, pipeline is connected separately between the nozzle and the oil storage room.
9. the lubricating system as described in one of preceding claims, which is characterized in that the setting of oil stream detector is in oil storage room and pipe The junction in road.
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