CN110002772A - A kind of low-grade magnesite prepares method of magnesium oxide - Google Patents

A kind of low-grade magnesite prepares method of magnesium oxide Download PDF

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Publication number
CN110002772A
CN110002772A CN201910302189.2A CN201910302189A CN110002772A CN 110002772 A CN110002772 A CN 110002772A CN 201910302189 A CN201910302189 A CN 201910302189A CN 110002772 A CN110002772 A CN 110002772A
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low
raw material
magnesite
magnesium oxide
magnetic
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CN110002772B (en
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李伟
高飞
刘立勋
王酉宁
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Dalian Earth Environment Technology Co Ltd
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Dalian Earth Environment Technology Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03BSEPARATING SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS
    • B03B9/00General arrangement of separating plant, e.g. flow sheets
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2/00Lime, magnesia or dolomite
    • C04B2/10Preheating, burning calcining or cooling
    • C04B2/102Preheating, burning calcining or cooling of magnesia, e.g. dead burning

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)

Abstract

The present invention provides a kind of low-grade magnesites to prepare method of magnesium oxide, comprising the following steps: broken classification, calcining, sieve classification, gravity treatment, magnetic separation, mixed calcining.The technique that the present invention uses preparatory calcining-classification-gravity treatment-magnetic separation-to calcine again, first calcines low-grade magnesite, MgCO under cryogenic3Meeting incomplete decomposing generates CO, CO can play the role of reducing gas, weak magnetism mineral in magnesite are reduced to ferromagnetism iron mineral, then it is classified, different gravity treatment and magnetic separation process are chosen according to size fractionated magnesite characteristic, finally again by the magnesite mixed calcining after purification, 98.5% or more the magnesia grade of acquisition, take full advantage of low-grade magnesite, make low-grade magnesite obtain recycling rationally to utilize, resource utilization is improved, land occupation is reduced, there is preferable Social benefit and economic benefit.

Description

A kind of low-grade magnesite prepares method of magnesium oxide
Technical field
The present invention relates to low-grade magnesite technical field of beneficiation, specifically a kind of low-grade magnesite prepares magnesia Method.
Background technique
China's magnesite resource rich reserves, about 3,100,000,000 t of proven reserve, account for a quarter of whole world gross reserves, main It is distributed in Liaoning, two province of Shandong, reserves are total to account for about the 95.11% of national gross reserves, and wherein Liaoning Province is concentrated mainly on Liaoning Southern areas, such as Haicheng City, Yingkou area, proved field has 12, and 25.77 hundred million t of reserves accounts for about national gross reserves 85%, account for the 20% of whole world gross reserves.However the Persisting exploitation and high added value magnesium salts product due to magnesite resource are to former material Expect desired continuous improvement, capable of directly meeting the magnesite (content of magnesia 43%~47.8%) of production requirement, resource is increasingly It is few.Simultaneously because the rough operation of magnesite resource, leads to high-quality resource relative shortage.Even more noteworthy low-grade magnesite A large amount of discarded huge wastes for not only causing resource of mine, and pollute surrounding enviroment.Major impurity in magnesite includes CaO、Al2O3、SiO2、Fe2O3Deng impurity content height will result directly in the reduction of content of MgO in magnesite, and then lead to its derivative The consequences such as quality decline, the increase of production cost and the destruction of ecological environment of product.Purification side about low-grade magnesite Method, industrial at present mainly to use flotation and chemical purification, floatation process equipment investment is big, and process flow is complicated, production cost Height, and need to cause the pollution of environment and the waste of water resource using flotation agent and a large amount of water resource.Chemical purification Process flow is more complicated, and technological parameter is difficult to control, and is difficult to accomplish the zero-emission of chemical agent in production process, and be produced into Therefore this height does not obtain substantive application in the industrial production.
Summary of the invention
The purpose of the present invention is to provide a kind of low-grade magnesites to prepare method of magnesium oxide, to solve above-mentioned background skill The problem of art.
The technical scheme of the present invention is realized as follows:
A kind of low-grade magnesite prepares method of magnesium oxide, comprising the following steps:
(1) magnesite operation after crushing and screening obtains roasting raw material;
(2) step (1) roasting raw material is sent into 30 ~ 40min of calcined by rotary kiln, be then cooled to room temperature;
(3) magnesite after step (2) calcining is broken, then acquisition -6mm raw material, 6 ~ 12mm raw material are classified through the double-deck reciprocating sieve With 12 ~ 20mm raw material;
(4) -6mm raw material is sent into jigging machine progress gravity treatment to sort, the light product of acquisition -6mm and -6mm weight product;
(5) 6 ~ 12mm raw material is sent into shaking table progress gravity treatment to sort, obtains the light product of 6 ~ 12mm and 6 ~ 12mm weight product;
(6) 12 ~ 20mm raw material is sent into jigging machine progress gravity treatment to sort, obtains the light product of 12 ~ 20mm and 12 ~ 20mm weight product;
(7) the light product of step (4) -6mm is sent into magnetic separator progress magnetic separation to sort, acquisition -6mm magnetic concentrate and -6mm magnetic separation tail Mine;
(8) the light product of (5) 6 ~ 12mm of step is sent into magnetic separator progress magnetic separation to sort, obtains 6 ~ 12mm magnetic concentrate and 6 ~ 12mm Magnetic tailing;
(9) step (7) -6mm magnetic tailing and the light product of (6) 12 ~ 20mm of step filtered, dried, moisture is less than 5%, then It is uniformly mixed with (8) 6 ~ 12mm magnetic tailing of step, obtains mixture;
(10) step (9) mixture is sent into 1 ~ 2h of calcined by rotary kiln, then cools to room temperature, obtains magnesium oxide product.
Preferably, step (1) the roasting raw material granularity is less than 20mm.
Preferably, step (2) calcination temperature is 580 DEG C ~ 680 DEG C.
Preferably, step (4) jigging machine is rember vibratory jig, and the pulp density of jigging machine is 20% ~ 25%.
Preferably, step (5) shaking table is air table.
Preferably, step (6) jigging machine is diaphragm jig, and the pulp density of jigging machine is 20% ~ 25%.
Preferably, step (7) magnetic separator is high gradient magnetic separator, and magnetic field strength is 1.2T ~ 1.5T.
Preferably, step (8) magnetic separator is dry-type magnetic extractor, and magnetic field strength is 0.8T ~ 1.0T.
Preferably, step (10) calcination temperature is 750 DEG C ~ 850 DEG C.
The invention has the benefit that
The technique that the present invention uses preparatory calcining-classification-gravity treatment-magnetic separation-to calcine again, first by low-grade magnesite in low temperature item It is calcined under part, MgCO3Meeting incomplete decomposing generates CO, and CO can play the role of reducing gas, by the weak magnetism in magnesite Mineral reduction is ferromagnetism iron mineral, is then classified, different gravity treatment and magnetic are chosen according to size fractionated magnesite characteristic Technique is selected, finally again by the magnesite mixed calcining after purification, 98.5% or more the magnesia grade of acquisition is taken full advantage of low Grade magnesite makes low-grade magnesite obtain recycling and rationally utilizes, and improves resource utilization, reduces land occupation, has preferable Social benefit and economic benefit.
Specific embodiment
Technical solution of the present invention is clearly and completely described below in conjunction with embodiment, it is clear that implement describedly Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common Technical staff's every other embodiment obtained without making creative work belongs to the model that the present invention protects It encloses.
Liaoning low-grade magnesite content of magnesia is 41.08%, SiO2Content is 3.01%, and CaO content is 3.22%, TFe content are 1.25%.
Embodiment 1
A kind of low-grade magnesite prepares method of magnesium oxide, comprising the following steps:
(1) magnesite operation after crushing and screening obtains roasting raw material;
(2) step (1) roasting raw material is sent into calcined by rotary kiln 40min, calcination temperature is 580 DEG C, is then cooled to room temperature;
(3) magnesite after step (2) calcining is broken, then acquisition -6mm raw material, 6 ~ 12mm raw material are classified through the double-deck reciprocating sieve With 12 ~ 20mm raw material;
(4) by -6mm raw material be sent into rember vibratory jig carry out gravity treatment sort, pulp density 20%, the light product of acquisition -6mm and - 6mm weight product;
(5) 6 ~ 12mm raw material is sent into air table progress gravity treatment to sort, obtains the light product of 6 ~ 12mm and 6 ~ 12mm weight product;
(6) 12 ~ 20mm raw material is sent into diaphragm jig progress gravity treatment to sort, pulp density 20% obtains 12 ~ 20mm and gently produces Product and 12 ~ 20mm weight product;
(7) the light product of step (4) -6mm is sent into high gradient magnetic separator progress magnetic separation to sort, magnetic field strength 1.5T, obtain - 6mm magnetic concentrate and -6mm magnetic tailing;
(8) the light product of (5) 6 ~ 12mm of step be sent into dry-type magnetic extractor carry out magnetic separation and sort, magnetic field strength be 1.0T obtain 6 ~ 12mm magnetic concentrate and 6 ~ 12mm magnetic tailing;
(9) step (7) -6mm magnetic tailing and the light product of (6) 12 ~ 20mm of step filtered, dried, moisture is less than 5%, then It is uniformly mixed with (8) 6 ~ 12mm magnetic tailing of step, obtains mixture;
(10) step (9) mixture is sent into calcined by rotary kiln 2h, calcination temperature is 750 DEG C, then cools to room temperature, obtains oxygen Change magnesium products.
It is 98.55% that caustic-calcined magnesite content of magnesia, which is made, in the present embodiment, CaO content 0.30%, SiO2Content is 0.29, TFe content is 0.30%.
Embodiment 2
A kind of low-grade magnesite prepares method of magnesium oxide, comprising the following steps:
(1) magnesite operation after crushing and screening obtains roasting raw material;
(2) step (1) roasting raw material is sent into calcined by rotary kiln 35min, calcination temperature is 630 DEG C, is then cooled to room temperature;
(3) magnesite after step (2) calcining is broken, then acquisition -6mm raw material, 6 ~ 12mm raw material are classified through the double-deck reciprocating sieve With 12 ~ 20mm raw material;
(4) by -6mm raw material be sent into rember vibratory jig carry out gravity treatment sort, pulp density 25%, the light product of acquisition -6mm and - 6mm weight product;
(5) 6 ~ 12mm raw material is sent into air table progress gravity treatment to sort, obtains the light product of 6 ~ 12mm and 6 ~ 12mm weight product;
(6) 12 ~ 20mm raw material is sent into diaphragm jig progress gravity treatment to sort, pulp density 25% obtains 12 ~ 20mm and gently produces Product and 12 ~ 20mm weight product;
(7) the light product of step (4) -6mm is sent into high gradient magnetic separator progress magnetic separation to sort, magnetic field strength 1.3T, obtain - 6mm magnetic concentrate and -6mm magnetic tailing;
(8) the light product of (5) 6 ~ 12mm of step be sent into dry-type magnetic extractor carry out magnetic separation and sort, magnetic field strength be 0.9T obtain 6 ~ 12mm magnetic concentrate and 6 ~ 12mm magnetic tailing;
(9) step (7) -6mm magnetic tailing and the light product of (6) 12 ~ 20mm of step filtered, dried, moisture is less than 5%, then It is uniformly mixed with (8) 6 ~ 12mm magnetic tailing of step, obtains mixture;
(10) step (9) mixture is sent into calcined by rotary kiln 1.5h, calcination temperature is 800 DEG C, then cools to room temperature, obtains Magnesium oxide product.
It is 98.59% that caustic-calcined magnesite content of magnesia, which is made, in the present embodiment, CaO content 0.28%, SiO2Content is 0.27, TFe content is 0.27%.
Embodiment 3
A kind of low-grade magnesite prepares method of magnesium oxide, comprising the following steps:
(1) magnesite operation after crushing and screening obtains roasting raw material;
(2) step (1) roasting raw material is sent into calcined by rotary kiln 30min, calcination temperature is 680 DEG C, is then cooled to room temperature;
(3) magnesite after step (2) calcining is broken, then acquisition -6mm raw material, 6 ~ 12mm raw material are classified through the double-deck reciprocating sieve With 12 ~ 20mm raw material;
(4) by -6mm raw material be sent into rember vibratory jig carry out gravity treatment sort, pulp density 30%, the light product of acquisition -6mm and - 6mm weight product;
(5) 6 ~ 12mm raw material is sent into air table progress gravity treatment to sort, obtains the light product of 6 ~ 12mm and 6 ~ 12mm weight product;
(6) 12 ~ 20mm raw material is sent into diaphragm jig progress gravity treatment to sort, pulp density 30% obtains 12 ~ 20mm and gently produces Product and 12 ~ 20mm weight product;
(7) the light product of step (4) -6mm is sent into high gradient magnetic separator progress magnetic separation to sort, magnetic field strength 1.2T, obtain - 6mm magnetic concentrate and -6mm magnetic tailing;
(8) the light product of (5) 6 ~ 12mm of step be sent into dry-type magnetic extractor carry out magnetic separation and sort, magnetic field strength be 0.8T obtain 6 ~ 12mm magnetic concentrate and 6 ~ 12mm magnetic tailing;
(9) step (7) -6mm magnetic tailing and the light product of (6) 12 ~ 20mm of step filtered, dried, moisture is less than 5%, then It is uniformly mixed with (8) 6 ~ 12mm magnetic tailing of step, obtains mixture;
(10) step (9) mixture is sent into calcined by rotary kiln 1h, calcination temperature is 850 DEG C, then cools to room temperature, obtains oxygen Change magnesium products.
It is 98.63% that caustic-calcined magnesite content of magnesia, which is made, in the present embodiment, CaO content 0.27%, SiO2Content is 0.26, TFe content is 0.25%.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention Within mind and principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.

Claims (8)

1. a kind of low-grade magnesite prepares method of magnesium oxide, comprising the following steps:
(1) magnesite operation after crushing and screening obtains roasting raw material;
(2) step (1) roasting raw material is sent into 30 ~ 40min of calcined by rotary kiln, be then cooled to room temperature;
(3) magnesite after step (2) calcining is broken, then acquisition -6mm raw material, 6 ~ 12mm raw material are classified through the double-deck reciprocating sieve With 12 ~ 20mm raw material;
(4) -6mm raw material is sent into jigging machine progress gravity treatment to sort, the light product of acquisition -6mm and -6mm weight product;
(5) 6 ~ 12mm raw material is sent into shaking table progress gravity treatment to sort, obtains the light product of 6 ~ 12mm and 6 ~ 12mm weight product;
(6) 12 ~ 20mm raw material is sent into jigging machine progress gravity treatment to sort, obtains the light product of 12 ~ 20mm and 12 ~ 20mm weight product;
(7) the light product of step (4) -6mm is sent into magnetic separator progress magnetic separation to sort, acquisition -6mm magnetic concentrate and -6mm magnetic separation tail Mine;
(8) the light product of (5) 6 ~ 12mm of step is sent into magnetic separator progress magnetic separation to sort, obtains 6 ~ 12mm magnetic concentrate and 6 ~ 12mm Magnetic tailing;
(9) step (7) -6mm magnetic tailing and the light product of (6) 12 ~ 20mm of step filtered, dried, moisture is less than 5%, then It is uniformly mixed with (8) 6 ~ 12mm magnetic tailing of step, obtains mixture;
(10) step (9) mixture is sent into 1 ~ 2h of calcined by rotary kiln, then cools to room temperature, obtains magnesium oxide product.
2. a kind of low-grade magnesite according to claim 1 prepares method of magnesium oxide, which is characterized in that the step (1) roasting raw material granularity is less than 20mm.
3. a kind of low-grade magnesite according to claim 1 prepares method of magnesium oxide, which is characterized in that the step (2) calcination temperature is 580 DEG C ~ 680 DEG C.
4. a kind of low-grade magnesite according to claim 1 prepares method of magnesium oxide, which is characterized in that the step (4) jigging machine is rember vibratory jig, and the pulp density of jigging machine is 20% ~ 25%.
5. a kind of low-grade magnesite according to claim 1 prepares method of magnesium oxide, which is characterized in that the step (5) shaking table is air table.
6. a kind of low-grade magnesite according to claim 1 prepares method of magnesium oxide, which is characterized in that the step (6) jigging machine is diaphragm jig, and the pulp density of jigging machine is 20% ~ 25%.
7. a kind of low-grade magnesite according to claim 1 prepares method of magnesium oxide, which is characterized in that the step (7) magnetic separator is high gradient magnetic separator, and magnetic field strength is 1.2T ~ 1.5T.
8. a kind of low-grade magnesite according to claim 1 prepares method of magnesium oxide, which is characterized in that the basis A kind of low-grade magnesite described in claim 1 prepares method of magnesium oxide, which is characterized in that step (10) the calcining temperature Degree is 750 DEG C ~ 850 DEG C.
CN201910302189.2A 2019-04-16 2019-04-16 Method for preparing magnesium oxide from low-grade magnesite Active CN110002772B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110498621A (en) * 2019-09-02 2019-11-26 于景坤 A kind of preparation method of ultra-fine purification concentrate powder magnesite clinker
CN112320826A (en) * 2020-10-29 2021-02-05 刘峰 Method for jointly preparing high-purity magnesium oxide and refined ammonium sulfate by using low-grade magnesite
CN115572080A (en) * 2022-11-09 2023-01-06 营口菱镁化工集团有限公司 Preparation method of feed-grade magnesium oxide

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB380868A (en) * 1931-06-06 1932-09-29 Octave Tagnon Improvements in and relating to the decomposition of magnesium carbonate-containing ores
RU2595120C1 (en) * 2015-06-17 2016-08-20 Общество С Ограниченной Ответственностью "Группа "Магнезит" Method of thermomechanical enrichment of magnesite in indirect heating furnaces

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB380868A (en) * 1931-06-06 1932-09-29 Octave Tagnon Improvements in and relating to the decomposition of magnesium carbonate-containing ores
RU2595120C1 (en) * 2015-06-17 2016-08-20 Общество С Ограниченной Ответственностью "Группа "Магнезит" Method of thermomechanical enrichment of magnesite in indirect heating furnaces

Non-Patent Citations (1)

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Title
邓玉芬等: "菱镁矿阶梯化煅烧制备活性氧化镁", 非金属矿, vol. 40, no. 1, pages 16 - 18 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110498621A (en) * 2019-09-02 2019-11-26 于景坤 A kind of preparation method of ultra-fine purification concentrate powder magnesite clinker
CN110498621B (en) * 2019-09-02 2021-11-05 于景坤 Preparation method of superfine purified concentrate powder sintered magnesia
CN112320826A (en) * 2020-10-29 2021-02-05 刘峰 Method for jointly preparing high-purity magnesium oxide and refined ammonium sulfate by using low-grade magnesite
CN115572080A (en) * 2022-11-09 2023-01-06 营口菱镁化工集团有限公司 Preparation method of feed-grade magnesium oxide
CN115572080B (en) * 2022-11-09 2024-01-16 营口菱镁化工集团有限公司 Preparation method of feed-grade magnesium oxide

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