CN110001264A - A kind of sculpture modelled after an antique does old technology - Google Patents
A kind of sculpture modelled after an antique does old technology Download PDFInfo
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- CN110001264A CN110001264A CN201910366696.2A CN201910366696A CN110001264A CN 110001264 A CN110001264 A CN 110001264A CN 201910366696 A CN201910366696 A CN 201910366696A CN 110001264 A CN110001264 A CN 110001264A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C3/00—Processes, not specifically provided for elsewhere, for producing ornamental structures
- B44C3/06—Sculpturing
Abstract
The present invention relates to statue engraving technology fields, old technology is done more particularly to a kind of sculpture modelled after an antique, the problem of aiming to solve the problem that dyeing in the prior art does that old Wood sculpture color is unnatural, fugitive color, can not embodying antique effect true to nature, technical points are: S1, configuration wood moulding powder；S2, configuration dyeing wood moulding powder；S3, using hot pressing formation process, the dyeing wood moulding powder is mated formation into slab, covers polyester film, steel plate, it is hot-forming, obtain sculpture product；S4, sculpture product pretreatment；S5, upper Lasaxing Oilfield；S6, preservative treatment；S7, configuration maceration extract；S8, using vacuum pressed dipping by the way of, sculpture product is entirely immersed in immersion treatment 1-2h in maceration extract；S9, corona treatment；S10, intensive treatment.The invention enables the dyeing of sculpture product is naturally uniform, not fugitive color, do old effect it is true to nature, naturally, processing deeper into, thoroughly, moreover it is possible to the time for doing old processing is greatly shortened.
Description
Technical field
The present invention relates to statue engraving technology fields, and in particular to a kind of sculpture modelled after an antique does old technology.
Background technique
Sculpture, which refers to, to be moulded, for beautifying city or carve for commemoration meaning with certain implied meaning, symbol or pictograph
Visual article and souvenir.Sculpture is one kind of plastic arts, is also known as carved, and is carving, carves, the general name of three kinds of method for creating of modeling, refers to
With various plastic materials (such as gypsum, resin, clay) or hard material (such as timber, stone, metal, the jade that can carve, can carve
Block, agate, aluminium, glass reinforced plastic, sandstone, copper etc.), visual, the artistic image that can touch with certain space are createed, so as to reflection
Social life, the aesthetic method of art of expression man, Aesthetic Emotion, aesthetic ideal art.Carving substance is reduced by carving, carving
Material, modeling then increase plastic materials and qualities by heap to achieve the purpose that creation of art.
Currently, being directed to the method that Wood sculpture colours, there are mainly two types of: first is that being carried out using colored paint to timber
Surface coloring, this method is applied widely, the coloring of various colors can be carried out to Wood sculpture, however, the carving under this method
It moulds that product color is unnatural, easily eclipsed and discoloration, and there is a problem that at high cost.Second is that after timber is carried out gas fumigation
Its surface layer is coloured, but this method can discharge some toxic gases in operation, cause human safety issues, and
And the depth of coloring, than shallower, the phase will appear the case where leaking color after processing.
Therefore, aging method is done in above two dyeing, and color is unnatural, fugitive color, and it is true to nature can not to embody Wood sculpture
Antique-imitation effect.
Summary of the invention
Therefore, the technical problem to be solved in the present invention is that dyeing in the prior art is overcome to do old Wood sculpture color not
Natural, fugitive color, can not embody the defect of antique effect true to nature, so that providing a kind of sculpture modelled after an antique does old technology.
Above-mentioned technical purpose of the invention has the technical scheme that
A kind of sculpture modelled after an antique does old technology, comprising the following steps:
S1, configuration wood moulding powder: by wood powder by esterification or it is etherification modified after, be placed in high-pressure reaction vessel, steamed using water
Gas carries out explosion, expanding treatment to modified wood powder, is dissolved in organic solvent with thermoplastic polymer monomer therewith, heated to stir
After mixing dispersion cooling, attractant is added and carries out polymerization reaction, and is not much different using with temperature of reaction system in 5 DEG C of water termination
Reaction, is finally distilled to recover solvent, after cooling washing filters drying, obtains wood moulding powder；
S2, configuration dyeing wood moulding powder: water and the wood moulding powder are added in staining jar, while disperse dyes and poly- second are added
Acetoacetic ester emulsion adhesive simultaneously stirs evenly, the heat preservation dyeing 20-40min under normal temperature and pressure or high temperature and pressure, after the completion of dyeing,
Washing drying is filtered, dyeing wood moulding powder is obtained；
S3, plastotype: using hot pressing formation process, the dyeing wood moulding powder mated formation into slab, covers polyester film, steel plate, heat
It is molded, obtain sculpture product；
S4, sculpture product pretreatment: white spirit pit mud plus water are configured to the white spirit pit mud solution that weight ratio is 25%, and will
Sculpture product to be processed is immersed at least 30min in white spirit pit mud solution, after then being cleaned using 5% sodium bicarbonate solution
It carries out drying processing, when its surface water content in 50%-60%, puts it into and store 15min in freezer, dried after taking-up
Dry-cure, until sculpture product surface ice crystal evaporating completely；
S5, upper Lasaxing Oilfield: needing to do former subordinates point to the sculpture product and wax, and room temperature is stood until wax is frozen into
Type；
S6, preservative treatment: the remainder of the sculpture product is smeared into preservative, sculpture product is done into former subordinates therewith
Divide and carry out paraffin removal, so that sculpture product surface can be in contact with air；
S7, configuration maceration extract: 3-5 parts of orange peel, 2-4 parts of ramulus mori, 0.8-1.5 parts of sodium carboxymethylcelluloses, 1-2 parts of pyrosulfuric acids
Sodium, 0.5-0.8 part ammonium chloride, 0.8-1.5 parts of polyvinyl alcohol, 160-180 parts of water；
S8, dipping: by the way of vacuum pressed dipping, timber is entirely immersed in the maceration extract of step S7 configuration and is soaked
Bubble processing 1-2h；
S9, corona treatment: putting 2-3h for sculpture product in step S8 is quiet at high temperature, then utilizes atmosphere medium
The low temperature plasma that barrier discharge generates is handled；
S10, intensive treatment: being impregnated sculpture product 2-13h using aqueous solution of urea, cleaned up after pulling out using clear water,
And place 2-3 angel its naturally dry to water content lower than 15% hereinafter,.
Optionally, in the step S1, the thermoplastic polymer monomer is styrene, acrylonitrile, acrylic acid, third
One or more of combination in e pioic acid methyl ester, methyl methacrylate.
Optionally, in the step S1, the organic solvent is chloroform, methylene chloride, hexamethylene, acrylonitrile, first
Benzene, dimethylbenzene, combination one or more of in N,N-dimethylformamide.
Optionally, in the step S2, water and the wood moulding powder, bath raio 10-200:1, dye are added in staining jar
Liquid pH value is 3.0-5.0；Dyeing temperature is 60-140 DEG C, time 20-240min, disperse dyes and wood moulding powder mass ratio
For 1:20-500, disperse dyes are azo, Anthraquinones or heterocyclic dyestuff.
Optionally, in the step S6, after preservative treatment, to sculpture product do it is old after rest part wax
Processing, the upper Lasaxing Oilfield use high melting-point wax.
Optionally, in the step S6, after paraffin removal is processed, former subordinates point coating attractant is done to sculpture product, it is described
Attractant is combination one or more in fulvic acid, lignin and humus.
Optionally, in the step S7, orange peel and ramulus mori be crushed into 100 mesh jointly, is then gone with 3 times of its gross mass
Ionized water mixes jointly, heating boiling boil 25min after, filter extract filtrate it is spare, then by sodium carboxymethylcellulose, pyrosulfuric acid
Gained after mixing, is extracted filtrate and is added, is again stirring for uniformly, and adjust molten by sodium, ammonium chloride, polyvinyl alcohol and water jointly
The pH value of liquid entirety is 5.6-6.2, obtains maceration extract.
Optionally, in the step S8, sculpture product is placed in vacuum pressure impregnation tank, is vacuumized, vacuum degree is worked as
After reaching -0.2 to -0.1MPa, 15min is kept, the configured maceration extract is then rapidly injected, continues to keep 40min, this
After be forced into 0.1-0.5MPa, keep 50min, slowly release internal pressure, maceration extract is extracted out, the timber after taking out dipping.
Optionally, in the step S9, the time of the Low Temperature Plasma Treating timber is 16-18s, and dielectric impedance is put
The power supply of electricity is high-frequency and high-voltage power supply, frequency 2kHz-2.4kHz, voltage range 3kV-3.4kV.
Optionally, in the step S10, the mass concentration of the aqueous solution of urea is 1.4%, by sculpture product at 46 DEG C
Lower immersion 12-13h, is cleaned up after pulling out with clear water, quiet under conditions of 10 DEG C, relative air humidity are 40% to put 2-3 days,
It is set to naturally dry to water content lower than 15% or less.
Technical solution of the present invention has the advantages that
1. sculpture of the invention does old technology, the wood powder of etherificate or esterification modification is subjected to high-temperature high-pressure steam processing
Afterwards, in conjunction with in-situ polymerization, a kind of wood moulding powder that particle uniformly, without plastics is reunited is obtained, disperse dyes can be further used
Colored wood moulding powder is made in dyeing, these dyeing wood moulding powder can be applied to the bright and beautiful sculpture product of preparation uniform in color, coloured light；Separately
Outside, modified wood powder is made to obtain abundant, bigger pore structure, herein modified wood powder processing by high-temperature high-pressure steam
On the basis of combine the polymerization that gradually heats up, pass through the polymer generated and run through, is the transitional pore that is filled in modified wood powder, micro-
In hole or pit, and it is wrapped in modified wood powder surface, to form structure uniformly perfect organic combination.
2. sculpture of the invention does old technology, used and the very similar hot water of temperature of reaction system when polymerization reaction terminates
Reaction is terminated, the polymer for being effectively prevented generation contracts on cooling suddenly, falls off and reunite, ensure that between wood powder and polymer
It is firmly combined, and modified wood powder and thermoplastic polymer monomer is placed in organic solvent under the appropriate temperature conditions, make
Polymerized monomer is fully infiltrated into the pore structure of modified wood powder, is conducive to the progress of home position polymerization reaction, it is ensured that sculpture product color
Nature, not fugitive color.
3. sculpture of the invention does old technology, pre-processed using white spirit pit mud liquid, it is abundant due to containing in pit mud liquid
Microorganism, sculpture product surface is handled by microorganism, processing method is simple, after processing sculpted surface uniformly from
So, and it is less to wood surface injury, the faint scent of timber can be increased, improve simple and unsophisticated sense.
4. sculpture of the invention does old technology, sculpture product after pretreatment needs it to do old part using mold into
Lasaxing Oilfield on row makes it do former subordinates position and is coated with Chinese wax block, then to remaining position brushing preservative of timber, due to upper wax excessively
Reason, preservative, which will not be applied to, does former subordinates position, and the rest part for not doing Lasaxing Oilfield can be to subsequent after absorbing preservative
Maceration extract plays the role of anti-oxidation, etch-proof, realizes and do to timber privileged site the effect of old processing；Sculpture product
It does former subordinates point or because being coated with preservative on adjacent rest part, will affect erosion of the maceration extract to former subordinates point is done, therefore
The rest part of sculpture product does Lasaxing Oilfield again, and realization preservative is isolated with maceration extract, and then preservative will not interfere shadow
Sound does old effect；In conjunction with aforementioned schemes, if upper Lasaxing Oilfield directly is carried out in rest part, then can without coating preservative
There is a situation where maceration extracts, and seriously corroded occurs in the junction for doing former subordinates point and rest part；High melting-point wax is used simultaneously, is melted
Point is higher than the wax in previous step, to can dissolve the wax for doing former subordinates point under the certain temperature in paraffin removal treatment process
Removal.
5. sculpture of the invention does old technology, former subordinates is done to sculpture product and divides brushing attractant, had using attractant and draw
The characteristics of luring can induce in maceration extract microorganism to be intended to close and be attached to and do former subordinates doing former subordinates point and smearing attractant
Point, to realize that the former subordinates of doing of timber in a short time is just being damaged by corrosion respectively, reach the aesthetic feeling of ancient grey mulberry, improves product
Surcharge.
6. sculpture of the invention does old technology, maceration extract ingredient is simple, safe and nontoxic, noresidue, and solution is integrally in slightly sour
Property, improve strong acid and easily cause the obvious problem of etching phenomenon, under the action of vacuum pressed dipping technique, do old rate with
Effect is greatly improved, while having the advantages that quickly to penetrate into lumber fibre and not influencing wood internal structure intensity, thus
Effectively old degree is done in control, and old treatment effect is done in promotion.
7. sculpture of the invention does old technology, using Low Temperature Plasma Treating timber, and the time is controlled at 16 to 18 seconds
Between, uniform, continuous old trace can be formed on sculpture product surface, use for a long time will not fade.
8. sculpture of the invention does old technology, temperature intensive treatment is carried out to sculpture product, it is water-soluble to place it in urea
It is impregnated in liquid, on the one hand can improve the old effect of doing of abovementioned steps, on the other hand improve and do old stability, play reparation timber
Effect, to prevent the erosion of moth.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, with reference to embodiments, to the present invention
It is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to
Limit the present invention.
Embodiment 1:
A kind of sculpture modelled after an antique does old technology, comprising the following steps:
S1, configuration wood moulding powder: log powder or degreasing wood powder are used into acetic anhydride, propionic andydride, phthalic anhydride or Malaysia
Acid anhydrides carries out esterification treatment, or carries out etherification process using benzyl chloride, acrylonitrile, dithyl sulfate or epoxychloropropane, with
The hydrophilic radicals such as the hydroxyl in timber are closed to improve the hydrophobicity of timber, are subsequently placed in sealing high-pressure reaction vessel,
At 100 DEG C maintain pressure 1MPa, using vapor to modified wood powder carry out explosion, expanding treatment 120-200min, therewith with heat
Thermoplastic plastic polymerized monomer is (styrene, acrylonitrile, acrylic acid, methyl acrylate, one or more of in methyl methacrylate
Combination) it is dissolved in organic solvent (chloroform, methylene chloride, hexamethylene, acrylonitrile, toluene, dimethylbenzene, N, N- dimethyl formyl
One or more of combination in amine) in, it is heated be dispersed with stirring it is cooling after, be added peroxide attractant polymerize it is anti-
It answers, and react using being not much different with temperature of reaction system in 5 DEG C of water termination, be finally distilled to recover solvent, washed through cooling
After filtering drying, wood moulding powder is obtained；
Wherein, the condition of polymerization reaction refers under the conditions of the temperature never more than 40 DEG C with the heating of 0.5-2.0 DEG C/min
Rate is warming up to 50-80 DEG C, isothermal reaction 20-240min, the temperature in this embodiment of the invention, preferably never more than 40 DEG C
It is warming up to 50-70 DEG C with the heating rate of 0.5-1.0 DEG C/min under the conditions of degree, isothermal reaction 60-180min；
S2, configuration dyeing wood moulding powder: water and the wood moulding powder are added in staining jar, while disperse dyes and poly- second are added
Acetoacetic ester emulsion adhesive simultaneously stirs evenly, the heat preservation dyeing 20-40min under normal temperature and pressure or high temperature and pressure, after the completion of dyeing,
Washing drying is filtered, dyeing wood moulding powder is obtained；
Wherein, dyeing condition is water and wood moulding powder bath raio is 100:1, and dye liquor pH value 3.0, dyeing temperature is 80 DEG C, when
Between be 60min, make dye wood moulding powder have the effect of that uniform in color, coloured light are bright and beautiful；And poly- ethyl acetate emulsion adhesive helps
In color is attached to wood moulding powder surface；
S3, plastotype: using hot pressing formation process, the dyeing wood moulding powder mated formation into slab, covers polyester film, steel plate, heat
It is molded, obtain sculpture product；
S4, sculpture product pretreatment: white spirit pit mud plus water are configured to the white spirit pit mud solution that weight ratio is 25%, and will
Sculpture product to be processed is immersed at least 30min in white spirit pit mud solution, after then being cleaned using 5% sodium bicarbonate solution
It carries out drying processing, when its surface water content in 50%-60%, puts it into and store 15min in freezer, dried after taking-up
Dry-cure, until sculpture product surface ice crystal evaporating completely can increase so that white spirit pit mud solution is small to the corrosivity of timber
The faint scent for adding timber improves simple and unsophisticated sense；
S5, upper Lasaxing Oilfield: having effigurate mold frame using round and rectangle etc. and be fitted in sculpture product surface,
And using having the mud of viscosity to echo at the gap of mold frame and wood surface, the sculpture surrounded by mold frame is defined
Product, which is divided into, does former subordinates point, i.e., implements to do old processing to the part for demand, melt to pour into timber mold frame
Liquid state Chinese wax after change, and back and forth scraped using scraper plate and stopped afterwards for several times is stood and is completely solidified into type to Chinese wax to complete pair
Do the waxing of former subordinates point；
S6, preservative treatment: the remainder of sculpture product is smeared into preservative, quaternary ammonium salt is used in inventing this embodiment
As preservative, the former subordinates point of doing of sculpture product is subjected to paraffin removal therewith, i.e., sculpture product is put under the conditions of 60 DEG C -70 DEG C
High temperature bucket in 40-60min, the former subordinates of doing of final timber is removed in Chinese wax respectively, and sculpture product surface is exposed to
In air；
S7, configuration maceration extract: 3 parts of orange peel, 2 parts of ramulus mori, 0.8 part of sodium carboxymethylcellulose, 1.5 parts of sodium pyrosulfates, 0.5 part
Ammonium chloride, 0.8 part of polyvinyl alcohol, 160 parts of water；
Wherein, orange peel and ramulus mori be crushed into 100 mesh jointly, then mixed jointly with 3 times of its gross mass of deionized water,
Heating boiling boil 25min after, filter extract filtrate it is spare, then by sodium carboxymethylcellulose, sodium pyrosulfate, ammonium chloride, poly- second
Gained after mixing, is extracted filtrate and is added, is again stirring for uniformly, and the pH value for adjusting solution entirety is by enol and water jointly
5.6-6.2 obtaining maceration extract；
S8, dipping: sculpture product being placed in vacuum pressure impregnation tank, is vacuumized, when vacuum degree reach -0.2 to -
After 0.1MPa, 15min is kept, the configured maceration extract is then rapidly injected, continued to keep 40min, hereafter be forced into
0.1-0.5MPa keeps 50min, slowly releases internal pressure, maceration extract is extracted out, the timber after taking out dipping；
S9, corona treatment: putting 2-3h for sculpture product in step S8 is quiet at high temperature, then utilizes atmosphere medium
The low temperature plasma that barrier discharge generates is handled；
Wherein, the time of Low Temperature Plasma Treating timber is 16-18s, and the power supply of dielectric barrier discharge is high-frequency and high-voltage
Power supply, frequency 2kHz-2.4kHz, voltage range 3kV-3.4kV；
S10, intensive treatment: sculpture product 12-13h is impregnated using the aqueous solution of urea that mass concentration is 1.4%, after pulling out
Cleaned up using clear water, and 10 DEG C, relative air humidity be 40% under conditions of place 2-3 angel it naturally dry to and contains
Water be lower than 15% hereinafter,.
Embodiment 1:
A kind of sculpture modelled after an antique does old technology, comprising the following steps:
S1, configuration wood moulding powder: log powder or degreasing wood powder are used into acetic anhydride, propionic andydride, phthalic anhydride or Malaysia
Acid anhydrides carries out esterification treatment, or carries out etherification process using benzyl chloride, acrylonitrile, dithyl sulfate or epoxychloropropane, with
The hydrophilic radicals such as the hydroxyl in timber are closed to improve the hydrophobicity of timber, are subsequently placed in sealing high-pressure reaction vessel,
At 180 DEG C maintain pressure 8MPa, using vapor to modified wood powder carry out explosion, expanding treatment 180-240min, therewith with heat
Thermoplastic plastic polymerized monomer is (styrene, acrylonitrile, acrylic acid, methyl acrylate, one or more of in methyl methacrylate
Combination) it is dissolved in organic solvent (chloroform, methylene chloride, hexamethylene, acrylonitrile, toluene, dimethylbenzene, N, N- dimethyl formyl
One or more of combination in amine) in, it is heated be dispersed with stirring it is cooling after, be added peroxide attractant polymerize it is anti-
It answers, and react using being not much different with temperature of reaction system in 5 DEG C of water termination, be finally distilled to recover solvent, washed through cooling
After filtering drying, wood moulding powder is obtained；
Wherein, the condition of polymerization reaction refers under the conditions of the temperature never more than 40 DEG C with the heating of 0.5-2.0 DEG C/min
Rate is warming up to 50-60 DEG C, isothermal reaction 10-120min, then increases temperature 10-20 with the heating rate of 0.5-2.0 DEG C/min
DEG C, further 10~120min of isothermal reaction；
S2, configuration dyeing wood moulding powder: water and the wood moulding powder are added in staining jar, while disperse dyes and poly- second are added
Acetoacetic ester emulsion adhesive simultaneously stirs evenly, the heat preservation dyeing 20-40min under normal temperature and pressure or high temperature and pressure, after the completion of dyeing,
Washing drying is filtered, dyeing wood moulding powder is obtained；
Wherein, dyeing condition is water and wood moulding powder bath raio is 200:1, and dye liquor pH value 5.0, dyeing temperature is 120 DEG C, when
Between be 200min, make dye wood moulding powder have the effect of that uniform in color, coloured light are bright and beautiful；And poly- ethyl acetate emulsion adhesive helps
In color is attached to wood moulding powder surface；
S3, plastotype: using hot pressing formation process, the dyeing wood moulding powder mated formation into slab, covers polyester film, steel plate, heat
It is molded, obtain sculpture product；
S4, sculpture product pretreatment: white spirit pit mud plus water are configured to the white spirit pit mud solution that weight ratio is 25%, and will
Sculpture product to be processed is immersed at least 30min in white spirit pit mud solution, after then being cleaned using 5% sodium bicarbonate solution
It carries out drying processing, when its surface water content in 50%-60%, puts it into and store 15min in freezer, dried after taking-up
Dry-cure, until sculpture product surface ice crystal evaporating completely can increase so that white spirit pit mud solution is small to the corrosivity of timber
The faint scent for adding timber improves simple and unsophisticated sense；
S5, upper Lasaxing Oilfield: having effigurate mold frame using round and rectangle etc. and be fitted in sculpture product surface,
And using having the mud of viscosity to echo at the gap of mold frame and wood surface, the sculpture surrounded by mold frame is defined
Product, which is divided into, does former subordinates point, i.e., implements to do old processing to the part for demand, melt to pour into timber mold frame
Liquid state Chinese wax after change, and back and forth scraped using scraper plate and stopped afterwards for several times is stood and is completely solidified into type to Chinese wax to complete pair
Do the waxing of former subordinates point；
S6, preservative treatment: the remainder of sculpture product is smeared into preservative, quaternary ammonium salt is used in inventing this embodiment
Upper Lasaxing Oilfield is carried out as preservative, and in the part that sculpture product smears preservative, upper Lasaxing Oilfield uses polyethylene wax etc.
High melting-point wax；
The former subordinates point of doing of sculpture product is subjected to paraffin removal, i.e., the high temperature being put into sculpture product under the conditions of 60 DEG C -70 DEG C
40-60min in bucket, the former subordinates of doing of final timber are removed in Chinese wax respectively, and sculpture product face is exposed in air, then
Former subordinates point coating attractant is done to sculpture product, does former subordinates point coating fulvic acid, lignin in sculpture product using brush；
S7, configuration maceration extract: 5 parts of orange peel, 4 parts of ramulus mori, 1.5 parts of sodium carboxymethylcelluloses, 2 parts of sodium pyrosulfates, 0.8 part of chlorine
Change ammonium, 1.5 parts of polyvinyl alcohol, 180 parts of water；
Wherein, orange peel and ramulus mori be crushed into 100 mesh jointly, then mixed jointly with 3 times of its gross mass of deionized water,
Heating boiling boil 25min after, filter extract filtrate it is spare, then by sodium carboxymethylcellulose, sodium pyrosulfate, ammonium chloride, poly- second
Gained after mixing, is extracted filtrate and is added, is again stirring for uniformly, and the pH value for adjusting solution entirety is by enol and water jointly
5.6-6.2 obtaining maceration extract；
S8, dipping: sculpture product being placed in vacuum pressure impregnation tank, is vacuumized, when vacuum degree reach -0.2 to -
After 0.1MPa, 15min is kept, the configured maceration extract is then rapidly injected, continued to keep 40min, hereafter be forced into
0.1-0.5MPa keeps 50min, slowly releases internal pressure, maceration extract is extracted out, the timber after taking out dipping；
S9, corona treatment: putting 2-3h for sculpture product in step S8 is quiet at high temperature, then utilizes atmosphere medium
The low temperature plasma that barrier discharge generates is handled；
Wherein, the time of Low Temperature Plasma Treating timber is 16-18s, and the power supply of dielectric barrier discharge is high-frequency and high-voltage
Power supply, frequency 2kHz-2.4kHz, voltage range 3kV-3.4kV；
S10, intensive treatment: sculpture product 12-13h is impregnated using the aqueous solution of urea that mass concentration is 1.4%, after pulling out
Cleaned up using clear water, and 10 DEG C, relative air humidity be 40% under conditions of place 2-3 angel it naturally dry to and contains
Water be lower than 15% hereinafter,.
Embodiment 3:
A kind of sculpture modelled after an antique does old technology, comprising the following steps:
S1, configuration wood moulding powder: log powder or degreasing wood powder are used into acetic anhydride, propionic andydride, phthalic anhydride or Malaysia
Acid anhydrides carries out esterification treatment, or carries out etherification process using benzyl chloride, acrylonitrile, dithyl sulfate or epoxychloropropane, with
The hydrophilic radicals such as the hydroxyl in timber are closed to improve the hydrophobicity of timber, are subsequently placed in sealing high-pressure reaction vessel,
At 140 DEG C maintain pressure 4MPa, using vapor to modified wood powder carry out explosion, expanding treatment 180-240min, therewith with heat
Thermoplastic plastic polymerized monomer is (styrene, acrylonitrile, acrylic acid, methyl acrylate, one or more of in methyl methacrylate
Combination) it is dissolved in organic solvent (chloroform, methylene chloride, hexamethylene, acrylonitrile, toluene, dimethylbenzene, N, N- dimethyl formyl
One or more of combination in amine) in, it is heated be dispersed with stirring it is cooling after, be added peroxide attractant polymerize it is anti-
It answers, and react using being not much different with temperature of reaction system in 5 DEG C of water termination, be finally distilled to recover solvent, washed through cooling
After filtering drying, wood moulding powder is obtained；
Wherein, the condition of polymerization reaction refers under the conditions of the temperature never more than 40 DEG C with the heating of 0.5-2.0 DEG C/min
Rate is warming up to 50-60 DEG C, isothermal reaction 10-60min, then continues to increase temperature 5- with the heating rate of 0.5-2.0 DEG C/min
10 DEG C, after isothermal reaction 10-60min, 5-10 DEG C of temperature is further then increased with the heating rate of 0.5-2.0 DEG C/min, it is permanent
Temperature reaction 10-60min
S2, configuration dyeing wood moulding powder: water and the wood moulding powder are added in staining jar, while disperse dyes and poly- second are added
Acetoacetic ester emulsion adhesive simultaneously stirs evenly, the heat preservation dyeing 20-40min under normal temperature and pressure or high temperature and pressure, after the completion of dyeing,
Washing drying is filtered, dyeing wood moulding powder is obtained；
Wherein, dyeing condition is water and wood moulding powder bath raio is 100:1, and dye liquor pH value 4.0, dyeing temperature is 100 DEG C, when
Between be 160min, make dye wood moulding powder have the effect of that uniform in color, coloured light are bright and beautiful；And poly- ethyl acetate emulsion adhesive helps
In color is attached to wood moulding powder surface；
S3, plastotype: using hot pressing formation process, the dyeing wood moulding powder mated formation into slab, covers polyester film, steel plate, heat
It is molded, obtain sculpture product；
S4, sculpture product pretreatment: white spirit pit mud plus water are configured to the white spirit pit mud solution that weight ratio is 25%, and will
Sculpture product to be processed is immersed at least 30min in white spirit pit mud solution, after then being cleaned using 5% sodium bicarbonate solution
It carries out drying processing, when its surface water content in 50%-60%, puts it into and store 15min in freezer, dried after taking-up
Dry-cure, until sculpture product surface ice crystal evaporating completely can increase so that white spirit pit mud solution is small to the corrosivity of timber
The faint scent for adding timber improves simple and unsophisticated sense；
S5, upper Lasaxing Oilfield: having effigurate mold frame using round and rectangle etc. and be fitted in sculpture product surface,
And using having the mud of viscosity to echo at the gap of mold frame and wood surface, the sculpture surrounded by mold frame is defined
Product, which is divided into, does former subordinates point, i.e., implements to do old processing to the part for demand, melt to pour into timber mold frame
Liquid state Chinese wax after change, and back and forth scraped using scraper plate and stopped afterwards for several times is stood and is completely solidified into type to Chinese wax to complete pair
Do the waxing of former subordinates point；
S6, preservative treatment: the remainder of sculpture product is smeared into preservative, quaternary ammonium salt is used in inventing this embodiment
Upper Lasaxing Oilfield is carried out as preservative, and in the part that sculpture product smears preservative, upper Lasaxing Oilfield uses polyethylene wax etc.
High melting-point wax；
The former subordinates point of doing of sculpture product is subjected to paraffin removal, i.e., the high temperature being put into sculpture product under the conditions of 60 DEG C -70 DEG C
40-60min in bucket, the former subordinates of doing of final timber are removed in Chinese wax respectively, and sculpture product face is exposed in air, then
Former subordinates point coating attractant is done to sculpture product, does former subordinates point coating fulvic acid, lignin in sculpture product using brush；
S7, configuration maceration extract: 4 parts of orange peel, 3 parts of ramulus mori, 1 part of sodium carboxymethylcellulose, 1.5 parts of sodium pyrosulfates, 0.6 part of chlorine
Change ammonium, 1 part of polyvinyl alcohol, 170 parts of water；
Wherein, orange peel and ramulus mori be crushed into 100 mesh jointly, then mixed jointly with 3 times of its gross mass of deionized water,
Heating boiling boil 25min after, filter extract filtrate it is spare, then by sodium carboxymethylcellulose, sodium pyrosulfate, ammonium chloride, poly- second
Gained after mixing, is extracted filtrate and is added, is again stirring for uniformly, and the pH value for adjusting solution entirety is by enol and water jointly
5.6-6.2 obtaining maceration extract；
S8, dipping: sculpture product being placed in vacuum pressure impregnation tank, is vacuumized, when vacuum degree reach -0.2 to -
After 0.1MPa, 15min is kept, the configured maceration extract is then rapidly injected, continued to keep 40min, hereafter be forced into
0.1-0.5MPa keeps 50min, slowly releases internal pressure, maceration extract is extracted out, the timber after taking out dipping；
S9, corona treatment: putting 2-3h for sculpture product in step S8 is quiet at high temperature, then utilizes atmosphere medium
The low temperature plasma that barrier discharge generates is handled；
Wherein, the time of Low Temperature Plasma Treating timber is 16-18s, and the power supply of dielectric barrier discharge is high-frequency and high-voltage
Power supply, frequency 2kHz-2.4kHz, voltage range 3kV-3.4kV；
S10, intensive treatment: sculpture product 12-13h is impregnated using the aqueous solution of urea that mass concentration is 1.4%, after pulling out
Cleaned up using clear water, and 10 DEG C, relative air humidity be 40% under conditions of place 2-3 angel it naturally dry to and contains
Water be lower than 15% hereinafter,.
Obviously, the above embodiments are merely examples for clarifying the description, and does not limit the embodiments.It is right
For those of ordinary skill in the art, can also make on the basis of the above description it is other it is various forms of variation or
It changes.There is no necessity and possibility to exhaust all the enbodiments.And it is extended from this it is obvious variation or
It changes still within the protection scope of the invention.
Claims (10)
1. a kind of sculpture modelled after an antique does old technology, which comprises the following steps:
S1, configuration wood moulding powder: by wood powder by esterification or it is etherification modified after, be placed in high-pressure reaction vessel, utilize vapor pair
Modified wood powder carries out explosion, expanding treatment, is dissolved in organic solvent with thermoplastic polymer monomer therewith, heated stirring point
After cold scattering but, attractant is added and carries out polymerization reaction, and using be not much different with temperature of reaction system terminated in 5 DEG C of water it is anti-
It answers, is finally distilled to recover solvent, after cooling washing filters drying, obtain wood moulding powder；
S2, configuration dyeing wood moulding powder: water and the wood moulding powder are added in staining jar, while disperse dyes and poly- acetic acid second are added
Ester emulsion adhesive simultaneously stirs evenly, the heat preservation dyeing 20-40min under normal temperature and pressure or high temperature and pressure, after the completion of dyeing, through taking out
Drainage washes drying, obtains dyeing wood moulding powder；
S3, plastotype: hot pressing formation process is used, the dyeing wood moulding powder is mated formation into slab, polyester film, steel plate is covered, is hot pressed into
Type obtains sculpture product；
S4, sculpture product pretreatment: white spirit pit mud plus water are configured to the white spirit pit mud solution that weight ratio is 25%, and will be wait locate
The sculpture product of reason is immersed at least 30min in white spirit pit mud solution, carries out after then being cleaned using 5% sodium bicarbonate solution
Processing is dried, when its surface water content in 50%-60%, puts it into and stores 15min in freezer, carried out at drying after taking-up
Reason, until sculpture product surface ice crystal evaporating completely；
S5, upper Lasaxing Oilfield: it needs to do former subordinates point to the sculpture product and waxes, and room temperature is stood until wax coagulation forming；
S6, preservative treatment: smearing preservative for the remainder of the sculpture product, therewith by sculpture product do former subordinates point into
Row paraffin removal, so that sculpture product surface can be in contact with air；
S7, configuration maceration extract: 3-5 parts of orange peel, 2-4 parts of ramulus mori, 0.8-1.5 parts of sodium carboxymethylcelluloses, 1-2 parts of sodium pyrosulfates,
0.5-0.8 parts of ammonium chlorides, 0.8-1.5 parts of polyvinyl alcohol, 160-180 parts of water；
S8, dipping: by the way of vacuum pressed dipping, timber is entirely immersed in the maceration extract of step S7 configuration at immersion
Manage 1-2h；
S9, corona treatment: putting 2-3h for sculpture product in step S8 is quiet at high temperature, is then stopped using atmosphere medium
The low temperature plasma that electric discharge generates is handled；
S10, intensive treatment: sculpture product 2-13h is impregnated using aqueous solution of urea, is cleaned up after pulling out using clear water, and put
Set 2-3 angel its naturally dry to water content lower than 15% hereinafter,.
2. a kind of sculpture modelled after an antique according to claim 1 does old technology, which is characterized in that in the step S1, the heat
Thermoplastic plastic polymer monomer is styrene, acrylonitrile, acrylic acid, methyl acrylate, a kind of or several in methyl methacrylate
The combination of kind.
3. a kind of sculpture modelled after an antique according to claim 2 does old technology, which is characterized in that described to have in the step S1
Solvent be chloroform, methylene chloride, hexamethylene, acrylonitrile, toluene, dimethylbenzene, it is a kind of in N,N-dimethylformamide or
Several combinations.
4. a kind of sculpture modelled after an antique according to claim 1 does old technology, which is characterized in that in the step S2, dyeing
Water and the wood moulding powder, bath raio 10-200:1, dye liquor pH value 3.0-5.0 are added in cylinder；Dyeing temperature is 60-140
DEG C, time 20-240min, disperse dyes and wood moulding powder mass ratio are 1:20-500, and disperse dyes are azo, Anthraquinones
Or heterocyclic dyestuff.
5. a kind of sculpture modelled after an antique according to claim 1 does old technology, which is characterized in that in the step S6, in anti-corrosion
After processed, to sculpture product do it is old after rest part carry out upper Lasaxing Oilfield, the upper Lasaxing Oilfield uses high melting-point wax.
6. a kind of sculpture modelled after an antique according to claim 5 does old technology, which is characterized in that in the step S6, in paraffin removal
After processed, former subordinates point coating attractant is done to sculpture product, the attractant is a kind of in fulvic acid, lignin and humus
Or a variety of combination.
7. a kind of sculpture modelled after an antique according to claim 1 does old technology, which is characterized in that in the step S7, by orange peel
It crushed 100 mesh jointly with ramulus mori, then mixed jointly with 3 times of its gross mass of deionized water, after 25min is boiled in heating boiling, mistake
It is spare to filter to extract filtrate, then mixes sodium carboxymethylcellulose, sodium pyrosulfate, ammonium chloride, polyvinyl alcohol jointly with water
After even, gained is extracted into filtrate and is added, is again stirring for uniformly, and the pH value for adjusting solution entirety is 5.6-6.2, is impregnated
Liquid.
8. a kind of sculpture modelled after an antique according to claim 1 does old technology, which is characterized in that in the step S8, by sculpture
Product is placed in vacuum pressure impregnation tank, is vacuumized, and after vacuum degree reaches -0.2 to -0.1 MPa, keeps 15min, then
It is rapidly injected the configured maceration extract, continues to keep 40mi n, is hereafter forced into 0.1-0.5MPa, keep 50min, slowly
Internal pressure is released, maceration extract is extracted out, the timber after taking out dipping.
9. a kind of sculpture modelled after an antique according to claim 1 does old technology, which is characterized in that described low in the step S9
The time that isothermal plasma handles timber is 16-18s, and the power supply of dielectric barrier discharge is high-frequency and high-voltage power supply, frequency 2kHz-
2.4kHz, voltage range 3kV-3.4kV.
10. a kind of sculpture modelled after an antique according to claim 1 does old technology, which is characterized in that described in the step S10
The mass concentration of aqueous solution of urea is 1.4%, and sculpture product is impregnated 12-13h at 46 DEG C, is cleaned and is done with clear water after pulling out
Only, 10 DEG C, relative air humidity be 40% under conditions of it is quiet put 2-3 days, make its naturally dry to water content be lower than 15% with
Under.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103387415A (en) * | 2013-07-30 | 2013-11-13 | 苏州广林建设有限责任公司 | Old style forming method of Jinshan stone with decoration effect |
| CN103865098A (en) * | 2014-03-21 | 2014-06-18 | 中南林业科技大学 | Preparation method and application of wood plastic composite |
| CN104589438A (en) * | 2014-12-09 | 2015-05-06 | 安徽省阜南志峰工艺品有限公司 | Archaizing distressing method for jujube wood |
| CN106182263A (en) * | 2016-07-13 | 2016-12-07 | 阜南县猛发工艺品有限公司 | A kind of aging wooden products processing method |
| CN108789706A (en) * | 2018-06-20 | 2018-11-13 | 桐乡市乌镇内利仿古园林建设有限公司 | A kind of ancient building does old processing method with timber |
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2019
- 2019-04-30 CN CN201910366696.2A patent/CN110001264A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103387415A (en) * | 2013-07-30 | 2013-11-13 | 苏州广林建设有限责任公司 | Old style forming method of Jinshan stone with decoration effect |
| CN103865098A (en) * | 2014-03-21 | 2014-06-18 | 中南林业科技大学 | Preparation method and application of wood plastic composite |
| CN104589438A (en) * | 2014-12-09 | 2015-05-06 | 安徽省阜南志峰工艺品有限公司 | Archaizing distressing method for jujube wood |
| CN106182263A (en) * | 2016-07-13 | 2016-12-07 | 阜南县猛发工艺品有限公司 | A kind of aging wooden products processing method |
| CN108789706A (en) * | 2018-06-20 | 2018-11-13 | 桐乡市乌镇内利仿古园林建设有限公司 | A kind of ancient building does old processing method with timber |
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Application publication date: 20190712 |