CN110028900A - A kind of automobile finish brilliant liquid of plating and preparation method thereof - Google Patents
A kind of automobile finish brilliant liquid of plating and preparation method thereof Download PDFInfo
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- CN110028900A CN110028900A CN201910183654.5A CN201910183654A CN110028900A CN 110028900 A CN110028900 A CN 110028900A CN 201910183654 A CN201910183654 A CN 201910183654A CN 110028900 A CN110028900 A CN 110028900A
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- Prior art keywords
- plating
- brilliant liquid
- automobile finish
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/16—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers in which all the silicon atoms are connected by linkages other than oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Chemically Coating (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of automobile finish brilliant liquid of plating and preparation method thereof, plate brilliant liquid includes following raw material by weight percentage: Perhydropolysilazane 15~25%, hydrophilic titanium dioxide 2~7%, silane coupling agent 0.5~3%, dispersing agent 0.5~3%, cosolvent 0.5~3%, organic solvent 60~80%.After plating crystalline substance liquid of the invention is used on automobile finish, the water droplet contact angle of water formation is met less than 24 °, large area water skiing group can be formed, lacquer painting glossiness value added >=15Gs, compared to the existing plating crystal layer for plating only 2 weeks timeliness that brilliant liquid is formed, plating crystal layer timeliness of the invention is up to 10 months or more, substantially increases service life, crystal layer hardness >=6H after solidification.
Description
Technical field
It is brilliant with plating that the present invention relates to plating crystalline substance liquid for Motor Maintenance and preparation method thereof more particularly to a kind of automobile finish
Liquid and preparation method thereof.
Background technique
The matrix resin of automobile coating is generally traditional organic resin such as epoxy resin, acrylic resin, polyurethane resin, and
Organic species expose easily aging in a natural environment, the aging of automobile finish be mainly shown as loss of gloss, colour fading, discoloration and
Fall off dusting etc., and illumination, temperature change, moisture in nature and chemicals corrosion are lead to automobile finish aging main
Factor.Plating is brilliant, as newest lacquer painting maintenance technology, forms one layer of powerful protection crystal and ultraviolet filtering in automobile finish
Layer, can be improved lacquer painting brightness and intensity, prevent scratch, antiultraviolet and anticorrosion, effectively isolation dust, greasy dirt, mould, water
Erosion of the particles such as molecule to vehicle paint.
Common lacquer painting protective agent is that have the brilliant liquid of hydrophobic plating, but hydrophobic effect is unsatisfactory, when contact rainwater,
In mist, air when steam, bodywork surface is easy to be detained small water droplet, and small water droplet is left with watermark or water stain after disappearing.Publication No.
The Chinese patent of CN103897589A discloses a kind of inorganic water skiing of automobile finish and plates brilliant liquid and plating crystal method, and plating brilliant liquid includes nothing
Machine quartz, fatty glyceride, nonionic surfactant, cationic surface active agent and pure water form silicon oxygen in lacquer painting
One layer crystal body of based structures, this layer crystal body can make water not form water droplet and form large area water skiing group and slide downwards automatically,
The problem of can solve lacquer painting after rain there are raindrop traces.But due to having used surfactant to reduce coating hydrophilic angle, surface
Activating agent belongs to organic substance, and exposure is easy aging in the natural environment, so that crystal layer cannot keep long timeliness, service life
It is short.
Summary of the invention
Goal of the invention: in view of the above problems, the present invention proposes that a kind of brilliant liquid of plating, the plating crystalline substance liquid form one in surface of vehicle paint
Layer high-hydrophilic, long timeliness, the crystal layer with higher lacquer painting hardness.It is a further object of the present invention to provide the plating crystalline substance liquid
Preparation method.
Technical solution: automobile finish of the present invention includes following raw material: perhydro with brilliant liquid is plated by weight percentage
Polysilazane 15~25%, hydrophilic titanium dioxide 2~7%, silane coupling agent 0.5~3%, dispersing agent 0.5~3% help
Solvent 0.5~3%, organic solvent 60~80%.
The Perhydropolysilazane primarily serves lacquer painting protection, lacquer painting blast and the effect as adhesive.
The silane coupling agent is one or both of KH550, KH560 or KH570, plays dispersion aids and helps viscous
The effect of mixture.
The dispersing agent is at least one of propylene glycol monomethyl ether (PM) or dipropylene glycol methyl ether (DPM).
The cosolvent is at least one of polyvinyl butyral (PVB) or polyethylene glycol (PEG).
The organic solvent is one of ethyl acetate, butyl acetate, hexamethylene, n-hexane, chloroform or two
Kind.
The hydrophilic titanium dioxide can make to plate brilliant liquid with excellent hydrophilicity, hydrophilic titanium dioxide used
The partial size of titanium is 2~200nm, and if more than this particle size range, the plating crystalline substance liquid stability of preparation is bad, and is coated on automobile finish
Plating crystal layer have particle, hydrophilic effect does not reach requirement.
The method of the present invention for preparing above-mentioned plating crystalline substance liquid, comprising the following steps:
(1) organic solvent and hydrophilic titanium dioxide are mixed by weight percentage, with the stirring of 100~250rpm revolving speed
It mixes；It is subsequently added into dispersing agent, continues to stir and evenly mix with 100~250rpm revolving speed；Cosolvent is added, with 300~600rpm
Revolving speed stirring 10~for 24 hours, obtained solution A；
(2) organic solvent and Perhydropolysilazane are mixed by weight percentage, it is mixed with the stirring of 100~250rpm revolving speed
It is even, obtained solution；Silane coupling agent is added, 1~2h, obtained solution B are stirred with 100~250rpm revolving speed；
(3) solution B is added in solution A, stir 10 under 25~50 DEG C of water-baths with 300~600rpm revolving speed~for 24 hours, system
Brilliant liquid must be plated.
The utility model has the advantages that compared with prior art, remarkable advantage of the invention is: plating crystalline substance liquid of the invention is used for automobile finish
After upper, the water droplet contact angle of water formation is met less than 24 °, can form large area water skiing group, lacquer painting glossiness value added >=15Gs, phase
Than in the plating crystal layer of existing only 2 weeks timeliness, plating crystal layer timeliness of the invention is up to 10 months or more, substantially increases using the longevity
Life, crystal layer hardness >=6H after solidification, lacquer painting intensity is high, prevents scratch.
Specific embodiment
Below with reference to embodiment, the present invention is further illustrated.
Embodiment 1
Raw material composition: Perhydropolysilazane 25%, hydrophilic titanium dioxide 2%, silane coupling agent: KH5500.25%
With KH570 0.25%, dispersing agent: propylene glycol monomethyl ether PM 0.25% and dipropylene glycol methyl ether DPM 0.25%%, cosolvent: poly-
Ethylene glycol PEG-2000.5%, organic solvent: ethyl acetate 39.5% and hexamethylene 32%, wherein hydrophilic titanium dioxide
Partial size be 2nm.
Preparation method:
(1) hydrophilic titanium dioxide is added in ethyl acetate solvent under stirring, with the stirring of 250rpm revolving speed
It mixes；It is subsequently added into dispersing agent PM and DPM, is stirred and evenly mixed with 250rpm revolving speed；Cosolvent PEG-2000 is added, with 600rpm
Revolving speed stirs for 24 hours, obtains solution A；
(2) Perhydropolysilazane is added in hexamethylene under stirring, is stirred and evenly mixed with 250rpm revolving speed；It adds
Silane coupling agent KH550 and KH570 stir 2h, obtained solution B with 250rpm revolving speed；
(3) it takes solution B to be added slowly in solution A, 10h is stirred under 25 DEG C of water-baths with 600rpm revolving speed, be made and plate brilliant liquid.
Embodiment 2
Raw material composition: Perhydropolysilazane 20%, hydrophilic titanium dioxide 5%, silane coupling agent: KH5500.5% and
KH570 0.5%, dispersing agent: propylene glycol monomethyl ether PM 1.5%, cosolvent: polyethylene glycol PEG-2001% and polyvinyl alcohol contracting fourth
Aldehyde PVB 0.5%, organic solvent: ethyl acetate 41% and hexamethylene 30%, wherein the partial size of hydrophilic titanium dioxide is
20nm。
Preparation method:
(1) hydrophilic titanium dioxide is added in ethyl acetate solvent under stirring, with the stirring of 100rpm revolving speed
It mixes；It is subsequently added into dispersing agent PM, is stirred and evenly mixed with 100rpm revolving speed；Cosolvent PEG-2000 and PVB are added, with 300rpm
Revolving speed stirs 10h, obtains solution A；
(2) Perhydropolysilazane is added in hexamethylene under stirring, is stirred and evenly mixed with 100rpm revolving speed；It adds
Silane coupling agent KH550 and KH570 stir 1h, obtained solution B with 100rpm revolving speed；
(3) it takes solution B to be added slowly in solution A, is stirred under 35 DEG C of water-baths with 300rpm revolving speed for 24 hours, be made and plate brilliant liquid.
Embodiment 3
Raw material composition: Perhydropolysilazane 15%, hydrophilic titanium dioxide 6%, silane coupling agent: KH5501.5% and
KH560 1.5%, dispersing agent: propylene glycol monomethyl ether PM 1.5% and dipropylene glycol methyl ether DPM 1.5%, cosolvent: polyethylene glycol
PEG-2003%, organic solvent: butyl acetate 40% and hexamethylene 30%, wherein the partial size of hydrophilic titanium dioxide is
100nm。
Preparation method:
(1) hydrophilic titanium dioxide is added in butyl acetate solvent under stirring, with the stirring of 200rpm revolving speed
It mixes；It is subsequently added into dispersing agent PM and DPM, is stirred and evenly mixed with 200rpm revolving speed；Cosolvent PEG-2000 is added, with 400rpm
Revolving speed stirs 18h, obtains solution A；
(2) Perhydropolysilazane is added in hexamethylene under stirring, is stirred and evenly mixed with 200rpm revolving speed；It adds
Silane coupling agent KH550 and KH560 stir 1.5h, obtained solution B with 200rpm revolving speed；
(3) it takes solution B to be added slowly in solution A, 18h is stirred under 45 DEG C of water-baths with 400rpm revolving speed, be made and plate brilliant liquid.
Embodiment 4
Raw material composition: Perhydropolysilazane 20%, hydrophilic titanium dioxide 7%, silane coupling agent: KH5501.5% and
KH5701.5%, dispersing agent: propylene glycol monomethyl ether PM 1.5% and dipropylene glycol methyl ether DPM 1.5%, cosolvent: polyethylene glycol
PEG-200 3%, organic solvent: ethyl acetate 40% and hexamethylene 24%, wherein the partial size of hydrophilic titanium dioxide is
200nm。
Preparation method:
(1) hydrophilic titanium dioxide is added in ethyl acetate solvent under stirring, with the stirring of 250rpm revolving speed
It mixes；It is subsequently added into dispersing agent PM and DPM, is stirred and evenly mixed with 250rpm revolving speed；Cosolvent PEG-2000 is added, with 500rpm
Revolving speed stirs for 24 hours, obtains solution A；
(2) Perhydropolysilazane is added in hexamethylene under stirring, is stirred and evenly mixed with 250rpm revolving speed；It adds
Silane coupling agent KH550 and KH570 stir 2h, obtained solution B with 250rpm revolving speed；
(3) it takes solution B to be added slowly in solution A, 10h is stirred under 50 DEG C of water-baths with 600rpm revolving speed, be made and plate brilliant liquid.
Comparative example 1
Raw material composition: Perhydropolysilazane 25%, hexamethylene 75%.
Preparation method:
Perhydropolysilazane is added in cyclohexane solvent under stirring, is stirred and evenly mixed with 600rpm revolving speed, is prepared
Plate brilliant liquid.
Comparative example 2
Raw material composition: Perhydropolysilazane 10%, hydrophilic titanium dioxide 15%, silane coupling agent: KH550 1.5%
With KH570 1.5%, dispersing agent: propylene glycol monomethyl ether PM 1.5% and dipropylene glycol methyl ether DPM 1.5%, cosolvent: poly- second two
Alcohol PEG-200 3%, organic solvent: ethyl acetate 30% and hexamethylene 36%, wherein the partial size of hydrophilic titanium dioxide is
50nm。
Preparation method:
(1) hydrophilic titanium dioxide is added in ethyl acetate solvent under stirring, with the stirring of 250rpm revolving speed
It mixes；It is subsequently added into dispersing agent PM and DPM, is stirred and evenly mixed with 250rpm revolving speed；Cosolvent PEG-2000 is added, with 500rpm
Revolving speed stirs for 24 hours, obtains solution A；
(2) Perhydropolysilazane is added in hexamethylene under stirring, is stirred and evenly mixed with 250rpm revolving speed；It adds
Silane coupling agent KH550 and KH570 stir 2h, obtained solution B with 250rpm revolving speed；
(3) it takes solution B to be added slowly in solution A, 15h is stirred under 35 DEG C of water-baths with 600rpm revolving speed, be made and plate brilliant liquid.
Comparative example 3
Raw material composition: Perhydropolysilazane 20%, hydrophilic titanium dioxide 5%, dispersing agent: propylene glycol monomethyl ether PM
1.5%, cosolvent: polyethylene glycol PEG-200 1% and polyvinyl butyral PVB 0.5%, organic solvent: ethyl acetate
42% and hexamethylene 30%, wherein the partial size of hydrophilic titanium dioxide is 20nm.
Preparation method:
(1) hydrophilic titanium dioxide is added in ethyl acetate solvent under stirring, with the stirring of 100rpm revolving speed
It mixes；It is subsequently added into dispersing agent PM, is stirred and evenly mixed with 100rpm revolving speed；Cosolvent PEG-2000 and PVB are added, with 300rpm
Revolving speed stirs 10h, obtains solution A；
(2) Perhydropolysilazane is added in hexamethylene under stirring, is stirred and evenly mixed with 100rpm revolving speed, is made molten
Liquid B；
(3) it takes solution B to be added slowly in solution A, is stirred under 35 DEG C of water-baths with 300rpm revolving speed for 24 hours, be made and plate brilliant liquid.
By the brilliant liquid erasing of plating obtained by Examples 1 to 4 and comparative example 1~3 on the clean paint plate that deoiled, room temperature is solid
Change for 24 hours, paint plate surface forms uniformly plating crystal layer, is tested for the property to plating crystal layer, test result is as shown in table 1.
Each embodiment of table 1 plates the performance test data that brilliant liquid forms plating crystal layer in paint plate surface
Weatherability test: the paint plate that surface is coated with plating crystal layer is placed in natural environment, its hydrophilic and stabilization of periodic observation
Performance has the time limit to fall off as weatherability when water droplet contact angle is greater than 60 ° or coating.
As known from Table 1, the contact angle of 40 ° of crystal layer of plating is formed by without hydrophilic titanium dioxide compared to comparative example 1,
So that the hydrophily of plating crystal layer significantly improves, contact angle is down within 30 ° for the addition of hydrophilic titanium dioxide, minimum 20 °.
This is because, on the one hand, hydrophilic titanium dioxide changes through sunlight irradiation lower surface configuration, has Superhydrophilic；
On the other hand, nano-titanium dioxide and Perhydropolysilazane, which play, acts synergistically, and both has water-wet behavior, wherein nanometer two
The hydrophily of titanium oxide is most efficient.
Although nano-titanium dioxide can be improved the hydrophily of plating crystal layer, works as and contain excessively high hydrophilic nano in system
Not high enough with the combination degree of lacquer painting base material when titanium dioxide, desirable is not achieved in service life and glossiness value added,
There can be negative influence to the increase of glossiness and weatherability.In comparative example 2, when hydrophilic content of titanium dioxide is up to
15%, although showing preferable hydrophily, contact angle minimizes 20 °, and adhesive force is 1 grade, other embodiments and comparison
The adhesive force of example is 0 grade, and series is bigger, and adhesion effect is poorer, it is seen that the hydrophilic nano titanium dioxide of too high levels will lead to
The combination degree for plating crystal layer and base material is not high；Glossiness value added only has 3Gs, and the weatherability service life only has 1 month, and coating is very
It falls off fastly.Comprehensively consider, when content is 5% to hydrophilic titanium dioxide in system (embodiment 2), is being obviously improved its parent
While aqueous, moreover it is possible to guarantee smaller to glossiness value added and aging effects.
Plating crystalline substance liquid prepared by comparative example 3 is 25 °, has preferable hydrophily although the contact angle of plating crystal layer is lower,
Its weather-proof time limit only has 3 months.Silane coupling agent, the hydrophilic nano two as inorganic substances are free of this is because plating in brilliant liquid
The compatibility of titanium oxide and the Perhydropolysilazane as organic substance is bad, and prepared plating crystalline substance fluidity can be undesirable.Therefore
The present invention is added silane coupling agent in plating brilliant liquid, and silane coupling agent is in hydrophilic nano titanium dioxide and Perhydropolysilazane
Molecular bridge is erected between interface, so that the material of both properties great disparity is linked together, maintains the stability for plating brilliant liquid, from
And coating more evenly, improve the service performance for plating brilliant liquid.
Claims (10)
1. a kind of automobile finish brilliant liquid of plating, which is characterized in that by weight percentage include following raw material: Perhydropolysilazane
15~25%, hydrophilic titanium dioxide 2~7%, silane coupling agent 0.5~3%, dispersing agent 0.5~3%, cosolvent 0.5~
3%, organic solvent 60~80%.
2. automobile finish according to claim 1 is with plating brilliant liquid, which is characterized in that the silane coupling agent be KH550,
One or both of KH560 or KH570.
3. automobile finish according to claim 1 is with plating brilliant liquid, which is characterized in that the dispersing agent be propylene glycol monomethyl ether or
At least one of dipropylene glycol methyl ether.
4. the automobile finish according to claim 1 brilliant liquid of plating, which is characterized in that the cosolvent is polyvinyl alcohol contracting fourth
At least one of aldehyde or polyethylene glycol.
5. the automobile finish according to claim 1 brilliant liquid of plating, which is characterized in that the organic solvent is acetic acid second
One or both of ester, butyl acetate, hexamethylene, n-hexane, chloroform.
6. the automobile finish according to claim 1 brilliant liquid of plating, which is characterized in that the grain of the hydrophilic titanium dioxide
Diameter is 2~200nm.
7. a kind of method for preparing automobile finish described in claim 1 and plating brilliant liquid, which comprises the following steps:
(1) organic solvent and hydrophilic titanium dioxide are mixed by weight percentage, is stirred and evenly mixed；Dispersing agent is subsequently added into,
Continue to stir and evenly mix；Add cosolvent, stirring 10~for 24 hours, obtained solution A；
(2) organic solvent and Perhydropolysilazane are mixed by weight percentage, is stirred and evenly mixed, obtained solution；It is even that silane is added
Join agent, stirs 1~2h, obtained solution B；
(3) solution B is added in solution A, stir 10 under 25~50 DEG C of water-baths~for 24 hours, it is made and plates brilliant liquid.
8. the automobile finish according to claim 7 method for plating brilliant liquid, which is characterized in that organic in the step (1)
It is 100~250rpm that revolving speed, which is mixed, in solvent and hydrophilic titanium dioxide, the speed of agitator after dispersing agent is added is 100~
250rpm, the speed of agitator after cosolvent is added are 300~600rpm.
9. the automobile finish according to claim 7 method for plating brilliant liquid, which is characterized in that organic in the step (2)
It is 100~250rpm that revolving speed, which is mixed, in solvent and Perhydropolysilazane, the speed of agitator after silane coupling agent is added is 100~
250rpm。
10. the automobile finish according to claim 7 method for plating brilliant liquid, which is characterized in that solution in the step (3)
It is 300~600rpm that revolving speed, which is mixed, in B and solution A.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910183654.5A CN110028900A (en) | 2019-03-12 | 2019-03-12 | A kind of automobile finish brilliant liquid of plating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910183654.5A CN110028900A (en) | 2019-03-12 | 2019-03-12 | A kind of automobile finish brilliant liquid of plating and preparation method thereof |
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| Publication Number | Publication Date |
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| CN110028900A true CN110028900A (en) | 2019-07-19 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910183654.5A Pending CN110028900A (en) | 2019-03-12 | 2019-03-12 | A kind of automobile finish brilliant liquid of plating and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111548732A (en) * | 2020-04-30 | 2020-08-18 | 广州弘海化工科技有限公司 | Super-hydrophilic silicon nano-microstructure anti-reflection coating and preparation and use methods thereof |
| CN115109515A (en) * | 2022-07-04 | 2022-09-27 | 得尔塔(云浮)新材料有限公司 | Preparation method and preparation device of crystal plating liquid for automobile paint surface |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103897589A (en) * | 2014-04-11 | 2014-07-02 | 马忠毅 | Inorganic water-skiing crystal plating liquid for car paint surface and crystal plating method |
| CN104826785A (en) * | 2015-06-02 | 2015-08-12 | 李虎 | Application method of plating crystal liquid used for painted surfaces and hubs of automobile |
| CN104830105A (en) * | 2015-06-02 | 2015-08-12 | 李虎 | Crystal coating liquid for automotive paint surfaces and wheel hubs |
| CN107384219A (en) * | 2017-08-10 | 2017-11-24 | 中国科学院长春应用化学研究所 | A kind of automobile finish polishing agent and preparation method thereof |
| CN108485329A (en) * | 2018-05-05 | 2018-09-04 | 泉州三欣新材料科技有限公司 | A kind of super-hydrophilic self-cleaning coating sol and its preparation and application |
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2019
- 2019-03-12 CN CN201910183654.5A patent/CN110028900A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103897589A (en) * | 2014-04-11 | 2014-07-02 | 马忠毅 | Inorganic water-skiing crystal plating liquid for car paint surface and crystal plating method |
| CN104826785A (en) * | 2015-06-02 | 2015-08-12 | 李虎 | Application method of plating crystal liquid used for painted surfaces and hubs of automobile |
| CN104830105A (en) * | 2015-06-02 | 2015-08-12 | 李虎 | Crystal coating liquid for automotive paint surfaces and wheel hubs |
| CN107384219A (en) * | 2017-08-10 | 2017-11-24 | 中国科学院长春应用化学研究所 | A kind of automobile finish polishing agent and preparation method thereof |
| CN108485329A (en) * | 2018-05-05 | 2018-09-04 | 泉州三欣新材料科技有限公司 | A kind of super-hydrophilic self-cleaning coating sol and its preparation and application |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111548732A (en) * | 2020-04-30 | 2020-08-18 | 广州弘海化工科技有限公司 | Super-hydrophilic silicon nano-microstructure anti-reflection coating and preparation and use methods thereof |
| CN115109515A (en) * | 2022-07-04 | 2022-09-27 | 得尔塔(云浮)新材料有限公司 | Preparation method and preparation device of crystal plating liquid for automobile paint surface |
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Application publication date: 20190719 |