CN110028145A - A kind of thermal power plant indirect air cooling unit Circulating Water Corrosion control system and method - Google Patents
A kind of thermal power plant indirect air cooling unit Circulating Water Corrosion control system and method Download PDFInfo
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- CN110028145A CN110028145A CN201910328892.0A CN201910328892A CN110028145A CN 110028145 A CN110028145 A CN 110028145A CN 201910328892 A CN201910328892 A CN 201910328892A CN 110028145 A CN110028145 A CN 110028145A
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/66—Treatment of water, waste water, or sewage by neutralisation; pH adjustment
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/02—Non-contaminated water, e.g. for industrial water supply
- C02F2103/023—Water in cooling circuits
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Abstract
The invention discloses a kind of thermal power plant indirect air cooling unit Circulating Water Corrosion control system and methods, including indirect cool tower, condenser, water circulating pump, carbon dioxide storage tank, aqueduct, detector and controller;The outlet of indirect cool tower is connected with the entrance of condenser, the outlet of condenser is connected with the entrance of water circulating pump, the outlet of water circulating pump and the outlet of carbon dioxide storage tank by aqueduct after pipeline and pipe with the entrance of indirect cool tower by being connected, condenser outlet is connected with the thief hatch on pipeline between water circulating pump entrance with the entrance of detector, the output end of detector is connected with the input terminal of controller, the output end of controller is connected with the control terminal of carbon dioxide storage tank, the system and method, which can effectively solve the problem that, existing in the prior art causes water resource waste by replacing section recirculated water, circulating-water bypass stream process invests the problem of big O&M cost is high and recirculated water agent-feeding treatment water quality indicator is difficult to control conductance raising.
Description
Technical field
The invention belongs to chemistry and technology of chemical engineering and new energy and field of energy-saving technology, are related to a kind of thermal power plant
Indirect air cooling unit Circulating Water Corrosion control system and method.
Background technique
Company standard is mainly the execution provided referring to manufacturer at present, in conjunction with DL/T1717-2017 " fuel gas-steam
Combined cycle power plant's chemical supervision fire protection technology " in surface indirect air cooling system circulating water quality requirement, just to fired power generating unit
The indexs such as pH value, conductivity, the oxygen content of normal working cycles water propose basic demand: whenever pH=6.5-8.5 (does not permit
Perhaps more than 9);10 μ S/cm of conductivity (25 DEG C) <;Recirculated water O2=30~300 μ g/L, silica≤20 μ g/L.
According to thermal power plant indirect air cooling unit practical operating experiences feed back prove, circulation there are carbon steel, no
The electrochemical state of rust steel and 1050A fine aluminium ternary corrosion system, using fine aluminium material following as air cooling heat radiator structure material
All there is water quality deterioration, pH burst although having used the demineralized water of high quality in constructin phase and operation in ring water system
Property increase (pH=8.5 aluminium starts to corrode, and pH=9 starts fast erosion), cause 1050A fine aluminium air cooling heat radiator occur it is serious
Corrosion leakage leads to the production accident of compressor emergency shutdown, causes huge threat to indirect air cooling unit safety operation.It is indirectly empty
Cool circulation water system moisture storage capacity is big, only by change the method for water management pH in Circulating Water it is unsatisfactory and with water-saving design thinking carry on the back
Road and speed;The pH value that unit recirculated water is effectively reduced using recirculated water cation bed treatment process, work well but once invest compared with
Greatly, later period operation and maintenance amount is big;A small amount of phosphoric acid is added in recirculated water or ammonium hydroxide is adjusted pH, exists although pH value can be controlled
A certain range reduces tubing corrosion risk, but salt content increases in demineralized water, and conductivity can also increase.
Three of the above method, from different angles pair between SAPMAC method system circulating water water quality be adjusted processing, control water
Matter pH value, but the application at present in cool circulation water system is still not perfect, and need to reinforce the compound research of basic type, controlled investment
The operating cost in later period is saved, cross-over experiment is carried out, convenient for expanding application.
Summary of the invention
It is an object of the invention to overcome the above-mentioned prior art, a kind of thermal power plant indirect air cooling machine is provided
Group Circulating Water Corrosion control system and method, which, which can effectively solve the problem that, existing in the prior art passes through replacement section
Dividing recirculated water that water resource waste, circulating-water bypass stream process is caused to invest, big O&M cost is high and recirculated water agent-feeding treatment water quality refers to
It marks and is difficult to control the problem of conductance increases.
In order to achieve the above objectives, thermal power plant indirect air cooling unit Circulating Water Corrosion control system packet of the present invention
Include indirect cool tower, condenser, water circulating pump, carbon dioxide storage tank, aqueduct, detector and controller;
The outlet of indirect cool tower is connected with the entrance of condenser, and the outlet of condenser is connected with the entrance of water circulating pump,
The outlet of water circulating pump and the outlet of carbon dioxide storage tank pass through the entrance phase after pipeline and pipe by aqueduct and indirect cool tower
Connection, condenser outlet are connected with the thief hatch on pipeline between water circulating pump entrance with the entrance of detector, detector
Output end is connected with the input terminal of controller, and the output end of controller is connected with the control terminal of carbon dioxide storage tank.
It is connected between the entrance of detector and the thief hatch by the first control valve.
The exit of carbon dioxide storage tank is provided with the second control valve, the control of the output end of controller and the second control valve
End is connected.
The outlet of carbon dioxide storage tank is connected by third control valve with aqueduct.
The controller is PLC controller.
The detector is pH value detector, gas concentration lwevel detector or carbonate concentration detector.
Indirect air cooling unit Circulating Water Corrosion control method in thermal power plant of the present invention the following steps are included:
When detector be pH value detector when, then by detector real-time detection condenser outlet with water circulating pump entrance it
Between in pipeline recirculated water pH value, when the pH value of recirculated water exceeds pH value in pipeline between condenser outlet and water circulating pump entrance
When preset value, then the second control valve is controlled, by being filled in the intermittent recirculated water into aqueduct of carbon dioxide storage tank
Carbon dioxide gas, so that the pH value of recirculated water is in preset in pipeline between condenser outlet and water circulating pump entrance
In pH value range;
When detector is carbonate concentration detector, is exported by detector real-time detection condenser and be pumped into recirculated water
Between mouthful in pipeline recirculated water carbonate concentration, when between condenser outlet and water circulating pump entrance in pipeline recirculated water carbon
When acid group concentration is less than or equal to carbonate concentration preset value, then the second control valve is controlled, it is intermittent by carbon dioxide storage tank
It is filled with carbon dioxide gas in recirculated water into aqueduct, so that between condenser outlet and water circulating pump entrance in pipeline
The carbonate concentration of recirculated water is within the scope of preset carbonate concentration;
When detector is gas concentration lwevel detector, is exported by detector real-time detection condenser and be pumped into recirculated water
Between mouthful in pipeline recirculated water gas concentration lwevel, when recirculated water in pipeline between condenser outlet and water circulating pump entrance
When gas concentration lwevel is less than or equal to gas concentration lwevel preset value, then the second control valve is controlled, by between carbon dioxide storage tank
It is filled with carbon dioxide gas in the recirculated water into aqueduct of having a rest property, so that between condenser outlet and water circulating pump entrance
The gas concentration lwevel of recirculated water is within the scope of preset gas concentration lwevel in pipeline.
The invention has the following advantages:
Thermal power plant indirect air cooling unit Circulating Water Corrosion control system and method for the present invention are in concrete operations
When, using carbon dioxide gas as medicament, by the way that carbon dioxide gas is added in the recirculated water into cold group, thus recycling
H is ionized out in water+Ion so that the chemical attack of system material be inhibited to react, while will not be produced with reducing the pH value of recirculated water
Raw new corrosion product, and then the risk of system corrosion is reduced, the hidden danger of unit safety operation is reduced, with other medicaments and place
Reason method compares more securely and reliably, can save a large amount of demineralized waters, and structure is simple, easy to operate, primary investment and maintenance
Expense is extremely low, and economic benefit and environmental benefit are significant.
Detailed description of the invention
Fig. 1 is the structural diagram of the present invention.
Wherein, 1 it is condenser, 2 be indirect cool tower, 3 be water circulating pump, 4 be third control valve, 5 is carbon dioxide storage tank, 6
It is detector for controller, 7,8 is the first control valve.
Specific embodiment
The invention will be described in further detail with reference to the accompanying drawing:
The carbon dioxide to dissociate in water is highly unstable, is easy to be influenced by factors such as temperature, pressure, times.Between cooling system
Recirculated water is closed cycle, and pressure is generated by cooling tower static pressure and water circulating pump 3, dissolution of the carbon dioxide gas in demineralized water
Increase with the increase of pressure, is reduced with the raising of water temperature.Free carbon dioxide gas is easily escaped from water body.
Cold group recirculated water water temperature is generally below 60 DEG C between nominal situation operation is lower, rotten in chrome-bearing steel iron in the region lower than 60 DEG C
Protectiveness corrosion product protective film can be formed after erosion, slow down the rate of corrosion;Between cold group recirculated water be added carbon dioxide after
Carbon dioxide partial pressure is extremely low, and when the partial pressure of carbon dioxide is lower than 0.02MPa, then corrosion be can be ignored.
It should be noted that a cold group adds CO 2 technology to be to adjust pH value based on carbon dioxide attribute, two
Carbonoxide claims anhydride of carbonic acid, is one of oxycarbide, is a kind of inorganic matter, and when low concentration is non-toxic.Carbon dioxide can be dissolved in
Water simultaneously reacts generation carbonic acid with water, and unstable carbonic acid is readily decomposed to water and carbon dioxide, and free carbon dioxide escapes,
Chemical equation in water are as follows:
H2O+CO2=H2CO3
H2CO3=H2O+CO2
Hydrogen ion is reacted with the hydroxide ion in water generates water, will not additionally add other impurities ion, while effectively
The pH value for reducing recirculated water makes an alkaline corrosion for cold heat sink tube bank and cycle chemistry corrosion be effectively controlled, controls
Circulating water quality index is in the reasonable scope.
Based on the above principles, with reference to Fig. 1, thermal power plant indirect air cooling unit Circulating Water Corrosion control of the present invention
System includes indirect cool tower 2, condenser 1, water circulating pump 3, carbon dioxide storage tank 5, aqueduct, detector 7 and controller 6;Between
The outlet of cold tower 2 is connected with the entrance of condenser 1, and the outlet of condenser 1 is connected with the entrance of water circulating pump 3, recirculated water
The outlet of pump 3 and the outlet of carbon dioxide storage tank 5 by aqueduct after pipeline and pipe with the entrance of indirect cool tower 2 by being connected
Logical, the outlet of condenser 1 is connected with the thief hatch on pipeline between 3 entrance of water circulating pump with the entrance of detector 7, detector 7
Output end be connected with the input terminal of controller 6, the output end of controller 6 is connected with the control terminal of carbon dioxide storage tank 5.
It is connected between the entrance of detector 7 and the thief hatch by the first control valve 8;Carbon dioxide storage tank 5 goes out
It is provided with the second control valve at mouthful, the output end of controller 6 is connected with the control terminal of the second control valve;Carbon dioxide storage tank 5
Outlet be connected by third control valve 4 with aqueduct;The controller 6 is PLC controller;The detector 7 is pH
It is worth detector, gas concentration lwevel detector or carbonate concentration detector.
Indirect air cooling unit Circulating Water Corrosion control method in thermal power plant of the present invention the following steps are included:
When detector 7 is pH value detector, then entered by the outlet of 7 real-time detection condenser 1 of detector with water circulating pump 3
Between mouthful in pipeline recirculated water pH value, when the pH value of recirculated water is super in pipeline between the outlet of condenser 1 and 3 entrance of water circulating pump
Out when pH value preset value, then the second control valve is controlled, passes through the intermittent recirculated water into aqueduct of carbon dioxide storage tank 5
In be filled with carbon dioxide gas so that between the outlet of condenser 1 and 3 entrance of water circulating pump in pipeline at the pH value of recirculated water
In in preset pH value range;
When detector 7 is carbonate concentration detector, pass through the outlet of 7 real-time detection condenser 1 of detector and recirculated water
The carbonate concentration for pumping recirculated water in pipeline between 3 entrances follows in pipeline between 3 entrance of water circulating pump when condenser 1 is exported
When the carbonate concentration of ring water is less than or equal to carbonate concentration preset value, then the second control valve is controlled, carbon dioxide storage tank 5 is passed through
It is filled with carbon dioxide gas in the intermittent recirculated water into aqueduct, so that the outlet of condenser 1 and 3 entrance of water circulating pump
Between in pipeline the carbonate concentration of recirculated water be within the scope of preset carbonate concentration;
When detector 7 is gas concentration lwevel detector, pass through the outlet of 7 real-time detection condenser 1 of detector and recirculated water
The gas concentration lwevel for pumping recirculated water in pipeline between 3 entrances, when condenser 1 exports between 3 entrance of water circulating pump in pipeline
When the gas concentration lwevel of recirculated water is less than or equal to gas concentration lwevel preset value, then the second control valve is controlled, titanium dioxide is passed through
It is filled with carbon dioxide gas in the intermittent recirculated water into aqueduct of carbon storage tank 5, so that the outlet of condenser 1 and recirculated water
The gas concentration lwevel for pumping recirculated water in pipeline between 3 entrances is within the scope of preset gas concentration lwevel.
Embodiment one
A cool circulation water system is taken to be directly added into the pH value of the mode control loop water of carbon dioxide gas, in engineering reality
Good result is obtained in example application, the indexs such as pH value and conductivity can control in the reasonable scope, and table 1 is that certain power plant adds CO2
Adjust the table of water quality, wherein since the October plus carbon dioxide gas, data are shown, water after carbon dioxide gas is added
PH value, conductance and the Al content of matter are all gradually reduced.
Table 1
Date | pH | Conductivity/(μ S/cm) | Aluminium/(μ g/L) | Iron/(μ g/L) |
October 26 | 9.23 | 31.88 | 1594 | 2940 |
October 28 | 9.03 | 19.32 | 1328 | 2798 |
October 31 | 8.94 | 19.20 | 1137 | 2735 |
November 1 | 8.89 | 17.80 | 1034 | 2615 |
November 2 | 8.84 | 16.06 | 799.3 | 2450 |
November 3 | 8.78 | 15.40 | 694.2 | 2379 |
November 4 | 8.69 | 15.02 | 657.2 | 2070 |
November 5 | 8.68 | 14.82 | 654.5 | 2032 |
November 6 | 8.45 | 13.78 | 647.5 | 2756 |
November 7 | 8.42 | 10.76 | 549.0 | 1586 |
November 8 | 8.10 | 10.21 | 462.4 | 1287 |
November 10 | 7.97 | 10.03 | 429.2 | 715.8 |
November 12 | 7.71 | 9.510 | 382.5 | 654.4 |
November 14 | 7.52 | 9.350 | 351.9 | 497.1 |
November 18 | 7.51 | 7.220 | 124.7 | 271.3 |
November 20 | 7.49 | 6.640 | 91.40 | 205.2 |
November 22 | 8.19 | 4.630 | 66.40 | 92.10 |
In the present embodiment, using in recirculated water be added carbon dioxide effectively control pH value, not only control pH value for a long time
It makes in the reasonable scope, and other water quality indicators can control and maintain good level.
In the debugging stage, due to equipment manufacturing defect early period, erection stage anti-corrosion is impaired or rinse stage is due to newly-built
Originally demineralized water water is limited for unit, leads to rinse unqualified, generation pH value raising, to prevent apparatus body from further corroding,
It generallys use addition ammonium hydroxide to be adjusted pH, ammonium hydroxide is carried out in two steps with reacting for the carbon dioxide in demineralized water:
NH3H2O+CO2=NH4HCO3
NH4HCO3+NH4OH=(NH4)2CO3+H2O
By above-mentioned reactional equation it is found that the carbon dioxide reaction in ammonium hydroxide and demineralized water is weak acid and weak base reaction, reaction
Final result is alkalescent, less free H+And OH-Reach chemical balance, the pH value of ammonification processing control loop water is certain
In range, tubing corrosion can be slowed down, but ammonia residual control aspect has certain difficulty, conductivity can also rise, therefore ammonification side
Formula effect is less desirable, is not recommended to use.
Since system debug operation plus carbon dioxide, pass through the prolonged water quality under different phase difference operating condition
Assay examination, circulating water quality is good, and the indexs such as pH value, iron and aluminium are always maintained in the reasonable scope, and system material is rotten
Erosion influences to be substantially reduced, and the service life of cool equipment between extension guarantees the long-term safety reliability service of unit.
Start water circulating pump 3 and carry out circulation flushing, detection recirculated water includes pH value, conductivity, iron content, aluminium content and hangs
Floating object should drain, and replaced with demineralized water when the conductivity of recirculated water is more than 50 μ S/cm.When conductivity is less than 10 μ S/cm, pH
Value is at 6.5~8.2, and after rinsing qualification, then successively demineralized water is rinsed on cooling triangle, and water rinses on each cooling triangle
3~4h continuously detects circulating water quality, mainly includes pH value, conductivity and aluminium content, keeps a close eye on pH in Circulating Water and aluminium contains
The situation of change of amount, it is ensured that water quality reaching standard.After bringing into operation when the pH value of recirculated water be more than or equal to 8.5, then into recirculated water plus
Enter carbon dioxide gas, so that the pH value of adjustment recirculated water is adjusted to 7.2-8.3.
It should be noted that the present invention is using carbon dioxide as gas media, and it is cheap to facilitate buying, it is easy to precisely control
It makes and adds, cooling system water correction is more soft between the weak acid environment pair formed after dissolution, more conducively controls, and to recirculated water
The influence of conductance is very limited, while not introducing other ions, effectively inhibits the chemical attack reaction of influence system material, in conjunction with
Automatic medicament feeding system accurately controls the additive amount of (pressure of decompression adjustment gas, flow) carbon dioxide, and recirculated water is effectively reduced
Middle erosive carbon dioxide makes pH value control in the reasonable scope to system corrosion of metal, guarantees cycle water safety.
Claims (7)
1. a kind of thermal power plant indirect air cooling unit Circulating Water Corrosion control system, which is characterized in that including indirect cool tower (2),
Condenser (1), water circulating pump (3), carbon dioxide storage tank (5), aqueduct, detector (7) and controller (6);
The outlet of indirect cool tower (2) is connected with the entrance of condenser (1), the outlet of condenser (1) and the entrance of water circulating pump (3)
Be connected, the outlet of water circulating pump (3) and the outlet of carbon dioxide storage tank (5) by after pipeline and pipe by aqueduct and
The entrance of cold tower (2) is connected, the thief hatch and detector between condenser (1) outlet and water circulating pump (3) entrance on pipeline
(7) entrance is connected, and the output end of detector (7) is connected with the input terminal of controller (6), the output end of controller (6)
It is connected with the control terminal of carbon dioxide storage tank (5).
2. thermal power plant indirect air cooling unit Circulating Water Corrosion control system according to claim 1, which is characterized in that
It is connected between the entrance and thief hatch of detector (7) by the first control valve (8).
3. thermal power plant indirect air cooling unit Circulating Water Corrosion control system according to claim 2, which is characterized in that
The exit of carbon dioxide storage tank (5) is provided with the second control valve, the output end of controller (6) and the control terminal of the second control valve
It is connected.
4. thermal power plant indirect air cooling unit Circulating Water Corrosion control system according to claim 3, which is characterized in that
The outlet of carbon dioxide storage tank (5) is connected by third control valve (4) with aqueduct.
5. thermal power plant indirect air cooling unit Circulating Water Corrosion control system according to claim 1, which is characterized in that
The controller (6) is PLC controller.
6. thermal power plant indirect air cooling unit Circulating Water Corrosion control system according to claim 1, which is characterized in that
The detector (7) is pH value detector, gas concentration lwevel detector or carbonate concentration detector.
7. a kind of thermal power plant indirect air cooling unit Circulating Water Corrosion control method, which is characterized in that be based on claim 6 institute
The thermal power plant indirect air cooling unit Circulating Water Corrosion control system stated, comprising the following steps:
When detector (7) are pH value detector, then pass through detector (7) real-time detection condenser (1) outlet and water circulating pump
(3) between entrance in pipeline recirculated water pH value, recycled in pipeline when between condenser (1) outlet and water circulating pump (3) entrance
When the pH value of water exceeds pH value preset value, then the second control valve is controlled, it is intermittent to water-supply-pipe by carbon dioxide storage tank (5)
It is filled with carbon dioxide gas in recirculated water in road, so that pipeline between condenser (1) outlet and water circulating pump (3) entrance
The pH value of middle recirculated water is in preset pH value range;
When detector (7) are carbonate concentration detector, are exported and recycled by detector (7) real-time detection condenser (1)
Between water pump (3) entrance in pipeline recirculated water carbonate concentration, when condenser (1) outlet water circulating pump (3) entrance between
When the carbonate concentration of recirculated water is less than or equal to carbonate concentration preset value in pipeline, then the second control valve is controlled, dioxy is passed through
Change carbon storage tank (5) intermittent recirculated water into aqueduct in be filled with carbon dioxide gas so that condenser (1) outlet with
The carbonate concentration of recirculated water is within the scope of preset carbonate concentration in pipeline between water circulating pump (3) entrance;
When detector (7) is gas concentration lwevel detector, is exported and recycled by detector (7) real-time detection condenser (1)
Between water pump (3) entrance in pipeline recirculated water gas concentration lwevel, when condenser (1) outlet with water circulating pump (3) entrance it
Between when the gas concentration lwevel of recirculated water is less than or equal to gas concentration lwevel preset value in pipeline, then control the second control valve, lead to
It crosses in the intermittent recirculated water into aqueduct of carbon dioxide storage tank (5) and is filled with carbon dioxide gas, so that condenser (1)
The gas concentration lwevel of recirculated water is in preset gas concentration lwevel range in pipeline between outlet and water circulating pump (3) entrance
It is interior.
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Cited By (3)
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CN111777157A (en) * | 2020-05-27 | 2020-10-16 | 华能陕西渭南热电有限公司 | Cold circulating water quality adjusting method |
CN111807495A (en) * | 2020-08-05 | 2020-10-23 | 西安热工研究院有限公司 | Water quality control device and method for preventing corrosion of indirect air-cooling circulating water system |
CN112858615A (en) * | 2021-01-21 | 2021-05-28 | 西安热工研究院有限公司 | Water sample pH adjusting device and working method thereof |
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