CN110003733A - A kind of density board, particle board barrier peculiar smell coating and preparation method thereof - Google Patents

A kind of density board, particle board barrier peculiar smell coating and preparation method thereof Download PDF

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Publication number
CN110003733A
CN110003733A CN201811553741.7A CN201811553741A CN110003733A CN 110003733 A CN110003733 A CN 110003733A CN 201811553741 A CN201811553741 A CN 201811553741A CN 110003733 A CN110003733 A CN 110003733A
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CN
China
Prior art keywords
peculiar smell
coating
preparation
particle board
filler
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Pending
Application number
CN201811553741.7A
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Chinese (zh)
Inventor
陈烜
黄宏存
朱清梅
袁业兴
符誉龄
范秀婷
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Hainan Kai Kai Shui New Material Co Ltd
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Hainan Kai Kai Shui New Material Co Ltd
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Priority to CN201811553741.7A priority Critical patent/CN110003733A/en
Publication of CN110003733A publication Critical patent/CN110003733A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/04Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C09D127/08Homopolymers or copolymers of vinylidene chloride
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/48Stabilisers against degradation by oxygen, light or heat
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/14Gas barrier composition

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of density boards, particle board barrier peculiar smell coating and preparation method thereof, and the coating is made of polyvinylidene emulsions, antioxidant, filler and the Ba/Zn stabilizer that solid content is 40%-50%.The coating production, comprising the following steps: polyvinylidene emulsions are added first in high-speed mixer and 25min-30min is mixed in filler, adds antioxidant and continuess to mix stirring 5min-10min;Stabilizer is added later, is stirred until emulsion appearance stable homogeneous;Finally add organic silicon defoamer again, stirs until no macroscopic bubble.The additional amount of the organic silicon defoamer is 8th/3000 to thousand/1000ths of raw material weight, and the mixing speed is that 250-300 turns/min.Barrier peculiar smell coating of the invention can obstruct the pernicious gases such as the formaldehyde of density board and particle board volatilization, avoid it and cause damages to human body and environment, and is easy to use, and curing time is short, material safety and environmental protection, meet food hygiene requirement.

Description

A kind of density board, particle board barrier peculiar smell coating and preparation method thereof
Technical field
The present invention relates to a kind of barrier peculiar smell coating and preparation method thereof, in particular to a kind of density boards, particle board barrier Peculiar smell coating and preparation method thereof.
Background technique
Density board is also referred to as fiberboard, be using wood fiber or other plant fiber as raw material, apply Lauxite or other Artificial board made of applicable adhesive is mainly used for laminated flooring, door-plate, partition wall, furniture etc..Density plate surface is smooth It is smooth, material is fine and closely woven, performance is stable, edge is secured, easy to process, avoid rotten, the problems such as damaging by worms, and plate surface Good decorative property.But existing density board and particle board are due to containing more non-environmental protection type adhesive, the non-environmental protection type glue in inside Glutinous agent can often volatilize the harmful gas such as formaldehyde, cause biggish harm to human body and environment.In the prior art frequently with powder Last type spray sprays furniture density board and particle plate surface, is oxidized the formaldehyde of density board and particle plate surface point Solution.But after the formaldehyde on density board and particle board surface layer is decomposed, more the adhesive of deep layer can slowly give out formaldehyde, the party Method cannot prevent the formaldehyde of density board and particle board deep layer toward external penetration.
Summary of the invention
In consideration of it, the present invention proposes a kind of density board, particle board barrier peculiar smell coating and preparation method thereof, solves density The technical issues of being dissipated outside plate and particle board formaldehyde, influencing environmental and human health impacts.
The technical scheme of the present invention is realized as follows:
A kind of density board, particle board barrier peculiar smell coating and preparation method thereof, including following raw material: solid content is Polyvinylidene emulsions, antioxidant, filler and the Ba/Zn stabilizer of 40%-50%.
More preferably, the solid content be 40%-50% 1-5 parts of 60-70 parts of polyvinylidene emulsions, antioxidant, 10-20 parts and 5-30 parts of Ba/Zn stabilizer of filler.
More preferably, the filler is talcum powder and/or calcium carbonate.It is at low cost, and the phase between other components of the invention Capacitive is good.
More preferably, the partial size of the filler is 500nm-1000nm.The compatibility that low partial size more can guarantee.
More preferably, Ba/Zn stabilizer is zinc stearate (ZnSt), in calcium stearate (CaSt), barium stearate (BaSt) It is one or more.Under the addition of the stabilizer can be such that component of the invention is used for a long time, stable chemical performance reduces air to it Oxidation, enable the excellent yellowing resistance that has of clay, and it is environment-protecting and non-poisonous.
More preferably, antioxidant is 1010 antioxidants and/or 1076 antioxidants.Mainly prevent polyvinylidene chloride oxygen Change, xanthochromia.Both antioxidants are suitable for the invention formula, and using effect is good compared with other oxidants after addition.
More preferably, a kind of density board, the preparation method of particle board barrier peculiar smell coating, comprising the following steps: first in height Polyvinylidene emulsions are added in fast mixing machine and 25min-30min is mixed in filler, adds antioxidant and continuess to mix Stir 5min-10min;Stabilizer is added later, is stirred until emulsion appearance stable homogeneous;Finally add organosilicon defoaming again Agent is stirred until no macroscopic bubble.The characteristics of present invention is according to formula constituent, is stirred by the way of in batches It mixes, raw material of the invention preferably fully reacting can be made, and there is good compatibility, and in reaction process between component Side reaction does not occur.If defoaming agent addition is too early, other materials can be hindered compatible.Such as it is added antioxidant in advance, antioxidant can be by In heated or by high shearing force, antioxidant effect is lost.
More preferably, the additional amount of the organic silicon defoamer is 8th/3000 to thousand/1000ths of raw material weight.
More preferably, the mixing speed is that 250-300 turns/min.
Compared with prior art, the beneficial effects of the present invention are:
Barrier peculiar smell coating of the invention increases polyvinylidene emulsions in formula so that coating have it is excellent Oxygen barrier and hinder it is moist, can obstruct density board, in particle board quick release pernicious gas, and its internal glue can be obstructed Glutinous agent and outside air contact, prevent internal adhesive avoids density from the pernicious gases such as formaldehyde that volatilize outward again Plate and particle board volatilization pernicious gas cause damages to human body and environment, and are not influenced by ambient humidity, light and temperature under being used for a long time.Match Antioxidant is increased in side, can make to keep high barrier property in coating long-term use process.Stabilizer is increased in formula, It can promote the present invention that can preferably control and improve the anti-yellowing property of coating, also, by the addition of filler, improve The crack resistance of coating can be applied in the field more demanding to appearance.Barrier peculiar smell coating of the invention, can be by spraying It is used with modes such as brushings, easy to use, curing time is short, can quickly obstruct the volatilization of peculiar smell.Meanwhile barrier of the invention is different Taste coating material safety and environmental protection meets food hygiene requirement.
Preparation method of the invention can make raw material of the invention preferably fully reacting, not generate side reaction, to make Obtaining coating obtained has high barrier and high yellowing resistance.
Specific embodiment
In order to be best understood from the technology of the present invention content, specific embodiment is provided below, the present invention is described further.
Embodiment 1
A kind of density board, particle board obstruct peculiar smell coating, and being composed by the following raw materials by weight: solid content is 40%- 50% 60 parts of polyvinylidene emulsions, 1 part of antioxidant, 10 parts of filler and 5 parts of Ba/Zn stabilizer.Filler be talcum powder and The mixing of calcium carbonate.Ba/Zn stabilizer is the mixing of zinc stearate (ZnSt), calcium stearate (CaSt), barium stearate (BaSt). Antioxidant is the mixing of 1010 antioxidants and 1076 antioxidants.
The preparation method of a kind of density board, particle board barrier peculiar smell coating, comprising the following steps: first in high-speed mixer 25min is mixed in middle addition polyvinylidene emulsions and filler, adds antioxidant and continuess to mix stirring 5min;Later again Stabilizer is added, stirs until emulsion appearance stable homogeneous;Finally add organic silicon defoamer, stirring to no macroscopic bubble again Until.The additional amount of organic silicon defoamer is 3/1000ths of raw material weight.Mixing speed is 250 turns/min.
Embodiment 2
A kind of density board, particle board obstruct peculiar smell coating, and being composed by the following raw materials by weight: solid content is 40%- 50% 70 parts of polyvinylidene emulsions, 5 parts of antioxidant, 20 parts of filler and 30 parts of Ba/Zn stabilizer.Filler is talcum powder. Ba/Zn stabilizer is zinc stearate (ZnSt).Antioxidant is 1010 antioxidants.
The preparation method of a kind of density board, particle board barrier peculiar smell coating, comprising the following steps: first in high-speed mixer 30min is mixed in middle addition polyvinylidene emulsions and filler, adds antioxidant and continuess to mix stirring 10min;Later Stabilizer is added, is stirred until emulsion appearance stable homogeneous;Finally add organic silicon defoamer, stirring to no macroscopic gas again Until bubble.The additional amount of organic silicon defoamer is 8/1000ths of raw material weight.Mixing speed is 300 turns/min.
Embodiment 3
A kind of density board, particle board obstruct peculiar smell coating, and being composed by the following raw materials by weight: solid content is 40%- 50% 65 parts of polyvinylidene emulsions, 3 parts of antioxidant, 15 parts of filler and 18 parts of Ba/Zn stabilizer.Filler is that partial size is The calcium carbonate of 500nm-1000nm.Ba/Zn stabilizer is barium stearate (BaSt).Antioxidant is 1076 antioxidants.
The preparation method of a kind of density board, particle board barrier peculiar smell coating, comprising the following steps: first in high-speed mixer 28min is mixed in middle addition polyvinylidene emulsions and filler, adds antioxidant and continuess to mix stirring 8min;Later again Stabilizer is added, stirs until emulsion appearance stable homogeneous;Finally add organic silicon defoamer, stirring to no macroscopic bubble again Until.The additional amount of organic silicon defoamer is 5/1000ths of raw material weight.Mixing speed is 280 turns/min.
Embodiment 4
Ba/Zn stabilizer in embodiment 3 is barium stearate (BaSt), replacement are as follows: lead stearate (PbSt).Remaining formula It is constant.
Embodiment 5
Antioxidant in embodiment 3 is 1076 antioxidants, replacement are as follows: 168 antioxidants.Remaining formula is constant.
Embodiment 6
Filler in embodiment 3 is the calcium carbonate that partial size is 500nm-1000nm, replacement are as follows: titanium dioxide.Remaining formula is not It is right.
Comparative example 1
Composition of raw materials in embodiment 3 is constant.
The preparation method of a kind of density board, particle board barrier peculiar smell coating, replacement are as follows: be added in high-speed mixer poly- inclined 30min is mixed in dichloroethylene lotion, filler, antioxidant and stabilizer, stirs until emulsion appearance stable homogeneous;Finally Again plus organic silicon defoamer, it stirs until no macroscopic bubble.The additional amount of organic silicon defoamer is the thousand of raw material weight / five.Mixing speed is 300 turns/min.
Comparative example 2
Solid content in embodiment 3 is 65 parts of polyvinylidene emulsions of 40%-50%, replacement are as follows: solid content It is 65 parts of polyvinylidene emulsions of 20%-30%, remaining formula is constant.
According to embodiment 1 to barrier peculiar smell coating obtained by embodiment 3, can obstruct density board, in particle board quickly The pernicious gas of release, and contacting for its internal adhesive and outside air can be obstructed, prevent internal adhesive from Volatilize the pernicious gases such as formaldehyde outward again, avoids density board and particle board volatilization pernicious gas causes to endanger to human body and environment Evil.The barrier peculiar smell coating overall performance according to made from embodiment 4 to embodiment 6 is preferable, and the coating of embodiment 4 is due to containing weight Metallic lead is toxic, vulnerable to sulphide staining.Coating made from embodiment 5, yellowing resistance are made not as good as embodiment 1 to embodiment 3 Coating.The coating of embodiment 6 is at high cost, and compatibility is not fine.The coating of comparative example 1, it is secondary anti-due to having in reaction process It should occur, barrier property is poor.The coating of comparative example 2, barrier property is less than coating made from embodiment 1 to embodiment 3.
Barrier peculiar smell coating of the invention increases polyvinylidene emulsions (PVDC), intermolecular agglutination in formula Power is strong, and crystallinity is high, and the chlorine atom in molecule has hydrophobicity, not will form hydrogen bond, and oxygen molecule and hydrone are difficult at PVDC points It is moved in son, so that coating has excellent oxygen barrier and hinders moist, density board can be obstructed, quick release has in particle board Evil gas, and adhesive of its inside and contacting for outside air can be obstructed, prevent internal adhesive from waving outward again The pernicious gases such as formaldehyde are sent out, density board is avoided and particle board volatilization pernicious gas causes damages to human body and environment, and is long-term It is not influenced by ambient humidity, light and temperature under use.Antioxidant is increased in formula, can make to keep high in coating long-term use process Barrier property.Stabilizer is increased in formula, can promoting the present invention that can preferably control and improve, coating is heated and illumination Under the conditions of anti-yellowing property improve the crack resistance of coating, can apply to appearance also, by the addition of filler More demanding field.Barrier peculiar smell coating of the invention can be used, easy to use, solidification by modes such as spraying and brushings Time is short, can quickly obstruct the volatilization of peculiar smell.Meanwhile barrier peculiar smell coating material safety and environmental protection of the invention, meet food and defends It is raw to require, pass through FDA (Food and Drug Adminstration of the US) certification.Preparation method of the invention can make raw material of the invention Preferably fully reacting does not generate side reaction, so that coating high barrier obtained and high yellowing resistance.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention Within mind and principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.

Claims (9)

1. a kind of density board, particle board obstruct peculiar smell coating and preparation method thereof, which is characterized in that including following raw material: solid Content is polyvinylidene emulsions, antioxidant, filler and the Ba/Zn stabilizer of 40%-50%.
2. a kind of density board according to claim 1, particle board obstruct peculiar smell coating and preparation method thereof, feature exists In 10-20 parts of 1-5 parts of 60-70 parts of polyvinylidene emulsions, antioxidant, the filler that, the solid content is 40%-50% and 5-30 parts of Ba/Zn stabilizer.
3. a kind of density board according to claim 1, particle board obstruct peculiar smell coating and preparation method thereof, feature exists In the filler is talcum powder and/or calcium carbonate.
4. a kind of density board according to claim 1 to 3, particle board obstruct peculiar smell coating and preparation method thereof, special Sign is that the partial size of the filler is 500nm-1000nm.
5. a kind of density board according to claim 4, particle board obstruct peculiar smell coating and preparation method thereof, feature exists In Ba/Zn stabilizer is one of zinc stearate (ZnSt), calcium stearate (CaSt), barium stearate (BaSt) or a variety of.
6. according to claim 1, a kind of density board described in 2,3 or 5, particle board barrier peculiar smell coating and preparation method thereof, It is characterized in that, antioxidant is 1010 antioxidants and/or 1076 antioxidants.
7. a kind of density board according to claim 1, particle board obstruct peculiar smell coating and preparation method thereof, feature exists In, comprising the following steps: polyvinylidene emulsions are added first in high-speed mixer and 25min- is mixed in filler 30min adds antioxidant and continuess to mix stirring 5min-10min;Stabilizer is added later, and stirring is equal until emulsion appearance One stablizes;Finally add organic silicon defoamer again, stirs until no macroscopic bubble.
8. a kind of density board according to claim 7, particle board obstruct peculiar smell coating and preparation method thereof, feature exists In the additional amount of the organic silicon defoamer is 8th/3000 to thousand/1000ths of raw material weight.
9. a kind of density board according to claim 7 or 8, particle board obstruct peculiar smell coating and preparation method thereof, feature It is, the mixing speed is that 250-300 turns/min.
CN201811553741.7A 2018-12-18 2018-12-18 A kind of density board, particle board barrier peculiar smell coating and preparation method thereof Pending CN110003733A (en)

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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115851020A (en) * 2022-12-08 2023-03-28 陈士震 Floor waterproof coating and preparation method and application thereof

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2060655A (en) * 1979-10-12 1981-05-07 Kureha Chemical Ind Co Ltd Latex of vinylidene chloride copolymers, its preparation and use
JPH0354229A (en) * 1989-07-21 1991-03-08 Daicel Chem Ind Ltd Coating composition for forming heat-sealable coating film
JPH04304275A (en) * 1991-04-01 1992-10-27 Asahi Chem Ind Co Ltd Pretreatment of vinylidene chloride latex
CN1340076A (en) * 1999-02-16 2002-03-13 纳幕尔杜邦公司 Gas barrier coating system for polymeric films and rigid containers
CN102275362A (en) * 2011-05-04 2011-12-14 海南赛诺实业有限公司 Water vapor separation type polyvinylidene chloride coating film and manufacturing method thereof
CN105585726A (en) * 2015-12-25 2016-05-18 江苏东材新材料有限责任公司 High-barrier polyester film and preparation method thereof
KR20170077931A (en) * 2015-12-28 2017-07-07 주식회사 상보 Manufacturing method of the barrier film and barrier film
CN107141662A (en) * 2017-05-10 2017-09-08 浙江衢州巨塑化工有限公司 A kind of preparation method for the polyvinylidene chloride composition for extending the food fresh keeping phase
CN107699062A (en) * 2017-09-27 2018-02-16 南通瑞普埃尔生物工程有限公司 A kind of aqueous environment protection alkali resistant is water-fast acid-proof bottom coating and its production technology
CN108129926A (en) * 2017-12-21 2018-06-08 常德金德新材料科技股份有限公司 Barrier coating and its preparation method and application
TW201839064A (en) * 2017-02-28 2018-11-01 日商積水化學工業股份有限公司 Gas barrier material and thermosetting resin composition

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2060655A (en) * 1979-10-12 1981-05-07 Kureha Chemical Ind Co Ltd Latex of vinylidene chloride copolymers, its preparation and use
JPH0354229A (en) * 1989-07-21 1991-03-08 Daicel Chem Ind Ltd Coating composition for forming heat-sealable coating film
JPH04304275A (en) * 1991-04-01 1992-10-27 Asahi Chem Ind Co Ltd Pretreatment of vinylidene chloride latex
CN1340076A (en) * 1999-02-16 2002-03-13 纳幕尔杜邦公司 Gas barrier coating system for polymeric films and rigid containers
CN102275362A (en) * 2011-05-04 2011-12-14 海南赛诺实业有限公司 Water vapor separation type polyvinylidene chloride coating film and manufacturing method thereof
CN105585726A (en) * 2015-12-25 2016-05-18 江苏东材新材料有限责任公司 High-barrier polyester film and preparation method thereof
KR20170077931A (en) * 2015-12-28 2017-07-07 주식회사 상보 Manufacturing method of the barrier film and barrier film
TW201839064A (en) * 2017-02-28 2018-11-01 日商積水化學工業股份有限公司 Gas barrier material and thermosetting resin composition
CN107141662A (en) * 2017-05-10 2017-09-08 浙江衢州巨塑化工有限公司 A kind of preparation method for the polyvinylidene chloride composition for extending the food fresh keeping phase
CN107699062A (en) * 2017-09-27 2018-02-16 南通瑞普埃尔生物工程有限公司 A kind of aqueous environment protection alkali resistant is water-fast acid-proof bottom coating and its production technology
CN108129926A (en) * 2017-12-21 2018-06-08 常德金德新材料科技股份有限公司 Barrier coating and its preparation method and application

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
中国大百科全书出版社编辑部: "《中国大百科全书(化学)(1)》", 31 December 1989, 中国大百科全书出版社编辑部编 *
刘西文: "《塑料配混工(中、高级)培训教程》", 31 January 2017, 文化发展出版社 *
杨松柏等: "论聚偏二氯乙烯树脂水性涂料", 《中国涂料》 *
骆光林: "《包装材料学 第2版》", 31 May 2015, 湖南科学技术出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115851020A (en) * 2022-12-08 2023-03-28 陈士震 Floor waterproof coating and preparation method and application thereof

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