CN110010945A - A7The iron-based flow battery of model and its positive and negative anodes electrolyte and preparation method - Google Patents
A7The iron-based flow battery of model and its positive and negative anodes electrolyte and preparation method Download PDFInfo
- Publication number
- CN110010945A CN110010945A CN201910240702.XA CN201910240702A CN110010945A CN 110010945 A CN110010945 A CN 110010945A CN 201910240702 A CN201910240702 A CN 201910240702A CN 110010945 A CN110010945 A CN 110010945A
- Authority
- CN
- China
- Prior art keywords
- electrolyte
- iron
- flow battery
- positive
- model
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/18—Regenerative fuel cells, e.g. redox flow batteries or secondary fuel cells
- H01M8/184—Regeneration by electrochemical means
- H01M8/188—Regeneration by electrochemical means by recharging of redox couples containing fluids; Redox flow type batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0025—Organic electrolyte
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
The present invention relates to a kind of A7The iron-based flow battery of model and its positive and negative anodes electrolyte and preparation method, belong to electrochemical field, can be widely applied to the extensive energy storage of new energy.A of the invention7The active material of electrolyte liquid described in the iron-based flow battery of model is K3Fe(CN)6, constant pH maintains with hexa-hydrochloric acid；Anode electrolyte active material is Fe (3,4 '-dmbpy)3Cl2, constant pH maintains with amion acetic acid-hydrochloric acid；Positive and negative anodes solid-state energy storage material is Prussian blue Fe4[Fe(CN)6]3；Pass through intermediate K3Fe(CN)6With Fe (3,4 '-dmbpy)3Cl2Redox realize the electronic/electrical lotus in positive and negative anodes and solid energy storage material Fe4[Fe(CN)6]3Between transmit.Its energy density is up to the 2 times or more of existing all-vanadium flow battery, but the cost of active material only has its 1/10th.
Description
Technical field
The present invention relates to a kind of A7The iron-based flow battery of model and its positive and negative anodes electrolyte and preparation method, belong to electrochemistry
Field can be widely applied to the extensive energy storage of new energy.
Background technique
Widely replacing fossil energy using renewable energy such as solar energy, wind energies is after avoiding greenhouse effects catastrophic
One of optimal strategy of fruit.However the intermittence of solar energy and wind energy brings huge challenge to the safety management of power grid.Intelligence
A kind of reliable energy storage device of the development need of power grid carrys out the input and output of regulation power, to reach highest energy utilization effect
Rate.In various extensive energy storage programs, draw water energy storage and compressed-air energy storage have a best cost-effectiveness, but two
Person needs special geography and geologic requirements.In addition to this two, flow battery with its fast response time, can be quickly charged and discharged and
The advantages that security performance is high becomes one of most potential large-scale energy storage device.The active material of flow battery is dissolved in
In electrolyte；Under the promotion of pump, electrolyte is circulated between fluid reservoir and electrode chamber.This design feature keeps liquid stream electric
The power in pond and capacity are mutually indepedent, can improve the flexibility of system design significantly, be conducive to meet the different need of client
It asks.But the low energy densities of flow battery and inexpensive benefit are at the two big factors for hindering the application of its widespread commercialization.
Summary of the invention
The object of the present invention is to provide a kind of A7The iron-based flow battery of model and its positive and negative anodes electrolyte and preparation method, gram
The shortcoming of existing flow battery is taken, realizes flow battery high-energy density and cost effective target.
A of the present invention7The iron-based flow battery of model is improved on the basis of existing flow battery, mainly by cathode,
Electrolyte liquid, cathode solid energy storage material, anode, anode electrolyte, positive solid energy storage material and amberplex (every
Film) composition the pile that is unified into of multiple batteries monomer, cathode solid energy storage material is placed in cathode pot, carries out negative electricity by pumping
The conveying of liquid is solved, positive solid energy storage material is placed in positive tank, carries out the conveying of anode electrolyte by pumping.It is negative in pile
Pole room is linked to be circuit, electrolyte liquid recycle stream in the circuit with cathode pot, electrolyte liquid delivery pump with electrolysis fluid catheter
It is dynamic.Cathode chamber in pile is linked to be circuit by electrolysis fluid catheter and positive tank, anode electrolyte delivery pump, and anode electrolyte exists
It is circulated in the circuit.
A of the invention7The iron-based flow battery key of model is that the active material of the electrolyte liquid is K3Fe(CN)6,
Its constant pH is maintained with hexa-hydrochloric acid, and corresponding cathode solid-state energy storage material is Prussian blue Fe4
[Fe(CN)6]3；Anode electrolyte active material is Fe (3,4 '-dmbpy)3Cl2, constant pH is with amion acetic acid-hydrochloric acid
It maintains, and corresponding positive solid-state energy storage material is Prussian blue Fe4[Fe(CN)6]3；Pass through intermediate K3Fe(CN)6With
Fe(3,4’-dmbpy)3Cl2Redox realize the electronic/electrical lotus in positive and negative electrode and solid energy storage material Fe4[Fe
(CN)6]3Between transmitting.
The pH of electrolyte liquid is 5.0-7.0；The pH of anode electrolyte is 1.5-2.5.
The composition of the electrolyte liquid are as follows: 0.02-0.8M K3Fe(CN)6+0.02-1.6M C6H12N4/HCl+0.02-
1.6M NaCl。
The preparation method of the electrolyte liquid, includes the following steps, following number indicates the amount of substance:
Step A weighs 1 part of K3Fe(CN)6, it is soluble in water, it is sufficiently stirred；
Step B, weighs 1-2 parts of hexas and 1-2 parts of HCl are added in step A solution, is sufficiently stirred；
Step C weighs 1-2 parts of NaCl and is added in step B solution, is sufficiently stirred；
It is eventually adding water, by each substance constant volume to concentration range: 0.02-0.8M K3Fe(CN)6+0.02-1.6M
C6H12N4/HCl+0.02-1.6M NaCl。
The composition of the anode electrolyte are as follows: 0.02-0.8M Fe (3,4 '-dmbpy)3Cl2+0.0002-0.08M
C2H5NO2/HCl+0.02-1.6M NaCl.Wherein, 3,4 '-dmbpy are 3,4 '-dimethyl -2, and 2 '-bipyridyls, structural formula is such as
Under:
The preparation method of the anode electrolyte, includes the following steps, following number indicates the amount of substance:
Step A weighs 1 part of FeCl2With 3 part 3,4 '-dimethyl -2,2 '-bipyridyls are soluble in water, are sufficiently stirred；
Step B weighs 0.01-0.1 parts of C2H5NO2/ HCl is added in step A solution, is sufficiently stirred；
Step C weighs 1-2 parts of NaCl and is added in step B solution, is sufficiently stirred；
It is eventually adding water, by each substance constant volume to concentration range: 0.02-0.8M Fe (3,4 '-dmbpy)3Cl2+0.0002-
0.08M C2H5NO2/HCl+0.02-1.6M NaCl。
A of the invention7The iron-based flow battery of model is with K3Fe(CN)6As negative electrode active material, Fe (3,4 '-dmbpy)3Cl2Prussian blue to be used as positive and negative anodes solid-state ergastic substances for positive active material, electrode reaction is as follows:
Negative reaction:
Anode reaction:
Its working principle is that using intermediate electricity to [Fe (CN)6]3-/[Fe(CN)6]4-[Fe (3,4 '-dmbpy)3]3+/
[Fe(3,4’-dmbpy)3]2+Realize transmitting of the electronic/electrical lotus between electrode and solid-state energy storage material are Prussian blue, thus
Realize the storage and release of energy.When charge and discharge, positive and negative electrode electrolyte circulates in respective circuit, but solid energy storage
Material is not with electrolyte flow.When charging, K3Fe(CN)6It is reduced into K4Fe(CN)6, K4Fe(CN)6Prussia is given electron transmission
It is blue；Fe(3,4'-dmbpy)3Cl2It is oxidized to Fe (3,4 '-dmbpy)3Cl3, Fe (3,4 '-dmbpy)3Cl3Charge transfer to general
Shandong scholar is blue；When electric discharge, K4Fe(CN)6It is oxidized to K3Fe(CN)6, K3Fe(CN)6Fe is given charge transfer2[Fe(CN)6]；Fe(3,
4’-dmbpy)3Cl3It is reduced into Fe (3,4 '-dmbpy)3Cl2, Fe (3,4 '-dmbpy)3Cl2Fe [Fe is given electron transmission
(CN)6].The positive and negative electrode standard electric potential difference of battery cell is 0.65V.
A of the invention7The iron-based flow battery of model, due to selecting iron compound to store up as electrolyte active material and solid-state
Energy material, thus may be implemented cost effective.Meanwhile it being advantageously implemented using solid iron compound come stored electrons and charge
High-energy density.A of the invention7The iron-based flow battery energy density of model can reach existing all-vanadium flow battery energy density
2 times or more, but the cost of active material only has its 1/10th.
Detailed description of the invention
Fig. 1 is A of the invention7The structural schematic diagram of the iron-based flow battery monomer of model.
Specific embodiment
(arrow is electrolyte flow direction in figure) as shown in Figure 1, A of the invention7The iron-based flow battery of model mainly by cathode,
Electrolyte liquid, cathode solid energy storage material, anode, anode electrolyte, positive solid energy storage material and amberplex (every
Film) composition the pile that is unified into of multiple batteries monomer, cathode solid energy storage material is placed in cathode pot, carries out negative electricity by pumping
The conveying of liquid is solved, positive solid energy storage material is placed in positive tank, carries out the conveying of anode electrolyte by pumping.It is negative in pile
Pole room is linked to be circuit, electrolyte liquid recycle stream in the circuit with cathode pot, electrolyte liquid delivery pump with electrolysis fluid catheter
It is dynamic.Cathode chamber in pile is linked to be circuit by electrolysis fluid catheter and positive tank, anode electrolyte delivery pump, and anode electrolyte exists
It is circulated in the circuit.The electrolyte liquid is 0.02-0.8M K3Fe(CN)6+0.02-1.6M C6H12N4/HCl+
The aqueous solution of 0.02-1.6M NaCl, anode electrolyte are 0.02-0.8M Fe (3,4 '-dmbpy)3Cl2+0.0002-0.08M
C2H5NO2The aqueous solution of/HCl+0.02-1.6M NaCl.The cathode solid energy storage material and positive solid energy storage material are
It is Prussian blue.
The electrolyte liquid selects K3Fe(CN)6It is dissolved into water, and C is added6H12N4/ HCl and NaCl are obtained.
The anode electrolyte selects presoma FeCl2It is dissolved in 3,4 '-dimethyl -2 of presoma, in 2 '-bipyridyls,
And C is added2H5NO2/ HCl and NaCl are obtained.
The pH of electrolyte liquid is 5.0-7.0；The pH of anode electrolyte is 1.5-2.5.
The inert materials such as carbon felt, graphite felt, graphite plate, graphite paper or carbon cloth can be selected in the positive and negative electrode of battery cell.Ion
Battery cell is divided into cathode chamber, anode chamber and the sodium chloride electrolysis of centre liquid chamber three parts, sodium chloride electrolyte by exchange membrane
Concentration is 0.5-1.5M, and anode is in cathode chamber, and cathode is in anode chamber.The amberplex selects cation-exchange membrane
And anion-exchange membrane.Cation-exchange membrane is in cathode side, and anion-exchange membrane is in positive side.
A of the invention7In charge and discharge process, positive and negative anodes electrolyte is electrolysed by positive and negative anodes the iron-based flow battery of model respectively
Liquid delivery pump is constantly pumped into battery cell, and the flowing of electrolyte accelerates the substance transmittance process in electrode interface, is conducive to
Reduce the electrochemistry and concentration polarization in electrode reaction.The rated power of battery depends on the size of pile, and amount of capacity depends on
In electrolyte and solid energy storage material.
A of the invention7When the iron-based flow battery charge and discharge of model, the negative, positive pole electrolyte in negative, positive pole tank is in electrolyte
Under the promotion of delivery pump, is entered in negative, positive pole room by electrolysis fluid catheter and carry out electrode reaction, then flow back to negative, positive pole tank again
In, electronic/electrical lotus is passed to negative, positive pole solid energy storage material.
The content of each substance is molar concentration in embodiment.
Embodiment 1: 100mL 0.02M K is prepared3Fe(CN)6+0.02M C6H12N4/ HCl+0.02M NaCl electrolyte
0.002mol K is weighed first3Fe(CN)6, it is placed in 250mL beaker, 50mL water is added, is sufficiently stirred；Then according to
Secondary addition 0.002mol C6H12N4, 0.002mol/HCl is sufficiently stirred；0.002molNaCl is sequentially added, solution is added water to
For 100mL, the electrolyte to get required preparation is sufficiently stirred.
Embodiment 2: 100mL 0.4M K is prepared3Fe(CN)6+0.8M C6H12N4/ HCl+0.8M NaCl electrolyte
0.04mol K is weighed first3Fe(CN)6, it is placed in 250mL beaker, 50mL water is added, is sufficiently stirred；Then successively
0.08mol C is added6H12N4, 0.08mol/HCl is sufficiently stirred；0.08molNaCl is sequentially added, adding water to solution is
The electrolyte to get required preparation is sufficiently stirred in 100mL.
Embodiment 3: 100mL 0.8M K is prepared3Fe(CN)6+1.6M C6H12N4/ HCl+1.6M NaCl electrolyte
0.08mol K is weighed first3Fe(CN)6, it is placed in 250mL beaker, 50mL water is added, is sufficiently stirred；Then successively
0.16mol C is added6H12N4, 0.16mol/HCl is sufficiently stirred；0.16molNaCl is sequentially added, adding water to solution is
The electrolyte to get required preparation is sufficiently stirred in 100mL.
Embodiment 4: it prepares 100mL 0.02M Fe (3,4 '-dmbpy)3Cl2+0.0002M C2H5NO2/HCl+0.02M
NaCl electrolyte
0.002mol FeCl is weighed first2It with 0.006mol 3,4 '-dmbpy, is placed in 250mL beaker, 50mL is added
Water is sufficiently stirred；Then 0.00002mol C is sequentially added2H5NO2, 0.00002molHCl, 0.002mol NaCl are sufficiently stirred
It mixes；Adding water to solution is 100mL, up to the electrolyte of required preparation.
Embodiment 5: it prepares 100mL 0.4M Fe (3,4 '-dmbpy)3Cl2+0.04M C2H5NO2/ HCl+0.8M NaCl electricity
Solve liquid
0.04mol FeCl is weighed first2It with 0.12mol 3,4 '-dmbpy, is placed in 250mL beaker, 50mL water is added,
It is sufficiently stirred；Then 0.004mol C is sequentially added2H5NO2, 0.004molHCl, 0.08mol NaCl are sufficiently stirred；It adds water to
Solution is 100mL, up to the electrolyte of required preparation.
Embodiment 6: it prepares 100mL 0.8M Fe (3,4 '-dmbpy)3Cl2+0.08M C2H5NO2/ HCl+1.6M NaCl electricity
Solve liquid
0.08mol FeCl is weighed first2It with 0.24mol 3,4 '-dmbpy, is placed in 250mL beaker, 50mL water is added,
It is sufficiently stirred；Then 0.008mol C is sequentially added2H5NO2, 0.008molHCl, 0.16mol NaCl are sufficiently stirred；It adds water to
Solution is 100mL, up to the electrolyte of required preparation.
Embodiment 7:
A of the invention7The anion-exchange membrane and cation-exchange membrane of the iron-based flow battery of model are surrounded with battery case
One sodium chloride electrolysis liquid chamber, and the positive and negative pole room of battery is separated；Positive and negative electrode is done with carbon felt, the apparent area of the two is
10cm2.Electrolyte liquid is 10ml 0.02M K3Fe(CN)6+0.02M C6H12N4/ HCl+0.02M NaCl solution, cathode pot
In it is Prussian blue be 2.15 grams；Anode electrolyte is 10ml 0.02M Fe (3,4 '-dmbpy)3Cl2+0.0002M C2H5NO2/
HCl+0.02M NaCl solution, Prussian blue in positive tank are 2.86 grams；Charging and discharging currents are 10mA, and electrolyte flow rate is
The energy density of 10mL/min, battery are 106Wh/L, are 2.12 times of all-vanadium flow battery energy density (50Wh/L).
Embodiment 8:
A of the invention7The anion-exchange membrane and cation-exchange membrane of the iron-based flow battery of model are surrounded with battery case
One sodium chloride electrolysis liquid chamber, and the positive and negative pole room of battery is separated；Positive and negative electrode is done with carbon felt, the apparent area of the two is
10cm2.Electrolyte liquid is 10ml 0.4M K3Fe(CN)6+0.8M C6H12N4/ HCl+0.8M NaCl solution, in cathode pot
Prussian blue is 2.15 grams；Anode electrolyte is 10ml 0.4M Fe (3,4 '-dmbpy)3Cl2+0.04M C2H5NO2/HCl+
0.8M NaCl solution, Prussian blue in positive tank are 2.86 grams；Charging and discharging currents are 10mA, electrolyte flow rate 10mL/
The energy density of min, battery are 113Wh/L, are 2.26 times of all-vanadium flow battery energy density (50Wh/L).
Embodiment 9:
A of the invention7The anion-exchange membrane and cation-exchange membrane of the iron-based flow battery of model are surrounded with battery case
One sodium chloride electrolysis liquid chamber, and the positive and negative pole room of battery is separated；Positive and negative electrode is done with carbon felt, the apparent area of the two is
10cm2.Electrolyte liquid is 10ml 00.8M K3Fe(CN)6+1.6M C6H12N4/ HCl+1.6M NaCl solution, in cathode pot
It is Prussian blue be 2.15 grams；Anode electrolyte is 10ml 0.8M Fe (3,4 '-dmbpy)3Cl2+0.08M C2H5NO2/HCl+
1.6M NaCl solution, Prussian blue in positive tank are 2.86 grams；Charging and discharging currents are 10mA, electrolyte flow rate 10mL/
The energy density of min, battery are 109Wh/L, are 2.18 times of all-vanadium flow battery energy density (50Wh/L).
Claims (10)
1. a kind of A7The iron-based flow battery of model, including amberplex, positive and negative anodes, positive and negative anodes electrolyte, it is characterized in that: described
The active material of electrolyte liquid is K3Fe(CN)6, constant pH is maintained with hexa-hydrochloric acid, and is corresponding to it
Cathode solid-state energy storage material be Prussian blue Fe4[Fe(CN)6]3；Anode electrolyte active material is Fe (3,4 '-dmbpy)3Cl2, constant pH is maintained with amion acetic acid-hydrochloric acid, and corresponding positive solid-state energy storage material is Prussian blue Fe4
[Fe(CN)6]3；Pass through intermediate K3Fe(CN)6With Fe (3,4 '-dmbpy)3Cl2Redox realize the electronic/electrical lotus just
Negative electrode and solid energy storage material Fe4[Fe(CN)6]3Between transmitting.
2. a kind of A according to claim 17The iron-based flow battery of model, characterized in that the composition of the electrolyte liquid
Are as follows: 0.02-0.8M K3Fe(CN)6+0.02-1.6M C6H12N4/HCl+0.02-1.6M NaCl。
3. a kind of A according to claim 17The iron-based flow battery of model, characterized in that the composition of the anode electrolyte
Are as follows: 0.02-0.8M Fe (3,4 '-dmbpy)3Cl2+0.0002-0.08M C2H5NO2/HCl+0.02-1.6M NaCl；Wherein, 3,
4 '-dmbpy are 3,4 '-dimethyl -2, and 2 '-bipyridyls, structural formula is as follows:
4. a kind of A according to claim 17The iron-based flow battery of model, it is characterized in that: electrode reaction is as follows,
Negative reaction:
Anode reaction:
5. a kind of A according to claim 17The iron-based flow battery of model, characterized in that the pH of electrolyte liquid is 5.0-
7.0；The pH of anode electrolyte is 1.5-2.5.
6. a kind of A according to claim 17The iron-based flow battery of model, it is characterized in that: the positive and negative electrode of battery cell is selected
Carbon felt, graphite felt, graphite plate, graphite paper or carbon cloth inert material；Battery cell is divided into cathode chamber, cathode by amberplex
Room and intermediate sodium chloride electrolysis liquid chamber three parts, sodium chloride electrolyte concentration are 0.5-1.5M, and anode is born in cathode chamber
Pole is in anode chamber；The amberplex selects cation-exchange membrane and anion-exchange membrane, and cation-exchange membrane is in cathode
Side, anion-exchange membrane is in positive side.
7. a kind of A according to claim 17The iron-based flow battery of model, it is characterized in that: the positive and negative electrode standard of battery cell
Potential difference is 0.65V.
8. a kind of A7The iron-based flow battery positive and negative anodes electrolyte of model, including anode electrolyte and electrolyte liquid, characterized in that
The composition of the electrolyte liquid are as follows: 0.02-0.8M K3Fe(CN)6+0.02-1.6M C6H12N4/HCl+0.02-1.6M
NaCl；
The composition of the anode electrolyte are as follows: 0.02-0.8M Fe (3,4 '-dmbpy)3Cl2+0.0002-0.08M C2H5NO2/
HCl+0.02-1.6M NaCl；Wherein, 3,4 '-dmbpy are 3,4 '-dimethyl -2, and 2 '-bipyridyls, structural formula is as follows:
9. preparing a kind of A according to any one of claims 87The method of the iron-based flow battery electrolyte liquid of model, it is characterized in that: including
Following steps, following number indicate the amount of substance:
Step A weighs 1 part of K3Fe(CN)6, it is soluble in water, it is sufficiently stirred；
Step B, weighs 1-2 parts of hexas and 1-2 parts of HCl are added in step A solution, is sufficiently stirred；
Step C weighs 1-2 parts of NaCl and is added in step B solution, is sufficiently stirred；
It is eventually adding water, by each substance constant volume to concentration range: 0.02-0.8M K3Fe(CN)6+0.02-1.6M C6H12N4/HCl
+0.02-1.6M NaCl。
10. preparing a kind of A according to any one of claims 87The method of the iron-based flow battery anode electrolyte of model, it is characterized in that: including
Following steps, following number indicate the amount of substance:
Step A weighs 1 part of FeCl2With 3 part 3,4 '-dimethyl -2,2 '-bipyridyls are soluble in water, are sufficiently stirred；
Step B weighs 0.01-0.1 parts of C2H5NO2/ HCl is added in step A solution, is sufficiently stirred；
Step C weighs 1-2 parts of NaCl and is added in step B solution, is sufficiently stirred；
It is eventually adding water, by each substance constant volume to concentration range: 0.02-0.8M Fe (3,4 '-dmbpy)3Cl2+0.0002-
0.08M C2H5NO2/HCl+0.02-1.6M NaCl。
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910240702.XA CN110010945A (en) | 2019-03-28 | 2019-03-28 | A7The iron-based flow battery of model and its positive and negative anodes electrolyte and preparation method |
| CN201910709829.1A CN110416586B (en) | 2019-03-28 | 2019-08-02 | Iron-based flow battery, positive and negative electrolyte thereof and preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910240702.XA CN110010945A (en) | 2019-03-28 | 2019-03-28 | A7The iron-based flow battery of model and its positive and negative anodes electrolyte and preparation method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110010945A true CN110010945A (en) | 2019-07-12 |
Family
ID=67168504
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910240702.XA Pending CN110010945A (en) | 2019-03-28 | 2019-03-28 | A7The iron-based flow battery of model and its positive and negative anodes electrolyte and preparation method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110010945A (en) |
-
2019
- 2019-03-28 CN CN201910240702.XA patent/CN110010945A/en active Pending
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN110416586B (en) | Iron-based flow battery, positive and negative electrolyte thereof and preparation method | |
| CN105742656B (en) | A kind of zinc iodine solution galvanic battery | |
| CN109509901B (en) | Alkaline zinc-iron flow battery | |
| CN112467179B (en) | Alkaline all-iron flow battery | |
| CN113764714A (en) | Electrolyte of water system flow battery, all-iron water system flow battery and application | |
| CN103401045A (en) | Flow-battery energy storage system with photoelectric effect | |
| CN109904506A (en) | A3The iron-based flow battery of model and its positive and negative anodes electrolyte and preparation method | |
| CN110010947A (en) | A1The iron-based flow battery of model and its positive and negative anodes electrolyte and preparation method | |
| CN105810986A (en) | Zinc-iron based ionic liquid redox flow battery | |
| CN103456977B (en) | Improve the method for operation efficiency of all-vanadium redox flow battery | |
| JP6247778B2 (en) | Quinone polyhalide flow battery | |
| CN109935875A (en) | A2The iron-based flow battery of model and its positive and negative anodes electrolyte and preparation method | |
| CN110010949A (en) | Positive and negative anodes electrolyte and preparation method thereof and in A11It is applied in model flow battery | |
| CN109950599A (en) | Positive and negative anodes electrolyte and preparation method thereof and in A8It is applied in model flow battery | |
| CN109860673A (en) | A16Model high energy density cells and its positive and negative anodes electrolyte and preparation method | |
| CN110010944A (en) | Positive and negative anodes electrolyte and preparation method thereof and in A13It is applied in model flow battery | |
| CN110010943A (en) | Positive and negative anodes electrolyte and preparation method thereof and in A14It is applied in model flow battery | |
| CN110010945A (en) | A7The iron-based flow battery of model and its positive and negative anodes electrolyte and preparation method | |
| CN110010950A (en) | A6The iron-based flow battery of model and its positive and negative anodes electrolyte and preparation method | |
| CN109888356A (en) | A5The iron-based flow battery of model and its positive and negative anodes electrolyte and preparation method | |
| CN110010946A (en) | A4The iron-based flow battery of model and its positive and negative anodes electrolyte and preparation method | |
| CN109888355A (en) | Positive and negative anodes electrolyte and preparation method thereof and in A9It is applied in model flow battery | |
| CN109888339A (en) | Positive and negative anodes electrolyte and preparation method thereof and in A10It is applied in model flow battery | |
| CN109950600A (en) | Positive and negative anodes electrolyte and preparation method thereof and in A12It is applied in model flow battery | |
| CN109904508A (en) | A18Model high energy density cells and its positive and negative anodes electrolyte and preparation method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20190712 |