CN110003724A - A kind of strong concrete interfacial agents and preparation method thereof - Google Patents
A kind of strong concrete interfacial agents and preparation method thereof Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D109/00—Coating compositions based on homopolymers or copolymers of conjugated diene hydrocarbons
- C09D109/06—Copolymers with styrene
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/10—Homopolymers or copolymers of methacrylic acid esters
- C09D133/12—Homopolymers or copolymers of methyl methacrylate
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
Abstract
The invention discloses a kind of strong concrete interfacial agents and preparation method thereof, belong to building material technical field.On the one hand the present invention participates in the hydration reaction of interface concrete using the carboxyl introduced, carry out preferable water-reduction, increase the jelling structure intensity of boundary material, on the other hand long hydrocarbon chain hydrophobic group and good water solubility are utilized, connect hydrophilic group, by reducing surface tension reduction after oil-based release agent demoulding is remained, and reduces the pollution to interface.Using the self character of elastomer, with preferable toughness and elasticity, swelling stress when slowing down a part of interface cohesion and prevent from cracking, increase the mechanical property at interface.Sour complexing agent is added and increases the compactness of junction so that capillary interstice is filled, alkaline environment holding and carbon dioxide absorption, promote the growth of calcium carbonate crystal, enhance interface performance.The present invention solves the problems, such as current concrete interface agent cohesive force, poor waterproof properties.
Description
Technical field
The invention belongs to building material technical fields, and in particular to a kind of strong concrete interfacial agents and its preparation side
Method.
Background technique
In the construction, transformation and reinforcing engineering in bridge, tunnel and house, the knot at new-old concrete interface is often referred to
Conjunction problem, according to the correlation theory at interface it is found that the combination of material is in interface be it is most weak, most of destroy all occurs to exist
Interface or since interface.The quality of new-old concrete interface cohesion directly influences the quality problems of construction work, such as
Fruit interfacial adhesion is inadequate, just will appear such as and phenomena such as crack, stick up skin, peel off occurs, make it is integrally-built using function and
Safety is damaged again.
Concrete interface agent is also known as interface bonding agent, interfacial agents.Interfacial agents used in engineering mainly have cement net at present
Slurry, expanding cement net slurry, epoxy glue, polymer-modified cement mortar etc., wherein polymer-modified cement mortar is by cement, bone
Material, high molecular polymer binding material and various auxiliary agents are formulated, and are the novel binder course processing after a kind of modified-high polymer
Material, can be formed after hydration reaction has larger bonding force and high-strength hardenite with a certain toughness with concrete, is application
Increase a kind of finish materials of functional material in long concrete wall or concrete surface, new and old coagulation can be increased
Bonding force between soil and between concrete and plastering mortar can replace traditional dabbing process, accelerate construction progress,
The adhesion strength of new-old concrete is directly related to the quality of concrete after repairing, reinforcing.China applies concrete interface at present
Mainly there is mortar base, concrete base layer, old wall floor tile base, various materials for wall bases, non-in the base of processing material
Metal veneer and decoration panel base, heat preservation styrofoam base etc..
Nevertheless, but the concrete interface agent in practical engineering application to there is adhesion strength mostly low, corrosion resistance,
Water resistance, durability and low temperature flexibility are poor, easily come unglued, crack under wet environment, falling off, hollowing the problems such as.Newly, old concrete
Adhesive surface has in the identical material of new, old concrete and similar internal structure, and for macroscopically, adhesive surface is by mixing always
Three phase materials of solidifying soil, novel concrete and interfacial agents composition, during Frozen-thawed cycled, positive and negative due to temperature alternately changes,
Alternate tensile stress is generated on pore periphery, so that adhesive surface is damaged, caused by Frozen-thawed cycled to certain number
When tensile stress reaches the adhesion strength at interface, adhesive surface will generate microcrack, and with the development of microcrack, perforation causes to glue
Junction is destroyed.
Traditional processing method is to carry out dabbing processing, to increase the bond area of concrete mortar and the base that constructs, from
And cohesive force being improved, but the processing method can only solve the problems, such as local, effect is less desirable, and time-consuming.Have at present
Concrete interface agent after dry powder-shaped concrete interface agent or polymer dispersion liquid and cement mixing.But dry powder-shaped coagulation
Soil Interface agent adhesive property is general, and waterproof performance is poor；And the concrete interface agent after polymer dispersion liquid and cement mixing
Dry very fast, easy cracking.
With the continuous development of architecture construction technology, bamboo (wood) glued board, industrializes template system at large-scale steel form
It is widely applied, although the concrete work seam surface finish and impression quality that are formed by concrete substage construction constantly mention
Height, but it is next difficult with concrete surface adhesive tape to later process such as concrete surface plasterings, this kind of surface is usually adopted
Manually dabbing is pocessed after rinsing.But such processing mode is long in time limit, cost is high, construction quality is difficult to reach design and want
It asks, building easily forms weak link at construction joint position or leaves hidden danger, jeopardizes the safety of building when serious.Therefore, it opens
Issue that a kind of cohesive force is strong, waterproof performance is excellent, operable time is long, splitting resistance is good, can be applied to oil pollution basal plane
Concrete interface agent it is necessary.
Summary of the invention
The technical problems to be solved by the invention: aiming at the problem that current concrete interface agent cohesive force, poor waterproof properties,
A kind of strong concrete interfacial agents and preparation method thereof are provided.
In order to solve the above technical problems, the present invention is using technical solution as described below:
A kind of strong concrete interfacial agents, including antipollution surfactant additives, interface cohesion additive, anti-water reactive agent, network
Mixture.
The antipollution surfactant additives the preparation method comprises the following steps:
(1) it takes 4,4- oxydibenzoic acid, 80 ~ 100:1 in mass ratio ~ 3 that n,N-Dimethylformamide is added, adds 4,4- bis-
The thionyl chloride of 2 ~ 5 times of phenylate dioctyl phthalate quality is stirred, and is evaporated under reduced pressure, and filtering takes filter cake 2 ~ 5:10 ~ 15 in mass ratio to add
Enter petroleum ether, stands, take precipitating drying, obtain dried object, methyl acrylate 4 ~ 7:10 ~ 15 in mass ratio is taken to be added dropwise to 3,3'- bis-
Tert-butyl -4,4'- diamino-diphenyl -4 " is stirred in-tert-butyl benzene methylmethane, is evaporated under reduced pressure, obtains vacuum distillation object；
(2) it takes vacuum distillation object 2 ~ 5:5 in mass ratio ~ 10 that chloroform is added, the pyridine stirring of vacuum distillation amount of substance 2 ~ 5% is added
Mixing, obtain mixed liquor a, take dried object 1 ~ 4:5 in mass ratio ~ 10 be added chloroform, obtain mixed liquor b, take mixed liquor b in mass ratio 3 ~
5:5 ~ 8 are added dropwise in mixed liquor a, are controlled 60 ~ 90min of time for adding, are stirred, and filter, filter residue is taken to wash through deionized water,
Up to antipollution surfactant additives.
The interface cohesion additive the preparation method comprises the following steps: take thermoplastic styrene butadiene rubber SBS4402 1 ~ 3:10 in mass ratio ~
30 addition dimethylbenzene are stirred, and add the Decanol of xylene mass 50 ~ 70%, and ultrasound is stirred, must be stirred
Object takes stirring mixture 10 ~ 20:3 in mass ratio ~ 5 that lubrication activity agent is added, stands to get interface cohesion additive.
The lubrication activity agent are as follows: take calcium stearate 3 ~ 5:1 in mass ratio ~ 3 that calcium oleate is added, calcium oleate quality 20 is added
~ 30% fatty acid methyl ester polyethers sodium sulfonate is stirred, and obtains mixture, take emulsifier 2 ~ 5:10 in mass ratio ~ 20 addition go from
Sub- water is stirred, and obtains mixed liquor, is taken mixture 2 ~ 5:10 in mass ratio ~ 15 that mixed liquor is added and is stirred, is cooled to room temperature,
Up to lubrication activity agent.
The emulsifier are as follows: take OP-10 1 ~ 3:2 in mass ratio ~ 5 be added Tween-80 mixing to get.
The anti-water reactive agent the preparation method comprises the following steps:
S1. it takes lauryl sodium sulfate 2 ~ 5:10 in mass ratio ~ 20 that ethyl alcohol is added to be stirred, adds lauryl sodium sulfate
The methyltriethoxysilane that 3 ~ 8 times of quality adjusts pH to 7 ~ 9, is stirred, and filters, and takes and filters slag through deionized water, anhydrous
Ethanol washing, it is dry, obtain dried object a；
S2. it takes octamethylcy-clotetrasiloxane 2 ~ 5:3 in mass ratio ~ 8 that t etram-ethyltetravinylcyclotetrasiloxane is added, obtains mixture
A is passed through nitrogen protection, and the catalyst that mixture a mass 2 ~ 5% is added is stirred, then is warming up to 100 ~ 110 DEG C of heat preservations, cold
But, cooled material is obtained, takes cooled material 3 ~ 5:3 in mass ratio ~ 6:10 ~ 15 that containing hydrogen silicone oil, isopropanol is added, adds cooled material quality
1 ~ 5% chloroplatinic acid is kept the temperature, rotary evaporation in 80 ~ 85 DEG C, and it is dry to collect rotary evaporation residue 10 ~ 15:2 in mass ratio ~ 8 addition
Dry object a mixing is to get anti-water reactive agent.
Catalyst in the step S2 are as follows: take tetramethylammonium hydroxide 2 ~ 5:1 in mass ratio ~ 3 that tetrabutyl hydrogen-oxygen is added
Change ammonium mixing to get.
The complexing agent are as follows: take citric acid, succinic acid, oxalic acid, chlorogenic acid, tartaric acid, formic acid, any one in malic acid
Kind or it is any it is several by any mass ratio mix to get.
The preparation method includes the following steps: to take antipollution surfactant additives 5 ~ 10:1 in mass ratio ~ 4 that sodium hydroxide is added
Solution is stirred, and is cooled to room temperature, and cooled material a is obtained, and according to the mass fraction, takes 5 ~ 10 parts of cooled material a, 30 ~ 50 parts of interface knots
Additive, 20 ~ 30 parts of anti-water reactive agents, 2 ~ 5 parts of complexing agent mixing are closed to get strong concrete interfacial agents.
The present invention is compared with other methods, and advantageous effects are:
(1) antipollution surfactant additives prepared by the present invention are to be obtained with 4,4- oxydibenzoic acid, thionyl chloride through acylation reaction
To starting monomer, then with methyl acrylate, 3,3'- di-t-butyl -4,4'- diamino-diphenyl -4, "-tert-butyl benzene methylmethane is
Raw material is reacted, and is generated the polymer containing tert-butyl, then carry out amidation process with starting monomer, is obtained antipollution interface
On the one hand additive, the balance with preferable hydrophilic and oleophilic participate in the aquation of interface concrete using the carboxyl of introducing
Reaction, carries out preferable water-reduction, increases the jelling structure intensity of boundary material, on the other hand hydrophobic using long hydrocarbon chain
Base and good water solubility, connect hydrophilic group, reduce the repulsion between identical electrical hydrophilic group, thus make surfactant from
Closer arrangement between son remains reduction after oil-based release agent demoulding by reducing surface tension, and reduces to interface
Pollution；
(2) interface cohesion additive prepared by the present invention be using thermoplastic styrene butadiene rubber SBS4402 as raw material, be added Decanol into
Row mixing is added interfacial agents latter aspect and forms shaggy configuration, and to have when new-old concrete interface cohesion anti-
The effect of sliding, interface cohesion is finer and close, on the other hand utilizes the self character of elastomer, has fill concrete cementitious material
Effect, with preferable toughness and elasticity, swelling stress when slowing down a part of interface cohesion and prevent from cracking, increase
The mechanical property at interface, while lubrication activity agent is added, so that preferably being combined dispersion with hydrated product, form uniform boundary
Face articulated system；
(3) anti-water reactive agent prepared by the present invention is mixed with lauryl sodium sulfate, methyltriethoxysilane, through the shape that alkalizes
At the powder with poly- sesquialter silane structure to rise as carrier, octamethylcy-clotetrasiloxane, tetramethyl tetravinyl ring four is added
Siloxanes reacts the low-surface-energy activating agent for the hydrophobic cross-linker to be formed through being catalyzed with containing hydrogen silicone oil again, is formed in interfacial agents interface
Super-hydrophobic silicon fiml does not influence the adhesive property of cementitious material after demoulding, form protective film to interface, outside moisture is to interface
The influence of junction；
(4) present invention is being eventually adding sour complexing agent, is complexed with a part of alkaline matter in the cementitious material of interface, and calcium is formed
Complex compound carries out infiltration filling to interface, so that capillary interstice is filled, the compactness of junction is increased, in alkali
Property environment holding and carbon dioxide absorption, promote the growth of calcium carbonate crystal, complexing agent to the enrichment of calcium ion with
And promote to occur complexing-precipitation of precipitated calcium silicate reaction, promote the aquation of unhydrated cement granules, form self-compaction
Concrete combination interface, enhances interface performance.
Specific embodiment
Thermoplastic styrene butadiene rubber SBS4402 are as follows: the content of styrene and butadiene ratio is 40:60.
Antipollution surfactant additives the preparation method comprises the following steps:
(1) it takes 4,4- oxydibenzoic acid, 80 ~ 100:1 in mass ratio ~ 3 that n,N-Dimethylformamide is added, adds 4,4- bis-
The thionyl chloride of 2 ~ 5 times of phenylate dioctyl phthalate quality, heating 70 ~ 80 DEG C be stirred 3 ~ 5h, be evaporated under reduced pressure, filtering, take filter cake by
Petroleum ether is added in 2 ~ 5:10 of mass ratio ~ 15, stands 20 ~ 50min, takes precipitating drying, obtain dried object, take methyl acrylate by quality
3,3'- di-t-butyl -4,4'- diamino-diphenyl -4 is added dropwise to than 4 ~ 7:10 ~ 15 " in-tert-butyl benzene methylmethane, in 70 ~ 80
DEG C it is stirred 2 ~ 4h, is evaporated under reduced pressure, obtains vacuum distillation object；
(2) it takes vacuum distillation object 2 ~ 5:5 in mass ratio ~ 10 that chloroform is added, the pyridine of vacuum distillation amount of substance 2 ~ 5%, stirring is added
Mix 20 ~ 30min, obtain mixed liquor a, take dried object 1 ~ 4:5 in mass ratio ~ 10 be added chloroform, obtain mixed liquor b, take mixed liquor b by
Mass ratio 3 ~ 5:5 ~ 8 are added dropwise in mixed liquor a, are controlled 60 ~ 90min of time for adding, are stirred 3 ~ 5h in 30 ~ 35 DEG C, are filtered,
Filter residue is taken to wash through deionized water to get antipollution surfactant additives.
Emulsifier are as follows: take OP-10 1 ~ 3:2 in mass ratio ~ 5 be added Tween-80 mixing to get.
Lubrication activity agent are as follows: take calcium stearate 3 ~ 5:1 in mass ratio ~ 3 that calcium oleate is added, calcium oleate quality 20 ~ 30% is added
Fatty acid methyl ester polyethers sodium sulfonate, be stirred 20 ~ 30min in 30 ~ 50 DEG C, obtain mixture, take emulsifier in mass ratio 2 ~
Deionized water is added in 5:10 ~ 20, is stirred 30 ~ 40min in 40 ~ 50 DEG C, obtains mixed liquor, takes mixture 2 ~ 5:10 in mass ratio
~ 15 are added mixed liquor, are stirred 1 ~ 3h in 90 ~ 95 DEG C, are cooled to room temperature to get lubrication activity agent.
Interface cohesion additive the preparation method comprises the following steps: take 1 ~ 3:10 ~ 30 in mass ratio thermoplastic styrene butadiene rubber SBS4402 plus
Enter dimethylbenzene, be stirred 20 ~ 30min in 20 ~ 30 DEG C, adds the Decanol of xylene mass 50 ~ 70%, ultrasound 5 ~
10min is stirred 4 ~ 6h in 25 ~ 30 DEG C, obtains stirring mixture, takes stirring mixture 10 ~ 20:3 in mass ratio ~ 5 that profit is added
Sliding activating agent, in 25 ~ 30 DEG C of 30 ~ 50min of standing to get interface cohesion additive.
Catalyst are as follows: take tetramethylammonium hydroxide 2 ~ 5:1 in mass ratio ~ 3 be added tetrabutylammonium hydroxide mixing to get.
Anti- water reactive agent the preparation method comprises the following steps:
S1. it takes lauryl sodium sulfate 2 ~ 5:10 in mass ratio ~ 20 that the ethyl alcohol that mass fraction is 80% is added, is stirred in 5000r/min
10 ~ 20min of mixing is mixed, 3 ~ 8 times of lauryl sodium sulfate quality of methyltriethoxysilane is added, adjusts pH to 7 ~ 9, in
40 ~ 50 DEG C are stirred 1 ~ 3h, filter, and take and filter slag through deionized water, dehydrated alcohol washing, drying obtains dried object a；
S2. it takes octamethylcy-clotetrasiloxane 2 ~ 5:3 in mass ratio ~ 8 that t etram-ethyltetravinylcyclotetrasiloxane is added, obtains mixture
A is passed through nitrogen protection, and the catalyst of mixture a mass 2 ~ 5% is added, is stirred 20 ~ 30min in 80 ~ 90 DEG C, then be warming up to
100 ~ 110 DEG C of 3 ~ 6h of heat preservation, are cooled to 80 ~ 85 DEG C, obtain cooled material, and cooled material 3 ~ 5:3 in mass ratio ~ addition of 6:10 ~ 15 is taken to contain
Hydrogen silicone oil, isopropanol add the chloroplatinic acid of cooled material quality 1 ~ 5%, and in 80 ~ 85 DEG C of 2 ~ 4h of heat preservation, rotary evaporation collects rotation
Turn evaporation residue 10 ~ 15:2 in mass ratio ~ 8 and dried object a mixing is added to get anti-water reactive agent.
Complexing agent are as follows: take citric acid, succinic acid, oxalic acid, chlorogenic acid, tartaric acid, formic acid, in malic acid any one or
It is any it is several by any mass ratio mix to get.
A kind of preparation method of strong concrete interfacial agents, includes the following steps: to take antipollution surfactant additives by matter
The sodium hydroxide solution that mass fraction is 35% is added than 5 ~ 10:1 ~ 4 for amount, is warming up to 95 ~ 100 DEG C and is stirred 1 ~ 4h, is cooled to
Room temperature obtains cooled material a, according to the mass fraction, takes 5 ~ 10 parts of cooled material a, 30 ~ 50 parts of interface cohesion additives, 20 ~ 30 parts of waterproofs
Activating agent, 2 ~ 5 parts of complexing agent mixing are to get strong concrete interfacial agents.
Embodiment 1
Thermoplastic styrene butadiene rubber SBS4402 are as follows: the content of styrene and butadiene ratio is 40:60.
Antipollution surfactant additives the preparation method comprises the following steps:
(1) it takes 4,4- oxydibenzoic acid 80:1 in mass ratio that n,N-Dimethylformamide is added, adds 4,4- diphenyl ether two
The thionyl chloride that 2 times of formic acid quality, 70 DEG C of heating are stirred 3h, are evaporated under reduced pressure, and filtering takes filter cake 2:10 to be in mass ratio added
Petroleum ether stands 20min, takes precipitating drying, obtain dried object, methyl acrylate 4:10 in mass ratio is taken to be added dropwise to 3,3'-, bis- uncle
Butyl -4,4'- diamino-diphenyl -4 " in-tert-butyl benzene methylmethane, is stirred 2h in 70 DEG C, is evaporated under reduced pressure, must depressurize steaming
Evaporate object；
(2) it takes vacuum distillation object 2:5 in mass ratio that chloroform is added, the pyridine of vacuum distillation amount of substance 2% is added, is stirred
20min obtains mixed liquor a, takes dried object 1:5 in mass ratio that chloroform is added, obtains mixed liquor b, take mixed liquor b 3:5 drop in mass ratio
It adds in mixed liquor a, controls time for adding 60min, be stirred 3h in 30 DEG C, filter, take filter residue to wash through deionized water, i.e.,
Obtain antipollution surfactant additives.
Emulsifier are as follows: take OP-10 1:2 in mass ratio be added Tween-80 mixing to get.
Lubrication activity agent are as follows: take calcium stearate 3:1 in mass ratio that calcium oleate is added, the fat of calcium oleate quality 20% is added
Sour methyl esters polyethers sodium sulfonate is stirred 20min in 30 DEG C, obtains mixture, takes emulsifier 2:10 in mass ratio that deionization is added
Water is stirred 30min in 40 DEG C, obtains mixed liquor, takes mixture 2:10 in mass ratio that mixed liquor is added, is stirred in 90 DEG C
1h is cooled to room temperature to get lubrication activity agent.
Interface cohesion additive the preparation method comprises the following steps: take thermoplastic styrene butadiene rubber SBS4402 1:10 in mass ratio be added two
Toluene is stirred 20min in 20 DEG C, adds the Decanol of xylene mass 50%, and ultrasonic 5min is stirred in 25 DEG C
4h obtains stirring mixture, takes stirring mixture 10:3 in mass ratio that lubrication activity agent is added, in 25 DEG C of standing 30min to get boundary
Face combines additive.
Catalyst are as follows: take tetramethylammonium hydroxide 2:1 in mass ratio be added tetrabutylammonium hydroxide mixing to get.
Anti- water reactive agent the preparation method comprises the following steps:
S1. take lauryl sodium sulfate 2:10 in mass ratio that the ethyl alcohol that mass fraction is 80% is added, it is mixed in 5000r/min stirring
10min is closed, 3 times of lauryl sodium sulfate quality of methyltriethoxysilane is added, adjusts pH to 7, it is mixed in 40 DEG C of stirrings
1h is closed, is filtered, takes and filters slag through deionized water, dehydrated alcohol washing, drying obtains dried object a；
S2. it takes octamethylcy-clotetrasiloxane 2:3 in mass ratio that t etram-ethyltetravinylcyclotetrasiloxane is added, obtains mixture a, lead to
Enter nitrogen protection, the catalyst of mixture a mass 2% be added, is stirred 20min in 80 DEG C, then be warming up to 100 DEG C of heat preservation 3h,
80 DEG C are cooled to, cooled material is obtained, takes cooled material 3:3:10 in mass ratio that containing hydrogen silicone oil, isopropanol is added, adds cooling material
The chloroplatinic acid of amount 1%, in 80 DEG C of heat preservation 2h, rotary evaporation collects rotary evaporation residue 10:2 in mass ratio and dried object a is added
Mixing is to get anti-water reactive agent.
Complexing agent are as follows: take citric acid, succinic acid, oxalic acid by any mass ratio mix to get.
A kind of preparation method of strong concrete interfacial agents, includes the following steps: to take antipollution surfactant additives by matter
It measures and the sodium hydroxide solution that mass fraction is 35% is added than 5:1, be warming up to 95 DEG C and be stirred 1h, be cooled to room temperature, obtain cooling
Object a takes 5 parts of cooled material a, 30 parts of interface cohesion additives, 20 parts of anti-water reactive agents, 2 parts of complexing agents mixed according to the mass fraction
It closes to get strong concrete interfacial agents.
Embodiment 2
Thermoplastic styrene butadiene rubber SBS4402 are as follows: the content of styrene and butadiene ratio is 40:60.
Antipollution surfactant additives the preparation method comprises the following steps:
(1) it takes 4,4- oxydibenzoic acid 90:2 in mass ratio that n,N-Dimethylformamide is added, adds 4,4- diphenyl ether two
The thionyl chloride that 3 times of formic acid quality, 75 DEG C of heating are stirred 4h, are evaporated under reduced pressure, and filtering takes filter cake 4:12 to be in mass ratio added
Petroleum ether stands 35min, takes precipitating drying, obtain dried object, methyl acrylate 6:13 in mass ratio is taken to be added dropwise to 3,3'-, bis- uncle
Butyl -4,4'- diamino-diphenyl -4 " in-tert-butyl benzene methylmethane, is stirred 3h in 75 DEG C, is evaporated under reduced pressure, must depressurize steaming
Evaporate object；
(2) it takes vacuum distillation object 3:7 in mass ratio that chloroform is added, the pyridine of vacuum distillation amount of substance 4% is added, is stirred
25min obtains mixed liquor a, takes dried object 3:7 in mass ratio that chloroform is added, obtains mixed liquor b, take mixed liquor b 4:6 drop in mass ratio
It adds in mixed liquor a, controls time for adding 75min, be stirred 4h in 32 DEG C, filter, take filter residue to wash through deionized water, i.e.,
Obtain antipollution surfactant additives.
Emulsifier are as follows: take OP-10 2:3 in mass ratio be added Tween-80 mixing to get.
Lubrication activity agent are as follows: take calcium stearate 4:2 in mass ratio that calcium oleate is added, the fat of calcium oleate quality 25% is added
Sour methyl esters polyethers sodium sulfonate is stirred 25min in 40 DEG C, obtains mixture, takes emulsifier 3:15 in mass ratio that deionization is added
Water is stirred 35min in 45 DEG C, obtains mixed liquor, takes mixture 4:12 in mass ratio that mixed liquor is added, is stirred in 92 DEG C
2h is cooled to room temperature to get lubrication activity agent.
Interface cohesion additive the preparation method comprises the following steps: take thermoplastic styrene butadiene rubber SBS4402 2:20 in mass ratio be added two
Toluene is stirred 25min in 25 DEG C, adds the Decanol of xylene mass 60%, and ultrasonic 8min is stirred in 27 DEG C
5h obtains stirring mixture, takes stirring mixture 15:4 in mass ratio that lubrication activity agent is added, in 27 DEG C of standing 40min to get boundary
Face combines additive.
Catalyst are as follows: take tetramethylammonium hydroxide 4:2 in mass ratio be added tetrabutylammonium hydroxide mixing to get.
Anti- water reactive agent the preparation method comprises the following steps:
S1. take lauryl sodium sulfate 3:15 in mass ratio that the ethyl alcohol that mass fraction is 80% is added, it is mixed in 5000r/min stirring
15min is closed, 5 times of lauryl sodium sulfate quality of methyltriethoxysilane is added, adjusts pH to 8, it is mixed in 45 DEG C of stirrings
2h is closed, is filtered, takes and filters slag through deionized water, dehydrated alcohol washing, drying obtains dried object a；
S2. it takes octamethylcy-clotetrasiloxane 4:6 in mass ratio that t etram-ethyltetravinylcyclotetrasiloxane is added, obtains mixture a, lead to
Enter nitrogen protection, the catalyst of mixture a mass 4% be added, is stirred 25min in 85 DEG C, then be warming up to 105 DEG C of heat preservation 5h,
83 DEG C are cooled to, cooled material is obtained, takes cooled material 4:5:12 in mass ratio that containing hydrogen silicone oil, isopropanol is added, adds cooling material
The chloroplatinic acid of amount 3%, in 82 DEG C of heat preservation 3h, rotary evaporation collects rotary evaporation residue 12:5 in mass ratio and dried object a is added
Mixing is to get anti-water reactive agent.
Complexing agent are as follows: take oxalic acid, chlorogenic acid, tartaric acid by any mass ratio mix to get.
A kind of preparation method of strong concrete interfacial agents, includes the following steps: to take antipollution surfactant additives by matter
It measures and the sodium hydroxide solution that mass fraction is 35% is added than 8:3, be warming up to 95 DEG C and be stirred 3h, be cooled to room temperature, obtain cooling
Object a takes 7 parts of cooled material a, 40 parts of interface cohesion additives, 25 parts of anti-water reactive agents, 3 parts of complexing agents mixed according to the mass fraction
It closes to get strong concrete interfacial agents.
Embodiment 3
Thermoplastic styrene butadiene rubber SBS4402 are as follows: the content of styrene and butadiene ratio is 40:60.
Antipollution surfactant additives the preparation method comprises the following steps:
(1) it takes 4,4- oxydibenzoic acid 100:3 in mass ratio that n,N-Dimethylformamide is added, adds 4,4- diphenyl ether two
The thionyl chloride that 5 times of formic acid quality, 80 DEG C of heating are stirred 5h, are evaporated under reduced pressure, and filtering takes filter cake 5:15 to be in mass ratio added
Petroleum ether stands 50min, takes precipitating drying, obtain dried object, methyl acrylate 7:15 in mass ratio is taken to be added dropwise to 3,3'-, bis- uncle
Butyl -4,4'- diamino-diphenyl -4 " in-tert-butyl benzene methylmethane, is stirred 4h in 80 DEG C, is evaporated under reduced pressure, must depressurize steaming
Evaporate object；
(2) it takes vacuum distillation object 5:10 in mass ratio that chloroform is added, the pyridine of vacuum distillation amount of substance 5% is added, is stirred
30min obtains mixed liquor a, takes dried object 4:10 in mass ratio that chloroform is added, obtains mixed liquor b, take mixed liquor b 5:8 drop in mass ratio
It adds in mixed liquor a, controls time for adding 90min, be stirred 5h in 35 DEG C, filter, take filter residue to wash through deionized water, i.e.,
Obtain antipollution surfactant additives.
Emulsifier are as follows: take OP-10 3:5 in mass ratio be added Tween-80 mixing to get.
Lubrication activity agent are as follows: take calcium stearate 5:3 in mass ratio that calcium oleate is added, the fat of calcium oleate quality 30% is added
Sour methyl esters polyethers sodium sulfonate is stirred 30min in 50 DEG C, obtains mixture, takes emulsifier 5:20 in mass ratio that deionization is added
Water is stirred 40min in 50 DEG C, obtains mixed liquor, takes mixture 5:15 in mass ratio that mixed liquor is added, is stirred in 95 DEG C
3h is cooled to room temperature to get lubrication activity agent.
Interface cohesion additive the preparation method comprises the following steps: take thermoplastic styrene butadiene rubber SBS4402 3:30 in mass ratio be added two
Toluene is stirred 30min in 30 DEG C, adds the Decanol of xylene mass 70%, and ultrasonic 10min is stirred in 30 DEG C
6h obtains stirring mixture, takes stirring mixture 20:5 in mass ratio that lubrication activity agent is added, in 30 DEG C of standing 50min to get boundary
Face combines additive.
Catalyst are as follows: take tetramethylammonium hydroxide 5:3 in mass ratio be added tetrabutylammonium hydroxide mixing to get.
Anti- water reactive agent the preparation method comprises the following steps:
S1. take lauryl sodium sulfate 5:20 in mass ratio that the ethyl alcohol that mass fraction is 80% is added, it is mixed in 5000r/min stirring
20min is closed, 8 times of lauryl sodium sulfate quality of methyltriethoxysilane is added, adjusts pH to 9, it is mixed in 50 DEG C of stirrings
3h is closed, is filtered, takes and filters slag through deionized water, dehydrated alcohol washing, drying obtains dried object a；
S2. it takes octamethylcy-clotetrasiloxane 5:8 in mass ratio that t etram-ethyltetravinylcyclotetrasiloxane is added, obtains mixture a, lead to
Enter nitrogen protection, the catalyst of mixture a mass 5% be added, is stirred 30min in 90 DEG C, then be warming up to 110 DEG C of heat preservation 6h,
85 DEG C are cooled to, cooled material is obtained, takes cooled material 5:6:15 in mass ratio that containing hydrogen silicone oil, isopropanol is added, adds cooling material
The chloroplatinic acid of amount 5%, in 85 DEG C of heat preservation 4h, rotary evaporation collects rotary evaporation residue 15:8 in mass ratio and dried object a is added
Mixing is to get anti-water reactive agent.
Complexing agent are as follows: take tartaric acid, formic acid, malic acid by any mass ratio mix to get.
A kind of preparation method of strong concrete interfacial agents, includes the following steps: to take antipollution surfactant additives by matter
It measures and the sodium hydroxide solution that mass fraction is 35% is added than 10:4, be warming up to 100 DEG C and be stirred 4h, be cooled to room temperature, obtain cold
But object a takes 10 parts of cooled material a, 50 parts of interface cohesion additives, 30 parts of anti-water reactive agents, 5 parts of complexing agents according to the mass fraction
Mixing is to get strong concrete interfacial agents.
Comparative example 1: it is essentially identical with the preparation method of embodiment 1, it has only the difference is that lacking antipollution surfactant additives.
Comparative example 2: it is essentially identical with the preparation method of embodiment 1, it has only the difference is that lacking interface cohesion additive.
Comparative example 3: it is essentially identical with the preparation method of embodiment 1, it has only the difference is that lacking anti-water reactive agent.
Comparative example 4: it is essentially identical with the preparation method of embodiment 1, it has only the difference is that lacking complexing agent.
Comparative example 5: the strong concrete interfacial agents of Yangzhou company production.
Embodiment is tested with strong concrete interfacial agents obtained by comparative example according to JC/T907-2002 standard,
Test result is as shown in table 1.
Table 1:
In conclusion the strong concrete interfacial agents adhesion strength that the present invention is prepared is preferable, waterproof performance is stronger.It compares
In commercial product, effect is more preferable, is worth promoting.
The foregoing is merely preferred modes of the invention, are not intended to limit the invention, all in spirit and original of the invention
Within then, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.
Claims (9)
1. a kind of strong concrete interfacial agents, which is characterized in that including antipollution surfactant additives, interface cohesion additive,
Anti- water reactive agent, complexing agent.
2. strong concrete interfacial agents according to claim 1, which is characterized in that the antipollution surfactant additives
The preparation method comprises the following steps:
(1) it takes 4,4- oxydibenzoic acid, 80 ~ 100:1 in mass ratio ~ 3 that n,N-Dimethylformamide is added, adds 4,4- bis-
The thionyl chloride of 2 ~ 5 times of phenylate dioctyl phthalate quality is stirred, and is evaporated under reduced pressure, and filtering takes filter cake 2 ~ 5:10 ~ 15 in mass ratio to add
Enter petroleum ether, stands, take precipitating drying, obtain dried object, methyl acrylate 4 ~ 7:10 ~ 15 in mass ratio is taken to be added dropwise to 3,3'- bis-
Tert-butyl -4,4'- diamino-diphenyl -4 " is stirred in-tert-butyl benzene methylmethane, is evaporated under reduced pressure, obtains vacuum distillation object；
(2) it takes vacuum distillation object 2 ~ 5:5 in mass ratio ~ 10 that chloroform is added, the pyridine stirring of vacuum distillation amount of substance 2 ~ 5% is added
Mixing, obtain mixed liquor a, take dried object 1 ~ 4:5 in mass ratio ~ 10 be added chloroform, obtain mixed liquor b, take mixed liquor b in mass ratio 3 ~
5:5 ~ 8 are added dropwise in mixed liquor a, are controlled 60 ~ 90min of time for adding, are stirred, and filter, filter residue is taken to wash through deionized water,
Up to antipollution surfactant additives.
3. strong concrete interfacial agents according to claim 1, which is characterized in that the system of the interface cohesion additive
Preparation Method are as follows: take thermoplastic styrene butadiene rubber SBS4402 1 ~ 3:10 in mass ratio ~ 30 that dimethylbenzene is added and be stirred, add two
The Decanol of toluene quality 50 ~ 70%, ultrasound, is stirred, obtains stirring mixture, takes stirring mixture 10 ~ 20:3 in mass ratio
~ 5 are added lubrication activity agent, stand to get interface cohesion additive.
4. strong concrete interfacial agents according to claim 3, which is characterized in that the lubrication activity agent are as follows: take hard
Calcium oleate is added in resin acid calcium 3 ~ 5:1 in mass ratio ~ 3, and the fatty acid methyl ester polyethers sodium sulfonate that calcium oleate quality 20 ~ 30% is added stirs
Mixing is mixed, mixture is obtained, takes emulsifier 2 ~ 5:10 in mass ratio ~ 20 that deionized water is added and is stirred, obtain mixed liquor, take mixing
Object 2 ~ 5:10 in mass ratio ~ 15 is added mixed liquor and is stirred, and is cooled to room temperature to get lubrication activity agent.
5. strong concrete interfacial agents according to claim 4, which is characterized in that the emulsifier are as follows: take OP-10 by
1 ~ 3:2 of mass ratio ~ 5 be added Tween-80 mixing to get.
6. strong concrete interfacial agents according to claim 1, which is characterized in that the preparation side of the anti-water reactive agent
Method are as follows:
S1. it takes lauryl sodium sulfate 2 ~ 5:10 in mass ratio ~ 20 that ethyl alcohol is added to be stirred, adds lauryl sodium sulfate
The methyltriethoxysilane that 3 ~ 8 times of quality adjusts pH to 7 ~ 9, is stirred, and filters, and takes and filters slag through deionized water, anhydrous
Ethanol washing, it is dry, obtain dried object a；
S2. it takes octamethylcy-clotetrasiloxane 2 ~ 5:3 in mass ratio ~ 8 that t etram-ethyltetravinylcyclotetrasiloxane is added, obtains mixture
A is passed through nitrogen protection, and the catalyst that mixture a mass 2 ~ 5% is added is stirred, then is warming up to 100 ~ 110 DEG C of heat preservations, cold
But, cooled material is obtained, takes cooled material 3 ~ 5:3 in mass ratio ~ 6:10 ~ 15 that containing hydrogen silicone oil, isopropanol is added, adds cooled material quality
1 ~ 5% chloroplatinic acid is kept the temperature, rotary evaporation in 80 ~ 85 DEG C, and it is dry to collect rotary evaporation residue 10 ~ 15:2 in mass ratio ~ 8 addition
Dry object a mixing is to get anti-water reactive agent.
7. strong concrete interfacial agents according to claim 6, which is characterized in that the catalyst in the step S2
Are as follows: take tetramethylammonium hydroxide 2 ~ 5:1 in mass ratio ~ 3 be added tetrabutylammonium hydroxide mixing to get.
8. strong concrete interfacial agents according to claim 1, which is characterized in that the complexing agent are as follows: take citric acid,
Succinic acid, oxalic acid, chlorogenic acid, tartaric acid, formic acid, in malic acid any one or it is any it is several mixed by any mass ratio,
To obtain the final product.
9. a kind of preparation method of the strong concrete interfacial agents as described in claim 1 ~ 8 any one, which is characterized in that
The preparation method includes the following steps: to take antipollution surfactant additives 5 ~ 10:1 in mass ratio ~ 4 that sodium hydroxide solution stirring is added
Mixing, be cooled to room temperature, obtain cooled material a, according to the mass fraction, take 5 ~ 10 parts of cooled material a, 30 ~ 50 parts of interface cohesion additives,
20 ~ 30 parts of anti-water reactive agents, 2 ~ 5 parts of complexing agent mixing are to get strong concrete interfacial agents.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114907772A (en) * | 2022-05-26 | 2022-08-16 | 山东北方现代化学工业有限公司 | Special polyfluorosiloxane demoulding coating for precast concrete member and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101481236A (en) * | 2009-02-12 | 2009-07-15 | 重庆交通大学 | Rapid patching material for cement concrete pavement faulting of slab ends and patching method thereof |
| CN103436117A (en) * | 2013-07-19 | 2013-12-11 | 北京东方雨虹防水技术股份有限公司 | Concrete surfactant and preparation method thereof |
| CN105111932A (en) * | 2015-08-26 | 2015-12-02 | 武汉知睿达新材料有限公司 | Production method of reactive organosilicon waterproofing agent |
| CN108727532A (en) * | 2018-06-29 | 2018-11-02 | 淮安市冰青建设工程管理有限公司 | A kind of preparation method of amination polyester emulsion |
| CN108753161A (en) * | 2018-06-29 | 2018-11-06 | 佛山皖阳生物科技有限公司 | A kind of preparation method of timber special-purpose organic silicon waterproofing agent |
| CN109021778A (en) * | 2018-06-29 | 2018-12-18 | 淮安市冰青建设工程管理有限公司 | A kind of preparation method of high attachment waterborne epoxy coatings |
-
2019
- 2019-02-25 CN CN201910135383.6A patent/CN110003724A/en not_active Withdrawn
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101481236A (en) * | 2009-02-12 | 2009-07-15 | 重庆交通大学 | Rapid patching material for cement concrete pavement faulting of slab ends and patching method thereof |
| CN103436117A (en) * | 2013-07-19 | 2013-12-11 | 北京东方雨虹防水技术股份有限公司 | Concrete surfactant and preparation method thereof |
| CN105111932A (en) * | 2015-08-26 | 2015-12-02 | 武汉知睿达新材料有限公司 | Production method of reactive organosilicon waterproofing agent |
| CN108727532A (en) * | 2018-06-29 | 2018-11-02 | 淮安市冰青建设工程管理有限公司 | A kind of preparation method of amination polyester emulsion |
| CN108753161A (en) * | 2018-06-29 | 2018-11-06 | 佛山皖阳生物科技有限公司 | A kind of preparation method of timber special-purpose organic silicon waterproofing agent |
| CN109021778A (en) * | 2018-06-29 | 2018-12-18 | 淮安市冰青建设工程管理有限公司 | A kind of preparation method of high attachment waterborne epoxy coatings |
Non-Patent Citations (1)
| Title |
|---|
| 仇国全等: "含叔丁基可溶性芳香聚酰胺的制备及其性能研究", 《功能高分子学报》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114907772A (en) * | 2022-05-26 | 2022-08-16 | 山东北方现代化学工业有限公司 | Special polyfluorosiloxane demoulding coating for precast concrete member and preparation method thereof |
| CN114907772B (en) * | 2022-05-26 | 2023-05-23 | 山东北方现代化学工业有限公司 | Special polyfluorosiloxane release coating for precast concrete members and preparation method thereof |
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Application publication date: 20190712 |