CN110003783A - A kind of graphene functional anticorrosive paint and preparation method thereof - Google Patents
A kind of graphene functional anticorrosive paint and preparation method thereof Download PDFInfo
- Publication number
- CN110003783A CN110003783A CN201910300740.XA CN201910300740A CN110003783A CN 110003783 A CN110003783 A CN 110003783A CN 201910300740 A CN201910300740 A CN 201910300740A CN 110003783 A CN110003783 A CN 110003783A
- Authority
- CN
- China
- Prior art keywords
- graphene
- anticorrosive paint
- agent
- raw material
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/54—Improvements relating to the production of bulk chemicals using solvents, e.g. supercritical solvents or ionic liquids
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of graphene functional anticorrosive paints and preparation method thereof, and raw material includes: graphene solution 6~13%, polyurethane 25~80%, auxiliary agent 0.5~2%, surplus are water.The concentration of graphene solution is 0.5~6mg/ml.The piece diameter of graphene raw material is 5~14 μm.The present invention also provides the preparation methods of the coating, include: step 1, weighing each raw material in proportion；Step 2, graphene is added to the water and is stirred until homogeneous, graphene solution is made；Mixing speed is 300~500 revs/min, and mixing time is 10~20 minutes；Step 3, graphene solution, polyurethane, auxiliary agent, water are mixed evenly, it is 1300~2000 revs/min that speed, which is mixed, is mixed 10~30 minutes；Obtain graphene anticorrosive paint.Coating prepared by the present invention has excellent anti-corrosion function, has a extensive future.
Description
Technical field
The present invention relates to a kind of coating and preparation method thereof, and in particular, to a kind of graphene functional anticorrosive paint and its
Preparation method.
Background technique
Graphene is the single layer of carbon atom material being stripped out from graphite, tightly packed at single layer two dimension bee by carbon atom
Nest shape lattice structure, it is the material that thickness known to the mankind is most thin, quality is most hard, electric conductivity is best.Graphene has excellent
Different mechanics, electrical and optical properties, structure is highly stable, and researcher not yet has found have carbon atom to lack in graphene so far
The case where mistake, the link between carbon atom is very flexible, also harder than diamond, on the intensity steel more best than in the world is taller
100 times, if packaging bag is made with graphene, it will bear about two tons of heavy articles, almost transparent, but extremely cause
It is close, it is waterproof, airtight, it can not pass through atomic size the smallest helium, conduct electricity very well, the fortune of electronics in graphene
Dynamic speed has reached the 1/300 of the light velocity, and electric conductivity has been more than any traditional conductive material, chemical property similar to graphite surface,
Various atoms and molecule can be adsorbed and be desorbed, the ability of strong acid and strong base is also resisted.Graphene also has excellent resist simultaneously
Bacterium and far-infrared functional.
Summary of the invention
The object of the present invention is to provide a kind of graphene coating and preparation method thereof, which has excellent anti-corrosion function
Can, it has a extensive future；The preparation method simple process is easy to operate, low in cost, high financial profit, is suitble to heavy industrialization
Production.
In order to achieve the above object, the present invention provides a kind of graphene functional anticorrosive paints, wherein the graphene
The raw material of functional anticorrosive paint includes by mass percentage: graphene solution 6~13%, polyurethane 25~80%, auxiliary agent 0.5
~2%, surplus is water.Water is preferably deionized water.
Above-mentioned graphene functional anticorrosive paint, wherein the graphene solution is prepared by graphene raw material and water
It forms；The graphene raw material includes process for preparing graphenes by chemical vapour deposition, chemistry redox graphene, carbon dioxide
Supercritical expansion removes graphene oxide, the coupling agent modified graphene oxide, amino macromolecule of graphene, chemical oxidation removing
Any one or more in modified graphene oxide, cationic surfactant modified graphene oxide.
Above-mentioned graphene functional anticorrosive paint, wherein the concentration of the graphene solution is 0.5~6mg/ml.
Above-mentioned graphene functional anticorrosive paint, wherein the piece diameter of the graphene raw material is 5~14 μm.
Above-mentioned graphene functional anticorrosive paint, wherein the auxiliary agent includes packing agent, defoaming agent, curing agent, anti-settling
Any one or more in agent.
Above-mentioned graphene functional anticorrosive paint, wherein the defoaming agent includes silicone emulsion, high-carbon alcohol fatty acid ester
Compound, polyoxyethylene polyoxypropylene pentaerythrite ether, any one or more in polyoxyethylene polyoxy propyl alcohol amidogen ether.
Above-mentioned graphene functional anticorrosive paint, wherein the packing agent includes diatomite, mica powder, kaolin, carbon
Any one or more in sour calcium, white carbon black.
Above-mentioned graphene functional anticorrosive paint, wherein the curing agent includes 593 curing agent, 810 curing agent, T31
Curing agent, ketimine cured dose, LITE3005 curing agent, any one or more in NX-2040 curing agent.
Above-mentioned graphene functional anticorrosive paint, wherein the anti-settling agent includes modified hydrogenated castor oil, polyamide
Wax, organobentonite, fumed silica, any one or more in modified polyurea N- methylpyrrole solution.
The present invention also provides the preparation methods of above-mentioned graphene functional anticorrosive paint, wherein the method includes:
Step 1, each raw material is weighed in proportion；Step 2, graphene is added to the water and is stirred until homogeneous, graphene solution is made；Stirring
Speed is 300~500 revs/min, and mixing time is 10~20 minutes；Step 3, by graphene solution, polyurethane, auxiliary agent, water
It is mixed evenly, it is 1300~2000 revs/min that speed, which is mixed, is mixed 10~30 minutes；It is anti-to obtain graphene
Rotten coating.
Graphene functional anticorrosive paint provided by the invention and preparation method thereof has the advantage that
The graphene that the present invention uses has biggish specific surface area and unique two-dimensional slice structure, and graphene is in coating
In it is evenly dispersed, form fine and close physical shielding layer, extend the diffusion path of corrosive medium, significantly reduce corrosion because
The diffusion rate of son, and can effectively prevent coating by the diffusion of crazing when external interference.Therefore graphene prepared by the present invention
Anticorrosive paint has excellent anti-corrosion function.
Specific embodiment
A specific embodiment of the invention is further described below.
Graphene functional anticorrosive paint provided by the invention, raw material includes by mass percentage: graphene solution 6~
13%, polyurethane 25~80%, auxiliary agent 0.5~2%, surplus are water.Water is preferably deionized water.
Preferably, which is formulated by graphene raw material and water；Graphene raw material includes chemical gaseous phase
Sedimentation prepares graphene, chemistry redox graphene, CO 2 supercritical expansion removing graphene, chemical oxidation removing
Graphene oxide, coupling agent modified graphene oxide, the macromolecule modified graphene oxide of amino, cationic surfactant change
Any one or more in property graphene oxide.
The concentration of graphene solution is 0.5~6mg/ml.
The piece diameter of graphene raw material is 5~14 μm.
Auxiliary agent includes any one or more in packing agent, defoaming agent, curing agent, anti-settling agent.
Defoaming agent includes silicone emulsion, the fatty acid ester compounded object of higher alcohols, polyoxyethylene polyoxypropylene pentaerythrite ether, gathers
Any one or more in ethylene oxide polyoxy propyl alcohol amidogen ether.
Packing agent includes any one or more in diatomite, mica powder, kaolin, calcium carbonate, white carbon black.
Curing agent include 593 curing agent, 810 curing agent, T31 curing agent, ketimine cured dose, LITE3005 curing agent,
Any one or more in NX-2040 curing agent.
Anti-settling agent includes modified hydrogenated castor oil, polyamide wax, organobentonite, fumed silica, modified polyurea N-
Any one or more in methylpyrrole solution.
The present invention also provides the preparation method of the graphene functional anticorrosive paint, it includes: step 1, weigh in proportion
Each raw material；Step 2, graphene is added to the water and is stirred until homogeneous, graphene solution is made；Step 3, by graphene solution,
Polyurethane, auxiliary agent, water are mixed evenly, and obtain graphene anticorrosive paint.
Preferably, mixing speed is 300~500 revs/min in step 2, and mixing time is 10~20 minutes.
It is 1300~2000 revs/min that speed is mixed in step 3, is mixed 10~30 minutes.
Graphene functional anticorrosive paint provided by the invention and preparation method thereof is done further below with reference to embodiment
Description.
Embodiment 1
A kind of graphene functional anticorrosive paint, raw material includes by mass percentage:
The raw material of graphene functional anticorrosive paint includes by mass percentage: graphene solution 6%, polyurethane 25%,
Auxiliary agent 0.5%, surplus are water.Water is preferably deionized water.
Graphene solution is formulated by graphene raw material and water；Graphene raw material is prepared comprising chemical vapour deposition technique
Graphene.
The concentration of graphene solution is 0.5mg/ml.The piece diameter of graphene raw material is 5~14 μm.
Auxiliary agent includes any one or more in packing agent, defoaming agent, curing agent, anti-settling agent.
Defoaming agent includes silicone emulsion.
Packing agent includes diatomite.
Curing agent includes 593 curing agent.
Anti-settling agent includes modified hydrogenated castor oil.
The present embodiment additionally provides the preparation method of the graphene functional anticorrosive paint, it includes:
Step 1, each raw material is weighed in proportion；Step 2, graphene is added to the water and is stirred until homogeneous, graphene is made
Solution；Mixing speed is 300~500 revs/min, and mixing time is 10~20 minutes；Step 3, by graphene solution, poly- ammonia
Ester, auxiliary agent, water are mixed evenly, and it is 1300~2000 revs/min that speed, which is mixed, are mixed 10~30 minutes；?
To graphene anticorrosive paint.
Embodiment 2
A kind of graphene functional anticorrosive paint, raw material includes by mass percentage:
The raw material of graphene functional anticorrosive paint includes by mass percentage: graphene solution 7.5%, polyurethane
40%, auxiliary agent 0.8%, surplus are water.Water is preferably deionized water.
Graphene solution is formulated by graphene raw material and water；Graphene raw material includes chemistry redox graphite
Alkene.
The concentration of graphene solution is 1.5mg/ml.The piece diameter of graphene raw material is 5~14 μm.
Auxiliary agent includes any one or more in packing agent, defoaming agent, curing agent, anti-settling agent.
Defoaming agent includes the fatty acid ester compounded object of higher alcohols.
Packing agent includes mica powder or kaolin.
Curing agent includes 810 curing agent.
Anti-settling agent includes polyamide wax.
The present embodiment additionally provides the preparation method of the graphene functional anticorrosive paint, it includes:
Step 1, each raw material is weighed in proportion；Step 2, graphene is added to the water and is stirred until homogeneous, graphene is made
Solution；Mixing speed is 300~500 revs/min, and mixing time is 10~20 minutes；Step 3, by graphene solution, poly- ammonia
Ester, auxiliary agent, water are mixed evenly, and it is 1300~2000 revs/min that speed, which is mixed, are mixed 10~30 minutes；?
To graphene anticorrosive paint.
Embodiment 3
A kind of graphene functional anticorrosive paint, raw material includes by mass percentage:
The raw material of graphene functional anticorrosive paint includes by mass percentage: graphene solution 9%, polyurethane 55%,
Auxiliary agent 1%, surplus are water.Water is preferably deionized water.
Graphene solution is formulated by graphene raw material and water；Graphene raw material is expanded comprising CO 2 supercritical
Remove the graphene oxide of graphene or chemical oxidation removing.
The concentration of graphene solution is 3mg/ml.The piece diameter of graphene raw material is 5~14 μm.
Auxiliary agent includes any one or more in packing agent, defoaming agent, curing agent, anti-settling agent.
Defoaming agent includes polyoxyethylene polyoxypropylene pentaerythrite ether.
Packing agent includes calcium carbonate.
Curing agent includes T31 curing agent.
Anti-settling agent includes organobentonite or fumed silica.
The present embodiment additionally provides the preparation method of the graphene functional anticorrosive paint, it includes:
Step 1, each raw material is weighed in proportion；Step 2, graphene is added to the water and is stirred until homogeneous, graphene is made
Solution；Mixing speed is 300~500 revs/min, and mixing time is 10~20 minutes；Step 3, by graphene solution, poly- ammonia
Ester, auxiliary agent, water are mixed evenly, and it is 1300~2000 revs/min that speed, which is mixed, are mixed 10~30 minutes；?
To graphene anticorrosive paint.
Embodiment 4
A kind of graphene functional anticorrosive paint, raw material includes by mass percentage:
The raw material of graphene functional anticorrosive paint includes by mass percentage: graphene solution 11%, polyurethane 70%,
Auxiliary agent 1.5%, surplus are water.Water is preferably deionized water.
Graphene solution is formulated by graphene raw material and water；Graphene raw material includes coupling agent modified graphite oxide
Alkene.
The concentration of graphene solution is 4.5mg/ml.The piece diameter of graphene raw material is 5~14 μm.
Auxiliary agent includes any one or more in packing agent, defoaming agent, curing agent, anti-settling agent.
Defoaming agent includes polyoxyethylene polyoxy propyl alcohol amidogen ether.
Packing agent includes white carbon black.
Curing agent includes ketimine cured dose.
Anti-settling agent includes modified polyurea N- methylpyrrole solution.
The present embodiment additionally provides the preparation method of the graphene functional anticorrosive paint, it includes:
Step 1, each raw material is weighed in proportion；Step 2, graphene is added to the water and is stirred until homogeneous, graphene is made
Solution；Mixing speed is 300~500 revs/min, and mixing time is 10~20 minutes；Step 3, by graphene solution, poly- ammonia
Ester, auxiliary agent, water are mixed evenly, and it is 1300~2000 revs/min that speed, which is mixed, are mixed 10~30 minutes；?
To graphene anticorrosive paint.
Embodiment 5
A kind of graphene functional anticorrosive paint, raw material includes by mass percentage:
The raw material of graphene functional anticorrosive paint includes by mass percentage: graphene solution 13%, polyurethane 80%,
Auxiliary agent 2%, surplus are water.Water is preferably deionized water.
Graphene solution is formulated by graphene raw material and water；Graphene raw material includes the macromolecule modified oxidation of amino
Graphene, cationic surfactant modified graphene oxide.
The concentration of graphene solution is 6mg/ml.The piece diameter of graphene raw material is 5~14 μm.
Auxiliary agent includes any one or more in packing agent, defoaming agent, curing agent, anti-settling agent.
Defoaming agent includes silicone emulsion, the fatty acid ester compounded object of higher alcohols, polyoxyethylene polyoxypropylene pentaerythrite ether, gathers
Any one or more in ethylene oxide polyoxy propyl alcohol amidogen ether.
Packing agent includes any one or more in diatomite, mica powder, kaolin, calcium carbonate, white carbon black.
Curing agent includes LITE3005 curing agent or NX-2040 curing agent.
Anti-settling agent includes modified hydrogenated castor oil, polyamide wax, organobentonite, fumed silica, modified polyurea N-
Any one or more in methylpyrrole solution.
The present embodiment additionally provides the preparation method of the graphene functional anticorrosive paint, it includes:
Step 1, each raw material is weighed in proportion；Step 2, graphene is added to the water and is stirred until homogeneous, graphene is made
Solution；Mixing speed is 300~500 revs/min, and mixing time is 10~20 minutes；Step 3, by graphene solution, poly- ammonia
Ester, auxiliary agent, water are mixed evenly, and it is 1300~2000 revs/min that speed, which is mixed, are mixed 10~30 minutes；?
To graphene anticorrosive paint.
The graphene of graphene functional anticorrosive paint provided by the invention and preparation method thereof, use compares table with biggish
Area and unique two-dimensional slice structure, graphene is evenly dispersed in coating, forms fine and close physical shielding layer, extends
The diffusion path of corrosive medium significantly reduces the diffusion rate of corrosion factor, and can effectively prevent coating by external interference
The diffusion of Shi Yinwen.Therefore graphene anticorrosive paint prepared by the present invention has excellent anti-corrosion function, has a extensive future；
The preparation method simple process is easy to operate, low in cost, high financial profit, is suitble to large-scale industrial production.
It is discussed in detail although the contents of the present invention have passed through above preferred embodiment, but it should be appreciated that above-mentioned
Description is not considered as limitation of the present invention.After those skilled in the art have read above content, for of the invention
A variety of modifications and substitutions all will be apparent.Therefore, protection scope of the present invention should be limited to the appended claims.
Claims (10)
1. a kind of graphene functional anticorrosive paint, which is characterized in that the raw material of the graphene functional anticorrosive paint presses quality
Percentages include: graphene solution 6~13%, polyurethane 25~80%, auxiliary agent 0.5~2%, surplus are water.
2. graphene functional anticorrosive paint as described in claim 1, which is characterized in that the graphene solution passes through graphite
Alkene raw material is formulated with water；The graphene raw material includes process for preparing graphenes by chemical vapour deposition, chemistry redox
Graphene oxide, the coupling agent modified oxidation stone that graphene, CO 2 supercritical expansion removing graphene, chemical oxidation are removed
In the macromolecule modified graphene oxide of black alkene, amino, cationic surfactant modified graphene oxide any one or it is more
Kind.
3. graphene functional anticorrosive paint as claimed in claim 2, which is characterized in that the concentration of the graphene solution is
0.5~6mg/ml.
4. graphene functional anticorrosive paint as claimed in claim 2, which is characterized in that the piece diameter of the graphene raw material is
5~14 μm.
5. graphene functional anticorrosive paint as described in claim 1, which is characterized in that the auxiliary agent includes packing agent, disappears
Infusion, curing agent, any one or more in anti-settling agent.
6. graphene functional anticorrosive paint as claimed in claim 5, which is characterized in that the defoaming agent includes emulsification silicon
Oil, the fatty acid ester compounded object of higher alcohols, polyoxyethylene polyoxypropylene pentaerythrite ether, appointing in polyoxyethylene polyoxy propyl alcohol amidogen ether
It anticipates one or more.
7. graphene functional anticorrosive paint as claimed in claim 5, which is characterized in that the packing agent include diatomite,
Mica powder, kaolin, calcium carbonate, any one or more in white carbon black.
8. graphene functional anticorrosive paint as claimed in claim 5, which is characterized in that the curing agent includes 593 solidifications
Agent, 810 curing agent, T31 curing agent, ketimine cured dose, LITE3005 curing agent, any one in NX-2040 curing agent
Or it is a variety of.
9. graphene functional anticorrosive paint as claimed in claim 5, which is characterized in that the anti-settling agent includes modified hydrogenated
Castor oil, polyamide wax, organobentonite, fumed silica, in modified polyurea N- methylpyrrole solution any one or
It is a variety of.
10. a kind of preparation method of the graphene functional anticorrosive paint as described in any one of claim 1~9, feature
It is, the method includes:
Step 1, each raw material is weighed in proportion；
Step 2, graphene is added to the water and is stirred until homogeneous, graphene solution is made；Mixing speed is 300~500 revs/min
Clock, mixing time are 10~20 minutes；
Step 3, graphene solution, polyurethane, auxiliary agent, water are mixed evenly, be mixed speed be 1300~2000 turns/
Minute, it is mixed 10~30 minutes；Obtain graphene anticorrosive paint.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910300740.XA CN110003783A (en) | 2019-04-15 | 2019-04-15 | A kind of graphene functional anticorrosive paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910300740.XA CN110003783A (en) | 2019-04-15 | 2019-04-15 | A kind of graphene functional anticorrosive paint and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110003783A true CN110003783A (en) | 2019-07-12 |
Family
ID=67171955
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910300740.XA Pending CN110003783A (en) | 2019-04-15 | 2019-04-15 | A kind of graphene functional anticorrosive paint and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110003783A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110655809A (en) * | 2019-10-29 | 2020-01-07 | 江苏华光粉末有限公司 | Polyamide wax modified sea urchin-shaped graphene and preparation method thereof, and anticorrosive powder coating and preparation process thereof |
| CN112323483A (en) * | 2020-11-03 | 2021-02-05 | 南通强生石墨烯科技有限公司 | Graphene waterproof agent for textile |
| CN112898890A (en) * | 2021-03-22 | 2021-06-04 | 辽阳康达塑胶树脂有限公司 | Preparation process and production line of anticorrosive material |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101676317A (en) * | 2008-09-16 | 2010-03-24 | 上海美东生物材料有限公司 | Application of cardanol in epoxy resin curing |
| CN102498146A (en) * | 2009-06-29 | 2012-06-13 | 波利莫莱特股份有限公司 | Polymer compositions and methods of making and using the same |
| CN103865359A (en) * | 2014-03-20 | 2014-06-18 | 长春市三化实业有限责任公司 | Oil pollution resistant polyaniline anticorrosive coating and preparation method thereof |
| CN106189713A (en) * | 2016-08-25 | 2016-12-07 | 北京尚德安耐新材料科技有限公司 | The preparation and application of watersoluble plumbago alkene anticorrosive paint |
| CN106430165A (en) * | 2016-10-26 | 2017-02-22 | 上海纳米技术及应用国家工程研究中心有限公司 | Preparation method of high-quality low-defect single-layer graphene |
| CN106832883A (en) * | 2017-01-17 | 2017-06-13 | 南通强生安全防护科技股份有限公司 | Aqueous PU composite mortars of Graphene and its production and use |
| CN106867298A (en) * | 2017-03-15 | 2017-06-20 | 中国科学院宁波材料技术与工程研究所 | The preparation method of graphite alkenes anticorrosive paint |
| CN107151493A (en) * | 2017-04-28 | 2017-09-12 | 叶镜枝 | Aqueous PVDF fluorocarbon coatings and its coating process |
| CN108531006A (en) * | 2018-04-19 | 2018-09-14 | 多凌新材料科技股份有限公司 | The waterborne anti-corrosive primer and preparation method thereof of graphene enhancing |
| US20180346755A1 (en) * | 2017-06-02 | 2018-12-06 | Samsung Display Co., Ltd. | Nanocomposite body, method of manufacturing the same, and nanocomposite film including the nanocomposite body |
-
2019
- 2019-04-15 CN CN201910300740.XA patent/CN110003783A/en active Pending
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101676317A (en) * | 2008-09-16 | 2010-03-24 | 上海美东生物材料有限公司 | Application of cardanol in epoxy resin curing |
| CN102498146A (en) * | 2009-06-29 | 2012-06-13 | 波利莫莱特股份有限公司 | Polymer compositions and methods of making and using the same |
| CN103865359A (en) * | 2014-03-20 | 2014-06-18 | 长春市三化实业有限责任公司 | Oil pollution resistant polyaniline anticorrosive coating and preparation method thereof |
| CN106189713A (en) * | 2016-08-25 | 2016-12-07 | 北京尚德安耐新材料科技有限公司 | The preparation and application of watersoluble plumbago alkene anticorrosive paint |
| CN106430165A (en) * | 2016-10-26 | 2017-02-22 | 上海纳米技术及应用国家工程研究中心有限公司 | Preparation method of high-quality low-defect single-layer graphene |
| CN106832883A (en) * | 2017-01-17 | 2017-06-13 | 南通强生安全防护科技股份有限公司 | Aqueous PU composite mortars of Graphene and its production and use |
| CN106867298A (en) * | 2017-03-15 | 2017-06-20 | 中国科学院宁波材料技术与工程研究所 | The preparation method of graphite alkenes anticorrosive paint |
| CN107151493A (en) * | 2017-04-28 | 2017-09-12 | 叶镜枝 | Aqueous PVDF fluorocarbon coatings and its coating process |
| US20180346755A1 (en) * | 2017-06-02 | 2018-12-06 | Samsung Display Co., Ltd. | Nanocomposite body, method of manufacturing the same, and nanocomposite film including the nanocomposite body |
| CN108531006A (en) * | 2018-04-19 | 2018-09-14 | 多凌新材料科技股份有限公司 | The waterborne anti-corrosive primer and preparation method thereof of graphene enhancing |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110655809A (en) * | 2019-10-29 | 2020-01-07 | 江苏华光粉末有限公司 | Polyamide wax modified sea urchin-shaped graphene and preparation method thereof, and anticorrosive powder coating and preparation process thereof |
| CN110655809B (en) * | 2019-10-29 | 2021-02-05 | 江苏华光粉末有限公司 | Polyamide wax modified sea urchin-shaped graphene and preparation method thereof, and anticorrosive powder coating and preparation process thereof |
| CN112323483A (en) * | 2020-11-03 | 2021-02-05 | 南通强生石墨烯科技有限公司 | Graphene waterproof agent for textile |
| CN112898890A (en) * | 2021-03-22 | 2021-06-04 | 辽阳康达塑胶树脂有限公司 | Preparation process and production line of anticorrosive material |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN110003783A (en) | A kind of graphene functional anticorrosive paint and preparation method thereof | |
| Kouhbanani et al. | One-step green synthesis and characterization of iron oxide nanoparticles using aqueous leaf extract of Teucrium polium and their catalytic application in dye degradation | |
| Moussavi et al. | High-rate adsorption of acetaminophen from the contaminated water onto double-oxidized graphene oxide | |
| Bai et al. | Branched mesoporous Mn3O4 nanorods: facile synthesis and catalysis in the degradation of methylene blue | |
| Muruganandham et al. | Synthesis of N, C codoped hierarchical porous microsphere ZnS as a visible light-responsive photocatalyst | |
| Zhou et al. | Controlled synthesis of rh-In2O3 nanostructures with different morphologies for efficient photocatalytic degradation of oxytetracycline | |
| Mustafa et al. | Surface properties of the mixed oxides of iron and silica | |
| Konicki et al. | Removal of anionic dyes using magnetic Fe@ graphite core-shell nanocomposite as an adsorbent from aqueous solutions | |
| Nguyen et al. | Chemical synthesis and characterization of palladium nanoparticles | |
| Zhao et al. | Rapid microwave-assisted synthesis of hierarchical ZnO hollow spheres and their application in Cr (VI) removal | |
| Jiang et al. | Porous F-doped BiVO4: Synthesis and enhanced photocatalytic performance for the degradation of phenol under visible-light illumination | |
| Huang et al. | Enhanced surface hydroxyl groups by using hydrogen peroxide on hollow tubular alumina for removing fluoride | |
| Shi et al. | N-doping Ta2O5 nanoflowers with strong adsorption and visible light photocatalytic activity for efficient removal of methylene blue | |
| Liu et al. | Defects and interface states related photocatalytic properties in reduced and subsequently nitridized Fe3O4/TiO2 | |
| Lei et al. | Preparation of copper-incorporated mesoporous alumina abrasive and its CMP behavior on hard disk substrate | |
| Liu et al. | Atomic surface of fused silica and polishing mechanism interpreted by molecular dynamics and density functional theory | |
| García-Gómez et al. | Ionic liquid-assisted sonochemical synthesis of SnS nanostructures | |
| Aggarwal et al. | Influence of perfluorinated end groups on the SFRD of [Pt (cod) Me (CnF2n+ 1)] onto porous Al2O3 in CO2 under reductive conditions | |
| Li et al. | NaOH-embedded three-dimensional porous boron nitride for efficient formaldehyde removal | |
| Seisenbaeva et al. | General Facile Approach to Transition‐Metal Oxides with Highly Uniform Mesoporosity and Their Application as Adsorbents for Heavy‐Metal‐Ion Sequestration | |
| Wang et al. | Designing of Co3O4/N-doped carbon and Co-Co3O4/N-doped carbon nanomaterials via sol-gel route with unexpected high catalytic performances toward hydrogenation reduction of 4-Nitrophenol | |
| Yin et al. | Effect of Sr (OH) 2 as a pH regulator on different plane sapphire substrate chemical mechanical polishing | |
| Gao et al. | Adsorption of methyl orange on magnetically separable mesoporous titania nanocomposite | |
| Mirhosseini et al. | Novel adsorbent g‐C3N4/ZnV2O4 for efficient removal of crystal violet dye: Removal process optimization, adsorption isotherms, and kinetic modeling | |
| Alharthi et al. | Low temperature ionothermal synthesis of TiO2 nanomaterials for efficient photocatalytic H2 production, dye degradation and photoluminescence studies |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190712 |