CN110003988A - A kind of aerosol and preparation method thereof that removing adhesive sticker residue glue and application method - Google Patents
A kind of aerosol and preparation method thereof that removing adhesive sticker residue glue and application method Download PDFInfo
- Publication number
- CN110003988A CN110003988A CN201910367270.9A CN201910367270A CN110003988A CN 110003988 A CN110003988 A CN 110003988A CN 201910367270 A CN201910367270 A CN 201910367270A CN 110003988 A CN110003988 A CN 110003988A
- Authority
- CN
- China
- Prior art keywords
- parts
- aerosol
- adhesive sticker
- residue glue
- added
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003292 glue Substances 0.000 title claims abstract description 72
- 239000000443 aerosol Substances 0.000 title claims abstract description 57
- 239000000853 adhesive Substances 0.000 title claims abstract description 50
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 50
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- 238000001856 aerosol method Methods 0.000 title claims description 4
- 238000000034 method Methods 0.000 title abstract description 18
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000003380 propellant Substances 0.000 claims abstract description 14
- -1 sodium alkyl benzene Chemical class 0.000 claims abstract description 12
- 229940077388 benzenesulfonate Drugs 0.000 claims abstract description 10
- 239000011734 sodium Substances 0.000 claims abstract description 10
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 10
- 235000019441 ethanol Nutrition 0.000 claims abstract description 8
- 238000002156 mixing Methods 0.000 claims description 36
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 28
- 239000000243 solution Substances 0.000 claims description 27
- 229910052757 nitrogen Inorganic materials 0.000 claims description 25
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 claims description 23
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 20
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
- 238000010438 heat treatment Methods 0.000 claims description 15
- 229910000271 hectorite Inorganic materials 0.000 claims description 15
- 239000000843 powder Substances 0.000 claims description 15
- 230000000694 effects Effects 0.000 claims description 13
- 239000008399 tap water Substances 0.000 claims description 13
- 235000020679 tap water Nutrition 0.000 claims description 13
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 12
- 239000002253 acid Substances 0.000 claims description 12
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 12
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 12
- 239000007921 spray Substances 0.000 claims description 12
- 239000000230 xanthan gum Substances 0.000 claims description 12
- 229920001285 xanthan gum Polymers 0.000 claims description 12
- 229940082509 xanthan gum Drugs 0.000 claims description 12
- 235000010493 xanthan gum Nutrition 0.000 claims description 12
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 11
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 11
- 239000012266 salt solution Substances 0.000 claims description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 10
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 10
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 10
- 238000001816 cooling Methods 0.000 claims description 10
- 239000012153 distilled water Substances 0.000 claims description 10
- 238000007710 freezing Methods 0.000 claims description 10
- 230000008014 freezing Effects 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 8
- RWRIWBAIICGTTQ-UHFFFAOYSA-N difluoromethane Chemical compound FCF RWRIWBAIICGTTQ-UHFFFAOYSA-N 0.000 claims description 8
- 239000006185 dispersion Substances 0.000 claims description 8
- 238000004321 preservation Methods 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 238000003837 high-temperature calcination Methods 0.000 claims description 7
- 230000010355 oscillation Effects 0.000 claims description 7
- 230000002085 persistent effect Effects 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 6
- 239000001361 adipic acid Substances 0.000 claims description 6
- 235000011037 adipic acid Nutrition 0.000 claims description 6
- 229910017604 nitric acid Inorganic materials 0.000 claims description 6
- 229910000027 potassium carbonate Inorganic materials 0.000 claims description 6
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 6
- 239000004575 stone Substances 0.000 claims description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 6
- BOUGCJDAQLKBQH-UHFFFAOYSA-N 1-chloro-1,2,2,2-tetrafluoroethane Chemical class FC(Cl)C(F)(F)F BOUGCJDAQLKBQH-UHFFFAOYSA-N 0.000 claims description 5
- 239000007864 aqueous solution Substances 0.000 claims description 5
- 238000001354 calcination Methods 0.000 claims description 5
- 239000008367 deionised water Substances 0.000 claims description 5
- 229910021641 deionized water Inorganic materials 0.000 claims description 5
- 239000005457 ice water Substances 0.000 claims description 5
- 238000010907 mechanical stirring Methods 0.000 claims description 5
- ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 claims description 5
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 5
- 239000003643 water by type Substances 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 4
- 238000000227 grinding Methods 0.000 claims description 3
- 230000008595 infiltration Effects 0.000 claims description 3
- 238000001764 infiltration Methods 0.000 claims description 3
- 238000010583 slow cooling Methods 0.000 claims description 3
- 239000000344 soap Substances 0.000 claims description 3
- 150000002641 lithium Chemical class 0.000 claims description 2
- 238000010257 thawing Methods 0.000 claims description 2
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract description 9
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract description 9
- 239000000463 material Substances 0.000 abstract description 8
- 230000006378 damage Effects 0.000 abstract description 4
- 239000003960 organic solvent Substances 0.000 abstract description 4
- 229920003023 plastic Polymers 0.000 abstract description 4
- 239000004033 plastic Substances 0.000 abstract description 4
- 230000036541 health Effects 0.000 abstract description 3
- 229910052751 metal Inorganic materials 0.000 abstract description 3
- 239000002184 metal Substances 0.000 abstract description 3
- 210000001328 optic nerve Anatomy 0.000 abstract description 3
- 210000002345 respiratory system Anatomy 0.000 abstract description 3
- 208000027418 Wounds and injury Diseases 0.000 abstract description 2
- 239000011521 glass Substances 0.000 abstract description 2
- 210000003491 skin Anatomy 0.000 abstract description 2
- 208000014674 injury Diseases 0.000 abstract 1
- 239000002994 raw material Substances 0.000 abstract 1
- 239000000047 product Substances 0.000 description 12
- 239000002245 particle Substances 0.000 description 10
- 229910002804 graphite Inorganic materials 0.000 description 7
- 239000010439 graphite Substances 0.000 description 7
- 230000009471 action Effects 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- 238000004026 adhesive bonding Methods 0.000 description 4
- 229910021645 metal ion Inorganic materials 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 230000008961 swelling Effects 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- 229920002125 Sokalan® Polymers 0.000 description 3
- 150000001335 aliphatic alkanes Chemical class 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 229910052744 lithium Inorganic materials 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- 229910052749 magnesium Inorganic materials 0.000 description 3
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 3
- 239000004584 polyacrylic acid Substances 0.000 description 3
- 239000006228 supernatant Substances 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 229910000275 saponite Inorganic materials 0.000 description 2
- MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000001293 FEMA 3089 Substances 0.000 description 1
- 240000002853 Nelumbo nucifera Species 0.000 description 1
- 235000006508 Nelumbo nucifera Nutrition 0.000 description 1
- 235000006510 Nelumbo pentapetala Nutrition 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 206010052428 Wound Diseases 0.000 description 1
- 241000276425 Xiphophorus maculatus Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 125000002843 carboxylic acid group Chemical group 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 230000010339 dilation Effects 0.000 description 1
- 238000004851 dishwashing Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000010559 graft polymerization reaction Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- PQIOSYKVBBWRRI-UHFFFAOYSA-N methylphosphonyl difluoride Chemical group CP(F)(F)=O PQIOSYKVBBWRRI-UHFFFAOYSA-N 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 230000009972 noncorrosive effect Effects 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000010148 water-pollination Effects 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0043—For use with aerosol devices
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/042—Acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/24—Organic compounds containing halogen
-
- C11D2111/10—
-
- C11D2111/44—
Abstract
The invention discloses a kind of aerosols for removing adhesive sticker residue glue and preparation method thereof and application method, the aerosol to be prepared by raw material once: 5-10 parts of expanded granular, 3-7 parts of penetrant, 80-150 parts of propellant, 2-5 parts of sodium alkyl benzene sulfonate.Aerosol prepared by the present invention can quickly and effectively remove the adhesive sticker removing residual glue trace on the surfaces such as plastics, metal, plank, glass, and without organic solvents such as methanol, ethyl alcohol, benzene homologues, it is nonirritant to human skin, optic nerve and respiratory system, secondary injury will not be caused to object material itself, be widely portable to family, office, in automobile etc. in the sealed environment that health requirements are higher and need often to close the doors and windows.
Description
Technical field
The invention belongs to aerosol production technical fields, and in particular to a kind of aerosol and its system for removing adhesive sticker residue glue
Preparation Method and application method.
Background technique
Adhesive sticker, double-sided adhesive have many advantages, such as that easy to use, sticking effect is good, are widely used in packaging, logistics, doctor
In the industries such as medicine, electric appliance and daily life, especially adhesive sticker advertisement, on utility poles, and on bus stop board, grade separation
On bridge railings, metope, ground, the places such as escalator are seen everywhere, these extremely difficult removings of advertisement removing residual glue trace seriously affect
Environmental sanitation also brings many inconvenience to people's lives.
Currently, people are used to remove there are mainly two types of the methods of adhesive sticker, one is using steel wire after being impregnated with dish washing liquid water
Ball or blade hang adhesive sticker etc. and paste object, this method not only low efficiency, but also are also easy to make the surface of object to be treated
At damage；The second is using the organic solvents such as sprinkling methanol, ethyl alcohol, benzene homologues, acetone, turpentine oil on object and containing having
The adhesive sticker aerosol of solvent, this aerosol solvability is strong, can effectively remove the remaining glue stain of body surface, but
It is that these organic solvents and the aerosol containing organic solvent can generate problems, such as: 1, it evaporate into air immediately, quilt
People can stimulate respiratory tract, or even stimulation optic nerve after absorbing, healthy hidden danger then be caused, especially in family, office, automobile
It is interior to wait higher to health requirements and be frequently necessary in the enclosed environment closed the doors and windows；2, directly contact can damage human skin；
3, while removing body surface glue stain can also dissolution be generated to the surface of object, it especially can be to resin, plastics material
The object of matter is dissolved, and the service life of object is reduced；4, it is easy to pollute the environment.
These problems cause inconvenience to people's lives, therefore how to research and develop a kind of non-corrosive, environment friend
Alright, non-stimulated to human body, damage will not be caused to object itself, the high-efficient environment-friendly type aerosol of removal glue stain seems
It is particularly important.
Summary of the invention
The purpose of the present invention is be directed to existing problem, provide it is a kind of remove adhesive sticker residue glue aerosol and its preparation
Method and application method.
The present invention is achieved by the following technical solutions:
A kind of aerosol for removing adhesive sticker residue glue, component by weight is as follows: 5-10 parts of expanded granular, 3-7 parts of penetrant,
80-150 parts of propellant, 2-5 parts of sodium alkyl benzene sulfonate.
Preferably, a kind of aerosol for removing adhesive sticker residue glue, wherein the propellant is F-11, difluoro first
One of alkane, three chloro-tetrafluoroethanes or combination.
Preferably, it is a kind of remove adhesive sticker residue glue aerosol, wherein the expanded granular the preparation method is as follows:
1) taking concentration is 10-20 parts of solution of potassium carbonate of 0.1-0.3mol/L, and concentration is the sodium carbonate liquor of 0.1-0.3mol/L
5-15 parts, mixing salt solution is made after mixing, then takes 10-15 parts of hectorite to be added in mixing salt solution, is in revolving speed
Mechanical stirring 3-5h under 800-1000r/min is subsequently placed at -10--15 DEG C natural thaw 20- after cryogenic freezing 10-20h
25h is placed on for repeated freezing defrosting 4-5 times in centrifuge and is centrifuged 10-15min with the rate of 3500-4500r/min, incline on
Clear liquid, which is placed in 70-80 DEG C of baking oven, to be dried to constant weight, spare；
2) it will be added in Muffle furnace by pretreated hectorite, 150-200 is heated to the heating rate of 10-15 DEG C/min
DEG C, keep the temperature 10-30min after be heated to 400-500 DEG C, high-temperature calcination 3-4h again with the heating rate of 20-30 DEG C/min, then with
The cooling rate slow cooling of 3-5 DEG C/min repeats above-mentioned heating calcining cooling 3-5 times, can be prepared by modified lithium soap to room temperature
Stone；
3) 13-17 parts of xanthan gum are taken, is added in 30-50 parts of deionized waters, xanthan gum solution is made in stirring and dissolving, then heats
To 50-60 DEG C, it is then added ammonium persulfate 0.1-0.2 parts, the sodium hydroxide solution of 3-5mol/L is added after heat preservation 5-10min
4-6 parts, N, N,0.2-0.3 parts of methylene-bisacrylamide, 5-8 parts of acrylic acid and modified hectorite, are heated to after mixing
70-80 DEG C, isothermal reaction 3-5h, to which after reaction, place the product in dried in 50-60 DEG C of baking oven to constant weight, then through super
Crushing of Ultrafine can be prepared by the expanded granular that average grain diameter is 10-20um.
Preferably, it is a kind of remove adhesive sticker residue glue aerosol, wherein the penetrant the preparation method is as follows:
1) 15-20 parts of the concentrated sulfuric acid of 95-98% are taken, 3-5 parts of the concentrated nitric acid of 65-70% is made mixed acid solution, then takes after mixing
It 5-8 parts of nano graphite powder, is added in mixed acid solution, is heated to 60-70 DEG C, impregnate 1-2h, then rinsed with deionized water
20-30min is placed in 60-70 DEG C of baking oven and dries to constant weight, is then placed in 800-1000 DEG C of Muffle furnace again and calcines 3-7h, makes
Obtain expanded nano-graphites powder；
2) expanded nano-graphites powder is added in distilled water, the expansion nano stone that concentration is 0.5-0.8% is made after mixing
Then ink powder aqueous solution takes 3-5 parts of adipic acid, the vibrating dispersion 1-1.5h under 400-600W ultrasonic wave adds acrylic acid 4-7
Part, continue vibrating dispersion 1-1.5h, is then added ammonium persulfate 0.1-0.2 parts, 5-10 parts of the hydrochloric acid of concentration 10-15%, in revolving speed
To be stirred to react 3-4h in the ice-water bath of 50-100r/min, product ethyl alcohol and distilled water are alternately washed to neutrality, then set
It dries in 40-60 DEG C of baking oven to constant weight, then smashes it through nanoscale sieve through ultra-fine grinding machine, can be prepared by infiltration and help
Agent.
Preferably, it is a kind of remove adhesive sticker residue glue aerosol, wherein the aerosol the preparation method is as follows: will expansion
Particle is added in closed container, is vibrated under 400-600W ultrasonic wave, and it is 20- that flow velocity is then passed through into container
40ml/min, the nitrogen that temperature is 50-70 DEG C, is continually fed into 30-50min, after being passed through to nitrogen, is cooled to room temperature, then
It is passed through the nitrogen for carrying penetrant with the flow velocity of 30-50ml/min, is passed through container completely to the nitrogen containing penetrant
In subsequent persistent oscillation 1-2h, then product is removed rapidly, being mutually encapsulated into after mixing with propellant, sodium alkyl benzene sulfonate has
In the pressure vessel of valve system, it can be prepared by.
Preferably, a kind of aerosol for removing adhesive sticker residue glue, wherein the application method of the aerosol is as follows: taking a small amount of
Tap water is sprayed on adhesive sticker residue glue surface, is then rubbed 1-2min on residue glue surface with hand, is then sprayed on residue glue surface
Aerosol, continue rub 2-3min, wait rub after continue spray tap water, stand 3-5min after with hand rubbing i.e. can reach
Remove the effect of adhesive sticker.
The present invention has the advantage that compared with prior art
1. the aerosol prepared by the present invention for removing adhesive sticker residue glue is solid phase aerosol, by gas phase adsorption method, so that
Penetrant is adsorbed on expanded granular surface and forms complex solid particle, which has good water swellability and infiltration
Permeability can effectively penetrate into adhesive sticker residue glue under the kneading action of external force, reduce the stickiness and reduction of gluing object
The contact area of residue glue and object material, to realize the removing of residue glue, the expanded granular of addition has extremely strong water swelling
Performance, can effectively penetrate into adhesive sticker residue glue under external force, can increase gluing in residue glue by water swelling
The Kong Rong of object hole, so that the spacing between the chemical bond of gluing object increases, so that the binding force between chemical bond is reduced, thus
So that gluing object loses/reduce stickiness, while expanded granular can also penetrate between residue glue and the contact surface of object material, lead to
Water swelling is crossed to increase the spacing of residue glue Yu object material contacts face, so that contact area is reduced, so that residue glue is in external force
Rubbing under be easy quickly removal；Contain anionic group carboxylic acid group in the penetrant of addition, with calcium, the magnesium etc. in tap water
There is good adsorptivity, so that penetrant can be very good to penetrate into not under the kneading action of external force between metal ion
In dry glue residue glue, to improve the permeability of solia particle in aerosol；Injection power of the propellant of addition as aerosol
Source can make the solia particle in aerosol spray with mist, can not only solid particle be made to be evenly distributed in residue glue
Surface, but also the dosage of solid particle can be reduced, it increases operation rate；The sodium alkyl benzene sulfonate of addition is as surfactant
The residue glue surface tension after moistening can be reduced, is conducive to solid particle and penetrates into residue glue；The aerosol can be fast and effective
Remove plastics, metal, plank, the surfaces such as glass adhesive sticker removing residual glue trace, and have without methanol, ethyl alcohol, benzene homologues etc.
Solvent, it is nonirritant to human skin, optic nerve and respiratory system, secondary wound will not be caused to object material itself
Evil, be widely portable to family, office, in automobile etc. to the sealing that health requirements are higher and need often to close the doors and windows
In environment.
2. it is prepared by the present invention for removing the aerosol of adhesive sticker residue glue, wherein the expanded granular added is with extremely strong
Hectorite is immersed in the mixing salt solution being made of potassium carbonate and sodium carbonate first, lithium can be improved by water-swelling property
The expansion capacity of saponite, then through multiple freeze-thaw, the hole that can increase hectorite space structure holds aperture, to improve lithium
The expansion capacity of saponite；Secondly treated hectorite is subjected to high-temperature calcination, the platy layer in lithium soap stone structure can be increased
Spacing can be further improved the expansion capacity of hectorite and improve the adsorptivity of hectorite；Finally in initiator and crosslinking agent
Under the action of with xanthan gum and acrylic acid graft polymerization reaction occurs, the particle with extremely strong water swellability is formed, wherein adding
The hydrophily of expanded granular can be improved in the xanthan gum added, to improve the absorption speed of expanded granular, quickly inhales to realize
Water swellable effect.
3. it is prepared by the present invention for removing the aerosol of adhesive sticker residue glue, wherein the penetrant added rubbing in external force
Under stranding effect and the suction-operated of metal ion, it can be very good to penetrate into adhesive sticker residue glue, to improve aerosol
Nano-graphite is immersed in the mixed acid solution being made of the concentrated sulfuric acid and concentrated nitric acid by function and effect first, it is oxidation-treated can
To improve the dispersibility of nano-graphite in water, then the interlamellar spacing of graphite surface can be increased through high-temperature calcination, to reduce stone
The apparent density of ink, improves the dilation of graphite, increases the adsorptivity of graphite；Secondly, making expanded graphite, third using ultrasonic wave
Olefin(e) acid and adipic acid are evenly dispersed in water, then introduce anionic group carboxylic acid in polyacrylic acid under the action of initiator
Base, so that modified polyacrylic acid has suction-operated to cation, and by causing in-situ polymerization and macromolecular reaction, so that
The interlayer of graphite oxide and the macromolecular of modified polyacrylic acid are bonded, form the penetrant with fine adsorptivity.
4. it is prepared by the present invention for removing the application method of the aerosol of adhesive sticker residue glue, first by adhesive sticker residue glue table
It is rubbed after the wetting of face with hand, the metal ions such as the calcium in tap water, magnesium can be promoted to penetrate into residue glue, then spray aerosol again
Agent is rubbed, then under the action of external force and under the suction-operated of metal ions such as calcium, magnesium, and the solia particle in aerosol can be with
It penetrates into the gap of residue glue and object contact surface and in the hole of residue glue, then sprays tap water again and stood, passed through
Continuous water suction can be such that solia particle expands, so that the viscosity of adhesive in residue glue is reduced, to realize the removal of residue glue；It should
The utilization rate of aerosol can be improved in application method, improves the elimination effect of aerosol, reaches to realize to the removal rate of residue glue
To 100%.
Specific embodiment
Below with reference to specific implementation method, the present invention is described further.
Embodiment 1
A kind of aerosol for removing adhesive sticker residue glue, by weight component are as follows: 5 parts of expanded granular, is cast 3 parts of penetrant
80 parts of agent, 2 parts of sodium alkyl benzene sulfonate.
Preferably, wherein the propellant is one of F-11, difluoromethane, three chloro-tetrafluoroethanes or group
It closes.
Preferably, wherein the expanded granular the preparation method is as follows:
1) taking concentration is 10 parts of solution of potassium carbonate of 0.1mol/L, and concentration is 5 parts of sodium carbonate liquor of 0.1mol/L, is made after mixing
Mixing salt solution is obtained, then takes 10 parts of hectorite to be added in mixing salt solution, the mechanical stirring 5h in the case where revolving speed is 800r/min,
Natural thaw 25h after cryogenic freezing 20h is subsequently placed at -10 DEG C, and repeated freezing, which thaws 5 times, to be placed in centrifuge with 3500r/
The rate of min is centrifuged 15min, and the supernatant that inclines, which is placed in 70 DEG C of baking ovens, to be dried to constant weight, spare；
2) it will be added in Muffle furnace by pretreated hectorite, and be heated to 150 DEG C with the heating rate of 10 DEG C/min, heat preservation
400 DEG C, high-temperature calcination 4h are heated to the heating rate of 20 DEG C/min again after 10min, it is then slow with the cooling rate of 3 DEG C/min
Slowly it is cooled to room temperature, above-mentioned heating calcining cooling 5 times is repeated, can be prepared by modified hectorite；
3) 13 parts of xanthan gum are taken, is added in 30 parts of deionized waters, xanthan gum solution is made in stirring and dissolving, is then heated to 50
DEG C, it is then added 0.1 part of ammonium persulfate, 4 parts of sodium hydroxide solution, the N, N of 3mol/L are added after heat preservation 5min,Methylene
0.2 part of bisacrylamide, 5 parts of acrylic acid and modified hectorite, are heated to 70 DEG C, isothermal reaction 5h, wait react after mixing
After, it place the product in drying in 50 DEG C of baking ovens to constant weight, is then pulverized, can be prepared by average grain diameter is 10um's
Expanded granular.
Preferably, wherein the penetrant the preparation method is as follows:
1) 15 parts of the concentrated sulfuric acid of 95% are taken, 3 parts of 65% concentrated nitric acid is made mixed acid solution, then takes nano graphite powder 5 after mixing
Part, it is added in mixed acid solution, is heated to 60 DEG C, impregnate 2h, then rinse 20min with deionized water, be placed in 60 DEG C of baking ovens
Then middle drying is placed in 800 DEG C of Muffle furnaces again to constant weight and calcines 7h, expanded nano-graphites powder is made；
2) expanded nano-graphites powder is added in distilled water, the expanded nano-graphites powder that concentration is 0.5% is made after mixing
Then aqueous solution takes 3 parts of adipic acid, the vibrating dispersion 1.5h under 400W ultrasonic wave adds 4 parts of acrylic acid, after persistent oscillation point
1.5h is dissipated, is then added 0.1 part of ammonium persulfate, 5 parts of the hydrochloric acid of concentration 10%, stirring is anti-in the ice-water bath that revolving speed is 50r/min
4h is answered, product ethyl alcohol and distilled water are alternately washed to neutrality, is subsequently placed in 40 DEG C of baking ovens and dries to constant weight, then through super
Subtle pulverizer smashes it through nanoscale sieve, can be prepared by penetrant.
Preferably, wherein the aerosol the preparation method is as follows: expanded granular is added in closed container,
It is vibrated under 400W ultrasonic wave, it is 20ml/min that flow velocity is then passed through into container, and the nitrogen that temperature is 50 DEG C is continually fed into
30min after being passed through to nitrogen, is cooled to room temperature, then the nitrogen for carrying penetrant is passed through with the flow velocity of 30ml/min,
It is passed through subsequent persistent oscillation 2h in container completely to the nitrogen containing penetrant, then removes product rapidly, with propellant, alkane
It is mutually encapsulated into the pressure vessel with valve system, can be prepared by after the mixing of base benzene sulfonic acid sodium salt.
Preferably, wherein the application method of the aerosol is as follows: a small amount of tap water being taken to be sprayed at adhesive sticker residue glue table
On face, 1min then is rubbed on residue glue surface with hand, then sprays aerosol on residue glue surface, continues to rub 2min, wait rub
After continue spray tap water, stand 3-5min after with hand rubbing i.e. can reach remove adhesive sticker effect.
Embodiment 2
A kind of aerosol for removing adhesive sticker residue glue, by weight component are as follows: 7 parts of expanded granular, is cast 5 parts of penetrant
120 parts of agent, 3 parts of sodium alkyl benzene sulfonate.
Preferably, wherein the propellant is one of F-11, difluoromethane, three chloro-tetrafluoroethanes or group
It closes.
Preferably, wherein the expanded granular the preparation method is as follows:
1) taking concentration is 15 parts of solution of potassium carbonate of 0.2mol/L, and concentration is 10 parts of sodium carbonate liquor of 0.2mol/L, after mixing
Mixing salt solution is made, then takes 13 parts of hectorite to be added in mixing salt solution, the mechanical stirring in the case where revolving speed is 900r/min
4h, is subsequently placed at -12 DEG C natural thaw 23h after cryogenic freezing 15h, repeated freezing thaw 4 times be placed in centrifuge with
The rate of 4000r/min is centrifuged 13min, and the supernatant that inclines, which is placed in 75 DEG C of baking ovens, to be dried to constant weight, spare；
2) it will be added in Muffle furnace by pretreated hectorite, and be heated to 180 DEG C with the heating rate of 12 DEG C/min, heat preservation
450 DEG C, high-temperature calcination 3.5h are heated to the heating rate of 25 DEG C/min again after 20min, then with the cooling rate of 4 DEG C/min
Slow cooling repeats above-mentioned heating calcining cooling 4 times, can be prepared by modified hectorite to room temperature；
3) 15 parts of xanthan gum are taken, is added in 40 parts of deionized waters, xanthan gum solution is made in stirring and dissolving, is then heated to 55
DEG C, it is then added 0.1 part of ammonium persulfate, 5 parts of sodium hydroxide solution, the N, N of 4mol/L are added after heat preservation 7min,Methylene
0.2 part of bisacrylamide, 7 parts of acrylic acid and modified hectorite, are heated to 75 DEG C, isothermal reaction 4h, wait react after mixing
After, it place the product in drying in 55 DEG C of baking ovens to constant weight, is then pulverized, can be prepared by average grain diameter is 15um's
Expanded granular.
Preferably, wherein the penetrant the preparation method is as follows:
1) 17 parts of the concentrated sulfuric acid of 97% are taken, 4 parts of 68% concentrated nitric acid is made mixed acid solution, then takes nano graphite powder 7 after mixing
Part, it is added in mixed acid solution, is heated to 65 DEG C, impregnate 1.5h, then rinse 25min with deionized water, be placed in 65 DEG C of bakings
It dries in case to constant weight, is then placed in again in 900 DEG C of Muffle furnaces and calcines 5h, expanded nano-graphites powder is made；
2) expanded nano-graphites powder is added in distilled water, the expanded nano-graphites powder that concentration is 0.7% is made after mixing
Then aqueous solution takes 4 parts of adipic acid, the vibrating dispersion 1.3h under 400W ultrasonic wave adds 5 parts of acrylic acid, after persistent oscillation point
1.3h is dissipated, is then added 0.1 part of ammonium persulfate, 7 parts of the hydrochloric acid of concentration 13%, stirring is anti-in the ice-water bath that revolving speed is 70r/min
3.5h is answered, product ethyl alcohol and distilled water are alternately washed to neutrality, is subsequently placed in 50 DEG C of baking ovens and dries to constant weight, then pass through
Ultra-fine grinding machine smashes it through nanoscale sieve, can be prepared by penetrant.
Preferably, wherein the aerosol the preparation method is as follows: expanded granular is added in closed container,
It is vibrated under 500W ultrasonic wave, it is 30ml/min that flow velocity is then passed through into container, and the nitrogen that temperature is 60 DEG C is continually fed into
40min after being passed through to nitrogen, is cooled to room temperature, then the nitrogen for carrying penetrant is passed through with the flow velocity of 40ml/min,
Be passed through subsequent persistent oscillation 1.5h in container completely to the nitrogen containing penetrant, then remove product rapidly, with propellant,
It is mutually encapsulated into the pressure vessel with valve system, can be prepared by after sodium alkyl benzene sulfonate mixing.
Preferably, wherein the application method of the aerosol is as follows: a small amount of tap water being taken to be sprayed at adhesive sticker residue glue table
On face, 1.5min then is rubbed on residue glue surface with hand, then sprays aerosol on residue glue surface, continues to rub 2.5min, to
Continue to spray tap water after rubbing, can reach the effect for removing adhesive sticker with hand rubbing after standing 4min.
Embodiment 3
A kind of aerosol for removing adhesive sticker residue glue, by weight component are as follows: 10 parts of expanded granular, is cast 7 parts of penetrant
150 parts of agent, 5 parts of sodium alkyl benzene sulfonate.
Preferably, wherein the propellant is one of F-11, difluoromethane, three chloro-tetrafluoroethanes or group
It closes.
Preferably, wherein the expanded granular the preparation method is as follows:
1) taking concentration is 20 parts of solution of potassium carbonate of 0.3mol/L, and concentration is 15 parts of sodium carbonate liquor of 0.3mol/L, after mixing
Mixing salt solution is made, then takes 15 parts of hectorite to be added in mixing salt solution, the mechanical stirring in the case where revolving speed is 1000r/min
3h, is subsequently placed at -15 DEG C natural thaw 20h after cryogenic freezing 10h, repeated freezing thaw 4 times be placed in centrifuge with
The rate of 4500r/min is centrifuged 10min, and the supernatant that inclines, which is placed in 80 DEG C of baking ovens, to be dried to constant weight, spare；
2) it will be added in Muffle furnace by pretreated hectorite, and be heated to 200 DEG C with the heating rate of 15 DEG C/min, heat preservation
500 DEG C, high-temperature calcination 3h are heated to the heating rate of 30 DEG C/min again after 30min, it is then slow with the cooling rate of 5 DEG C/min
Slowly it is cooled to room temperature, above-mentioned heating calcining cooling 3 times is repeated, can be prepared by modified hectorite；
3) 17 parts of xanthan gum are taken, is added in 50 parts of deionized waters, xanthan gum solution is made in stirring and dissolving, is then heated to 60
DEG C, it is then added 0.2 part of ammonium persulfate, 6 parts of sodium hydroxide solution, the N, N of 5mol/L are added after heat preservation 10min,Methylene
0.3 part of bisacrylamide, 8 parts of acrylic acid and modified hectorite, are heated to 80 DEG C, isothermal reaction 3h, wait react after mixing
After, it place the product in drying in 60 DEG C of baking ovens to constant weight, is then pulverized, can be prepared by average grain diameter is 20um's
Expanded granular.
Preferably, wherein the penetrant the preparation method is as follows:
1) 20 parts of the concentrated sulfuric acid of 98% are taken, 5 parts of 70% concentrated nitric acid is made mixed acid solution, then takes nano graphite powder 8 after mixing
Part, it is added in mixed acid solution, is heated to 70 DEG C, impregnate 1h, then rinse 30min with deionized water, be placed in 70 DEG C of baking ovens
Then middle drying is placed in 1000 DEG C of Muffle furnaces again to constant weight and calcines 3h, expanded nano-graphites powder is made；
2) expanded nano-graphites powder is added in distilled water, the expanded nano-graphites powder that concentration is 0.8% is made after mixing
Then aqueous solution takes 5 parts of adipic acid, the vibrating dispersion 1h under 600W ultrasonic wave, adds 7 parts of acrylic acid, continues vibrating dispersion
1h, is then added 0.2 part of ammonium persulfate, and 10 parts of the hydrochloric acid of concentration 15% is stirred to react in the ice-water bath that revolving speed is 100r/min
Product ethyl alcohol and distilled water are alternately washed to neutrality, are subsequently placed in 60 DEG C of baking ovens and dry to constant weight, then through ultra-fine by 3h
Atomizer smashes it through nanoscale sieve, can be prepared by penetrant.
Preferably, wherein the aerosol the preparation method is as follows: expanded granular is added in closed container,
It is vibrated under 600W ultrasonic wave, it is 40ml/min that flow velocity is then passed through into container, and the nitrogen that temperature is 70 DEG C is continually fed into
30min after being passed through to nitrogen, is cooled to room temperature, then the nitrogen for carrying penetrant is passed through with the flow velocity of 50ml/min,
It is passed through subsequent persistent oscillation 1h in container completely to the nitrogen containing penetrant, then removes product rapidly, with propellant, alkane
It is mutually encapsulated into the pressure vessel with valve system, can be prepared by after the mixing of base benzene sulfonic acid sodium salt.
Preferably, wherein the application method of the aerosol is as follows: a small amount of tap water being taken to be sprayed at adhesive sticker residue glue table
On face, 2min then is rubbed on residue glue surface with hand, then sprays aerosol on residue glue surface, continues to rub 3min, wait rub
After continue spray tap water, stand 5min after with hand rubbing i.e. can reach remove adhesive sticker effect.
Comparative example 1: removal expanded granular, remaining is same as Example 1.
Comparative example 2: removal penetrant, remaining is same as Example 1.
Test example 1: following tests example uses application method provided by the present application, for plastics, metal.Removing and plank base
Remaining double-sided adhesive (long 5cm, wide 1cm) of the same race processes on material, can remove various bases just with hand rubbing after 5min to stand
The time of double-sided adhesive residue glue on material be according to come judge aerosol except glue effect.In order to reduce the error of test, try every time
The dosage of agent keeps identical, and carries out 20 parallel tests, as far as possible reduction test error due to caused by human factor, test
As a result as shown in the table:
As can be seen from the above table, the present invention prepares aerosol and has well except glue effect, and removes glue significant effect, has very
Good commercial value.
Test example 2: taking 3g expanded granular, is divided into 6 groups, and being respectively put into floor space is 3cm2Container in, write down just
Begin height, and liquid level is then added water into container higher than expanded granular 3cm, after standing 5min, the water in container is poured out, applies lotus
It carries up to expanded granular recovery elemental height, records load weight, as a result as shown in the table:
As can be seen from the above table, the expanded granular in aerosol prepared by the present invention can produce greatly swollen after water swelling
Expansive force, to quickly and effectively make adhesive sticker residue glue be detached from substrate surface, to realize the quick removing of residue glue.
The above description is merely a specific embodiment, but scope of protection of the present invention is not limited thereto, any
It transforms or replaces, should be covered by the scope of protection of the present invention without what creative work was expected.
Claims (6)
1. a kind of aerosol for removing adhesive sticker residue glue, which is characterized in that component is as follows by weight: 5-10 parts of expanded granular,
3-7 parts of penetrant, 80-150 parts of propellant, 2-5 parts of sodium alkyl benzene sulfonate.
2. a kind of aerosol for removing adhesive sticker residue glue as described in claim 1, which is characterized in that the propellant is trichlorine
One of one fluoromethane, difluoromethane, three chloro-tetrafluoroethanes or combination.
3. a kind of aerosol for removing adhesive sticker residue glue as described in claim 1, which is characterized in that the system of the expanded granular
Preparation Method is as follows:
1) taking concentration is 10-20 parts of solution of potassium carbonate of 0.1-0.3mol/L, and concentration is the sodium carbonate liquor of 0.1-0.3mol/L
5-15 parts, mixing salt solution is made after mixing, then takes 10-15 parts of hectorite to be added in mixing salt solution, is in revolving speed
Mechanical stirring 3-5h under 800-1000r/min is subsequently placed at -10--15 DEG C natural thaw 20- after cryogenic freezing 10-20h
25h is placed on for repeated freezing defrosting 4-5 times in centrifuge and is centrifuged 10-15min with the rate of 3500-4500r/min, incline on
Clear liquid, which is placed in 70-80 DEG C of baking oven, to be dried to constant weight, spare；
2) it will be added in Muffle furnace by pretreated hectorite, 150-200 is heated to the heating rate of 10-15 DEG C/min
DEG C, keep the temperature 10-30min after be heated to 400-500 DEG C, high-temperature calcination 3-4h again with the heating rate of 20-30 DEG C/min, then with
The cooling rate slow cooling of 3-5 DEG C/min repeats above-mentioned heating calcining cooling 3-5 times, can be prepared by modified lithium soap to room temperature
Stone；
3) 13-17 parts of xanthan gum are taken, is added in 30-50 parts of deionized waters, xanthan gum solution is made in stirring and dissolving, then heats
To 50-60 DEG C, it is then added ammonium persulfate 0.1-0.2 parts, the sodium hydroxide solution of 3-5mol/L is added after heat preservation 5-10min
4-6 parts, N, N,0.2-0.3 parts of methylene-bisacrylamide, 5-8 parts of acrylic acid and modified hectorite, are heated to after mixing
70-80 DEG C, isothermal reaction 3-5h, to which after reaction, place the product in dried in 50-60 DEG C of baking oven to constant weight, then through super
Crushing of Ultrafine can be prepared by the expanded granular that average grain diameter is 10-20um.
4. a kind of aerosol for removing adhesive sticker residue glue as described in claim 1, which is characterized in that the system of the penetrant
Preparation Method is as follows:
1) 15-20 parts of the concentrated sulfuric acid of 95-98% are taken, 3-5 parts of the concentrated nitric acid of 65-70% is made mixed acid solution, then takes after mixing
It 5-8 parts of nano graphite powder, is added in mixed acid solution, is heated to 60-70 DEG C, impregnate 1-2h, then rinsed with deionized water
20-30min is placed in 60-70 DEG C of baking oven and dries to constant weight, is then placed in 800-1000 DEG C of Muffle furnace again and calcines 3-7h, makes
Obtain expanded nano-graphites powder；
2) expanded nano-graphites powder is added in distilled water, the expansion nano stone that concentration is 0.5-0.8% is made after mixing
Then ink powder aqueous solution takes 3-5 parts of adipic acid, the vibrating dispersion 1-1.5h under 400-600W ultrasonic wave adds acrylic acid 4-7
Part, continue vibrating dispersion 1-1.5h, is then added ammonium persulfate 0.1-0.2 parts, 5-10 parts of the hydrochloric acid of concentration 10-15%, in revolving speed
To be stirred to react 3-4h in the ice-water bath of 50-100r/min, product ethyl alcohol and distilled water are alternately washed to neutrality, then set
It dries in 40-60 DEG C of baking oven to constant weight, then smashes it through nanoscale sieve through ultra-fine grinding machine, can be prepared by infiltration and help
Agent.
5. a kind of aerosol for removing adhesive sticker residue glue as described in claim 1, which is characterized in that the preparation of the aerosol
Method is as follows: expanded granular being added in closed container, is vibrated under 400-600W ultrasonic wave, is then led into container
Entering flow velocity is 20-40ml/min, and the nitrogen that temperature is 50-70 DEG C is continually fed into 30-50min, cold after being passed through to nitrogen
But to room temperature, then the nitrogen for carrying penetrant is passed through with the flow velocity of 30-50ml/min, it is complete to the nitrogen containing penetrant
All-pass enters subsequent persistent oscillation 1-2h in container, then removes product rapidly, common after mixing with propellant, sodium alkyl benzene sulfonate
It is encapsulated in the pressure vessel with valve system, can be prepared by.
6. a kind of aerosol for removing adhesive sticker residue glue as described in claim 1, which is characterized in that the use of the aerosol
Method is as follows: taking a small amount of tap water to be sprayed on adhesive sticker residue glue surface, then rubs 1-2min on residue glue surface with hand, then
Residue glue surface spray aerosol, continue rub 2-3min, wait rub after continue spray tap water, stand 3-5min after use
Hand rubbing can reach the effect for removing adhesive sticker.
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| CN101186864A (en) * | 2007-11-09 | 2008-05-28 | 大连工业大学 | Degumming agent and method for removing bottom glue at plastic surface by using the same |
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| CN108042967A (en) * | 2017-12-27 | 2018-05-18 | 广东自由能科技股份有限公司 | A kind of fluorine-containing high-efficiency environment friendly extinguishing chemical and preparation method thereof |
| CN109266422A (en) * | 2018-09-30 | 2019-01-25 | 镇江宝海船舶五金有限公司 | A kind of lubricant and preparation method thereof being applicable in marine anchor chain |
| CN109679608A (en) * | 2017-10-18 | 2019-04-26 | 中国石油化工股份有限公司 | High temperature resistant acid resistant form foaming water discharge agent and preparation method and application |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101186864A (en) * | 2007-11-09 | 2008-05-28 | 大连工业大学 | Degumming agent and method for removing bottom glue at plastic surface by using the same |
| CN107384605A (en) * | 2017-08-31 | 2017-11-24 | 重庆尚洁日化用品有限公司 | A kind of detergent for toilet |
| CN109679608A (en) * | 2017-10-18 | 2019-04-26 | 中国石油化工股份有限公司 | High temperature resistant acid resistant form foaming water discharge agent and preparation method and application |
| CN108042967A (en) * | 2017-12-27 | 2018-05-18 | 广东自由能科技股份有限公司 | A kind of fluorine-containing high-efficiency environment friendly extinguishing chemical and preparation method thereof |
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